JP2012037325A - Method for testing unvulcanized carcass ply - Google Patents

Method for testing unvulcanized carcass ply Download PDF

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JP2012037325A
JP2012037325A JP2010176367A JP2010176367A JP2012037325A JP 2012037325 A JP2012037325 A JP 2012037325A JP 2010176367 A JP2010176367 A JP 2010176367A JP 2010176367 A JP2010176367 A JP 2010176367A JP 2012037325 A JP2012037325 A JP 2012037325A
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carcass ply
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unvulcanized
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ply
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JP5480749B2 (en
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Midori Tanaka
翠 田中
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Bridgestone Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a method for testing unvulcanized carcass ply by which drawing drag of a ply cord and positional relation between the cord and rubber or the like are evaluated by the unvulcanized carcass ply.SOLUTION: When the drawing drag of the ply cord 4 is tested by a sample of the unvulcanized carcass ply consisting of a rubber drawing layer including a plurality of ply cords 4 in parallel by drawing, a sample 2 of the unvulcanized carcass ply is expanded at arbitrary expansion rate in the direction perpendicular to the extension direction of the cord 4 and after that, a hard member 6 is adhered to at least one surface of the sample 2.

Description

本発明は、未加硫カーカスプライの試験方法に関するものである。   The present invention relates to a method for testing an unvulcanized carcass ply.

製品タイヤの骨格構造を構成するカーカスは、通常、複数本のプライコードを並行に引き揃え、そのコードをゴムで被覆したゴム引き層からなるカーカスプライの一枚以上で形成されている。
このようなタイヤを製造するための、生タイヤの成形に当っては、未加硫カーカスプライはシェーピング工程等で拡張変形されるため、その中に埋設配置されたプライコードと、未加硫ゴムとの間に隙間が生じ、プライコードの引き抜き抗力が低下するおそれがあった。
The carcass constituting the skeleton structure of the product tire is usually formed of one or more carcass plies made of a rubberized layer in which a plurality of ply cords are arranged in parallel and the cords are covered with rubber.
In forming a raw tire for manufacturing such a tire, an unvulcanized carcass ply is expanded and deformed in a shaping process or the like, and therefore, a ply cord embedded in the tire and an unvulcanized rubber There was a possibility that a clearance was generated between the ply cord and the pulling resistance of the ply cord was lowered.

これがため、未加硫カーカスプライのプライコードの引き抜き力を測定するために、未加硫カーカスプライのサンプルを、上記の拡張変形と相関をもたせて拡張変形させた状態での、プライコードの引き抜き力(引抜き抗力)を測定することが行われていた。   For this reason, in order to measure the pulling force of the uncured carcass ply ply cord, the uncured carcass ply sample is pulled out in a state of being expanded and deformed in correlation with the above-mentioned expanded deformation. Measuring force (pull-out drag) has been done.

しかるに、このような引き抜き測定方法では、引張り試験機により、未加硫カーカスプライを、コードの延在方向と直行する方向に所要の拡張率に拡張変形させた状態を維持しつつプライコードを引き抜く必要があるため、カーカスプライを拡張させる装置と、コードを引き抜くための装置との二台の装置が必要であったり、そのための専用装置の開発が必要となり、装置の複雑化や試験コストの増加率が不可避であった。   However, in such a pull-out measurement method, the ply cord is pulled out while maintaining a state in which the uncured carcass ply is expanded and deformed to a required expansion rate in a direction perpendicular to the extending direction of the cord by a tensile tester. Therefore, it is necessary to have two devices, one for expanding the carcass ply and the other for pulling out the cord, and it is necessary to develop a dedicated device for that purpose. The rate was inevitable.

この一方で、未加硫カーカスプライのサンプルを拡張変形することなく、そのままの未拡張サンプル状態で引抜き抗力を測定する場合には、拡張サンプルのプライコードの引き抜き抗力を測定した場合と比較して、測定結果が大きく異なることになるため、現実に即したカーカスプライの測定方法ではなかった。   On the other hand, when the pulling resistance is measured in the unexpanded sample state without expanding the uncured carcass ply sample as compared with the case where the pulling resistance of the ply cord of the expanded sample is measured. Since the measurement results differ greatly, it was not an actual carcass ply measurement method.

