JP2012038477A - Cylindrical battery - Google Patents

Cylindrical battery Download PDF

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JP2012038477A
JP2012038477A JP2010175752A JP2010175752A JP2012038477A JP 2012038477 A JP2012038477 A JP 2012038477A JP 2010175752 A JP2010175752 A JP 2010175752A JP 2010175752 A JP2010175752 A JP 2010175752A JP 2012038477 A JP2012038477 A JP 2012038477A
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positive electrode
electrode current
lid
current collecting
collecting member
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Yuki Takei
祐紀 武井
Yoshimasa Koishikawa
佳正 小石川
Hirofumi Hori
浩文 堀
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Vehicle Energy Japan Inc
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Hitachi Vehicle Energy Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

PROBLEM TO BE SOLVED: To obtain a cylindrical battery which can simply and sufficiently ensure an electrical conduction between a positive electrode collector member and a lid, and can be easily assembled.SOLUTION: A cylindrical battery 1 comprises a lid case (connection member) 35 electrically connecting a positive electrode collector member 40 and a lid 31 in the state of being interposed therebetween. The lid case 35 is fixed to the positive electrode collector member 40 in the state that a contact pressure is applied to a contact area between the positive electrode collector member 40 and the lid case 35 by being press-contacted to the positive electrode collector member 40, and is electrically connected to the positive electrode collector member 40.

Description

本発明は、例えばリチウムイオン二次電池などの非水電解液二次電池に用いられる円筒形電池に関する。   The present invention relates to a cylindrical battery used for a nonaqueous electrolyte secondary battery such as a lithium ion secondary battery.

地球温暖化の環境問題や化石燃料の枯渇問題から、環境負荷の小さい電気自動車(EV)や駆動の一部を電気モーターで補助するハイブリッド電気自動車(HEV)が各自動車メーカーで開発、販売され、その電源として、高容量で高出力であり、さらに様々な環境での耐久性を有する電池が求められている。   Due to global warming environmental issues and fossil fuel depletion problems, each automobile manufacturer has developed and sold electric vehicles (EV) with a low environmental impact and hybrid electric vehicles (HEV) that assist electric motors with a part of driving, As a power source, a battery having high capacity and high output and durability in various environments is demanded.

現在、これらの自動車に搭載されている電池の主流はニッケル水素電池であり、次世代としてリチウムイオン二次電池が注目されている。これらの電池は、携帯電話やノートパソコンなどの小形民生用に広く普及しており、ここで培った技術を発展させ、自動車用途への適用を進めている。   Currently, nickel-hydrogen batteries are the mainstream of batteries installed in these automobiles, and lithium ion secondary batteries are attracting attention as the next generation. These batteries are widely used for small-sized consumer products such as mobile phones and notebook computers, and the technology cultivated here is developed and applied to automobile applications.

自動車用途に求められる構造面の特徴としては、幅広い周波数帯の振動耐久性、電池の大形化での数十〜数百Aの大電流通電に耐えられる集電構造、低温から高温の温度領域での密閉性などである。   Structural features required for automotive applications include vibration durability in a wide frequency band, current collection structure that can withstand large currents of tens to hundreds of amps when batteries are made larger, and temperature ranges from low to high temperatures. Such as hermeticity.

リチウムイオン二次電池などの非水電解液二次電池の形状としては、一般に円筒形と角形に大別され、円筒形でも電極端子の取り出し方、密閉封口方法などで様々な形状が検討されている。小形民生用においては、正極及び負極の未塗工部から通電のためにタブを取り出し、正極は蓋体に溶接され、負極は電池缶に溶接されて、電気を取り出す方法などが用いられている。この場合、タブは1〜数本取り付けられているのが一般的である。   The shape of non-aqueous electrolyte secondary batteries such as lithium ion secondary batteries is generally roughly divided into cylindrical and rectangular shapes, and various shapes have been studied for cylindrical shapes, such as how to take out electrode terminals and sealing and sealing methods. Yes. In small consumer use, a method is used in which a tab is taken out for energization from uncoated portions of the positive electrode and the negative electrode, the positive electrode is welded to a lid, the negative electrode is welded to a battery can, and electricity is taken out. . In this case, one to several tabs are generally attached.

自動車用途では、大電流通電に耐えるために確実な導通が求められており、タブが多数取り付けられることもある。これらのタブは電極集電部材と溶接され、例えば、正極集電部材はリードを介して蓋体に溶接され、負極集電部材は電池缶に溶接される(特許文献1)。   In automobile applications, reliable conduction is required in order to withstand large current energization, and many tabs may be attached. These tabs are welded to the electrode current collecting member. For example, the positive electrode current collecting member is welded to the lid through the lead, and the negative electrode current collecting member is welded to the battery can (Patent Document 1).

特開2002-231244号公報JP 2002-231244 JP

しかしながら、リードを介して正極集電部材と蓋体を接続する方法の場合、溶接により電気的な導通は十分に確保されるが、正極集電部材とリード、蓋体とリードの二箇所を溶接する必要があった。これらの溶接作業は、溶接部に電解液が付着すると溶接できないので、注液作業より先に行う必要がある。一方、溶接作業を注液作業より先に行うと、電解液の注入流路を確保するため蓋体の位置を一時的に避けて、電解液を注入した後に蓋体を所定位置に戻す必要があるため、作業が複雑になり、工数が多かった。   However, in the case of the method of connecting the positive electrode current collector and the lid through the lead, the electrical continuity is sufficiently ensured by welding, but the positive electrode current collector and the lead, and the lid and the lead are welded. There was a need to do. Since these welding operations cannot be welded if the electrolytic solution adheres to the welded portion, it is necessary to perform these welding operations prior to the liquid injection operation. On the other hand, if the welding operation is performed prior to the pouring operation, it is necessary to temporarily avoid the position of the lid in order to secure the electrolyte injection flow path, and to return the lid to a predetermined position after injecting the electrolyte. As a result, the work was complicated and man-hours were large.

本発明は、上記事案に鑑みてなされたものであり、その目的は、正極集電部材と蓋体との間の電気的導通を簡単かつ十分に確保することができ、容易に組み立てることができる円筒形電池を提供することにある。   The present invention has been made in view of the above-described case, and the object thereof is to easily and sufficiently ensure the electrical continuity between the positive electrode current collecting member and the lid, and can be easily assembled. The object is to provide a cylindrical battery.

