JP2012087346A - Reflow apparatus of tin-electroplated steel sheet - Google Patents

Reflow apparatus of tin-electroplated steel sheet Download PDF

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JP2012087346A
JP2012087346A JP2010233698A JP2010233698A JP2012087346A JP 2012087346 A JP2012087346 A JP 2012087346A JP 2010233698 A JP2010233698 A JP 2010233698A JP 2010233698 A JP2010233698 A JP 2010233698A JP 2012087346 A JP2012087346 A JP 2012087346A
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steel sheet
tin
electrotin
conductor roll
plated steel
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Shinji Ezaki
慎次 江崎
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Nippon Steel Engineering Co Ltd
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Nippon Steel Engineering Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To eliminate unnecessary energizing heating to thereby save energy and improve uniformity of product quality of a tin-electroplated steel sheet in the reflow treatment by energizing heating of the tin-electroplated steel sheet.SOLUTION: In a reflow apparatus 6 of the tin-electroplated steel sheet, a tin-electroplated steel sheet S which is tin-electroplated in a plating apparatus and then continuously conveyed is subjected to energizing heating at least with an entrance-side conductor roll 11 and an exit-side conductor roll 12 to allow tin on the surface of the tin-electroplated steel sheet S to melt and then water-cooled by passing through a quench tank 13 containing cooling water. The exit-side conductor roll 12 is arranged in water contained in the quench tank 13, and support rolls 14 are arranged in a plurality of places starting from the position where the tin-electroplated steel sheet S begins to contact the exit-side conductor roll 12 so as to sandwich the tin-electroplated steel sheet S between the support roll 14 and the exit-side conductor roll 12.

Description

本発明は、連続電気錫めっきラインにおいて、めっき装置で電気錫めっきされて連続的に送られてくる電気錫めっき鋼板の合金化処理(リフロー処理)を行うリフロー装置に関する。   The present invention relates to a reflow apparatus that performs an alloying process (reflow process) on an electrotin-plated steel sheet that is continuously electrotin plated with a plating apparatus in a continuous electrotin plating line.

連続電気錫めっきラインにおいては、めっき装置で電気錫めっきされた電気錫めっき鋼板のめっき面に光沢を持たせるためと、地金と錫めっき層間に合金層を形成するためにリフロー処理を行うが、このリフロー処理のための加熱方法には、(1)ガス、電熱による間接加熱、(2)直接通電による抵抗加熱、(3)高周波磁界による誘導加熱等の方法が知られている。ただし、上記のガス、電熱による間接加熱方法は、応答性が悪くライン速度変更等の操業条件の変化に追従できず、また通常の場合であってもライン長が長くなるという欠点があり、高周波磁界による誘導加熱は設備が高くなるという欠点があるので、直接通電による加熱方法が広く使用されている。   In continuous electrotin plating line, reflow treatment is performed to make the plating surface of electrotin plating steel sheet electroplated with plating equipment bright and to form an alloy layer between the metal and tin plating layers. As heating methods for this reflow treatment, there are known methods such as (1) indirect heating by gas and electric heating, (2) resistance heating by direct energization, and (3) induction heating by a high frequency magnetic field. However, the above-mentioned indirect heating method using gas or electric heat has a drawback that it is not responsive and cannot follow changes in operating conditions such as line speed change, and it has the disadvantage that the line length becomes long even in normal cases. Since induction heating by a magnetic field has a disadvantage that the equipment becomes expensive, a heating method by direct energization is widely used.

この直接通電による加熱を利用したリフロー処理では、所定の間隔をおいて配置された入側コンダクターロールと出側コンダクターロールを用い、これらのコンダクターロール間の電気錫めっき鋼板に通電し抵抗加熱する。そして、この抵抗加熱により電気錫めっき鋼板を錫の融点(232℃)以上に加熱して、電気錫めっき鋼板表面の錫を溶融させた後、冷却水を入れたクエンチタンクに通して急冷する。   In the reflow process using heating by direct energization, an entrance-side conductor roll and an exit-side conductor roll arranged at a predetermined interval are used, and the electrotin-plated steel sheet between these conductor rolls is energized and resistance-heated. Then, the electric tin-plated steel sheet is heated above the melting point (232 ° C.) of tin by this resistance heating to melt the tin on the surface of the electrotin-plated steel sheet, and then rapidly cooled through a quench tank containing cooling water.

