JP2010235356A - Method for manufacturing metal wired flat glass - Google Patents

Method for manufacturing metal wired flat glass Download PDF

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Publication number
JP2010235356A
JP2010235356A JP2009083489A JP2009083489A JP2010235356A JP 2010235356 A JP2010235356 A JP 2010235356A JP 2009083489 A JP2009083489 A JP 2009083489A JP 2009083489 A JP2009083489 A JP 2009083489A JP 2010235356 A JP2010235356 A JP 2010235356A
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Japan
Prior art keywords
glass
roll
metal wire
metal
flat glass
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Pending
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JP2009083489A
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Japanese (ja)
Inventor
Atsushi Tsuji
篤史 辻
Tatsuya Tsuzuki
都築  達也
Tadashi Muramoto
正 村本
Naoki Mitamura
直樹 三田村
Atsushi Tanigawa
篤 谷川
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Central Glass Co Ltd
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Central Glass Co Ltd
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Publication date
Application filed by Central Glass Co Ltd filed Critical Central Glass Co Ltd
Priority to JP2009083489A priority Critical patent/JP2010235356A/en
Priority to PCT/JP2010/055510 priority patent/WO2010113837A1/en
Publication of JP2010235356A publication Critical patent/JP2010235356A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • C03B13/12Rolling glass with enclosures, e.g. wire, bubbles, fibres, particles or asbestos
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B13/00Rolling molten glass, i.e. where the molten glass is shaped by rolling
    • C03B13/16Construction of the glass rollers

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for obtaining a high quality metal wired flat glass having a smooth surface without requiring a polishing process which causes cost increase in the production of a metal wired flat glass by a roll forming method. <P>SOLUTION: In the method for manufacturing a metal wired flat glass in which a metal wire is inserted into the flat glass by the roll forming method, the rolls consist of a base material having quality or structure capable of containing liquid in the inside, the molten glass is formed by rotating the pair of rolls while supplying a vapor film of liquid therebetween and a metal wire is inserted as well. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、ロールアウト方式による金属線入り板ガラスの製造方法に関する。   The present invention relates to a method for producing a metal wire-containing plate glass by a roll-out method.

板ガラスの製造方法としては、種々のものが知られている。特に普及しているものとして、スズフロート法、ロールアウト法が挙げられる。   Various methods for producing plate glass are known. Particularly popular are the tin float method and the rollout method.

スズフロート法は、現在板ガラスの大量生産法として最も広く普及しているもので、溶融スズ上にガラスを浮かべて延伸成形される方法である。大面積の板ガラスを製造するのに適した方法であるが、常温では固体である金属スズを常時溶融状態に保たなければならないため、窯の保温に要するエネルギーは莫大である。   The tin float method is currently most widely used as a mass production method for sheet glass, and is a method in which glass is floated on molten tin and stretch-formed. Although this method is suitable for producing large-area plate glass, the metal tin that is solid at room temperature must be kept in a molten state at all times, so that the energy required to keep the kiln warm is enormous.

ロールアウト法は、一般に金属ロールにより溶融ガラスを挟み、成形するもので、スズフロート法と比較して低コストで簡易な装置構成でガラス成形が行える長所がある。しかし、金属ロールとの接触により溶融ガラスが急冷されるため、成形されたガラスにロールとの接触痕、しわ、うねりが残ることが避けがたく、高品質な板ガラス製品を得るには研磨工程が不可欠である。   The roll-out method is generally a method in which a molten glass is sandwiched between metal rolls and molded, and has an advantage that glass molding can be performed with a simple apparatus configuration at a lower cost than the tin float method. However, since the molten glass is rapidly cooled by contact with the metal roll, it is inevitable that contact marks, wrinkles, and undulations remain on the formed glass, and a polishing process is required to obtain a high-quality sheet glass product. It is essential.

これらの理由から、建築用などの大きなガラス板は、殆どの場合スズフロート法によって製造されている。しかし、線入り板ガラスや網入り板ガラスのような金属線入り板ガラスは、溶融ガラス中に金属線を挿入する必要があり、スズフロート法で製造することが困難である。このため金属線入り板ガラスは、図1に示すように、ロール成形時に金属線を同時に挿入することによってロールアウト法で製造されている (例えば特許文献1参照)。   For these reasons, large glass plates for construction and the like are almost always manufactured by a tin float method. However, a metal wire-containing plate glass such as a wire-containing plate glass or a mesh-containing plate glass needs to insert a metal wire into the molten glass, and is difficult to manufacture by a tin float method. For this reason, as shown in FIG. 1, the metal wire-containing plate glass is manufactured by a roll-out method by simultaneously inserting metal wires during roll forming (see, for example, Patent Document 1).