上記課題を解決する本発明の円筒形電池は、正極集電部材と蓋体との間に介在されて正極集電部材と蓋体との間を電気的に接続する接続部材を備えており、その接続部材は、正極集電部材に押接されて正極集電部材と接続部材との接触面部に面圧をかけた状態で正極集電部材に固定され、前記正極集電部材に電気的に接続されることを特徴としている。   The cylindrical battery of the present invention that solves the above problems includes a connection member that is interposed between the positive electrode current collector and the lid and electrically connects the positive electrode current collector and the lid, The connecting member is fixed to the positive current collecting member while being pressed against the positive current collecting member and applied a surface pressure to the contact surface portion between the positive current collecting member and the connecting member, and electrically connected to the positive current collecting member. It is characterized by being connected.

本発明によれば、正極集電部材と蓋体との間に介在されて正極集電部材と蓋体との間を電気的に接続する接続部材を備えており、その接続部材は、正極集電部材に押接されて正極集電部材と接続部材との接触面部に面圧をかけた状態で正極集電部材に固定され、前記正極集電部材に電気的に接続される構成を有しているので、正極集電部材と蓋体との間の電気的な導通を面圧によって確保することができ、正極集電部材と蓋体との接触面部の通電抵抗を低減できる。   According to the present invention, the connecting member that is interposed between the positive current collecting member and the lid and electrically connects the positive current collecting member and the lid is provided. The positive electrode current collector is fixed to the positive electrode current collector member while being pressed against the electric member to apply a surface pressure to the contact surface portion between the positive electrode current collector member and the connection member, and is electrically connected to the positive electrode current collector member. Therefore, electrical continuity between the positive electrode current collector and the lid can be ensured by the surface pressure, and the energization resistance of the contact surface portion between the positive electrode current collector and the lid can be reduced.

したがって、従来と比較して、正極集電部材と蓋体との間のリードの溶接作業を行う必要がなく、正極集電部材と蓋体との間の接続作業を簡単化でき、電気的な導通を簡単かつ確実に確保することができる。そして、リードを省略することができ、部品点数を減らすことができる。   Therefore, it is not necessary to perform a lead welding operation between the positive electrode current collecting member and the lid, and the connection work between the positive electrode current collecting member and the lid can be simplified and compared with the conventional case. Conduction can be ensured easily and reliably. And a lead can be omitted and the number of parts can be reduced.

また、蓋体を取り付けるタイミングを任意に設定することができ、例えば、電池缶内に電解液を注入した後で蓋体を取り付けることによって、従来のように、蓋体の位置をずらしたり、所定位置に戻す等の作業を不要とし、組み立てるための工数を減らし、作業を簡単化することができる。また、従来のように正極集電部材と蓋体とがリードでつながれた状態で蓋体を開閉する作業を省略することができ、工数削減により製造コストを低減することができる。   In addition, the timing of attaching the lid can be arbitrarily set. For example, by attaching the lid after injecting the electrolyte into the battery can, the lid can be shifted in position as in the past, Work such as returning to the position is unnecessary, man-hours for assembly can be reduced, and the work can be simplified. Further, it is possible to omit the operation of opening and closing the lid body in a state where the positive electrode current collecting member and the lid body are connected by leads as in the prior art, and the manufacturing cost can be reduced by reducing the number of steps.

本実施の形態における円筒形電池の断面図。Sectional drawing of the cylindrical battery in this Embodiment. 正極集電部材と蓋ケースとの固定方法の一例を示す断面拡大図。The cross-sectional enlarged view which shows an example of the fixing method of a positive electrode current collection member and a cover case. 図2の分解状態を示す断面拡大図。The cross-sectional enlarged view which shows the decomposition | disassembly state of FIG. 正極集電部材と蓋ケースとの固定方法の他の一例を示す断面拡大図。The cross-sectional enlarged view which shows another example of the fixing method of a positive electrode current collection member and a cover case. 図4の分解状態を示す断面拡大図。The cross-sectional enlarged view which shows the decomposition | disassembly state of FIG.

以下、図面を参照して、本発明を円筒形電池に適応した実施の形態について説明する。
円筒形電池1は、本実施の形態では、リチウムイオン二次電池を構成するものであり、図1に示すように、有底円筒状の電池缶11と、電池缶11内に収容される電極群21と、電池缶11の開放端部にかしめ固定されて封口する蓋体31を有している。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments in which the present invention is applied to a cylindrical battery will be described below with reference to the drawings.
In the present embodiment, the cylindrical battery 1 constitutes a lithium ion secondary battery. As shown in FIG. 1, a cylindrical battery can 11 having a bottom and an electrode accommodated in the battery can 11. A group 21 and a lid 31 that is caulked and fixed to the open end of the battery can 11 are sealed.

電池缶11は、ニッケルメッキが施された厚さ0.5mmの炭素鋼によって構成されており、外径40mm、高さ100mmに寸法が設定されている。電池缶11は、電極群21が挿入された後に、開口端部の直下にグルービング加工が施されて凸部12が形成される。凸部12は、蓋体31を載せることができるように径方向中心に向かって突出して周状に連続する形状を有する。   The battery can 11 is made of nickel steel plated 0.5 mm thick carbon steel, and the dimensions are set to an outer diameter of 40 mm and a height of 100 mm. After the electrode group 21 is inserted, the battery can 11 is subjected to a grooving process immediately below the opening end portion to form the convex portion 12. The convex portion 12 has a shape that protrudes toward the center in the radial direction so that the lid body 31 can be placed and is continuous in a circumferential shape.

電池缶11内には、電極群21を収容した後に、電解液が所定量注入される。電解液には、エチレンカーボネート(EC)、ジメチルカーボネート(DMC)、ジエチルカーボネート(DEC)を体積比1:1:1で混合した混合有機溶媒中に、電解質として6フッ化リン酸リチウムを1モル/リットル溶解したものが用いられる。   A predetermined amount of electrolyte is injected into the battery can 11 after the electrode group 21 is accommodated. In the electrolyte solution, 1 mol of lithium hexafluorophosphate as an electrolyte is mixed in a mixed organic solvent in which ethylene carbonate (EC), dimethyl carbonate (DMC), and diethyl carbonate (DEC) are mixed at a volume ratio of 1: 1: 1. / L dissolved material is used.

