JP2012204459A - Solar battery module and method of manufacturing the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a solar battery module that exerts predetermined performance for a long term, is stably usable, has light weight and high mechanical strength and can be reduced in cost, and a method of manufacturing the same.SOLUTION: A solar battery module is provided with a surface protection layer at the surface side of a solar battery sub module through a first adhesive filled layer containing ionomer resin, and a back surface protection layer at the back surface side of the solar battery sub module through a second adhesive filled layer. In the solar battery sub module, a light absorption layer of CIGS film is formed on a substrate having an aluminum anodic oxide film formed on the surface of a metal sheet. The back surface protection layer has at least a support plate out of a back sheet and the support plate. The support plate is formed of an aluminum plate, aluminum ally plate or galvalume steel plate which has a thickness of 0.1 to 1.0 mm. The surface protection layer is formed of glass having a thickness of 0.6 to 1.5 mm. The flexural stress of the solar battery module is equal to 100 MPa or more.

Description

  The present invention relates to a thin film solar cell module using CIGS as a photoelectric conversion layer and a method for manufacturing the same, and in particular, the surface protective layer is thin glass and the back protective layer has a support plate and is lightweight and has high mechanical strength. The present invention also relates to a low-cost thin-film solar cell module and a method for manufacturing the same.

  A solar cell is formed by connecting a number of solar cells in a stacked structure in which a light absorption layer of a semiconductor that generates current by light absorption is sandwiched between a lower electrode (back electrode) and an upper electrode (transparent electrode). It is configured and formed on a substrate. A solar cell having such a configuration is attracting attention as clean energy. Therefore, research on solar cells has been actively conducted, and improvements have been attempted from various viewpoints.

As an example, solar cells are weak in moisture, and when moisture enters, characteristics such as conversion efficiency deteriorate. In particular, CIS (CuInSe ₂ ) having a chalcopyrite structure composed of Ib group, IIIb group, and VIb element, CIGS (Cu (In, Ga) Se ₂ ) obtained by further dissolving Ga in CIS, and the like, absorb light. A chalcopyrite solar cell used as a layer uses a ZnO film or the like as a transparent electrode, so that the transparent electrode is altered by the ingress of moisture. As a result, the resistance value of the transparent electrode is increased, and the conversion efficiency is greatly decreased.
However, as is well known, solar cells are often installed outdoors, such as mounts, roofs or rooftops installed outdoors. Therefore, various proposals for improving the waterproofness of the solar cell module have been made (Patent Documents 1 to 5, etc.).

  In Patent Document 1, a plurality of CIS-based thin-film solar cell device portions laminated in the order of an alkali barrier layer, a metal back electrode layer, a light absorption layer, a buffer layer, and a window layer on a glass substrate are electrically connected by a conductive pattern. Semi-strengthened white plate by using an ethylene vinyl acetate (hereinafter referred to as EVA) resin film (or sheet) cross-linked by heating and causing a polymerization reaction to the connected CIS thin film solar cell circuit (or submodule) A CIS thin film solar cell module having a structure in which a cover glass made of glass or the like is attached is described.

Patent Document 2 describes a sealing material that forms a solar cell module by sealing a solar cell element, an upper transparent protective material, and a lower substrate protective material.
The ethylene / unsaturated carboxylic acid copolymer or ionomer thereof used as the sealing material has an unsaturated carboxylic acid content of 4% by weight or more, preferably 5 to 20% by weight, and a melting point by DSC of 85 ° C. or more, preferably Is 90-110 ° C.
Patent Document 2 discloses, as solar cell elements, silicon-based materials such as single crystal silicon, polycrystalline silicon, and amorphous silicon, III-V groups such as gallium-arsenic, copper-indium-selenium, cadmium-tellurium, and II- It describes that various types of solar cell elements such as Group VI compound semiconductors can be used.

Patent documents 3-5 aim at providing the solar cell sealing material excellent in transparency, heat resistance, adhesiveness, etc.
Patent Document 3 discloses an ethylene / unsaturated carboxylic acid copolymer having an unsaturated carboxylic acid content of 4% by weight or more and a melting point of 80 ° C. or higher, or an ionomer thereof, as a solar cell encapsulating material. , (B) and (C) are described.
(A) Oligoamide-modified product obtained by melt-kneading the ethylene / unsaturated carboxylic acid copolymer or its ionomer with nylon salt or aminocarboxylic acid, and (B) the ethylene / unsaturated carboxylic acid copolymer. Or a modified polyamide oligomer obtained by melting and kneading the ionomer and a polyamide oligomer having a primary amino group at one or both ends, and (C) the ethylene / unsaturated carboxylic acid copolymer or the ionomer thereof, This is a modified polypropylene wax obtained by melt-kneading a polypropylene wax having an average molecular weight of 50,000 or less, an ethylene / α-olefin copolymer having a number average molecular weight of 100,000 or more, a radical generator and a crosslinking aid.

  In Patent Document 4, an unsaturated carboxylic acid content is 4% by weight or more and an ethylene / unsaturated carboxylic acid copolymer having a melting point of 85 ° C. or higher or its ionomer is 100 parts by weight. A solar cell element sealing material comprising a polymer composition formed by blending 1 to 30 parts by weight of an inorganic filler having a refractive index difference of 0.15 or less with an ionomer is described. Moreover, in patent document 4, an inorganic filler is a silicon compound.

Patent Document 5 discloses an ethylene / unsaturated carboxylic acid copolymer having an unsaturated carboxylic acid content of 4% by weight or more and a melting point of 85 ° C. or more, or an ionomer thereof, and a glass fiber mat having a thickness of 0.05 to 1.0 mm. Is described as a solar cell element sealing material in a solar cell module comprising a laminate in which glass fiber mats are laminated so as not to appear on the surface layer.
In Patent Documents 3 to 5, as solar cell elements, silicon-based materials such as single crystal silicon, polycrystalline silicon, and amorphous silicon, III-V groups such as gallium-arsenic, copper-indium-selenium, cadmium-tellurium, etc. Various solar cell elements such as II-VI group compound semiconductor systems can be used, and it is described that the sealing material of the present invention can be applied to sealing any of these solar cell elements.

Patent Document 6 also relates to ionomer compositions, polymer films or sheets derived therefrom, and safety laminates and their use in solar cell modules.
Patent Document 6 discloses an ionomer copolymer of an α-olefin and an α, β-ethylenically unsaturated carboxylic acid having 3 to 8 carbons, based on the total weight of the ionomer copolymer, of about 1 to about 30% by weight. A polymer film or sheet comprising an ionomer composition comprising: the carboxylic acid at a level of 1 to 100 mole percent, based on the total number of moles of carboxylate groups in the ionomer copolymer, with one or more metal ions A polymer film or sheet is described wherein the ionomer copolymer has a melt index of from about 20 to about 300 g / 10 min.

JP 2007-123725 A JP 2000-186114 A Japanese Patent Laid-Open No. 2001-119056 Japanese Patent No. 4325965 Japanese Patent No. 4437348 Special table 2010-519346

As described above, Patent Document 1 retains impact strength and waterproofness by providing the most common white plate tempered glass as the surface protective layer. However, in the case of a tempered glass having a thickness of 3.2 mm that is generally used, its weight is 7.5 kg / m ² . For this reason, in Patent Document 1, it is difficult to reduce the weight.
In patent document 2 and patent document 6, although ionomer resin sealing material is used, both weight reduction and high intensity | strength cannot be implement | achieved simultaneously.

  Moreover, even if it is a solar cell module using the solar cell element sealing material currently disclosed by patent documents 3-5, both weight reduction and high intensity | strength cannot be implement | achieved simultaneously.

  Here, as a characteristic required for the solar cell module having a long-term reliability of 20 to 30 years, it is a matter of course that the conversion efficiency of the solar cell itself is high, but weather resistance, heat resistance, flame retardancy, It is excellent in water resistance, moisture resistance, wind pressure resistance, yield resistance, and other characteristics. In addition, it is necessary to reduce the construction cost for installing the solar cell module and the panel itself together with lowering the price. In order to reduce the overall cost of conventional heavy-duty solar cell panels and solar cell modules that use tempered glass as the surface protective layer, it also takes costs such as reinforcement work to fix to ordinary houses or slate roofs, etc. It is desired to realize a solar cell module that is light in weight and excellent in performance.

  The object of the present invention is to eliminate the problems based on the above prior art, to exhibit a predetermined performance over a long period of time, to be used stably, a lightweight, high mechanical strength, and low cost solar A battery module and a manufacturing method thereof are provided.

  In order to achieve the above object, according to a first aspect of the present invention, a surface protection layer is provided on the front surface side of the solar cell submodule via a first adhesive filling layer, and on the back surface side of the solar cell submodule. A solar cell module in which a back surface protective layer is provided via a second adhesive filling layer, and the solar cell submodule is sealed by the first adhesive filling layer and the second adhesive filling layer, The back surface protective layer includes at least the support plate among the support plates that reinforce the back sheet and the solar cell module, and the support plate is an aluminum plate, aluminum alloy plate, or galbarium having a thickness of 0.1 to 1.0 mm. The first adhesive filling layer includes an ionomer resin, and the surface protective layer is made of glass having a thickness of 0.6 to 1.5 mm. In the solar cell submodule, a light absorption layer composed of a CIGS film is formed on a substrate in which an anodized aluminum film is formed on the surface of a metal sheet. The present invention provides a solar cell module having a bending stress of 100 MPa or more.