このような直接通電によるリフロー処理を行うリフロー装置には、上述のとおり、入側コンダクターロール、出側コンダクターロール及びクエンチタンクが必要であるが、従来、これらは、電気錫めっき鋼板の走行方向に、入側コンダクターロール、クエンチタンク、出側コンダクターロールの順に配置されていた(特許文献1〜3参照)。   As described above, the reflow apparatus for performing the reflow process by direct energization requires the entry side conductor roll, the exit side conductor roll, and the quench tank, but conventionally, these are in the traveling direction of the electrotin-plated steel sheet. , The entrance conductor roll, the quench tank, and the exit conductor roll were arranged in this order (see Patent Documents 1 to 3).

特開平7−335371号公報JP 7-335371 A 特開2000−273682号公報JP 2000-273682 A 特開2007−169768号公報JP 2007-169768 A

電気錫めっき鋼板のリフロー処理において電気錫めっき鋼板の温度は、本来、クエンチタンクに入る前に錫の融点以上になればよい。   In the reflow treatment of the electrotin-plated steel sheet, the temperature of the electrotin-plated steel sheet should originally be equal to or higher than the melting point of tin before entering the quench tank.

しかし、上述した従来のリフロー装置におけるコンダクターロールの位置関係では、クエンチタンクを出た後の電気錫めっき鋼板も通電加熱される。このクエンチタンクを出た後の電気錫めっき鋼板の加熱は、リフロー処理には不必要であるから、その分、エネルギーの無駄が生じる。   However, according to the positional relationship of the conductor rolls in the conventional reflow apparatus described above, the electrotin-plated steel sheet after exiting the quench tank is also heated by energization. Since the heating of the electrotin-plated steel sheet after leaving the quench tank is unnecessary for the reflow process, energy is wasted correspondingly.

そこで、本発明が解決しようとする課題は、電気錫めっき鋼板の通電加熱によるリフロー処理において、不必要な通電加熱をなくして省エネルギーを図ることにある。   Therefore, the problem to be solved by the present invention is to save energy by eliminating unnecessary energization heating in the reflow process by electroheating of the electrotin-plated steel sheet.

上記課題を解決するため、本発明者は、クエンチタンク内で電気錫めっき鋼板を支持するために従来から配置されていた水中ロールを出側コンダクターロールとして使用することを考えた。   In order to solve the above-mentioned problems, the present inventor considered using an underwater roll that has been conventionally arranged as an outgoing conductor roll in order to support an electrotin-plated steel sheet in a quench tank.

ただし、単に水中ロールを出側コンダクターロールとするだけでは、以下の問題があることがわかった。   However, it was found that simply using the underwater roll as the outgoing conductor roll has the following problems.

すなわち、とくに電気錫めっき鋼板の走行速度が高速になると、水の粘性や表面張力等により電気錫めっき鋼板と出側コンダクターロールとの間に水が巻き込まれる。そうすると、電気錫めっき鋼板と出側コンダクターロールとの間の電気抵抗が増加し、電力損失も増大する。また、電気錫めっき鋼板の走行速度によっては、上記電気抵抗が変動することにより、電気錫めっき鋼板と出側コンダクターロールとの間にアークが発生し、電気錫めっき鋼板及び出側コンダクターロールに表面疵が発生するおそれがある。   That is, particularly when the traveling speed of the electrotin-plated steel sheet becomes high, water is caught between the electrotin-plated steel sheet and the outgoing conductor roll due to the viscosity or surface tension of water. If it does so, the electrical resistance between an electrotin plating steel plate and an outgoing side conductor roll will increase, and a power loss will also increase. Further, depending on the traveling speed of the electrotin-plated steel sheet, the electric resistance fluctuates, so that an arc is generated between the electrotin-plated steel sheet and the outgoing conductor roll, and the surface of the electric tin-plated steel sheet and the outgoing conductor roll is increased. There is a risk of wrinkles.

そこで、本発明では、電気錫めっき鋼板と出側コンダクターロールとの間に水が巻き込まれることを防止するために、電気錫めっき鋼板が出側コンダクターロールに接触し始める位置にサポートロールを配置し、このサポートロールと出側コンダクターロールとで電気錫めっき鋼板を挟み込むようにした。   Therefore, in the present invention, in order to prevent water from being caught between the electric tin-plated steel sheet and the outgoing conductor roll, a support roll is disposed at a position where the electric tin-plated steel sheet begins to contact the outgoing conductor roll. The electrotin-plated steel sheet was sandwiched between the support roll and the outgoing conductor roll.

