JP2011063633A - Emulsifying additive for oil-water fuel - Google Patents

Emulsifying additive for oil-water fuel Download PDF

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JP2011063633A
JP2011063633A JP2009212679A JP2009212679A JP2011063633A JP 2011063633 A JP2011063633 A JP 2011063633A JP 2009212679 A JP2009212679 A JP 2009212679A JP 2009212679 A JP2009212679 A JP 2009212679A JP 2011063633 A JP2011063633 A JP 2011063633A
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oil
water
fatty acid
fuel
stearate
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Yasuhiro Hosokawa
細川康弘
Takeshi Takizumi
瀧住武司
Chikakuni Gamo
蒲生哉邦
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an emulsifying additive for oil-water fuel, reducing the surface tension between oil and water when added to the water and the oil, promoting the association and dissociation of the oil and the water, enabling complete combustion, and useful for environmental safeguard and an energy-saving fuel. <P>SOLUTION: The emulsifying additive for the oil-water fuel is a composite emulsifier obtained by mixing equal amounts of glycerol/palm nut fatty acid ester, a glyceryl ester of Solanum nigrum acid, glyceryl oleate, a fatty acid ester of A stearate, a fatty acid ester of A sucrose, oleic acid stearate, glyceryl stearate, a palm nut fatty acid/amine propyl-trimethyl sucrose amino acid anhydride, a palm nut fatty acid amine DEA, and has a multiple hydrophile-lipophile balance (HLB) mass. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は油水燃料の乳化添加剤に関し、詳細には、水と油に添加されば、油と水の表面張力を下がり、油水の融合と解離を促進し、完全燃焼が可能となり、環境保全と省エネな燃料に有益となるものに関する。 The present invention relates to an oil-water fuel emulsifying additive, and more specifically, when added to water and oil, the surface tension of oil and water is lowered, fusion and dissociation of oil-water are promoted, complete combustion is possible, and It is useful for energy-saving fuel.

従来に燃料油の使い方は、直接に燃料を燃焼させが、完全燃焼は難しいので、有害物を生じ、たとえば、CO,CO,NOなどが発生易い、大気汚染と地球温暖化の元となり、なお、燃料油費用が高騰しており、燃料コスト削減考えなければならない場合もある。 Conventionally, the use of fuel oil directly burns fuel, but complete combustion is difficult, so it produces harmful substances, for example, CO, CO 2 , NO X, etc. are easily generated, causing air pollution and global warming. However, fuel oil costs are soaring and there are cases where it is necessary to consider reducing fuel costs.

本発明の目的は、前述公知の燃料油の使用上の欠点を改善する油水燃料の乳化添加剤を提供することにある。 It is an object of the present invention to provide an oil-water fuel emulsifying additive that improves the above-mentioned drawbacks of using known fuel oils.

本発明の油水燃料の乳化添加剤の組合せは、グリセリンパームナッツ脂肪酸エステル1と、イヌホオズキ酸グリセリル2と、オレイン酸グリセリル3と、Aステアレート脂肪酸エステル4と、A蔗糖脂肪酸エステル5と、オレイン酸ステアレート6と、ステアリン酸グリセリル7と、パームナッツ脂肪酸アミンプロピルトリメチル蔗糖アミン酸無水物8と、パームナッツ脂肪酸アミンDEA9とで、等量混和の複合乳化剤である。
本発明の乳化添加剤を採用するときには、水量と重油量比率は30:70の混合物に投入して、生成された燃料と、完全に水混入しない、水量と重油量比率は0:100の一般的純重油を比較すれば、10%の燃料が節減できて、なお、乳化添加剤を採用し、水量と重油量比率は40:60の混合物に投入して、生成された燃料と、完全に水混入しない、水量と重油量比率は0:100の一般的純重油を比較すれば、23%の燃料が節減できる。
The oil / water fuel emulsifying additive combination of the present invention comprises: glycerin palm nut fatty acid ester 1, glyceryl inufozuki, glyceryl oleate 3, A stearate fatty acid ester 4, A sucrose fatty acid ester 5, and oleic acid It is a composite emulsifier in which equal amounts of stearate 6, glyceryl stearate 7, palm nut fatty acid amine propyltrimethyl sucrose amine anhydride 8 and palm nut fatty acid amine DEA9 are mixed.
When employing the emulsifying additive of the present invention, the ratio of water to heavy oil is generally 30:70 and the generated fuel is not completely mixed with water. The ratio of water to heavy oil is generally 0: 100. Compared with pure heavy oil, 10% of fuel can be saved, and emulsified additive is used, and the ratio of water and heavy oil is introduced into a mixture of 40:60. Compared with general pure heavy oil with a water / heavy oil ratio of 0: 100 without water mixing, 23% of fuel can be saved.

