JP2011104551A5 - - Google Patents

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JP2011104551A5
JP2011104551A5 JP2009264383A JP2009264383A JP2011104551A5 JP 2011104551 A5 JP2011104551 A5 JP 2011104551A5 JP 2009264383 A JP2009264383 A JP 2009264383A JP 2009264383 A JP2009264383 A JP 2009264383A JP 2011104551 A5 JP2011104551 A5 JP 2011104551A5
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Prior art keywords
electron donor
polylactic acid
molecular weight
based resin
supply agent
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JP2009264383A
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JP5392719B2 (en
JP2011104551A (en
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Figure 2011104551
Figure 2011104551

Claims (10)

微生物による生物学的処理に用いられ、該微生物に電子供与体を供給する電子供与体供給剤において、
重量平均分子量が略12000以下、結晶化度が10%以上で且つ40%以下であって使用環境の温度下で固体状態にあるポリ乳酸系樹脂を含むことを特徴とする電子供与体供給剤。
In an electron donor supply agent which is used for biological treatment by a microorganism and supplies an electron donor to the microorganism,
What is claimed is: 1. An electron donor supplier comprising a polylactic acid-based resin having a weight average molecular weight of about 12000 or less and a crystallinity of 10% or more and 40% or less and in a solid state at the temperature of use environment.
前記ポリ乳酸系樹脂は、重量平均分子量が略9500以上であることを特徴とする請求項1に記載の電子供与体供給剤。   The electron donor supply agent according to claim 1, wherein the polylactic acid-based resin has a weight average molecular weight of about 9500 or more. 微生物による生物学的処理に用いられ、該微生物に電子供与体を供給する電子供与体供給剤の製造方法において、
原料のポリ乳酸系樹脂の分子量を低下させる低分子量化工程と、
その低分子量化工程にて低分子量化されたポリ乳酸系樹脂を、その融点以上の温度で融解する融解工程と、
その融解工程により融解されたポリ乳酸系樹脂を、融点未満の温度でアニールするアニール工程とを有し、
そのアニール工程により結晶化させて固体状態としたポリ乳酸系樹脂を用いて電子供与体供給剤を製造することを特徴とする電子供与体供給剤の製造方法。
In a method of producing an electron donor supply agent which is used for biological treatment by a microorganism and supplies an electron donor to the microorganism,
A molecular weight reduction process for reducing the molecular weight of the raw material polylactic acid resin,
A melting step of melting the polylactic acid based resin reduced in molecular weight in the step of reducing molecular weight at a temperature above its melting point;
Annealing the polylactic acid-based resin melted by the melting step at a temperature below the melting point;
What is claimed is: 1. A method for producing an electron donor supply agent, comprising producing an electron donor supply agent using a polylactic acid-based resin that has been crystallized and solidified in the annealing step.
前記低分子量化工程は、重量平均分子量が略9500以上で且つ略12000以下の範囲となるように、原料のポリ乳酸系樹脂を低分子量化するものであることを特徴とする請求項3に記載の電子供与体供給剤の製造方法。   The said molecular weight reduction process molecular-weight-reduces the polylactic acid-type resin of a raw material so that a weight average molecular weight may be in the range of about 9500 or more and about 12000 or less, It is characterized by said Of electron donor donors. 前記アニール工程は、前記ポリ乳酸系樹脂の結晶化度が、10%以上で且つ40%以下となるようにアニールを行うものであることを特徴とする請求項3又は4に記載の電子供与体供給剤の製造方法。   5. The electron donor according to claim 3, wherein the annealing step is performed such that the crystallinity of the polylactic acid-based resin is 10% or more and 40% or less. Method of manufacturing feed agent. 生物学的処理によって被処理物質中の特定成分を無害化する環境浄化方法において、
請求項1しくは2に記載の電子供与体供給剤又は請求項3から5のいずれかに記載の製造方法によって製造された電子供与体供給剤を用いて生物学的処理を行うことを特徴とする環境浄化方法。
In an environmental purification method for harmonizing a specific component in a substance to be treated by biological treatment,
Characterized by performing a biological process using an electron donor supplying agent produced by the production method according to any one of 5 the electron donor supply agent or claim 3 according to claim 1 young properly 2 How to clean up the environment.
前記被処理物質は水系の液体であり、
前記特定成分は、窒素化合物であり、
前記電子供与体供給剤を用いて液中の窒素化合物を除去する脱窒処理を行うことを特徴とする請求項6に記載の環境浄化方法。
The substance to be treated is a water-based liquid,
The specific component is a nitrogen compound,
7. The environmental purification method according to claim 6, wherein denitrification treatment for removing nitrogen compounds in the liquid is performed using the electron donor supply agent.
前記ポリ乳酸系樹脂に含まれるポリ乳酸が、前記被処理物質中において、略3w/v%の濃度となるように投入されていることを特徴とする請求項7に記載の環境浄化方法。   8. The environmental purification method according to claim 7, wherein polylactic acid contained in the polylactic acid-based resin is added so as to have a concentration of about 3 w / v% in the substance to be treated. 前記被処理物質は、土壌であり、
前記特定成分は、窒素化合物であり、
前記電子供与体供給剤を用いて土壌中の窒素化合物を除去する脱窒処理を行うことを特徴とする請求項6に記載の環境浄化方法。
The substance to be treated is soil,
The specific component is a nitrogen compound,
7. The environmental purification method according to claim 6, wherein denitrification treatment for removing nitrogen compounds in the soil is performed using the electron donor supply agent.
酢酸と乳酸とが添加された硝酸含有水溶液を用い、該水溶液中で増殖する微生物を集積培養し、その集積培養微生物を前記被処理物質中に添加することを特徴とする請求項7から9のいずれかに記載の環境浄化方法 10. The method according to any one of claims 7 to 9, wherein the nitric acid-containing aqueous solution to which acetic acid and lactic acid are added is accumulated and cultured in the aqueous solution, and the accumulated culture microorganism is added to the substance to be treated. The environmental purification method described in any one .
JP2009264383A 2009-11-19 2009-11-19 Electron donor supplier, method for producing electron donor supplier, and environmental purification method using the same Expired - Fee Related JP5392719B2 (en)