すなわち、本発明は、めっき装置で電気錫めっきされて連続的に送られてくる電気錫めっき鋼板に対し、少なくとも入側コンダクターロール及び出側コンダクターロールによる通電加熱で電気錫めっき鋼板表面の錫を溶融させた後、冷却水を入れたクエンチタンクを通して水冷する電気錫めっき鋼板のリフロー装置において、出側コンダクターロールをクエンチタンクの水中に配置し、電気錫めっき鋼板が出側コンダクターロールに接触し始める位置から複数箇所にサポートロールを配置し、このサポートロールと出側コンダクターロールとで電気錫めっき鋼板を挟み込むようにしたことを特徴とするものである。   That is, the present invention relates to an electrotin-plated steel sheet that has been electrotin-plated continuously by a plating apparatus, and at least the tin on the surface of the electrotin-plated steel sheet is heated by energization heating with an entrance-side conductor roll and an exit-side conductor roll. In the reflow device for electrotinned steel sheet, which is melted and then cooled with water through a quench tank containing cooling water, the outgoing conductor roll is placed in the water of the quench tank, and the electric tinned steel sheet begins to contact the outgoing conductor roll. Support rolls are arranged at a plurality of positions from the position, and the electrotin-plated steel sheet is sandwiched between the support roll and the outgoing conductor roll.

また、本発明では、上記構成に加えて、電気錫めっき鋼板が出側コンダクターロールに接触し始める位置の入側に堰を配置し、電気錫めっき鋼板に誘導されるクエンチタンク内の冷却水の流れが、電気錫めっき鋼板が出側コンダクターロールに接触し始める位置に向かうことを妨げるようにすることができる。   In the present invention, in addition to the above-described configuration, a weir is disposed on the entry side where the electrotin-plated steel sheet begins to contact the output-side conductor roll, and the cooling water in the quench tank is guided to the electrotin-plated steel sheet. The flow can be prevented from going to a position where the electrotinned steel sheet begins to contact the outgoing conductor roll.

このように堰を設けることで、電気錫めっき鋼板と出側コンダクターロールとの間に水が巻き込まれることを、より確実に防止できる。   By providing the weir in this way, it is possible to more reliably prevent water from being caught between the electrotin-plated steel sheet and the outgoing conductor roll.

本発明では、出側コンダクターロールをクエンチタンクの水中に配置したので、不必要な通電加熱をなくすことができ、省エネルギーを図ることができる。   In the present invention, since the outgoing conductor roll is arranged in the water of the quench tank, unnecessary energization heating can be eliminated and energy saving can be achieved.

さらに、クエンチタンクの水中で、電気錫めっき鋼板が出側コンダクターロールに接触し始める位置から複数箇所にサポートロールを配置し、このサポートロールと出側コンダクターロールとで電気錫めっき鋼板を挟み込むようにしたので、電気錫めっき鋼板と出側コンダクターロールとの間に水が巻き込まれることを防止でき、水の巻き込みによる電気抵抗の増加やアークの発生といった不具合が発生することを防止できる。また、上述のように堰を設けることで、この水の巻き込みをより確実に防止できる。   Furthermore, in the quench tank water, support rolls are placed in multiple locations from the position where the electroplated steel sheet begins to contact the output conductor roll, and the electrotin plated steel sheet is sandwiched between the support roll and the output conductor roll. Therefore, it is possible to prevent water from being caught between the electrotin-plated steel sheet and the outgoing conductor roll, and it is possible to prevent the occurrence of problems such as an increase in electrical resistance and arcing due to the entrainment of water. Further, by providing the weir as described above, it is possible to more reliably prevent the water from being involved.

