JP2011235546A - Apparatus and method for manufacturing film or sheet - Google Patents

Apparatus and method for manufacturing film or sheet Download PDF

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JP2011235546A
JP2011235546A JP2010109341A JP2010109341A JP2011235546A JP 2011235546 A JP2011235546 A JP 2011235546A JP 2010109341 A JP2010109341 A JP 2010109341A JP 2010109341 A JP2010109341 A JP 2010109341A JP 2011235546 A JP2011235546 A JP 2011235546A
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molten resin
die
axis direction
flow path
resin
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Kensuke Onishi
健介 大西
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Sumitomo Chemical Co Ltd
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Sumitomo Chemical Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/695Flow dividers, e.g. breaker plates
    • B29C48/70Flow dividers, e.g. breaker plates comprising means for dividing, distributing and recombining melt flows
    • B29C48/705Flow dividers, e.g. breaker plates comprising means for dividing, distributing and recombining melt flows in the die zone, e.g. to create flow homogeneity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/362Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using static mixing devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/695Flow dividers, e.g. breaker plates
    • B29C48/70Flow dividers, e.g. breaker plates comprising means for dividing, distributing and recombining melt flows
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/27Cleaning; Purging; Avoiding contamination
    • B29C48/272Cleaning; Purging; Avoiding contamination of dies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/305Extrusion nozzles or dies having a wide opening, e.g. for forming sheets
    • B29C48/307Extrusion nozzles or dies having a wide opening, e.g. for forming sheets specially adapted for bringing together components, e.g. melts within the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/49Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using two or more extruders to feed one die or nozzle
    • B29C48/495Feed-blocks

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an apparatus and method for manufacturing a film or a sheet having a superior quality by sufficiently reducing attachment of foreign matter to the lip mouth of a die.SOLUTION: The apparatus for manufacturing the film or the sheet includes an extruder, a die, a flow path which communicates the extruder with the die and a resin displacement mechanism which is disposed in the middle of the flow path, has such a configuration that the flow path is divided into a plurality of branched paths and, thereafter, the plurality of branched paths are again joined together, and changes positions of molten resin flowing through the flow paths. The resin displacement mechanism has at least first and second branched paths by which the molten resin fed from the flow paths is separated in an X-axis direction, on the position where the molten resin is transferred in a Z-direction toward the die. The first and second branched paths are separated from each other in the X-axis direction on the upstream side, thereafter, are extended so as to come close to each other and the positional relation in the X-axis direction is reversed and the first and second branched paths come close to each other and are joined on the downstream side.

Description

本発明は、ダイから溶融樹脂を押し出してフィルム又はシートを製造するための装置及び方法に関する。   The present invention relates to an apparatus and method for producing a film or sheet by extruding a molten resin from a die.

押出機から供給される溶融樹脂をフィードパイプを通じてダイへ移送し、ダイから溶融樹脂を押し出すことによって樹脂フィルム(厚み5〜500μm程度)又は樹脂シート(厚み500μm〜50mm程度)が製造される。複数の押出機から一つのダイに溶融樹脂を供給することにより、多層フィルム又は多層シートを製造することも可能である。下記特許文献1には、複数の流路を有する装置を用いて多層フィルムを製造する方法が記載されている。   The molten resin supplied from the extruder is transferred to a die through a feed pipe, and the molten resin is extruded from the die to produce a resin film (thickness of about 5 to 500 μm) or a resin sheet (thickness of about 500 μm to 50 mm). It is also possible to produce a multilayer film or a multilayer sheet by supplying molten resin to a single die from a plurality of extruders. Patent Document 1 listed below describes a method for producing a multilayer film using an apparatus having a plurality of flow paths.

特開平4−278324号公報JP-A-4-278324

ところで、一定の期間にわたって樹脂フィルム又は樹脂シートの成形を行うと、樹脂の劣化物や添加剤の凝集物などの異物がダイのリップ口に付着することがある。異物がリップ口に付着する現象は当該分野において「メヤニ」と称される。異物が一旦リップ口に付着すると、成形時間の経過とともに当該箇所に異物が蓄積し、これが溶融樹脂と接触したり、成形品に混入したりする。   By the way, when a resin film or a resin sheet is molded over a certain period, foreign matters such as a deteriorated resin or an aggregate of additives may adhere to the lip opening of the die. The phenomenon in which foreign matter adheres to the lip mouth is referred to as “Meani” in the art. Once the foreign matter adheres to the lip mouth, the foreign matter accumulates at the location as the molding time elapses, and it comes into contact with the molten resin or enters the molded product.

リップ口に蓄積した異物は成形品の品質低下の原因となることから、添加剤処方を改良したり、樹脂の滑りを良くするためにリップ口に特殊メッキを施したりする対策が講じられてきた。しかしながら、従来の技術ではリップ口への異物の付着を十分に低減することができず、更なる改良が求められていた。   Since foreign matter accumulated in the lip mouth causes deterioration of the quality of the molded product, measures have been taken to improve the additive formulation and to apply special plating to the lip mouth to improve resin slipping. . However, the conventional technique cannot sufficiently reduce the adhesion of foreign matter to the lip mouth, and further improvement has been demanded.

本発明は、ダイのリップ口への異物の付着を十分に低減でき、優れた品質のフィルム又はシートを製造できる装置及び方法を提供することを目的とする。   It is an object of the present invention to provide an apparatus and a method that can sufficiently reduce the adhesion of foreign matter to the lip opening of a die and can produce a film or sheet of excellent quality.

押出機から流路を通じてダイへと溶融樹脂を移送する場合、流路の壁面近傍は溶融樹脂の流速が低いため、当該領域に滞留が生じやすい。本発明者らは、溶融樹脂の滞留によって流路内に生じた異物(樹脂の劣化物や添加剤の凝集物)がダイのリップ口に付着することに着目した。本発明者らは、流路の壁面近傍における滞留によって異物が発生したとしても、これをリップ口に蓄積させない手法について検討した。その結果、溶融樹脂をダイに導入する直前に、流路の壁面近傍を流れてきた溶融樹脂と、流路の中央部を流れた溶融樹脂とを置換することより、リップ口への異物付着を十分に低減できることを見出し、以下の発明を完成させた。   When the molten resin is transferred from the extruder to the die through the flow path, the flow rate of the molten resin is low in the vicinity of the wall surface of the flow path, so that the region tends to stay. The inventors of the present invention have focused on the fact that foreign matters (resin degradation products and additive agglomerates) generated in the flow path due to the residence of the molten resin adhere to the lip mouth of the die. The present inventors have studied a technique for preventing foreign matter from being accumulated in the lip mouth even if foreign matter is generated due to staying in the vicinity of the wall surface of the flow path. As a result, just before the molten resin is introduced into the die, the molten resin that has flowed near the wall surface of the flow path is replaced with the molten resin that has flowed in the center of the flow path, so that foreign matter adheres to the lip mouth. The inventors have found that it can be sufficiently reduced, and have completed the following invention.