電極群21は、正極と負極との間にセパレータを介して正極及び負極を軸芯22に捲回して構成された捲回体25と、捲回体25の両端に設けられた正極集電部材40及び負極集電部材50を備えた構成を有している。   The electrode group 21 includes a wound body 25 configured by winding the positive electrode and the negative electrode around the shaft core 22 via a separator between the positive electrode and the negative electrode, and a positive electrode current collecting member provided at both ends of the wound body 25 40 and a negative electrode current collecting member 50.

正極は、リチウムマンガン複合酸化物として代表的なマンガン酸リチウム(LiMn2O4)を正極活物質とし、正極活物質85重量部に対して、導電材として鱗片状黒鉛10重量部と、結着材としてポリフッ化ビニリデン(PVDF)5重量部とを添加し、これに分散媒としてN-メチル-2-ピロリドンを添加、混練したスラリーを厚さ20μmのアルミニウム箔の両面に均一塗布し、乾燥させた後、プレス、裁断して得られたものを用いている。   The positive electrode is composed of lithium manganate (LiMn 2 O 4), which is a typical lithium manganese composite oxide, as a positive electrode active material, with respect to 85 parts by weight of the positive electrode active material, 10 parts by weight of flake graphite as a conductive material, and polyfluoride as a binder. After adding 5 parts by weight of vinylidene chloride (PVDF) and adding N-methyl-2-pyrrolidone as a dispersion medium to this, the kneaded slurry was uniformly applied to both sides of an aluminum foil having a thickness of 20 μm and dried. The one obtained by pressing and cutting is used.

一方、負極は、負極活物質の炭素材として非晶質炭素粉末90重量部に、結着材としてポリフッ化ビニリデン10重量部を添加し、これに分散媒としてN-メチル-2-ピロリドンを添加、混練したスラリーを、厚さ10μmの圧延銅箔の両面に均一塗布し、乾燥させた後、プレス、裁断して得られたものを用いている。
そして、セパレータには、厚さ30μmのポリエチレン製微多孔膜が用いられている。
On the other hand, for the negative electrode, 90 parts by weight of amorphous carbon powder as a carbon material for the negative electrode active material, 10 parts by weight of polyvinylidene fluoride as a binder, and N-methyl-2-pyrrolidone as a dispersion medium are added thereto. The kneaded slurry is uniformly coated on both sides of a rolled copper foil having a thickness of 10 μm, dried, then pressed and cut.
For the separator, a polyethylene microporous film having a thickness of 30 μm is used.

負極は、正極に比べ若干幅長とされており、正極及び負極の幅方向一方側の長辺部には、それぞれ正極タブ23と負極タブ24が形成されている。正極タブ23と負極タブ24は、長辺部に等間隔でかつ矩形状に切り欠かれて形成されており、電極群21から軸方向に向かって互いに離反する方向に突出するように形成されている。正極タブ23は、正極集電部材40に溶接されて電気的に接続され、負極タブ24は、負極集電部材50に溶接されて電気的に接続される。   The negative electrode is slightly wider than the positive electrode, and a positive electrode tab 23 and a negative electrode tab 24 are formed on the long side of one side in the width direction of the positive electrode and the negative electrode, respectively. The positive electrode tab 23 and the negative electrode tab 24 are formed so as to be cut out in a rectangular shape at equal intervals on the long side portion, and formed so as to protrude from the electrode group 21 in a direction away from each other in the axial direction. Yes. The positive electrode tab 23 is welded and electrically connected to the positive electrode current collecting member 40, and the negative electrode tab 24 is welded and electrically connected to the negative electrode current collecting member 50.

正極集電部材40と負極集電部材50は、例えば金属などの導電性材料によって構成されており、捲回体25よりも若干小さな外径を有する略円形の板状部材によって形成されている。正極集電部材40は、軸芯22の正極タブ23側の端部に固定され、負極集電部材50は、軸芯22の負極タブ24側の端部に固定されている。   The positive electrode current collecting member 40 and the negative electrode current collecting member 50 are made of, for example, a conductive material such as metal, and are formed by a substantially circular plate-like member having an outer diameter slightly smaller than that of the wound body 25. The positive electrode current collecting member 40 is fixed to the end of the shaft core 22 on the positive electrode tab 23 side, and the negative electrode current collecting member 50 is fixed to the end of the shaft core 22 on the negative electrode tab 24 side.

正極集電部材40は、円形板状のウェブ部41と、ウェブ部41の径方向中心位置でウェブ部41の軸方向に筒状に突出して軸芯22の端部に挿入されるボス部42と、ウェブ部41の外周端縁で折曲されてボス部42の突出方向とは反対方向に突出する周壁部(穴部)43を有している。   The positive electrode current collecting member 40 includes a circular plate-like web portion 41 and a boss portion 42 that protrudes in a cylindrical shape in the axial direction of the web portion 41 at the radial center position of the web portion 41 and is inserted into the end portion of the shaft core 22. And a peripheral wall portion (hole portion) 43 that is bent at the outer peripheral edge of the web portion 41 and protrudes in a direction opposite to the protruding direction of the boss portion 42.

ウェブ部41には、貫通穴41aが穿設されており、この貫通穴41aを通して電池缶11に電解液を注入できる。また、貫通穴41aは、正極集電部材40に蓋体31の蓋ケース35を取り付ける際に、位置決めピン(図示せず)の先端を挿入して正極集電部材40を位置決め固定するのに用いることができる。ボス部42には、軸芯22の中心穴22aに連通する開口穴42aが穿設されており、溶接工具(図示せず)を挿通して電池缶11の底部13に負極集電部材50の負極リード27を溶接できるようになっている。   The web portion 41 is provided with a through hole 41a, and the electrolyte can be injected into the battery can 11 through the through hole 41a. Further, the through hole 41 a is used for positioning and fixing the positive electrode current collecting member 40 by inserting the tip of a positioning pin (not shown) when attaching the lid case 35 of the lid body 31 to the positive electrode current collecting member 40. be able to. An opening hole 42 a communicating with the center hole 22 a of the shaft core 22 is formed in the boss portion 42, and a welding tool (not shown) is inserted through the bottom portion 13 of the battery can 11 to connect the negative electrode current collecting member 50. The negative electrode lead 27 can be welded.

