JP2012111120A - Image forming apparatus, and image forming method - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an image forming apparatus which performs image formation by applying recording liquid to an intermediate transfer body by a head, and which suppresses blotting even though processing solution, other than the recording liquid, or powder or the like is not applied, while guaranteeing ejection performance of the recording liquid from the head, and an image forming method using the same.SOLUTION: The image forming apparatus uses: the intermediate transfer body 37 to which the conductive recording liquid ejected by a nozzle 61a included in heads 61Y, 61M, 61C and 61BK (hereinafter referred to as a head 61) is applied and which has a conductive surface; a voltage applying means 33 which performs voltage application using at least AC voltage between the intermediate transfer body 37 and the head 61 for electrolyzing the conductive recording liquid that is ejected from the head 61 and is in a state of bridging between the head 61 and the intermediate transfer body 37; and a control means 40 which controls frequency and/or voltage value in the voltage application in order to control discharge by the voltage applied to the conductive recording liquid by performing the voltage application.

Description

  The present invention relates to an inkjet image forming method in which a recording liquid such as ink is applied to an intermediate transfer member by a head to form an image, and an image forming apparatus using the same.

  Conventionally, it has been equipped with a head that ejects droplets of recording liquid such as ink from a plurality of minute nozzles by a movable actuator method typified by a piezo method, a heated film boiling method typified by a thermal method, etc. 2. Description of the Related Art An inkjet image forming apparatus such as an inkjet printer is known (for example, see [Patent Document 1] and [Patent Document 2]).

  In the inkjet system, in the configuration in which the recording liquid is directly discharged from the head to the recording material such as recording paper, the head and the recording material are close to each other, so paper dust, dust, etc. adhering to the recording material is applied to the nozzle. Easy to adhere. When paper dust or the like adheres to the nozzle, the flying direction of droplets ejected from the nozzle is disturbed, or the nozzle is blocked, resulting in a reduction in image quality and reliability. In order to avoid such a problem, priority is given to the ejection stability from the nozzles, and it is common to use a recording liquid having a low viscosity. However, a recording liquid having a low viscosity is applied to the recording material. Bleeding is likely to occur when landing.

  In view of this, an image forming apparatus that includes an intermediate transfer member that carries the recording liquid discharged from the head, forms an image on the intermediate transfer member, and then transfers the image to a recording material has been proposed (for example, Patent Document 1). (See Patent Document 2)).

  Further, in the image forming apparatus provided with the intermediate transfer member as described above, an image forming device including a processing liquid applying unit that applies a processing liquid for changing the pH of the recording liquid to the intermediate transfer member in order to further reduce bleeding. Has been proposed (see, for example, [Patent Document 1]). In this image forming apparatus, in the recording liquid, at least a pigment and polymer fine particles are dispersed in a medium composed of water and a water-soluble solvent, and the pigment and polymer fine particles are aggregated by changing pH.

  In addition, in an image forming apparatus provided with an intermediate transfer body, an image forming apparatus in which a powder that absorbs a recording liquid is previously deposited on the intermediate transfer body in order to reduce bleeding is proposed (for example, [Patent Documents] 2]).

  However, such an image forming apparatus has a problem that the printing speed decreases due to the application of the treatment liquid or powder, and the apparatus becomes large. In particular, in the configuration in which the powder is applied, the powder tends to adhere to the nozzle and the discharge performance of the recording liquid from the head tends to decrease. It is necessary to solve the problem while ensuring the discharge performance.

  The present invention suppresses bleeding without applying a treatment liquid or powder other than the recording liquid while ensuring the discharge performance of the recording liquid from the head. The recording liquid is applied to the intermediate transfer member by the head. An object of the present invention is to provide an image forming apparatus for forming an image and an image forming method using the image forming apparatus.

  In order to achieve the above object, an invention according to claim 1 is provided with a head provided with a nozzle for discharging a conductive recording liquid and a conductive recording liquid discharged by the head. At least between the intermediate transfer member and the head for electrolyzing the conductive recording liquid discharged from the head and temporarily bridging between the head and the intermediate transfer member. A voltage applying means for applying a voltage by an alternating voltage; a transfer means for transferring an image carried on the intermediate transfer member to the recording material by a conductive recording liquid; and applying the voltage to the conductive recording liquid. The image forming apparatus includes a voltage application control unit that controls a frequency and / or a voltage value of the voltage application in order to control a discharge caused by the applied voltage.

  According to a second aspect of the present invention, in the image forming apparatus according to the first aspect, when the voltage application control unit controls the frequency of the voltage application, the frequency is the frequency at which the conductive recording liquid is ejected from the nozzle. It is characterized by the above.

  According to a third aspect of the present invention, in the image forming apparatus according to the first or second aspect, the voltage application by the voltage applying unit is performed by superimposing a DC voltage on an AC voltage.

  According to a fourth aspect of the present invention, in the image forming apparatus according to any one of the first to third aspects, the image forming apparatus further includes a current detection unit configured to detect a current flowing through the conductive recording liquid in the state.

  According to a fifth aspect of the present invention, in the image forming apparatus according to any one of the first to fourth aspects, the plurality of heads are provided, and the voltage application control unit individually applies the voltage to each of the heads. It is controllable to be performed.

  The invention according to claim 6 is the image forming apparatus according to any one of claims 1 to 5, wherein the conductive recording liquid contains water as a solvent, and the pigment is dispersed by an anionic dispersant. The intermediate transfer member functions as an anode when a voltage is applied by the voltage applying unit.

  A seventh aspect of the present invention is an image forming method for forming an image using the image forming apparatus according to any one of the first to sixth aspects.

  The present invention provides a head having a nozzle for discharging a conductive recording liquid, an intermediate transfer member to which a conductive recording liquid discharged by the head is applied, at least a surface of which is conductive, and a head discharged from the head. Voltage application for applying voltage by at least an alternating voltage between the intermediate transfer body and the head for electrolyzing the conductive recording liquid in a state where the head and the intermediate transfer body are temporarily bridged And a transfer means for transferring an image carried on the intermediate transfer member to the recording material by a conductive recording liquid, and for controlling a discharge due to a voltage applied to the conductive recording liquid by the voltage application. Since the image forming apparatus has a voltage application control means for controlling the frequency and / or voltage value of the voltage application, the treatment liquid or powder other than the conductive recording liquid is obtained by electrolysis of the conductive recording liquid. In addition to this, it is possible to suppress bleeding, and in addition to this, voltage application by applying such a voltage using at least an AC voltage controlled in such a manner that the frequency and / or voltage value is applied. Therefore, it is possible to prevent or reduce the scattering of the conductive recording liquid and the load on the head and the intermediate transfer member due to the discharge due to the discharge, thereby providing an image forming apparatus capable of forming a good image. .

  When the voltage application control means controls the frequency of the voltage application, if the frequency is set to be equal to or higher than the frequency at which the conductive recording liquid is discharged from the nozzle, the conductive recording liquid is electrolyzed. It is possible to suppress bleeding without applying treatment liquid or powder other than the recording liquid, and in addition to this, at least using an AC voltage controlled in such a manner that the frequency and / or voltage value is applied. By applying such a voltage, when the frequency of the printing pressure is the same as the frequency of discharging the conductive recording liquid from the nozzle, the frequency of the printing pressure is controlled from the nozzle to the conductive recording liquid by relatively simple control. When the frequency is higher than the frequency at which the ink is discharged, it is more highly possible to prevent or reduce the scattering of the conductive recording liquid and the load on the head and intermediate transfer member due to the discharge caused by the voltage application. The ability, it is possible to provide an image forming apparatus which makes it possible to perform good image formation.