本発明の装置は、フィルム又はシートを製造するためのものであり、溶融樹脂を移送するための押出機と、押出機からの溶融樹脂をフィルム状又はシート状にするためのダイと、押出機とダイとを連通する流路と、流路の途中に設けられ、流路が複数の分岐路に分かれた後、複数の分岐路が再度合流する構成を有し、流路を流れる溶融樹脂の位置を変更する樹脂置換機構とを備える。ダイから押し出される溶融樹脂の厚み方向をX軸方向とし、幅方向をY軸方向としたXYZ直交座標系を設定した場合、上記樹脂置換機構は、ダイに向けて溶融樹脂がZ方向に移送される位置に、流路から供給される溶融樹脂をX軸方向に分離させる第1及び第2の分岐路を少なくとも有する。第1及び第2の分岐路は、上流側においてX軸方向に互いに遠ざかり、その後、互いに近づくように延びてX軸方向の位置関係が逆転し、下流側においてX軸方向に互いに近づいて合流している。   The apparatus of the present invention is for producing a film or sheet, and includes an extruder for transferring a molten resin, a die for forming the molten resin from the extruder into a film or sheet, and an extruder. And a flow path that communicates with the die, and is provided in the middle of the flow path. After the flow path is divided into a plurality of branch paths, the plurality of branch paths are joined again, and the molten resin that flows through the flow path And a resin replacement mechanism for changing the position. When an XYZ orthogonal coordinate system is set in which the thickness direction of the molten resin extruded from the die is the X-axis direction and the width direction is the Y-axis direction, the resin replacement mechanism moves the molten resin toward the die in the Z direction. At least a first branch path and a second branch path for separating the molten resin supplied from the flow path in the X-axis direction. The first and second branch paths move away from each other in the X-axis direction on the upstream side, and then extend so as to approach each other, the positional relationship in the X-axis direction is reversed, and approach each other in the X-axis direction on the downstream side and merge. ing.

上記装置は、流路の壁面近傍を流れてきた樹脂と、流路の中央部を流れてきた樹脂とを樹脂置換機構によって置換することができる。流路の中央部を流れてきた樹脂には滞留を起因とする異物が含まれている可能性が低い。ダイに溶融樹脂を導入するに先立ち、異物の含有量が少ない樹脂が流路の壁面近傍を流れるようにすることで、リップ口に異物が付着しにくくなり、高品質のフィルム又はシートを安定的に製造できる。   The above apparatus can replace the resin flowing near the wall surface of the flow path with the resin flowing in the center of the flow path by the resin replacement mechanism. The resin that has flowed through the center of the flow path is unlikely to contain foreign matter due to retention. Prior to introducing the molten resin into the die, the resin with a low content of foreign matter flows in the vicinity of the wall surface of the flow path, making it difficult for foreign matter to adhere to the lip mouth and stable high-quality film or sheet. Can be manufactured.

本発明は、単層フィルム又は単層シートの製造装置に限らず、多層フィルム又は多層シートの製造装置も提供する。すなわち、本発明は、多層フィルム又は多層シートの製造装置であって、溶融樹脂をそれぞれ移送するための複数の押出機と、複数の押出機からの溶融樹脂をフィルム状又はシート状にするためのダイと、複数の押出機とダイとをそれぞれ連通する複数の流路と、複数の流路のうち少なくとも多層フィルム又は多層シートの最外層をなす溶融樹脂を移送する流路の途中に設けられ、当該流路が複数の分岐路に分かれた後、複数の分岐路が再度合流する構成を有し、当該流路を流れる溶融樹脂の位置を変更する樹脂置換機構とを備える装置を提供する。ダイから押し出される溶融樹脂の厚み方向をX軸方向とし、幅方向をY軸方向としたXYZ直交座標系を設定した場合、上記樹脂置換機構は、ダイに向けて溶融樹脂がZ方向に移送される位置に、当該流路から供給される溶融樹脂をX軸方向に分離させる第1及び第2の分岐路を少なくとも有する。第1及び第2の分岐路は、上流側においてX軸方向に互いに遠ざかり、その後、互いに近づくように延びてX軸方向の位置関係が逆転し、下流側においてX軸方向に互いに近づいて合流している。   The present invention provides not only a single-layer film or single-layer sheet manufacturing apparatus but also a multilayer film or multilayer sheet manufacturing apparatus. That is, this invention is a manufacturing apparatus of a multilayer film or a multilayer sheet, Comprising: A plurality of extruders for respectively transporting a molten resin, and a method for forming a molten resin from a plurality of extruders into a film or a sheet A die, a plurality of flow passages communicating with the plurality of extruders and the die, respectively, and provided in the middle of the flow passage for transferring the molten resin forming the outermost layer of at least the multilayer film or the multilayer sheet among the plurality of flow passages, An apparatus is provided that includes a structure in which a plurality of branch paths merge again after the flow path is divided into a plurality of branch paths, and a resin replacement mechanism that changes the position of the molten resin flowing through the flow paths. When an XYZ orthogonal coordinate system is set in which the thickness direction of the molten resin extruded from the die is the X-axis direction and the width direction is the Y-axis direction, the resin replacement mechanism moves the molten resin toward the die in the Z direction. At least a first branch path and a second branch path for separating the molten resin supplied from the flow path in the X-axis direction. The first and second branch paths move away from each other in the X-axis direction on the upstream side, and then extend so as to approach each other, the positional relationship in the X-axis direction is reversed, and approach each other in the X-axis direction on the downstream side and merge. ing.

多層フィルム又は多層シートを製造するための上記装置は、流路の壁面近傍を流れてきた樹脂と、流路の中央部を流れた樹脂とを樹脂置換機構によって置換することができる。これにより、ダイのリップ口に異物が付着しにくくなり、高品質の多層フィルム又は多層シートを安定的に製造できる。特に、多層フィルム又は多層シートを製造するプロセスにおいては、リップ口に異物が蓄積すると多層フィルム又は多層シートの最外層に欠陥が生じやすい。このため、最外層をなす溶融樹脂を移送する流路に少なくとも上記樹脂置換機構を設けることが品質向上及び歩留まり向上に有効である。   The apparatus for producing a multilayer film or a multilayer sheet can replace the resin flowing near the wall surface of the flow path and the resin flowing in the center of the flow path with a resin replacement mechanism. This makes it difficult for foreign matter to adhere to the lip opening of the die, and a high-quality multilayer film or multilayer sheet can be stably produced. In particular, in a process for producing a multilayer film or multilayer sheet, if foreign matter accumulates in the lip opening, defects are likely to occur in the outermost layer of the multilayer film or multilayer sheet. For this reason, it is effective for quality improvement and yield improvement to provide at least the resin replacement mechanism in the flow path for transferring the molten resin forming the outermost layer.

なお、上記特許文献1(特開平4−278324号公報)には多層フィルムの製造装置に関する発明が記載されているが、当該発明は本発明とは解決すべき課題が明らかに異なる。また、特許文献1の図面には、複数の流路を備えた装置が図示されているものの、当該文献は流路の壁面近傍を流れてきた樹脂と、流路の中央部を流れた樹脂とを置換するというような技術的思想を開示するものではない。   In addition, although the invention regarding the manufacturing apparatus of a multilayer film is described in the said patent document 1 (Unexamined-Japanese-Patent No. 4-278324), the said invention clearly differs in the subject which should be solved. In addition, although the drawing of Patent Document 1 shows an apparatus having a plurality of flow paths, the document describes a resin that has flown near the wall surface of the flow path, and a resin that has flowed in the center of the flow path. The technical idea of substituting is not disclosed.