本発明のリフロー装置を適用した連続電気錫めっきラインの構成例を示す。The structural example of the continuous electrotin plating line to which the reflow apparatus of this invention is applied is shown. 本発明のリフロー装置の一実施例を示す。1 shows an embodiment of a reflow apparatus of the present invention. 従来のリフロー装置を示す。The conventional reflow apparatus is shown. 図2のリフロー装置における電気錫めっき鋼板の温度変化と電力使用量を示す。The temperature change and electric power consumption of an electro tin plating steel plate in the reflow apparatus of FIG. 2 are shown. 図3のリフロー装置における電気錫めっき鋼板の温度変化と電力使用量を示す。The temperature change and electric power consumption of an electro tin plating steel plate in the reflow apparatus of FIG. 3 are shown. 本発明のリフロー装置の他の実施例の要部を示す。The principal part of the other Example of the reflow apparatus of this invention is shown. 図6のリフロー装置における堰の配置を示す。The arrangement | positioning of the weir in the reflow apparatus of FIG. 6 is shown. 本発明のリフロー装置のさらに他の実施例を示す。Another embodiment of the reflow apparatus of the present invention will be described.

以下、図面に示す実施例に基づき本発明の実施の形態を説明する。   Embodiments of the present invention will be described below based on examples shown in the drawings.

図1は、本発明のリフロー装置を適用した連続電気錫めっきラインの構成例を示す。   FIG. 1 shows a configuration example of a continuous electrotin plating line to which the reflow apparatus of the present invention is applied.

この連続電気錫めっきラインにおいて、ペイオフリール1a又は1bから供給された鋼板は、入側ルーパ3を経て前処理装置4に導入される。前処理装置4では、鋼板のアルカリ洗浄、酸洗、水洗等の前処理を行い、鋼板表面を清浄化する。なお、図1中の符号2は、先行する鋼板と後続の鋼板とを接続し、連続処理を行うための溶接機である。   In this continuous electric tin plating line, the steel sheet supplied from the payoff reel 1 a or 1 b is introduced into the pretreatment device 4 through the entry side looper 3. In the pretreatment device 4, the steel sheet surface is cleaned by performing pretreatment such as alkali washing, pickling, and water washing of the steel sheet. In addition, the code | symbol 2 in FIG. 1 is a welding machine for connecting a preceding steel plate and a succeeding steel plate and performing a continuous process.

表面を清浄化された鋼板は、めっき装置5で電気錫めっきされ、リフロー装置6でリフロー処理される。リフロー処理された電気錫めっき鋼板は、後処理装置7に導入される。後処理装置7では、変色防止等の後処理を行う。後処理後の電気錫めっき鋼板は、出側ルーパ9を経て、巻き取りリール9a又は9bで巻き取られる。   The steel plate whose surface has been cleaned is subjected to electrotin plating by the plating device 5 and reflowed by the reflow device 6. The electrotin-plated steel sheet subjected to the reflow treatment is introduced into the post-processing device 7. The post-processing device 7 performs post-processing such as discoloration prevention. The electroplated steel sheet after the post-treatment passes through the exit side looper 9 and is taken up by the take-up reel 9a or 9b.

図2は、図1の連続電気錫めっきラインに適用される本発明のリフロー装置の一実施例を示す。通電加熱を利用したリフロー装置では、電気錫めっき鋼板の走行方向の入側及び出側に入側コンダクターロールと出側コンダクターロールを配置するが、本発明のリフロー装置6では、出側コンダクターロール12を、冷却水を入れたクエンチタンク13の水中に配置し、入側コンダクターロール11と出側コンダクターロール12との間の電気錫めっき鋼板Sに通電し抵抗加熱する。そして、この抵抗加熱により電気錫めっき鋼板Sを錫の融点(232℃)以上に加熱して、電気錫めっき鋼板S表面の錫を溶融させた後、クエンチタンク13に通して急冷する。   FIG. 2 shows an embodiment of the reflow apparatus of the present invention applied to the continuous electrotin plating line of FIG. In the reflow apparatus using current heating, the entrance-side conductor roll and the exit-side conductor roll are arranged on the entry side and the exit side in the traveling direction of the electrotin-plated steel sheet. In the reflow apparatus 6 of the present invention, the exit-side conductor roll 12 Is placed in the water of the quench tank 13 containing cooling water, and the electric tin-plated steel sheet S between the inlet-side conductor roll 11 and the outlet-side conductor roll 12 is energized for resistance heating. Then, the electric tin-plated steel sheet S is heated to the melting point (232 ° C.) or higher of tin by this resistance heating to melt the tin on the surface of the electric tin-plated steel sheet S, and then rapidly cooled through the quench tank 13.

