JP2011015610A - Collagen component-containing processed food and method for producing the same - Google Patents
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Abstract
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本発明は、コラーゲン成分を経口摂取することを目的とした加工食品において、コラーゲン由来のゼラチンおよびコラーゲンペプチドの混合物を成形加工することにより、高含量でコラーゲン成分を含み、保形性に優れ、パリッとした好ましい歯ごたえがあり、口溶けが良く、そのままで手軽においしく咀嚼、摂取できるコラーゲン成分含有加工食品に関するものである。 The present invention is a processed food intended for oral intake of a collagen component. By molding and processing a mixture of collagen-derived gelatin and collagen peptide, it contains a high content of the collagen component, has excellent shape retention, and is crisp. It is related to a collagen component-containing processed food that has a good crunchy texture, good melting in the mouth, and can be easily chewed and ingested as it is.
近年、ゼラチンやコラーゲンペプチド等のコラーゲン成分の経口摂取による各種効能が報告されている。いくつか例を挙げると、コラーゲンペプチドの経口摂取により、皮膚角質層の吸水能が増加する可能性が示唆されること(非特許文献1を参照)、500mgのゼラチンと200mgのグリシンを含有するゼラチン/グリシン丸剤をドライスキンの患者に経口摂取させることにより、肌の水結合能力が顕著に上昇すること(非特許文献2を参照)、ゼラチンを爪の脆弱な患者に経口摂取させたところ爪の脆弱性が改善すること(非特許文献3を参照)、ゼラチンを経口摂取させたところ毛髪が太くなり、強度を増加する(非特許文献4を参照)などがある。そのため、コラーゲン成分を経口摂取する健康食品の市場ニーズが高く、様々な形態で多数市販されている。 In recent years, various effects of oral intake of collagen components such as gelatin and collagen peptides have been reported. Some examples suggest that oral intake of collagen peptides may increase the water absorption capacity of the stratum corneum (see Non-Patent Document 1), gelatin containing 500 mg gelatin and 200 mg glycine / When glycine pills are orally ingested by dry skin patients, the water-binding ability of the skin is remarkably increased (see Non-Patent Document 2), and gelatin is orally ingested by patients with weak nails. (See Non-Patent Document 3), and when gelatin is orally ingested, the hair becomes thicker and the strength is increased (see Non-Patent Document 4). For this reason, there is a great market need for health foods that are orally ingested with collagen components, and many are marketed in various forms.
コラーゲン成分、特にコラーゲンペプチドを摂取する形態として、錠剤、乾燥粉末またはそれらを溶解して含有させた様々な飲食品がある。それらのコラーゲン成分の含有量が高いほど、摂取効率が良いため、乾燥粉末のまま摂取すれば最も効率が良いと言える。しかし、乾燥粉末のままでは取り扱いにくく、非常に摂取しにくいため、飲料などに溶かして摂取するのが一般的である。溶かす手間を省いたドリンク状の製品が市販されているが、風味、におい、溶液粘度上昇の問題などにより、高濃度にできないため、物流コストやコラーゲン摂取効率等が悪く、コラーゲン単位重量当たりの販売単価が高くなる欠点がある。錠剤などでは、摂取時に水などを別途必要とするため利便性に欠ける。チュアブルタブレットに加工すればそれらの欠点を改善できるが、高濃度でコラーゲンを配合すると、口の中でべたついたり歯に付着したりする問題がある。 As a form for ingesting collagen components, particularly collagen peptides, there are tablets, dry powders, or various foods and drinks in which they are dissolved. The higher the content of these collagen components, the better the intake efficiency. Therefore, it can be said that the highest efficiency is obtained when the dry powder is ingested. However, since it is difficult to handle as it is as a dry powder and it is very difficult to take it, it is generally taken in a beverage or the like. A drink-like product that eliminates the hassle of dissolving is commercially available, but due to problems such as flavor, odor, and increased viscosity of the solution, it cannot be made high in concentration, so the distribution cost and collagen intake efficiency are poor, and sales per unit weight of collagen There is a drawback that the unit price is high. Tablets and the like are not convenient because they require additional water when ingested. These defects can be improved by processing into chewable tablets, but when collagen is added at a high concentration, there are problems of stickiness in the mouth and adhesion to teeth.
それを改善する技術がいくつか提案されている。例えば、コラーゲンペプチドを多量に含有するチュアブルタブレットとして、特定の低分子量範囲(平均分子量4000以下)のコラーゲンペプチドを使用するか、N末端基をグリシン等の特殊なアミノ酸残基の割合を調整することで歯つきを改善し、経口摂取できる形態としている(特許文献1参照)。しかし、それらの方法は、コラーゲンペプチドを特別な分子量範囲や、特殊なN末端基の割合にコントロールしなければならない。 Several techniques have been proposed to improve it. For example, as a chewable tablet containing a large amount of collagen peptide, use a collagen peptide with a specific low molecular weight range (average molecular weight of 4000 or less), or adjust the ratio of special amino acid residues such as glycine in the N-terminal group This improves the toothing and can be taken orally (see Patent Document 1). However, these methods must control the collagen peptide to a specific molecular weight range and a specific N-terminal group ratio.
別の方法として、コラーゲンペプチドに加えて、HLB値が1〜7の乳化剤と、粉末状濃縮大豆タンパク、結晶セルロース、及びα化デンプンのいずれかを含有させることによって、経口摂取時の歯つきを抑制する方法が公開されている(特許文献2参照)。しかし、コラーゲンペプチド以外の基材を多く加えるため、コラーゲンペプチドの含有量をその分減らさざるを得ないため、摂取効率が低下する。 As another method, in addition to a collagen peptide, an emulsifier having an HLB value of 1 to 7 and any one of powdered concentrated soy protein, crystalline cellulose, and pregelatinized starch can be used to reduce toothing when taken orally. The method of suppressing is open | released (refer patent document 2). However, since a large amount of base material other than the collagen peptide is added, the content of the collagen peptide has to be reduced accordingly, so that the intake efficiency decreases.
また、特定の平均粒子径の非水溶性カルシウム塩及び難水溶性多糖類を含有し、コラーゲンの含有量が10〜60質量%であるコラーゲン錠剤が開示されている(特許文献3参照)。しかし、非水溶性カルシウム塩粒子を使用するため、得られる錠剤は口触りが悪く、粉っぽさがあり、一般の加工食品としては満足のいく食感ではない。 In addition, a collagen tablet containing a water-insoluble calcium salt having a specific average particle size and a poorly water-soluble polysaccharide and having a collagen content of 10 to 60% by mass is disclosed (see Patent Document 3). However, since the water-insoluble calcium salt particles are used, the obtained tablets have a bad touch and are powdery, which is not a satisfactory texture as a general processed food.
健康食品は、定期的に摂取し続けるため、飽きが来ないような見た目の形を楽しめることや、さまざまな味付けや、おいしく摂取できる食感が望まれているが、上記の特許文献に記載されている発明ではその点は考慮されていない。 Since healthy foods are taken regularly, it is desired that they can enjoy a form that does not get bored, have various flavors, and can be eaten deliciously. This point is not taken into consideration in the present invention.
飽きが来ない摂取方法として、デザートやスナック菓子のような形態での摂取が考えられる。たとえば市販されているグミ、マシュマロやソフトキャンディは、コラーゲン由来のゼラチンを使用して作られる代表的なお菓子である。ところがこれらの食品は加工方法に起因して糖質が多く、コラーゲン成分含有量が少ないため、コラーゲンの摂取には不向きで、嗜好品の目的で不定期に摂取される傾向があり、目的に合わない。例えば、ゼラチンを使用したグミキャンディに空気を巻き込ませることで、もちもちした新食感を得る技術が公開されている(特許文献4参照)。しかし、当該グミキャンディはコラーゲン成分であるゼラチンを含むが、ゼラチン含有量が20%を超えることができない旨記載されており摂取効率が悪い。 As an ingestion method that does not get tired, ingestion in the form of desserts and snacks can be considered. For example, commercially available gummi, marshmallow, and soft candy are typical sweets made using collagen-derived gelatin. However, these foods are high in carbohydrates due to processing methods and have a low collagen content, so they are unsuitable for collagen intake and tend to be consumed irregularly for the purpose of luxury goods. Absent. For example, a technique for obtaining a fresh texture by bringing air into a gummy candy using gelatin has been disclosed (see Patent Document 4). However, although the gummy candy contains gelatin which is a collagen component, it is described that the gelatin content cannot exceed 20%, and the intake efficiency is poor.
本発明は、口内で粉砕容易なパリッとした食感を楽しめ、口溶けが良く歯つきがない、手軽に経口摂取できるように、さまざまな味付けやさまざまな形状に成形もでき、なおかつコラーゲン成分の摂取効率も良いコラーゲン成分含有加工食品を提供することを目的とする。 The present invention enjoys a crispy texture that can be easily pulverized in the mouth, melts well in the mouth, has no teeth, can be easily ingested, and can be shaped into various flavors and shapes, and ingested with a collagen component. The object is to provide a processed food containing collagen components with good efficiency.