本発明の方法は、フィルム又はシートを製造するためのものであり、押出機からダイに流路を通じて溶融樹脂を供給する工程と、ダイから溶融樹脂を押し出してフィルム又はシートを成形する工程とを備える。ダイから押し出される溶融樹脂の厚み方向をX軸方向とし、幅方向をY軸方向としたXYZ直交座標系を設定した場合、上記流路の途中には、複数の分岐路に分かれた後、複数の分岐路が再度一つの流路となって溶融樹脂をダイに向けてZ方向に移送し、流路を流れる溶融樹脂の位置を変更する樹脂置換機構が設けられている。樹脂置換機構が少なくとも有する第1及び第2の分岐路に溶融樹脂を導入することにより、第1及び第2の分岐路内の溶融樹脂は、上流側においてX軸方向に互いに遠ざかり、その後、互いに近づくように流れてX軸方向の位置関係が逆転し、下流側においてX軸方向に互いに近づいて合流する。   The method of the present invention is for producing a film or sheet, and includes a step of supplying a molten resin from an extruder to a die through a flow path, and a step of extruding the molten resin from the die to form a film or sheet. Prepare. When an XYZ orthogonal coordinate system is set in which the thickness direction of the molten resin extruded from the die is the X-axis direction and the width direction is the Y-axis direction, The resin replacement mechanism for changing the position of the molten resin flowing in the flow path is provided by transferring the molten resin in the Z direction toward the die again. By introducing the molten resin into at least the first and second branch paths that the resin replacement mechanism has, the molten resin in the first and second branch paths moves away from each other in the X-axis direction on the upstream side, and thereafter Flowing closer to each other, the positional relationship in the X-axis direction is reversed, and on the downstream side, they approach each other in the X-axis direction and merge.

上記方法においては、樹脂置換機構が流路の壁面近傍を流れてきた樹脂と、流路の中央部を流れた樹脂とを置換する。これにより、ダイのリップ口に異物が付着しにくくなり、高品質のフィルム又はシートを安定的に製造できる。   In the above method, the resin replacement mechanism replaces the resin that has flowed near the wall surface of the flow path with the resin that has flowed in the center of the flow path. This makes it difficult for foreign matter to adhere to the lip opening of the die, and a high-quality film or sheet can be stably produced.

本発明は、単層フィルム又は単層シートの製造方法に限らず、多層フィルム又は多層シートの製造方法も提供する。すなわち、本発明は、多層フィルム又は多層シートの製造方法であって、複数の押出機からダイに複数の流路を通じて溶融樹脂をそれぞれ供給する工程と、ダイから溶融樹脂を押し出して多層フィルム又は多層シートを成形する工程とを備える方法を提供する。ダイから押し出される溶融樹脂の厚み方向をX軸方向とし、幅方向をY軸方向としたXYZ直交座標系を設定した場合、複数の流路のうち少なくとも多層フィルム又は多層シートの最外層をなす溶融樹脂を移送する流路の途中には、複数の分岐路に分かれた後、複数の分岐路が再度一つの流路となって溶融樹脂をダイに向けてZ方向に移送し、当該流路を流れる溶融樹脂の位置を変更する樹脂置換機構が設けられている。樹脂置換機構が少なくとも有する第1及び第2の分岐路に溶融樹脂を導入することにより、第1及び第2の分岐路内の溶融樹脂は、上流側においてX軸方向に互いに遠ざかり、その後、互いに近づくように流れてX軸方向の位置関係が逆転し、下流側においてX軸方向に互いに近づいて合流する。   This invention provides not only the manufacturing method of a single layer film or a single layer sheet but the manufacturing method of a multilayer film or a multilayer sheet. That is, the present invention is a method for producing a multilayer film or a multilayer sheet, comprising a step of supplying molten resin from a plurality of extruders to a die through a plurality of flow paths, and extruding the molten resin from the die to form the multilayer film or multilayer Forming a sheet. When the XYZ orthogonal coordinate system is set with the thickness direction of the molten resin extruded from the die as the X-axis direction and the width direction as the Y-axis direction, the melting that forms at least the outermost layer of the multilayer film or multilayer sheet among the plurality of channels In the middle of the flow path for transferring the resin, after being divided into a plurality of branch paths, the plurality of branch paths again become one flow path to transfer the molten resin to the die in the Z direction, A resin replacement mechanism for changing the position of the flowing molten resin is provided. By introducing the molten resin into at least the first and second branch paths that the resin replacement mechanism has, the molten resin in the first and second branch paths moves away from each other in the X-axis direction on the upstream side, and thereafter Flowing closer to each other, the positional relationship in the X-axis direction is reversed, and on the downstream side, they approach each other in the X-axis direction and merge.

多層フィルム又は多層シートを製造するための上記方法においては、樹脂置換機構が流路の壁面近傍を流れてきた樹脂と、流路の中央部を流れた樹脂とを置換する。これにより、ダイのリップ口に異物が付着しにくくなり、高品質の多層フィルム又は多層シートを安定的に製造できる。特に、多層フィルム又は多層シートを製造するプロセスにおいては、リップ口に異物が蓄積すると多層フィルム又は多層シートの最外層に欠陥が生じやすい。このため、最外層をなす溶融樹脂を移送する流路に少なくとも上記樹脂置換機構を設けて樹脂を置換することが品質向上及び歩留まり向上に有効である。   In the above method for producing a multilayer film or a multilayer sheet, the resin replacement mechanism replaces the resin that has flowed in the vicinity of the wall surface of the flow path with the resin that has flowed in the center of the flow path. This makes it difficult for foreign matter to adhere to the lip opening of the die, and a high-quality multilayer film or multilayer sheet can be stably produced. In particular, in a process for producing a multilayer film or multilayer sheet, if foreign matter accumulates in the lip opening, defects are likely to occur in the outermost layer of the multilayer film or multilayer sheet. For this reason, it is effective to improve the quality and the yield by replacing the resin by providing at least the resin replacement mechanism in the flow path for transferring the molten resin forming the outermost layer.

本発明によれば、ダイのリップ口への異物の付着を十分に低減でき、優れた品質のフィルム又はシートを製造できる。   According to the present invention, it is possible to sufficiently reduce the adhesion of foreign matter to the lip opening of the die, and it is possible to manufacture a film or sheet with excellent quality.

本発明に係る多層フィルム又は多層シートの製造装置の好適な実施形態を示す模式図である。It is a schematic diagram which shows suitable embodiment of the manufacturing apparatus of the multilayer film or multilayer sheet which concerns on this invention. 多層フィルム又は多層シートの製造用のTダイの内部構造を示す断面図である。It is sectional drawing which shows the internal structure of T die for manufacture of a multilayer film or a multilayer sheet. 図1に示す装置が備える樹脂置換機構の構成を示す模式図である。It is a schematic diagram which shows the structure of the resin replacement mechanism with which the apparatus shown in FIG. 1 is provided. 樹脂置換機構の分岐部の構成を示す斜視図である。It is a perspective view which shows the structure of the branch part of a resin substitution mechanism. 樹脂置換機構の分岐部の構成を示す断面図である。It is sectional drawing which shows the structure of the branch part of a resin substitution mechanism. 樹脂置換機構の第1の再配置部の構成を示す斜視図である。It is a perspective view which shows the structure of the 1st rearrangement part of a resin replacement mechanism. 樹脂置換機構の第2の再配置部の構成を示す斜視図である。It is a perspective view which shows the structure of the 2nd rearrangement part of a resin replacement mechanism. 樹脂置換機構の合流部の構成を示す斜視図である。It is a perspective view which shows the structure of the junction part of a resin substitution mechanism. 2つの分岐路によって溶融樹脂が置換される様子を示す模式図である。It is a schematic diagram which shows a mode that molten resin is substituted by two branch paths. 断面形状が円形の流路と矩形の流路とを接続するための流路の構成を示す斜視図である。It is a perspective view which shows the structure of the flow path for connecting a flow path with a circular cross-sectional shape, and a rectangular flow path. 本発明に係る単層フィルム又は単層シートの製造装置の一実施形態を示す模式図である。It is a schematic diagram which shows one Embodiment of the manufacturing apparatus of the single layer film or single layer sheet which concerns on this invention.

本発明の好適な実施形態について、図面を参照しながら詳細に説明する。   DESCRIPTION OF EMBODIMENTS Preferred embodiments of the present invention will be described in detail with reference to the drawings.