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JP2011104551A5 true JP2011104551A5 (en) 2012-12-20
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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5909836B2 (en) * 2012-02-03 2016-04-27 東洋製罐株式会社 Electron donor supply agent and environmental purification method using the same
JP6232601B2 (en) * 2013-08-22 2017-11-22 国立大学法人豊橋技術科学大学 Polylactic acid resin for use in anaerobic digestion process and method for producing the same
JP6713661B2 (en) * 2016-02-03 2020-06-24 国立大学法人豊橋技術科学大学 Polylactic acid porous pellet and method for producing the same
WO2018155436A1 (en) * 2017-02-24 2018-08-30 株式会社カネカ Denitrification method and denitrification apparatus
JP6844591B2 (en) 2018-07-10 2021-03-17 東洋製罐グループホールディングス株式会社 Polylactic acid copolymer and its production method
CN113646384A (en) 2019-03-29 2021-11-12 东洋制罐集团控股株式会社 Polylactic acid solid composition and production method thereof

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JP4331378B2 (en) * 2000-04-20 2009-09-16 大成建設株式会社 Soil purification method
JP2004175848A (en) * 2002-11-25 2004-06-24 Taiho Ind Co Ltd Biodegradable resin molding having denitrifying action
JP2006218456A (en) * 2005-02-14 2006-08-24 Kokusai Kogyo Co Ltd Soil purifying method utilizing biodegradable resin
JP2008068233A (en) * 2006-09-15 2008-03-27 Hitachi Plant Technologies Ltd Nitrogen elimination measure and nitrogen removing apparatus

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