特開2003−12341号公報JP 2003-12341 A

前述したように、既存のロールアウト法では、ロールに金属製のものが使用されている。金属ロール表面は平滑であるが、金属ロールとの接触により溶融ガラスが急冷されるため、成形されたガラスにロールとの接触痕の他、しわ、うねりが残ることとなる。そのため、ロール成形後、ガラスが冷却された段階で、研磨する工程が必須となっている。この研磨は当然ガラスの表裏両面を行う必要があり、通常のスズフロートガラスと比較すると、極めて高コストになってしまうという問題がある。   As described above, in the existing rollout method, a metal roll is used. Although the surface of the metal roll is smooth, the molten glass is rapidly cooled by contact with the metal roll, so that wrinkles and undulations remain in the formed glass in addition to the contact marks with the roll. Therefore, after roll forming, a polishing step is essential when the glass is cooled. This polishing naturally requires both the front and back surfaces of the glass, and there is a problem that the cost becomes extremely high as compared with ordinary tin float glass.

また、金属ロールによる表面の急冷により内部応力が発生するという問題がある。この内部応力はガラス冷却後まで残存し、時間が経ってからガラスと金属線の膨張係数の差から、金属線周囲のガラス部分に微小なクラックを発生させる。これはガラスの強度低下や自然割れの原因となり、問題となっている。   In addition, there is a problem that internal stress occurs due to rapid cooling of the surface by a metal roll. This internal stress remains after the glass is cooled, and after a period of time, minute cracks are generated in the glass portion around the metal wire due to the difference in expansion coefficient between the glass and the metal wire. This causes a decrease in strength of the glass and natural cracking, which is a problem.

本発明は、板ガラス中に金属線が挿入されている、金属線入り板ガラスのロールアウト法による製造方法であって、該ロールが液体を内部に包含しうる材質または構造からなる基材からなり、対のロールを回転させながらロール間で液体の蒸気膜を介して溶融ガラスを成形するとともに、金属線を挿入することを特徴とする金属線入り板ガラスの製造方法である。     The present invention is a method of manufacturing a metal wire-containing plate glass by a roll-out method in which a metal wire is inserted into the plate glass, and the roll is made of a base material made of a material or a structure that can contain a liquid inside, A molten glass is formed between liquid rolls through a vapor film of liquid while rotating a pair of rolls, and a metal wire is inserted.

また、蒸気膜を生成する液体が水であることを特徴とする、上記の金属線入り板ガラスの製造方法である。   Moreover, the liquid which produces | generates a vapor | steam film | membrane is water, It is a manufacturing method of said metal wire containing plate glass.

本発明によれば、ロールアウト法による金属線入り板ガラスの製造において、高コストの原因となる研磨工程を経ずに、表面の平滑な高品質の金属線入り板ガラスを得ることが出来る。   ADVANTAGE OF THE INVENTION According to this invention, in manufacture of the metal wire containing plate glass by the roll-out method, the high quality metal wire containing plate glass with the smooth surface can be obtained, without passing through the grinding | polishing process which causes high cost.

本発明は、板ガラス中に金属線が挿入されている、金属線入り板ガラスのロールアウト法による製造方法であって、該ロールが液体を内部に包含しうる材質または構造からなる基材からなり、対のロールを回転させながらロール間で液体の蒸気膜を介して溶融ガラスを成形するとともに、金属線を挿入することを特徴とする金属線入り板ガラスの製造方法である。   The present invention is a method of manufacturing a metal wire-containing plate glass by a roll-out method in which a metal wire is inserted into the plate glass, and the roll is made of a base material made of a material or a structure that can contain a liquid inside, A molten glass is formed between liquid rolls through a vapor film of liquid while rotating a pair of rolls, and a metal wire is inserted.

図1に、ロールアウト法により金属線入りガラスを作成する方法を示す。ガラス溶融槽1で溶解された溶融ガラス2は、ロール4によって板状に成形されるが、このとき上方より金属線3を同時に巻き込み、金属線の挿入された金属線入り板ガラスが製造される。この金属線が、平行な複数本の場合は線入り板ガラス、交差して網状になっているものを網入り板ガラスと呼び、割れたガラスを飛散させない効果があることから、種々の用途が考えられている。   FIG. 1 shows a method for producing glass with a metal wire by the roll-out method. The molten glass 2 melted in the glass melting tank 1 is formed into a plate shape by a roll 4. At this time, the metal wire 3 is simultaneously wound from above to produce a metal wire-containing plate glass into which the metal wire is inserted. In the case where there are a plurality of metal wires parallel to each other, a wire-containing plate glass, a crossed net-like glass plate is called a net-containing plate glass, and since it has an effect of preventing the broken glass from scattering, various uses are considered. ing.