<多層フィルム又は多層シートの製造装置>
図1に示す製造装置50は、多層フィルム又は多層シート(以下、「多層成形体」という。)を製造するためのものである。製造装置50は、3つの押出機1A,1B,1Cと、押出機1A,1B,1Cからの溶融樹脂が押し出されるTダイ5と、押出機1A,1B,1CとTダイ5とをそれぞれ連通する3つの流路8A,8B,8Cと、流路8A,8Bにそれぞれ設けられた樹脂置換機構10A,10Bとを備える。なお、流路8A,8Bは、多層成形体20の最外層20A,20Bをなす溶融樹脂をそれぞれ移送する流路である(図2参照)。
<Manufacturing apparatus for multilayer film or multilayer sheet>
A manufacturing apparatus 50 shown in FIG. 1 is for manufacturing a multilayer film or a multilayer sheet (hereinafter referred to as “multilayer molded body”). The manufacturing apparatus 50 communicates the three extruders 1A, 1B, and 1C, the T die 5 from which the molten resin from the extruders 1A, 1B, and 1C is extruded, and the extruders 1A, 1B, 1C, and the T die 5 respectively. Three flow paths 8A, 8B, 8C and resin replacement mechanisms 10A, 10B provided in the flow paths 8A, 8B, respectively. The flow paths 8A and 8B are flow paths that respectively transfer the molten resin forming the outermost layers 20A and 20B of the multilayer molded body 20 (see FIG. 2).

押出機1A,1B,1Cとしては、特に制限はないが、通常、一軸又は二軸押出機を用いることができる。具体例として、例えば一軸スクリュー押出機、同方向二軸回転スクリュー押出機、異方向二軸回転スクリュー押出機等のスクリュー押出機が挙げられる。   Although there is no restriction | limiting in particular as extruder 1A, 1B, 1C, Usually, a single screw or a twin screw extruder can be used. Specific examples include screw extruders such as a single screw extruder, a same direction twin screw extruder, and a different direction twin screw extruder.

図1に示すように、ダイから押し出される溶融樹脂の厚み方向をX軸方向とし、その幅方向をY軸方向としたXYZ直交座標系を設定した場合、Tダイ5は、流路8A,8B,8Cを通じて供給される溶融樹脂をY軸方向に広げるとともにZ方向に吐出して多層成形体20が成形されるように設けられている。図2に示すように、Tダイ5のリップ口5aから溶融樹脂をZ軸の矢印方向に吐出することにより、多層成形体20が成形される。多層成形体20は、最外層20A,20Bと、これらの間の中間層20Cとからなる。   As shown in FIG. 1, when an XYZ orthogonal coordinate system is set in which the thickness direction of the molten resin extruded from the die is the X-axis direction and the width direction is the Y-axis direction, the T die 5 has flow paths 8A and 8B. , 8C is provided such that the molten resin supplied through 8C is expanded in the Y-axis direction and discharged in the Z direction to form the multilayer molded body 20. As shown in FIG. 2, the multilayer molded body 20 is molded by discharging molten resin from the lip port 5 a of the T die 5 in the arrow direction of the Z axis. The multilayer molded body 20 includes outermost layers 20A and 20B and an intermediate layer 20C therebetween.

3つの流路8A,8B,8Cは、押出機1A,1B,1Cを出た溶融樹脂をTダイ5に導入するためのものである。押出機1A,1B,1Cを出た溶融樹脂は、温度が150〜500℃程度であり、圧力が0.1〜50MPa程度であるため、流路8A,8B,8Cはこれらの条件に耐え得る構造となっている。流路8A,8B,8Cの断面形状は、溶融樹脂の滞留を抑制する観点から円形が好ましい。   The three flow paths 8A, 8B, 8C are for introducing the molten resin that has exited the extruders 1A, 1B, 1C into the T-die 5. Since the molten resin exiting the extruders 1A, 1B, and 1C has a temperature of about 150 to 500 ° C. and a pressure of about 0.1 to 50 MPa, the flow paths 8A, 8B, and 8C can withstand these conditions. It has a structure. The cross-sectional shapes of the flow paths 8A, 8B, 8C are preferably circular from the viewpoint of suppressing the stay of the molten resin.

樹脂置換機構10A,10Bは、図3に示す通り、流路8A,8Bにそれぞれ設けられている。樹脂置換機構10Aは、流路8Aが2つの分岐路(第1及び第2の分岐路)12A,13Aに分かれた後、分岐路12A,13Aが再度合流する構成を有し、流路8Aを流れてきた溶融樹脂の位置を変更する機能を有する。樹脂置換機構10Bもこれと同様に、流路8Bが2つの分岐路(第1及び第2の分岐路)12B,13Bに分かれた後、分岐路12B,13Bが再度合流する構成を有し、流路8Bを流れてきた溶融樹脂の位置を変更する機能を有する。第1及び第2の分岐路は、上流側においてX軸方向に互いに遠ざかり、その後、X軸方向に互いに近づき、かつY軸方向に互いに遠ざかるように延びてX軸方向の位置が逆転し、かつY軸方向に互いに近づくように延びてY軸方向の位置関係が一致し、その後、下流側においてX軸方向に互いに近づいて合流していることが好ましい。樹脂置換機構10A,10Bは同様の構成及び機能を有するので、以下、樹脂置換機構10Aについて詳細に説明する。   As shown in FIG. 3, the resin replacement mechanisms 10A and 10B are provided in the flow paths 8A and 8B, respectively. The resin replacement mechanism 10A has a configuration in which the flow path 8A is divided into two branch paths (first and second branch paths) 12A and 13A, and then the branch paths 12A and 13A are joined again. It has a function of changing the position of the molten resin that has flowed. Similarly to this, the resin replacement mechanism 10B has a configuration in which after the flow path 8B is divided into two branch paths (first and second branch paths) 12B and 13B, the branch paths 12B and 13B merge again. It has a function of changing the position of the molten resin that has flowed through the flow path 8B. The first and second branch paths are separated from each other in the X-axis direction on the upstream side, and then extend so as to approach each other in the X-axis direction and away from each other in the Y-axis direction, and the positions in the X-axis direction are reversed, and It is preferable that they extend so as to approach each other in the Y-axis direction so that the positional relationships in the Y-axis direction coincide with each other, and then approach each other in the X-axis direction and merge on the downstream side. Since the resin replacement mechanisms 10A and 10B have the same configuration and function, the resin replacement mechanism 10A will be described in detail below.

樹脂置換機構10Aは、図3に示すように、Tダイ5に向けて溶融樹脂がZ方向に移送される位置に設けられている。2つの分岐路12A,13Aは、流路8Aから供給される溶融樹脂がX軸方向に分離するように流路8Aから分岐している。分岐路12A,13Aは樹脂置換機構10Aの上流側においてX軸方向に互いに遠ざかり、その後、互いに近づくように延びている。そして、分岐路12A,13Aはすれ違うようにしてクロスしてX軸方向の位置関係が逆転し、樹脂置換機構10Aの下流側においてX軸方向に互いに近づいて合流している。樹脂置換機構10Aを出た溶融樹脂は、そのままTダイ5へと供給されるようになっている。   As shown in FIG. 3, the resin replacement mechanism 10 </ b> A is provided at a position where the molten resin is transferred in the Z direction toward the T die 5. The two branch paths 12A and 13A are branched from the flow path 8A so that the molten resin supplied from the flow path 8A is separated in the X-axis direction. The branch paths 12A and 13A extend away from each other in the X-axis direction on the upstream side of the resin replacement mechanism 10A, and then extend so as to approach each other. Then, the branch paths 12A and 13A cross each other so that the positional relationship in the X-axis direction is reversed, and they approach and merge with each other in the X-axis direction on the downstream side of the resin replacement mechanism 10A. The molten resin leaving the resin replacement mechanism 10A is supplied to the T die 5 as it is.

