JP2012171929A - Herbicidal composition and method for killing weed - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an excellent herbicidal composition and a method for killing weeds.SOLUTION: The herbicidal composition includes 4-chloro-5-[1,3-dioxocyclohexa-2-yl]carbonyl-2,3-dihydrobenzothiophene-1,1-dioxide, and pyrimisulfan or the like, and cumyluron or the like as active ingredients, and can control weeds.

Description

  The present invention relates to a herbicidal composition and a method for controlling weeds.

At present, many herbicides are used, but there are many kinds of weeds to be controlled, and the occurrence is long. Therefore, a herbicide having a high herbicidal effect, a broad herbicidal spectrum, and excellent crop selectivity is desired.
It is known that certain triketone compounds have herbicidal activity (see, for example, Patent Document 1).
These compounds are very effective in controlling a wide range of weed species that occur in paddy fields, but when used alone, they are not satisfactory for controlling many types of weeds simultaneously.

JP 2000-178268 A

  Under such circumstances, the present invention has excellent crop-weed selectivity, has high herbicidal activity and a broad herbicidal spectrum, can control a wide range of weeds at once, and further increases the productivity of crops. An object of the present invention is to provide a herbicidal composition and a method for controlling weeds that contribute to improvement and labor saving and have little influence on the environment.

  As a result of studying to find an excellent herbicidal composition and a method for controlling weeds, the present inventor has found that a herbicidal composition containing the following components (A), (B), and (C) as active ingredients (hereinafter referred to as the active ingredients) Have been found to be able to effectively control weeds with insufficient control effect, and to reduce the number of spraying times, leading to the present invention. .

That is, the present invention is as follows.
[1] A herbicidal composition containing the component (A), the component (B), and the component (C) as active ingredients.
Component (A): 4-chloro-5- [1,3-dioxocyclohex-2-yl] carbonyl-2,3-dihydrobenzothiophene-1,1-dioxide.
Component (B): at least one compound selected from the group consisting of pyrimisulphan, propyrisulfuron, penoxsulam, and metazosulfuron.
Component (C): at least one compound selected from the group consisting of cumyluron, chromeprop, simethrin, dimetamethrin, dimrone, pyrazolate, pyrazoxifene, benzophenap, and MCPB.
[2] The herbicidal composition according to [1], wherein the weight ratio of the component (A), the component (B), and the component (C) is in the range of 1: 0.1: 0.01 to 1: 10: 200. object.
[3] A method for controlling weeds, wherein an effective amount of component (A), component (B), and component (C) is applied to weeds or a place where weeds grow.
[4] The method for controlling weeds according to [3], wherein the place where the weeds grow is a paddy field or a field.
[5] Use of the composition containing the component (A), the component (B), and the component (C) for controlling weeds.

  According to the present invention, weeds can be controlled.

This invention herbicidal composition contains a component (A), a component (B), and a component (C) as an active ingredient.
Component (A) is a compound represented by the formula (I) described in JP-A No. 2000-178268.

  Component (B) is at least one compound selected from the group consisting of pyrimisulphan, propyrisulfuron, penoxsulam, and methazosulfuron.

プロピリスルフロン（Ｐｒｏｐｙｒｉｓｕｌｆｕｒｏｎ）は、特許第３６８２２８８号公報に記載された、式（III）で示される化合物である。

ペノキススラム（Ｐｅｎｏｘｓｕｌａｍ）は、米国特許第５８５８９２４号明細書に記載された、式（IV）で示される化合物である。

メタゾスルフロン（Ｍｅｔａｚｏｓｕｌｆｕｒｏｎ）は、特許第３９８２５４２号公報に記載された、式（Ｖ）で示される化合物である。

Pyrimisulfan is a compound represented by the formula (II) described in Japanese Patent No. 3632947.

Propyrisulfuron is a compound represented by the formula (III) described in Japanese Patent No. 3682288.

Penoxsulam is a compound of formula (IV) described in US Pat. No. 5,858,924.

Metazosulfuron is a compound represented by the formula (V) described in Japanese Patent No. 3985422.

  Component (C) is at least one compound selected from the group consisting of cumyluron, chromeprop, simethrin, dimetamethrin, dimelon, pyrazolate, pyrazoxifene, benzophenap, and MCPB.

Cumylon is a CAS No. 99485-76-4.
Clomeprop is a CAS No. 84496-56-0.
Cimetrin is a CAS No. 1014-70-6.
Dimetamethrin is available from CAS No. 22936-75-0.
Daimuron is a CAS No. 42609-52-9.
Pyrazolate is CASNo. 5801-68-0.
Pyrazoxifene is available from CAS No. It is a compound of 71561-11-0.
MCPB is a CAS No. 94-81-5.

  This invention herbicidal composition contains a component (A), a component (B), and a component (C). The herbicidal composition of the present invention is usually further added with an auxiliary for formulation such as an inert carrier, a surfactant, a sticking agent, a dispersing agent, a stabilizer, etc., and a wettable powder, a granular wettable powder, a flowable powder, a granule, It is formulated into dry flowables, emulsions, aqueous solutions, oils, smokes, aerosols, microcapsules and the like. In the present herbicidal composition, the total of component (A), component (B), and component (C) is usually 1 to 90% by weight.