その上、従来は、未加硫カーカスプライを拡張変形させた場合の、プライコードと未加硫ゴムとの間の隙間や位置関係を正確に評価する手法がなかった。   In addition, conventionally, there has been no method for accurately evaluating the gap and positional relationship between the ply cord and the unvulcanized rubber when the unvulcanized carcass ply is expanded and deformed.

本発明の目的は、未加硫カーカスプライでプライコードの引抜き抗力や、コードとゴムの位置関係等を評価できる未加硫カーカスプライの試験方法を提供することにある。   An object of the present invention is to provide an unvulcanized carcass ply test method capable of evaluating the pulling resistance of a ply cord, the positional relationship between the cord and rubber, and the like with the unvulcanized carcass ply.

本発明の一の実施形態は、複数本のプライコードを並行に引き揃えたゴム引き層からなる未加硫カーカスプライのサンプルでプライコードの引き抜き抗力を試験するに当たり、前記未加硫カーカスプライのサンプルをコードの延在方向と直行する方向に任意の拡張率で拡張させた後、前記サンプルの少なくとも一面に硬質部材を接着させるものである。   In one embodiment of the present invention, when testing the unbonded carcass ply with a sample of unvulcanized carcass ply composed of a rubberized layer in which a plurality of ply cords are aligned in parallel, After the sample is expanded at an arbitrary expansion rate in a direction perpendicular to the extending direction of the cord, a hard member is bonded to at least one surface of the sample.

ここで、「任意の拡張率」とは、カレンダーで処理後のコード間の間隔を基準にしたとき、その間隔を基準対比100〜400%の範囲で拡張させた割合をいうものとする。   Here, the “arbitrary expansion rate” refers to a ratio in which the interval is expanded in the range of 100 to 400% compared to the reference when the interval between codes processed by the calendar is used as a reference.

このような試験方法においてより好ましくは、前記硬質部材を未加硫カーカスプライのサンプルの両面に接着させる。   More preferably, in such a test method, the hard member is bonded to both sides of the sample of the unvulcanized carcass ply.

本発明の一の実施形態は、複数本のプライコードを並行に引き揃えたゴム引き層からなる未加硫カーカスプライのサンプルで、プライコードと未加硫ゴムとの隙間を試験するに当たり、前記未加硫カーカスプライのサンプルをコードの延在方向と直行する方向に任意の拡張率で拡張させた後、ゴムとコードの間に形成される隙間を硬化材料で埋め込み、事後的に未加硫ゴムを剥ぎ取って、前記コードと硬化材料を取り出すものである。   One embodiment of the present invention is a sample of an unvulcanized carcass ply composed of a rubberized layer in which a plurality of ply cords are aligned in parallel, and the gap between the ply cord and the unvulcanized rubber is tested. After the uncured carcass ply sample is expanded at an arbitrary expansion rate in the direction perpendicular to the direction in which the cord extends, the gap formed between the rubber and the cord is filled with a hardened material, and the unvulcanized afterwards The rubber and the cured material are taken out by peeling off the rubber.

本発明の一の実施形態では、未加硫カーカスプライのサンプルをプライコードの延在方向と直交する方向に所要の拡張率まで拡張させた後、そのサンプルの少なくとも一面に硬質材を接着させることで、拡張させた未加硫カーカスプライのサンプルを引張り試験機から外した後であっても、所要の拡張状態を維持することができるので、未加硫カーカスプライサンプルを拡張させた状態で、一の引抜き装置をもって引抜き抗力を、簡易にかつ低コストで測定することができる。   In one embodiment of the present invention, an unvulcanized carcass ply sample is expanded to a required expansion rate in a direction orthogonal to the direction in which the ply cord extends, and then a hard material is bonded to at least one surface of the sample. Even after the expanded unvulcanized carcass ply sample is removed from the tensile tester, the required expanded state can be maintained, so that the unvulcanized carcass ply sample is expanded, With one pulling device, the pulling resistance can be measured easily and at low cost.