  If the voltage application by the voltage application means is performed by superimposing a direct current voltage on an alternating current voltage, no treatment liquid or powder other than the conductive recording liquid is applied by electrolysis of the conductive recording liquid. In addition, it is possible to suppress bleeding, and in addition to this, by applying such a voltage using at least an AC voltage controlled in such a manner that the frequency and / or voltage value is applied, the AC voltage is reduced and compared. It is possible to prevent or reduce the scattering of the conductive recording liquid due to the discharge caused by the voltage application and the load on the head and the intermediate transfer member, while reducing the load on the head and the intermediate transfer member. An image forming apparatus that can be performed can be provided.

  If there is a current detection means for detecting the current flowing in the conductive recording liquid in the state, electrolysis of the conductive recording liquid, without applying a treatment liquid or powder other than the conductive recording liquid, Bleeding can be suppressed, and in addition to this, voltage application is performed using at least an AC voltage whose frequency and / or voltage value is controlled in this manner based on the current detected by the current detection means. Therefore, it is possible to prevent or reduce the scattering of the conductive recording liquid due to the discharge caused by the voltage application and the load on the head and the intermediate transfer body to a higher degree, thereby enabling the formation of a good image. An apparatus can be provided.

  If there are a plurality of the heads and the voltage application control means can control the voltage application to be performed individually in each of the heads, conductive recording can be performed by electrolysis of the conductive recording liquid. Bleeding can be suppressed without applying a treatment liquid or powder other than the liquid, and in addition to this, the frequency and / or voltage value is applied to each head, and the AC voltage is individually controlled for each head. By applying such a voltage using at least, it is possible to more highly prevent or reduce the scattering of the conductive recording liquid due to the discharge resulting from the application of the voltage and the load on the head and the intermediate transfer member with higher controllability. Therefore, it is possible to provide an image forming apparatus that can perform good image formation.

  The conductive recording liquid contains water as a solvent, the pigment is dispersed by an anionic dispersant, and the intermediate transfer member functions as an anode when a voltage is applied by the voltage applying unit. The electrolysis of a highly versatile conductive recording liquid can suppress bleeding without applying a treatment liquid or powder other than the conductive recording liquid, and in addition to this, the frequency and / or By applying such a voltage using at least an alternating voltage controlled in such a manner that the voltage value is applied, scattering of the conductive recording liquid due to discharge resulting from such voltage application and load on the head and the intermediate transfer member are prevented or reduced. Therefore, it is possible to provide an image forming apparatus that can perform good image formation.

  Since the present invention is in an image forming method for forming an image using such an image forming apparatus, the electrolysis of the conductive recording liquid causes bleeding without applying a treatment liquid or powder other than the conductive recording liquid. In addition to this, by applying the voltage using at least an AC voltage controlled in such a manner that the frequency and / or voltage value is applied, the conductive recording by the discharge resulting from the voltage application is performed. Since it is possible to prevent or reduce the splashing of liquid and the load on the head and the intermediate transfer member, it is possible to provide an image forming method capable of performing good image formation.

1 is a schematic front view of an image forming apparatus to which the present invention is applied. FIG. 2 is a schematic diagram illustrating a state in which conductive recording liquid is applied from a head to an intermediate transfer member in the image forming apparatus illustrated in FIG. 1. FIG. 2 is a conceptual diagram illustrating a state where pigments in a conductive recording liquid discharged from a head in the image forming apparatus illustrated in FIG. 1 are aggregated via protons. FIG. 2 is a conceptual diagram showing a state of a liquid column by a conductive recording liquid formed between a cathode and an anode in the image forming apparatus shown in FIG. FIG. 3 is a conceptual diagram illustrating a configuration example having a current detection unit that detects a current flowing in a conductive recording liquid in a state where a head and an intermediate transfer member are temporarily bridged. It is a conceptual diagram of the evaluation pattern used for the experiment for confirming whether image formation is performed by application of this invention. FIG. 3 is a conceptual diagram showing a state in which pigments in a conductive recording liquid discharged from a head in an image forming apparatus having a metal intermediate transfer member surface aggregated via protons and metal cations. FIG. 2 is a schematic front view illustrating a configuration example of an image forming apparatus having a transfer image carrier having an elastic surface in an image forming apparatus having a metal intermediate transfer body surface.

  FIG. 1 shows an outline of an image forming apparatus to which the present invention is applied. The image forming apparatus 100 is a printer as an ink jet printer and can perform full-color image formation. The image forming apparatus 100 performs an image forming process based on an image signal corresponding to image information received from the outside.

  The image forming apparatus 100 can form an image on a sheet-like recording medium using not only plain paper generally used for copying, but also OHP sheets, cardboard, cardboard, cardboard, and envelopes. It is. The image forming apparatus 100 is a single-sided image forming apparatus that can form an image on one side of a transfer sheet S that is a recording medium as a recording medium that is a recording medium. It may be an image forming apparatus.

  The image forming apparatus 100 ejects a recording liquid, which is a conductive recording liquid as ink of that color, capable of forming an image as an image corresponding to each color separated into yellow, magenta, cyan, and black. The recording heads 61 </ b> Y, 61 </ b> M, 61 </ b> C, and 61 </ b> BK are recording heads that are ink heads as recording liquid discharge bodies.

  The heads 61Y, 61M, 61C, and 61BK are disposed at positions facing the outer peripheral surface of the intermediate transfer body 37 that is an intermediate transfer drum disposed at a substantially central portion of the main body 99 of the image forming apparatus 100. The heads 61Y, 61M, 61C, 61BK are arranged in this order from the upstream side in the A1 direction, which is the moving direction of the intermediate transfer body 37 and is the clockwise direction in FIG. In the drawing, Y, M, C, and BK added after the numerals of the reference numerals indicate members for yellow, magenta, cyan, and black.

  The heads 61Y, 61M, 61C, and 61BK are respectively ink ejection devices 60Y, 60M, which are recording liquid ejection devices for forming yellow (Y), magenta (M), cyan (C), and black (BK) images. It is provided in 60C and 60BK. Each of the heads 61Y, 61M, 61C, and 61BK is provided in the ink ejection devices 60Y, 60M, 60C, and 60BK in such a manner that a plurality of the heads 61Y, 61M, 61C, and 61BK are arranged in parallel in the direction perpendicular to the paper surface of FIG.

  The intermediate transfer body 37 is rotated in the A1 direction and is recorded in yellow, magenta, cyan, and black from the heads 61Y, 61M, 61C, and 61BK in an area facing the heads 61Y, 61M, 61C, and 61BK. The liquids are ejected and applied in such a manner that they are sequentially superimposed, and an image is formed on the surface. As described above, the image forming apparatus 100 has a tandem structure in which the heads 61Y, 61M, 61C, and 61BK are opposed to the intermediate transfer member 37 and are arranged in parallel in the A1 direction.

  The recording liquid is ejected or applied to the intermediate transfer member 37 by the heads 61Y, 61M, 61C, 61BK upstream of the A1 direction so that the image areas of yellow, magenta, cyan, and black are overlapped at the same position on the intermediate transfer member 37. The timing is shifted from the side toward the downstream side.

  The image forming apparatus 100 includes ink discharge devices 60Y, 60M, 60C, and 60BK that are provided with heads 61Y, 61M, 61C, and 61BK, and an intermediate transfer member 37 that is transferred as the intermediate transfer member 37 rotates in the A1 direction. A transport unit 10 serving as a paper transport unit for transporting the paper S, and a feeding unit that can load a large number of transfer sheets S and feeds only the top transfer sheet S among the stacked transfer sheets S toward the transport unit 10. It has a paper unit 20 and a paper discharge tray 25 on which a large number of printed transfer papers S that have been transported by the transport unit 10 can be stacked.

  The image forming apparatus 100 includes ink discharge devices 60Y, 60M, 60C, and 60BK that are provided with heads 61Y, 61M, 61C, and 61BK, and an intermediate transfer member 37 that is transferred as the intermediate transfer member 37 rotates in the A1 direction. A transport unit 10 serving as a paper transport unit for transporting the paper S, and a feeding unit that can load a large number of transfer sheets S and feeds only the top transfer sheet S among the stacked transfer sheets S toward the transport unit 10. It has a paper unit 20 and a paper discharge tray 25 on which a large number of printed transfer papers S that have been transported by the transport unit 10 can be stacked.