  Examples of the inert carrier include a solid carrier, a liquid carrier, and a gas carrier.

  Examples of the solid carrier include clays (for example, kaolin, diatomaceous earth, synthetic hydrous silicon oxide, fusami clay, bentonite, acidic clay), talc, and other inorganic minerals (for example, sericite, quartz powder, sulfur powder, activated carbon, Examples of the liquid carrier include water, alcohols (for example, methanol, ethanol), ketones (for example, acetone, methyl ethyl ketone), aromatic carbonization, and the like. Hydrogens (eg, benzene, toluene, xylene, ethylbenzene, methylnaphthalene), aliphatic hydrocarbons (eg, n-hexane, cyclohexane, kerosene), esters (eg, ethyl acetate, butyl acetate), nitriles (eg, , Acetonitrile, isobutylnitrile), ethers (eg Dioxane, diisopropyl ether), acid amides (e.g., N, N- dimethylformamide, dimethylacetamide), and halogenated hydrocarbons (e.g., dichloroethane, trichlorethylene, carbon tetrachloride) and the like.

  Surfactants include, for example, alkyl sulfates, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers and their polyoxyethylene compounds, polyoxyethylene glycol ethers, polyhydric alcohol esters, and sugar alcohols. Derivatives.

  Examples of other formulation adjuvants include casein, gelatin, polysaccharides (eg, starch, arabic gum, cellulose derivatives, alginic acid), lignin derivatives, bentonite, saccharides, synthetic water-soluble polymers (eg, polyvinyl alcohol, polyvinyl pyrrolidone). , Polyacrylic acid), PAP (isopropyl acid phosphate), BHT (2,6-di-tert-butyl-4-methylphenol), BHA (2-tert-butyl-4-methoxyphenol and 3-tert-butyl) And mixtures with -4-methoxyphenol), vegetable oils, mineral oils, fatty acids, and fatty acid esters.

In the method for controlling weeds of the present invention, effective amounts of the component (A), the component (B), and the component (C) are applied to the weed or a place where the weed grows. The herbicidal composition of the present invention can be used in the weed control method of the present invention. The application method of the herbicidal composition of the present invention includes, for example, a method of treating the foliage of the present herbicidal composition on weeds, a method of treating the herbicidal composition of the present invention on the soil surface where weeds grow, and the present herbicidal composition of paddy field. Examples thereof include a method of treating the surface water, and a method of mixing the herbicidal composition of the present invention with the soil where weeds grow. In the weed control method of the present invention, the total amount of component (A), component (B) and component (C) per 10,000 m ² for controlling weeds is usually 1 to 5000 g, preferably 10 to 1000 g. Used.

  In the present invention, examples of the weight ratio of the components (A), (B), and (C) used as active ingredients include a range of 1: 0.1: 0.01 to 1: 100: 200.

  When the component (B) is pyrimylsulfan and the component (C) is cumylron, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is pyrimisulphan and the component (C) is chromeprop, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is pyrimylsulfan and the component (C) is simethrin, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is pyrimylsulfan and the component (C) is dimetamethrin, the weight ratio of the components (A), (B) and (C) used as the active component is, for example, 1: 0. The range of 1: 0.01-1: 10: 10 is mentioned.

  When the component (B) is pyrimylsulfan and the component (C) is Daimron, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is pyrimisulphan and the component (C) is pyrazoxifene, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is pyrimylsulfan and the component (C) is pyrazolate, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0. The range of 1: 1 to 1: 10: 200 is mentioned.

  When the component (B) is pyrimisulphan and the component (C) is benzophenap, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: The range of 0.1: 1 to 1: 10: 100 is mentioned.

  When the component (B) is pyrimylsulfan and the component (C) is MCPB, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0. The range of 1: 1-1: 10: 10 is mentioned.

  When the component (B) is propyrisulfuron and the component (C) is cumylron, the weight ratio of the components (A), (B) and (C) used as the active ingredient is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is propyrisulfuron and the component (C) is chromeprop, the weight ratio of the components (A), (B) and (C) used as the active ingredients is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is propyrisulfuron and the component (C) is cimetrin, the weight ratio of the components (A), (B) and (C) used as the active ingredient is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is propyrisulfuron and the component (C) is dimetamethrin, the weight ratio of the components (A), (B) and (C) used as the active ingredient is, for example, 1: 0. The range of 1: 0.01-1: 10: 10 is mentioned.

  When the component (B) is propyrisulfuron and the component (C) is Daimron, the weight ratio of the components (A), (B) and (C) used as the active ingredient is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is propyrisulfuron and the component (C) is pyrazoxifene, the weight ratio of the components (A), (B) and (C) used as the active ingredient is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is propyrisulfuron and the component (C) is pyrazolate, the weight ratio of the components (A), (B) and (C) used as the active ingredient is, for example, 1: 0. The range of 1: 1 to 1: 10: 200 is mentioned.