本発明の他の実施形態では、未加硫カーカスプライのサンプルをコードの延在方向と直行する方向に任意の拡張率で拡張させた後、ゴムとコードの間に形成される隙間を硬化材料や石膏などの硬化材料で埋め込み、事後的に未加硫ゴムを剥ぎ取って前記コードと硬化材料を取り出すことで、未加硫カーカスプライの拡張状態で未加硫ゴムとコードの間に形成される隙間を形状化して、その断面形状等を直接観察して評価することができる。   In another embodiment of the present invention, after a sample of an unvulcanized carcass ply is expanded at an arbitrary expansion rate in a direction orthogonal to the extending direction of the cord, the gap formed between the rubber and the cord is cured. It is formed between the unvulcanized rubber and the cord in the expanded state of the unvulcanized carcass ply by embedding with a cured material such as gypsum and plaster and then stripping off the unvulcanized rubber and taking out the cord and the cured material. The gap can be shaped, and its cross-sectional shape can be directly observed and evaluated.

また本発明では、拡張時の引抜き抗力、空隙率やコードヘのゴム付き量等を開発評価項目として使用することができ、量産後の兆候管理において、製品タイヤでのカーカスプライが空隙部の中でコードが遊ぶこと等に由来するプライウェーブ、シェーピング工程等でコードがセンター側へ引き抜けること等に由来して、カーカスプライの折り返し高さが規定の高さに位置しない状態または、ビードコア直下に所定のゴム厚みにならない状態等の製品不良を未然に防止できる。   In addition, in the present invention, the pulling resistance at the time of expansion, the void ratio, the amount of rubber attached to the cord, etc. can be used as development evaluation items, and the carcass ply in the product tire is in the gap in the sign management after mass production. The ply wave derived from playing the cord, etc., the cord is pulled out to the center side in the shaping process, etc., or the carcass ply folded height is not located at the specified height, or a predetermined amount just below the bead core It is possible to prevent product defects such as the rubber thickness not being reached.

本発明の一の実施形態に係る未加硫カーカスプライの試験方法で使用する未加硫カーカスプライのサンプルを拡張装置で拡張した状態を示す斜視図である。It is a perspective view which shows the state which expanded the sample of the unvulcanized carcass ply used with the test method of the unvulcanized carcass ply which concerns on one Embodiment of this invention with the expansion apparatus. 本発明の一の実施形態に係る未加硫カーカスプライの試験方法で使用する未加硫カーカスプライにサンプルを接着させた硬質部材とともに示す斜視図である。It is a perspective view shown with the hard member which made the sample adhere | attach the unvulcanized carcass ply used with the test method of the unvulcanized carcass ply which concerns on one Embodiment of this invention. 本発明の他の実施形態に係る未加硫カーカスプライの試験方法で使用する未加硫カーカスプライを引っ張った後、樹脂部材を埋め込んだ状態を示す拡大側面図である。It is an enlarged side view which shows the state which embedded the resin member, after pulling the unvulcanized carcass ply used with the test method of the unvulcanized carcass ply which concerns on other embodiment of this invention. 図3に示す未加硫カーカスプライのゴムを剥ぎ取った状態を示す斜視図である。It is a perspective view which shows the state which peeled off the rubber | gum of the unvulcanized carcass ply shown in FIG.

以下に、図面を参照しながら本発明の未加硫カーカスプライのサンプルの試験方法を詳細に説明する。
図中1は未加硫カーカスプライのサンプルを拡張する拡張装置の全体を示し、この拡張装置1には、未加硫カーカスプライサンプル2を挟持する挟持手段3を図では上下に具える。
ここで、未加硫カーカスプライサンプル2は複数本のプライコード4を並行に引き揃えた未加硫ゴム5のゴム引き層からなる。
Hereinafter, a method for testing a sample of an unvulcanized carcass ply of the present invention will be described in detail with reference to the drawings.
In the figure, reference numeral 1 denotes an entire expansion device for expanding a sample of an unvulcanized carcass ply. The expansion device 1 is provided with clamping means 3 for clamping an unvulcanized carcass ply sample 2 in the vertical direction in the figure.
Here, the unvulcanized carcass ply sample 2 is composed of a rubberized layer of unvulcanized rubber 5 in which a plurality of ply cords 4 are aligned in parallel.

この拡張装置1では、図では上下の挟持手段3により、未加硫カーカスプライサンプル2をコード4の延在方向と直行する方向に拡張できるような向きで未加硫カーカスプライサンプル2の両面の端部を挟持する。   In this expansion device 1, the unvulcanized carcass ply sample 2 is extended on both sides of the unvulcanized carcass ply sample 2 in such a direction that the unvulcanized carcass ply sample 2 can be expanded in a direction perpendicular to the extending direction of the cord 4 by the upper and lower clamping means 3. Hold the end.