また、本発明のリフロー装置6では、クエンチタンク13の水中で電気錫めっき鋼板Sが出側コンダクターロール12に接触し始める位置から複数箇所(実施例では3箇所)にサポートロール14を配置し、このサポートロール14と出側コンダクターロール12とで電気錫めっき鋼板Sを挟み込むようにしている。これによって、電気錫めっき鋼板Sと出側コンダクターロール12との間に水が巻き込まれることを防止している。なお、出側コンダクターロール12は直径600mm程度であり、サポートロール14は直径200mm程度とすることができる。   Further, in the reflow device 6 of the present invention, the support rolls 14 are arranged at a plurality of locations (three locations in the embodiment) from the position at which the electrotin-plated steel sheet S starts to contact the outgoing conductor roll 12 in the water of the quench tank 13, The electrotin-plated steel sheet S is sandwiched between the support roll 14 and the outgoing conductor roll 12. Thus, water is prevented from being caught between the electrotin-plated steel sheet S and the outgoing conductor roll 12. In addition, the output side conductor roll 12 can be about 600 mm in diameter, and the support roll 14 can be about 200 mm in diameter.

一方、従来のリフロー装置においては、図3に示すように出側コンダクターロール12は、クエンチタンク13の後段に配置され、クエンチタンク13の水中には、別途に水中ロール15が配置される。   On the other hand, in the conventional reflow apparatus, as shown in FIG. 3, the outgoing conductor roll 12 is disposed downstream of the quench tank 13, and an underwater roll 15 is separately disposed in the water of the quench tank 13.

図4は、図2に示した本発明のリフロー装置6における電気錫めっき鋼板Sの温度変化と電力使用量を示す。また、図5は、図3に示した従来のリフロー装置6における電気錫めっき鋼板Sの温度変化と電力使用量を示す。図4及び図5において横軸は、リフロー装置の走行方向の位置を示し、A〜Eは、それぞれ図2及び図3のA〜Eの位置に対応する。なお、位置Bは、電気錫めっき鋼板Sを錫の融点(232℃)として電気錫めっき鋼板S表面の錫を溶融させる位置である。   FIG. 4 shows the temperature change and power consumption of the electrotin-plated steel sheet S in the reflow apparatus 6 of the present invention shown in FIG. Moreover, FIG. 5 shows the temperature change and electric power consumption of the electrotin-plated steel sheet S in the conventional reflow apparatus 6 shown in FIG. 4 and 5, the horizontal axis indicates the position of the reflow device in the traveling direction, and A to E correspond to the positions A to E in FIGS. 2 and 3, respectively. In addition, the position B is a position where the tin on the surface of the electrotin-plated steel sheet S is melted with the electrotin-plated steel sheet S as the melting point of tin (232 ° C.).

図4及び図5を比較すると、従来のリフロー装置では位置A〜Eまでを加熱するのに対し、本発明のリフロー装置では位置A〜Dまでを通電加熱する。すなわち、従来は、リフロー処理には不必要な位置D〜Eの間も通電加熱していたが、本発明では、位置D〜Eの間は通電加熱しないので、その分、電力使用量を削減できる。例えば、一般的なリフロー装置では位置A〜Eが約20mであり、位置D〜Eが約2mであるので、本発明により電力使用量を約10%削減できる。   4 and 5, the conventional reflow apparatus heats up to positions A to E, while the reflow apparatus of the present invention heats up to positions A to D. That is, in the past, energization heating was performed even between positions D to E, which are unnecessary for the reflow process, but in the present invention, energization heating is not performed between positions D to E, so that the amount of power used is reduced accordingly. it can. For example, in a general reflow apparatus, the positions A to E are about 20 m and the positions D to E are about 2 m, so that the power consumption can be reduced by about 10% according to the present invention.

図6は、本発明のリフロー装置の他の実施例の要部を示す。図6のリフロー装置6では、電気錫めっき鋼板Sが出側コンダクターロール12に接触し始める位置の入側(図6では上方)に堰16を配置している。この堰16は、図7に示すように、出側コンダクターロール12の全長にわたるように配置されている。このように堰16を配置することで、電気錫めっき鋼板Sに誘導されるクエンチタン13内の冷却水の流れが、電気錫めっき鋼板Sが出側コンダクターロール12に接触し始める位置に向かうことを妨げることができる。   FIG. 6 shows a main part of another embodiment of the reflow apparatus of the present invention. In the reflow device 6 of FIG. 6, the weir 16 is disposed on the entry side (upward in FIG. 6) where the electrotin-plated steel sheet S begins to contact the output conductor roll 12. As shown in FIG. 7, the weir 16 is arranged so as to cover the entire length of the outgoing conductor roll 12. By arranging the weir 16 in this way, the flow of cooling water in the quencher 13 guided to the electrotin-plated steel sheet S is directed to a position where the electrotin-plated steel sheet S starts to contact the outgoing conductor roll 12. Can be disturbed.