本発明者らは、鋭意検討した結果、コラーゲン成分であるゼラチンとコラーゲンペプチドとの混合物を溶液状態で気泡を含ませ、加工すると、高含量でコラーゲン成分を含み、保形性に優れ、パリッとした好ましい歯ごたえがあり、口溶けが良く、そのままで手軽においしく咀嚼、摂取できる食品が得られることを見出し、本発明を完成した。 As a result of intensive studies, the inventors of the present invention have included a mixture of gelatin and collagen peptide, which are collagen components, in a solution state to contain bubbles, and when processed, they contain a high content of collagen components, excellent shape retention, and crispness. The present invention has been completed by discovering that a food product that can be easily chewed and ingested as it is is obtained.
すなわち、本発明は、ゼラチン及びコラーゲンペプチドを主要材料として含む組成物に気泡を含ませてなる、乾燥形態のコラーゲン成分含有加工食品であって、前記組成物中のゼラチンの含量が当該組成物の重量を基準に15〜45重量%であり、コラーゲンペプチドの含量が25〜85重量%であり、当該加工食品の見かけ密度が0.2〜0.7g/cm3であることを特徴とする加工食品にある。 That is, the present invention is a processed food containing a collagen component in a dry form, in which air bubbles are included in a composition containing gelatin and a collagen peptide as main materials, wherein the gelatin content in the composition is that of the composition. 15 to 45% by weight based on the weight, collagen peptide content is 25 to 85% by weight, and the apparent density of the processed food is 0.2 to 0.7 g / cm 3 In food.
さらに、本発明は上記コラーゲン成分含有加工食品の製造方法であって、
a. ゼラチン及びコラーゲンペプチドを主要材料として含む組成物に水を加えて、固形分濃度が10〜40重量%となるような量を用いて加温することにより水に溶解させる工程、ここで、前記組成物中のゼラチンの含量が当該組成物の重量を基準に15〜45重量%及びコラーゲンペプチドの含量が25〜85重量%となるように組成物中に含有させ、
b. 得られた水溶液を、攪拌することにより水溶液中に気泡を形成する工程、ここで、得られる加工食品の見かけ密度が0.2〜0.7g/cm3となるようにする、
c. 得られた気泡を含む水溶液を当該水溶液の凝固点よりも1〜10℃高い温度に冷却する工程、
d. さらに冷却することにより得られるゲルを所定の形態に成形する工程、及び
e. 成形したゲルを乾燥する工程
を含む方法にある。
Furthermore, the present invention is a method for producing the processed collagen-containing processed food,
a. A step of adding water to a composition containing gelatin and a collagen peptide as main materials, and heating the composition using an amount such that the solid content concentration is 10 to 40% by weight, wherein the composition is dissolved in water; The gelatin content in the product is contained in the composition so that the content of the gelatin is 15 to 45% by weight based on the weight of the composition and the content of the collagen peptide is 25 to 85% by weight,
b. A step of forming bubbles in the aqueous solution by stirring the obtained aqueous solution, wherein the apparent density of the obtained processed food is 0.2 to 0.7 g / cm 3 ;
c. Cooling the obtained aqueous solution containing bubbles to a temperature 1 to 10 ° C. higher than the freezing point of the aqueous solution,
d. Further forming the gel obtained by cooling into a predetermined form, and e. The method includes a step of drying the formed gel.
本発明により得られるコラーゲン成分含有加工食品は、気泡を含ませて成形・乾燥することによって、コラーゲンペプチドを大量に含ませても、コラーゲンペプチドの種類によらず、咀嚼した時に歯につきにくく、口溶けが良くなる。さらに、ゼラチンおよびコラーゲンペプチドの呈味と臭いが目立たなくなるため、さまざまな食味をつけることができる。 The collagen component-containing processed food obtained according to the present invention contains foam and is shaped and dried, so that even if it contains a large amount of collagen peptide, it does not easily touch teeth when chewed, regardless of the type of collagen peptide, and melts in the mouth. Will be better. Furthermore, since the taste and smell of gelatin and collagen peptides are not noticeable, various tastes can be added.
本発明の加工食品は、コラーゲン成分を大量、例えば、当該加工食品の重量を基準にゼラチンとコラーゲンペプチドとの合計量で40重量%以上、60重量%以上、80重量%以上、さらには100重量%含ませることができ、効率の良いコラーゲン成分の摂取ができる。 The processed food of the present invention has a large amount of collagen component, for example, 40% by weight or more, 60% by weight or more, 80% by weight or more, and further 100% in total amount of gelatin and collagen peptide based on the weight of the processed food. % Can be contained, and the collagen component can be efficiently ingested.
ゼラチンとコラーゲンペプチドを組み合わせることにより、ゼラチンのゲル化能力によって保形性がよくなり、さまざまな形態の加工食品に成形することができる。さらにゼラチンの保護コロイド性が、発生させた気泡や、油脂を含む食味(カレーやココアパウダー、味噌など)、粉末(ハーブ粉末、コショウ、唐辛子など)などを、溶液中に安定して分散させておくことができ、ゲル化後に乾燥させることにより、最終的な加工食品の形態でもその分散状態を保持でき、しかも均質な様々な味付けができる。 By combining gelatin and a collagen peptide, the shape-retaining property is improved by the gelation ability of gelatin, and can be formed into various forms of processed foods. In addition, the protective colloidal properties of gelatin make it possible to stably disperse generated bubbles, fat-containing tastes (curry, cocoa powder, miso, etc.), powders (herb powder, pepper, chili, etc.) in the solution. By drying after gelation, the dispersed state can be maintained even in the final processed food form, and various homogeneous flavors can be obtained.
本発明の加工食品は、パリッとした食感を楽しめ、口溶けが良く歯つきがなく、気軽に楽しく経口摂取できる。ゼラチンのゼリー強度やゼラチンとコラーゲンペプチドとの組成比を調節したり、増粘多糖類を一部含有させたりすることで、パリパリ感からサクサク感まで食感を変えることもできる。その形態は、お菓子のように気軽に摂取できる健康食品への用途に特に有用で、スナック菓子のような食品となり得る。通常のスナック菓子は、デンプン質で油を使用するものが多く、高脂肪・高カロリーとなるが、本発明は同様の食感を楽しめ、カロリーを抑えた代替え食品となり得る。主成分がタンパク質からなる乾燥食品であるので、スナック菓子等に比べて栄養価が高い。焼成させる必要がなく、成形後も可逆的に湯に溶解できるので、加工装置を洗浄しやすい利点もある。 The processed food of the present invention enjoys a crisp texture, melts well in the mouth and does not have teeth, and can be easily orally ingested. The texture can be changed from crispy to crispy by adjusting the gelatin jelly strength, the composition ratio between gelatin and collagen peptide, or by partially containing a thickening polysaccharide. The form is particularly useful for use as a health food that can be easily ingested like sweets, and can be a food such as a snack. Many ordinary snacks are starchy and oil is used, resulting in a high fat and high calorie content. However, the present invention can provide a similar texture and can be an alternative food with reduced calories. Since it is a dry food consisting mainly of protein, its nutritional value is higher than snacks. There is also an advantage that it is easy to clean the processing apparatus because it can be reversibly dissolved in hot water after molding without the need for firing.
本発明の加工食品は、直接摂取を目的としたフレーク、バー、せんべい、ビスケット、チップス、クラッカー、ポン菓子、クルトン状のスナック菓子や、可食性容器、たとえばアイスクリームやソフトクリームのコーン部、モナカの皮、パニプリ、ウエハースのような使い方にも適用でき、健康食品ばかりでなく、広範囲の食品に使用できるという利点がある。 The processed foods of the present invention are flakes, bars, rice crackers, biscuits, chips, crackers, pon confectionery, crouton-like snacks intended for direct consumption, edible containers such as cones of ice cream and soft cream, monaca It can be applied to uses such as leather, panipri and wafers, and has the advantage that it can be used for a wide range of foods as well as health foods.
上述したように、本発明はゼラチン及びコラーゲンペプチドを主要材料として含む組成物に気泡を含ませてなる、乾燥形態のコラーゲン成分含有加工食品であって、前記組成物中のゼラチンの含量が当該組成物の重量を基準に15〜45重量%であり、コラーゲンペプチドの含量が25〜85重量%であり、当該加工食品の見かけ密度が0.2〜0.7g/cm3であることを特徴とするコラーゲン成分含有加工食品にある。 As described above, the present invention is a processed food containing a collagen component in a dry form, in which air bubbles are included in a composition containing gelatin and a collagen peptide as main materials, and the gelatin content in the composition is the composition. 15 to 45% by weight based on the weight of the product, the content of collagen peptide is 25 to 85% by weight, and the apparent density of the processed food is 0.2 to 0.7 g / cm 3. It is in processed food containing collagen components.
