JP2011052034A5 - - Google Patents

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JP2011052034A5
JP2011052034A5 JP2009199303A JP2009199303A JP2011052034A5 JP 2011052034 A5 JP2011052034 A5 JP 2011052034A5 JP 2009199303 A JP2009199303 A JP 2009199303A JP 2009199303 A JP2009199303 A JP 2009199303A JP 2011052034 A5 JP2011052034 A5 JP 2011052034A5
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polyamide resin
flame retardant
flame
resin composition
retardant
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JP2009199303A
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JP5504756B2 (en
JP2011052034A (en
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Description

すなわち、本発明は、
(1)(a)1,5−ジアミノペンタンと炭素数6以上のジカルボン酸を主要成分として含有する単量体から構成されるポリアミド樹脂100重量部に対して、(b)難燃剤1〜50重量部を配合してなる難燃性ポリアミド樹脂組成物、
(2)前記(b)難燃剤がリン系難燃剤、窒素系難燃剤、金属水酸化物系難燃剤および臭素系難燃剤から選ばれた少なくとも1種であることを特徴とする(1)記載の難燃性ポリアミド樹脂組成物、
(3)前記(b)難燃剤がメラミンシアヌレートであり、(b)難燃剤の配合量が、(a)1,5−ジアミノペンタンと炭素数6以上のジカルボン酸を主要成分として含有する単量体から構成されるポリアミド樹脂100重量部に対して3〜20重量部であることを特徴とする(1)または(2)に記載の難燃性ポリアミド樹脂組成物、
(4)炭素数6以上のジカルボン酸が、アジピン酸、アゼライン酸、セバシン酸、ドデカン二酸、テレフタル酸、およびイソフタル酸から選ばれる少なくとも1種である(1)〜(3)のいずれかに記載の難燃性ポリアミド樹脂組成物、
(5)前記(a)1,5−ジアミノペンタンと炭素数6以上のジカルボン酸を主要成分として含有する単量体から構成されるポリアミド樹脂の大気平衡吸水率が、3.0%以上である(1)〜(4)のいずれかに記載の難燃性ポリアミド樹脂組成物、
(6)さらにガラス繊維を配合してなる(1)〜(5)のいずれかに記載の難燃性ポリアミド樹脂組成物、
)(1)〜()のいずれかに記載の難燃性ポリアミド樹脂組成物からなる成形品
である
That is, the present invention
(1) (b) Flame retardant 1-50 with respect to 100 parts by weight of a polyamide resin composed of monomers containing as main components 1,5-diaminopentane and a dicarboxylic acid having 6 or more carbon atoms A flame retardant polyamide resin composition comprising a weight part,
(2) The (b) flame retardant is at least one selected from a phosphorus flame retardant, a nitrogen flame retardant, a metal hydroxide flame retardant, and a bromine flame retardant. A flame retardant polyamide resin composition,
(3) The flame retardant (b) is melamine cyanurate, and the blending amount of the flame retardant (b) includes (a) 1,5-diaminopentane and a dicarboxylic acid having 6 or more carbon atoms as main components. The flame-retardant polyamide resin composition according to (1) or (2), which is 3 to 20 parts by weight with respect to 100 parts by weight of a polyamide resin composed of a monomer;
(4) The dicarboxylic acid having 6 or more carbon atoms is at least one selected from adipic acid, azelaic acid, sebacic acid, dodecanedioic acid, terephthalic acid, and isophthalic acid, according to any one of (1) to (3) The flame-retardant polyamide resin composition according to the description,
(5) The atmospheric equilibrium water absorption of a polyamide resin composed of a monomer containing (a) 1,5-diaminopentane and a dicarboxylic acid having 6 or more carbon atoms as main components is 3.0% or more. (1) to the flame retardant polyamide resin composition according to any one of (4),
(6) The flame-retardant polyamide resin composition according to any one of (1) to (5), further comprising glass fiber,
( 7 ) A molded article comprising the flame-retardant polyamide resin composition according to any one of (1) to ( 6 ) ,
It is .

