JP2010260806A - Transparent sheet-like cosmetic - Google Patents

Transparent sheet-like cosmetic Download PDF

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JP2010260806A
JP2010260806A JP2009111863A JP2009111863A JP2010260806A JP 2010260806 A JP2010260806 A JP 2010260806A JP 2009111863 A JP2009111863 A JP 2009111863A JP 2009111863 A JP2009111863 A JP 2009111863A JP 2010260806 A JP2010260806 A JP 2010260806A
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sheet
cosmetic
transparent
biocellulose
soluble component
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JP5618173B2 (en
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Norio Sakaki
教生 榊
Fumiko Kaneno
芙美子 金野
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Toyo Shinyaku Co Ltd
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Toyo Shinyaku Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a transparent sheet-like cosmetic that exhibits excellent properties such as excellent external appearances, ready applicability, visibility of ameliorating effects on skin conditions and the like during service, and the like. <P>SOLUTION: The sheet-like cosmetic comprises biocellulose and a high-refractive water-soluble component and has a transparent external appearance. Preferably, the high-refractive water-soluble component is one or a mixture of two or more selected from among a polyhydric alcohol and saccharide. More preferably, the polyhydric alcohol or saccharide is one or a mixture of two or more selected from among glycerine, 1,3-butylene glycol, pentanediol, diglycerine, polyglycerine, glucose, sorbitol and sucrose. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、外観に優れ、貼りやすく、使用中に皮膚状態の改善効果等が見える等といった優れた効果のある、透明なシート状化粧品に関する。   The present invention relates to a transparent sheet-like cosmetic product that has excellent effects such as excellent appearance, easy application, and improved skin condition during use.

バイオセルロースは、不織布に比べて繊維のキメが細かく、保水力に優れている(特許文献1および2)。このようなバイオセルロースの特性を生かし、顔用マスクなどに利用するシート状化粧品を製造する試みもなされている(特許文献3)。しかしながら、バイオセルロースに生理活性成分やその他の成分を含浸させ、シート状化粧品を製造する際には、バイオセルロースとその他の成分との屈折率の違いから、不透明にならざるを得ないといった問題点があった。   Biocellulose is finer in fiber texture than a non-woven fabric and has excellent water retention (Patent Documents 1 and 2). Attempts have been made to produce sheet-like cosmetics to be used for facial masks and the like by making use of such characteristics of biocellulose (Patent Document 3). However, when manufacturing a sheet-like cosmetic product by impregnating biocellulose with bioactive ingredients and other ingredients, there is a problem that it must be opaque due to the difference in refractive index between biocellulose and other ingredients. was there.

特開平05−229063号公報Japanese Patent Laid-Open No. 05-229063 特開平03−157402号公報Japanese Patent Laid-Open No. 03-157402 特開2006−298846号公報JP 2006-29884 A

本発明は、使用感や外観に優れ、貼りやすく、使用中に皮膚状態の改善効果等が見えるといった優れた効果のある、透明なシート状化粧品に関する。   The present invention relates to a transparent sheet-like cosmetic product that has excellent effects such as excellent usability and appearance, easy application, and improved skin condition during use.

本発明は、バイオセルロースと高屈折率水溶性成分とを含有し、外観が透明であることを特徴とするシート状化粧品に関する。   The present invention relates to a sheet-like cosmetic comprising biocellulose and a high refractive index water-soluble component and having a transparent appearance.

好ましくは、前記高屈折率水溶性成分が、多価アルコール類または糖類から選ばれる1種または2種以上の混合物である、外観が透明であることを特徴とするシート状化粧品に関する。   Preferably, the high refractive index water-soluble component is one or a mixture of two or more selected from polyhydric alcohols or saccharides, and the appearance is transparent.