さらに、本発明は上記コラーゲン成分含有加工食品の製造方法であって、
a. ゼラチン及びコラーゲンペプチドを主要材料として含む組成物に水を加えて、固形分濃度が10〜40重量%となるような量を用いて加温することにより水に溶解させる工程、ここで、前記組成物中のゼラチンの含量が当該組成物の重量を基準に15〜45重量%及びコラーゲンペプチドの含量が25〜85重量%となるように組成物中に含有させ、
b. 得られた水溶液を、攪拌することにより水溶液中に気泡を形成する工程、ここで、得られる加工食品の見かけ密度が0.2〜0.7g/cm3となるようにする、
c. 得られた気泡を含む水溶液を当該水溶液の凝固点よりも1〜10℃高い温度に冷却する工程、
d. さらに冷却することにより得られたゲルを所定の形態に成形する工程、及び
e. 成形したゲルを乾燥する工程
を含む方法にある。
Furthermore, the present invention is a method for producing the processed collagen-containing processed food,
a. A step of adding water to a composition containing gelatin and a collagen peptide as main materials, and heating the composition using an amount such that the solid content concentration is 10 to 40% by weight, wherein the composition is dissolved in water; The gelatin content in the product is contained in the composition so that the content of the gelatin is 15 to 45% by weight based on the weight of the composition and the content of the collagen peptide is 25 to 85% by weight,
b. A step of forming bubbles in the aqueous solution by stirring the obtained aqueous solution, wherein the apparent density of the obtained processed food is 0.2 to 0.7 g / cm 3 ;
c. Cooling the obtained aqueous solution containing bubbles to a temperature 1 to 10 ° C. higher than the freezing point of the aqueous solution,
d. Further forming the gel obtained by cooling into a predetermined form, and e. The method includes a step of drying the formed gel.
以下、本発明の実施の形態についてさらに具体的に本発明について記載する。 Hereinafter, the present invention will be described more specifically with respect to embodiments of the present invention.
本発明で使用できるゼラチンは、牛皮、豚皮、牛骨、豚骨、魚皮、魚鱗等いずれの起源のゼラチンでも使用できる。市販品としては、ニッピ社製のデイリーゼラチンDB、デイリーゼラチンDG、デイリーゼラチンDPなどを使用することができる。ゼラチンをコラーゲンペプチドに加えることで、成形加工時および輸送、包装時に保形性を保つことができ、そのためにゲル化能が必要となる。ゲル化能の指標としてゼリー強度(JISK 6503)で判断することができ、ゼリー強度が高すぎるとゲルが成形しにくくなったり、加工食品の食感が硬すぎたりする問題が生じ、低すぎると保形性が悪くなる。したがって本発明で使用できるゼリー強度は、好ましくは、60〜320g(JIS K6503に準拠)であり、より好ましくは、70〜280gである。粘度が高いゼラチンは、コラーゲンペプチドと共に水に溶解させたとき高粘度液となるため、成形性が悪くなり、得られたコラーゲン加工食品が口腔内でべたつきやすく、粘度が低いものは、気泡を安定して含ませにくく、粘度2.0〜7.0mPa・s(JIS K6503に準拠)のものが好ましく、粘度2.5〜7.0mPa・sのものがより好ましく、2.5〜4.0mPa・sのものが最も好ましい。 As the gelatin that can be used in the present invention, gelatin of any origin such as cow skin, pig skin, cow bone, pig bone, fish skin, fish scale, etc. can be used. As commercially available products, Daily Gelatin DB, Daily Gelatin DG, Daily Gelatin DP, etc. manufactured by Nippi Co., Ltd. can be used. By adding gelatin to the collagen peptide, shape retention can be maintained during molding, transportation, and packaging, and thus gelation ability is required. Jelly strength (JISK 6503) can be determined as an index of gelling ability. If the jelly strength is too high, the gel is difficult to mold or the texture of the processed food is too hard. The shape retention becomes worse. Therefore, the jelly strength that can be used in the present invention is preferably 60 to 320 g (based on JIS K6503), and more preferably 70 to 280 g. Gelatin with high viscosity becomes a high-viscosity liquid when dissolved in water together with collagen peptide, resulting in poor moldability, and the resulting collagen processed food is easily sticky in the oral cavity. The viscosity is preferably 2.0 to 7.0 mPa · s (based on JIS K6503), more preferably 2.5 to 7.0 mPa · s, and more preferably 2.5 to 4.0 mPa · s. -S is most preferred.
本発明で使用できるコラーゲンペプチドは、コラーゲンの加水分解物であって、ゲル化能がないものである。牛皮、豚皮、牛骨、豚骨、魚皮、魚鱗等いずれの起源のコラーゲンペプチドでも使用できる。ニッピ社製、ニッピコラーゲン100、ニッピペプタイドFCP、ニッピペプタイドPRA-Pなどの市販品を使用することができる。 The collagen peptide that can be used in the present invention is a hydrolyzate of collagen and has no gelling ability. Collagen peptides of any origin such as cow skin, pig skin, cow bone, pig bone, fish skin, fish scale, etc. can be used. Commercially available products such as Nippi, Nippi Collagen 100, Nippi Peptide FCP, Nippi Peptide PRA-P can be used.
コラーゲンペプチドの製造方法は、特に限定されないが、例えば、特開昭52−111600号公報や特開昭52−122400号公報で公開されている方法が適用できる。特に限定されないが、コラーゲンペプチドの製造方法を以下に示す。 The method for producing the collagen peptide is not particularly limited, and for example, methods disclosed in Japanese Patent Application Laid-Open Nos. 52-111600 and 52-122400 can be applied. Although it does not specifically limit, the manufacturing method of a collagen peptide is shown below.
原料はコラーゲン成分を含むものであれば使用できる。例えば、魚の皮、鱗、豚の皮、牛の皮、骨、オセインまたはゼラチンを使用することができる。コラーゲン成分の含有量はできるだけ多いものが望ましく、水分を除いた固形分中のコラーゲン成分が80重量%以上であることが望ましい。コラーゲンを含む湿潤した生の原料(生の皮など)の場合、コラーゲンの変性温度以上に加熱(例えば、牛皮であれば60℃以上に加熱する)して使用する。加水分解の時間を短縮したい場合は、あらかじめ原料を細断しておいても良い。乾燥した状態の原料であれば、数時間〜数日の間、水に浸して水戻ししてから加熱変性させて使用する。骨や魚鱗の場合、塩酸を加えてリン酸カルシウムを溶解、除去(通常の骨ゼラチン製造工程の脱灰工程と同様)した後、水洗いしてから加熱変性させて使用する。固形の原料の場合は、撹拌できる程度に水を加えて分散液とすることで、酵素を効率よく作用させることができる。固形の原料より、ゼラチンの水溶液を基質として使用する方法が最も容易である。以上のような原料と水を含む分散液もしくはゼラチン水溶液を基質として、水溶液中のタンパク質含有量(乾燥重量)に対し、市販のタンパク質分解酵素(たとえばナガセサンバイオ社製ビオプラーゼSP、ノボ社製プロタメックスなど)を0.3〜3重量%加え、1〜10時間作用させることで加水分解する。pHと温度は使用した酵素の至適条件(通常の酵素製剤では、パンフレットに記載されている)を採択して行うことができる。加水分解後、85℃以上に加熱し、30分保持することで酵素を失活させ反応を停止させる。反応停止後、ろ過を行って原料の残滓を分離する。その際、珪藻土などのろ過助剤を使用することで精製度が上がる。脱色や脱臭のために活性炭のような吸着剤を使用しても良い。得られたろ過液を殺菌し、噴霧乾燥することによってコラーゲンペプチド乾燥粉末が得られる。 The raw material can be used as long as it contains a collagen component. For example, fish skin, scales, pig skin, cow skin, bone, ossein or gelatin can be used. The content of the collagen component is desirably as much as possible, and the collagen component in the solid content excluding moisture is desirably 80% by weight or more. In the case of a wet raw material containing collagen (raw skin, etc.), it is used after being heated to a temperature above the denaturation temperature of collagen (for example, heating to 60 ° C. or higher for cow skin). In order to shorten the hydrolysis time, the raw material may be shredded in advance. If it is a raw material in a dry state, it is immersed in water for several hours to several days and then used after being denatured by heating. In the case of bones and fish scales, hydrochloric acid is added to dissolve and remove calcium phosphate (similar to the decalcification process in the normal bone gelatin production process), then washed with water and then heat denatured before use. In the case of a solid raw material, the enzyme can be allowed to act efficiently by adding water to the extent that it can be stirred to form a dispersion. The method using an aqueous gelatin solution as a substrate is easier than a solid raw material. Using a dispersion containing the above raw materials and water or an aqueous gelatin solution as a substrate, the protein content (dry weight) in the aqueous solution is compared with a commercially available proteolytic enzyme (for example, Biolase SP manufactured by Nagasesan Bio, Pro It is hydrolyzed by adding 0.3 to 3% by weight of Tamex, etc.) and allowing it to act for 1 to 10 hours. The pH and temperature can be determined by adopting the optimum conditions for the enzyme used (in ordinary enzyme preparations, described in a pamphlet). After hydrolysis, the enzyme is deactivated by heating to 85 ° C. or higher and held for 30 minutes to stop the reaction. After stopping the reaction, the raw material residue is separated by filtration. At that time, the degree of purification is increased by using a filter aid such as diatomaceous earth. An adsorbent such as activated carbon may be used for decolorization and deodorization. The obtained filtrate is sterilized and spray-dried to obtain a collagen peptide dry powder.