本発明により、油水燃料の完全燃焼が可能となり、有害物は殆ど生じない、混入の水も燃料となり、コスト削減に効果が明らかである。詳しいのは、下記のようである。
1.使用するには、高価な器材が要らなくて、僅かな費用で、使用開始できる。
2.元来の炉具交換しなくても使える、ただ、空気の進出量を調整すれば良い。
3.水のイオン或いは塩分が多すぎる場合に特別に濾過する以外、一般に、普通の水道水若しくは工業用水で使える。
4.最も多くの燃料を節減できる、使用する重油或いは石油の違った燃料より、10〜15%の燃料削減ができる。
5.油水燃料の産出エネは、器材より違いがあるが、殆ど、全部燃料で使ったものと、100%同一である。
According to the present invention, complete combustion of oil-water fuel becomes possible, almost no harmful substances are generated, and mixed water also becomes fuel, which is clearly effective for cost reduction. The details are as follows.
1. To use it, no expensive equipment is required and it can be used at a low cost.
2. It can be used without replacing the original furnace, just adjusting the amount of air advancement.
3. In general, it can be used with ordinary tap water or industrial water except for special filtration when water ions or salt content is too high.
4). The fuel savings of 10-15% can be achieved compared to the fuels that use the heavy oil or petroleum that can save the most fuel.
5). Oil and water fuel output differs from equipment, but is almost 100% identical to that used for all fuel.

