JP2011119034A - Fuel cell - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a fuel cell with no reduction of cell performance in storage. <P>SOLUTION: The fuel cell 100 includes a plurality of containing chambers 1, a connection part 2 connecting together the containing chambers 1, a closing means 10 closing the connection part 2 to freely open, and an oxidation electrode 4 and a reduction electrode 3 disposed in any one of the containing chambers 1 with a space between them. An alkali electrolyte solution 8 is contained in any one of the containing chambers 1 and glucose 9 is contained in another one of the containing chambers. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a fuel cell.

  2. Description of the Related Art Conventionally, there are fuel cells having a structure using glucose as a fuel, one using an electrode on which an enzyme is immobilized as a catalyst, and one using a metal electrode as a catalyst. Patent Document 1 discloses a fuel cell using an electrode on which an enzyme is immobilized as a catalyst. Non-Patent Document 1 discloses a glucose-air fuel cell that promotes the oxidation reaction of sugar by a metal catalyst. It is known that when the fuel of a glucose-air fuel cell using a metal electrode described in Non-Patent Document 1 is made strongly alkaline, the oxidation reaction of glucose on the metal catalyst is promoted. As the fuel, a fuel in which a glucose solution is mixed with an aqueous solution of potassium hydroxide or sodium hydroxide is generally used.

JP 2007-188810 A (Claim 1, paragraph [0011])

Isao Taniguchi, Kumamoto University “Practical development of bioelectrochemistry-Practical development of biosensors and biocells / Chapter 15 Glucose-air fuel cell”, CMC Publishing Co., Ltd., March 2007, p. 252-270

When glucose is exposed to alkaline conditions, isomerization proceeds and fructose and mannose are produced. In most cases, it is known to be a mixture of glucose and fructose. Since fructose has a weaker function as a fuel than glucose, it has been found by experiments of the present inventors that the output decreases when used as a fuel for a sugar-air fuel cell.
That is, if glucose and an alkaline solution are mixed and stored when the battery is not used, the performance of glucose as a fuel deteriorates, leading to a decrease in battery performance.

  The present invention has been made in view of the above-described circumstances, and an object of the present invention is to provide a fuel cell in which battery performance does not deteriorate during storage.

In order to achieve the above object, the present invention provides the following means.
According to the present invention, a plurality of storage chambers, a connection portion that connects the storage chambers, a closing unit that closes the connection portion so that the connection portions can be opened, and an interior of any one of the storage chambers are arranged at intervals. Provided is a fuel cell comprising an oxidation electrode and a reduction electrode, wherein an alkaline electrolyte solution is accommodated in any one of the accommodation chambers, and glucose is contained in any one of the other accommodation chambers.

  According to the fuel cell of the present invention, the alkaline electrolyte solution and glucose are mixed to become a fuel liquid by opening the closing means when the battery is used. In a state where the oxidation electrode is immersed in the fuel liquid, glucose contained in the fuel liquid is oxidized by releasing electrons. On the other hand, in the reducing electrode, oxygen supplied from the storage chamber or the atmosphere receives electrons generated in the oxidizing electrode and is reduced. At this time, electrons emitted from the oxidation electrode cannot move in the fuel liquid, and therefore pass through an external circuit of the battery in which both electrodes are electrically connected. Thereby, power generation is performed as a battery.

  In this case, when the battery is not used, the alkaline electrolyte solution and glucose are separated by a clogging means, whereby isomerization of glucose by alkali can be prevented. Therefore, even a battery using a strong alkaline electrolyte solution can maintain high battery performance until the start of use.

  In the above invention, the closing means may be a partition member that is disposed at a position that closes the connecting portion and can be broken by an external force. Moreover, in the said invention, the said connection part is a connection pipe | tube which has a part which can be elastically deformed, and the said external force may be applied to the said partition member by the elastic deformation of the said connection pipe | tube. Thus, the alkaline electrolyte solution and glucose can be mixed safely and easily without directly touching the strong alkaline solution.

  In the said invention, the protection member which suppresses the elastic deformation of the said connecting pipe may be provided so that removal is possible. With such a configuration, while the protective member is provided on the connecting portion, the connecting portion cannot be elastically deformed greatly, so that it is possible to prevent the partition member from being accidentally broken when the battery is not used. When the battery is used, the elastic member can be deformed by removing the protective member.