コラーゲンペプチドの含有量や物理特性も口溶けや食感を左右する。コラーゲンペプチド選択の指標として、動粘度を使用することができる。したがって、動粘度を測定しさえすれば、本発明で使用可能か否かを容易に判断できる。動粘度測定方法を後述する実施例に示した。40℃における動粘度が5.0mm2/sを超えると、ゲル化能が生じ始めるため、歯つき、口溶けが悪くなり、好ましくない。動粘度が5.0mm2/s以下であれば使用でき、好ましくは、1.5〜4.1、最も好ましくは、2.0〜3.2の範囲である。動粘度が低い(低分子量)コラーゲンペプチドは呈味の悪いことが知られている。しかし、動粘度の低いコラーゲンペプチドをゼラチンと共に水に溶解させると、分子レベルで混合されるため(すなわち、ゼラチン及びコラーゲンペプチド双方とも水に溶解しているので均質に混合され、あたかも同一物質のように挙動する)、ゼラチンの相対的に大きな分子量が寄与し、平均分子量としては大幅に引き上げられ、呈味の悪さなどの低分子量コラーゲンペプチドの欠点を低減できる。 Collagen peptide content and physical properties also affect mouth melting and texture. Kinematic viscosity can be used as an indicator of collagen peptide selection. Therefore, as long as the kinematic viscosity is measured, it can be easily determined whether it can be used in the present invention. The kinematic viscosity measurement method is shown in the examples described later. When the kinematic viscosity at 40 ° C. exceeds 5.0 mm 2 / s, gelling ability starts to occur, so that toothing and melting in the mouth are deteriorated, which is not preferable. If kinematic viscosity is 5.0 mm < 2 > / s or less, it can be used, Preferably it is 1.5-4.1, Most preferably, it is the range of 2.0-3.2. Collagen peptides with low kinematic viscosity (low molecular weight) are known to have poor taste. However, when collagen peptides with low kinematic viscosity are dissolved in water together with gelatin, they are mixed at the molecular level (that is, both gelatin and collagen peptides are dissolved in water, so they are mixed homogeneously, as if they were the same substance. The relatively large molecular weight of gelatin contributes, the average molecular weight is greatly increased, and the disadvantages of low molecular weight collagen peptides such as poor taste can be reduced.
ゼラチン及びコラーゲンペプチドを主要材料として含む組成物中のゼラチンの含量は当該組成物の重量を基準に15〜45重量%、好ましくは、20〜40重量%、より好ましくは20〜35重量%であり、コラーゲンペプチドの含量は25〜85重量%であり、好ましくは、35〜85重量%、より好ましくは40〜65重量%である。ゼラチンとコラーゲンペプチドの含量に関して、ゼラチンが45重量%を超えると口溶け、歯つきが悪くなり、15重量%未満では成形しにくく、しかも製造した加工食品が脆くなり、取扱いが困難になるため好ましくない。コラーゲンペプチドは摂取効率が悪くならない範囲で、任意の含有量を採択でき、味付け、着色、芳香付け、加工性や食感改良のために加える添加剤の含有量によって変更できる。特許文献1に示されているように従来技術では25重量%以上含有すれば、摂取効率が良いとされているので好ましく、ゼラチンより含有量が多いものがより好ましい。本件発明では、添加剤を含有させない場合であれば、85重量%まで含有させることができる。 The content of gelatin in the composition containing gelatin and collagen peptide as main materials is 15 to 45% by weight, preferably 20 to 40% by weight, more preferably 20 to 35% by weight, based on the weight of the composition. The collagen peptide content is 25 to 85% by weight, preferably 35 to 85% by weight, more preferably 40 to 65% by weight. As for the content of gelatin and collagen peptide, if gelatin exceeds 45% by weight, the mouth melts and the teeth become worse, and if it is less than 15% by weight, it is difficult to mold, and the processed food produced becomes brittle and difficult to handle. . Collagen peptides can be selected in any content as long as the intake efficiency does not deteriorate, and can be changed depending on the content of additives added for seasoning, coloring, aromatization, processability and texture improvement. As shown in Patent Document 1, it is preferable that the content is 25% by weight or more in the prior art because it is considered that the intake efficiency is good, and more than gelatin is more preferable. In this invention, if it is a case where an additive is not contained, it can be contained to 85 weight%.
本発明の加工食品は、当該加工食品の重量を基準にゼラチンとコラーゲンペプチドとの合計量で40重量%以上、60重量%以上、80重量%以上、さらには100重量%含有させることができる。 The processed food of the present invention can be contained in a total amount of gelatin and collagen peptide of 40% by weight, 60% by weight, 80% by weight, or even 100% by weight based on the weight of the processed food.
ゼラチンのみで本発明の組成物を構成すると口内で溶解しにくく、摂取した時に歯つき、べたつきを引き起こすが、コラーゲンペプチドが多量に含まれていることで口溶けが良くなる。コラーゲンペプチドのみが組成物中に大量に含まれる場合、気泡を安定した状態で含ませることができず、上記の効果は得られない。 When the composition of the present invention is composed only of gelatin, it is difficult to dissolve in the mouth and causes toothing and stickiness when ingested. However, the presence of a large amount of collagen peptide improves mouth melting. When only a collagen peptide is contained in a large amount in the composition, bubbles cannot be contained in a stable state, and the above effect cannot be obtained.
本発明では、主要材料であるゼラチン及びコラーゲンペプチド以外に、本発明の組成物中に味付け、着色、芳香付け、加工性や食感改良のための添加剤を加えることができる。これらの目的を達成するためにいずれの添加剤でも使用できるが、例えば、香料、香辛料、調味料、食品添加物、増粘多糖類、果汁、ココア、コーヒー、緑茶や紅茶などの茶系エキス類、野菜、肉及び魚のエキスまたは粉末等がある。これらの添加剤の使用量は、主要材料の作用を害しない範囲で使用できるが、目的の加工食品に応じて適宜選択できる。 In the present invention, additives for seasoning, coloring, aromatization, processability and texture improvement can be added to the composition of the present invention in addition to gelatin and collagen peptides as the main materials. Any additive can be used to achieve these purposes. For example, flavorings, spices, seasonings, food additives, thickening polysaccharides, fruit juice, cocoa, coffee, green tea, tea and other tea-based extracts , Vegetable, meat and fish extracts or powders. The amount of these additives can be used within a range that does not impair the action of the main material, but can be appropriately selected according to the intended processed food.
本発明のゼラチン及びコラーゲンペプチドを主要材料として含む組成物に水を加えて、固形分濃度が10〜40重量%となるような量を用いて水を加温して溶解させることができる。10重量%未満では、気泡を含ませた状態でゲル化することが困難となり、40重量%を超えると粘度が高くなるので撹拌しにくく、気泡を形成することが困難になったり、ゲル化速度が上がったりするため成形しにくくなる問題が生じる。好ましくは、固形分濃度は20〜30重量%である。 Water can be dissolved by adding water to the composition containing gelatin and collagen peptide of the present invention as main materials, and using water in an amount such that the solid concentration is 10 to 40% by weight. If it is less than 10% by weight, it is difficult to gel in a state where bubbles are included, and if it exceeds 40% by weight, the viscosity becomes high, so it is difficult to stir, making it difficult to form bubbles, As a result, the problem that molding becomes difficult occurs. Preferably, the solid content concentration is 20-30% by weight.