Claims (7)

(a)1,5−ジアミノペンタンと炭素数6以上のジカルボン酸を主要成分として含有する単量体から構成されるポリアミド樹脂100重量部に対して、(b)難燃剤1〜50重量部を配合してなる難燃性ポリアミド樹脂組成物。 (A) With respect to 100 parts by weight of a polyamide resin composed of a monomer containing 1,5-diaminopentane and a dicarboxylic acid having 6 or more carbon atoms as main components, (b) 1 to 50 parts by weight of a flame retardant A flame retardant polyamide resin composition obtained by blending. 前記(b)難燃剤がリン系難燃剤、窒素系難燃剤、金属水酸化物系難燃剤および臭素系難燃剤から選ばれた少なくとも1種であることを特徴とする請求項1に記載の難燃性ポリアミド樹脂組成物。The flame retardant according to claim 1, wherein the flame retardant (b) is at least one selected from a phosphorus flame retardant, a nitrogen flame retardant, a metal hydroxide flame retardant, and a bromine flame retardant. Flammable polyamide resin composition. 前記(b)難燃剤がメラミンシアヌレートであり、(b)難燃剤の配合量が、(a)1,5−ジアミノペンタンと炭素数6以上のジカルボン酸を主要成分として含有する単量体から構成されるポリアミド樹脂100重量部に対して3〜20重量部であることを特徴とする請求項1または2に記載の難燃性ポリアミド樹脂組成物。(B) The flame retardant is melamine cyanurate, and (b) the amount of the flame retardant is (a) a monomer containing 1,5-diaminopentane and a dicarboxylic acid having 6 or more carbon atoms as main components. The flame-retardant polyamide resin composition according to claim 1 or 2, wherein the flame-retardant polyamide resin composition is 3 to 20 parts by weight with respect to 100 parts by weight of the constituted polyamide resin. 炭素数6以上のジカルボン酸が、アジピン酸、アゼライン酸、セバシン酸、ドデカン二酸、テレフタル酸、およびイソフタル酸から選ばれる少なくとも1種である請求項1〜3のいずれかに記載の難燃性ポリアミド樹脂組成物。The flame retardant according to any one of claims 1 to 3, wherein the dicarboxylic acid having 6 or more carbon atoms is at least one selected from adipic acid, azelaic acid, sebacic acid, dodecanedioic acid, terephthalic acid, and isophthalic acid. Polyamide resin composition. 前記(a)1,5−ジアミノペンタンと炭素数6以上のジカルボン酸を主要成分として含有する単量体から構成されるポリアミド樹脂の大気平衡吸水率が、3.0%以上である請求項1〜4のいずれかに記載の難燃性ポリアミド樹脂組成物。2. The atmospheric equilibrium water absorption of a polyamide resin composed of a monomer containing (a) 1,5-diaminopentane and a dicarboxylic acid having 6 or more carbon atoms as main components is 3.0% or more. The flame-retardant polyamide resin composition in any one of -4. さらにガラス繊維を配合してなる請求項1〜5のいずれかに記載の難燃性ポリアミド樹脂組成物。Furthermore, the flame-retardant polyamide resin composition in any one of Claims 1-5 formed by mix | blending glass fiber. 請求項1〜6のいずれかに記載の難燃性ポリアミド樹脂組成物からなる成形品。The molded article which consists of a flame-retardant polyamide resin composition in any one of Claims 1-6.
JP2009199303A 2009-08-31 2009-08-31 Flame retardant polyamide resin composition and molded article comprising the same Active JP5504756B2 (en)

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JP2011052034A JP2011052034A (en) 2011-03-17
JP2011052034A5 true JP2011052034A5 (en) 2012-08-02
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JP2013064091A (en) * 2011-09-20 2013-04-11 Unitika Ltd Polyamide resin composition and molding obtained by molding the same
KR101949184B1 (en) 2012-02-29 2019-02-18 도레이 카부시키가이샤 Polyamide resin composition with excellent color tone
CN112625431A (en) * 2020-12-21 2021-04-09 宁波高新区卓尔化工科技有限公司 PA packaging material
CN115894899A (en) * 2021-08-05 2023-04-04 上海凯赛生物技术股份有限公司 Polyamide copolymer PA5IT and preparation method thereof
CN114181390B (en) * 2021-12-23 2023-02-10 北京化工大学 Bio-based high-temperature-resistant polyamide and preparation method thereof

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JP4595883B2 (en) * 2005-05-17 2010-12-08 三菱化学株式会社 Manufacturing method of hinged molded article
JP5282371B2 (en) * 2006-05-16 2013-09-04 三菱化学株式会社 Copolymer polyamide resin
JP5013764B2 (en) * 2006-06-29 2012-08-29 旭化成ケミカルズ株式会社 Flame retardant polyamide resin composition and production method
DE102007037019A1 (en) * 2007-08-06 2009-02-12 Clariant International Limited Flame retardant mixture for thermoplastic polymers and flame-retardant polymers
JP2009070779A (en) * 2007-09-18 2009-04-02 Toray Ind Inc Arc-extinguishing apparatus for electric power switches
JP5644037B2 (en) * 2008-02-14 2014-12-24 三菱化学株式会社 Polyamide resin composition

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