本発明の油水燃料の乳化添加剤の組合せは、図1で示されるように、グリセリンパームナッツ脂肪酸エステル1と、イヌホオズキ酸グリセリル2と、オレイン酸グリセリル3と、Aステアレート脂肪酸エステル4と、A蔗糖脂肪酸エステル5と、オレイン酸ステアレート6と、ステアリン酸グリセリル7と、パームナッツ脂肪酸アミンプロピルトリメチル蔗糖アミン酸無水物8と、パームナッツ脂肪酸アミンDEA9とで、等量混和の複合乳化剤である。
前記グリセリンパームナッツ脂肪酸エステル1と、イヌホオズキ酸グリセリル2と、オレイン酸グリセリル3と、Aステアレート脂肪酸エステル4と、A蔗糖脂肪酸エステル5と、オレイン酸ステアレート6と、ステアリン酸グリセリル7と、パームナッツ脂肪酸アミンプロピルトリメチル蔗糖アミン酸無水物8と、パームナッツ脂肪酸アミンDEA9の成分は、すべて、植物より抽出精練からになり、例えば、ココナッツ油、パームナッツ油、菜油、豆油、甘蔗などを、図2で示されるように製品化するのは、レジンの鑑定10から始まり、混合物遠心機で液体アミンをイオン化する11と、真空濃縮処理12と、品質検査13と、荷積み14と、秤量15と、出荷判断16で、本発明の乳化添加剤19製品となって出荷できる。
本発明の油水燃料の乳化添加剤の使用前の事前処理は、図3で示されるように、油20を、ポンプ駆動の混合機混合溝21に入れて、水22と混合後、さらに、本発明の乳化添加剤19を入れて混合させ、このような、次々に添加混合で、燃油を差し替える新世代の燃料23,24と生成され、通常には、1つの産出循環は、30分時間を要り、約5トンの産出となり、1日20時間の作動とすれば、毎日の平均産出値は200トンとなる。
本発明の油水燃料の乳化添加剤の経済利益の分析は、図4で示されるように、本発明の乳化添加剤19を採用し、水量と重油量比率は30:70の混合物に投入して、生成された燃料23と、完全に水混入しない、水量と重油量比率は0:100の一般的純重油を比較すれば、10%の燃料が節減できて、なお、乳化添加剤19を採用し、水量と重油量比率は40:60の混合物に投入して、生成された燃料24と、完全に水混入しない、水量と重油量比率は0:100の一般的純重油を比較すれば、23%の燃料が節減できる。
As shown in FIG. 1, the oil / water fuel emulsifying additive combination of the present invention comprises glycerin palm nut fatty acid ester 1, glyceryl canine benzoate, glyceryl oleate 3, A stearate fatty acid ester 4, and A A sucrose fatty acid ester 5, oleic acid stearate 6, glyceryl stearate 7, palm nut fatty acid amine propyl trimethyl sucrose amine anhydride 8 and palm nut fatty acid amine DEA 9 are composite emulsifiers mixed in equal amounts.
The glycerin palm nut fatty acid ester 1, glyceryl canine benzoate 2, glyceryl oleate 3, A stearate fatty acid ester 4, A sucrose fatty acid ester 5, oleic acid stearate 6, glyceryl stearate 7, palm The components of nut fatty acid amine propyl trimethyl sucrose amine anhydride 8 and palm nut fatty acid amine DEA9 are all extracted and refined from plants, for example, coconut oil, palm nut oil, vegetable oil, bean oil, sweet potato, etc. As shown in FIG. 2, the commercialization starts with resin identification 10, ionizing the liquid amine with a mixture centrifuge 11, vacuum concentration treatment 12, quality inspection 13, loading 14, weighing 15, In the shipping judgment 16, the product can be shipped as the 19 emulsifying additive product of the present invention.
As shown in FIG. 3, the pre-treatment before using the oil / water fuel emulsifying additive of the present invention is performed by putting the oil 20 into a pump-driven mixer mixing groove 21 and mixing it with water 22, The emulsifying additive 19 of the invention is added and mixed, and such a new generation of fuels 23 and 24 that replaces the fuel oil is generated by successive addition and mixing, and usually one output circulation takes 30 minutes time In short, if the output is about 5 tons and operated for 20 hours a day, the average daily output will be 200 tons.
As shown in FIG. 4, the analysis of the economic benefits of the oil-water fuel emulsifying additive of the present invention employs the emulsifying additive 19 of the present invention, and the ratio of water amount to heavy oil amount is charged into a 30:70 mixture. Compared with the produced fuel 23 and the general pure heavy oil with a water / heavy oil ratio of 0: 100 that does not completely mix with water, the fuel can be reduced by 10%, and the emulsifying additive 19 is adopted. The ratio of water and heavy oil is 40:60, and the generated fuel 24 is not mixed with water. The ratio of water and heavy oil is 0: 100. 23% of fuel can be saved.

本発明の油水燃料の乳化添加剤の組合せを示す図である。It is a figure which shows the combination of the emulsification additive of the oil-water fuel of this invention. 本発明の油水燃料の乳化添加剤の製品化を示す図である。It is a figure which shows commercialization of the emulsification additive of the oil-water fuel of this invention. 本発明の油水燃料の乳化添加剤の使用前の事前処理を示す図である。It is a figure which shows the pre-processing before use of the emulsification additive of the oil-water fuel of this invention. 本発明の油水燃料の乳化添加剤の経済利益の分析図である。It is an analysis figure of the economic profit of the emulsification additive of the oil-water fuel of this invention.

1 グリセリンパームナッツ脂肪酸エステル
2 イヌホオズキ酸グリセリル
3 オレイン酸グリセリル
4 Aステアレート脂肪酸エステル
5 A蔗糖脂肪酸エステル
6 オレイン酸ステアレート
7 ステアリン酸グリセリル
8 パームナッツ脂肪酸アミンプロピルトリメチル蔗糖アミン酸無水物
9 パームナッツ脂肪酸アミンDEA
10 レジンの鑑定
11 混合物遠心機で液体アミンをイオン化する
12 真空濃縮処理
13 品質検査
14 荷積み
15 秤量
16 出荷判断
19 乳化添加剤
20 燃油
21 混合機混合溝
22 水
23 燃料
24 燃料
DESCRIPTION OF SYMBOLS 1 Glycerine palm nut fatty acid ester 2 Inglycol glyceryl 3 glyceryl oleate 4 A stearate fatty acid ester 5 A sucrose fatty acid ester 6 oleic acid stearate 7 glyceryl stearate 8 palm nut fatty acid amine propyl trimethyl sucrose amino acid anhydride 9 palm nut fatty acid Amine DEA
10 Identification of Resin 11 Ionizing Liquid Amine with Mixture Centrifuge 12 Vacuum Concentration Process 13 Quality Inspection 14 Loading 15 Weighing 16 Shipping Judgment 19 Emulsifying Additive 20 Fuel Oil 21 Mixer Mixing Groove 22 Water 23 Fuel 24 Fuel