本発明は、本発明の組成物を水に溶解させることにより得た水溶液を、攪拌することにより水溶液中に気泡を形成させる。気泡を形成するには、ミキサーやホモジナイザのような攪拌手段を使用することができる。気泡は微細なものである必要がある。溶液を撹拌して完全に透明感がなくなり、ミルク様に白濁し、滑らかなクリーム状になるまで撹拌する必要がある。後述する実施例に示した配合であればホモジナイザで実施例に示した条件で3分間撹拌すれば十分であるが仕込量を増やした場合には時間を延長するなどして適宜変更することができる。撹拌しながら冷水浴などによって、溶液の凝固点よりも1℃〜10℃高い温度まで撹拌しながら冷却し、さらに所望の形状の型に流し入れて冷蔵庫内でゲル化させる。冷却温度は好ましくは凝固点より4〜6℃高い温度である。凝固点測定方法を後述の実施例に示すが、あらかじめ溶液から少量抜き取り、凝固点を測定しておくとよい。凝固点に近い温度まで降温させると溶液の粘度が上昇し、気泡や添加した粉末などが安定した分散状態になり、型に流し入れることができる。凝固点以下の温度まで冷却すると型に流し込む前にゲル化してしまい、任意の形状に加工できない。凝固点より大幅に高い場合、型の中で粘度が低い溶液状態となり、さらにゲル化までに時間がかかるため、泡が上部に浮かんだり、添加物が沈澱したりして偏りが生じる。撹拌して泡立てた後はできるだけ速やかにゲル化させることが望ましい。特に限定されないが、冷却・ゲル化させる方法として、次のような態様がある。 In the present invention, bubbles are formed in an aqueous solution by stirring an aqueous solution obtained by dissolving the composition of the present invention in water. In order to form bubbles, a stirring means such as a mixer or a homogenizer can be used. Air bubbles need to be fine. It is necessary to stir the solution until it becomes completely transparent, becomes milky and becomes a smooth cream. In the case of the formulation shown in the examples described later, it is sufficient to stir for 3 minutes with the homogenizer under the conditions shown in the examples. However, when the amount charged is increased, it can be appropriately changed by extending the time. . The mixture is cooled with stirring to a temperature 1 ° C. to 10 ° C. higher than the freezing point of the solution by a cold water bath or the like, and poured into a mold having a desired shape to be gelled in a refrigerator. The cooling temperature is preferably 4 to 6 ° C. higher than the freezing point. The method for measuring the freezing point will be described in the following examples, but it is preferable to extract a small amount from the solution in advance and measure the freezing point. When the temperature is lowered to a temperature close to the freezing point, the viscosity of the solution increases, and bubbles and added powder become a stable dispersed state, which can be poured into a mold. When cooled to a temperature below the freezing point, it gels before pouring into the mold and cannot be processed into an arbitrary shape. When the temperature is significantly higher than the freezing point, a solution state having a low viscosity is formed in the mold, and further time is required for gelation. As a result, bubbles are floated on the top and additives are precipitated, resulting in unevenness. After stirring and foaming, it is desirable to gel as quickly as possible. Although it does not specifically limit, there exists the following aspects as a method of cooling and gelatinizing.
1)溶液を入れる型をあらかじめ10℃以下に冷やしておき、5mm以下に薄く流し込むことによって、速やかに凝固点以下に冷却され、シート状ゲルに加工できる。
2)任意の厚さのスリットを通して、冷却した金属製の回転ドラム上に塗布し、引き剥がすことで、連続的にシート状ゲルとして加工することができる。
1)または2)の方法で得たシート状ゲルを、任意の形状に型抜きすることができる。
1) The mold into which the solution is put is cooled in advance to 10 ° C. or less and poured into a thickness of 5 mm or less, so that it can be quickly cooled below the freezing point and processed into a sheet-like gel.
2) It can be continuously processed into a sheet-like gel by applying it on a cooled metal rotating drum through a slit having an arbitrary thickness and peeling it off.
The sheet-like gel obtained by the method 1) or 2) can be punched into an arbitrary shape.
成形後の形状で厚みが1cm以上あるものは、乾燥に時間がかかり、経口摂取時に咀嚼しにくくなるため好ましくない。好ましくは、3〜5mmの厚さである。乾燥はゼラチンの乾燥工程でも使用されているような、バンド乾燥機を使用できる。すなわち成形したゲルを網にのせ、融点未満(ゲルが溶融しない温度、たとえば凝固点を採用しても良い)に調節した除湿空気を送り、水分を12%以下まで低減させる。味付けで加えるエキスや粉末の比重に左右されるが、泡だてしないでそのまま乾燥した場合の見かけの密度は1g/cm3であり、気泡を含んでいる分これより小さい数値となる。上述したように本発明の組成物の水溶液を、ミキサーやホモジナイザを使用すれば、容易に均一で微細な気泡を含ませることができ、見かけの密度は0.2〜0.7/cm3とすることができる。具体的な配合例を後述の実施例に示す。0.7g/cm3を超えると気泡が不均一で本発明の効果は得られない。0.2g/cm3未満では、気泡が多すぎてもろくなり加工が困難となる。コラーゲンペプチドを減らし、ゼラチンの割合を増やした場合は、気泡の安定性が増すため0.2g/cm3未満とすることができるが、歯つき、口溶けが悪くなるため好ましくない。 A shape with a thickness of 1 cm or more after molding is not preferable because it takes time to dry and it becomes difficult to chew when taken orally. Preferably, the thickness is 3 to 5 mm. For drying, a band dryer, which is also used in the gelatin drying process, can be used. That is, the molded gel is placed on a net, and dehumidified air adjusted to a temperature lower than the melting point (a temperature at which the gel does not melt, for example, a freezing point may be adopted) is sent to reduce the moisture to 12% or less. Although it depends on the specific gravity of the extract or powder added by seasoning, the apparent density when dried as it is without foaming is 1 g / cm 3 , which is smaller than this because it contains bubbles. As described above, if an aqueous solution of the composition of the present invention is used with a mixer or a homogenizer, uniform and fine bubbles can be easily included, and the apparent density is 0.2 to 0.7 / cm 3 . can do. Specific blending examples are shown in the examples described later. If it exceeds 0.7 g / cm 3 , the bubbles are not uniform and the effect of the present invention cannot be obtained. If it is less than 0.2 g / cm 3 , even if there are too many bubbles, it becomes brittle and processing becomes difficult. When the collagen peptide is reduced and the ratio of gelatin is increased, the stability of the bubbles is increased, so that it can be set to less than 0.2 g / cm 3 , but this is not preferable because toothing and mouth melting worsen.
乾燥後の成形物は空気輸送、コンベア輸送に耐える強度をもつので、製品の輸送、包装などの取り扱いが容易となる。 Since the dried molded product has a strength that can withstand pneumatic transportation and conveyor transportation, it can be easily handled such as transportation and packaging of products.
本発明の加工食品は、アミノ酸摂取用や、美容用健康食品として直接摂取を目的としたフレーク、バー、せんべい、ビスケット、チップス、クラッカー、ポン菓子、クルトン状のスナック菓子や、可食性容器、たとえばアイスクリームやソフトクリームのコーン部、モナカの皮、パニプリ、ウエハース等の広範囲の食品に使用できる。 Processed foods of the present invention are flakes, bars, rice crackers, biscuits, chips, crackers, pon confectionery, crouton-shaped snack confectionery, edible containers such as ice cream for the purpose of ingesting amino acids and directly as beauty health foods. It can be used for a wide range of foods such as cream and soft cream cones, monaca peel, panipuri, and wafers.
以下、実施例により本発明を更に具体的に説明するが、本発明はこれらに限定されるものではない。実施例を説明するのに先立ち、本発明で使用している動粘度および凝固点の測定方法について述べる。 EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited thereto. Prior to describing the examples, a method for measuring kinematic viscosity and freezing point used in the present invention will be described.
<動粘度測定方法>
コラーゲンペプチド粉末5gを水25mLに溶解した液を検液とし、それを毛細管粘度計(ウベローデ型粘度計、オストワルド型粘度計などの市販品を使用することができる)にその粘度計の使用方法に従った一定量(たとえば、ウベローデ型粘度計の場合、液受け部の標線の下限と上限の間に液面がくればよい)を入れ、40℃に保温した恒温槽に粘度計ごと垂直に静置し、検液が40℃に達したあとで流下時間を測定し、式(1)に従って動粘度を算出する。詳細な試験方法は、食品添加物公定書第8版、一般試験法28.粘度測定法に準拠する。
<Kinematic viscosity measurement method>
A solution obtained by dissolving 5 g of collagen peptide powder in 25 mL of water is used as a test solution, and this is used as a capillary viscometer (commercially available products such as Ubbelohde viscometer and Ostwald viscometer can be used). Put a certain amount (for example, in the case of Ubbelohde viscometer, the liquid level should be between the lower limit and upper limit of the liquid receiving part), and put the viscometer vertically in a thermostatic bath kept at 40 ° C. Allow to stand, measure the flow down time after the test solution reaches 40 ° C., and calculate the kinematic viscosity according to the equation (1). The detailed test method is as follows. Conforms to viscosity measurement method.
<凝固点測定方法>
100mLのビーカーに検液を30〜50mL入れ、ビーカーの溶液が入っている部分を10〜20℃の冷水に浸す。温度計を入れ、連続的に撹拌する。凝固点より高い温度ではほとんど抵抗なく撹拌できる。凝固点となるとゲル化するため、撹拌を一時的に止めると撹拌方向と逆の方向に液が動く。この状態になったときの温度を読み取り、凝固点とする。
<Method of measuring freezing point>
30 to 50 mL of the test solution is placed in a 100 mL beaker, and the portion containing the beaker solution is immersed in cold water at 10 to 20 ° C. Put thermometer and stir continuously. Stirring can be carried out almost without resistance at temperatures higher than the freezing point. Since gelation occurs at the freezing point, the liquid moves in the direction opposite to the stirring direction when stirring is temporarily stopped. The temperature at which this state is reached is read and used as the freezing point.
コラーゲン加工食品を製造する際、例えば、本発明のa)工程で得られる原料水溶液を一部抜き取り、あらかじめ凝固点を測定しておけば、気泡を形成させた後の冷却温度の目安を定めることができる。以下に述べる実施例1〜14、比較例1〜6でも気泡形成前に凝固点を測定し、冷却温度の目安とした。 When producing a collagen processed food, for example, if a part of the raw material aqueous solution obtained in step a) of the present invention is extracted and the freezing point is measured in advance, a guideline for the cooling temperature after forming bubbles can be determined. it can. In Examples 1 to 14 and Comparative Examples 1 to 6 described below, the freezing point was measured before the formation of bubbles, and used as a guideline for the cooling temperature.