図3〜8を参照しながら、樹脂置換機構10Aの構成について、より詳細に説明する。樹脂置換機構10Aは、分岐部15Aと、第1の再配置部16Aと、第2の再配置部17Aと、合流部18Aとを備え、これらがZ軸方向の上流側から下流側に向けて配置されている。流路8Aから供給される溶融樹脂はZ方向に流れ、分岐部15Aに導入されるようになっている。   The configuration of the resin replacement mechanism 10A will be described in more detail with reference to FIGS. The resin replacement mechanism 10A includes a branch portion 15A, a first rearrangement portion 16A, a second rearrangement portion 17A, and a merging portion 18A, which are directed from the upstream side to the downstream side in the Z-axis direction. Is arranged. The molten resin supplied from the flow path 8A flows in the Z direction and is introduced into the branch portion 15A.

樹脂置換機構10Aは、Tダイ5の上流側であってTダイ5までの距離が比較的近い位置に設けられている。この距離は、溶融樹脂の粘度や添加剤の種類にもよるが、好ましくは0〜30cmであり、より好ましくは0〜10cmである。樹脂置換機構10AをTダイ5から離れた位置に設置すると、樹脂置換機構10AからTダイ5の間の流路内においてその壁面近傍に異物の滞留が生じやすく、これがリップ口5aに異物が蓄積する原因となりやすい。樹脂置換機構10AをTダイ5の直ぐ近くに配置する好適な手段として、樹脂置換機構10Aを内蔵したフィードブロックを作製し、これをTダイ5の上流側に連結することが挙げられる。   The resin replacement mechanism 10 </ b> A is provided on the upstream side of the T die 5 and at a relatively short distance to the T die 5. This distance is preferably 0 to 30 cm, more preferably 0 to 10 cm, although it depends on the viscosity of the molten resin and the type of additive. When the resin replacement mechanism 10A is installed at a position away from the T die 5, foreign matter is likely to stay in the vicinity of the wall surface in the flow path between the resin replacement mechanism 10A and the T die 5, which accumulates foreign matter in the lip port 5a. It is easy to cause. As a suitable means for arranging the resin replacement mechanism 10 </ b> A in the immediate vicinity of the T die 5, a feed block including the resin replacement mechanism 10 </ b> A is manufactured and connected to the upstream side of the T die 5.

分岐部15Aにおいて分岐路12A,13AはX軸方向に分かれ、その後、X軸方向に互いに遠ざかるように延びている(図4,5参照)。図5を参照すると、分岐部15Aにおいて、分岐路12Aの延在方向はX軸の矢印方向へのベクトル成分を有し、分岐路13Aの延在方向はこれと反対方向へのベクトル成分を有する。   In the branch portion 15A, the branch paths 12A and 13A are divided in the X-axis direction, and then extend away from each other in the X-axis direction (see FIGS. 4 and 5). Referring to FIG. 5, in branching portion 15A, the extending direction of branching path 12A has a vector component in the direction of the arrow on the X axis, and the extending direction of branching path 13A has a vector component in the opposite direction. .

第1の再配置部16Aは、X軸方向に並んでいた分岐路12A,13AをY軸方向に離間した状態で並ぶようにするための部分である(図6参照)。第1の再配置部16Aにおいて分岐路12A,13Aは、上流側から下流側に向けてX軸方向に互いに近づき且つY軸方向に互いに遠ざかるように延びている。   The first rearrangement unit 16A is a part for arranging the branch paths 12A and 13A arranged in the X-axis direction so as to be separated in the Y-axis direction (see FIG. 6). In the first rearrangement section 16A, the branch paths 12A and 13A extend from the upstream side toward the downstream side so as to approach each other in the X axis direction and away from each other in the Y axis direction.

第2の再配置部17Aは、分岐路12A,13AのX軸方向の位置関係が第1の再配置部16Aの上流側におけるそれと逆になるようにするための部分である(図7参照)。第2の再配置部17Aにおいて分岐路12A,13Aは、上流側から下流側に向けてX軸方向に互いに遠ざかり且つY軸方向に互いに近づくように延びている。   The second rearrangement unit 17A is a part for making the positional relationship in the X-axis direction of the branch paths 12A and 13A opposite to that on the upstream side of the first rearrangement unit 16A (see FIG. 7). . In the second rearrangement portion 17A, the branch paths 12A and 13A extend from the upstream side toward the downstream side so as to be away from each other in the X-axis direction and closer to each other in the Y-axis direction.

合流部18Aは、分岐路12A,13Aを合流させるための部分である。図8を参照すると、合流部18Aにおいて、分岐路12Aの延在方向はX軸の矢印方向と反対方向へのベクトル成分を有し、分岐路12Bの延在方向はX軸の矢印方向へのベクトル成分を有する。   The junction 18A is a part for joining the branch paths 12A and 13A. Referring to FIG. 8, in the junction 18A, the extending direction of the branch path 12A has a vector component in the direction opposite to the arrow direction of the X axis, and the extending direction of the branch path 12B is in the direction of the arrow of the X axis. Has vector components.

樹脂置換機構10Aを流路8Aに設けることで、樹脂置換機構10Aの上流側において流路8Aの壁面近傍を流れていた溶融樹脂と、流路8Aの中央部を流れていた溶融樹脂とを置換することができる。これにより、図9に示す通り、樹脂置換機構10Aの下流側の流路内においては、異物を含有する可能性が低い溶融樹脂が流路の壁面近傍を流れ、他方、異物を含有する可能性が比較的高い溶融樹脂が流路の中央部を流れることとなる。   By providing the resin replacement mechanism 10A in the flow path 8A, the molten resin flowing near the wall surface of the flow path 8A on the upstream side of the resin replacement mechanism 10A and the molten resin flowing in the center of the flow path 8A are replaced. can do. As a result, as shown in FIG. 9, in the flow path on the downstream side of the resin replacement mechanism 10A, the molten resin that has a low possibility of containing foreign substances flows near the wall surface of the flow path, and may contain foreign substances. A relatively high molten resin flows through the center of the flow path.

なお、図9では、説明を分かりやすくするために、樹脂置換機構10Aの入口においてX軸方向の両端の領域Xにのみ色を付し、Y軸方向の両端の領域Yには色を付していない。実際は流路8Aの壁面近傍を通過してきた溶融樹脂は、流路8Aの内周面の全体にわたって存在する。このため、流路8Aの壁面近傍のうち図9において色を付さなかった部分の溶融樹脂は、樹脂置換機構10Aでは置換されずにTダイ5に至ることになる。しかし、この溶融樹脂から形成される部分は、多層成形体20の成形後に耳部としてカットされる。このため、この部分に外観不良などが生じても問題とはならない。   In FIG. 9, for ease of explanation, only the regions X at both ends in the X axis direction are colored at the entrance of the resin replacement mechanism 10A, and the regions Y at both ends in the Y axis direction are colored. Not. Actually, the molten resin that has passed near the wall surface of the flow path 8A exists over the entire inner peripheral surface of the flow path 8A. For this reason, the molten resin in the vicinity of the wall surface of the flow path 8A that is not colored in FIG. 9 reaches the T die 5 without being replaced by the resin replacement mechanism 10A. However, the portion formed from the molten resin is cut as an ear after the multilayer molded body 20 is molded. For this reason, even if an appearance defect or the like occurs in this portion, there is no problem.