In the above invention, a displaceable movable portion may be provided at a position facing the partition member, and a breakable portion having a sharp end that can penetrate the partition member may be fixed to the movable portion.
By setting it as such a structure, since a force can be directly applied to a partition member, a partition can be fractured | ruptured reliably.

In the above invention, the closing means may be a valve that can be opened and closed. This makes it possible to freely control communication between the storage chambers.
For example, it is possible to prevent glucose isomerization by alkali when the battery is not used by closing the valve until the start of use and opening the valve at the start of use as a battery. Moreover, the movement of the fuel liquid to another storage chamber can be blocked by closing the valve again after the fuel liquid is prepared. In such a case, high battery performance can be maintained until the start of use, and the state in which the reduction electrode and the oxidation electrode are immersed in the fuel liquid can be stably maintained when the battery is used.

The present invention relates to two storage chambers that are disposed in an up-and-down state in an unused state, a connecting portion that connects the storage chambers, and an oxidation electrode and a reduction chamber that are disposed at an interval in the upper storage chamber. There is provided a fuel cell including an electrode, in which solid glucose is fixed in the upper storage chamber, and an alkaline electrolyte solution is stored in the lower storage chamber.
Since glucose is fixed in the upper storage chamber when the battery is not used, the alkaline electrolyte solution and glucose can be isolated. Thereby, isomerization by the alkaline electrolyte solution when the battery is not used can be prevented. In addition, since the storage chambers can communicate with each other, the alkaline electrolyte solution and glucose can be mixed by simply turning the fuel cell upside down, so that it is possible to easily generate power.

In the said invention, the said alkaline electrolyte solution may contain either potassium hydroxide, sodium hydroxide, or lithium hydroxide.
The present invention does not require consideration of isomerization of glucose with an alkaline electrolyte solution when the battery is not used. Therefore, since the electrolyte solution exhibiting any strong alkalinity can be used, the power generation performance of the fuel cell can be improved.

  According to the present invention, in a fuel cell using a metal catalyst and glucose, it is possible to prevent glucose from being isomerized by an alkaline electrolyte solution and maintain high battery performance until the battery is used. .

It is sectional drawing which shows the fuel cell which concerns on 1st Embodiment. (A) shows a fuel cell when not in use, and (b) shows a fuel cell when in use. It is sectional drawing which shows the fuel cell which concerns on 2nd Embodiment. It is sectional drawing which shows the fuel cell which concerns on 3rd Embodiment. It is sectional drawing which shows the fuel cell which concerns on 4th Embodiment. It is sectional drawing which shows the fuel cell which concerns on 5th Embodiment. It is sectional drawing which shows the fuel cell which concerns on 6th Embodiment. It is sectional drawing which shows the fuel cell which concerns on 7th Embodiment. (A) shows a fuel cell when not in use, and (b) shows a fuel cell when in use.

<First Embodiment>
A fuel cell according to a first embodiment of the present invention will be described below with reference to FIG.
As shown in FIG. 1, the fuel cell 100 according to the present embodiment includes a first storage chamber 1a, a second storage chamber 1b, a connecting portion 2, a reduction electrode 3, an oxidation electrode 4, a positive electrode terminal 5, and A negative electrode terminal 6, an oxygen supply unit 7, an alkaline electrolyte solution 8, glucose 9, a blocking means 10, and a protective member 11 are provided.

The first storage chamber 1a and the second storage chamber 1b are housings made of a watertight material.
The connecting portion 2 is a tubular member that connects the first storage chamber 1a and the second storage chamber 1b, and at least a portion thereof is formed of a tubular elastic member.

The reducing electrode 3 is composed of a plate-like member in which manganese oxide is fixed to a metal net, and is provided in the first storage chamber 1a.
The oxidation electrode 4 is composed of a plate-like member made of a conductive material such as carbon paper carrying gold as a catalyst, and is disposed at a distance d from the reduction electrode 3 of the first storage chamber 1a. Yes.