(実施例1)
牛皮由来ゼラチン(ゼリー強度277g、粘度3.5mPa・s)8g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)8g、グラニュー糖4gを200mLのビーカーに秤量して混合し、それに水64mLを加えて室温で30分間膨潤後、60℃に加温・撹拌して溶解した。得られた溶液にバニラエッセンスを5滴加え、ホモジナイザ(ヤマト科学社製、ULTRA-DISPERSER MODEL LK-41)を用い、ホモジナイザ付属のスピードコントローラの目盛を50%に設定し、3分間処理して、気泡を形成し、得られた気泡包含液の入ったビーカーを17℃の水浴に浸して継続的に撹拌して、液を30℃まで冷却後、3mm厚さのシート成形用の型に流し込んだ。冷蔵庫内で30分間静置して得られたシート状ゲルを、直径25mmの丸型で打ち抜き、円盤状のゲルを成形した。それらを網に乗せ、乾燥機内で除湿された27℃の空気で一晩乾燥し、さらに、55℃で1時間加温して乾燥することで、円盤状バニラ味の加工食品を得た。
Example 1
Cow skin-derived gelatin (jelly strength 277 g, viscosity 3.5 mPa · s) 8 g, pig skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 8 g, and granulated sugar 4 g were weighed into a 200 mL beaker and mixed with water. After adding 64 mL and swelling at room temperature for 30 minutes, it was dissolved by heating and stirring to 60 ° C. Add 5 drops of vanilla essence to the resulting solution, use a homogenizer (manufactured by Yamato Kagaku, ULTRA-DISPERSER MODEL LK-41), set the scale of the speed controller attached to the homogenizer to 50%, and treat for 3 minutes. Bubbles were formed, and the resulting beaker containing the bubble-containing liquid was immersed in a water bath at 17 ° C. and continuously stirred. The solution was cooled to 30 ° C. and then poured into a 3 mm-thick sheet mold. . The sheet-like gel obtained by standing for 30 minutes in the refrigerator was punched out with a round shape having a diameter of 25 mm to form a disc-like gel. They were placed on a net, dried overnight in air at 27 ° C. dehumidified in a dryer, and further heated at 55 ° C. for 1 hour to dry, thereby obtaining a processed food with a disk-like vanilla taste.
(実施例2)
牛皮由来ゼラチン(ゼリー強度277g、粘度3.5mPa・s)4g、コラーゲンペプチド(動粘度2.2mm2/s)12g、グラニュー糖4gを混合し、水30mLを加えて室温で膨潤させ、それ以後は実施例1と同様の製造工程によってバニラ味の加工食品を得た。
(Example 2)
Cow skin derived gelatin (jelly strength 277 g, viscosity 3.5 mPa · s) 4 g, collagen peptide (kinematic viscosity 2.2 mm 2 / s) 12 g, granulated sugar 4 g are mixed, 30 mL of water is added and swollen at room temperature, and thereafter Obtained the processed food of vanilla taste by the manufacturing process similar to Example 1.
(実施例3)
牛皮由来ゼラチン(ゼリー強度277g、粘度3.5mPa・s)6g、コラーゲンペプチド(動粘度2.2mm2/s)10gに水48mLを加えて30分膨潤後、60℃で溶解した。カレー粉2gを混ぜて実施例1と同様の条件でホモジナイザを用いて3分間処理して気泡を形成し、得られた気泡包含液の入ったビーカーを17℃の水浴に浸して継続的に撹拌して、液を29℃まで冷却後、3mm厚のシート成形用の型に流し込んだ。冷蔵庫内で30分間静置して得られたシート状ゲルを、5mm幅で長さ7cmに切断し、棒状のゲルを得た。それらを網に乗せ、乾燥機内で除湿された27℃の空気で一晩乾燥し、さらに、55℃、1時間加温して乾燥することで棒状のカレー味の加工食品を得た。
(Example 3)
48 g of water was added to 6 g of cowhide-derived gelatin (jelly strength 277 g, viscosity 3.5 mPa · s) and collagen peptide (kinematic viscosity 2.2 mm 2 / s) 10 g, and the mixture was swollen for 30 minutes and then dissolved at 60 ° C. 2 g of curry powder was mixed and treated with a homogenizer for 3 minutes under the same conditions as in Example 1 to form bubbles. The resulting beaker containing the bubble-containing liquid was immersed in a water bath at 17 ° C. and continuously stirred. Then, after cooling the liquid to 29 ° C., it was poured into a 3 mm thick sheet molding die. A sheet-like gel obtained by allowing to stand for 30 minutes in a refrigerator was cut to a length of 7 cm with a width of 5 mm to obtain a rod-like gel. They were placed on a net, dried overnight at 27 ° C. air dehumidified in a dryer, and further heated at 55 ° C. for 1 hour to dry to obtain a processed food with a rod-like curry taste.
(実施例4)
魚鱗由来ゼラチン(ゼリー強度77g、粘度2.5mPa・s)8g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)9g、グラニュー糖4g、水48mLを加えて30分膨潤し、60℃に加温して溶解後、緑茶粉末を0.5g加えた。それ以後は、冷却時の液温を26℃、乾燥空気の温度を25℃とした以外は、実施例1と同様の製造方法にて、円盤状の緑茶味の加工食品を得た。
Example 4
Fish scale-derived gelatin (jelly strength 77 g, viscosity 2.5 mPa · s) 8 g, pig skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 9 g, granulated sugar 4 g, and water 48 mL were added and swollen for 30 minutes, 60 ° C. After heating to dissolve, 0.5 g of green tea powder was added. Thereafter, a disk-shaped green tea-flavored processed food was obtained by the same production method as in Example 1 except that the liquid temperature during cooling was 26 ° C. and the temperature of dry air was 25 ° C.
(実施例5)
牛皮由来ゼラチン(ゼリー強度277g、粘度3.5mPa・s)8g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)8g、水48mLを加えて30分膨潤後、60℃で溶解した。焼そばソース10mLを混ぜ、それ以後は実施例1と同様にして、円盤状の焼そば味の加工食品を得た。
(Example 5)
8 g of cowhide-derived gelatin (jelly strength 277 g, viscosity 3.5 mPa · s), 8 g of pig skin-derived collagen peptide (dynamic viscosity 2.2 mm 2 / s) and 48 mL of water were added and swollen for 30 minutes, and then dissolved at 60 ° C. 10 mL of yakisoba sauce was mixed, and thereafter, a disk-shaped processed food with yakisoba taste was obtained in the same manner as in Example 1.
(実施例6)
牛皮由来ゼラチン(ゼリー強度277g、粘度3.5mPa・s)8g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)8g、グラニュー糖4gに水48mLを加えて30分膨潤後、60℃に加温して溶解した。味噌5gを混ぜ、それ以後は実施例1と同様にして、円盤状の味噌味の加工食品を得た。
(Example 6)
Cow skin-derived gelatin (jelly strength 277 g, viscosity 3.5 mPa · s) 8 g, pig skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 8 g, granulated sugar 4 g with 48 mL of water and swollen for 30 minutes, then 60 ° C. And dissolved by heating. After 5 g of miso was mixed, a disk-shaped processed food with miso taste was obtained in the same manner as in Example 1.
(実施例7)
牛骨ゼラチン(ゼリー強度165g、粘度3.8mPa・s)3g、魚鱗由来コラーゲンペプチド(動粘度3.2mm2/s)17gを混合し、水30mLを加えて30分間膨潤し、60℃に加温して溶解し、それ以後、冷却温度を34℃とした以外は実施例1と同様に加工して無味の円盤状加工食品を得た。
(Example 7)
Beef bone gelatin (jelly strength 165 g, viscosity 3.8 mPa · s) 3 g and fish scale-derived collagen peptide (kinematic viscosity 3.2 mm 2 / s) 17 g are mixed, 30 mL of water is added and swollen for 30 minutes and heated to 60 ° C. It melted by warming, and thereafter processed in the same manner as in Example 1 except that the cooling temperature was set to 34 ° C. to obtain a tasteless disk-shaped processed food.
(実施例8)
牛骨ゼラチン(ゼリー強度165g、粘度3.8mPa・s)6g、魚鱗由来コラーゲンペプチド(動粘度1.5mm2/s、オリが発生し、呈味が悪い)10g、キシリトール4g、緑茶粉末0.5gを混合し、水48mLを加えて30分間膨潤し、60℃に加温し、実施例3と同様に加工して、緑茶味の棒状加工食品を得た。
(Example 8)
Beef bone gelatin (jelly strength 165 g, viscosity 3.8 mPa · s) 6 g, fish scale-derived collagen peptide (kinematic viscosity 1.5 mm 2 / s, odor generated, poor taste) 10 g, xylitol 4 g, green tea powder 0. 5 g was mixed, 48 mL of water was added and swollen for 30 minutes, heated to 60 ° C., and processed in the same manner as in Example 3 to obtain a green tea-flavored stick-shaped processed food.
