JP2010515568A5 - - Google Patents
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- JP2010515568A5 JP2010515568A5 JP2009545624A JP2009545624A JP2010515568A5 JP 2010515568 A5 JP2010515568 A5 JP 2010515568A5 JP 2009545624 A JP2009545624 A JP 2009545624A JP 2009545624 A JP2009545624 A JP 2009545624A JP 2010515568 A5 JP2010515568 A5 JP 2010515568A5
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- JP
- Japan
- Prior art keywords
- zeolite
- catalyst
- modified
- bulk
- molar ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000010457 zeolite Substances 0.000 claims 14
- 239000003054 catalyst Substances 0.000 claims 6
- 229910052782 aluminium Inorganic materials 0.000 claims 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 4
- 238000002441 X-ray diffraction Methods 0.000 claims 2
- 150000001491 aromatic compounds Chemical class 0.000 claims 2
- -1 sodium cations Chemical class 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 238000010555 transalkylation reaction Methods 0.000 claims 1
Claims (3)
揮発性物質を含まない基準で、ゼオライト６０〜９０重量％を含み、残りのアルミナが、結合剤であり、
触媒が、Ｘ線回折（ＸＲＤ）で測定して少なくとも５０の絶対強度を有し、ゼオライトが、ゼオライトのバルクアルミニウム含量の少なくとも６０％の骨格アルミニウム含量をさらに有する触媒。 A catalyst comprising a zeolite of Y-85 or modified LZ-210, wherein the catalyst is
Containing 60-90% by weight of zeolite on a volatile-free basis, the remaining alumina being the binder,
A catalyst wherein the catalyst has an absolute intensity of at least 50 as measured by X-ray diffraction (XRD) and the zeolite further has a framework aluminum content of at least 60% of the bulk aluminum content of the zeolite.
（ｂ）第２のゼオライトを５５０℃〜８５０℃の範囲の温度で熱水的に処理して、第１のバルクＳｉ／Ａｌ２モル比を有し、第１の単位格子サイズ未満の第２の単位格子サイズを有する第３のゼオライトを生成するステップと；
（ｃ）第３のゼオライトを４未満のｐＨを有するアンモニウムイオン水溶液の十分な量と、第３のゼオライトのナトリウムカチオンの少なくとも一部をアンモニウムイオンで交換するのに十分な時間接触させて、第１のバルクＳｉ／Ａｌ２モル比を超え、６．５〜２７の範囲の第２のバルクＳｉ／Ａｌ２モル比を有するＹ−８５または修飾ＬＺ−２１０ゼオライトを生成するステップであって、Ｙ−８５または修飾ＬＺ−２１０ゼオライトが、Ｙ−８５または修飾ＬＺ−２１０ゼオライト中のすべてのアルミニウムの少なくとも６０％を占める骨格アルミニウム含量、およびＸ線回折によって測定して少なくとも５０の絶対強度をさらに有するステップと
を含むＹ−８５または修飾ＬＺ−２１０ゼオライト触媒を調製する方法。 (A) treating the first zeolite with an aqueous ionic solution to obtain a second zeolite having a first unit cell size;
(B) it is treated hydrothermally at temperatures in the second range of zeolite 550 ° C. to 850 ° C., having a first bulk Si / Al 2 molar ratio of less than the first unit cell size second Producing a third zeolite having a unit cell size of
(C) contacting the third zeolite with a sufficient amount of an aqueous ammonium ion solution having a pH of less than 4 for a time sufficient to exchange at least a portion of the sodium cations of the third zeolite with ammonium ions; exceeding one bulk Si / Al 2 molar ratio, and generating a Y-85 or modified LZ-210 zeolite having a second bulk Si / Al 2 molar ratio in the range of 6.5 to 27, Y -85 or modified LZ-210 zeolite further has a framework aluminum content accounting for at least 60% of all aluminum in the Y-85 or modified LZ-210 zeolite, and an absolute strength as measured by X-ray diffraction A method of preparing a Y-85 or modified LZ-210 zeolite catalyst comprising the steps of:
A process for the transalkylation of an aromatic compound comprising the step of contacting an aromatic compound and an aromatic substrate with the catalyst of claim 1.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/622,896 US20080171649A1 (en) | 2007-01-12 | 2007-01-12 | Modified Y-85 and LZ-210 Zeolites |
| US11/622,925 US7517825B2 (en) | 2007-01-12 | 2007-01-12 | Aromatic transalkylation using a LZ-210 zeolite |
| US11/622,941 US20080171902A1 (en) | 2007-01-12 | 2007-01-12 | Aromatic Transalkylation Using a Y-85 Zeolite |
| PCT/US2008/050400 WO2008088962A1 (en) | 2007-01-12 | 2008-01-07 | Y-85 and modified lz-210 zeolites |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013131095A Division JP5894559B2 (en) | 2007-01-12 | 2013-06-21 | Y-85 and modified LZ-210 zeolite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010515568A JP2010515568A (en) | 2010-05-13 |