  Since the positive electrode terminal 5 and the negative electrode terminal 6 have a function of moving electrons emitted from the oxidation electrode 4 to the reduction electrode 3, they are made of graphite which is a conductive material. The positive electrode terminal 5 and the negative electrode terminal 6 are arranged through the wall surface at the lower end of one side surface of the first storage chamber 1a, one end is exposed to the outside, and the other end is inside the first storage chamber 1a, respectively. And fixed to the oxidation electrode 4. One end exposed to the outside of the positive electrode terminal 5 and the negative electrode terminal 6 is connected to an external circuit (not shown).

  The oxygen supply part 7 is comprised with the opening part and ventilation waterproof material. In this embodiment, the breathable material is a porous resin film having pores, and a PTFE sheet is used. This sheet blocks the passage of liquid and allows the passage of the amount of gas necessary to generate electricity at maximum power. The oxygen supply unit 7 is provided so as to liquid-tightly seal the opening that penetrates the wall surface of the first storage chamber 1a. Inside the first storage chamber 1 a of the oxygen supply unit 7, the reduction electrode 3 is disposed adjacent to the oxygen supply unit 7 so as to cover the oxygen supply unit 7.

The alkaline electrolyte solution 8 employs an aqueous solution mainly composed of potassium hydroxide, and is adjusted to an appropriate pH for promoting the oxidation reaction. The alkaline electrolyte solution 8 is stored in the first storage chamber 1a. That is, the electrodes 3 and 4 are always immersed in the alkaline electrolyte solution 8.
As the glucose 9, an aqueous glucose solution prepared at an appropriate concentration necessary for power generation is used. Glucose 9 is stored in the second storage chamber 1b.

The closing means 10 is configured to close the connecting portion 2 so as to be openable and to isolate the first storage chamber 1a from the second storage chamber 1b. In the present embodiment, the closing means 10 is a partition member that is broken when stress is applied and enables the connecting portion 2 to be opened. Examples of such a partition member include a thin glass plate and a thin plastic plate. Further, as shown in FIG. 1 (a), the partition member is liquid-tight so as to block an opening that is a boundary between the first storage chamber 1a side and the second storage chamber 1b side inside the connecting portion 2. Is arranged.
The protection member 11 is arbitrarily provided so as to be removable on the outside of the connecting portion 2 and prevents the connecting portion 2 from being deformed when the battery is not used. The protection member 11 supports the first storage chamber 1 a and the second storage chamber 1 b in a state where the protection member 11 is provided in the connecting portion 2.

The operation of the fuel cell 100 according to this embodiment configured as described above will be described below.
According to the fuel cell 100 according to the present embodiment, when the battery is not used, the glucose 9 is separated from the first storage chamber 1a in which the alkaline electrolyte solution 8 is stored and the closing means 10 in the second storage chamber. 1b. At the start of use of the battery, by applying an external force P to the connecting portion 2 and bending it, the partition member is broken as shown in FIG. 1 (b), and the first storage chamber 1a and the second storage chamber. 1b is opened. Thereby, the alkaline electrolyte solution 8 and the glucose 9 are mixed to become the fuel liquid 12.

  When the fuel liquid 12 in which the alkaline electrolyte solution 8 and glucose 9 are mixed contacts the oxidation electrode 4, electrons are released from the glucose 9 contained in the fuel liquid 12. That is, glucose 9 is oxidized to gluconolactone, and the emitted electrons flow to the oxidation electrode 4. At this time, hydrogen ions are generated in the fuel liquid 12. Further, the electrons released from the glucose 9 and flowing to the oxidation electrode 4 cannot move through the fuel liquid 12, and are supplied to the reduction electrode 3 through an external circuit (not shown). On the other hand, in the reducing electrode 3, oxygen is reduced to water by supplying hydrogen ions in the fuel liquid 12 and electrons from the reducing electrode 3 to oxygen supplied from the outside air via the oxygen supply unit 7. Become. As a result, power is generated as a battery, and a current flows in the external circuit.

  As described above, the fuel cell according to the present embodiment can store glucose 9 in a state where it is not in contact with the alkaline electrolyte solution 8 when the battery is not used. Thereby, it is possible to prevent glucose 9 from being isomerized by the alkaline electrolyte solution 8. Moreover, since the glucose 9 does not contact the oxidation electrode 4 when the battery is not used, the power generation reaction can be suppressed. Accordingly, it is possible to suppress a decrease in battery performance during the storage period.