さらに好ましくは、本発明は、前記多価アルコール類または糖類が、グリセリン、1,3−ブチレングリコール、ペンタンジオール、ジグリセリン、ポリグリセリン、グルコース、ショ糖の中から選ばれる1種または2種以上の混合物である、外観が透明であることを特徴とするシート状化粧品に関する。   More preferably, in the present invention, the polyhydric alcohol or saccharide is one or more selected from glycerin, 1,3-butylene glycol, pentanediol, diglycerin, polyglycerin, glucose, and sucrose. It is related with the sheet-like cosmetics characterized by the external appearance being transparent.

本発明によれば、使用感や外観に優れ、貼りやすく、使用中に皮膚状態の改善効果等が見える等といった優れた効果のある、透明なシート状化粧品を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, it is excellent in a usability | use_condition and an external appearance, it is easy to stick and can provide the transparent sheet-like cosmetics with the outstanding effects, such as seeing the improvement effect of a skin state etc. during use.

図1はシート状化粧品A(左)とシート状化粧品B(右)の写真である。FIG. 1 is a photograph of sheet-like cosmetic A (left) and sheet-like cosmetic B (right). 図2はシート状化粧品A(左)とシート状化粧品B(右)の写真である。黒板の上に文字「マ」を付し、その上にシート状化粧品を置いたものである。FIG. 2 is a photograph of the sheet-like cosmetic A (left) and the sheet-like cosmetic B (right). The letter “ma” is attached on the blackboard, and the sheet-like cosmetic is placed on it. 図3はシート状化粧品Aを顔用マスクに成型した写真である。黒板の上に文字「○」を付し、その上にシート状化粧品を置いたものである。FIG. 3 is a photograph of the sheet-shaped cosmetic A molded into a facial mask. A letter “○” is attached on the blackboard, and a sheet-like cosmetic is placed thereon.

以下、本発明の実施形態について説明する。なお、本発明は、下記実施形態の記載により限定して解釈するべきでなく、特許請求の範囲における記載の範囲内で種々の変更が可能である。   Hereinafter, embodiments of the present invention will be described. In addition, this invention should not be limited and interpreted by description of the following embodiment, A various change is possible within the range of description in a claim.

本発明は、バイオセルロースと高屈折率水溶性成分とを含有し、外観が透明であることを特徴とするシート状化粧品に関する。好ましくは、前記高屈折率水溶性成分が、多価アルコール類または糖類から選ばれる1種または2種以上の混合物である。さらに好ましくは、前記多価アルコール類または糖類が、グリセリン、1,3−ブチレングリコール、ペンタンジオール、ジグリセリン、ポリグリセリン、グルコース、ソルビトール、ショ糖から選ばれる1種または2種以上の混合物である。   The present invention relates to a sheet-like cosmetic comprising biocellulose and a high refractive index water-soluble component and having a transparent appearance. Preferably, the high refractive index water-soluble component is one or a mixture of two or more selected from polyhydric alcohols or saccharides. More preferably, the polyhydric alcohol or saccharide is one or a mixture of two or more selected from glycerin, 1,3-butylene glycol, pentanediol, diglycerin, polyglycerin, glucose, sorbitol, and sucrose. .

本発明に用いるバイオセルロースとは、微生物が産生するセルロースであり、直径4nmのミクロフィブリルが多数集ったフィブリルからなる。酢酸菌などを静置培養することにより、空気−液体培地界面にバイオセルロース膜が形成される。   The biocellulose used in the present invention is cellulose produced by microorganisms, and is composed of fibrils in which a large number of microfibrils having a diameter of 4 nm are gathered. By stationary culture of acetic acid bacteria and the like, a biocellulose film is formed at the air-liquid medium interface.

たとえば、培養によってバイオセルロース膜を形成させた後、水で洗浄し、培地を除去し、次いでアルカリ処理を行い、微生物および不純物を除去する。アルカリ処理は、生成されたバイオセルロース膜の約10倍量のアルカリ溶液(例えば2%程度の水酸化ナトリウム溶液)で、1〜2時間煮沸すればよい。その後、中性になるまで水洗し、目的のバイオセルロース膜を得ることができる。 For example, after forming a biocellulose film by culturing, washing with water, removing the medium, and then performing an alkali treatment to remove microorganisms and impurities. The alkali treatment may be boiled for about 1 to 2 hours with an alkali solution (for example, about 2% sodium hydroxide solution) about 10 times as much as the produced biocellulose membrane. Then, it wash | cleans with water until it becomes neutral, and can obtain the target biocellulose film | membrane.