そして挟持手段3を上下方向に移動して、未加硫カーカスプライサンプル2を任意の拡張率、好ましくは生タイヤでのプライの拡張率と同等の100〜200%の範囲で拡張させる。次いで、その状態を維持したまま未加硫カーカスプライサンプル2の少なくとも一面、図では両面に硬質部材6を、例えば接着剤や糊を用いて接着して固定する。   And the clamping means 3 is moved to the up-down direction, and the unvulcanized carcass ply sample 2 is expanded in an arbitrary expansion rate, preferably in the range of 100 to 200% equivalent to the expansion rate of the ply in the raw tire. Next, the hard member 6 is bonded and fixed to at least one surface of the unvulcanized carcass ply sample 2 in the figure, while maintaining that state, for example, using an adhesive or glue.

本発明では、拡張状態で硬質部材6を接着することで、図2に未加硫カーカスプライの斜視図で示すように、拡張装置1から未加硫カーカスプライサンプル2を取り除いた後であっても、未加硫カーカスプライサンプル2は拡張した状態を維持することができる。そのサンプルにより、シェーピング工程等の拡張変形と相関をもたせて拡張変形させた状態での、プライコードの引抜き抗力を測定することができる。   In the present invention, after the uncured carcass ply sample 2 is removed from the expansion device 1, as shown in the perspective view of the unvulcanized carcass ply in FIG. However, the unvulcanized carcass ply sample 2 can maintain the expanded state. With the sample, it is possible to measure the pulling drag force of the ply cord in a state in which it is expanded and deformed in correlation with expansion deformation such as a shaping process.

ここで、硬質部材6の材質や形状は特に限定されることはないが、未加硫カーカスプライサンプル2を拡張して拡張装置1から取り除いた後に拡張状態を維持でき、未加硫カーカスプライサンプル2のゴム収縮力以上に耐えうる剛性を持った板であればよく、具体的には所定の形状の木板、鉄板、プラスチック板等をあげることができる。   Here, the material and shape of the hard member 6 are not particularly limited, but the expanded state can be maintained after the unvulcanized carcass ply sample 2 is expanded and removed from the expansion device 1, and the unvulcanized carcass ply sample can be maintained. It is sufficient if it is a plate having rigidity that can withstand the rubber shrinkage force of 2 or more, and specifically, a wooden plate, an iron plate, a plastic plate or the like having a predetermined shape can be mentioned.

このような未加硫カーカスプライの試験方法においてより好ましくは、硬質部材6を未加硫カーカスプライサンプル2の両面に接着させることで、拡張状態をより確実に長期間にわたって保つことができる。   In such an unvulcanized carcass ply test method, more preferably, the expanded state can be more reliably maintained over a long period of time by bonding the hard member 6 to both surfaces of the unvulcanized carcass ply sample 2.

図3は本発明の他の実施形態に係る未加硫カーカスプライの試験方法で使用する未加硫カーカスプライを引っ張った後、硬化材料を埋め込んだ状態を示す拡大側面図である。
未加硫カーカスプライサンプル2を拡張させて、好ましくは硬質部材6で固定した後に、未加硫カーカスプライサンプル2の未加硫ゴム5とコード4の間に形成される隙間に硬化材料7、例えば液体樹脂を流し込み、一定時間乾燥して、隙間を固定させることが好ましい。
FIG. 3 is an enlarged side view showing a state in which a cured material is embedded after pulling an unvulcanized carcass ply used in a test method for an unvulcanized carcass ply according to another embodiment of the present invention.
After the unvulcanized carcass ply sample 2 is expanded and preferably fixed by the hard member 6, the cured material 7 is placed in the gap formed between the unvulcanized rubber 5 and the cord 4 of the unvulcanized carcass ply sample 2. For example, it is preferable to pour liquid resin and dry for a certain period of time to fix the gap.