上記のような溶融樹脂の置換を行うことにより、Tダイ5のリップ口5aに異物が付着しにくくなり、高品質の多層成形体を安定的に製造することが可能となる。特に、リップ口5aに異物が蓄積すると多層成形体20の最外層20A,20Bに外観不良などの不具合が生じやすいため、最外層用の溶融樹脂を移送する流路8A,8Bに樹脂置換機構10A,10Bをそれぞれ設けることが品質向上及び歩留まり向上に有効である。   By performing the replacement of the molten resin as described above, it is difficult for foreign matters to adhere to the lip port 5a of the T die 5, and it becomes possible to stably manufacture a high-quality multilayer molded body. In particular, if foreign matter accumulates in the lip port 5a, defects such as defective appearance are likely to occur in the outermost layers 20A and 20B of the multilayer molded body 20, and therefore the resin replacement mechanism 10A is provided in the flow paths 8A and 8B for transferring the outermost layer molten resin. , 10B are effective in improving quality and yield.

なお、樹脂置換機構10Aにおける分岐路の本数は、2本に限定されるものではなく、3本以上としてもよいが、当該機構の製造上の観点からして2本であることが好ましい。分岐路12A,13Aの断面形状は、流路8Aの壁面近傍を流れる溶融樹脂を効果的に分断し、その後、再度合流させる観点から、矩形であることが好ましい。図10に示す流路19は、断面形状が円形の流路と矩形の流路とを接続するためのものである。樹脂置換機構10A,10Bの上流側及び下流側に流路19をそれぞれ設けることが好ましい。   Note that the number of branch paths in the resin replacement mechanism 10A is not limited to two and may be three or more, but two is preferable from the viewpoint of manufacturing the mechanism. The cross-sectional shapes of the branch paths 12A and 13A are preferably rectangular from the viewpoint of effectively dividing the molten resin flowing in the vicinity of the wall surface of the flow path 8A and then joining again. A channel 19 shown in FIG. 10 is for connecting a channel having a circular cross-sectional shape and a rectangular channel. It is preferable to provide the flow paths 19 on the upstream side and the downstream side of the resin replacement mechanisms 10A and 10B, respectively.

<多層フィルム又は多層シートの製造方法>
製造装置50を使用して多層成形体(多層フィルム又は多層シート)を製造する方法について説明する。本実施形態に係る方法は、押出機1A,1B,1Cから流路8A,8B,8Cを通じてTダイ5に溶融樹脂をそれぞれ供給する工程と、Tダイ5から溶融樹脂を押し出して多層成形体20を成形する工程とを備える。
<Method for producing multilayer film or multilayer sheet>
A method for producing a multilayer molded body (multilayer film or multilayer sheet) using the production apparatus 50 will be described. In the method according to the present embodiment, the molten resin is supplied from the extruders 1A, 1B, and 1C to the T die 5 through the flow paths 8A, 8B, and 8C, and the molten resin is extruded from the T die 5 to form the multilayer molded body 20. Forming the step.

流路8Aに設けられた樹脂置換機構10Aに溶融樹脂を導入することで、樹脂置換機構10Aの上流側において流路8Aの壁面近傍を流れていた溶融樹脂と、流路8Aの中央部を流れていた溶融樹脂とを置換する。より具体的には、まず、分岐路12A,13Aを通じてX軸方向に互いに遠ざかり、その後、互いに近づくように溶融樹脂を流す。そして、分岐路12A,13A内をそれぞれ流れる溶融樹脂のX軸方向の位置関係を逆転させた後、これらの溶融樹脂をX軸方向に互いに近づくように流して合流させる。樹脂置換機構10Aを通過させた溶融樹脂を、そのままTダイ5へと供給する。なお、流路8A及びこれに設けられた樹脂置換機構10Bについても上記と同様である。   By introducing the molten resin into the resin replacement mechanism 10A provided in the flow path 8A, the molten resin flowing in the vicinity of the wall surface of the flow path 8A on the upstream side of the resin replacement mechanism 10A and the central portion of the flow path 8A are flowed. Replace the molten resin. More specifically, the molten resin is first flowed away from each other in the X-axis direction through the branch paths 12A and 13A, and then approached to each other. Then, after reversing the positional relationship in the X-axis direction of the molten resins flowing in the branch paths 12A and 13A, these molten resins are flowed so as to approach each other in the X-axis direction and merged. The molten resin that has passed through the resin replacement mechanism 10 </ b> A is supplied to the T die 5 as it is. The flow path 8A and the resin replacement mechanism 10B provided in the flow path 8A are the same as described above.

多層成形体の原料に使用する熱可塑性樹脂は特に限定されるものではなく、例えばエチレン単独重合体、プロピレン単独重合体、ブテン単独重合体、ヘキセン単独重合体、環状オレフィン単独重合体、エチレン−プロピレン共重合体、エチレン−1−ブテン共重合体、エチレン−1−ヘキセン共重合体、エチレン−1−オクテン共重合体、プロピレン−1−ブテン共重合体、プロピレン−1−ヘキセン共重合体、プロピレン−1−オクテン共重合体、エチレン−プロピレン−1−ブテン共重合体、エチレン−プロピレン−1−ヘキセン共重合体、プロピレン−エチレンブロック共重合体、エチレン−プロピレン−1−オクテン共重合体、エチレン−スチレン共重合体、プロピレン−スチレン共重合体、エチレン−ビニルシクロヘキサン共重合体、プロピレン−ビニルシクロヘキサン共重合体、エチレン−メタクリル酸メチル共重合体などのポリオレフィン系樹脂;ポリメチルメタクリレート、エチレン−エチルアクリレート共重合体などのアクリル系樹脂;ブタジエン−スチレン共重合体、アクリロニトリル−スチレン共重合体、ポリスチレン、スチレン−ブタジエン−スチレン共重合体、スチレン−イソプレン−スチレン共重合体、スチレン−アクリル酸共重合体等のスチレン系樹脂;塩化ビニル系樹脂、ポリフッ化ビニル、ポリフッ化ビニリデンなどのフッ化ビニル系樹脂;6−ナイロン、6,6−ナイロン、12−ナイロンなどのアミド系樹脂;ポリエチレンテレフタレート、ポリブチレンテレフタレートなどの飽和エステル系樹脂;ポリカーボネート、ポリフェニレンオキサイド、ポリアセタール、ポリフェニレンスルフィド、シリコーン樹脂、熱可塑性ウレタン樹脂、ポリエーテルエーテルケトン、ポリエーテルイミド、ポリアクリロニトリル、セルロース誘導体、ポリスルホン、ポリエーテルスルホン、各種熱可塑性エラストマーなどが挙げられる。これらの架橋物や変性物などを原料として用いてもよい。上記材料は、1種を単独で又は2種以上を組み合わせて用いてもよい。原料の樹脂に添加剤が適宜含有されていてもよい。   The thermoplastic resin used for the raw material of the multilayer molded body is not particularly limited. For example, ethylene homopolymer, propylene homopolymer, butene homopolymer, hexene homopolymer, cyclic olefin homopolymer, ethylene-propylene Copolymer, ethylene-1-butene copolymer, ethylene-1-hexene copolymer, ethylene-1-octene copolymer, propylene-1-butene copolymer, propylene-1-hexene copolymer, propylene -1-octene copolymer, ethylene-propylene-1-butene copolymer, ethylene-propylene-1-hexene copolymer, propylene-ethylene block copolymer, ethylene-propylene-1-octene copolymer, ethylene -Styrene copolymer, propylene-styrene copolymer, ethylene-vinylcyclohexane copolymer Polyolefin resins such as propylene-vinylcyclohexane copolymer and ethylene-methyl methacrylate copolymer; acrylic resins such as polymethyl methacrylate and ethylene-ethyl acrylate copolymer; butadiene-styrene copolymer, acrylonitrile-styrene Styrene resins such as copolymers, polystyrene, styrene-butadiene-styrene copolymers, styrene-isoprene-styrene copolymers, styrene-acrylic acid copolymers; vinyl chloride resins, polyvinyl fluoride, polyvinylidene fluoride, etc. Vinyl fluoride resins; amide resins such as 6-nylon, 6,6-nylon, 12-nylon; saturated ester resins such as polyethylene terephthalate and polybutylene terephthalate; polycarbonate, polyphenyleneoxy Id, polyacetal, polyphenylene sulfide, silicone resin, thermoplastic urethane resins, polyether ether ketone, polyetherimide, polyacrylonitrile, cellulose derivatives, polysulfone, polyether sulfone, and various thermoplastic elastomers. These cross-linked products and modified products may be used as raw materials. You may use the said material individually by 1 type or in combination of 2 or more types. Additives may be appropriately contained in the raw material resin.