周壁部43は、短軸円筒形状を有しており、後述する蓋ケース35の周壁部37が挿入された場合に周壁部43の内周面が蓋ケース35の周壁部37の外周面に対向する内径と、電池缶11に電極群21が収容された状態で電池缶11の凸部12よりも開放端部側に突出する軸方向高さを有している。そして、周壁部43の外周面には、電極群21の正極タブ23が溶接されている。   The peripheral wall portion 43 has a short-axis cylindrical shape, and the inner peripheral surface of the peripheral wall portion 43 faces the outer peripheral surface of the peripheral wall portion 37 of the lid case 35 when a peripheral wall portion 37 of the lid case 35 described later is inserted. The inner diameter of the battery can 11 and the height in the axial direction projecting to the open end side of the protrusion 12 of the battery can 11 when the electrode group 21 is accommodated in the battery can 11. The positive electrode tab 23 of the electrode group 21 is welded to the outer peripheral surface of the peripheral wall portion 43.

負極集電部材50は、円形板状のウェブ部51と、ウェブ部51の径方向中心位置で軸方向に筒状に延出して軸芯22の端部に外嵌されるボス穴部52と、ウェブ部51の外周端縁で折曲されてボス穴部52と同方向に突出する周状の脚部53を有している。脚部53は、電池缶11の底部13に当接して電極群21を電池缶11内に支持するためのものであり、脚部53の外周面には負極タブ24が溶接されている。   The negative electrode current collecting member 50 includes a circular plate-like web portion 51, a boss hole portion 52 that extends in a cylindrical shape in the axial direction at the center position in the radial direction of the web portion 51, and is externally fitted to the end portion of the shaft core 22. The peripheral leg 53 is bent at the outer peripheral edge of the web 51 and protrudes in the same direction as the boss hole 52. The leg portion 53 is for contacting the bottom portion 13 of the battery can 11 to support the electrode group 21 in the battery can 11, and the negative electrode tab 24 is welded to the outer peripheral surface of the leg portion 53.

負極集電部材50には、負極リード27が設けられている。負極リード27は、一端が負極集電部材50に電気的に接続されている。負極リード27の他端は、電極群21を電池缶11内に挿入することによって電池缶11の底面13に対向して配置され、抵抗溶接により電池缶11に電気的に接続される。   The negative electrode current collecting member 50 is provided with a negative electrode lead 27. One end of the negative electrode lead 27 is electrically connected to the negative electrode current collecting member 50. The other end of the negative electrode lead 27 is arranged to face the bottom surface 13 of the battery can 11 by inserting the electrode group 21 into the battery can 11 and is electrically connected to the battery can 11 by resistance welding.

蓋体31は、電池缶11の開放端部を閉塞する大きさを有する円形の板状部材からなり、中心位置には電池缶11よりも軸方向に突出する膨出部32が形成されており、その膨出部32の周囲を取り囲むように平板状の周縁部33が形成されている。   The lid 31 is made of a circular plate member having a size that closes the open end of the battery can 11, and a bulging portion 32 that protrudes in the axial direction from the battery can 11 is formed at the center position. A flat peripheral portion 33 is formed so as to surround the bulging portion 32.

蓋体31と正極集電部材40との間には、本発明の特徴的な構成である蓋ケース(接続部材)35が介在されている。   A lid case (connection member) 35 that is a characteristic configuration of the present invention is interposed between the lid body 31 and the positive electrode current collecting member 40.

蓋ケース35は、正極集電部材40と蓋体31との間を電気的に接続するものであり、一端が正極集電部材40に接続され、他端が蓋体31に接続される。蓋ケース35は、正極集電部材40に押接されて正極集電部材40と蓋ケース35との接触面部に面圧をかけた状態で正極集電部材40に固定され、正極集電部材40に電気的に接続される構成を有している。   The lid case 35 electrically connects the positive electrode current collecting member 40 and the lid body 31, one end is connected to the positive electrode current collecting member 40, and the other end is connected to the lid body 31. The lid case 35 is fixed to the positive electrode current collector member 40 while being pressed against the positive electrode current collector member 40 and applying a surface pressure to the contact surface portion between the positive electrode current collector member 40 and the lid case 35. It has the structure electrically connected to.

蓋ケース35は、リング状部材からなり、正極集電部材40の周壁部43の内径側に挿入される周壁部(軸部)37と、周壁部の軸方向一方端部で折曲されて径方向外側に向かって平板状に広がる載置部36と、載置部36の外周端縁で折曲されて軸方向に沿って周壁部37と離反する方向に突出する折曲部38を有している。   The lid case 35 is made of a ring-shaped member, and is bent at a peripheral wall portion (shaft portion) 37 inserted on the inner diameter side of the peripheral wall portion 43 of the positive electrode current collector member 40 and one end portion in the axial direction of the peripheral wall portion. A mounting portion 36 that spreads in the form of a plate toward the outside in the direction, and a bent portion 38 that is bent at the outer peripheral edge of the mounting portion 36 and protrudes in a direction away from the peripheral wall portion 37 along the axial direction. ing.

周壁部37は、短軸の円筒形状を有しており、正極集電部材40の周壁部43の内周面に対向する外径と、電解液の注入流路となる中央開口部を形成する内径を有している。載置部36は、蓋体31の周縁部33を上面に全周に亘って接面した状態で載せることができるように形成されている。折曲部38は、電池缶11の開放端部とともに径方向内側に折り曲げることにより、載置部36との間に蓋体31の周縁部33を挟持して蓋体31をかしめ固定し、蓋ケース35と蓋体31との間を電気的に接続する構成を有する。   The peripheral wall portion 37 has a short-axis cylindrical shape, and forms an outer diameter facing the inner peripheral surface of the peripheral wall portion 43 of the positive electrode current collecting member 40 and a central opening serving as an electrolyte injection channel. It has an inner diameter. The mounting portion 36 is formed so that the peripheral portion 33 of the lid body 31 can be placed on the upper surface in a state of being in contact with the entire periphery. The bent portion 38 is bent inward in the radial direction together with the open end of the battery can 11, so that the peripheral portion 33 of the lid 31 is sandwiched between the mounting portion 36 and the lid 31 is caulked and fixed. The case 35 and the lid 31 are electrically connected.