  When the component (B) is propyrisulfuron and the component (C) is benzophenap, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: The range of 0.1: 1 to 1: 10: 100 is mentioned.

  When the component (B) is propyrisulfuron and the component (C) is MCPB, the weight ratio of the components (A), (B) and (C) used as the active ingredient is, for example, 1: 0. The range of 1: 1-1: 10: 10 is mentioned.

  When the component (B) is penox slam and the component (C) is cumyluron, the weight ratio of the components (A), (B) and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is penox slam and the component (C) is chromeprop, the weight ratio of the components (A), (B), and (C) used as active ingredients is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is penox slam and the component (C) is cimetrin, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is penox slam and the component (C) is dimetamethrin, the weight ratio of the components (A), (B) and (C) used as the active component is, for example, 1: 0.1: The range of 0.01-1: 10: 10 is mentioned.

  When the component (B) is penox slam and the component (C) is Daimron, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is penoxsulam and the component (C) is pyrazoxifene, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is penox slam and the component (C) is pyrazolate, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 200 is mentioned.

  When the component (B) is penox slam and the component (C) is benzophenap, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is penox slam and the component (C) is MCPB, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 10 is mentioned.

  When the component (B) is metazosulfuron and the component (C) is cumylron, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is metazosulfuron and the component (C) is chromeprop, the weight ratio of the components (A), (B), and (C) used as active ingredients is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is metazosulfuron and the component (C) is simethrin, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is metazosulfuron and the component (C) is dimetamethrin, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 0.01-1: 10: 10 is mentioned.

  When the component (B) is metazosulfuron and the component (C) is Daimron, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is metazosulfuron and the component (C) is pyrazoxifene, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 100 is mentioned.

  When the component (B) is metazosulfuron and the component (C) is pyrazolate, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 200 is mentioned.

  When the component (B) is metazosulfuron and the component (C) is benzophenap, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0. The range of 1: 1-1: 10: 100 is mentioned.

  When the component (B) is metazosulfuron and the component (C) is MCPB, the weight ratio of the components (A), (B), and (C) used as the active component is, for example, 1: 0.1: The range of 1-1: 10: 10 is mentioned.

  In the present invention, weed control in paddy fields, upland fields, orchards where plowing or non-plowing cultivation is performed, or non-agricultural land is intended. Specific examples include the following weeds.

  Crabgrass (Digitaria ciliaris), goosegrass (Eleusine indica), green foxtail (Setaria viridis), giant foxtail (Setaria faberi), Kin foxtail (Setaria glauca), barnyardgrass (Echinochloa crus-galli), fall panicum (Panicum dichotomiflorum), Texas Pani cam (Panicum texanum), Meriken acne (Brachiaria platyphylla), Alexander glass (Braciaria plantagenea), Surinamegrass (Braciaria decumbens), Sebum sorghum (Sorghum halekeense) Emissions (Andropogon sorghum), bermudagrass (Cynodon dactylon), oats (Avena fatua), darnel (Lolium multiflorum), black grass (Alopecurus myosuroides), downy brome (Bromus tectorum), Arechinochahiki (Bromus sterilis), Hime canary grass (Phalaris minor) , Apera spica-venti, Poa annua, Agropyron repens, Cyperus iria, Cyperus rotundus, cymus , Pollula oleracea, Amaranthus retroflexus, Amaranthus hydritus, Amaranthus palm, Amaranthus palmeri, Anthus amuth spinosa), buckwheat (Fallopia convolvulus), sanaetade (Polygonum scabulum), American sanaetade (Persicaria pennsylvanica), hartade (Persicaria vulgaris), nagapumushi c Shi (Rumex obtusifolius), Japanese knotweed (Fallopia japonica), common lambsquarters (Chenopodium album), kochia (Kochia scoparia), knotweed (Polygonum longisetum), black nightshade (Solanum nigrum), white nosed Datura (Datura stramonium), Ipomoea purpurea (Ipomoea purpurea) , American morning glory (Ipomoea hederacea), Malmo American morning glory (Ipomoea hederacea var. integriuscula), beans morning glory (Ipomoea lacunosa), field bindweed (Convolvulus arvensis), Lamium purpureum (Lamium purpureum), henbit (Lamium amplexicaule), cocklebur (Xanthium pensylvanicum), wild sunflower (Helianthus annuus), Inukamitsure (Matricaria perforata or inodora), Chamomile (Matricaria chamomilla), corn marigold (Chrysanthemum segetum), orrasia (Matricaria matricariaides), ragweed (Ambrosia artemisiifo) ia), Ambrosia trifida (Ambrosia trifida), Erigeron canadensis (Erigeron canadensis), mugwort (Artemisia princeps), goldenrod (Solidago altissima), Erigeron bonariensis (Conyza bonariensis), the United States horn Aeschynomene indica (Sesbania exaltata), sicklepod (Cassia obtusifolia), Florida Bega Weed (Desmodium tortusum), White clover (Trifolium repens), Kudzu (Pueraria lobata), Caladium pea (Vicia angustifolia), Clover (Commelina communis) lina benghalensis), cleavers (Galium aparine), chickweed (Stellaria media), wild radish (Raphanus raphanistrum), Noharagarashi (Sinapis arvensis), shepherd's purse (Capsella bursa-pastoris), persian speedwell (Veronica persica), Veronica Hederifolia (Veronica hederifolia), field Pansy (Viola arvensis), Wild pansy (Viola tricolor), Papaver rhoeas, Forget-me-nots (Myosotis scorpioides), Otoweed (Asclepias syriaca) phorbia helioscopia), Euphorbia nutans (Chamaesyce nutans), the United States Fuuro (Geranium carolinianum), Netherlands Fuuro (Erodium cicutarium), horsetail (Equisetum arvense) upland weeds and the like;