なお、ポリオレフィン系樹脂の具体例としては、低密度ポリエチレン、線状ポリエチレン(エチレン・α−オレフィン共重合体)、高密度ポリエチレン等のポリエチレン系樹脂、ポリプロピレン、プロピレン・エチレン共重合体、プロピレン・1−ブテン共重合体等のポリプロピレン系樹脂、エチレン・環状オレフィン共重合体、エチレン・ビニルシクロヘキサン共重合体、ポリ(4−メチルペンテン−1)、ポリ(ブテン−1)、エチレン・アクリル酸メチル共重合体、エチレン・メタクリル酸メチル共重合体、エチレン・アクリル酸エチル共重合体、エチレン・酢酸ビニル共重合体などが挙げられる。   Specific examples of polyolefin resins include polyethylene resins such as low density polyethylene, linear polyethylene (ethylene / α-olefin copolymer) and high density polyethylene, polypropylene, propylene / ethylene copolymer, propylene / 1. -Polypropylene resin such as butene copolymer, ethylene / cyclic olefin copolymer, ethylene / vinylcyclohexane copolymer, poly (4-methylpentene-1), poly (butene-1), ethylene / methyl acrylate copolymer Examples thereof include a polymer, an ethylene / methyl methacrylate copolymer, an ethylene / ethyl acrylate copolymer, and an ethylene / vinyl acetate copolymer.

上記の樹脂から使用すべき原料を適宜選択し、これらを押出機1A,1B,1Cに供給することによって、通常、厚み5〜500μm程度の多層フィルム又は厚み500μm〜50mm程度の多層シートを製造する。上記製造方法によれば、溶融樹脂を樹脂置換機構10A,10Bを通過させて樹脂の置換を行うことで、Tダイ5のリップ口5aに異物が付着しにくくなり、高品質の多層成形体を安定的に製造できる。   By appropriately selecting raw materials to be used from the above resins and supplying them to the extruders 1A, 1B and 1C, a multilayer film having a thickness of about 5 to 500 μm or a multilayer sheet having a thickness of about 500 μm to 50 mm is usually produced. . According to the manufacturing method described above, the molten resin is passed through the resin replacement mechanisms 10A and 10B to replace the resin, thereby making it difficult for foreign matter to adhere to the lip port 5a of the T die 5 and producing a high-quality multilayer molded body. It can be manufactured stably.

以上、本発明の好適な実施形態について詳細に説明したが、本発明は上記実施形態に限定されるものではない。例えば、上記実施形態においては、最外層20A,20Bをなす溶融樹脂を移送する流路8A,8Bの両方に樹脂置換機構を設ける場合を挙げたが、例えば、最外層20Aに異物による欠陥が生じても製品の性質上、特に問題とならない場合は、最外層20B用の流路8Bのみに樹脂置換機構を設けてもよい。また、場合によっては、多層成形体20の中間層20C用の流路8Cに樹脂置換機構を設けてもよい。   The preferred embodiment of the present invention has been described in detail above, but the present invention is not limited to the above embodiment. For example, in the above embodiment, the case where the resin replacement mechanism is provided in both the flow paths 8A and 8B for transferring the molten resin forming the outermost layers 20A and 20B has been described. For example, the outermost layer 20A has defects due to foreign matters. However, if there is no particular problem due to the nature of the product, a resin replacement mechanism may be provided only in the flow path 8B for the outermost layer 20B. In some cases, a resin replacement mechanism may be provided in the flow path 8C for the intermediate layer 20C of the multilayer molded body 20.

更に上記実施形態においては、ダイとしてTダイを備えた場合を挙げたが、Tダイに限定されるものではなく、環状ダイ(クロスヘッドダイ)を備えてもよい。   Furthermore, in the said embodiment, although the case where T die was provided as a die | dye was mentioned, it is not limited to T die, You may provide a cyclic | annular die (crosshead die).

本発明に係る装置及び方法は、2層又は4層以上の多層成形体を製造するのに適用してもよい。更に図11に示すように、本発明は単層のフィルム又はシート(単層成形体)を製造するのに適用してもよい。図11に示す製造装置60は、フィルム又はシートを製造するためのものであり、押出機1Aと、Tダイ6と、押出機1とTダイ6とを連通する流路8と、樹脂置換機構10とを備える。樹脂置換機構10は、上述の樹脂置換機構10Aと同様の構成を有する。製造装置60及びこれを用いたフィルム又はシートの製造方法によれば、樹脂置換機構10が流路8内の溶融樹脂を置換することにより、Tダイ6のリップ口6aに異物が付着しにくくなり、高品質の単層成形体を安定的に製造できる。   The apparatus and method according to the present invention may be applied to produce a multilayer molded body having two layers or four or more layers. Furthermore, as shown in FIG. 11, the present invention may be applied to produce a single layer film or sheet (single layer molded product). A manufacturing apparatus 60 shown in FIG. 11 is for manufacturing a film or a sheet, and includes an extruder 1A, a T die 6, a flow path 8 that communicates the extruder 1 and the T die 6, and a resin replacement mechanism. 10. The resin replacement mechanism 10 has the same configuration as the resin replacement mechanism 10A described above. According to the manufacturing apparatus 60 and the method of manufacturing a film or sheet using the same, the resin replacement mechanism 10 replaces the molten resin in the flow path 8, so that it is difficult for foreign matter to adhere to the lip port 6 a of the T die 6. High-quality single-layer molded products can be stably produced.

1A,1B,1C…押出機、5,6…ダイ、8,8A,8B,8C …流路、10,10A,10B…樹脂置換機構、12A,13A…分岐路、12B,13B…分岐路、20…多層成形体(多層フィルム又は多層シート)、20A,20B…多層成形体の最外層、50…多層成形体の製造装置、60…単層成形体の製造装置。 1A, 1B, 1C ... Extruder, 5, 6 ... Die, 8, 8A, 8B, 8C ... Flow path, 10, 10A, 10B ... Resin replacement mechanism, 12A, 13A ... Branch path, 12B, 13B ... Branch path, DESCRIPTION OF SYMBOLS 20 ... Multilayer molded object (multilayer film or multilayer sheet), 20A, 20B ... Outermost layer of multilayer molded object, 50 ... Manufacturing apparatus of multilayer molded object, 60 ... Manufacturing apparatus of single layer molded object.