Further, since the closing means 10 is configured to be broken by an external force so that the connecting portion 2 can be opened, the alkaline electrolyte solution 8 is not directly touched when the connecting portion 2 is opened. Therefore, even if the alkaline electrolyte solution 8 is a strong alkaline solution, it can be easily and safely mixed with glucose 9.
By making both the alkaline electrolyte solution 8 and glucose 9 liquid, the mixing process can be speeded up. Further, since the reducing electrode 3 is in contact with the alkaline electrolyte solution in advance, the environment is suitable for oxygen reduction reaction.
Moreover, when the protective member 11 is provided in the connection part 2, it can prevent that a partition member is accidentally broken when the battery is not used.

Second Embodiment
A fuel cell according to a second embodiment of the present invention will be described below with reference to FIG.
The fuel cell 200 according to the present embodiment has the same configuration as that of the first embodiment except that the movable portion 23 is provided in the connecting portion 2 of the first embodiment, and the fracture portion 24 is provided in the movable portion. To do.

  The movable portion 23 is made of an elastic member and is disposed at a position facing the closing means 20. The breaking portion 24 is made of a member having a tip, and is provided inside the movable portion 23 so that the tip is directed to the closing means 20. The breaking portion 24 has a size that does not come into contact with the closing means 20 in a state where no external force is applied to the movable portion 23.

  When the battery is used, the blocking member 20 can be destroyed by removing the protective member 21 and applying an external force to the movable portion 23. In this embodiment, the closing means 20 uses a resin-made thin film having watertightness, such as polyethylene, polypropylene, and polyvinylidene chloride. The thin film is a film that is not dissolved by the alkaline electrolyte solution 8 and has a strength that allows the fracture portion 24 to penetrate by applying an external force to the movable portion 23.

By setting it as the said structure, since the fracture | rupture part 24 consists of a member which has a pointed end, it becomes easy to destroy the closure means 20. FIG. Thereby, the selection range of the isolation member used for the closing means is expanded. In addition, since it is not necessary to use all of the connecting portions between the storage chambers as elastic members, a battery having a more stable outer wall can be obtained.
In addition, the fracture | rupture part 24 may be provided in either the 1st storage chamber 1a side of the connection part 22, and the 2nd storage chamber 1b side.

<Third Embodiment>
A fuel cell according to a third embodiment of the present invention will be described below with reference to FIG.
The fuel cell 300 according to the present embodiment has the same configuration as that of the second embodiment except that the shape of the connecting portion 22 of the second embodiment and the arrangement of the movable portion 23 and the fracture portion 24 are changed.
In the present embodiment, the first storage chamber 1a and the second storage chamber 1b have at least one opening having the same size. The opening portions are arranged to face each other, and a closing means 30 is provided so as to close both storage chambers therebetween. The movable portion 33 is provided at a position facing the closing means 30 in the second storage chamber 1 b, and the breaking portion 34 is disposed inside the movable portion 33 so that the pointed end faces the closing means 30. The outside of the movable portion 33 is covered with a protection member 31. With such a configuration, the shape of the fuel cell can be simplified.

<Fourth embodiment>
A fuel cell according to a fourth embodiment of the present invention will be described below with reference to FIG.
The fuel cell 400 according to the present embodiment has the same configuration as that of the first embodiment except that the closing means 10 of the first embodiment is changed.

  In the present embodiment, a valve is used as the closing means 40. The valve is composed of a substantially cylindrical rotor, a valve casing, and a lever. In the center of the rotor, a flow path penetrating in the radial direction is formed. The valve casing is provided through the connecting portion 42 between the first storage chamber 1a and the second storage chamber 1b. The lever is disposed at one end of the rotor and can freely change the direction of the flow path. When the flow path is disposed laterally with respect to the first storage chamber 1a and the second storage chamber 1b, the connecting portion 42 is closed. When the flow path is disposed perpendicular to the first storage chamber 1a and the second storage chamber 1b, the connecting portion 42 is opened.