In this case, the glass constituting the surface protective layer is preferably blue plate glass or white plate glass.
In addition, the frame member has a frame member provided at a peripheral portion, the frame member includes a sealing material provided on the inside and an outer frame material provided on the outside, and the sealing material is made of butyl rubber or silicone resin. The outer frame material is preferably made of an aluminum frame or a metal foil tape.

Moreover, the board | substrate used for the said solar cell submodule is the clad material of aluminum, stainless steel, and aluminum, or the clad material of aluminum and stainless steel, for example.
Further, for example, the second adhesive filling layer does not contain the ionomer resin, and the back surface protective layer includes the support plate made of the back sheet and the galvalume steel plate.
Moreover, it is preferable that the intermediate sealing material for water vapor | steam invasion prevention is provided 5-30 mm inside from the peripheral part of the said back surface protective layer.
The intermediate sealing material is preferably composed of butyl rubber, polyolefin, polyisoprene or isoprene.

According to a second aspect of the present invention, a surface protective layer is provided on the front surface side of the solar cell submodule via a first adhesive filling layer, and a second adhesive filling layer is provided on the back surface side of the solar cell submodule. A back surface protective layer is provided, and the solar cell submodule is sealed by the first adhesive filling layer and the second adhesive filling layer,
The back surface protective layer includes at least the support plate among support plates that reinforce the back sheet and the solar cell module, and the support plate has an aluminum plate, aluminum alloy plate having a thickness of 0.1 to 1.0 mm, or It is composed of a galvalume steel plate, the first adhesive filling layer includes an ionomer resin, and the surface protective layer is composed of glass having a thickness of 0.6 to 1.5 mm. The solar cell submodule is obtained by forming a light absorption layer composed of a CIGS film on a substrate in which an anodized aluminum film is formed on the surface of a metal sheet, and the surface side of the solar cell submodule. And laminating and arranging the first adhesive filling layer and the surface protective layer, and the second adhesive filling layer and the back side of the solar cell submodule Placing by laminating a serial back surface protective layer, the plurality of layers, there is provided a method of manufacturing a solar cell module, characterized by a step of vacuum lamination in a state of being arranged by laminating.

Furthermore, in the step of arranging in a stacked manner, it is preferable to arrange an intermediate sealing material for preventing water vapor intrusion inside 5 to 30 mm from the peripheral edge of the back surface protective layer.
Moreover, it is preferable after the said vacuum laminating process to have the process of providing the frame member in which the sealing material was provided inside the outer frame material in the peripheral part of what was vacuum-laminated.

According to the present invention, mechanical strength such as wind pressure resistance and drooping resistance, and impact strength can be made equal to or higher than that of white sheet tempered glass. Further, the weight of the surface protective layer can be reduced to 25 to 47% of the white plate tempered glass (3.2 mm thick), and the support plate made of an aluminum plate, an aluminum alloy plate, or a galvalume steel plate is attached to the back surface. By providing it in the protective layer, the weight of the solar cell module can be 60 to 80% of that using tempered glass, and the solar cell module can be reduced in weight.
In addition, in order to form a CIGS film as a light absorption layer on this substrate in a roll-to-roll manufacturing method using a metal sheet on which an anodized film is formed without using a glass substrate for a solar cell submodule, A lightweight and low-cost solar cell module can be realized.

Here, moisture and water vapor diffuse from the end face (peripheral part) of the solar cell module and cause defects such as performance deterioration and wiring corrosion. However, according to the present invention, the end face (peripheral part) has a frame. It can suppress reliably by the sealing material of a member. Moreover, even if moisture permeates from the back surface, it can be prevented from reaching a transparent electrode such as a solar battery cell.
As described above, according to the present invention, it is possible to prevent moisture from entering the solar cell module, to exhibit stable performance over a long period of time, to be used stably, lightweight, high mechanical strength, and cost. A low solar cell module can be realized.
In addition, according to the manufacturing method of the solar cell module of this invention, the solar cell module which has the above-mentioned outstanding characteristic can be manufactured suitably.

(A) is typical sectional drawing which shows the arrangement | positioning state of each member before the vacuum lamination of the solar cell module of the 1st Embodiment of this invention, (b) is the 1st Embodiment of this invention. It is typical sectional drawing which shows a solar cell module. It is typical sectional drawing which shows an example of the solar cell submodule used for the solar cell module of the 1st Embodiment of this invention. (A) is typical sectional drawing which shows the arrangement | positioning state of each member before the vacuum lamination of the solar cell module of the modification of the 1st Embodiment of this invention, (b) is 1st of this invention. It is typical sectional drawing which shows the solar cell module of the modification of embodiment. (A) is typical sectional drawing which shows the arrangement | positioning state of each member before the vacuum lamination of the solar cell module of the 2nd Embodiment of this invention, (b) is the 2nd Embodiment of this invention. It is typical sectional drawing which shows a solar cell module. (A) is typical sectional drawing which shows the arrangement | positioning state of each member before the vacuum lamination of the solar cell module of the modification of the 2nd Embodiment of this invention, (b) is the 2nd of this invention. It is typical sectional drawing which shows the solar cell module of the modification of embodiment. (A) is typical sectional drawing which shows the arrangement | positioning state of each member before the vacuum lamination of the solar cell module of the 3rd Embodiment of this invention, (b) is the 3rd Embodiment of this invention. It is typical sectional drawing which shows a solar cell module. (A) is typical sectional drawing which shows the arrangement | positioning state of each member before the vacuum lamination of the solar cell module of the modification of the 3rd Embodiment of this invention, (b) is the 3rd of this invention. It is typical sectional drawing which shows the solar cell module of the modification of embodiment. It is typical sectional drawing which shows the conventional solar cell module. It is typical sectional drawing which shows the other conventional solar cell module.

Hereinafter, a solar cell module and a manufacturing method thereof according to the present invention will be described in detail based on preferred embodiments shown in the accompanying drawings.
Fig.1 (a) is typical sectional drawing which shows the arrangement | positioning state of each member before the vacuum lamination of the solar cell module of the 1st Embodiment of this invention, (b) is 1st implementation of this invention. It is typical sectional drawing which shows the solar cell module of a form.

As shown in FIG. 1B, in the solar cell module 10, a first adhesive filling layer 20 is provided on the surface 12 a of the solar cell submodule 12 so as to cover the solar cell submodule 12. An intermediate sealing material 18 is provided around the first adhesive filling layer 20. The intermediate sealing material 18 is provided at a position of a distance m from the peripheral edge α of the solar cell module 10, that is, inside the solar cell module 10.
A surface protective layer 22 is provided on the first adhesive filling layer 20 and the intermediate sealing material 18. As described above, the surface protective layer 22 is provided via the first adhesive filling layer 20.
A second adhesive filling layer 14 is provided on the back surface 12 b of the solar cell submodule 12 so as to cover the solar cell submodule 12. A back surface protective layer 16 is provided under the second adhesive filling layer 14. Thus, the back surface protective layer 16 is provided via the second adhesive filling layer 14.
The back surface protective layer 16 has, for example, a three-layer structure including a back sheet 16a, a third adhesive filling layer 16b, and a support plate 16c.

The first adhesive filling layer 20 is for sealing the solar cell submodule 12 and bonding the surface protective layer 22. The first adhesive filling layer 20 includes an ionomer resin. This ionomer resin is a mixture with an ethylene / unsaturated carboxylic acid copolymer. Specifically, as the ionomer resin, a product name Himiran (registered trademark) -ES manufactured by Mitsui-DuPont Polychemical Co., Ltd. can be suitably used.
Moreover, the thickness of the 1st contact bonding layer 20 is 100-1500 micrometers, for example, Preferably it is 400-1000 micrometers.

When the solar cell module 10 is installed outdoors, the surface protective layer 22 may be hit by rain, hail, hail, snow, stones, etc., but the solar cell sub-module 12 is protected from external forces, impacts, etc. applied from the outside. A protective material having high mechanical strength such as wind pressure resistance and drooping resistance, and high impact strength is used.
In addition to this, the surface protective layer 22 needs to be excellent in transparency, weather resistance, heat resistance, flame resistance, water resistance, moisture resistance, chemical resistance and other various characteristics.
Furthermore, the surface protective layer 22 protects the solar cell module 10 from dirt and the like, and suppresses a decrease in the amount of incident light on the solar cell submodule 12 due to dirt and the like.

The surface protective layer 22 is made of glass. As the glass, for example, low-cost blue plate glass (float glass, soda lime glass) or white plate glass is used, the thickness is 0.6 to 1.5 mm, and the thickness is 1.0 to 1.5 mm. Is preferred.
If the thickness of the surface protective layer 22 (thickness of the glass) is less than 0.6 mm, the solar cell submodule 12 cannot be sufficiently protected from external force, impact, etc. applied from the outside. On the other hand, if the thickness of the surface protective layer 22 exceeds 1.5 mm, the effect of reducing the weight cannot be obtained.
The white plate glass has a transmittance of 1 to 2% higher than the blue plate glass, and the white plate glass can increase the amount of light incident on the solar cell module.

The intermediate sealing material 18 is for suppressing moisture from entering the solar cell submodule 12 from the first adhesive filling layer 20, the second adhesive filling layer 14, and the like. The intermediate sealing material 18 is provided at a position of a distance m from the peripheral edge α of the solar cell module 10. This distance m is preferably 5 to 30 mm as a distance that does not reduce manufacturing variations and module efficiency. The width of the intermediate sealing material 18 is preferably 5 to 20 mm.
For the intermediate sealing material 18, for example, butyl rubber, polyisoprene, isoprene, polyolefin, or the like that exhibits thermoplasticity is used.