図2及び図3は、蓋ケース35の具体的な構成の一例を示す断面拡大図であり、図2は、図1のA部拡大図、図3は、図2の分解図である。図2及び図3に示される蓋ケース35Aは、ねじ締結構造によって正極集電部材40にねじ締結される。   2 and 3 are enlarged sectional views showing an example of a specific configuration of the lid case 35, FIG. 2 is an enlarged view of a portion A in FIG. 1, and FIG. 3 is an exploded view of FIG. The lid case 35A shown in FIGS. 2 and 3 is screwed to the positive electrode current collector 40 by a screw fastening structure.

蓋ケース35Aは、正極集電部材40の周壁部43の内周面に形成された雌ネジ部44に、蓋ケース35の周壁部37の外周面に形成された雄ネジ部39を螺入することにより、正極集電部材40に対して軸方向に移動される。   The lid case 35 </ b> A is screwed with the male screw portion 39 formed on the outer peripheral surface of the peripheral wall portion 37 of the lid case 35 into the female screw portion 44 formed on the inner peripheral surface of the peripheral wall portion 43 of the positive electrode current collecting member 40. Accordingly, the positive electrode current collector 40 is moved in the axial direction.

そして、正極集電部材40の周壁部43の頭頂面部(正極集電部材の接触面部)に蓋ケース35Aの載置部36の下面部(接続部材の接触面部)を押接させて、頭頂面部と下面部との間に面圧をかけた状態で正極集電部材40に固定される。   Then, the bottom surface portion (contact surface portion of the connecting member) of the mounting portion 36 of the lid case 35A is pressed against the top surface portion (contact surface portion of the positive electrode current collecting member) of the peripheral wall portion 43 of the positive electrode current collecting member 40, and the top surface portion It fixes to the positive electrode current collection member 40 in the state which applied the surface pressure between the lower surface part.

図4及び図5は、蓋ケース35の具体的な構造の他の一例を示す断面拡大図であり、図4は、図1のA部拡大図、図5は、図4の分解図である。図4及び図5に示される蓋ケース35Bは、正極集電部材40の周壁部43の内径側(穴部内)に蓋ケース35の周壁部(軸部)37を圧入することによって嵌合可能な圧入嵌合構造を有している。   4 and 5 are enlarged sectional views showing another example of the specific structure of the lid case 35, FIG. 4 is an enlarged view of a portion A in FIG. 1, and FIG. 5 is an exploded view of FIG. . 4 and 5 can be fitted by press-fitting the peripheral wall portion (shaft portion) 37 of the cover case 35 into the inner diameter side (inside the hole portion) of the peripheral wall portion 43 of the positive electrode current collecting member 40. It has a press-fit fitting structure.

蓋ケース35の周壁部37の外径は、正極集電部材40の周壁部43の内径よりも僅かに大きい寸法であって、正極集電部材40の周壁部43の内径側に蓋ケース35の周壁部37を圧入した場合に、正極集電部材40の周壁部43と蓋ケース35の周壁部37の少なくとも一方を径方向に弾性変形させて、周壁部43の内周面部に周壁部37の外周面部が所定の面圧をかけた状態で押接される寸法に設定されている。   The outer diameter of the peripheral wall portion 37 of the lid case 35 is slightly larger than the inner diameter of the peripheral wall portion 43 of the positive electrode current collecting member 40. When the peripheral wall portion 37 is press-fitted, at least one of the peripheral wall portion 43 of the positive electrode current collecting member 40 and the peripheral wall portion 37 of the lid case 35 is elastically deformed in the radial direction, and the inner peripheral surface portion of the peripheral wall portion 43 is formed on the inner peripheral surface portion. The outer peripheral surface portion is set to a size that is pressed in a state where a predetermined surface pressure is applied.

そして、正極集電部材40の周壁部43の先端部と蓋ケース35の周壁部37の先端部の少なくとも一方には、正極集電部材40の周壁部43の内径側に蓋ケース35の周壁部37の先端部の挿入を容易にするための面取り加工が施されている。   Further, at least one of the distal end portion of the peripheral wall portion 43 of the positive electrode current collecting member 40 and the distal end portion of the peripheral wall portion 37 of the lid case 35 is disposed on the inner diameter side of the peripheral wall portion 43 of the positive electrode current collecting member 40. A chamfering process for facilitating the insertion of the tip of 37 is performed.

次に、上記構成を有する円筒形電池1の組立方法について説明する。
まず、正極と負極の間にセパレータを介在させて正極と負極を軸芯22に捲回して捲回体25を作成し、捲回体25の両端部に正極集電部材40と負極集電部材50を取り付けて電極群21を形成する。電極群21は、正極集電部材40に正極タブ23が溶接され、負極集電部材50に負極タブ24が溶接され、負極集電部材50に負極リード27が溶接される。そして、電極群21を電池缶11内に収納して、負極リード27と電池缶11を溶接する。これにより、電池缶11と電極群21は一体に固定される。
Next, a method for assembling the cylindrical battery 1 having the above configuration will be described.
First, a separator is interposed between the positive electrode and the negative electrode, and the positive electrode and the negative electrode are wound around the shaft core 22 to form a wound body 25. A positive current collector 40 and a negative current collector are formed at both ends of the wound body 25. 50 is attached to form the electrode group 21. In the electrode group 21, the positive electrode tab 23 is welded to the positive electrode current collecting member 40, the negative electrode tab 24 is welded to the negative electrode current collecting member 50, and the negative electrode lead 27 is welded to the negative electrode current collecting member 50. And the electrode group 21 is accommodated in the battery can 11, and the negative electrode lead 27 and the battery can 11 are welded. Thereby, the battery can 11 and the electrode group 21 are fixed integrally.

それから、電池缶11の開放端部の直下にグルービング加工を施して凸部12を形成し、ガスケット10を挿入する。そして、正極集電部材40に蓋ケース35を押接して、正極集電部材40との接触面部に面圧をかけた状態で固定する。   Then, a grooving process is performed immediately below the open end of the battery can 11 to form a convex portion 12, and the gasket 10 is inserted. Then, the lid case 35 is pressed against the positive electrode current collecting member 40 and fixed in a state where a surface pressure is applied to the contact surface portion with the positive electrode current collecting member 40.