  Ashikaki (Leersia japonica), barnyardgrass (Echinochloa oryzicola), barnyardgrass (Echinochloa crus-galli var. Formosensis), leptochloa chinensis (Leptochloa chinenisis), smallflower umbrellaplant (Cyperus difformis), fimbristylis miliacea (Fimbristylis miliacea), Eleocharis acicularis (Eleocharis acicularis), Scirpus ( Sirpus juncoides, Sirpus wallicii, Cyperus serotinus, Kerowai (Eleocharis kuroguwai), Kokiyaga (Bolboschoenus kos) evnikovii), pulp (Schoenoplectus nipponicus), Monochoria (Monochoria vaginalis), false pimpernel (Lindernia procumbens), Abunome (Dopatrium junceum), Rotala indica (Rotala indica), Ammannia multiflora Roxb (Ammannia multiflora), Elatine triandra Schk (Elatine triandra), Choujitade (Ludwigia epilobioides) , Urikawa (Sagittaria pygmaea), Heramodaka (Arisma canaliculatum), Omodaka (Sagittaria trifolia), Hiramshiro (Potamogeton distinctus), Seri (Oen) e javanica), Mizuhakobe (Callitriche palustris), Azetougarashi (Lindernia micrantha), Amerikaazena (Lindernia dubia), Eclipta prostrata (Eclipta prostrata), Ibokusa (Murdannia keisak), Paspalum distichum (Paspalum distichum), Ezonosayanukagusa (Leersia oryzoides) paddy field weeds such as ;

  Naganetera phyloxeroides, Frogsbit (Limnobium spongia), Waterfern (Salvinia spp.), Duckweed (Pistia stratiotes), Water pennywort (genus Hydrocotyle spp.) demersum), duckweed (genus Lemna), crested lobster (Cabomba caroliniana), black peach (Hydryla verticillatis), Southern naad (Najas guadalupensis), pondweet (Potamogeton) n illinoensis, etc. Potamogeton Pectinatus) Water meal (Wolffia genus), water mills foil such (Myriophyllum spicatum, Myriophyllum heterophyllum etc.), water hyacinth (Eichhornia crassipes) or the like aquatic plants;

  Mosses, moss, hornworts. Cyanobacteria. Ferns. Suckers of perennial crops (fruits, stones, berries, nuts, citrus, hops, grapes, etc.).

The herbicidal composition of the present invention may be able to control weeds in the cultivated land in the cultivated land or the like where the following “crop” and the like are cultivated.
Agricultural crops: corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco, hop, etc.
Vegetables: Solanum vegetables (eggplants, tomatoes, potatoes, peppers, peppers), cucumbers (cucumbers, pumpkins, zucchini, watermelons, melons, cucumbers, etc.), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage) , Cabbage, mustard, broccoli, cauliflower, etc.), asteraceae vegetables (burdock, garlic, artichoke, lettuce, etc.), liliaceae vegetables (leek, onion, garlic, asparagus, etc.), celery family vegetables (carrot, parsley, celery, American Bow Fu etc.), Rubiaceae vegetables (spinach, chard, etc.), Lamiaceae vegetables (silla, mint, basil etc.), legumes (peas, kidney beans, azuki bean, broad beans, chickpea etc.), strawberries, sweet potatoes, yam, taro , Konjac, ginger, ok Etc..
Fruit trees: fruits (apples, pears, pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, umes, sweet cherry, apricots, prunes, etc.), citrus (citrus mandarin orange, lemon, lime, grapefruit) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, oil palm etc.
Trees other than fruit trees: tea, mulberry, flowering trees (Satsuki, camellia, hydrangea, sasanqua, shikimi, sakura, yurinoki, crape myrtle, snapdragon, etc.), roadside trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak) , Poplar, redwood, fu, sycamore, zelkova, blackfish, Japanese amberjack, moths, pine, pine, spruce, yew, elm, Japanese cypress, etc.), coral jug, dogwood, cedar, cypress, croton, masaki, kanamochi, etc.
Lawn: Shiba (Nasis, Pleurotus, etc.), Bermudagrass (Neurodonidae, etc.), Bentgrass (Oleoptera, Hykonukagusa, Odonoptera, etc.), Bluegrass (Nagahagusa, Oosuzunokatabira, etc.), Fescue (Oonishi nokegusa, Drosophila, etc.) , Grass, etc.), ryegrass (rat, wheat, etc.), anemonefish, and blue whale.
Other: Flowers (Rose, Carnation, Chrysanthemum, Eustoma, Gypsophila, Gerbera, Marigold, Salvia, Petunia, Verbena, Tulip, Aster, Gentian, Lily, Pansy, Cyclamen, Orchid, Lily of the valley, Lavender, Stock, Habutton, Primula, Poinsettia, gladiolus, cattleya, daisy, symbidium, begonia, etc.), biofuel plants (Jatropha, safflower, Amanas, switchgrass, miscanthus, kusayoshi, dangiku, kenaf, cassava, willow, etc.), houseplants, etc.