The second adhesive filling layer 14 seals the solar cell submodule 12 together with the first adhesive filling layer 20. The second adhesive filling layer 14 is for adhering the back surface protective layer 16. Similar to the first adhesive filling layer 20, the second adhesive filling layer 14 includes, for example, an ionomer resin. This ionomer resin is a mixture with an ethylene / unsaturated carboxylic acid copolymer. Specifically, as the ionomer resin, a product name Himiran (registered trademark) -ES manufactured by Mitsui-DuPont Polychemical Co., Ltd. can be suitably used.
Further, the thickness of the second adhesive layer 14 is, for example, 100 to 1500 μm, desirably 400 to 1000 μm, like the first adhesive filling layer 20.

  In the present embodiment, with respect to the second adhesive filling layer 14 between the back surface protective layer 16 and the solar cell submodule 12, an ionomer resin is used to increase the bending rigidity as the mechanical strength of the entire solar cell module 10. desirable. However, when the ionomer resin is used for the first adhesive filling layer 20 and the mechanical strength of the module laminate is satisfied by using a metal substrate for the solar cell sub-module 12, that is, the bending stress is 100 MPa or more. In some cases, a normal EVA (ethylene vinyl acetate) resin can be used for the second adhesive filling layer 14.

  The back surface protection layer 16 protects the solar cell module 10 (solar cell submodule 12) from the back side. As described above, the back surface protective layer 16 has a three-layer structure including the back sheet 16a, the third adhesive filling layer 16b, and the support plate 16c.

For the back sheet 16 a, for example, blue plate glass or white plate glass can be used similarly to the surface protective layer 22, and the thickness is the same as that of the surface protective layer 22.
In addition, a resin film can also be used for the back sheet 16a, for example, a structure in which an aluminum foil is sandwiched between resin films such as PET (polyethylene terephthalate), PEN (polyethylene naphthalate), and PVF (polyvinyl fluoride). Can be used. The configuration of the resin film is not particularly limited.

  The third adhesive filling layer 16b is for bonding the back sheet 16a and the support plate 16c. For the third adhesive filling layer 16 b, for example, a normal EVA (ethylene vinyl acetate) resin is used, and an ionomer resin can be used in the same manner as the first adhesive filling layer 20. Moreover, the thickness of the 3rd adhesion filling layer 16b is 100-1500 micrometers, for example like the 1st adhesion filling layer 20, Preferably it is 400-1000 micrometers.

The support plate 16c is for maintaining the strength of the solar cell module 10 at a predetermined strength while reducing the weight. The support plate 16c is made of, for example, a metal sheet such as an aluminum plate, an aluminum alloy plate having a good strength and corrosion resistance, such as 5000, 6000, and 7000, a galvalume steel plate, a stainless steel plate, and an aluminum-stainless steel clad steel plate. Is done. In addition, various metal members used as a back surface protective layer or a support in a known solar cell module can also be used as the support plate 16c. As the support plate 16c, you may use these metal plates and the metal member laminated | stacked with the above-mentioned glass plate or the resin film.
When a metal sheet made of an aluminum plate or an aluminum alloy plate is used for the support plate 16c, the surface is preferably anodized to improve corrosion resistance. In particular, in order to reduce the weight, a rubber sheet or a plastic resin honeycomb structure can be used as the support plate 16c in addition to the metal sheet.

  The support plate 16c has a thickness of 0.1 to 1.0 mm. When the thickness of the support plate 16c is less than 0.1 mm, the solar cell module 10 cannot obtain a predetermined strength. On the other hand, if the support plate 16c exceeds 1.0 mm, the cost increases and the low cost cannot be realized. Furthermore, the weight of the solar cell module 10 increases, and there is a possibility that weight reduction cannot be realized.

The solar cell module 10 of this embodiment has a bending stress of 100 MPa or more. If the bending stress is 100 MPa or more, the strength is equal to or higher than that of a conventional solar cell module using a tempered glass having a thickness of 3.2 mm.
The bending stress of the solar cell module 10 is obtained, for example, by measuring the yield stress with a bending tester that supports two points of the solar cell module 10 and applies stress to the center.

The solar cell module 10 of the present embodiment can be manufactured as follows.
First, as shown in FIG. 1A, a back sheet 16a, a third adhesive filling layer 16b, and a support are provided on the back surface 12b side of the solar cell submodule 12 as a second adhesive filling layer 14 and a back surface protective layer 16. The plates 16c are stacked and arranged. Next, on the surface 12 a side of the solar cell submodule 12, the first adhesive filling layer 20 and the intermediate sealing material 18 around the first adhesive filling layer 20 are located at a distance m from the peripheral portion α, for example, 5 to 30 mm inside. Further, the surface protective layer 22 is laminated on the first adhesive filling layer 20 and the intermediate sealing material 18 and disposed. Thereby, as shown to Fig.1 (a), it will be in the state by which each member was laminated | stacked and arrange | positioned.
Thereafter, in a state where the respective members are stacked and arranged, for example, using a vacuum laminator having a lifting means, a buffer plate, and a heating means, for example, at a temperature of 130 to 150 ° C., a total of 15 vacuum / press / holds. Vacuum laminate for ~ 30 minutes. Thereby, the solar cell module 10 of this embodiment shown in FIG.1 (b) is produced.

In the solar cell module 10 shown in FIG. 1B, the solar cell submodule 12 is an integrated structure of solar cells 40 that are photoelectric conversion elements, as shown in FIG. Note that a discrete type having one solar battery cell 40 is also included in the solar battery submodule.
Hereinafter, a specific example of the solar cell submodule 12 will be described in detail with reference to FIG.

  As shown in FIG. 2, the solar cell submodule 12 has a plurality of solar cells 40 including a lower electrode 32, a light absorption layer 34, a buffer layer 36, and an upper electrode 38 connected in series on a substrate 50. It will be. This solar cell (photoelectric conversion element) 40 uses a CIGS semiconductor compound as the light absorption layer 34. The solar cell submodule 12 has a first conductive member 42 and a second conductive member 44.

In the solar cell submodule 12, the substrate 50 is a flexible substrate including a base material 52, an Al (aluminum) layer 54, and an insulating layer 56.
The base material 52 and the Al layer 54 are integrally formed. The insulating layer 56 is an anodic oxide film having an Al porous structure formed by anodizing the surface of the Al layer 54. The clad substrate in which the base material 52 and the Al layer 54 are laminated and integrated is referred to as a metal substrate 55.

In the solar cell submodule 12 of the present invention, mild steel, heat resistant steel, or stainless steel is used as the (metal) base material 52 constituting the substrate 50.
The thickness of the substrate 52 is not particularly limited, but is preferably 10 to 1000 μm in consideration of the balance between flexibility and strength (rigidity), handling properties, and the like.

The Al layer 54 is a layer mainly composed of Al, and various types of Al and Al alloys can be used. In particular, Al having a purity of 99% by mass or more with few impurities is preferable. As purity, for example, 99.99 mass% Al, 99.96 mass% Al, 99.9 mass% Al, 99.85 mass% Al, 99.7 mass% Al, 99.5 mass% Al, etc. are preferable. .
Moreover, even if it is not high purity Al, industrial Al can also be utilized. Use of industrial Al is advantageous in terms of cost. However, it is important that Si is not precipitated in Al in terms of the insulating property of the insulating layer 56.

The thickness of the Al layer 54 is not particularly limited and can be appropriately selected. In the state where the solar cell submodule 12 is obtained, the thickness of the Al layer 54 is preferably 0.1 μm or more and less than the thickness of the base material 52. .
The Al layer 54 is formed by pretreatment of the Al surface, formation of the insulating layer 56 by anodic oxidation, generation of an intermetallic compound on the surface of the Al layer 54 and the substrate 52 during the formation of the light absorption layer 34, and the like. The thickness decreases. Therefore, the thickness at the time of forming an Al layer 54 to be described later is Al between the base material 52 and the insulating layer 56 in a state where the solar cell submodule 12 is formed in consideration of thickness reduction due to these. It is important that the thickness be such that layer 54 remains. For this reason, the thickness of the Al layer 54 is required to be 10 to 50 μm in order to form an insulating layer by anodic oxidation.

An insulating layer 56 is formed on the Al layer 54 (on the side opposite to the substrate 52). The insulating layer 56 is an Al anodic oxide film formed by anodizing the surface of the Al layer 54.
Here, various anodic oxide films formed by anodizing Al can be used for the insulating layer 56, but a porous anodic oxide film is preferable. This anodic oxide film is an alumina oxide film having pores of several tens of nanometers. Since the Young's modulus of the film is low, the film is highly resistant to bending and cracking caused by a difference in thermal expansion at high temperatures.

  The thickness of the insulating layer 56 is preferably 2 μm or more, and more preferably 5 μm or more. When the thickness of the insulating layer 56 is excessively large, it is not preferable because flexibility is lowered and cost and time required for forming the insulating layer 56 are required. Actually, the thickness of the insulating layer 56 is 50 μm or less, preferably 30 μm or less at maximum. For this reason, the preferable thickness of the insulating layer 56 is 2 to 50 μm.

Although the solar cell module 10 of this embodiment is a rigid type, a flexible substrate is used for the solar cell submodule 12, and for example, an insulation having a plurality of pores by anodization on a metal substrate 55 having a thickness of 50 to 200 μm. A layer 56 (insulating oxide film) is formed, and high insulation is ensured.
The substrate 50 used in the solar cell submodule 12 of this embodiment may be subjected to a specific sealing process after the Al layer 54 is anodized to form the insulating layer 56. The manufacturing process may include various processes other than the essential processes. For example, a degreasing process for removing the adhering rolling oil, a desmutting process for dissolving the smut on the surface of the Al layer 54, a roughening process for roughening the surface of the Al layer 54, and an anode on the surface of the Al layer 54 The substrate 50 is preferably subjected to an anodizing process for forming an oxide film and a sealing process for sealing the micropores of the anodized film.