ここで、図2及び図3に示す蓋ケース35Aの場合には、正極集電部材40の雌ネジ部44に蓋ケース35Aの雄ネジ部39を螺入して、正極集電部材40に蓋ケース35をねじ締結する。このねじ締結により、正極集電部材40と蓋ケース35Aは、正極集電部材40の周壁部43の頭頂面部が蓋ケース35の載置部36の下面部に押接されて、頭頂面部と下面部との間に面圧をかけた状態で固定される。この固定により、正極集電部材40と蓋ケース35Aとの間が電気的に接続された状態とされる。   Here, in the case of the lid case 35 </ b> A shown in FIGS. 2 and 3, the male screw portion 39 of the lid case 35 </ b> A is screwed into the female screw portion 44 of the positive electrode current collecting member 40, and the positive electrode current collecting member 40 is covered with the lid. The case 35 is fastened with screws. By this screw fastening, the positive electrode current collecting member 40 and the lid case 35 </ b> A are such that the top surface portion of the peripheral wall portion 43 of the positive electrode current collecting member 40 is pressed against the lower surface portion of the mounting portion 36 of the lid case 35. It is fixed in a state where surface pressure is applied to the part. By this fixing, the positive electrode current collecting member 40 and the lid case 35A are electrically connected.

ねじ締結は、例えば電池缶11の上方からピンなどの治具を挿入して、正極集電部材40を電池缶11に押圧し、正極集電部材40と電池缶11とが相対回転しないように周り止め固定した状態で蓋ケース35を回転させる方法、あるいは、正極集電部材40の貫通穴41aにピンを挿入して正極集電部材40を周り止め固定した状態で蓋ケース35Aを回転させる方法によって行われる。   For example, a jig such as a pin is inserted from above the battery can 11 to press the positive current collecting member 40 against the battery can 11 so that the positive current collecting member 40 and the battery can 11 do not rotate relative to each other. A method of rotating the lid case 35 in a state in which the rotation of the lid case 35 is fixed, or a method of rotating the lid case 35A in a state in which the positive electrode current collection member 40 is fixed in the direction of rotation by inserting a pin into the through hole 41a of the positive electrode current collection member 40. Is done by.

また、図4及び図5に示す蓋ケース35Bの場合には、正極集電部材40の周壁部43の内径側に蓋ケース35Bの周壁部37を圧入して、正極集電部材40に蓋ケース35Bを嵌合する。この圧入嵌合により、正極集電部材40と蓋ケース35Bは、正極集電部材40の周壁部43と蓋ケース35Bの周壁部37の少なくとも一方が径方向に弾性変形して、周壁部43の内周面部に周壁部37の外周面部が押接された状態で固定される。この固定により、正極集電部材40と蓋ケース35Bとの間が電気的に接続された状態とされる。   4 and 5, the peripheral wall portion 37 of the lid case 35B is press-fitted into the inner diameter side of the peripheral wall portion 43 of the positive electrode current collecting member 40 so that the positive electrode current collecting member 40 is covered with the lid case 35B. 35B is fitted. By this press fitting, the positive electrode current collecting member 40 and the lid case 35B are elastically deformed in the radial direction at least one of the peripheral wall portion 43 of the positive electrode current collector member 40 and the peripheral wall portion 37 of the lid case 35B. The outer peripheral surface portion of the peripheral wall portion 37 is fixed in a state of being pressed against the inner peripheral surface portion. By this fixing, the positive electrode current collecting member 40 and the lid case 35B are electrically connected.

なお、圧入時に正極集電部材40に作用する軸方向の力は、正極集電部材40から軸芯22に伝達され、軸芯22から負極集電部材50を介して電池缶11に伝達されて、電池缶11で受け止められる。したがって、正極集電部材40の周壁部43の内径側に蓋ケース35Bの周壁部37を圧入することができる。   The axial force acting on the positive electrode current collecting member 40 during press-fitting is transmitted from the positive electrode current collecting member 40 to the shaft core 22, and is transmitted from the shaft core 22 to the battery can 11 via the negative electrode current collecting member 50. The battery can 11 is received. Therefore, the peripheral wall portion 37 of the lid case 35 </ b> B can be press-fitted into the inner diameter side of the peripheral wall portion 43 of the positive electrode current collecting member 40.

正極集電部材40に蓋ケース35を固定した後、電池缶11内に電解液を注入する。蓋ケース35の中央には、中央開口部が大きく開口しており、従来の正極リブ等の電解液の注入を阻害するものは何も存在しないので、電解液を容易に注入することができる。   After fixing the lid case 35 to the positive electrode current collecting member 40, the electrolytic solution is injected into the battery can 11. At the center of the lid case 35, there is a large central opening, and there is nothing that obstructs injection of the electrolyte such as a conventional positive electrode rib, so that the electrolyte can be easily injected.

電解液の注入後、電池缶11に蓋体31を取り付けて電池缶11の開放端部を封口する。蓋体31を電池缶11の上方から電池缶11の内部に挿入して、蓋体31の外周縁部33を蓋ケース35の載置部36の上に載せる。そして、電池缶11の開放端部、ガスケット10、蓋ケース35の折曲部38を径方向内側に一体に折り曲げることにより、蓋体31を電池缶11にかしめ固定する。このかしめ固定により、載置部36と折曲部38との間に蓋体31の外周縁部33が挟持され、蓋ケース35と蓋体31との間が電気的に接続され、かつ、蓋体31によって電池缶11の開放端部が封口される。   After injecting the electrolyte, the lid 31 is attached to the battery can 11 and the open end of the battery can 11 is sealed. The lid 31 is inserted into the battery can 11 from above the battery can 11, and the outer peripheral edge 33 of the lid 31 is placed on the mounting portion 36 of the lid case 35. Then, the lid 31 is caulked and fixed to the battery can 11 by integrally bending the open end of the battery can 11, the gasket 10, and the bent portion 38 of the lid case 35 radially inward. By this caulking and fixing, the outer peripheral edge portion 33 of the lid body 31 is sandwiched between the placing portion 36 and the bent portion 38, the lid case 35 and the lid body 31 are electrically connected, and the lid The open end of the battery can 11 is sealed by the body 31.