  The above crops include genetically modified crops.

  The herbicidal composition of the present invention has selectivity for paddy rice. Therefore, the herbicidal composition of the present invention is suitable for a paddy field herbicidal composition.

  The herbicidal composition of the present invention can be mixed or used in combination with other herbicides, insecticides, fungicides, plant growth regulators, safeners, fertilizers and the like.

  EXAMPLES Hereinafter, although an Example, such as a formulation example and a test example, is given and this invention is demonstrated in more detail, this invention is not limited to these. In addition, "part" described in an Example means a weight part.

Formulation Example 1
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Ingredient (A) 0.7 part Ingredient (B): Pyrimisulphan 0.5 part Ingredient (C): Cumyllon 10.0 parts Neocor <registered trademark> YSK (dialkylsulfosuccinic acid ester surfactant): Daiichi Kogyo Seiyaku 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: Kunimine Industry Co., Ltd.) ) Made) 30.0 parts calcium carbonate 56.3 parts

Formulation Example 2
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Ingredient (A) 1.5 parts Ingredient (B): Pyrimisulphan 1.0 part Ingredient (C): Chlomeprop 7.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku ( 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: Sanyo Chemical Industries, Ltd.) Manufactured) 2.0 parts sodium tripolyphosphate 5.0 parts Serogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Industries Co., Ltd.) 10 0.0 part calcium carbonate 65.1 parts

Formulation Example 3
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Ingredient (A) 0.7 part Ingredient (B): Pyrimisulphan 0.5 part Ingredient (C): Cimetrin 1.5 parts Neocor <registered trademark> YSK (dialkylsulfosuccinate ester surfactant: Daiichi Kogyo Seiyaku 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: Kunimine Industry Co., Ltd.) ) Made) 30.0 parts calcium carbonate 64.8 parts

Formulation Example 4
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Pyrimisulphan 1.0 part Component (C): Dimetamethrin 1.2 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku ( 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: Sanyo Chemical Industries, Ltd.) Manufactured) 2.0 parts sodium tripolyphosphate 5.0 parts Serogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Industries Co., Ltd.) 10 0.0 part calcium carbonate 70.9 parts

Formulation Example 5
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Ingredient (A) 0.7 part Ingredient (B): Pyrimisulphan 0.5 part Ingredient (C): Daimlon 10.0 parts Neocor <registered trademark> YSK (dialkylsulfosuccinate ester surfactant: Daiichi Kogyo Seiyaku 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: Kunimine Industry Co., Ltd.) ) Made) 30.0 parts calcium carbonate 56.3 parts

Formulation Example 6
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Pyrimisulphan 1.0 part Component (C): Pyrazoxifene 36.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku ( 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: Sanyo Chemical Industries, Ltd.) Manufactured) 2.0 parts sodium tripolyphosphate 5.0 parts Serogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Industries Co., Ltd.) 10 0.0 part calcium carbonate 36.1 parts

Formulation Example 7
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 part Component (B): Pyrimisulphan 0.5 part Component (C): Pyrazolate 18.0 parts Neocor <registered trademark> YSK (dialkylsulfosuccinic acid ester surfactant): Daiichi Kogyo Seiyaku 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: Kunimine Industry Co., Ltd.) 30.0 parts calcium carbonate 48.3 parts

Formulation Example 8
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Pyrimisulphan 1.0 part Component (C): Benzofenap 16.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Oil 2.4 parts Olphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: Sanyo Chemical Industries) 2.0 parts sodium tripolyphosphate 5.0 parts Cellogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (bentonite: manufactured by Kunimine Industries Co., Ltd.) 10.0 parts calcium carbonate 56.1 parts

Formulation Example 9
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 part Component (B): Pyrimisulphan 0.5 part Component (C): MCPB 2.4 part Neocor <registered trademark> YSK (dialkylsulfosuccinate ester surfactant: Daiichi Kogyo Seiyaku 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: Kunimine Industry Co., Ltd.) ) Made) 30.0 parts calcium carbonate 63.9 parts

Formulation Example 10
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Propyrisulfuron 1.8 parts Component (C): Cumylron 20.0 parts Isoelite <registered trademark> L (manufactured by Shimizu Minato Sugar Co., Ltd.) 10.0 parts Ethylene glycol 9.0 parts New Calgen D-1518 (trade name, manufactured by Takemoto Yushi Co., Ltd.) 3.0 parts Agrisol <registered trademark> FL-2017 (manufactured by Kao Corporation) 2.0 parts Antifoam <registered trademark>> E-20 (manufactured by Kao Corporation) 0.3 part sorbic acid 0.1 part water 52.3 parts