In addition, the board | substrate 50 becomes flexible as the board | substrate 50 whole by making all the base material 52, Al layer 54, and the insulating layer 56 have flexibility, ie, a flexible thing. Thereby, for example, an alkali supply layer, a lower electrode, a light absorption layer, an upper electrode, and the like described later can be formed on the insulating layer 56 side of the substrate 50 by a roll-to-roll method.
In the present invention, a solar cell structure may be produced by continuously forming a plurality of layers from one roll unwinding to winding, or roll unwinding, film forming, winding The solar cell structure may be formed by performing the taking step a plurality of times. Further, as will be described later, an integration in which a plurality of solar cells 40 are electrically connected in series by adding a scribing process for separating and integrating the elements between the respective film forming processes to the production by the roll-to-roll method. Type solar cell submodule can be manufactured.

In the present invention, the Al layer 54 and the insulating layer 56 are not limited to be formed only on one surface of the base material 52, and the substrate in which the Al layer 54 and the insulating layer 56 are formed on both surfaces of the base material 52 is used. Alternatively, the Al layer may be a single layer, that is, an Al substrate provided with an insulating layer composed of the above-described anodized film.
As the metal substrate, a material in which a metal oxide film formed on the surface of the metal substrate by anodic oxidation is an insulator can be used. Therefore, in addition to aluminum (Al), specifically, zirconium (Zr), titanium (Ti), magnesium (Mg), copper (Cu), niobium (Nb), tantalum (Ta), etc., and their Alloys can be used. Aluminum is most preferable from the viewpoint of cost and characteristics required for the solar cell module.
Further, a so-called clad material may be used in which the metal layer is formed by rolling or hot dipping on a steel plate such as mild steel or stainless steel in order to improve heat resistance.

Here, an alkali supply layer 58 (an alkali metal supply source to the light absorption layer 34) is formed between the insulating layer 56 (substrate 50) and the lower electrode 32, that is, on the surface 56a of the insulating layer 56.
It is known that when an alkali metal (particularly Na) is diffused into the light absorption layer 34 made of CIGS, the photoelectric conversion efficiency is increased.
The alkali supply layer 58 is a layer for supplying an alkali metal to the light absorption layer 34 and is a layer of a compound containing an alkali metal. In the present invention, such an alkali supply layer 58 is provided between the insulating layer 56 and the lower electrode 32, so that when the light absorption layer 34 is formed, the alkali metal passes through the lower electrode 32 to the light absorption layer 34. It can diffuse and improve the conversion efficiency of the light absorption layer 34.

The alkali supply layer 58 is not limited, and a compound containing an alkali metal (a composition containing an alkali metal compound) such as NaO ₂ , Na ₂ S, Na ₂ Se, NaCl, NaF, or sodium molybdate is a main component. Various things are available. In particular, a compound containing SiO ₂ (silicon oxide) as a main component and NaO ₂ (sodium oxide) is preferable.
The compound of SiO ₂ and NaO ₂ have poor moisture resistance, since tends to carbonate was separated Na component, a metal component with added Ca more oxide that was three components Si-Na-Ca preferable.

In the present invention, the alkali metal supply source to the light absorption layer 34 is not limited to the alkali supply layer 58 alone.
For example, when the insulating layer 56 is the above-described porous anodic oxide film, a compound containing an alkali metal is introduced into the porous layer of the insulating layer 56 in addition to the alkali supply layer 58, so that the light absorption layer 34 may be an alkali metal supply source. Alternatively, the alkali supply layer 58 may not be provided, and a compound containing an alkali metal may be introduced only into the porous layer of the insulating layer 56 to serve as an alkali metal supply source to the light absorption layer 34.
As an example, when the alkali supply layer 58 is formed by sputtering, only the alkali supply layer 58 in which no compound containing an alkali metal exists in the insulating layer 56 can be formed. In addition, the insulating layer 56 is a porous anodic oxide film, and when the alkali supply layer 58 is formed by sol-gel reaction or dehydration drying of a sodium silicate aqueous solution, not only the alkali supply layer 58 but also the insulating layer 56 is formed. By introducing a compound containing an alkali metal into the porous layer, both the insulating layer 56 and the alkali supply layer 58 can serve as an alkali metal supply source to the light absorption layer 34.

In the solar cell submodule 12, the lower electrode 32 is formed on the alkali supply layer 58 so as to be arranged with a predetermined gap 33 from the adjacent lower electrode 32. Further, a light absorption layer 34 is formed on the lower electrode 32 while filling the gaps 33 of the lower electrodes 32. A buffer layer 36 is formed on the surface of the light absorption layer 34.
The light absorption layer 34 and the buffer layer 36 are arranged on the lower electrode 32 with a predetermined gap 37. Note that the gap 33 between the lower electrode 32 and the light absorption layer 34 (buffer layer 36) are formed at different positions in the arrangement direction of the solar cells 40.

Further, an upper electrode 38 is formed on the surface of the buffer layer 36 so as to fill the gap 37 of the light absorption layer 34 (buffer layer 36).
The upper electrode 38, the buffer layer 36 and the light absorption layer 34 are arranged with a predetermined gap 39. The gap 39 is provided at a position different from the gap between the lower electrode 32 and the gap between the light absorption layer 34 (buffer layer 36).
In the solar battery submodule 12, each solar battery cell 40 is electrically connected in series in the longitudinal direction of the substrate 50 (arrow L direction) by the lower electrode 32 and the upper electrode 38.

The lower electrode 32 is composed of, for example, a Mo electrode. The light absorption layer 34 is composed of a semiconductor compound having a photoelectric conversion function, for example, a CIGS film. Further, the buffer layer 36 is made of, for example, CdS, and the upper electrode 38 is made of, for example, ZnO.
The solar battery cell 40 is formed to extend long in the width direction orthogonal to the longitudinal direction L of the substrate 50. For this reason, the lower electrode 32 and the like also extend long in the width direction of the substrate 50.

As shown in FIG. 3, a first conductive member 42 is connected on the lower electrode 32 at the right end. The first conductive member 42 is for taking out an output from a negative electrode to be described later.
The first conductive member 42 is, for example, an elongated belt-like member, extends substantially linearly in the width direction of the substrate 50, and is connected to the lower electrode 32 at the right end. As shown in FIG. 3, the first conductive member 42 is formed, for example, by coating a copper ribbon 42 a with a coating material 42 b made of indium copper alloy. The first conductive member 42 is connected to the lower electrode 32 by, for example, ultrasonic soldering. Alternatively, the first conductive member 42 may be a conductive tape having an embossed structure formed by hot-plating In-Sn on a copper foil, and this conductive tape is connected by being bonded to the lower electrode 32 by pressure bonding with a roller. The

On the other hand, a second conductive member 44 is formed on the lower electrode 32 at the left end.
The second conductive member 44 is for taking out the output from the positive electrode, which will be described later, to the outside. Like the first conductive member 42, the second conductive member 44 is a strip-like member that extends substantially linearly in the width direction of the substrate 50. And connected to the lower electrode 32 at the left end.
The second conductive member 44 has the same configuration as that of the first conductive member 42. For example, the copper ribbon 44a is coated with a coating material 44b of indium copper alloy. You may connect.

  In addition, the light absorption layer 34 of the photovoltaic cell 40 of this embodiment is comprised by CIGS, and can be manufactured with the manufacturing method of a well-known CIGS type solar cell.

  In the solar cell submodule 12, when light enters the solar cell 40 from the upper electrode 38 side, this light passes through the upper electrode 38 and the buffer layer 36, and an electromotive force is generated in the light absorption layer 34. For example, a current from the upper electrode 38 toward the lower electrode 32 is generated. Note that the arrows shown in FIG. 2 indicate the direction of current, and the direction of movement of electrons is opposite to the direction of current. For this reason, in the photoelectric conversion unit 48, the leftmost lower electrode 32 in FIG. 2 is a positive electrode (positive electrode), and the rightmost lower electrode 32 is a negative electrode (negative electrode).

In the present embodiment, the electric power generated in the solar cell submodule 12 can be taken out of the solar cell submodule 12 from the first conductive member 42 and the second conductive member 44.
In the present embodiment, the first conductive member 42 is a negative electrode, and the second conductive member 44 is a positive electrode. Further, the first conductive member 42 and the second conductive member 44 may have opposite polarities, and are appropriately changed depending on the configuration of the solar battery cell 40, the solar battery submodule 12 configuration, and the like.
Moreover, in this embodiment, although each photovoltaic cell 40 was formed so that it might be connected in series with the longitudinal direction L of the board | substrate 50 by the lower electrode 32 and the upper electrode 38, it is not limited to this. For example, each solar battery cell 40 may be formed such that each solar battery cell 40 is connected in series in the width direction by the lower electrode 32 and the upper electrode 38.

  In the solar cell 40, the lower electrode 32 and the upper electrode 38 are both for taking out the current generated in the light absorption layer 34. Both the lower electrode 32 and the upper electrode 38 are made of a conductive material. The upper electrode 38 on the light incident side needs to have translucency.