(実施例9)
牛骨由来ゼラチン(ゼリー強度165g、粘度3.8mPa・s)8g、魚鱗由来コラーゲンペプチド(動粘度4.1mm2/s)8g、グラニュー糖4gに水64mLを加え、30分間膨潤し、60℃に加温して溶解し、冷却温度を35℃とした以外は実施例1と同様に加工して円盤状バニラ味の加工食品を得た。
Example 9
Beef bone-derived gelatin (jelly strength 165 g, viscosity 3.8 mPa · s) 8 g, fish scale-derived collagen peptide (kinematic viscosity 4.1 mm 2 / s) 8 g, granulated sugar 4 g was added with 64 mL of water, swollen for 30 minutes, 60 ° C. Was processed in the same manner as in Example 1 except that the cooling temperature was 35 ° C., and a processed food with a disc-like vanilla taste was obtained.
(実施例10)
魚皮由来ゼラチン(ゼリー強度260g、粘度7mPa・s)8gと魚鱗由来コラーゲンペプチド(動粘度3.2mm2/s)8g、グラニュー糖4gを混合し、水48mLを加え、30分間膨潤し、60℃に加温して溶解し、冷却温度を34℃とした以外は、実施例1と同様に加工してバニラ味の円盤状加工食品を得た。
(実施例11)
牛骨由来ゼラチン(ゼリー強度314g、粘度3.3mPa・s)7gと豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)8.5g、インスタントコーヒー0.5g、グラニュー糖4gを混合し、水64mLを加え、30分間膨潤し、60℃に加温して溶解し、冷却温度を28℃とした以外は、実施例1と同様に加工してコーヒー味の円盤状加工食品を得た。
(Example 10)
8 g of fish skin-derived gelatin (jelly strength: 260 g, viscosity: 7 mPa · s), 8 g of fish scale-derived collagen peptide (kinematic viscosity: 3.2 mm 2 / s) and 4 g of granulated sugar are mixed, added with 48 mL of water, swelled for 30 minutes, 60 A vanilla-flavored disc-shaped processed food was obtained by processing in the same manner as in Example 1 except that the solution was heated to 0 ° C. for dissolution and the cooling temperature was 34 ° C.
(Example 11)
Beef bone-derived gelatin (jelly strength 314 g, viscosity 3.3 mPa · s) 7 g, pork skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 8.5 g, instant coffee 0.5 g, granulated sugar 4 g, 64 mL of water was added, swelled for 30 minutes, heated to 60 ° C. to dissolve, and processed in the same manner as in Example 1 except that the cooling temperature was changed to 28 ° C. to obtain a discoid processed food with a coffee taste.
(実施例12)
牛骨由来ゼラチン(ゼリー強度165g、粘度3.8mPa・s)3.5g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)5g、カラギーナン(SATIAGEL BWJ40(SKWバイオシステムズ株式会社製))1g、一味唐辛子粉末0.5gに水90mLを加え、30分間膨潤し、65℃に加温して溶解し、冷却温度を36℃とした以外は実施例1と同様に加工して円盤状とうがらし味の加工食品を得た。
(Example 12)
Cattle bone-derived gelatin (jelly strength 165 g, viscosity 3.8 mPa · s) 3.5 g, pig skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 5 g, carrageenan (SATIAGEL BWJ40 (manufactured by SKW Biosystems)) 1 g, 90 g of water to 0.5 g of cinnamon pepper powder, swollen for 30 minutes, heated to 65 ° C. to dissolve, and processed in the same manner as in Example 1 except that the cooling temperature was set to 36 ° C. A taste processed food was obtained.
(実施例13)
牛骨由来ゼラチン(ゼリー強度165g、粘度3.8mPa・s)5g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)10g、カラギーナン(SATIAGEL BWJ40(SKWバイオシステムズ株式会社製))1g、グラニュー糖2g、粉末わさび2gに水80mLを加え、30分間膨潤し、65℃に加温して溶解し、冷却温度を44℃とした以外は実施例1と同様に加工して円盤状わさび味の加工食品を得た。
(Example 13)
Cattle bone-derived gelatin (jelly strength 165 g, viscosity 3.8 mPa · s) 5 g, pig skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 10 g, carrageenan (SATIAGEL BWJ40 (manufactured by SKW Biosystems)) 1 g, Add 80 mL of water to 2 g of granulated sugar and 2 g of powdered wasabi, swell for 30 minutes, dissolve by heating to 65 ° C., and process in the same manner as in Example 1 except that the cooling temperature is 44 ° C. Of processed food.
(実施例14)
牛骨由来ゼラチン(ゼリー強度165g、粘度3.8mPa・s)5g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)10g、寒天(SAI-7,台糖株式会社製)1g、グラニュー糖4gに水64mLを加え、30分間膨潤し、85℃に加温して溶解し、冷却温度を31℃とした以外は実施例1と同様に加工して円盤状バニラ味の加工食品を得た。
(Example 14)
Beef bone-derived gelatin (jelly strength 165 g, viscosity 3.8 mPa · s) 5 g, pig skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 10 g, agar (SAI-7, manufactured by Taiwan Sugar Co., Ltd.) 1 g, granulated sugar 64 g of water was added to 4 g, swelled for 30 minutes, heated to 85 ° C. to dissolve, and processed in the same manner as in Example 1 except that the cooling temperature was 31 ° C. to obtain a processed food with a disk-like vanilla taste .
(比較例1)
牛皮由来ゼラチン(ゼリー強度277g、粘度3.5mPa・s)10gに水80mLを加え、30分間膨潤し、60℃に加温して溶解し、それ以後は実施例1と同様に加工し、加工食品を得た。
(Comparative Example 1)
80 g of water is added to 10 g of cowhide-derived gelatin (jelly strength: 277 g, viscosity: 3.5 mPa · s), swollen for 30 minutes, heated to 60 ° C. to dissolve, and thereafter processed in the same manner as in Example 1. Got food.
(比較例2)
カラギーナン(SATIAGEL BWJ40(SKWバイオシステムズ株式会社製))0.5g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)10g、グラニュー糖4gに水48mLを加え、30分間膨潤し、80℃に加温して溶解し、冷却温度を50℃とする以外は、実施例1と同様に加工して円盤状のバニラ味の加工食品を試作しようとしたが、乾燥機から取り出す際、すべて粉々に破損し、目的とする円盤状には成形できなかった。
(Comparative Example 2)
Carrageenan (SATIAGEL BWJ40 (manufactured by SKW Biosystems)) 0.5 g, pork skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 10 g, granulated sugar 4 g is added with 48 mL of water, swollen for 30 minutes, 80 ° C. The sample was processed in the same manner as in Example 1 except that it was dissolved by heating to a cooling temperature of 50 ° C., and an attempt was made to produce a disk-shaped vanilla-flavored processed food. And could not be formed into the desired disk shape.
(比較例3)
寒天(SAI-7,台糖株式会社製)2g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)10g、グラニュー糖4gに水48mLを加え、30分間膨潤し、85℃に加温して溶解し冷却温度45℃とする以外は実施例1と同様にして円盤状のバニラ味の加工食品を試作したが、溶液の粘度が高く、気泡の形成性が悪かった。また、得られたゲルが柔らかく、型抜きすることができなかったので、成形型に乗せたまま乾燥して食感などを評価した。
(Comparative Example 3)
Add 48 mL of water to 2 g of agar (SAI-7, manufactured by Taiyo Co., Ltd.), 10 g of porcine skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s), 4 g of granulated sugar, swell for 30 minutes, and warm to 85 ° C. A disc-shaped processed food with vanilla taste was made in the same manner as in Example 1 except that it was dissolved and the cooling temperature was 45 ° C., but the viscosity of the solution was high and the foam formation was poor. Moreover, since the gel obtained was soft and could not be removed from the mold, it was dried while placed on a mold and evaluated for texture and the like.
(比較例4)
カラギーナン(SATIAGEL BWJ40、SKWバイオシステムズ株式会社製)1g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)10g、グラニュー糖4gに水48mLを加え30分間膨潤し、80℃に加温して溶解し、冷却温度50℃とする以外は実施例1と同様に加工して、円盤状バニラ味の加工食品を試作したが、溶液粘度が高く、安定した気泡形成ができなかった。そのまま型に流し、型抜きして乾燥したが、乾燥後は極めて脆く、取り出す際に割れてしまい目的とする形状の加工食品を得ることができなかった。
(Comparative Example 4)
Carrageenan (SATIAGEL BWJ40, manufactured by SKW Biosystems Co., Ltd.) 1 g, pork skin-derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 10 g, granulated sugar 4 g with 48 mL of water, swell for 30 minutes, and warm to 80 ° C. A processed food with a disk-like vanilla taste was made as a prototype by processing in the same manner as in Example 1 except that the cooling temperature was 50 ° C., but the solution viscosity was high and stable bubble formation was not possible. The product was poured into a mold as it was, and the mold was cut and dried. However, after drying, it was extremely brittle and cracked when taken out, so that a processed food with the desired shape could not be obtained.