Formulation Example 11
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Propyrisulfuron 1.8 parts Component (C): Chlomeprop 7.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku ( 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: Sanyo Chemical Industries, Ltd.) Manufactured) 2.0 parts sodium tripolyphosphate 5.0 parts Serogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Industries Co., Ltd.) 10 0.0 part calcium carbonate 64.3 parts

Formulation Example 12
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 parts Component (B): Propyrisulfuron 0.9 parts Component (C): Cimetrin 1.5 parts Neocor <registered trademark> YSK (dialkylsulfosuccinic ester surfactant): Daiichi Kogyo Seiyaku 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: Kunimine Industry Co., Ltd.) 30.0 parts calcium carbonate 64.4 parts

Formulation Example 13
The following components are mixed, and the mixture is wet pulverized to obtain a flowable agent.
Component (A) 1.5 parts Component (B): Propyrisulfuron 1.8 parts Component (C): Dimetamethrin 1.2 parts Isoelite <registered trademark> L (manufactured by Shimizu Minato Sugar Co., Ltd.) 10.0 parts Ethylene glycol 9.0 parts New Calgen D-1518 (trade name, manufactured by Takemoto Yushi Co., Ltd.) 3.0 parts Agrisol <registered trademark> FL-2017 (manufactured by Kao Corporation) 2.0 parts Antifoam <registered trademark>> E-20 (manufactured by Kao Corporation) 0.3 part sorbic acid 0.1 part water 71.1 parts

Formulation Example 14
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Propyrisulfuron 1.8 parts Component (C): Daimlon 20.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku ( 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: Sanyo Chemical Industries, Ltd.) Manufactured) 2.0 parts sodium tripolyphosphate 5.0 parts Serogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Industries Co., Ltd.) 10 0.0 part calcium carbonate 51.3 parts

Formulation Example 15
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 part Component (B): Propyrisulfuron 0.9 part Component (C): Pyrazoxifene 18.0 parts Neocor <registered trademark> YSK (dialkylsulfosuccinic acid ester surfactant): Daiichi Kogyo Seiyaku 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: Kunimine Industry Co., Ltd.) 30.0 parts calcium carbonate 47.9 parts

Formulation Example 16
The following components are mixed, and the mixture is wet pulverized to obtain a flowable agent.
Component (A) 1.5 parts Component (B): Propyrisulfuron 1.8 parts Component (C): Pyrazolate 36.0 parts Isoelite <registered trademark> L (manufactured by Shimizu Minato Sugar Co., Ltd.) 10.0 parts Ethylene glycol 9.0 parts New Calgen D-1518 (trade name, manufactured by Takemoto Yushi Co., Ltd.) 3.0 parts Agrisol <registered trademark> FL-2017 (manufactured by Kao Corporation) 2.0 parts Antifoam <registered trademark>> E-20 (manufactured by Kao Corporation) 0.3 part sorbic acid 0.1 part water 36.3 parts

Formulation Example 17
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Propyrisulfuron 1.8 parts Component (C): Benzofenap 16.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Oil and Fat 2.4 parts Olphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: Sanyo Chemical Industries) 2.0 parts sodium tripolyphosphate 5.0 parts Cellogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (bentonite: manufactured by Kunimine Industries Co., Ltd.) 10.0 parts calcium carbonate 55.3 parts

Formulation Example 18
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 parts Component (B): Propyrisulfuron 0.9 parts Component (C): MCPB 2.4 parts Neocor <registered trademark> YSK (dialkylsulfosuccinate ester surfactant: Daiichi Kogyo Seiyaku 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: Kunimine Industry Co., Ltd.) ) Made) 30.0 parts calcium carbonate 63.5 parts

Formulation Example 19
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Penox slum 0.6 parts Component (C): Cumylron 20.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku Co., Ltd.) 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries, Ltd.) 2.0 parts sodium tripolyphosphate 5.0 parts Cellogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Kogyo Co., Ltd.) 10.0 52.5 parts calcium carbonate

Formulation Example 20
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Ingredient (A) 0.7 part Ingredient (B): Penox slam 0.3 Part Ingredient (C): Chlomeprop 3.5 parts Neocol <registered trademark> YSK (dialkylsulfosuccinate ester surfactant: Daiichi Kogyo Seiyaku Co., Ltd. 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: manufactured by Kunimine Industry Co., Ltd.) 30.0 parts Calcium carbonate 63.0 parts

Formulation Example 21
The following components are mixed, and the mixture is wet pulverized to obtain a flowable agent.
Component (A) 1.5 parts Component (B): Penox slam 0.6 parts Component (C): Simethrin 3.0 parts Isoelite <registered trademark> L (manufactured by Shimizu Minato Sugar Co., Ltd.) 10.0 parts ethylene glycol 9.0 parts New Calgen D-1518 (trade name, manufactured by Takemoto Yushi Co., Ltd.) 3.0 parts Agrisol <registered trademark> FL-2017 (manufactured by Kao Corporation) 2.0 parts Antifoam <registered trademark> E -20 (manufactured by Kao Corporation) 0.3 parts sorbic acid 0.1 parts water 70.5 parts