  As shown in FIG. 1, the image forming apparatus 100 also removes the recording liquid remaining on the intermediate transfer body 37 from the intermediate transfer body 37 after the recording liquid is transferred to the transfer paper S. A cleaning unit 34 as a cleaning unit for cleaning, a carriage 50 as a head support that integrally supports the heads 61Y, 61M, 61C, and 61BK, a CPU that controls the overall operation of the image forming apparatus 100, a memory, and the like And a control unit 40 as control means.

  In addition to the intermediate transfer member 37, the transport unit 10 is disposed so as to face the intermediate transfer member 37, and when the transfer sheet S passes through the transfer unit 31 that is an area between the transfer unit S and the intermediate transfer member 37. The transfer means 64 for transferring the image of the recording liquid carried thereon onto the transfer paper S and the transfer paper S fed from the paper supply unit 20 are guided to the transfer unit 31 and passed through the transfer unit 31. A guide plate 39 that guides the transfer sheet S to the paper discharge table 25, and a motor or the like as a driving unit (not shown) that rotationally drives the intermediate transfer body 37 in the A1 direction. As described above, the image forming apparatus 100 is an indirect image forming apparatus that indirectly forms an image on the transfer sheet S using the intermediate transfer body 37.

  The transfer unit 64 includes a transfer roller 38 that rotates following the intermediate transfer member 37. The transfer roller 38 may include a heater for fixing the image transferred onto the transfer paper S to the transfer paper S. Further, the transport unit 10 may include a fixing roller as a fixing unit for fixing the image transferred from the intermediate transfer body 37 to the transfer sheet S by the transfer roller 38 on the transfer sheet S.

  As shown in FIG. 2, the intermediate transfer member 37 includes a support 37a made of aluminum, which is a conductive substrate, and a surface layer 37b made of silicone rubber formed on the support 37a. The material of the support 37a is not limited to aluminum, and may be formed of a metal such as an aluminum alloy, copper, or stainless steel as long as it has mechanical strength. The material of the surface layer 37b is not limited to silicone rubber. For the advantage of high releasability of the recording liquid, any elastic material having low surface energy and high followability to the transfer paper S may be used. You may form with rubber | gum, fluororubber, nitrile butadiene rubber, etc.

The surface layer 37b is a conductive rubber in which metal fine particles such as carbon, platinum, and gold as a conductive agent are dispersed and mixed in the rubber material in order to impart conductivity to the intermediate transfer member 37. It has become. However, when the number of conductive fine particles is increased, the conductivity is improved, but since there is a trade-off relationship in which the releasability is lowered, adjustment is necessary as appropriate. As will be described later, in order to form a desired potential difference in the liquid column of the recording liquid temporarily bridged by the heads 61Y, 61M, 61C, 61BK and the intermediate transfer body 37, the volume resistivity of the conductive rubber is 10 ^3. It is preferably less than Ω · cm, and preferably smaller than the volume resistivity of the recording liquid. The conductive agent may not be fine metal particles, and may be metal fibers or carbon nanotubes as long as conductivity is imparted to the surface layer 37b.

  The thickness of the surface layer 37b is preferably about 0.1 to 1 mm, and preferably 0.2 to 0.6 mm. However, the surface layer 37 b is not an essential component, and only the support 37 a may be used as the intermediate transfer member 37. Further, the intermediate transfer body 37 is not in a drum shape, but may be in an endless belt shape or in a sheet shape if possible.

  As shown in FIG. 1, the paper feeding unit 20 transports only the uppermost transfer paper S among the paper feed tray 21 on which a large number of transfer papers S can be stacked and the transfer paper S stacked on the paper feed tray 21. The sheet feeding roller 22 fed toward the unit 10, the casing 23 supporting the sheet feeding tray 21 and the sheet feeding roller 22, and the sheet feeding roller 22 are ejected from the recording liquid in the heads 61Y, 61M, 61C, 61BK. It has a motor or the like as a driving means (not shown) that rotates and feeds the transfer paper S so as to match the timing.

  The carriage 50 can be replaced with a new one when the heads 61Y, 61M, 61C, 61BK are deteriorated, and in order to facilitate maintenance, the heads 61Y, 61M, 61C, 61BK can be replaced. And can be attached to and detached from the main body 99. Each of the heads 61Y, 61M, 61C, 61BK can be independently attached to and detached from the main body 99 so that it can be replaced with a new one when deterioration or the like occurs and for easy maintenance. ing. This facilitates replacement work and maintenance work.

  The ink discharge devices 60Y, 60M, 60C, and 60BK have substantially the same configuration with respect to the other points although the colors of the recording liquid to be used are different. Each of the ink ejection devices 60Y, 60M, 60C, and 60BK includes a plurality of heads 61Y, 61M, 61C, and 61BK that are arranged in the main scanning direction. The ink ejection devices 60Y, 60M, 60C, and 60BK, and the image forming apparatus 100 are heads. It is a fixed full line type.

  The ink ejection devices 60Y, 60M, 60C, and 60BK are ink cartridges 81Y, 81M, and 81C that are recording liquid cartridges as main tanks that store the recording liquids of the corresponding colors supplied to the plurality of heads 61Y, 61M, 61C, and 61BK. , 81BK, a pump (not shown) as a supply pump for pumping and feeding the recording liquid stored in the ink cartridges 81Y, 81M, 81C, 81BK toward the heads 61Y, 61M, 61C, 61BK, and a pump Is a distributor as an ink supply unit that is a recording liquid supply unit that distributes and supplies the recording liquid supplied from the ink cartridges 81Y, 81M, 81C, and 81BK to the heads 61Y, 61M, 61C, and 61BK. With distributor tank

  The ink ejection devices 60Y, 60M, 60C, and 60BK are also inks (not shown) as ink amount detection means that are recording liquid amount detection means for detecting the recording liquid amount in order to detect a shortage of the recording liquid amount in the distributor tank. An amount detection sensor, a pipe (not shown) that forms a feeding path for the recording liquid between the ink cartridges 81Y, 81M, 81C, 81BK and the distributor tank together with a pump; a distributor tank and each head 61Y, 61M, 61C; And a pipe (not shown) that forms a recording liquid feeding path between the unit and 61BK.

  The ink cartridges 81Y, 81M, 81C, 81BK are replaced with new ones when the internal recording liquid is consumed and the remaining amount is low or no longer used, and in order to facilitate maintenance. 99 is removable.

  The operation of the pump is controlled by the control unit 40. Specifically, on the condition that the ink amount detection sensor detects the shortage of the recording liquid amount in the distributor tank, it is driven until this shortage is not detected, and the recording in the ink cartridges 81Y, 81M, 81C, 81BK is performed. Supply liquid to distributor tank. In this respect, the control unit 40 functions as an ink supply control unit that is a recording liquid supply control unit. The control unit 40 controls the driving of the image forming apparatus 100 even when not specifically described.

  The recording liquid contains at least a colorant corresponding to yellow, magenta, cyan, and black, an anionic dispersant that is a dispersant for the colorant, and a solvent. Due to the colorant and the dispersant, the ink component of the recording liquid has an anionic group. The solvent contains water from the viewpoint of safety and the conductivity from the viewpoint of causing electrolysis to be described later, and the recording liquid is a water-soluble recording liquid that is a conductive ink and a water-soluble ink. The recording liquid is desirably alkaline from the viewpoint of storage stability.