このように、上述のサポートロール14に加え、堰16を設けることで、電気錫めっき鋼板Sと出側コンダクターロール12との間に水が巻き込まれることを確実に防止できる。   Thus, by providing the weir 16 in addition to the above-described support roll 14, it is possible to reliably prevent water from being caught between the electrotin-plated steel sheet S and the outgoing conductor roll 12.

なお、以上の実施例では、リフロー処理のための加熱方法として、通電加熱を単独で用いた例を示したが、図8に示すように、クエンチタンク13の前段に高周波誘導加熱装置17を配置し、通電加熱と誘導加熱を併用してもよい。   In the above embodiment, as an example of the heating method for the reflow process, an example in which electric heating is used alone has been shown. However, as shown in FIG. In addition, electric heating and induction heating may be used in combination.

1a,1b ペイオフリール
2 溶接機
3 入側ルーパ
4 前処理装置
5 めっき装置
6 リフロー装置
7 後処理装置
8 出側ルーパ
9a,9b 巻き取りリール
11 入側コンダクターロール
12 出側コンダクターロール
13 クエンチタンク
14 サポートロール
15 水中ロール
16 堰
17 高周波誘導加熱装置
DESCRIPTION OF SYMBOLS 1a, 1b Payoff reel 2 Welding machine 3 Incoming looper 4 Pre-processing device 5 Plating device 6 Reflow device 7 Post-processing device 8 Outgoing looper 9a, 9b Take-up reel 11 Incoming conductor roll 12 Outgoing conductor roll 13 Quench tank 14 Support roll 15 Underwater roll 16 Weir 17 High frequency induction heating device

Claims (2)

めっき装置で電気錫めっきされて連続的に送られてくる電気錫めっき鋼板に対し、少なくとも入側コンダクターロール及び出側コンダクターロールによる通電加熱で電気錫めっき鋼板表面の錫を溶融させた後、冷却水を入れたクエンチタンクを通して水冷する電気錫めっき鋼板のリフロー装置において、
出側コンダクターロールをクエンチタンクの水中に配置し、電気錫めっき鋼板が出側コンダクターロールに接触し始める位置から複数箇所にサポートロールを配置し、このサポートロールと出側コンダクターロールとで電気錫めっき鋼板を挟み込むようにしたことを特徴とする電気錫めっき鋼板のリフロー装置。
Electrotin-plated steel sheet that has been electrotin-plated continuously by a plating device is cooled after melting tin on the surface of the electro-tin-plated steel sheet by energization heating with at least an entrance-side conductor roll and an exit-side conductor roll. In the reflow device for electrotinned steel sheet, which is water-cooled through a quench tank containing water,
Place the output side conductor roll in the water of the quench tank, place the support rolls at multiple locations from the position where the electroplated steel sheet starts to contact the output side conductor roll, and electroplating with this support roll and the output side conductor roll An electrotin-plated steel sheet reflow apparatus characterized by sandwiching a steel sheet.
電気錫めっき鋼板が出側コンダクターロールに接触し始める位置の入側に堰を配置し、電気錫めっき鋼板に誘導されるクエンチタンク内の冷却水の流れが、電気錫めっき鋼板が出側コンダクターロールに接触し始める位置に向かうことを妨げるようにした請求項1に記載の電気錫めっき鋼板のリフロー装置。   A weir is placed on the entry side where the electrotin-plated steel sheet starts to come into contact with the outgoing conductor roll, and the flow of cooling water in the quench tank is guided by the electric tin-plated steel sheet. The reflow apparatus for an electrotin-plated steel sheet according to claim 1, wherein the apparatus is prevented from going to a position at which the contact starts.
JP2010233698A 2010-10-18 2010-10-18 Reflow apparatus of tin-electroplated steel sheet Withdrawn JP2012087346A (en)

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