The lower electrode (back electrode) 32 is made of, for example, Mo, Cr, or W, and a combination thereof. The lower electrode 32 may have a single layer structure or a laminated structure such as a two-layer structure. The lower electrode 32 is preferably made of Mo.
The lower electrode 32 preferably has a thickness of 100 nm or more, and more preferably 0.45 to 1.0 μm.
The method for forming the lower electrode 32 is not particularly limited, and can be formed by a vapor phase film forming method such as an electron beam evaporation method or a sputtering method.

The upper electrode (transparent electrode) 38 is made of, for example, ZnO to which Al, B, Ga, Sb or the like is added, ITO (indium tin oxide), SnO ₂ , or a combination thereof. The upper electrode 38 may have a single layer structure or a laminated structure such as a two-layer structure. Further, the thickness of the upper electrode 38 is not particularly limited, and is preferably 0.3 to 1 μm.
The formation method of the upper electrode 38 is not particularly limited, and can be formed by a vapor deposition method such as an electron beam evaporation method or a sputtering method, or a coating method.

The buffer layer 36 is formed to protect the light absorption layer 34 when the upper electrode 38 is formed and to transmit light incident on the upper electrode 38 to the light absorption layer 34.
The buffer layer 36 is made of, for example, CdS, ZnS, ZnO, ZnMgO, ZnS (O, OH), or a combination thereof.
The buffer layer 36 preferably has a thickness of 0.03 to 0.1 μm. The buffer layer 36 is formed by, for example, a CBD (chemical bath) method.

The light absorption layer 34 is a layer that absorbs light that has passed through the upper electrode 38 and the buffer layer 36 and generates a current, and has a photoelectric conversion function. The light absorption layer 34 is composed of a CIGS film, and the CIGS film is made of a semiconductor having a chalcopyrite crystal structure. The composition of the CIGS film is, for example, Cu (In _1-x Ga _x ) Se ₂ (CIGS).

As a CIGS film forming method, 1) a multi-source deposition method, 2) a selenization method, 3) a sputtering method, 4) a hybrid sputtering method, and 5) a mechanochemical process method are known.
Other CIGS film formation methods include screen printing, proximity sublimation, MOCVD, and spray (wet film formation). For example, a fine particle film containing a group Ib element, a group IIIb element, and a group VIb element is formed on a substrate by a screen printing method (wet film forming method) or a spray method (wet film forming method), and then pyrolyzed ( At this time, a crystal having a desired composition can be obtained by performing a thermal decomposition treatment in a VIb group element atmosphere (JP-A-9-74065, JP-A-9-74213, etc.).
Such a film forming method shows good photoelectric conversion efficiency if CIGS is formed on the substrate as long as the temperature is 500 ° C. or higher, but the process time is short in consideration of manufacturing in a roll-to-roll method. Multisource deposition is preferred. In particular, the bilayer method is suitable.

As described above, the solar cell sub-module 12 of the present invention is manufactured by manufacturing the solar cells 40 in series on the substrate 50 described above. What is necessary is just to perform like a battery.
Hereinafter, an example of the manufacturing method of the solar cell submodule 12 shown in FIG. 2 will be described.

First, the substrate 50 formed as described above is prepared. Next, the alkali supply layer 58 is formed on the surface of the insulating layer 56 of the substrate 50 by, for example, sputtering using soda lime glass as a target or a sol-gel method using an alkoxide containing Si and Na.
Next, a Mo film to be the lower electrode 32 is formed on the surface of the alkali supply layer 58 by sputtering using, for example, a film forming apparatus.
Next, using a laser scribing method, for example, a predetermined position of the Mo film is scribed to form a gap 33 extending in the width direction of the substrate 50. Thereby, the lower electrodes 32 separated from each other by the gap 33 are formed.

Next, a CIGS film is formed as a light absorption layer 34 (p-type semiconductor layer) so as to cover the lower electrode 32 and fill the gap 33. This CIGS film is formed by any of the film forming methods described above.
Next, a CdS layer (n-type semiconductor layer) to be the buffer layer 36 is formed on the light absorption layer 34 (CIGS film) by, for example, a CBD (chemical bath) method. Thereby, a pn junction semiconductor layer is formed.
Next, a gap 37 extending in the width direction of the substrate 50 and reaching the lower electrode 32 is formed by scribing a predetermined position different from the gap 33 in the arrangement direction of the solar cells 40 using, for example, a laser scribing method. To do.

Next, on the buffer layer 36, for example, an ITO layer, a ZnO layer to which Al, B, Ga, Sb, or the like is added is formed by sputtering or coating so as to fill the gap 37. To do.
Next, the gaps 33 and 37 are gaps reaching a lower electrode 32 extending in the width direction of the substrate 50 by scribing a predetermined position different in the arrangement direction of the solar cells 40 using, for example, a laser scribing method. 39 is formed. Thereby, the photovoltaic cell 40 is formed.

Next, the solar cells 40 formed on the lower electrodes 32 at the left and right ends in the longitudinal direction L of the substrate 50 are removed by, for example, laser scribing or mechanical scrub, and the lower electrodes 32 are exposed. Next, the first conductive member 42 is connected to the lower electrode 32 at the right end, and the second conductive member 44 is connected to the lower electrode 32 at the left end using, for example, a conductive tape.
Thereby, as shown in FIG. 2, the solar cell submodule 12 in which the plurality of solar cells 40 are electrically connected in series can be manufactured.

In the solar cell module 10 of the present embodiment shown in FIG. 1B, the back surface protection layer 16 has a two-layer structure of a back sheet 16a and a support plate 16c, and, for example, a metal sheet is used for the support plate 16c. It is possible to achieve both weight reduction and high mechanical strength.
Moreover, since the surface protective layer 22 is made of glass having a thickness of 0.6 to 1.5 mm, the weight can be reduced to 25 to 47% of white plate tempered glass (3.2 mm thickness).
Furthermore, even when the back surface protective layer 16 is used for the support plate 16c, for example, a metal sheet is used, the weight of the solar cell module 10 is set to 60 to 80% of the weight using tempered glass. The solar cell module 10 can be reduced in weight.

By forming a CIGS film as a light-absorbing layer using a substrate in which an anodized film of aluminum is formed on the surface of a metal sheet that can be manufactured by a roll-to-roll manufacturing method, instead of a glass substrate as the solar cell submodule 12 A light-weight and low-cost solar cell module can be obtained.
In addition, according to the manufacturing method of the solar cell module 10 of this embodiment, the solar cell module 10 which has the above-mentioned outstanding characteristic can be manufactured suitably.

Here, a schematic cross-sectional view of a conventional solar cell module is shown in FIGS. In a conventional solar cell module 100 a shown in FIG. 8, a solar cell submodule 110 is surrounded by an adhesive filling layer 102, and a surface protective layer 104 is provided on the upper surface of the adhesive filling layer 102. Further, a back surface protective layer 106 is provided on the lower surface of the adhesive filling layer 102.
Further, the conventional solar cell module 100b of FIG. 9 differs from the solar cell module 100a shown in FIG. 8 in that a sealing material 112 is provided on the side end face 108, and the other configuration is a solar cell module. The same as 100a.

  In general, the surface of the solar cell submodule is formed of a transparent conductive film such as an ITO film, a ZnO (Al) film, or a ZnO (B) film. These transparent conductive films are very sensitive to moisture due to their materials. In the case of the solar cell module 100a configured as shown in FIG. 8, the side end surface 108 of the adhesive filling layer 102 surrounding the solar cell submodule 110 is exposed to the outside, and moisture enters the side end surface 108 to It reaches the surface of the battery submodule 110 and raises the resistance of the transparent conductive film, or reaches the junction under the transparent conductive film to generate a leakage current, thereby deteriorating the characteristics of the solar cell module. cause.

  On the other hand, in the case of the solar cell module 100b having the configuration shown in FIG. 9, since the side end face 108 of the adhesive filling layer 102 is covered with the sealing material 112, at first glance, moisture intrusion from the side end face 108 is prevented. Looks like you can. However, the outer periphery of the solar cell module 100b bends due to the difference in thermal expansion and contraction of the adhesive filling layer 102, the surface protective layer 104, the back surface protective layer 106, etc. in a high temperature and high humidity environment, and the peripheral edge of the sealing material 112 As a result, the intrusion of moisture from the side end face 108 of the solar cell module 100b cannot be prevented.

  On the other hand, in the solar cell module 10 shown in FIG. 1B, the intermediate sealing material 18 is arranged on the inner side of the periphery of the back surface protective layer 16 so that the intermediate sealing material 18 has the surface protective layer 22 and the back surface protective layer. Since 16 is located inside the solar cell module 10 joined, it is not exposed to the outside, and the intermediate sealing material 18 is not bent or peeled off due to the difference in thermal expansion and contraction. . The intermediate sealing material 18 is provided from at least the back surface 12b of the solar cell submodule 12 to the surface protective layer 22, and the intermediate sealing material 18 contacts the surface protective layer 22 to seal the first adhesive filling layer 20. Water intrusion from the side surface of the first adhesive filling layer 20 can be prevented, and water intrusion from at least the surface 12a side (upper side) of the solar cell submodule 12 can be suppressed. Further, a solar cell capable of reducing the generation of a corrosive substance generated by a reaction between moisture and the adhesive constituting the first adhesive filling layer 20, for example, acetic acid, and exhibiting stable performance over a long period of time. Module 10 may be used.