The pigment that is a colorant used in the recording liquid is not particularly limited, but as a pigment for orange or yellow, C.I. I. Pigment orange 31, C.I. I. Pigment orange 43, C.I. I. Pigment yellow 12, C.I. I. Pigment yellow 13, C.I. I. Pigment yellow 14, C.I. I. Pigment yellow 15, C.I. I. Pigment yellow 17, C.I. I. Pigment yellow 74, C.I. I. Pigment yellow 93, C.I. I. Pigment yellow 94, C.I. I. Pigment yellow 128, C.I. I. Pigment yellow 138, C.I. I. Pigment yellow 151, C.I. I. Pigment yellow 155, C.I. I. Pigment yellow 180, C.I. I. And CI Pigment Yellow 185.
Further, as a pigment for red or magenta, C.I. I. Pigment red 2, C.I. I. Pigment red 3, C.I. I. Pigment red 5, C.I. I. Pigment red 6, C.I. I. Pigment red 7, C.I. I. Pigment red 15, C.I. I. Pigment red 16, C.I. I. Pigment red 48: 1, C.I. I. Pigment red 53: 1, C.I. I. Pigment red 57: 1, C.I. I. Pigment red 122, C.I. I. Pigment red 123, C.I. I. Pigment red 139, C.I. I. Pigment red 144, C.I. I. Pigment red 149, C.I. I, Pigment Red 166, C.I. I. Pigment red 177, C.I. I. Pigment red 178, C.I. I. And CI Pigment Red 222.
Further, as a pigment for green or cyan, C.I. I. Pigment blue 15, C.I. I. Pigment blue 15: 2, C.I. I. Pigment blue 15: 3, C.I. I. Pigment blue 16, C.I. I. Pigment blue 60, C.I. I. And CI Pigment Green 7.
Further, as a pigment for black, C.I. I. Pigment black 1, C.I. I. Pigment black 6, C.I. I. Pigment black 7 and the like.
The content of the pigment in the recording liquid is usually 0.1 to 40% by mass, preferably 1 to 30% by mass, and more preferably 2 to 20% by mass.

  Examples of the anionic dispersant include, but are not limited to, fatty acid salt, alkyl sulfate ester salt, alkyl benzene sulfonate, alkyl naphthalene sulfonate, dialkyl sulfosuccinate, alkyl phosphate ester salt, naphthalene sulfonate formalin condensate, poly Examples thereof include oxyethylene alkyl sulfate esters, and two or more of them may be used in combination.

From the viewpoint of transferability, the recording liquid preferably further contains a resin having an anionic group in which a carboxyl group, a sulfonic acid group, a phosphonic acid group or the like is neutralized with a base.
The recording liquid may further contain a solvent soluble in water. Solvents that are soluble in water are not particularly limited, but are polyvalent such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, triethylene glycol, 1,5-pentanediol, 1,2,6-hexanetriol, and glycerin. Alcohols: ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monobutyl ether, dipropylene glycol monobutyl ether, ethylene oxide adduct of diglycerin Polyhydric alcohol derivatives such as pyrrolidone, N-methyl-2-pyrrolidone, Nitrogen-containing solvents such as hexylpyrrolidone and triethanolamine; alcohols such as ethanol, isopropyl alcohol, butyl alcohol and benzyl alcohol; sulfur-containing solvents such as thiodiethanol, thiodiglycerol, sulfolane and dimethyl sulfoxide; propylene carbonate, ethylene carbonate and the like These may be used in combination of two or more.

  As shown in FIG. 2, each of the heads 61Y, 61M, 61C, 61BK includes a conductive nozzle plate 61a disposed on the recording liquid discharge side facing downward in the drawing and a nozzle 61b formed on the nozzle plate 61a. And an ink chamber 61c supplied with the recording liquid from the distributor tank and filled with the recording liquid, and an ink discharge means (not shown) for discharging the recording liquid in the ink chamber 61c from the nozzle 61b. The nozzle plate 61a, the nozzle 61b, the ink chamber 61c, and the ink discharge means are provided as a set, and each head 61Y, 61M, 61C, 61BK is provided in large numbers, but only one of them is shown in FIG. Is illustrated. The nozzle plate 61a is provided in each of the heads 61Y, 61M, 61C, 61BK, and is common to all the nozzles 61b in each of the heads 61Y, 61M, 61C, 61BK.

  Although detailed illustration is omitted, the nozzle plate 61 a includes a conductive substrate and a water repellent film formed on the surface of the substrate facing the intermediate transfer body 37. The water-repellent film may be formed by applying a fluorine-based water repellent or a silicon-based water repellent, or may be formed by plating a fluorine-based polymer or a fluorine-metal compound eutectoid, Any film having water repellency is not particularly limited. The nozzle plate 61a includes a surface on the ink chamber 61c side as an interface forming portion that forms an interface with the recording liquid in the ink chamber 61c, and functions as a cathode as will be described later.

  The entire nozzle plate 61a may be conductive, or may be a member in which only the surface on the ink chamber 61c side is subjected to conductive treatment, or an intermediate member between the conductive member disposed on the ink chamber 61c side. You may comprise by the insulating member arrange | positioned by the transfer body 37 side.

  Since the conductive portion of the nozzle plate 61a is provided as a cathode as will be described later, it does not have to be made of a material having resistance to metal elution, and if it is made of a highly conductive material such as metal or carbon. Good.

  The nozzle plate 61 a is set so that the gap with the intermediate transfer member 37 is 50 to 200 μm. If the gap is less than 50 μm, it may be difficult to maintain the gap between the intermediate transfer member 37, which is a rotating body, and the nozzle plate 61a. If the gap exceeds 200 μm, the liquid injection described later may be performed. This is because it may be difficult to form a bridge. However, if the gap can be maintained, there is no particular problem even if it is less than 50 μm, and even if it is 200 μm or more, there is no problem if a stable liquid column bridge is formed.

  The ink ejecting means has a piezoelectric element as an actuator for ejecting the recording liquid from each nozzle 61b to be ejected and landed on the transfer paper S, and responds to a voltage pulse applied to the piezoelectric element under the control of the control unit 40. Thus, the recording liquid is discharged from the nozzle 61b. In this regard, the control unit 40 functions as an ink ejection control unit. The control unit 40 functioning as an ink ejection control unit inputs a voltage pulse for driving the piezoelectric element to each of the piezoelectric elements with a predetermined signal waveform.

  In this embodiment, the nozzle plate 61a, the nozzle 61b, the ink chamber 61c, and the ink discharge means are provided as a set, and are provided in each of the heads 61Y, 61M, 61C, and 61BK. In addition, the ink discharge means can individually control the discharge timing of the recording liquid from each nozzle 61b.

  The actuator of the ink discharge means may be a movable actuator of another method that is a shape deformation element method such as a piezo method, or the recording liquid is discharged from the nozzle 61b by a heater method such as a thermal method. Also good.

  The energization means 33 is realized as a part of the function of the control unit 40 and an electric circuit (not shown) that connects the power source 33a, the power source 33a to the support 37a, and grounds the nozzle plate 61a. Voltage application control means for controlling timing and application time.

  The power source 33a is connected to the support body 37a. In this embodiment, the energization means 33 causes the intermediate transfer member 37 to function as an anode and the nozzle plate 61a to function as a cathode, thereby aggregating the colorant components of the recording liquid on the intermediate transfer member 37 side, as will be described later. It is provided for producing an action.

  The power supply 33a forms a potential difference between the support 37a and the nozzle plate 61a by applying a voltage obtained by superimposing a DC voltage on the AC voltage to the support 37a. As described later, the power source 33a applies a voltage obtained by superimposing a DC voltage on an AC voltage to the support 37a, so that better image formation can be performed than applying only an AC voltage to the support 37a. The AC voltage value necessary for good image formation can also be reduced, and the configuration of the power source 33a itself or the configuration of the image forming apparatus 100 can be simplified. What is necessary is just to apply, and you may make it apply only an alternating voltage to the support body 37a.

The power source 33a may be connected to the nozzle plate 61a depending on the type of recording liquid to be used, or may be configured to be connected between the support 37a and the nozzle plate 61a.
The power source 33a is provided in each of the heads 61Y, 61M, 61C, 61BK.