(比較例5)
牛皮由来ゼラチン(ゼリー強度277g、粘度3.5mPa・s)2g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)14g、グラニュー糖4gに水30mLを加え、30分間膨潤し、60℃に加温して溶解し、実施例1と同様にして加工食品を試作したが、ゲル化が不十分で型抜きできず、目的とする円盤状コラーゲン加工食品に成形できなかった。
(Comparative Example 5)
Add 30 ml of water to cow skin derived gelatin (jelly strength 277 g, viscosity 3.5 mPa · s) 2 g, pig skin derived collagen peptide (kinematic viscosity 2.2 mm 2 / s) 14 g, granulated sugar 4 g, swell for 30 minutes, 60 ° C. The processed food was prototyped in the same manner as in Example 1, but the gelation was insufficient and the mold could not be punched, and could not be formed into the intended discoid collagen processed food.
(比較例6)
牛皮由来ゼラチン(ゼリー強度277g、粘度3.5mPa・s)6g、豚皮由来コラーゲンペプチド(動粘度2.2mm2/s)10g、グラニュー糖4gに水48mLを加え、30分膨潤後、60℃に加温して溶解した。気泡を形成せずにそのまま3mm厚さのシート成形用の型に流し込み、冷蔵庫でゲル化させた後、直径25mmに打ち抜き、網に乗せ、乾燥機内で除湿された27℃の空気を送り一晩乾燥後、55℃で1時間加温して乾燥することにより円盤状のバニラ味の加工食品を得た。
(Comparative Example 6)
Add 48 ml of water to 6 g of cow skin-derived gelatin (jelly strength 277 g, viscosity 3.5 mPa · s), 10 g of pig skin-derived collagen peptide (dynamic viscosity 2.2 mm 2 / s), 4 g of granulated sugar, swell for 30 minutes, and then 60 ° C. And dissolved by heating. Pour into a 3mm thick sheet mold without forming bubbles, gel in a refrigerator, punch out to 25mm diameter, place on a net, and send dehumidified 27 ° C air in the dryer overnight After drying, it was heated at 55 ° C. for 1 hour and dried to obtain a disk-like processed food with vanilla taste.
<評価>
表1に、各実施例及び比較例のゼラチン、コラーゲンペプチド及びその他の添加剤の配合割合、加えた水の量、固形分濃度、本発明のa)工程で得られる水溶液の凝固点(比較例の場合も同様の操作で得られる水溶液の凝固点)並びに冷却温度を示す。
<Evaluation>
Table 1 shows the blending ratio of gelatin, collagen peptide and other additives in each Example and Comparative Example, the amount of added water, the solid content concentration, and the freezing point of the aqueous solution obtained in the step a) of the present invention (of Comparative Example). In this case, the freezing point of the aqueous solution obtained by the same operation) and the cooling temperature are also shown.
実施例1〜14、比較例1〜6について、気泡形成性、型抜き性、乾燥品の保型性についての加工適性と、におい、食味、口溶け、歯つき、食感についての官能試験を行った結果を表2に示す。実施例1〜11で示したコラーゲン加工食品は、ほとんどの成分が、コラーゲン由来であるゼラチンとコラーゲンペプチドから構成され、得られたものは、元のゼラチンやコラーゲンペプチドの臭いや味が目立たず、容易に成形でき、摂取時の口解けが良く、歯つきが少ない特徴を有していた。これに対し、ゼラチンをカラギーナン、寒天等の増粘多糖類に置き換えた場合は、比較例2、3に示したように添加量が少ないと脆くなるため成形できず、比較例4に示したように添加量を多くすると、溶液粘度が上がるため気泡形成性が悪かった。また、これらの増粘多糖類を使用した製品は、経口内での口解けが悪く、歯につきやすいものとなった。ただし、実施例12〜14で示したように、ゲル化成分として増粘多糖類のみではなくゼラチンを併用することによって、加工適性、口解け、歯つきが改善され、コラーゲン加工食品を製造することができた。実施例12、13のカラギーナンを併用したものはサクサクとした食感となり、実施例14の寒天を併用したものはパリパリとした硬めの食感となった。比較例1のゼラチンのみで構成した場合や、比較例6の気泡を形成しない場合もコラーゲン由来の素材を主成分とした食品となるが、歯つきがひどく、ゼラチン独特の動物臭が目立ち、実用的ではなかった。比較例5のように、ゼラチンの割合を減らした場合はゲル、乾燥品いずれも強度的な問題が生じた。 For Examples 1 to 14 and Comparative Examples 1 to 6, sensory tests were conducted on foamability, mold release properties, processing suitability for dry product shape retention, odor, taste, mouth melt, toothing, and texture. The results are shown in Table 2. The processed collagen foods shown in Examples 1 to 11 are mostly composed of gelatin and collagen peptides derived from collagen, and the resulting products are inconspicuous in the odor and taste of the original gelatin and collagen peptides, It was easy to mold, had good mouthfeel when ingested, and had less teeth. On the other hand, when gelatin was replaced with thickening polysaccharides such as carrageenan and agar, as shown in Comparative Examples 2 and 3, when the addition amount was small, it became brittle and could not be molded. As shown in Comparative Example 4 When the amount added was increased, the viscosity of the solution increased, and the bubble formation was poor. In addition, products using these thickening polysaccharides have poor oral digestion and are easy to touch. However, as shown in Examples 12 to 14, by using not only thickening polysaccharides but also gelatin as a gelling component, processability, melting, and toothing are improved, and a processed collagen food is produced. I was able to. The combination of the carrageenan of Examples 12 and 13 resulted in a crisp texture, and the combination of agar in Example 14 resulted in a crisp and firm texture. Even when it is composed of only the gelatin of Comparative Example 1 or when the bubbles of Comparative Example 6 are not formed, it is a food mainly composed of a collagen-derived material, but its teeth are severe and the animal odor peculiar to gelatin is conspicuous and practical. It was not right. As in Comparative Example 5, when the ratio of gelatin was reduced, both the gel and the dried product had a problem of strength.
Claims (4)
a. ゼラチン及びコラーゲンペプチドを主要材料として含む組成物に水を加えて、固形分濃度が10〜40重量%となるような量を用いて加温することにより水に溶解させる工程、ここで、前記組成物中のゼラチンの含量が当該組成物の重量を基準に15〜45重量%及びコラーゲンペプチドの含量が25〜85重量%となるように組成物中に含有させ、
b. 得られた水溶液を、攪拌することにより水溶液中に気泡を形成する工程、ここで、得られる加工食品の見かけ密度が0.2〜0.7g/cm3となるようにする、
c. 得られた気泡を含む水溶液を当該水溶液の凝固点よりも1〜10℃高い温度に冷却する工程、
d. さらに冷却することにより得られるゲルを所定の形態に成形する工程、及び
e. 成形したゲルを乾燥する工程
を含む、前記加工食品の製造方法。 A method for producing a collagen component-containing processed food according to any one of claims 1 to 3, wherein the method comprises: a. A step of adding water to a composition containing gelatin and a collagen peptide as main materials, and heating the composition using an amount such that the solid content concentration is 10 to 40% by weight, wherein the composition is dissolved in water; The gelatin content in the product is contained in the composition so that the content of the gelatin is 15 to 45% by weight based on the weight of the composition and the content of the collagen peptide is 25 to 85% by weight,
b. A step of forming bubbles in the aqueous solution by stirring the obtained aqueous solution, wherein the apparent density of the obtained processed food is 0.2 to 0.7 g / cm 3 ;
c. Cooling the obtained aqueous solution containing bubbles to a temperature 1 to 10 ° C. higher than the freezing point of the aqueous solution,
d. Further forming the gel obtained by cooling into a predetermined form, and e. The manufacturing method of the said processed food including the process of drying the shape | molded gel.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101078260B1 (en) * | 2003-04-04 | 2011-10-31 | 스가쓰네 고우교 가부시키가이샤 | Device for holding a state of opening an opening and closing member |
CN107692226A (en) * | 2017-07-10 | 2018-02-16 | 杨宇 | A kind of collagen leisure food and preparation method thereof |
JP2021533807A (en) * | 2018-08-22 | 2021-12-09 | ゲリタ アクチェンゲゼルシャフト | Protein bar |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101078260B1 (en) * | 2003-04-04 | 2011-10-31 | 스가쓰네 고우교 가부시키가이샤 | Device for holding a state of opening an opening and closing member |
CN107692226A (en) * | 2017-07-10 | 2018-02-16 | 杨宇 | A kind of collagen leisure food and preparation method thereof |
JP2021533807A (en) * | 2018-08-22 | 2021-12-09 | ゲリタ アクチェンゲゼルシャフト | Protein bar |
JP7445646B2 (en) | 2018-08-22 | 2024-03-07 | ゲリタ アクチェンゲゼルシャフト | protein bar |
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