本発明に用いる高屈折率水溶性成分とは、屈折率(D線により、20℃で測定)が好ましくは1.40以上の水溶性成分であり、さらに好ましくは1.43以上である。   The high refractive index water-soluble component used in the present invention is a water-soluble component having a refractive index (measured at 20 ° C. by D-ray) of preferably 1.40 or more, and more preferably 1.43 or more.

本発明に用いる多価アルコール類とは、グリセリン、1,3−ブチレングリコール、ペンタンジオール、ジグリセリン、ポリグリセリン、エチレングリコール、ジエチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、グリコール、イソプレングリコール等の多価アルコール類である。また、本発明に用いる糖類とは、グルコース、ショ糖、ソルビトール等の糖類が挙げられる。これらのうち、透明性を容易に確保できることや湿潤作用に優れる1種または2種以上の混合物であることが好ましい。   The polyhydric alcohol used in the present invention is glycerin, 1,3-butylene glycol, pentanediol, diglycerin, polyglycerin, ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, glycol, isoprene. Polyhydric alcohols such as glycol. Examples of the saccharide used in the present invention include saccharides such as glucose, sucrose, and sorbitol. Among these, it is preferable to be one kind or a mixture of two or more kinds, which can easily ensure transparency and have an excellent wetting action.

本発明における「外観が透明であるシート状化粧品」とは、肉眼で見て、明らかに透明と感じ取れる程度の透明感があるシート状化粧品である。文字が記載されている板の上に、シート状化粧品置いたときに、文字があることが容易に判る程度の透明性が確保されていることが好ましい。   The “sheet-shaped cosmetic product having a transparent appearance” in the present invention is a sheet-shaped cosmetic product having a transparent feeling that is clearly transparent when viewed with the naked eye. When a sheet-like cosmetic product is placed on a plate on which characters are described, it is preferable to ensure transparency to such an extent that the characters can be easily found.

本発明における外観が透明であることを特徴とするシート状化粧品は、シート状化粧品を不透明にしない限りにおいて、必要に応じて、通常化粧品に使用可能な、生理活性成分、増粘剤、油剤、フッ素化合物、樹脂、界面活性剤、紫外線吸収剤、防腐剤、香料、色素、塩類、溶媒、キレート剤、中和剤、pH調整剤等の成分を配合することができる。 The sheet-like cosmetic characterized in that the appearance in the present invention is transparent, as long as the sheet-like cosmetic is not opaque, can be used for normal cosmetics as needed, physiologically active ingredients, thickeners, oils, Components such as a fluorine compound, a resin, a surfactant, an ultraviolet absorber, a preservative, a fragrance, a dye, a salt, a solvent, a chelating agent, a neutralizing agent, and a pH adjusting agent can be blended.

本発明の好ましいシート状化粧品の処方例は、シート状化粧品を不透明にしない限り制限は無いが、少なくとも以下の(A)〜(D)成分の組み合わせにより、透明性が得られればよい。その他の生理活性成分などを含んでも良いのは言うまでも無い。
(A)グリセリン 5〜60重量%
(B)多価アルコール類、糖類の1種または2種以上の混合物 0〜65重量%
(C)ヒアルロン酸ナトリウム 0.001〜1重量%
(D)精製水 残量
The preferable example of the sheet-like cosmetic of the present invention is not limited as long as the sheet-like cosmetic is not opaque, but it is sufficient that transparency is obtained by a combination of at least the following components (A) to (D). Needless to say, other physiologically active ingredients may be included.
(A) Glycerin 5-60% by weight
(B) Polyhydric alcohols, a mixture of one or more sugars 0 to 65% by weight
(C) Sodium hyaluronate 0.001-1% by weight
(D) Purified water remaining