  In the solar cell module 10 shown in FIG. 1B, the intermediate sealing material 18 is provided from the back surface 12b to the surface protective layer 22 of the solar cell submodule 12. However, the intermediate sealing material 18 is protected from the back surface. The second adhesive layer 14 may be separated by contacting the back sheet 16a of the layer 16 as well. With such a configuration, the intermediate sealing material 18 can also suppress moisture intrusion from the second adhesive layer 14, and corrosive substances generated by the reaction between the moisture and the second adhesive layer 14 can be prevented. It becomes possible to reduce more effectively, and it is possible to suppress a decrease in conversion efficiency of the solar cell submodule 12 due to an improvement in resistance due to alteration of the transparent electrode of the solar cell submodule 12 and to exhibit stable performance over a long period of time. The solar cell module 10 can be made.

In the present embodiment, the back surface protective layer 16 has a three-layer structure. However, like the solar cell module 10a shown in FIG. 3B, the back surface protective layer 16 has at least a support plate 16c. I just need it. In this case, the support plate 16 c serving as the back surface protective layer 16 is directly bonded to the second adhesive filling layer 14. Like the solar cell module 10a, by comprising the back surface protection layer 16 only with the support plate 16c, weight reduction and cost reduction can be achieved, maintaining predetermined intensity | strength about the solar cell module 10a.
When the solar cell module 10a shown in FIG. 3B is manufactured, as shown in FIG. 3A, for the back surface protective layer 16, the support plate 16c that becomes the back surface protective layer 16 is filled with the second adhesive. Since it only arrange | positions on the back surface of the layer 14, it can manufacture easily compared with the preparation methods of the solar cell module 10 shown to Fig.1 (a).

Next, a second embodiment will be described.
FIG. 4A is a schematic cross-sectional view showing an arrangement state of each member before vacuum lamination of the solar cell module according to the second embodiment of the present invention, and FIG. 4B is a second embodiment of the present invention. It is typical sectional drawing which shows the solar cell module of a form.
In addition, in this embodiment, the same code | symbol is attached | subjected to the same structure as the solar cell module 10 of 1st Embodiment shown to Fig.1 (a), (b), and the detailed description is abbreviate | omitted.

  As shown in FIG. 4B, the solar cell module 10b of the present embodiment is provided with an intermediate sealing material 18 as compared to the solar cell module 10 of the first embodiment (see FIG. 1B). The frame member 24 is formed on the peripheral portion β of the solar cell laminate 30 including the solar cell submodule 12, the second adhesion filling layer 14, the back surface protection layer 16, the first adhesion filling layer 20, and the surface protection layer 22. Since the other configuration is the same as that of the solar cell module 10 of the first embodiment, detailed description thereof is omitted.

  As shown in FIG. 4B, in the solar cell module 10b of the present embodiment, the frame member 24 improves the mechanical resistance of the solar cell module 10b, and improves the moisture diffusion resistance and moisture resistance from the peripheral portion β. It is for making it happen. The frame member 24 includes a peripheral sealing material 26 and an outer frame material 28 having a groove (concave portion). The peripheral sealing material 26 is provided on the inner side, and the outer frame material 28 is provided on the outer side.

As the peripheral sealing material 26, for example, butyl rubber, polyisoprene, isoprene, polyolefin, or the like that exhibits thermoplasticity is used. In addition, a silicone sealing material can be used as the peripheral sealing material 26.
The outer frame member 28 may be formed of a foil shape or a frame shape. The outer frame material 28 can be formed using, for example, aluminum, an aluminum alloy, copper, or a copper alloy. Furthermore, the outer frame material which carried out the alumite process for corrosion resistance improvement may be sufficient. For example, when a metal foil is used as the outer frame member 28, aluminum, an aluminum alloy, copper, or a copper alloy can be used. The thickness of the metal foil is, for example, 50 to 300 μm. The metal foil may be provided with an adhesive material in advance.

The outer frame member 28 may be a metal foil tape in which a black PET film is bonded to a metal foil from the viewpoint of the aesthetics and design of the solar cell module 10b.
When further moisture resistance is required, for example, butyl rubber is used for the peripheral seal material 26 and an L-shaped aluminum frame is used for the outer frame material 28.

In addition, the solar cell module 10b of this embodiment can be produced as follows.
Similar to the solar cell module 10 of the first embodiment, the solar cell module 10b of the present embodiment has a second adhesive filling layer on the back surface 12b side of the solar cell submodule 12 as shown in FIG. 14. As the back surface protective layer 16, a back sheet 16a, a third adhesive filling layer 16b, and a support plate 16c are laminated and disposed. Next, the first adhesive filling layer 20 and the surface protective layer 22 are laminated and disposed on the surface 12 a side of the solar cell submodule 12. Thereby, as shown to Fig.4 (a), it will be in the state by which each member was laminated | stacked and arrange | positioned.
Thereafter, in a state where the respective members are stacked and arranged, for example, using a vacuum laminator having a lifting means, a buffer plate, and a heating means, for example, at a temperature of 130 to 150 ° C., a total of 15 vacuum / press / holds. Apply vacuum lamination for ~ 30 minutes. Thereby, the solar cell laminated body 30 is formed (refer FIG.4 (b)).

Next, as shown in FIG. 4 (b), the peripheral sealing material 26 of the frame member 24 is attached to the peripheral portion β of the solar cell stack 30 and a part of the surface protective layer 22 surface and the support plate 16 c of the back protective layer 16. It is provided so as to cover a part of the surface. Then, the groove portion (concave portion) of the outer frame material 28 is fitted onto the peripheral seal material 26 and further bonded. Thus, the solar cell module 10b of this embodiment is produced.
Also in the solar cell module 10b of the present embodiment, since the configuration of the back surface protective layer 16 is the same as that of the solar cell module 10 of the first embodiment, the same effect as that of the solar cell module 10 of the first embodiment is obtained. be able to. Furthermore, mechanical resistance, moisture diffusion resistance and moisture resistance can be improved.

In this embodiment, the back surface protective layer 16 has a three-layer structure. However, like the solar cell module 10c shown in FIG. 5B, the back surface protective layer 16 has at least a support plate 16c. I just need it. In this case, the support plate 16 c serving as the back surface protective layer 16 is directly bonded to the second adhesive filling layer 14. Like the solar cell module 10c, by comprising the back surface protective layer 16 only with the support plate 16c, weight reduction and cost reduction can be achieved, maintaining predetermined intensity | strength about the solar cell module 10c.
When the solar cell module 10c shown in FIG. 5B is manufactured, as shown in FIG. 5A, for the back surface protective layer 16, the support plate 16c that becomes the back surface protective layer 16 is filled with the second adhesive. Since it only arrange | positions on the back surface of the layer 14, it can manufacture easily compared with the production method of the solar cell module 10b shown to Fig.4 (a).

Next, a third embodiment will be described.
FIG. 6A is a schematic cross-sectional view showing the arrangement state of each member before vacuum lamination of the solar cell module of the third embodiment of the present invention, and FIG. 6B is the third embodiment of the present invention. It is typical sectional drawing which shows the solar cell module of a form.
In addition, in this embodiment, the same code | symbol is attached | subjected to the same structure as the solar cell module 10 of 1st Embodiment shown to Fig.1 (a), (b), and the detailed description is abbreviate | omitted.

  As shown in FIG.6 (b), the solar cell module 10d of this embodiment is the solar cell module 10 (solar cell) compared with the solar cell module 10 (refer FIG.1 (b)) of 1st Embodiment. Since the frame member 24 is provided at the peripheral edge β of the laminated body 30a), and the other configuration is the same as that of the solar cell module 10 of the first embodiment, the detailed description thereof is as follows. Omitted.

In the solar cell module 10d of the present embodiment, the frame member 24 is for improving mechanical resistance and improving moisture diffusion resistance and moisture resistance from the peripheral edge β.
In addition, since the frame member 24 is the structure similar to the solar cell module 10b of 2nd Embodiment, the detailed description is abbreviate | omitted.

The solar cell module 10d of this embodiment can be manufactured as follows. First, as in the first embodiment, as shown in FIG. 6B, on the back surface 12b side of the solar cell submodule 12, as the second adhesive filling layer 14 and the back surface protective layer 16, a back sheet 16a, The third adhesive filling layer 16b and the support plate 16c are stacked and arranged. Next, on the surface 12 a side of the solar cell submodule 12, the first adhesive filling layer 20, the intermediate sealing material 18 around the first adhesive filling layer 20, a distance m from the peripheral edge β, for example, 5 to 30 mm inside Further, the surface protective layer 22 is laminated on the first adhesive filling layer 20 and the intermediate sealing material 18 and disposed. Thereby, as shown to Fig.6 (a), it will be in the state by which each member was laminated | stacked and arrange | positioned.
Next, in a state where the respective members are stacked and arranged, for example, using a vacuum laminator having an elevating means, a buffer plate, and a heating means, for example, at a temperature of 130 to 150 ° C., a vacuum / press / hold total Vacuum laminate for 15-30 minutes. Thereby, the solar cell laminated body 30a is formed (refer FIG.6 (b)).

Next, as shown in FIG. 6 (b), the peripheral sealing material 26 of the frame member 24 is applied to the peripheral edge β of the solar cell stack 30 a with a part of the surface protective layer 22 surface and one surface of the back surface protective layer 16. Provide to cover the part. Then, the groove portion (concave portion) of the outer frame material 28 is fitted onto the peripheral seal material 26 and further bonded. In this way, the solar cell module 10d of this embodiment is manufactured.
In the solar cell module 10d of the present embodiment, the same effects as those of the solar cell module 10 of the first embodiment can be obtained, and further, mechanical resistance, moisture diffusion resistance and moisture resistance can be further improved. it can.