Claims (3)

油水燃料の乳化添加剤であって、前記乳化添加剤は、グリセリンパームナッツ脂肪酸エステルと、イヌホオズキ酸グリセリルと、オレイン酸グリセリルと、Aステアレート脂肪酸エステルと、A蔗糖脂肪酸エステルと、オレイン酸ステアレートと、ステアリン酸グリセリルと、パームナッツ脂肪酸アミンプロピルトリメチル蔗糖アミン酸無水物と、パームナッツ脂肪酸アミンDEAとで、等量混和の複合乳化剤であり、多重の親水親油平衡値(HLB,hydrophile-lipophile babance)質量を備え、水と油に添加されば、油と水の表面張力を下がり、油水の融合と解離を促進し、完全燃焼が可能になり、環境保全と省エネな燃料に有益となることを特徴とする油水燃料の乳化添加剤。 An emulsifying additive for oil-water fuel, the emulsifying additive comprising: glycerin palm nut fatty acid ester, glyceryl dog benzoate, glyceryl oleate, A stearate fatty acid ester, A sucrose fatty acid ester, and oleic acid stearate , Glyceryl stearate, palm nut fatty acid amine propyl trimethyl sucrose amine anhydride, and palm nut fatty acid amine DEA are mixed emulsifiers in an equal amount and have multiple hydrophilic lipophilic equilibrium values (HLB, hydrophile-lipophile If it is added to water and oil, it will lower the surface tension of oil and water, promote the fusion and dissociation of oil and water, and enable complete combustion, which will be beneficial for environmental conservation and energy-saving fuel An oil-water fuel emulsifying additive. 前記油水燃料の乳化添加剤に、水量と油量比率は30:70であることを特徴とする請求項1に記載の油水燃料の乳化添加剤。 2. The oil / water fuel emulsification additive according to claim 1, wherein the oil / water fuel emulsification additive has a water amount to oil ratio of 30:70. 3. 前記油水燃料の乳化添加剤に、水量と油量比率は40:60であることを特徴とする請求項1に記載の油水燃料の乳化添加剤。 2. The oil / water fuel emulsification additive according to claim 1, wherein the water / oil ratio is 40:60.
JP2009212679A 2009-09-15 2009-09-15 Emulsifying additive for oil-water fuel Pending JP2011063633A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104560235A (en) * 2015-01-22 2015-04-29 南通恒隆化工有限公司 Emulsifier

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04363391A (en) * 1991-06-10 1992-12-16 Neos Co Ltd Emulsion fuel composition
JPH0913056A (en) * 1995-06-28 1997-01-14 Mitsubishi Heavy Ind Ltd Emulsified heavy oil fuel
JP2004010765A (en) * 2002-06-07 2004-01-15 Shigemi Sawada W/o-type emulsion fuel
JP2004123947A (en) * 2002-10-03 2004-04-22 Sanyo Chem Ind Ltd Emulsifier for emulsified fuel
JP2008013633A (en) * 2006-07-04 2008-01-24 Yukinobu Mori Emulsion fuel, its manufacturing apparatus and manufacturing method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04363391A (en) * 1991-06-10 1992-12-16 Neos Co Ltd Emulsion fuel composition
JPH0913056A (en) * 1995-06-28 1997-01-14 Mitsubishi Heavy Ind Ltd Emulsified heavy oil fuel
JP2004010765A (en) * 2002-06-07 2004-01-15 Shigemi Sawada W/o-type emulsion fuel
JP2004123947A (en) * 2002-10-03 2004-04-22 Sanyo Chem Ind Ltd Emulsifier for emulsified fuel
JP2008013633A (en) * 2006-07-04 2008-01-24 Yukinobu Mori Emulsion fuel, its manufacturing apparatus and manufacturing method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104560235A (en) * 2015-01-22 2015-04-29 南通恒隆化工有限公司 Emulsifier

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