本発明の透明なシート状化粧品の形状としては特に制限が無く、シート状化粧品を不透明にしない限りにおいて、楕円形、円形、ハート形、半円形、半楕円形、正方形、長方形、台形等にすることができる。また、位置合わせや使用性改善の目的で凸部や凹部を設けても構わない。さらに、使用部位によりそれぞれ形状や厚さや接着力を変化させてよい。 The shape of the transparent sheet-shaped cosmetic product of the present invention is not particularly limited, and may be elliptical, circular, heart-shaped, semi-circular, semi-elliptical, square, rectangular, trapezoidal, etc., as long as the sheet-shaped cosmetic is not opaque. be able to. Moreover, you may provide a convex part and a recessed part for the purpose of alignment and a usability improvement. Further, the shape, thickness, and adhesive force may be changed depending on the use site.

本発明の透明なシート状化粧品の適用部位としては、顔用、目元用、口元用、腕部用、脚部用、胸部用、腹部用、首部用等が挙げられる。貼り付け面積が大きい部位では、シート状化粧品の粘着力を上昇させるか、厚さを薄目にすることが好ましい。 Examples of the application site of the transparent sheet-like cosmetic of the present invention include face use, eye use, mouth use, arm use, leg use, chest use, abdominal use, and neck use. In a part where the pasting area is large, it is preferable to increase the adhesive strength of the sheet-like cosmetic or to reduce the thickness.

本発明の透明なシート状化粧品のシートの厚さとしては特に制限が無く、シート状化粧品を不透明にしない限りにおいて、全体が均一であっても、部分的に厚さが異なっていても良いが、密着性、透明性、強度を確保するため、0.3〜1.5mmの厚さが好ましい。 The thickness of the transparent sheet-like cosmetic sheet of the present invention is not particularly limited, and the thickness may be uniform or partially different as long as the sheet-like cosmetic is not opaque. In order to ensure adhesion, transparency and strength, a thickness of 0.3 to 1.5 mm is preferable.

本発明の透明なシート状化粧品は透明であるので、外観に優れ、貼りやすく、使用中に皮膚状態の改善効果等が見えるなどの優れた効果を有している。前記効果以外にも、適用部位や配合する生理活性成分により様々な効果が期待できる。例えば、小じわの改善効果、皮膚のターンオーバーの改善、マッサージ効果、保湿効果、血行促進、くまの改善効果、冷却効果、スリミング効果、整形効果などが期待できる。これらの効果は、透明なシート状化粧品のパック効果と配合されている成分による効果との相乗効果により得られる。 Since the transparent sheet-like cosmetic of the present invention is transparent, it has excellent effects such as excellent appearance, easy application, and the appearance of improving skin condition during use. In addition to the above effects, various effects can be expected depending on the application site and the physiologically active component to be blended. For example, fine wrinkle improvement effect, skin turnover improvement, massage effect, moisturizing effect, blood circulation promotion, bear improvement effect, cooling effect, slimming effect, shaping effect and the like can be expected. These effects are obtained by a synergistic effect between the effect of the transparent sheet-like cosmetic pack and the effect of the blended components.

以下、本発明の実施例について説明する。なお、本発明は、下記の実施例に限定して解釈すべきではなく、特許請求の範囲における記載の範囲内で種々の変更が可能である。   Examples of the present invention will be described below. It should be noted that the present invention should not be construed as being limited to the following examples, and various modifications can be made within the scope of the claims.

(実施例1)
下記の表1の処方になるように、バイオセルロースのシート状化粧品Aを製造した。
(表1)
Example 1
A biocellulose sheet-like cosmetic A was produced so as to have the formulation shown in Table 1 below.
(Table 1)

(比較例1)
精製水にバイオセルロースを含浸させ、シート状化粧品Bを作成した。
(Comparative Example 1)
Purified water was impregnated with biocellulose to prepare a sheet-like cosmetic B.