  The controller 40 as voltage application control means applies the AC voltage value of the power source 33a, the frequency of the AC voltage, and the DC voltage value to the recording liquid between the support 37a and the nozzle 61a by the power source 33a, as will be described later. In order to prevent discharge from being generated by the applied voltage or to the extent that the influence on the image by this discharge does not become a problem, control is performed so as to satisfy the above conditions. In other words, the control unit 40 serving as a voltage application control unit controls such discharge in such a manner that the AC voltage value, the frequency of the AC voltage, and the DC voltage value of the power source 33a are controlled so as to satisfy such conditions. The AC voltage value referred to here includes the AC voltage value corresponding to the phase with respect to the recording liquid ejection timing from the nozzle 61b at the frequency. As already described, the power source 33a may be at least for applying a voltage with an AC voltage. Therefore, when the power source 33a only applies a voltage with an AC voltage, a control unit as a voltage application control means is provided. 40 controls at least one of the AC voltage value of the power source 33a and the frequency of the AC voltage so as to satisfy such a condition.

  If this condition is satisfied, the control unit 40 as the voltage application control means controls the AC voltage value, the frequency of the AC voltage, and the DC voltage value of the power source 33a so as to be a predetermined constant set value. However, the AC voltage value of the power source 33a, the frequency of the AC voltage, and the DC voltage value may be configured to be controlled in such a manner that at least one of the AC voltage value and the AC voltage frequency is changed. In this case, it functions as voltage changing means. For example, when the control unit 40 functioning as the ink ejection control unit changes the signal waveform of the voltage pulse for driving the piezoelectric element, the voltage application control unit is set so as to satisfy the above-described condition accordingly. The control unit 40 functions as voltage changing means.

  Note that the control unit 40 as the voltage application control unit also controls the power supply 33a even when controlling the AC voltage value, the frequency of the AC voltage, and the DC voltage value of the power supply 33a to be a predetermined constant set value. The discharge is controlled by controlling the voltage application timing, the application time, the AC voltage value of the power source 33a, the frequency of the AC voltage, and the DC voltage value so as to satisfy the above-mentioned conditions.

  As shown in FIG. 1, the cleaning means 34 is constituted by a cleaning blade as a cleaning member formed of rubber as an elastic body, which is in contact with the intermediate transfer body 37 in a so-called counter contact manner. . The cleaning unit 34 may include a cleaning roller as a cleaning member together with the cleaning blade.

  In the image forming apparatus 100 having such a configuration, the intermediate transfer body 37 rotates in the A1 direction while facing the heads 61Y, 61M, 61C, 61BK in response to the input of a predetermined signal indicating the start of image formation. In the process, the yellow, magenta, cyan, and black recording liquids are transferred from the heads 61Y, 61M, 61C, and 61BK so that the image areas of the respective colors of yellow, magenta, cyan, and black overlap with the same position on the intermediate transfer body 37. The images are ejected in such a manner that they are sequentially overlapped from the upstream side toward the downstream side in the A1 direction, and an image is temporarily carried on the intermediate transfer member 37.

  At this time, the energization unit 33 is driven by the control unit 40 as the voltage application control unit, and a voltage is applied from the power source 33a to the support 37a, so that a potential difference is formed between the support 37a and the nozzle plate 61a.

  In this state, the recording liquid is applied from the heads 61Y, 61M, 61C, 61BK onto the intermediate transfer body 37. At that time, first, the heads 61Y, 61M, 61C, 61BK are used as shown in FIG. As shown in FIG. 2B, the recording liquid forming a meniscus in the nozzle 61b moves toward the intermediate transfer body 37 as shown in FIG. 2B, and the recording liquid is recorded between the nozzle 61b and the intermediate transfer body 37. A bridge of a liquid column made of liquid is temporarily formed, and then, as shown in FIG. 2C, the bridge of the liquid column made of recording liquid is divided so as to be carried on the intermediate transfer body 37, and the intermediate transfer. An image of the recording liquid is formed on the body 37.

In the state where the liquid injection bridge made of the recording liquid is formed as shown in FIG. 2B, the colorant component in the recording liquid is subjected to an aggregating action by the energizing means 33. Specifically, when a voltage is applied to the intermediate transfer member 37 by the energizing means 33, the nozzle plate 61a functioning as a cathode and the intermediate transfer member 37 functioning as an anode when a positive voltage is applied. Then, the following electrode reaction occurs, and water contained in the bridge of the liquid column of the recording liquid is electrolyzed.
^{_{Cathode: 4H 2 O + 4e - →}} 2H 2 + 4OH - ··· reaction formula (1)
_{^{Anode: 2H 2 O → 4H + +}} O 2 + 4e - ··· reaction formula (2)

  As a result, the water contained in the bridge of the liquid column of the recording liquid is oxidized on the surface of the intermediate transfer member 37 functioning as an anode to generate protons (H +), and as shown in FIG. The pigment P dispersed by D aggregates via protons. Thereby, the occurrence of bleeding between adjacent dots is suppressed, and a high-definition image is formed. In addition, there is an advantage that clogging of the nozzle 61b is prevented by such voltage application. The time for forming such a bridge can be controlled by the peak voltage and pulse width of the electromagnetic pulse applied to the piezoelectric element.

Here, the bridge of the liquid column formed between the cathode and the anode will be described with reference to FIG. Inside the bridge B of the liquid column, cations and anions move in the vicinity of the cathode C and the anode A, respectively. As a result, the surface of the cathode C and the anode A, the electric double layer E _C and E _A respectively is formed, the charging speed of the electric double layer E _C and E _A is the conductivity of the bridge B of the liquid column, recording It is almost determined by the concentration of ions contained in the liquid. At this time, when the voltage of the electric double layer E _A reaches several V, Faraday current flows water is electrolyzed. As a result, on the surface of the anode A, water is oxidized to generate protons, and the pigment dispersed by the anionic dispersant is aggregated. That is, at the moment when such a bridge is formed, ions that cause an aggregation action of the pigment are efficiently generated in the bridge, so that the pigment is aggregated simultaneously with the landing of the recording liquid on the intermediate transfer body 37. As a result, pigment bleeding does not occur between adjacent recording liquid dots, and a very high-definition solute image is formed.

As described above, the energizing means 33 includes the intermediate transfer body 37 and the heads 61Y, 61M, 61C, 61BK, specifically the nozzle plate 61a for electrolyzing the recording liquid forming the bridge B of the liquid column. It is the structure for performing the voltage application between.
This voltage application is controlled by the control unit 40 functioning as a voltage application control means and a voltage changing means in order to control the discharge caused by the voltage applied to the recording liquid by this voltage application. Such discharge and control modes will be described in detail later.

  The time from the formation of the bridge B of the liquid column to the separation is usually several microseconds to several tens of microseconds, and the conductivity of the recording liquid is usually several tens mS / m to several hundreds mS / second. m. For this reason, in order to form an image of the recording liquid on the intermediate transfer member 37, the voltage applied by the energizing means 33 is 1.23 V, which is the theoretical decomposition voltage of water, or a number that is a general condition for electrolysis of water. V to several tens of volts is insufficient, and it is preferably several tens of volts to several hundreds of volts.

  In synchronization with the timing at which the leading edge of the image carried on the intermediate transfer body 37 reaches the transfer unit 31, a single sheet of transfer paper S fed from the paper supply unit 20 is supplied to the transfer unit 31, and the transfer roller 38. , The image carried on the intermediate transfer body 37 is transferred to the transfer sheet S passing through the transfer unit 31, and an image is formed on the surface of the transfer sheet S. The transfer sheet S on which the image is formed is guided to the paper discharge tray 25 and stacked on the paper discharge tray 25.