| JP2010515568A5 true JP2010515568A5 (en) | 2010-09-02 |
Family
ID=39636334
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009545624A Pending JP2010515568A (en) | 2007-01-12 | 2008-01-07 | Y-85 and modified LZ-210 zeolite |
| JP2013131095A Active JP5894559B2 (en) | 2007-01-12 | 2013-06-21 | Y-85 and modified LZ-210 zeolite |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013131095A Active JP5894559B2 (en) | 2007-01-12 | 2013-06-21 | Y-85 and modified LZ-210 zeolite |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP2114565A4 (en) |
| JP (2) | JP2010515568A (en) |
| KR (1) | KR101474891B1 (en) |
| AR (1) | AR064882A1 (en) |
| BR (1) | BRPI0806530A2 (en) |
| SA (1) | SA08290007B1 (en) |
| TW (1) | TWI457174B (en) |
| WO (1) | WO2008088962A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012140287A (en) * | 2010-12-28 | 2012-07-26 | Jgc Catalysts & Chemicals Ltd | New faujasite type zeolite, method for production thereof, and catalyst including the faujasite type zeolite used for catalytic cracking of hydrocarbon |
| US8524966B1 (en) * | 2012-05-14 | 2013-09-03 | Uop Llc | Catalysts for improved cumene production and method of making and using same |
| US20200385322A1 (en) * | 2017-01-25 | 2020-12-10 | Exxonmobil Chemical Patents Inc. | Transalkylation Process and Catalyst Composition Used Therein |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4711770A (en) * | 1979-08-14 | 1987-12-08 | Union Carbide Corporation | Silicon substituted Y zeolite composition LZ-210 |
| US4503023A (en) * | 1979-08-14 | 1985-03-05 | Union Carbide Corporation | Silicon substituted zeolite compositions and process for preparing same |
| JPS61158811A (en) * | 1985-09-11 | 1986-07-18 | ユニオン・カ−バイド・コ−ポレ−シヨン | Silicon-substituted zeolite composition |
| GB8613132D0 (en) * | 1986-05-30 | 1986-07-02 | Shell Int Research | Hydrocarbon conversion catalysts |
| US5013699A (en) * | 1988-04-07 | 1991-05-07 | Uop | Novel zeolite compositions derived from zeolite Y |
| US5160033A (en) * | 1988-03-30 | 1992-11-03 | Uop | Octane gasoline catalyst and process using same in a hydrocracking process |
| US5207892A (en) * | 1988-04-07 | 1993-05-04 | Uop | Hydrocarbon conversion process employing a modified form of zeolite Y |
| JPH0274517A (en) * | 1988-09-08 | 1990-03-14 | Union Carbide Corp | Production of ultra-hydrophobic zeolite |
| US5036033A (en) * | 1989-05-26 | 1991-07-30 | Union Oil Company Of California | Alkylation catalyst and processes for preparing |
| US5157180A (en) * | 1989-05-26 | 1992-10-20 | Union Oil Company Of California | Alkylation and transalkylation processes |
| US5019543A (en) * | 1989-07-05 | 1991-05-28 | Exxon Research & Engineering Company | High silica crystalline zeolites and process for their preparation |
| US5275720A (en) * | 1990-11-30 | 1994-01-04 | Union Oil Company Of California | Gasoline hydrocracking catalyst and process |
-
2008
- 2008-01-07 BR BRPI0806530-6A2A patent/BRPI0806530A2/en not_active Application Discontinuation
- 2008-01-07 WO PCT/US2008/050400 patent/WO2008088962A1/en active Application Filing
- 2008-01-07 KR KR1020097016754A patent/KR101474891B1/en active IP Right Grant
- 2008-01-07 EP EP08713623A patent/EP2114565A4/en not_active Withdrawn
- 2008-01-07 JP JP2009545624A patent/JP2010515568A/en active Pending
- 2008-01-11 TW TW097101200A patent/TWI457174B/en active
- 2008-01-11 AR ARP080100148A patent/AR064882A1/en not_active Application Discontinuation
- 2008-01-12 SA SA08290007A patent/SA08290007B1/en unknown
-
2013
- 2013-06-21 JP JP2013131095A patent/JP5894559B2/en active Active
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