上述のように、本発明の円筒形電池1は、蓋ケース35を正極集電部材40にねじ締結、あるいは圧入嵌合して固定し(ステップS101)、電池缶11に電解液を注入し(ステップS102)、蓋体31を電池缶11にかしめ固定する(ステップS103)ことによって組み立てられる。   As described above, in the cylindrical battery 1 of the present invention, the lid case 35 is fixed to the positive electrode current collecting member 40 by screw fastening or press fitting (step S101), and the electrolytic solution is injected into the battery can 11 ( In step S102), the lid 31 is assembled by being caulked and fixed to the battery can 11 (step S103).

一方、従来の円筒形電池は、正極リードの一端を正極集電部材に溶接し(ステップS111)、正極リードの他端を蓋ケースに溶接し(ステップS112)、電解液の注入流路を確保するために蓋ケースの位置をずらした状態で電池缶11に電解液を注入し(ステップS113)、蓋ケースを正規の位置に戻して(ステップS114)、蓋ケースに蓋体をセットしてかしめ固定する(ステップS115)ことによって組み立てられる。   On the other hand, in the conventional cylindrical battery, one end of the positive electrode lead is welded to the positive electrode current collecting member (step S111), and the other end of the positive electrode lead is welded to the lid case (step S112), thereby securing an electrolyte injection channel. In order to do so, the electrolyte is injected into the battery can 11 with the position of the lid case shifted (step S113), the lid case is returned to the normal position (step S114), and the lid body is set in the lid case and caulked. It is assembled by fixing (step S115).

したがって、正極集電部材40と蓋体31との間の電気的な導通を確保するために、従来の円筒形電池では、正極リードの一端を正極集電部材に溶接するステップS111の工程と、正極リードの他端を蓋体に溶接するステップS112の工程の2つの工程が必要であるのに対し、本実施の形態の円筒形電池1では、蓋ケース35を正極集電部材40にねじ締結、あるいは圧入嵌合するステップS101の一つの工程でよく、従来よりも組立工数を少なくすることができ、組立作業の効率化を図ることができる。   Therefore, in order to ensure electrical continuity between the positive electrode current collecting member 40 and the lid 31, in the conventional cylindrical battery, the step of step S111 for welding one end of the positive electrode lead to the positive electrode current collecting member; In the cylindrical battery 1 according to the present embodiment, the lid case 35 is screwed to the positive electrode current collecting member 40, whereas the two steps of the step S112 of welding the other end of the positive electrode lead to the lid are necessary. Alternatively, one step of step S101 for press-fitting and fitting may be performed, the number of assembling steps can be reduced as compared with the conventional case, and the efficiency of the assembling work can be improved.

また、従来の円筒形電池において、電解液を注入する流路を確保するために蓋ケースの位置をずらしている場合には、電解液を注入した後に、蓋ケースを正規の位置に戻すステップS114の工程が必要であるのに対し、本実施の形態の円筒形電池1では、蓋ケース35を正規の位置に取り付けた状態で、蓋ケース35の中央開口部から電解液を注入することができるので、従来の蓋ケースを正規の位置に戻すステップS114の工程が不要であり、組立工数を少なくすることができ、組立作業の効率化を図ることができる。   Further, in the conventional cylindrical battery, when the position of the lid case is shifted in order to secure a flow path for injecting the electrolytic solution, after the electrolytic solution is injected, the lid case is returned to the normal position S114. On the other hand, in the cylindrical battery 1 of the present embodiment, the electrolytic solution can be injected from the central opening of the lid case 35 with the lid case 35 attached to a normal position. Therefore, the process of step S114 for returning the conventional lid case to the normal position is unnecessary, the number of assembling steps can be reduced, and the efficiency of the assembling work can be improved.

また、従来の円筒形電池では、正極集電部材と蓋ケースとの間を電気的に接続する正極リードが必要であったが、本実施の形態における円筒形電池1では、正極リードが不要であるので、部品点数を削減することができる。   Further, in the conventional cylindrical battery, the positive electrode lead that electrically connects the positive electrode current collecting member and the lid case is necessary. However, in the cylindrical battery 1 according to the present embodiment, the positive electrode lead is unnecessary. Therefore, the number of parts can be reduced.

また、本実施の形態における円筒形電池によれば、上蓋組立品を予め作っておく必要がなく、電池缶11の開放端部、ガスケット10、蓋ケース35の折曲部38を径方向内側に一体に折り曲げることによって、蓋体31を電池缶11にかしめ固定できるので、短い時間で製造することができる。   Further, according to the cylindrical battery in the present embodiment, it is not necessary to prepare an upper lid assembly in advance, and the open end portion of the battery can 11, the gasket 10, and the bent portion 38 of the lid case 35 are radially inward. Since the lid body 31 can be caulked and fixed to the battery can 11 by being bent together, it can be manufactured in a short time.

上記した本実施の形態における円筒形電池1によれば、蓋ケース35は、正極集電部材40に押接されて正極集電部材40と蓋ケース35との接触面部に面圧をかけた状態で正極集電部材40に固定され、正極集電部材40に電気的に接続されるので、正極集電部材40と蓋体31との間の電気的な導通を面圧によって確保することができ、正極集電部材40と蓋体31との接触面部の通電抵抗を低減できる。   According to the cylindrical battery 1 in the present embodiment described above, the lid case 35 is pressed against the positive electrode current collecting member 40 to apply a surface pressure to the contact surface portion between the positive electrode current collecting member 40 and the lid case 35. Is fixed to the positive electrode current collector member 40 and is electrically connected to the positive electrode current collector member 40, so that electrical continuity between the positive electrode current collector member 40 and the lid 31 can be ensured by the surface pressure. In addition, the energization resistance of the contact surface portion between the positive electrode current collecting member 40 and the lid 31 can be reduced.

また、円筒形電池1によれば、蓋ケース35を正極集電部材40に取り付けるタイミングを任意に設定することができ、例えば、電池缶11内に電解液を注入した後で蓋ケース35を取り付けることができる。   Moreover, according to the cylindrical battery 1, the timing which attaches the cover case 35 to the positive electrode current collection member 40 can be set arbitrarily, for example, after attaching electrolyte solution in the battery can 11, the cover case 35 is attached. be able to.