  When the image is transferred to the transfer paper S in this way, the recording liquid containing the aggregation component is transferred to the transfer paper S. Therefore, by forming an image with the colorant aggregated by the above-described aggregation action, even when the transfer paper S is plain paper, high image density can be achieved at high speed while preventing or suppressing feathering and bleeding. High-quality image formation is possible.

  In order to perform high-speed image formation, since the recording liquid needs to be quick-drying, the recording liquid generally has high absorbability to the transfer paper S. In this case, the recording liquid is deep in the transfer paper S. Penetrating to the surface and causing so-called offset, making it unsuitable for double-sided image formation. However, since the aggregating action reduces the absorbability of the recording liquid onto the transfer paper S, such a set-off is prevented or suppressed, which is suitable for double-sided image formation. Furthermore, since the absorbability of the recording liquid to the transfer paper S is reduced, deformation of the transfer paper S such as cockling and curling is suppressed or prevented, and thereby the transfer paper S carrying an image is conveyed. The handling of the transfer sheet S is facilitated, for example, the property is improved and jamming is prevented or suppressed.

  Almost no components due to the recording liquid remain on the intermediate transfer member 37 that has passed through the transfer unit 31 due to the transfer in the transfer unit 31, but the intermediate transfer member 37 is subjected to cleaning by the cleaning unit 34, thereby recording. Liquid offset is highly prevented or suppressed, and even when image formation is repeatedly performed, background contamination due to offset is prevented or suppressed, image deterioration and deterioration of the intermediate transfer body 37 are suppressed or prevented, and the time is good. Image formation can be performed.

  In the image forming apparatus 100 as described above, the recording liquid is recorded by the energizing means 33 before and after the intermediate transfer member 37 and the heads 61Y, 61M, 61C, 61BK are bridged between the nozzle plates 61a. If the voltage application for electrolyzing the liquid is continued, a discharge due to the voltage applied to the recording liquid is generated by this voltage application, which may cause a problem in image formation or apply a load to the image forming apparatus 100. I understood.

  When this phenomenon is verified in more detail, the discharge is a discharge in the air, and the recording liquid discharged from the heads 61Y, 61M, 61C, 61BK approaches the intermediate transfer body 37, and the recording liquid and the intermediate transfer body 37 are discharged. When the distance between the intermediate transfer body 37 and the head 61Y, 61M, 61C, 61BK bridges, the recording liquid cuts off. Considered to occur when the distance between the recording liquid and the heads 61Y, 61M, 61C, 61BK is a distance that causes a discharge due to the voltage applied to the recording liquid, away from 61Y, 61M, 61C, 61BK. Is done. In these cases, the recording liquid scatters due to the discharge and the image is disturbed. In the former case, the image is also disturbed by damage to the intermediate transfer member 37 due to the discharge. In the latter case, The water repellent film is destroyed by discharge or the main body of the nozzle plate 61a is also destroyed particularly when it is made of resin, so that the meniscus is not maintained in a normal state, and an image is also formed due to abnormal discharge of the recording liquid. It seems to be disturbed.

  Such a discharge is considered to be mainly the above-described discharge in the air, but may include a discharge in the recording liquid in addition to the discharge in the air. The discharge in the recording liquid is considered to be triggered by the occurrence of discharge in the air, and causes an unnecessary aggregation action in the recording liquid in the nozzle 61b or the recording liquid applied to the intermediate transfer body 37. It is guessed.

  In the image forming apparatus 100, the above-described conditions are satisfied, that is, such discharge is prevented, or the quality of the formed image and the load on the image forming apparatus 100 are suppressed so as not to cause a problem. In order to control, the controller 40 functioning as a voltage application control means applies a voltage between the intermediate transfer member 37 and the heads 61Y, 61M, 61C, 61BK, specifically, each nozzle plate 61a. It comes to perform control.

  Here, it supplements about the above-mentioned discharge. However, the intermediate transfer member 37 and the nozzle plate are not considered before and after the state where the bridge of the recording liquid is formed between the nozzle 61b and the intermediate transfer member 37 without considering the control of the discharge as described above. When the voltage application to 61a is continued by, for example, a DC voltage, the discharge is mainly performed at the end of the bridge, immediately before the recording liquid is cut, rather than immediately after the recording liquid bridges between the nozzle 61b and the intermediate transfer member 37. As the applied voltage is increased, the discharge generation time becomes earlier, and eventually discharge is confirmed before and after the bridge, but this discharge is compared with the discharge immediately before the bridge is cut. It turned out that it was weak discharge.

  The control by the control unit 40 functioning as the voltage application control means takes into account the above-described discharge mechanism, and the alternating current according to the state in which the recording liquid discharged from the nozzle 61b bridges between the nozzle 61b and the intermediate transfer body 37. The voltage application method is changed.

Specifically, if the applied voltage value is low and no discharge occurs before bridging, or if it does not affect the image, voltage application below the discharge start voltage is applied immediately before the recording liquid bridging ends. The frequency of the AC voltage and the phase with respect to the recording liquid ejection cycle are controlled so as to be performed.
Also, if the applied voltage is high and a discharge that affects the image occurs before bridging, it reaches a voltage higher than the discharge start voltage at the timing immediately after the recording liquid bridges, and immediately before the bridge ends. The frequency of the AC voltage and the phase with respect to the recording liquid ejection cycle are controlled so that a voltage lower than the timing discharge start voltage is applied.
The timing here is not particularly limited as long as it does not cause discharge.

In the case of applying a voltage value obtained by superimposing an AC voltage and a DC voltage or only an AC voltage, the voltage value is determined by the type of the recording liquid.
The frequency of the AC voltage is set corresponding to the set frequency of the discharge frequency because the ink discharge frequency, that is, the discharge frequency is set by each machine.

  If the frequency of the AC voltage is the same as the discharge frequency, the control of the frequency of the AC voltage itself is relatively easy. However, the frequency may be higher than the discharge frequency. In this case, as described later, Depending on the conditions, the weak discharge just before the bridging of the recording liquid has the advantage of being well controlled.

  When making the frequency of the AC voltage higher than the discharge frequency, it is particularly preferable from the viewpoint of easy control that the frequency is an integral multiple of the discharge frequency. However, when changing the frequency of the AC voltage in a timely manner, the frequency of the AC voltage may be lower than the discharge frequency.

When making the frequency of the AC voltage higher than the ejection frequency, it is preferable to determine the frequency of the AC voltage so as to satisfy the above-described conditions depending on the time for which the recording liquid bridges.
Regarding the time of the bridge state, that is, the timing at which the bridge is formed, this may be detected by detecting the current flowing in the recording liquid when the recording liquid bridges, or depending on the ink ejection conditions Those prepared in advance by measurement or the like may be used.

  In order to detect whether or not the recording liquid is in a bridging state, for example, as shown in FIG. 5, the current flowing through the recording liquid when the energizing means 33 bridges the recording liquid is detected. It is set as the structure provided with the ammeter 33b as a detection means. When such a configuration is used, overcurrent due to discharge can be detected in real time by monitoring the current value with the ammeter 33b, and even if a discharge occurs in the scale, the AC voltage and DC voltage, or the AC voltage The application timing and the like can be changed so as not to cause discharge. In the configuration shown in the figure, the ammeter 33b is provided on the nozzle plate 61a side, but the ammeter 33b may be provided on the power supply 33a side.

  When such time is prepared in advance by measurement or the like and used, for example, the temperature and humidity environment and the signal waveform input to the piezoelectric element provided in the ink discharge means by the control unit 40 functioning as the ink discharge control means. Depending on the combination with the input timing, the time for bridging from a certain reference time is measured and used. The temperature / humidity environment is detected, for example, by providing a temperature / humidity sensor in the image forming apparatus 100.

  As described above, the power source 33a is provided in each of the heads 61Y, 61M, 61C, and 61BK. Therefore, the control unit 40 functioning as a voltage application control unit controls voltage application in a manner in which the above-described discharge is controlled individually for each of the heads 61Y, 61M, 61C, and 61BK. In other words, the power source 33a can be controlled by the control unit 40 functioning as a voltage application control unit so that the voltage application is individually performed in such a manner in each of the heads 61Y, 61M, 61C, and 61BK. .