  With the above configuration, when the battery is not in use, the connecting portion 42 is closed by a valve, whereby the first storage chamber 1a in which the alkaline electrolyte solution is stored and the second storage chamber 1b in which the glucose 9 is stored. It becomes isolated. Thereby, when the battery is not used, isomerization of glucose 9 by the alkaline electrolyte solution 8 can be prevented. At the start of battery use, the alkaline electrolyte solution 8 and glucose 9 can be easily mixed by opening the connecting portion 42 with a valve. Further, when the connecting portion 42 is closed again after the fuel liquid 12 is prepared, the passage of the liquid is blocked and the first storage chamber 1a is closed. As a result, power generation is performed with the electrodes 3 and 4 immersed in the fuel liquid 12. Therefore, if the movement of the liquid between the storage chambers 1a and 1b is interrupted in a state where the fuel liquid 12 is stored in the first storage chamber 1a provided with the electrodes 2 and 3, the electrode becomes more stable to the fuel liquid 12. The immersed state can be maintained.

  Therefore, high battery performance can be maintained until the start of use of the battery, and stable electromotive force can be ensured when the battery is used. Further, the fuel liquid 12 can be prepared at an appropriate glucose concentration by adjusting the timing for opening and closing the connecting portion 42 by the valve.

<Fifth Embodiment>
A fuel cell according to a fifth embodiment of the present invention will be described below with reference to FIG.
As shown in FIG. 5, the fuel cell 500 according to the present embodiment is the fourth embodiment except that the third storage chamber 1 c is provided in the fourth embodiment and the alkaline electrolyte solution 8 is stored in the storage chamber. The configuration is the same as that of the form.

The third storage chamber 1c is a casing made of a watertight material and is connected to the second storage chamber 1b. When the battery is not used, the alkaline electrolyte solution 8 is stored in the third storage chamber 1c.
A valve 50ab and a valve 50bc are provided at the connecting portions 52ab and 52bc between the first storage chamber 1a and the second storage chamber 1b and the second storage chamber 1b and the third storage chamber 1c, respectively.

When the battery is used, the valve 50bc is opened, and the alkaline electrolyte solution 8 and glucose 9 are mixed to prepare the fuel liquid 12. Thereafter, the valve 50ab is opened so that the electrodes 3 and 4 are immersed in the fuel liquid 12, and the fuel liquid 12 is moved to the first storage chamber 1a. It is preferable that the valve 50ab and the valve 50bc are closed after the fuel liquid 12 is moved. According to the present embodiment, before the fuel liquid 12 is brought into contact with the electrode, it can be prepared uniformly with an appropriate glucose concentration, so that the oxidation reaction at the oxidation electrode 4 can be smoothly advanced.
In the present embodiment, glucose 9 and alkaline electrolyte solution 8 are stored in the second storage chamber 1b and the third storage chamber 1c, respectively, but the opposite may be possible.

<Sixth Embodiment>
A fuel cell according to a sixth embodiment of the present invention will be described below with reference to FIG.
As shown in FIG. 6, the fuel cell 600 according to the present embodiment has the same configuration as that of the fifth embodiment except that the combination for connecting the storage chambers of the fifth embodiment is changed.
The third storage chamber 1c is connected to the first storage chamber 1a and the second storage chamber 1b, respectively. When the battery is not used, the alkaline electrolyte solution 8 is stored in the third storage chamber 1c.
Connection portions 62a and 62b and connection portions 62b and 62c between the first storage chamber 1a and the second storage chamber 1b, the second storage chamber 1b and the third storage chamber 1c, and the first storage chamber 1a and the third storage chamber 1c. The connecting portions 62a and 62c are provided with a valve 60ab, a valve 60bc, and a valve 60ac, respectively.

  If it is set as the said structure, since the 2nd storage chamber 1b and the 3rd storage chamber 1c are each connected with the 1st storage chamber 1a, the valve | bulb 60ab and the valve | bulb 60ac can be open | released simultaneously. As a result, the fuel liquid 12 can be quickly moved to the first storage chamber 1a, so that the battery is suitable for use in an emergency. Further, in an emergency, it is possible to use the valve more quickly by opening all the valves at the same time. According to this embodiment, the fuel cell can be selected according to the situation during use.

<Seventh embodiment>
A fuel cell according to a seventh embodiment of the present invention will be described below with reference to FIG.
As shown in FIG. 7, the fuel cell 700 according to this embodiment includes a first storage chamber 1a, a second storage chamber 1b, a connecting portion 72, a reduction electrode 3 and an oxidation electrode 4, a positive electrode terminal 5, and A negative electrode terminal 6, an oxygen supply unit 7, an alkaline electrolyte solution 8, and solid glucose 79 are provided.