Formulation Example 22
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Penox slam 0.6 parts Component (C): Dimetamethrin 1.2 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku Co., Ltd.) 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries, Ltd.) 2.0 parts sodium tripolyphosphate 5.0 parts Cellogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Kogyo Co., Ltd.) 10.0 Part calcium carbonate 71.3 parts

Formulation Example 23
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 part Component (B): Penox slam 0.3 part Component (C): Daimlone 10.0 parts Neocor <registered trademark> YSK (dialkylsulfosuccinate ester surfactant: Daiichi Kogyo Seiyaku Co., Ltd. 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: manufactured by Kunimine Industry Co., Ltd.) 30.0 parts Calcium carbonate 56.5 parts

Formulation Example 24
The following components are mixed, and the mixture is wet pulverized to obtain a flowable agent.
Component (A) 1.5 parts Component (B): Penoxsulam 0.6 parts Component (C): Pyrazoxifene 36.0 parts Isoelite <registered trademark> L (manufactured by Shimizu Minato Sugar Co., Ltd.) 10.0 parts ethylene glycol 9.0 parts New Calgen D-1518 (trade name, manufactured by Takemoto Yushi Co., Ltd.) 3.0 parts Agrisol <registered trademark> FL-2017 (manufactured by Kao Corporation) 2.0 parts Antifoam <registered trademark> E -20 (manufactured by Kao Corporation) 0.3 part sorbic acid 0.1 part water 37.5 parts

Formulation Example 25
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Penox slam 0.6 parts Component (C): Pyrazolate 36.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku Co., Ltd.) 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries, Ltd.) 2.0 parts sodium tripolyphosphate 5.0 parts Cellogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Kogyo Co., Ltd.) 10.0 Calcium carbonate 36.5 parts

Formulation Example 26
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 part Component (B): Penox slum 0.3 part Component (C): Benzofenap 8.0 parts Neocor <registered trademark> YSK (dialkylsulfosuccinic acid ester surfactant): Daiichi Kogyo Seiyaku 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: Kunimine Industry Co., Ltd.) ) Made) 30.0 parts calcium carbonate 58.5 parts

Formulation Example 27
The following components are mixed, and the mixture is wet pulverized to obtain a flowable agent.
Component (A) 1.5 parts Component (B): Penox slam 0.6 parts Component (C): MCPB 4.8 parts Isoelite <registered trademark> L (manufactured by Shimizu Minato Sugar Co., Ltd.) 10.0 parts ethylene glycol 9.0 parts New Calgen D-1518 (trade name, manufactured by Takemoto Yushi Co., Ltd.) 3.0 parts Agrisol <registered trademark> FL-2017 (manufactured by Kao Corporation) 2.0 parts Antifoam <registered trademark> E -20 (manufactured by Kao Corporation) 0.3 part sorbic acid 0.1 part water 68.7 parts

Formulation Example 28
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 parts Component (B): Metazosulfuron 0.6 parts Component (C): Cumyllon 10.0 parts Neocor <registered trademark> YSK (dialkylsulfosuccinate ester surfactant: Daiichi Kogyo Seiyaku Co., Ltd. 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: manufactured by Kunimine Industry Co., Ltd.) 30.0 parts Calcium carbonate 56.2 parts

Formulation Example 29
The following components are mixed, and the mixture is wet pulverized to obtain a flowable agent.
Component (A) 1.5 parts Component (B): Metazosulfuron 1.2 parts Component (C): Chlomeprop 7.0 parts Isoelite <registered trademark> L (manufactured by Shimizu Minato Sugar Co., Ltd.) 10.0 parts ethylene glycol 9.0 parts New Calgen D-1518 (trade name, manufactured by Takemoto Yushi Co., Ltd.) 3.0 parts Agrisol <registered trademark> FL-2017 (manufactured by Kao Corporation) 2.0 parts Antifoam <registered trademark> E -20 (manufactured by Kao Corporation) 0.3 part sorbic acid 0.1 part water 65.9 parts

Formulation Example 30
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Metazosulfuron 1.2 parts Component (C): Simetrin 3.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku Co., Ltd.) 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries, Ltd.) 2.0 parts sodium tripolyphosphate 5.0 parts Cellogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Kogyo Co., Ltd.) 10.0 Calcium carbonate 68.9 parts

Formulation Example 31
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 part Component (B): Metazosulfuron 0.6 part Component (C): Dimetamethrin 0.6 part Neocor <registered trademark> YSK (dialkylsulfosuccinic ester surfactant): Daiichi Kogyo Seiyaku Co., Ltd. 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: manufactured by Kunimine Industry Co., Ltd.) 30.0 parts Calcium carbonate 65.6 parts