  Under such control, as shown in FIG. 2B, the recording liquid in a state where the heads 61Y, 61M, 61C, 61BK and the intermediate transfer body 37 are temporarily bridged is electrolyzed. For this purpose, the power supply 33a applies a voltage between the heads 61Y, 61M, 61C, 61BK and the intermediate transfer member 37, that is, a decomposition voltage as a control voltage.

It was confirmed whether image formation was performed satisfactorily by the following experiment considering the above conditions.
The experimental conditions are as follows.

The image forming apparatus used in the experiment is an image forming apparatus obtained by remodeling an ink jet printer GX5000 (manufactured by Ricoh) having the same configuration as that of the image forming apparatus 100 that satisfies the following conditions.
The intermediate transfer member 37 is a silicone rubber layer in which carbon is dispersed with a volume resistivity of 5.3 Ω · cm and a thickness of 0.5 mm as a surface layer 37b on the outer periphery of an aluminum base tube as a support 37a. And is driven to rotate in the A1 direction at an outer peripheral linear velocity of 500 mm / s.
An AC voltage was applied to the intermediate transfer member 31, and each head 61 was electrically grounded. Whether or not the DC voltage is superimposed on the AC voltage is as shown in the table below.

The gap between each head 61Y, 61M, 61C, 61BK and the intermediate transfer member 37 was 80 μm.
The transfer roller 38 is formed by forming a rubber layer having a thickness of 5 mm on a metal core.
As the cleaning means 34, a blade made of fluororubber was used.

  In this experiment, the heads 61Y, 61M, 61C, 61BK are not moved in the longitudinal direction of the intermediate transfer body 37, that is, the direction perpendicular to the A1 direction, ie, the direction perpendicular to the paper surface of FIG. 61M, 61C, 61BK were used in a fixed manner. Each head 61Y, 61M, 61C, 61BK was installed at a position shifted in the A1 direction as shown in FIG. Each of the heads 61Y, 61M, 61C, and 61BK includes a large number of nozzles 61b. However, this experiment was performed by discharging a recording liquid from the selected nozzle 61b so that bleeding can be evaluated later. FIG. 6 shows a conceptual diagram of an ejection pattern which is an image pattern formed by this experiment, that is, an evaluation pattern. The ejection pattern formed by this experiment is an image formed by repeating eight lines having different adjacent colors shown in the figure, and an evaluation described later was performed based on the image formation result by the ejection pattern. .

  The following recording liquid was used.

<Yellow recording liquid>
-Sulfonic acid group-bonded yellow pigment dispersion (CAB-O-JET-270Y, solid content 10% by mass, manufactured by Cabot Specialty Chemicals Inc.): 40.0% by mass
Triethylene glycol: 14.0% by mass
・ Glycerin: 30.0% by mass
Propylene glycol monobutyl ether: 7.0% by mass
・ Sodium dehydroacetate: 0.1% by mass
Distilled water: remaining amount Subsequently, the pH was adjusted to 9.2 with a 5% by mass aqueous solution of lithium hydroxide, and pressure filtration was performed with a membrane filter having an average pore diameter of 0.8 μm.

<Magenta recording liquid>
-Sulfonic acid group-bonded magenta pigment dispersion (CAB-O-JET-260M, solid content 10% by mass, manufactured by Cabot Specialty Chemicals, Inc.): 40.0% by mass
・ Diethylene glycol: 25.0% by mass
Propylene glycol monobutyl ether: 5.0% by mass
・ Sodium dehydroacetate: 0.1% by mass
Distilled water: remaining amount Subsequently, the pH was adjusted to 9.2 with a 5% by mass aqueous solution of lithium hydroxide, and pressure filtration was performed with a membrane filter having an average pore diameter of 0.8 μm.

<Cyan recording liquid>
-Sulfonic acid group-bonded cyan pigment dispersion (CAB-O-JET-250C, solid content 10% by mass, manufactured by Cabot Specialty Chemicals Inc.): 40.0% by mass
・ Ethylene glycol: 5.0% by mass
Triethylene glycol: 18.0% by mass
Propylene glycol monobutyl ether: 5.0% by mass
・ Sodium dehydroacetate: 0.1% by mass
Distilled water: remaining amount Subsequently, the pH was adjusted to 9.2 with a 5% by mass aqueous solution of lithium hydroxide, and pressure filtration was performed with a membrane filter having an average pore diameter of 0.8 μm.

<Black recording liquid>
-Sulfonic acid group-bonded carbon black pigment dispersion (CAB-O-JET-200, solid content 20% by mass, manufactured by Cabot Specialty Chemicals Inc.): 35.0% by mass
・ 2-Pyrrolidone: 9.0% by mass
・ Glycerin: 20.0% by mass
Propylene glycol monobutyl ether: 1.0% by mass
・ Sodium dehydroacetate: 0.1% by mass
・ Distilled water: remaining amount
Thereafter, the pH was adjusted to 9.2 with a 5% by mass aqueous solution of lithium hydroxide, and pressure filtration was performed with a membrane filter having an average pore diameter of 0.8 μm.

  In this evaluation, the signal waveforms input to the piezoelectric elements of all the nozzles 71b in each of the heads 61Y, 61M, 61C, 61BK are the same. By observation in advance, it was confirmed that the recording liquid bridge was formed between 7 μsec and 31 μsec after the input of each period of the signal waveform.

The evaluation procedure for each example and each comparative example is as follows.
(1) While moving each of the heads 61Y, 61M, 61C, 61BK in a direction perpendicular to the A1 direction and corresponding to the direction perpendicular to the paper surface in FIG. 1, one dot from each head 61Y, 61M, 61C, 61BK Ten line images were output along the A1 direction. The ejection frequency in each head 61Y, 61M, 61C, 61BK was 12.5 kHz, and the ejection time was 1 second.
(2) The Ricoh business coat gloss 100 was conveyed between the intermediate transfer member 37 and the transfer roller 38, and the conductive recording liquid image formed in (1) on the intermediate transfer member was transferred.
(3) Step (1) was performed again, and ink scattering on the intermediate transfer member 37 was observed.
(4) In (1) and (2), the discharge time was 4 seconds, and after repeating these 200 times, the state of the water-repellent film of each head 61Y, 61M, 61C, 61BK was observed.

  Table 1 below summarizes the conditions of each example and each comparative example, and the bleeding and ink scattering as evaluation results.

In the “conditions” shown in the table, “AC voltage value” means the peak value, that is, the maximum value of the AC voltage to be applied. The alternating voltage is applied as a sine wave.
In the “conditions” shown in the table, “frequency” means the frequency of the AC voltage to be applied.
In the “conditions” shown in the table, “DC voltage value” means the value of the DC voltage superimposed on the AC voltage.
In the “conditions” shown in the table, “timing” indicates that the timing at which the signal waveform for ejecting the recording liquid by operating the nozzle 71b is input to the piezoelectric element of the nozzle 71b is set to 0 μs as a reference. This is the AC voltage application timing at which the value of the AC voltage applied as a sine wave is Sin0. For example, when the “timing” is 5 μs, it means that the value of the AC voltage becomes 0 V after 5 μs after inputting the signal waveform applied to the piezoelectric element of the nozzle 71b. The wave phase changes and a positive voltage begins to be applied. When the “timing” value is negative, it means that the value of the AC voltage applied as a sine wave becomes 0 V before the input of the signal waveform.