このように隙間を固定化することで、未加硫カーカスプライサンプル2の未加硫ゴム5を剥ぎ取り、図4に斜視図で示すような、硬化材料7とコード4を取り出すことで、未加硫カーカスプライサンプル2の拡張変形で未加硫ゴム5とコード4の間に形成される隙間を形状化して、その断面形状等を観察して評価することができる。   By fixing the gap in this manner, the unvulcanized rubber 5 of the unvulcanized carcass ply sample 2 is peeled off, and the cured material 7 and the cord 4 as shown in the perspective view of FIG. A gap formed between the unvulcanized rubber 5 and the cord 4 can be formed by expansion deformation of the vulcanized carcass ply sample 2, and its cross-sectional shape and the like can be observed and evaluated.

硬化材料7は特に限定されることはないが、エポキシ樹脂、アクリル樹脂、ウレタン樹脂、ポリエステル樹脂、フェノール樹脂、石膏等をあげることができる。   Although the hardening material 7 is not specifically limited, An epoxy resin, an acrylic resin, a urethane resin, a polyester resin, a phenol resin, gypsum etc. can be mention | raise | lifted.

1 拡張装置
2 未加硫カーカスプライサンプル
3 挟持手段
4 プライコード
5 未加硫ゴム
6 硬質部材
7 硬化材料
DESCRIPTION OF SYMBOLS 1 Expansion apparatus 2 Unvulcanized carcass ply sample 3 Clamping means 4 Ply cord 5 Unvulcanized rubber 6 Hard member 7 Curing material

Claims (3)

複数本のプライコードを並行に引き揃えたゴム引き層からなる未加硫カーカスプライのサンプルでプライコードの引き抜き抗力を試験するに当たり、
前記未加硫カーカスプライのサンプルをコードの延在方向と直行する方向に任意の拡張率で拡張させた後、前記サンプルの少なくとも一面に硬質部材を接着させる未加硫カーカスプライの試験方法。
In testing the pulling resistance of the ply cord with a sample of an unvulcanized carcass ply consisting of a rubberized layer in which a plurality of ply cords are aligned in parallel,
A method for testing an unvulcanized carcass ply, in which a sample of the unvulcanized carcass ply is expanded at an arbitrary expansion rate in a direction orthogonal to the extending direction of the cord, and then a hard member is bonded to at least one surface of the sample.
前記硬質部材を未加硫カーカスプライのサンプルの両面に接着させる請求項1に記載の未加硫カーカスプライの試験方法。   The method for testing an unvulcanized carcass ply according to claim 1, wherein the hard member is adhered to both surfaces of a sample of the unvulcanized carcass ply. 複数本のプライコードを並行に引き揃えたゴム引き層からなる未加硫カーカスプライのサンプルで、プライコードと未加硫ゴムとの隙間を試験するに当たり、
前記未加硫カーカスプライのサンプルをコードの延在方向と直行する方向に任意の拡張率で拡張させた後、ゴムとコードの間に形成される隙間を硬化材料で埋め込み、事後的に未加硫ゴムを剥ぎ取って、前記コードと硬化材料を取り出す未加硫カーカスプライの試験方法。
When testing the gap between the ply cord and the unvulcanized rubber with a sample of an unvulcanized carcass ply consisting of a rubberized layer in which a plurality of ply cords are aligned in parallel,
The unvulcanized carcass ply sample is expanded at an arbitrary expansion rate in a direction perpendicular to the extending direction of the cord, and then a gap formed between the rubber and the cord is filled with a hardening material, and the unvulcanized material is added afterwards. A method for testing an unvulcanized carcass ply by peeling off the vulcanized rubber and taking out the cord and the cured material.
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CN105004618A (en) * 2015-07-03 2015-10-28 杭州朝阳橡胶有限公司 Rubber composite material fatigue analysis testing method
CN114088618A (en) * 2021-11-22 2022-02-25 三角轮胎股份有限公司 Method for detecting calendering and rubber coating quality of unvulcanized rubber-coated cord fabric

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CN105004618A (en) * 2015-07-03 2015-10-28 杭州朝阳橡胶有限公司 Rubber composite material fatigue analysis testing method
CN105004618B (en) * 2015-07-03 2018-04-24 杭州朝阳橡胶有限公司 A kind of rubber composite material analysis of fatigue test method
CN114088618A (en) * 2021-11-22 2022-02-25 三角轮胎股份有限公司 Method for detecting calendering and rubber coating quality of unvulcanized rubber-coated cord fabric
CN114088618B (en) * 2021-11-22 2024-01-30 三角轮胎股份有限公司 Method for detecting calendaring and coating quality of unvulcanized coated cord fabric

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