Claims (4)

フィルム又はシートの製造装置であって、
溶融樹脂を移送するための押出機と、
前記押出機からの溶融樹脂をフィルム状又はシート状にするためのダイと、
前記押出機と前記ダイとを連通する流路と、
前記流路の途中に設けられ、前記流路が複数の分岐路に分かれた後、前記複数の分岐路が再度合流する構成を有し、前記流路を流れる溶融樹脂の位置を変更する樹脂置換機構と、
を備え、
前記ダイから押し出される溶融樹脂の厚み方向をX軸方向とし、幅方向をY軸方向としたXYZ直交座標系を設定した場合、
前記樹脂置換機構は、前記ダイに向けて溶融樹脂がZ方向に移送される位置に、前記流路から供給される溶融樹脂をX軸方向に分離させる第1及び第2の分岐路を少なくとも有し、
前記第1及び第2の分岐路は、上流側においてX軸方向に互いに遠ざかり、その後、互いに近づくように延びてX軸方向の位置関係が逆転し、下流側においてX軸方向に互いに近づいて合流している、製造装置。
An apparatus for producing a film or sheet,
An extruder for transferring the molten resin;
A die for forming the molten resin from the extruder into a film or sheet; and
A flow path communicating the extruder and the die;
Resin replacement that is provided in the middle of the flow path, and has a configuration in which the plurality of branch paths merge again after the flow path is divided into a plurality of branch paths, and changes the position of the molten resin flowing in the flow path Mechanism,
With
When setting the XYZ orthogonal coordinate system with the thickness direction of the molten resin extruded from the die as the X-axis direction and the width direction as the Y-axis direction,
The resin replacement mechanism has at least first and second branch paths that separate the molten resin supplied from the flow path in the X-axis direction at a position where the molten resin is transferred in the Z direction toward the die. And
The first and second branch paths move away from each other in the X-axis direction on the upstream side, and then extend so as to approach each other, and the positional relationship in the X-axis direction is reversed. Manufacturing equipment.
多層フィルム又は多層シートの製造装置であって、
溶融樹脂をそれぞれ移送するための複数の押出機と、
前記複数の押出機からの溶融樹脂をフィルム状又はシート状にするためのダイと、
前記複数の押出機と前記ダイとをそれぞれ連通する複数の流路と、
前記複数の流路のうち少なくとも前記多層フィルム又は前記多層シートの最外層をなす溶融樹脂を移送する流路の途中に設けられ、当該流路が複数の分岐路に分かれた後、前記複数の分岐路が再度合流する構成を有し、当該流路を流れる溶融樹脂の位置を変更する樹脂置換機構と、
を備え、
前記ダイから押し出される溶融樹脂の厚み方向をX軸方向とし、幅方向をY軸方向としたXYZ直交座標系を設定した場合、
前記樹脂置換機構は、前記ダイに向けて溶融樹脂がZ方向に移送される位置に、当該流路から供給される溶融樹脂をX軸方向に分離させる第1及び第2の分岐路を少なくとも有し、
前記第1及び第2の分岐路は、上流側においてX軸方向に互いに遠ざかり、その後、互いに近づくように延びてX軸方向の位置関係が逆転し、下流側においてX軸方向に互いに近づいて合流している、製造装置。
An apparatus for producing a multilayer film or a multilayer sheet,
A plurality of extruders for respectively transporting the molten resin;
A die for forming the molten resin from the plurality of extruders into a film or sheet; and
A plurality of flow paths respectively communicating the plurality of extruders and the die;
Among the plurality of flow paths, at least the multilayer film or the multilayer sheet is provided in the middle of a flow path for transferring a molten resin forming the outermost layer, and the flow paths are divided into a plurality of branch paths, and then the plurality of branches A resin replacement mechanism for changing the position of the molten resin flowing through the flow path, having a configuration in which the paths merge again;
With
When setting the XYZ orthogonal coordinate system with the thickness direction of the molten resin extruded from the die as the X-axis direction and the width direction as the Y-axis direction,
The resin replacement mechanism has at least first and second branch paths that separate the molten resin supplied from the flow path in the X-axis direction at a position where the molten resin is transferred in the Z direction toward the die. And
The first and second branch paths move away from each other in the X-axis direction on the upstream side, and then extend so as to approach each other, and the positional relationship in the X-axis direction is reversed. Manufacturing equipment.
フィルム又はシートの製造方法であって、
押出機からダイに流路を通じて溶融樹脂を供給する工程と、前記ダイから溶融樹脂を押し出してフィルム又はシートを得る工程とを備え、
前記ダイから押し出される溶融樹脂の厚み方向をX軸方向とし、幅方向をY軸方向としたXYZ直交座標系を設定した場合、
前記流路の途中には、複数の分岐路に分かれた後、前記複数の分岐路が再度一つの流路となって溶融樹脂を前記ダイに向けてZ方向に移送し、前記流路を流れる溶融樹脂の位置を変更する樹脂置換機構が設けられており、
前記樹脂置換機構が少なくとも有する第1及び第2の分岐路に溶融樹脂を導入することにより、前記第1及び第2の分岐路内の溶融樹脂は、上流側においてX軸方向に互いに遠ざかり、その後、互いに近づくように流れてX軸方向の位置関係が逆転し、下流側においてX軸方向に互いに近づいて合流する、製造方法。
A method for producing a film or sheet,
A step of supplying the molten resin from the extruder to the die through a flow path, and a step of extruding the molten resin from the die to obtain a film or sheet,
When setting the XYZ orthogonal coordinate system with the thickness direction of the molten resin extruded from the die as the X-axis direction and the width direction as the Y-axis direction,
In the middle of the flow path, after being divided into a plurality of branch paths, the plurality of branch paths become a single flow path again to transfer the molten resin in the Z direction toward the die and flow through the flow path. A resin replacement mechanism that changes the position of the molten resin is provided,
By introducing the molten resin into at least the first and second branch paths of the resin replacement mechanism, the molten resin in the first and second branch paths is moved away from each other in the X-axis direction on the upstream side, and thereafter The manufacturing method of flowing so that it may mutually approach, the positional relationship of a X-axis direction may reverse, and it may mutually approach in the X-axis direction and may merge on the downstream side.
多層フィルム又は多層シートの製造方法であって、
複数の押出機からダイに複数の流路を通じて溶融樹脂をそれぞれ供給する工程と、前記ダイから溶融樹脂を押し出して多層フィルム又は多層シートを得る工程とを備え、
前記ダイから押し出される溶融樹脂の厚み方向をX軸方向とし、幅方向をY軸方向としたXYZ直交座標系を設定した場合、
前記複数の流路のうち少なくとも前記多層フィルム又は前記多層シートの最外層をなす溶融樹脂を移送する流路の途中には、複数の分岐路に分かれた後、前記複数の分岐路が再度一つの流路となって溶融樹脂を前記ダイに向けてZ方向に移送し、当該流路を流れる溶融樹脂の位置を変更する樹脂置換機構が設けられており、
前記樹脂置換機構が少なくとも有する第1及び第2の分岐路に溶融樹脂を導入することにより、前記第1及び第2の分岐路内の溶融樹脂は、上流側においてX軸方向に互いに遠ざかり、その後、互いに近づくように流れてX軸方向の位置関係が逆転し、下流側においてX軸方向に互いに近づいて合流する、製造方法。
A method for producing a multilayer film or a multilayer sheet,
A step of supplying molten resin from a plurality of extruders to a die through a plurality of flow paths, respectively, and a step of extruding the molten resin from the die to obtain a multilayer film or a multilayer sheet,
When setting the XYZ orthogonal coordinate system with the thickness direction of the molten resin extruded from the die as the X-axis direction and the width direction as the Y-axis direction,
Among the plurality of flow paths, at least in the middle of the flow path for transferring the molten resin forming the outermost layer of the multilayer film or the multilayer sheet, the plurality of branch paths are once again divided into a plurality of branch paths. A resin replacement mechanism is provided that moves the molten resin in the Z direction toward the die, becoming a flow path, and changes the position of the molten resin flowing through the flow path,
By introducing the molten resin into at least the first and second branch paths of the resin replacement mechanism, the molten resin in the first and second branch paths is moved away from each other in the X-axis direction on the upstream side, and thereafter The manufacturing method of flowing so that it may mutually approach, the positional relationship of a X-axis direction may reverse, and it may mutually approach in the X-axis direction and may merge on the downstream side.
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