In this embodiment, the back surface protective layer 16 has a three-layer structure. However, like the solar cell module 10e shown in FIG. 7B, the back surface protective layer 16 has at least a support plate 16c. I just need it. In this case, the support plate 16 c serving as the back surface protective layer 16 is directly bonded to the second adhesive filling layer 14. Like the solar cell module 10e, by comprising the back surface protection layer 16 only with the support plate 16c, weight reduction and cost reduction can be achieved, maintaining predetermined intensity | strength about the solar cell module 10a.
When the solar cell module 10e shown in FIG. 7B is manufactured, as shown in FIG. 7A, for the back surface protective layer 16, the support plate 16c that becomes the back surface protective layer 16 is filled with the second adhesive. Since it only arrange | positions on the back surface of the layer 14, it can manufacture easily compared with the preparation methods of the solar cell module 10d shown to Fig.6 (a).

  The present invention is basically configured as described above. As mentioned above, although the solar cell module of this invention and its manufacturing method were demonstrated in detail, this invention is not limited to the said embodiment, In the range which does not deviate from the main point of this invention, you may make a various improvement or change. Of course.

Hereinafter, the solar cell module of the present invention will be described more specifically.
In this example, test structures of Experimental Examples 1 to 7 shown in Table 1 below were produced in order to examine a lightweight and high mechanical strength solar cell module structure. And in order to evaluate the performance (yield stress, bending stress, displacement at yield) of the test structures of Experimental Examples 1-7, yield stress, displacement at yield using a bending tester (Shimadzu AG-10FD). Was measured.
In this example, the size of the test structures of Experimental Examples 1 to 7 was 15 cm × 7.5 cm. In the bending test, the test structure of Experimental Examples 1 to 7 was supported at a fulcrum interval of 10 cm, the center of the fulcrum interval was pushed from above, and the pushing speed was 1 mm / min.
In this example, the bending stress is obtained by converting the force applied to the size of the test structure 10 × 7.5 = 75 cm ² into stress (N / m ² ). Can be sought.

Bending stress σ = 3FL / 2bh ²
σ: Bending stress (MPa) F: Yield stress (N) L: Distance between supporting points (mm) b: Width (mm), h: Thickness (mm)

In the structure of the test structure shown in Table 1 below, the white plate reinforced GL of Example 1 is a single piece of white plate tempered glass, and the total thickness is 3.2 mm.
GL1.1 indicates that the surface protective layer is blue plate glass and the thickness is 1.1 mm. HM0.8 indicates that the sealing material of the adhesive filling layer is Himiran (registered trademark) -ES (HM) manufactured by Mitsui Deyupon Polychemical Co., Ltd., and the thickness is 0.8 mm.
EVA0.8 shows that the sealing material for the adhesive filling layer is Mitsui Chemicals Fabro Co., Ltd. solar eva, and the thickness is 0.8 mm.
EVA0.4 shows that the sealing material of the adhesive filling layer is Mitsui Chemicals Fabro Co., Ltd. solar eva, and the thickness is 0.4 mm.
The PV substrate 0.08 corresponds to the substrate of the solar cell submodule. This PV substrate 0.08 is a clad material of Al and SUS, and indicates that the thickness is 0.08 mm.
The back sheet 0.3 is a repnea TFB MD manufactured by Lintec Corporation, and indicates that the thickness is 0.3 mm.

The Al plate 0.4 corresponds to the support plate 16 c of the back surface protective layer 16. The Al plate 0.4 is a 1000th aluminum plate and indicates that its thickness is 0.4 mm.
The Al plate 1.0 corresponds to the support plate 16 c of the back surface protective layer 16. This Al plate 1.0 is a 1000th aluminum plate and indicates that its thickness is 1.0 mm.
The Galvalume steel plate 0.4 corresponds to the support plate 16c of the back surface protective layer 16 and indicates that its thickness is 0.4 mm.
Moreover, in the column of the test structures of Experimental Examples 2 to 10 shown in Table 1 below, the numerical value at the end indicates the total thickness. In this example, the yield means that the glass of the surface protective layer was broken.

  In this example, the test structures of Experimental Examples 2 to 10 were manufactured by laminating the structures shown in Table 1 and then pressing them at a temperature of 150 ° C. for 20 minutes using a vacuum laminator.

As shown in Table 1 above, in contrast to the yield stress of 0.67 kN in Experimental Example 1 of white plate tempered glass (3.2 mm thick), in Experimental Example 7 in which both layers of the sealing material are EVA, the yield stress is 0. 244 kN. However, when Experimental Examples 2 to 6 and Examples 8 to 10 in which at least one layer of the sealing material is HM, the yield stress is 0.399 kN or more.
Moreover, the aluminum plate which comprises a back surface protective layer showed the yield stress of 0.6 kN or more by 0.4 mm or more. In Experimental Example 5 in which the back surface protective layer was a galvalume steel plate, the yield stress was 1.43 kN, and in Experimental Example 10 in which the back surface protective layer was provided with a galbarium steel plate as a three-layer structure, the yield stress was 2 .28 kN, the highest value among Experimental Examples 1-10. These are all twice or more of tempered glass.
In Experimental Example 8 in which the back surface protective layer is composed only of the back sheet, although the yield stress is higher than in Experimental Example 7, it is considered that this is because one layer of the sealing material is HM. Compared to Experimental Example 6 in which the back sheet is replaced with a Galvalume steel plate compared to Experimental Example 8, both the yield stress and the bending stress are low, and the back surface protective layer is configured only by the back sheet. In Example 8, the bending stress does not reach 100 MPa.

  From the above, in order to achieve the same strength as white plate tempered glass, at least one adhesive filling layer is used as a sealing material made of high-rigidity ionomer resin, and the back surface protective layer is made of an Al plate or a Galvalume steel plate. It is effective to use a metal sheet such as, and at least a bending stress of 100 MPa or more is required. This is a bending stress value that sufficiently satisfies the wind-resistant load, snow-resistant, and earthquake-resistant load conditions for the photovoltaic power generation system.

In this example, in order to examine a light-weight and high mechanical strength solar cell module structure, all of the test structures of Experimental Examples 11 to 17 shown in Table 2 below were produced with the same size (15 cm × 7.5 cm). did. And each weight of the test structure of Experimental Examples 11-17 was measured, and the weight ratio of each Experimental Example 11-17 was calculated | required on the basis of Experimental Example 10. FIG. The results are shown in Table 2 below.
Here, Experimental Examples 12 to 17 are the same samples as Experimental Examples 2 to 7 of Example 1 described above. For this reason, the detailed description is abbreviate | omitted.

Experimental Example 10 includes a 3.2 mm thick whiteboard reinforced GL, a 0.8 mm thick EVA, a 0.08 mm thick PV substrate, a 0.8 mm thick EVA, and a thickness. Is manufactured by laminating 1.1 mm blue glass and pressing it at a temperature of 150 ° C. for 20 minutes using a vacuum laminator. In Experimental Example 10, the back surface protective layer is blue plate glass. For EVA, Solar Eva manufactured by Mitsui Chemicals Fabro Co., Ltd. was used.
In the column of the test structures of Experimental Examples 11 to 17 shown in Table 2 below, the numerical value at the end indicates the total thickness.

As shown in Table 2, when the back surface protective layer is made of an Al plate, the weight ratio is 0.51 to 0.65. Moreover, when a back surface protective layer is comprised with a galvalume steel plate, weight ratio is 0.68-0.71. Thus, when the back surface protective layer is composed of an Al plate or a galvalume steel plate, a significant reduction in weight is possible.
According to the results of the first example 1 and the present example (second example), it is effective that the back surface protection layer is made of a metal sheet such as an Al plate or a galvalume steel plate, thereby reducing the weight and mechanical strength. It became possible to obtain a high solar cell module.

  In this example, solar cell modules of Examples 1 to 4 and Comparative Example 1 shown below were produced, and their mechanical strength was evaluated.

Example 1
A solar cell module 10 having a substrate structure and including a solar cell submodule 12 using a CIGS film as a light absorption layer was manufactured as shown in FIG.
As the first adhesive filling layer 20 and the second adhesive filling layer 14, Himiran (registered trademark) -ES S7042 manufactured by Mitsui-DuPont Polychemical Co., Ltd., which is an ionomer resin, was used. The thickness of the first adhesive filling layer 20 and the second adhesive filling layer 14 was 800 μm.
For the surface protective layer 22, a blue plate glass having a thickness of 1.1 mm was used.
Furthermore, for the back surface protective layer 16, a repnea TFB MD manufactured by Lintec Corporation was used as the back sheet 16a. Further, a galvalume steel plate having a thickness of 0.4 mm was used as the support plate 16c, and this was adhered to the back sheet 16a by using EVA (Solar EVA manufactured by Mitsui Chemicals Fabro Co., Ltd.) as the third adhesive filling layer 16b. .
Moreover, as the intermediate sealing material 18, a sheet material of hot melt butyl rubber (M-155) manufactured by Yokohama Rubber Co., Ltd. is used, cut into a mouth shape, the width of the intermediate sealing material 18 is 5 mm, the outer periphery of the intermediate sealing material 18 and the sun. The distance from the periphery of the battery module 10 was 5 mm.

  In the production of Example 1, a total of 20 vacuum / press / hold at a temperature of 150 ° C. using a vacuum laminator having lifting and lowering means, a buffer plate, and a heating means in a state where such materials are laminated and arranged. Laminating was performed under the lamination condition of minutes.