Formulation Example 32
The following components are mixed, and the mixture is wet pulverized to obtain a flowable agent.
Component (A) 1.5 parts Component (B): Metazosulfuron 1.2 parts Component (C): Daimron 20.0 parts Isoelite <registered trademark> L (manufactured by Shimizu Minato Sugar Co., Ltd.) 10.0 parts ethylene glycol 9.0 parts New Calgen D-1518 (trade name, manufactured by Takemoto Yushi Co., Ltd.) 3.0 parts Agrisol <registered trademark> FL-2017 (manufactured by Kao Corporation) 2.0 parts Antifoam <registered trademark> E -20 (manufactured by Kao Corporation) 0.3 part sorbic acid 0.1 part water 52.9 parts

Formulation Example 33
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Metazosulfuron 1.2 parts Component (C): Pyrazoxifene 36.0 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku Co., Ltd.) 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries, Ltd.) 2.0 parts sodium tripolyphosphate 5.0 parts Cellogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Kogyo Co., Ltd.) 10.0 Calcium carbonate 35.9 parts

Formulation Example 34
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 0.7 part Component (B): Metazosulfuron 0.6 part Component (C): Pyrazolate 18.0 parts Neocor <registered trademark> YSK (dialkylsulfosuccinate ester surfactant): Daiichi Kogyo Seiyaku Co., Ltd. 0.5 part Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries) 2.0 part Kunigel <registered trademark> V1 (bentonite: manufactured by Kunimine Industry Co., Ltd.) 30.0 parts Calcium carbonate 48.2 parts

Formulation Example 35
The following components are mixed, and the mixture is wet pulverized to obtain a flowable agent.
Component (A) 1.5 parts Component (B): Metazosulfuron 1.2 parts Component (C): Benzofenap 16.0 parts Isoelite <registered trademark> L (manufactured by Shimizu Minato Sugar Co., Ltd.) 10.0 parts Ethylene glycol 9.0 parts New Calgen D-1518 (trade name, manufactured by Takemoto Yushi Co., Ltd.) 3.0 parts Agrisol <registered trademark> FL-2017 (manufactured by Kao Corporation) 2.0 parts Antifoam <registered trademark>> E-20 (manufactured by Kao Corporation) 0.3 part sorbic acid 0.1 part water 56.9 parts

Formulation Example 36
An appropriate amount of water is added to the mixture of the following elements and kneaded. The resulting kneaded product is granulated, then dried and sieved to obtain granules.
Component (A) 1.5 parts Component (B): Metazosulfuron 1.2 parts Component (C): MCPB 4.8 parts Matsumoto Microsphere <registered trademark> F-80E (plastic hollow body: Matsumoto Yushi Seiyaku Co., Ltd.) 2.4 parts Orphine <registered trademark> E1010 (manufactured by Nissin Chemical Industry Co., Ltd.) 3.0 parts Toxanone <registered trademark> GR31A (polycarboxylic acid type anionic surfactant: manufactured by Sanyo Chemical Industries, Ltd.) 2.0 parts sodium tripolyphosphate 5.0 parts Cellogen <registered trademark> 7A (Daiichi Kogyo Seiyaku Co., Ltd.) 3.0 parts Kunigel <registered trademark> V1 (Bentonite: manufactured by Kunimine Kogyo Co., Ltd.) 10.0 Calcium carbonate 67.1 parts

Test Example Soil is put into a 1 / 10,000 are plastic pot, and water is put into this pot and scraped. After standing for 3 days, seeded shoots of Echinochloa oryzicola and Shirapus juncoides are sown to a depth of about 0.5 cm from the surface of the soil, and Azena (Lindernia pyxidaria L.) with cover soil, and Seeds of oak (Monochoria vaginalis). This pot is placed in a greenhouse set at 20 to 25 ° C., and plants are grown under flooded conditions. When Tainubier reaches the maximum 2.5 leaf stage, water is added to a depth of 4 cm from the surface of the soil, and the formulation shown in the formulation example is treated in water.
Four weeks after the treatment, the herbicidal effect on each weed (0: no action to 100: complete killing) is investigated.

  As a result, it can be confirmed that any preparation shows a sufficient herbicidal effect on each weed.

  The herbicidal composition of the present invention has a wide applicability to many weed species and is excellent in crop selectivity, and is thereby extremely useful because it can be expected to save labor and reduce costs in farm work.

Claims (5)

A herbicidal composition comprising component (A), component (B), and component (C) as active ingredients.
Component (A): 4-chloro-5- [1,3-dioxocyclohex-2-yl] carbonyl-2,3-dihydrobenzothiophene-1,1-dioxide Component (B): Pyrimisulphan, Pro At least one compound selected from the group of pyrisulfuron, penoxsulam, and metazosulfuron Component (C): at least one selected from the group of cumyllon, chromepprop, simethrin, dimetamethrin, dimetron, pyrazolate, pyrazoxifene, benzophenap, and MCPB Compound of   The herbicidal composition according to claim 1, wherein the weight ratio of the component (A), the component (B), and the component (C) is in the range of 1: 0.1: 0.01 to 1: 10: 200.   A method for controlling weeds, wherein an effective amount of component (A), component (B), and component (C) is applied to weeds or a place where weeds grow.   The method for controlling weeds according to claim 3, wherein the place where weeds grow is a paddy field or a field.   Use of the composition containing the component (A), the component (B) and the component (C) for controlling weeds.