Each of the first storage chamber 1a and the second storage chamber 1b is a casing made of a watertight material, and is connected to each other by connecting portions 72 in the vertical direction.
The reduction electrode 3 is provided in the upper part of the first storage chamber 1a. The oxidation electrode 4 is disposed below the reduction electrode 3 of the first storage chamber 1a with a distance d. The positive electrode terminal 5 and the negative electrode terminal 6 are disposed through one wall upper end of the first storage chamber 1a through the wall surface, one end is exposed to the outside, and the other end is inside the first storage chamber 1a. And fixed to the oxidation electrode 4. One end exposed to the outside of the positive electrode terminal 5 and the negative electrode terminal 6 is connected to an external circuit (not shown). The oxygen supply unit 7 is provided so as to liquid-tightly seal the opening that penetrates the wall surface of the first storage chamber 1a. Inside the first storage chamber 1 a of the oxygen supply unit 7, the reduction electrode 3 is disposed adjacent to the oxygen supply unit 7 so as to cover the oxygen supply unit 7.

The alkaline electrolyte solution 8 is stored in the second storage chamber 1b.
As the glucose 79, an appropriate amount of powder necessary for power generation is used. Glucose 79 is joined to the inner wall of the first storage chamber 1a. Since water contains a hydroxyl group, it can be a component that isomerizes glucose. Therefore, it is preferable that glucose is accommodated in a solid state. For example, glucose 79 is kneaded with a small amount of starch paste, dried, and then joined to the inner wall of the first storage chamber 1a by starch paste. Alternatively, the glucose 79 powder may be wrapped with starch thin film (oblate etc.) and then joined to the inner wall of the first storage chamber 1a with starch paste.
By turning the fuel cell 700 upside down, the alkaline electrolyte solution 8 and glucose 79 can be mixed.

  With the above configuration, since power generation can be started by a simpler method, the fuel cell is suitable for use during a disaster.

  In the first to sixth embodiments, the glucose 9 uses an aqueous solution, but it may be a solid such as a powder.

DESCRIPTION OF SYMBOLS 1 Storage chamber 2,22,32,42,52,62,72 Connection part 3 Reduction electrode 4 Oxidation electrode 5 Positive electrode terminal 6 Negative electrode terminal 7 Oxygen supply part 8 Alkaline electrolyte solution 9,79 Glucose 10,40,50,60 Occlusion Means 11, 21, 31 Protection member 12 Fuel liquid 23, 33 Movable part 24 Breaking part 100, 200, 300, 400, 500, 600, 700 Fuel cell

Claims (8)

Multiple containment chambers;
A connecting portion for connecting the storage chambers;
Closure means for closably opening the connecting portion;
An oxidation electrode and a reduction electrode arranged at intervals in any of the storage chambers,
An alkaline electrolyte solution is stored in any of the storage chambers,
A fuel cell in which glucose is stored in any of the other storage chambers.   The fuel cell according to claim 1, wherein the closing means is a partition member that is disposed at a position that closes the connecting portion and can be broken by an external force. The connecting portion is a connecting pipe having a portion that can be elastically deformed;
The fuel cell according to claim 2, wherein the external force is applied to the partition member by elastic deformation of the connecting pipe.   The fuel cell according to claim 3, wherein a protective member that suppresses elastic deformation of the connecting pipe is detachably provided. A displaceable movable part is provided at a position facing the partition member,
The fuel cell according to claim 2, wherein a breakable portion having a tip that can penetrate the partition wall member is fixed to the movable portion.   The fuel cell according to claim 1, wherein the closing means is a valve that can be opened and closed. Two storage chambers that are arranged in an unused state above and below,
A connecting portion for communicating the containment chambers;
Comprising an oxidation electrode and a reduction electrode arranged at an interval inside the upper storage chamber;
Solid glucose is fixed in the upper storage chamber,
A fuel cell in which an alkaline electrolyte solution is accommodated in the lower accommodation chamber.   The fuel cell according to any one of claims 1 to 7, wherein the alkaline electrolyte solution contains any one of potassium hydroxide, sodium hydroxide, and lithium hydroxide.

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