(Example 2)
A solar cell module 10b shown in FIG. 4B was produced. In addition, the same thing as Example 1 was used except the frame member 24. FIG.
For the frame member 24, butyl rubber was used as the peripheral sealing material 26, and an Al foil tape was used for the outer frame material 28. In addition, Yokohama rubber M-155P was used for the butyl rubber.
In the production of Example 2, on the back surface 12b side of the solar cell submodule 12, the second adhesive filling layer 14, the back surface protection layer 16 (back sheet 16a, third adhesive filling layer 16b, and galvalume steel plate (support plate 16c)). ) And the first adhesive filling layer 20 and the surface protective layer 22 are disposed on the surface 12a side of the solar cell submodule 12, and then vacuum / press / hold at a temperature of 150 ° C. using a vacuum laminator. Lamination was performed under a total of 20 minutes of lamination conditions to obtain a solar cell laminate 30.
Then, butyl rubber was melted at 150 to 190 ° C., and the laminated side was coated with butyl rubber melted at a width of 5 to 10 mm from the peripheral edge to the peripheral edge of the four sides, and the surface of the surface protective layer and the surface of the back protective layer, and cooled and cured. Later, the AL foil tape was attached so as to surround the butyl rubber, and the frame member 24 was provided to produce the solar cell module 10b.

(Example 3)
A solar cell module 10b shown in FIG. 4B was produced. In addition, the same thing as Example 1 was used except the glass of the surface protective layer 22, and the frame member 24. FIG. A 1.1 mm thick white plate glass was used for the surface protective layer 22, and a silicone seal material was used as the peripheral seal material 26 for the frame member 24. The RTV sealing material KE-45 of Shin-Etsu Chemical Co., Ltd. was used for the silicone sealing material. Further, an L-shaped aluminum frame was used for the outer frame member 28.
In the production of Example 3, a solar cell laminate 30 was produced in the same manner as in Example 2, and then a silicone sealant was applied and embedded in an L-shaped aluminum frame groove in advance and laminated. The side was set in the groove of the aluminum frame, and the aluminum frame was fixed with screws. After that, the silicone sealing material was cured by leaving it at room temperature for 7 days to provide a frame member 24, thereby producing a solar cell module 10b.

Example 4
A solar cell module 10d shown in FIG. 6B was produced. In addition, the same thing as Example 1 was used except the frame member 24. FIG.
In the frame member 24, butyl rubber was used for the peripheral seal material 26, and an L-shaped aluminum frame was used for the outer frame material 28. In addition, Yokohama rubber M-155P was used for the butyl rubber.
When producing Example 4, vacuum lamination was performed as shown in Example 1 to produce a solar cell laminate 30a (see FIG. 6B). Thereafter, butyl rubber is melted at 150 to 190 ° C., applied and embedded in an L-shaped aluminum frame groove, and the peripheral edges of the four sides of the solar cell laminate 30a are sandwiched in the aluminum frame groove, and then at 90 ° C. in a constant temperature bath. After baking for 30 minutes and bonding, the aluminum frame was screwed and fixed, and the frame member 24 was attached to produce a solar cell module 10d.

(Comparative Example 1)
In Comparative Example 1, a blue sheet glass having a thickness of 1.0 mm is used for the surface protective layer 22, the first adhesive filling layer 20 and the second adhesive filling layer 14 are 400 μm in thickness, and Mitsui Chemicals Fabro Co., Ltd. A solar cell module was manufactured under the same manufacturing conditions as in Example 1 except that the solar cell was made of solar EVA.

  About the produced 5 types of solar cell modules of Examples 1 to 4 and Comparative Example 1, the conversion efficiency after a falling test and a dump heat test (left in an environment of a temperature of 85 ° C. and a humidity of 85 RH for 1000 hours) was measured. The results are shown in Table 3 below. Here, the falling test was conducted based on the evaluation standard of the international standard IEC 1646-10.17 for thin film solar cells. Moreover, the falling test and the dump heat test were performed continuously.

  In the dump heat test, when the conversion efficiency of the solar cell module maintained 90% or more of the initial value, it was evaluated as ◎, and the conversion efficiency of the solar cell module was 80% or more and less than 90% of the initial value. The case where the conversion efficiency of the solar cell module was 60% or more and less than 80% of the initial value was evaluated as △, and the case where the conversion efficiency of the solar cell module was less than 60 of the initial value was evaluated as x. evaluated.

As shown in Table 3 above, according to the solar cell module descending test, Comparative Example 1 shows the rigidity of the solar cell module structure including the surface protective layer, the first adhesive filling layer, the second adhesive filling layer, and the back surface protective layer. Since the strength and impact strength were low, the surface protective layer was cracked and cracked. Cracks also occurred in the CIGS solar cell itself or in the anodic oxide film that is the insulating layer of the metal substrate, and current leakage to the metal substrate caused a significant reduction in conversion efficiency.
Furthermore, in the comparative example 1, in the dump heat test after the falling test, moisture penetrates from the cracked portion of the glass of the surface protective layer, the transparent electrode of the solar cell submodule is altered, and the series resistance is increased. It is thought that the conversion efficiency of the module further decreased.

On the other hand, as in Examples 1 to 4, the mechanical strength of the solar cell module is improved by using an ionomer resin as at least the first adhesive filling layer under the blue sheet glass of the surface protective layer, and the yield test No cracks or cracks occur in the glass of the surface protective layer. Further, the mechanical strength can be obtained by providing an intermediate sealing material in which the sealing material is disposed on the inner side from the periphery as in the first and fourth examples, or by providing the peripheral sealing material as in the second and third examples. Can be raised. Thereby, peeling of the peripheral part of the solar cell submodule and generation of cavities can be suppressed and moisture diffusion from the peripheral part can be suppressed, and deterioration of conversion efficiency of the solar cell module in the dump heat test can be suppressed. It was.
From the above results, the effects of the present invention are clear.

10, 10a, 10b, 100a, 100b Solar cell module 12 Solar cell sub-module 14 Second adhesive filling layer 16 Back sheet 18 Intermediate sealing material 20 First adhesive filling layer 22 Surface protective layer 24 Frame member 26 Peripheral sealing material 28 Outer frame material 40 Solar cell 50 Substrate

Claims (10)

A surface protection layer is provided on the front surface side of the solar cell submodule via a first adhesive filling layer, and a back surface protection layer is provided on the back surface side of the solar cell submodule via a second adhesion filling layer, A solar cell module in which the solar cell submodule is sealed by a first adhesive filling layer and the second adhesive filling layer,
The back surface protective layer includes at least the support plate among support plates that reinforce the back sheet and the solar cell module, and the support plate has an aluminum plate, aluminum alloy plate having a thickness of 0.1 to 1.0 mm, or It is composed of galvalume steel plate,
The first adhesive filling layer includes an ionomer resin,
The surface protective layer is made of glass having a thickness of 0.6 to 1.5 mm,
The solar cell submodule is a substrate in which an anodized film of aluminum is formed on the surface of a metal sheet, and a light absorption layer composed of a CIGS film is formed.
The solar cell module, wherein the solar cell module has a bending stress of 100 MPa or more.   The solar cell module according to claim 1, wherein the glass constituting the surface protective layer is blue plate glass or white plate glass.   A frame member provided at a peripheral edge, the frame member includes a sealing material provided on an inner side and an outer frame material provided on an outer side, and the sealing material is made of butyl rubber or silicone resin; The solar cell module according to claim 1 or 2, wherein the outer frame material is made of an aluminum frame or a metal foil tape.   The sun according to any one of claims 1 to 3, wherein the metal sheet of the substrate used in the solar cell submodule is an aluminum material, a stainless steel and aluminum clad material, or an aluminum and stainless steel clad material. Battery module. The second adhesive filling layer does not contain the ionomer resin.
The said back surface protective layer is a solar cell module of any one of Claims 1-4 provided with the said support plate which consists of the said back sheet and the said galbarium steel plate.   The solar cell module according to any one of claims 1 to 5, wherein an intermediate sealing material for preventing entry of water vapor is provided 5 to 30 mm inside from the peripheral edge of the back surface protective layer.   The solar cell module according to claim 6, wherein the intermediate sealing material is made of butyl rubber, polyolefin, polyisoprene, or isoprene. A surface protection layer is provided on the front surface side of the solar cell submodule via a first adhesive filling layer, and a back surface protection layer is provided on the back surface side of the solar cell submodule via a second adhesion filling layer, A method for manufacturing a solar cell module in which the solar cell submodule is sealed by a first adhesive filling layer and the second adhesive filling layer,
The back surface protective layer includes at least the support plate among the support plates that reinforce the back sheet and the solar cell module, and the support plate has an aluminum plate, aluminum alloy plate having a thickness of 0.1 to 1.0 mm, or It is composed of galvalume steel plate,
The first adhesive filling layer includes an ionomer resin,
The surface protective layer is made of glass having a thickness of 0.6 to 1.5 mm,
The solar cell submodule is a substrate in which an anodized film of aluminum is formed on the surface of a metal sheet, and a light absorption layer composed of a CIGS film is formed.
The first adhesive filling layer and the surface protective layer are laminated and disposed on the front surface side of the solar cell submodule, and the second adhesive filling layer and the back surface protective layer are disposed on the rear surface side of the solar cell submodule. Laminating and arranging,
And a step of vacuum laminating in a state where the plurality of layers are laminated and disposed.   Furthermore, the manufacturing method of the solar cell module of Claim 8 which arrange | positions the intermediate | middle sealing material for water vapor | steam invasion inside 5-30 mm inside from the peripheral part of the said back surface protective layer in the process arrange | positioned in the said lamination | stacking.   The manufacturing method of the solar cell module of Claim 8 or 9 which has the process of providing the frame member in which the sealing material was provided inside the outer frame material in the peripheral part of the said vacuum lamination after the said vacuum lamination process.

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