In the “results” shown in the table, “bleeding” is observed with a microscope and evaluated for bleeding at the boundary portion of the recording liquid of each color, and the evaluation criteria are as follows.
・ The boundary can be seen very clearly ... ◎
・ The boundary is clearly visible ... ○
・ Slight bleeding but no problem level ... △
・ Lines are mixed and the original color is not clear ... ×
In the “results” shown in the table, “scattering” is an evaluation of the scattering of the recording liquid of each color on the intermediate transfer member 37, and the evaluation criteria are as follows.
・ Spattering is not confirmed ... ○
・ Slight splattering but no problem level ... △
・ Splashes violently and the line is fat ... ×

From the table, the effect on bleeding and scattering by application of AC voltage is confirmed.
It was also found that when an AC voltage having the same frequency as the ejection frequency is applied, it is possible to suppress discharge when the recording liquid bridge is broken. If the frequency of the AC voltage is made higher than the discharge frequency, depending on the conditions, weak discharge that occurs just before the recording liquid bridges is prevented or suppressed, so that scattering is prevented or suppressed to a satisfactory level, and the color in the recording liquid is suppressed. It was found that a good image quality without blurring can be obtained because a voltage necessary for electrolysis for aggregating the agent component is sufficiently provided.

  Next, the damage of the water repellent film before and after image formation was examined. Regarding each Example and Comparative Example 1, there was no particular change in the water repellent film. In the example where the scattering evaluation item of the example is Δ, a slight discharge may occur, but no change in the water-repellent film was confirmed. However, regarding Comparative Example 2, it was found by observation that the water repellent film was damaged. In addition, it was found that the meniscus formation was greatly deteriorated due to the influence.

Here, in the configuration in which the intermediate transfer body 37 is not provided with the surface layer 37b and is composed of the support body 37a, the support body 37a functions as an anode as described above. In this case, it is possible to oxidize the support body 37a which is a metal together with water on the surface of the support body 37a. When the support 37a, which is a metal, is oxidized, a metal cation excellent in aggregating the colorant is generated. Therefore, as shown in FIG. 7, an anionic property is obtained via a proton and a metal cation (M ^{n +} ). The pigment P dispersed by the dispersant D is aggregated, and the cohesion is increased.

  In such a configuration, as shown in FIG. 8, the transfer means 64 transfers not only the transfer roller 38 but also the image formed on the intermediate transfer member 37 and temporarily carries it as an elastic layer on the surface. It is desirable to provide an intermediate transfer drum 63 as a transfer image carrier having a rubber layer 63a. The intermediate transfer drum 63 is rotated with the intermediate transfer member 37, and the transfer roller 38 is rotated with the intermediate transfer drum 63. Since the surface of the intermediate transfer drum 63 is an elastic body, the transfer of the image from the intermediate transfer body 37 made of metal and having a high surface hardness is performed well, and the transferability is improved.

  The intermediate transfer drum 63 has a rubber layer 63a and a base 63b covered with the rubber layer 63a. Although it does not specifically limit as a material which comprises the base | substrate 63b, Metals, such as aluminum, an aluminum alloy, copper, and stainless steel, are mentioned. Although it does not specifically limit as a material which comprises the rubber layer 63a, Silicone rubber, urethane rubber, fluorine rubber, etc. are mentioned.

  Here, the control unit 40 is provided with the recording liquid ejected by the heads 61Y, 61M, 61C, 61BK and the heads 61Y, 61M, 61C, 61BK provided with the nozzle 61b that ejects the recording liquid, and the heads 61Y, 61M, 61C, 61BK. At least the surface of the intermediate transfer body 37 and the recording liquid ejected from the heads 61Y, 61M, 61C, 61BK and the heads 61Y, 61M, 61C, 61BK and the intermediate transfer body 37 are temporarily bridged. An energizing means 33 for applying a voltage by at least an alternating voltage between the intermediate transfer body 37 for electrolysis and the heads 61Y, 61M, 61C, 61BK, and an image carried on the intermediate transfer body 37 by a recording liquid In order to control the discharge due to the voltage applied to the recording liquid by applying the voltage, the transfer means 64 for transferring the image to the transfer paper S Voltage application stores the image forming program for executing an image forming method using a control unit 40 which functions as a voltage application control means for controlling the frequency and / or voltage value that. In this regard, the control unit 40 or the memory functions as an image forming program storage unit. Such an image forming program includes not only a memory provided in the control unit 40 but also a semiconductor medium (for example, ROM, non-volatile memory), an optical medium (for example, DVD, MO, MD, CD-R, etc.), a magnetic medium. (For example, a hard disk, a magnetic tape, a flexible disk, etc.) It can be stored in other storage media. When such an image forming program is stored in such a memory or other storage medium, the computer reading that stores the image forming program Configure possible recording media.

  The preferred embodiments of the present invention have been described above. However, the present invention is not limited to the specific embodiments, and the present invention described in the claims is not specifically limited by the above description. Various modifications and changes are possible within the scope of the above.

For example, in the above-described embodiment, a positive voltage is applied to the intermediate transfer body in a state where the pigment of the conductive recording liquid column is dispersed by the anionic dispersant and a bridge of the conductive recording liquid is formed. The intermediate transfer member functions as an anode when it is carried out, but the pigment in the conductive recording liquid is dispersed by a cationic dispersant and formed on the surface of the intermediate transfer member functioning as a cathode. Aggregation may be performed via physical ions.
The intermediate transfer member does not need to be conductive as a whole, and at least the surface may be conductive.

  The image forming apparatus to which the present invention is applied is not limited to the above-described type of image forming apparatus, but may be other types of image forming apparatuses, that is, a shuttle type with respect to the head, or a copying machine or a facsimile alone. Alternatively, these multifunction peripherals, multifunction peripherals such as monochrome machines related thereto, other image forming apparatuses used for forming electric circuits, and image forming apparatuses used for forming predetermined images in the biotechnology field may be used. . The number of heads is increased or decreased according to the application of the image forming apparatus, and may be one or plural.

  The effects described in the embodiments of the present invention are only the most preferable effects resulting from the present invention, and the effects of the present invention are limited to those described in the embodiments of the present invention. is not.

33 Voltage application means 33b Current detection means 37 Intermediate transfer body 40 Voltage application control means 61b Nozzle 61Y, 61M, 61C, 61BK Head 64 Transfer means 100 Image forming apparatus S Recording material

JP 2008-62397 A Japanese Patent Laid-Open No. 11-188858

Claims (7)

A head having a nozzle for discharging a conductive recording liquid;
An intermediate transfer body having at least a surface conductive, to which the conductive recording liquid discharged by the head is applied,
Voltage application by at least an alternating voltage between the intermediate transfer member and the head for electrolyzing the conductive recording liquid discharged from the head and temporarily bridging between the head and the intermediate transfer member Voltage applying means for performing,
Transfer means for transferring an image carried on the intermediate transfer member by a conductive recording liquid to a recording material;
An image forming apparatus comprising voltage application control means for controlling the frequency and / or voltage value of the voltage application in order to control the discharge due to the voltage applied to the conductive recording liquid by the voltage application. The image forming apparatus according to claim 1.
An image forming apparatus characterized in that when the voltage application control means controls the voltage application frequency, the frequency is equal to or higher than the frequency at which the conductive recording liquid is ejected from the nozzle. The image forming apparatus according to claim 1 or 2,
The image forming apparatus according to claim 1, wherein the voltage application by the voltage application unit is performed by superimposing a DC voltage on an AC voltage. The image forming apparatus according to any one of claims 1 to 3,
An image forming apparatus comprising: a current detection unit configured to detect a current flowing through the conductive recording liquid in the state. The image forming apparatus according to any one of claims 1 to 4,
A plurality of the heads;
The image forming apparatus, wherein the voltage application control unit can control the voltage application individually in each of the heads. The image forming apparatus according to any one of claims 1 to 5,
The conductive recording liquid contains water as a solvent, the pigment is dispersed by an anionic dispersant,
The image forming apparatus, wherein the intermediate transfer member functions as an anode when a voltage is applied by the voltage applying unit.   An image forming method for forming an image using the image forming apparatus according to claim 1.

Images