(評価)
実施例1のシート状化粧品Aと比較例1のシート状化粧品Bの透明感を肉眼で評価した結果、明らかにAの方が透明であった。シート状化粧品AおよびBの写真は図1〜3である。図1左および図2左はシート状化粧品A、図1右および図2右はシート状化粧品Bである。図3はシート状化粧品Aを顔用マスクに成型したものである。
(Evaluation)
As a result of evaluating the transparency of the sheet-like cosmetic A of Example 1 and the sheet-like cosmetic B of Comparative Example 1 with the naked eye, A was clearly more transparent. The photographs of the sheet-like cosmetics A and B are FIGS. The left side of FIG. 1 and FIG. 2 left is a sheet-like cosmetic A, and the right side of FIG. FIG. 3 shows a sheet-shaped cosmetic A molded into a facial mask.

図1より、シート状化粧品Aは透明であるが、シート状化粧品Bは白っぽく透明でないことが明らかである。また、図2や図3のようにシート状化粧品Aでは、板の上の文字「マ」や「○」が鮮明に見えるが、シート状化粧品Bでは文字が見えにくい。このことからも、AはBより透明であることが分かる。 From FIG. 1, it is clear that the sheet-like cosmetic A is transparent, but the sheet-like cosmetic B is whitish and not transparent. Further, as shown in FIGS. 2 and 3, in the sheet-like cosmetic A, the characters “MA” and “◯” on the plate are clearly visible, but in the sheet-like cosmetic B, the characters are difficult to see. This also indicates that A is more transparent than B.

このように本発明者らは、使用感や外観に優れ、貼りやすく、使用中に皮膚状態の改善効果等が見える等といった優れた効果のある、透明なシート状化粧品を提供することができた。 As described above, the present inventors have been able to provide a transparent sheet-like cosmetic product having excellent effects such as excellent usability and appearance, easy application, and improved skin condition during use. .

本発明によれば、使用感や外観に優れ、貼りやすく、使用中に皮膚状態の改善効果等が見える等といった優れた効果のある、透明なシート状化粧品を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, it is excellent in a usability | use_condition and an external appearance, it is easy to stick and can provide the transparent sheet-like cosmetics with the outstanding effects, such as seeing the improvement effect of a skin state etc. during use.

Claims (3)

バイオセルロースと高屈折率水溶性成分を含有し、外観が透明であることを特徴とするシート状化粧品。   A sheet-like cosmetic comprising a biocellulose and a water-soluble component having a high refractive index and having a transparent appearance. 請求項1に記載の高屈折率水溶性成分が、多価アルコール類または糖類から選ばれる1種または2種以上の混合物である、外観が透明であることを特徴とするシート状化粧品。   A sheet-like cosmetic product characterized in that the high refractive index water-soluble component according to claim 1 is one or a mixture of two or more selected from polyhydric alcohols or saccharides and has a transparent appearance. 請求項2に記載の多価アルコール類または糖類が、グリセリン、1,3−ブチレングリコール、ペンタンジオール、ジグリセリン、ポリグリセリン、グルコース、ショ糖の中から選ばれる1種または2種以上の混合物である、外観が透明であることを特徴とするシート状化粧品。

The polyhydric alcohol or saccharide according to claim 2 is one or a mixture of two or more selected from glycerin, 1,3-butylene glycol, pentanediol, diglycerin, polyglycerin, glucose, and sucrose. A sheet-like cosmetic product characterized by having a transparent appearance.

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JP2014133715A (en) * 2013-01-10 2014-07-24 Daiwabo Holdings Co Ltd Method for production of skin covering sheet for cosmetic preparation impregnation
US10113004B2 (en) * 2012-01-26 2018-10-30 Youcel Co., Ltd. Method for producing dried bio cellulose

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US10113004B2 (en) * 2012-01-26 2018-10-30 Youcel Co., Ltd. Method for producing dried bio cellulose
JP2014133715A (en) * 2013-01-10 2014-07-24 Daiwabo Holdings Co Ltd Method for production of skin covering sheet for cosmetic preparation impregnation

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