本発明は、上述の実施の形態に限定されるものではなく、本発明の趣旨を逸脱しない範囲で種々の変更が可能である。例えば、本実施の形態では、図2及び図3に示すように、蓋ケース35に雄ネジ部39を設け、正極集電部材40に雌ネジ部44を設けた場合を例に説明したが、正極集電部材40に雄ネジ部を設けて、蓋ケース35に雌ネジ部を設けた構成としてもよい。   The present invention is not limited to the above-described embodiment, and various modifications can be made without departing from the spirit of the present invention. For example, in the present embodiment, as shown in FIGS. 2 and 3, the case where the male screw part 39 is provided in the lid case 35 and the female screw part 44 is provided in the positive electrode current collecting member 40 has been described as an example. The positive electrode current collecting member 40 may be provided with a male screw portion, and the lid case 35 may be provided with a female screw portion.

また、図4及び図5に示すように、正極集電部材35の周壁部の内径側に蓋ケース35の周壁部37を圧入する構成の場合を例に説明したが、正極集電部材40の周壁部の外径側に蓋ケース35の周壁部37が圧入されて外嵌される構成としてもよい。   4 and 5, the case where the peripheral wall portion 37 of the lid case 35 is press-fitted into the inner diameter side of the peripheral wall portion of the positive electrode current collecting member 35 has been described as an example. It is good also as a structure by which the surrounding wall part 37 of the cover case 35 is press-fitted on the outer-diameter side of a surrounding wall part, and is externally fitted.

10 ガスケット
11 電池缶
21 電極群
31 蓋体
35 蓋ケース(接続部材)
37 周壁部(軸部)
39 雄ネジ部
40 正極集電部材
43 周壁部(穴部)
44 雌ネジ部
50 負極集電部材
10 Gasket 11 Battery Can 21 Electrode Group 31 Lid 35 Lid Case (Connecting Member)
37 Peripheral wall (shaft)
39 Male thread portion 40 Positive electrode current collecting member 43 Peripheral wall portion (hole portion)
44 Female thread portion 50 Negative electrode current collecting member

Claims (4)

正極集電部材と負極集電部材を有する電極群と、該電極群が収容される有底円筒状の電池缶と、該電池缶の開放端部を封口する蓋体を有する円筒形電池であって、
前記正極集電部材と前記蓋体との間に介在されて前記正極集電部材と前記蓋体との間を電気的に接続する接続部材を備え、
該接続部材は、前記正極集電部材に押接されて該正極集電部材と前記接続部材との接触面部に面圧をかけた状態で前記正極集電部材に固定され、前記正極集電部材に電気的に接続されることを特徴とする円筒形電池。
A cylindrical battery having an electrode group having a positive electrode current collecting member and a negative electrode current collecting member, a bottomed cylindrical battery can in which the electrode group is accommodated, and a lid for sealing the open end of the battery can. And
A connecting member interposed between the positive current collector and the lid and electrically connecting the positive current collector and the lid;
The connecting member is fixed to the positive current collecting member while being pressed against the positive current collecting member and applying a surface pressure to a contact surface portion between the positive current collecting member and the connecting member; A cylindrical battery characterized by being electrically connected to the battery.
前記正極集電部材と前記接続部材のいずれか一方に設けられた雌ネジ部に、前記正極集電部材と前記接続部材のいずれか他方に設けられた雄ネジ部を螺入することによって、前記接続部材を前記正極集電部材に対して軸方向に移動させて、前記正極集電部材の接触面部に前記接続部材の接触面部を押接した状態でねじ締結するねじ締結構造を有していることを特徴とする請求項1に記載の円筒形電池。   By screwing the male screw portion provided on either the positive electrode current collector member or the connection member into the female screw portion provided on either the positive electrode current collector member or the connection member, the It has a screw fastening structure in which the connecting member is moved in the axial direction with respect to the positive electrode current collecting member, and the screw is fastened with the contact surface portion of the connecting member being pressed against the contact surface portion of the positive electrode current collecting member. The cylindrical battery according to claim 1. 前記正極集電部材と前記接続部材のいずれか一方に設けられた穴部に、前記正極集電部材と前記接続部材のいずれか他方に設けられた軸部を圧入することによって、前記穴部の内周面部に前記軸部の外周面部を押接した状態で嵌合させる圧入嵌合構造を有していることを特徴とする請求項1に記載の円筒形電池。   By press-fitting a shaft portion provided on either the positive electrode current collector member or the connection member into a hole portion provided on either the positive electrode current collector member or the connection member, the hole portion 2. The cylindrical battery according to claim 1, wherein the cylindrical battery has a press-fitting fitting structure in which the outer peripheral surface portion of the shaft portion is fitted to the inner peripheral surface portion while being pressed. 前記接続部材は、かしめ固定によって前記蓋体に電気的に接続されることを特徴とする請求項1から請求項3のいずれか一項に記載の円筒形電池。   4. The cylindrical battery according to claim 1, wherein the connection member is electrically connected to the lid body by caulking. 5.
JP2010175752A 2010-08-04 2010-08-04 Cylindrical battery Withdrawn JP2012038477A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20170006809A (en) * 2015-07-09 2017-01-18 주식회사 엘지화학 Secondary battery
KR101776115B1 (en) 2017-03-22 2017-09-07 주식회사 비츠로셀 Energy storage device improving power property
CN114725628A (en) * 2022-04-21 2022-07-08 远景动力技术(江苏)有限公司 Battery assembly and battery manufacturing method
CN114725628B (en) * 2022-04-21 2024-05-10 远景动力技术(江苏)有限公司 Battery assembly and battery manufacturing method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20170006809A (en) * 2015-07-09 2017-01-18 주식회사 엘지화학 Secondary battery
KR101984883B1 (en) 2015-07-09 2019-05-31 주식회사 엘지화학 Secondary battery
KR101776115B1 (en) 2017-03-22 2017-09-07 주식회사 비츠로셀 Energy storage device improving power property
CN114725628A (en) * 2022-04-21 2022-07-08 远景动力技术(江苏)有限公司 Battery assembly and battery manufacturing method
CN114725628B (en) * 2022-04-21 2024-05-10 远景动力技术(江苏)有限公司 Battery assembly and battery manufacturing method

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