前述したように、既存の技術においては、このロールは金属製のものが使用されている。そのため、ロール成形後、ガラスが冷却された段階で、研磨する工程が必須となっていることや、ガラスの強度低下や自然割れの原因となっている。   As described above, in the existing technology, this roll is made of metal. Therefore, after roll forming, when the glass is cooled, a polishing step is indispensable, and the strength of the glass is reduced and natural cracks are caused.

本発明では、ロール4に液体を内部に包含しうる材質または構造からなる基材を使用し、対のロールを回転させながらロール間で液体の蒸気膜を介して溶融ガラスを成形することを特徴とする。   In the present invention, the roll 4 is made of a base material made of a material or structure capable of containing a liquid, and molten glass is formed between the rolls via a liquid vapor film while rotating the pair of rolls. And

ロール表面の液体を内部に包含しうるロール基材については、材質は多孔質の無機材料、金属材料、炭素材料や紙、繊維質などが挙げられる。これらの材料に求められる特性は蒸気膜を介して受ける溶融ガラス2からの放射熱に対する耐熱性、回転するロール上で充分な量の液体を内部に保持することのできる含水量、吸水速度や表面の平坦度などである。   As for the roll base material that can contain the liquid on the roll surface, examples of the material include porous inorganic materials, metal materials, carbon materials, paper, and fibers. The properties required for these materials are heat resistance against radiant heat from the molten glass 2 received through the vapor film, water content that can hold a sufficient amount of liquid on the rotating roll, water absorption speed and surface Flatness etc.

このとき、対を成すロール4はガラス溶融槽1からの距離、ロール回転速度、ロール間隔を自由に設定できることが望ましく、また図2に示すように、溶融ガラスGの温度に応じて、成形のためにロール対を一対以上並べても構わない。   At this time, it is desirable that the pair of rolls 4 can freely set the distance from the glass melting tank 1, the roll rotation speed, and the roll interval, and, as shown in FIG. Therefore, one or more pairs of rolls may be arranged.

なお、ロール成形においては、ロールは回転により溶融ガラスに引っ張り応力を加え、引き伸ばしながら成形する役目も持つ。蒸気膜を介した場合、ロールと溶融ガラスは非接触であるから、引っ張り応力を加えることが出来ない。この場合、製品にならないガラスの両端部分のみ引っ張り応力が加えられるような、例えばロール両端部には液体を包含しない材質を使うなどの工夫をすれば良い。   In roll forming, the roll applies a tensile stress to the molten glass by rotation and also has a role of forming while stretching. When the vapor film is interposed, the roll and the molten glass are not in contact with each other, so that a tensile stress cannot be applied. In this case, a device may be devised such that a tensile stress is applied only to both end portions of the glass that does not become a product, for example, a material that does not contain liquid is used at both end portions of the roll.

金属線入り板ガラスのロールアウト法による製造方法の模式図である。It is a schematic diagram of the manufacturing method by the rollout method of plate glass containing a metal wire. 複数のロール対を使用する場合の模式図である。It is a schematic diagram in the case of using a plurality of roll pairs.

1 ガラス溶融槽
2 溶融ガラス
3 金属線
4 ロール
5 金属線入りガラス
6 多段ロール
DESCRIPTION OF SYMBOLS 1 Glass melting tank 2 Molten glass 3 Metal wire 4 Roll 5 Glass with metal wire 6 Multistage roll

Claims (2)

板ガラス中に金属線が挿入されている、金属線入り板ガラスのロールアウト法による製造方法であって、該ロールが液体を内部に包含しうる材質または構造からなる基材からなり、対のロールを回転させながらロール間で液体の蒸気膜を介して溶融ガラスを成形するとともに、金属線を挿入することを特徴とする金属線入り板ガラスの製造方法。 A metal wire is inserted into a plate glass, and a method for producing a metal wire-containing plate glass by a roll-out method, wherein the roll is made of a base material made of a material or a structure capable of containing a liquid, and a pair of rolls is formed. A method for producing sheet glass containing metal wire, comprising forming molten glass between rolls through a vapor film of liquid while rotating and inserting a metal wire. 蒸気膜を生成する液体が水であることを特徴とする、請求項1に記載の金属線入り板ガラスの製造方法。 The method for producing a metal-lined plate glass according to claim 1, wherein the liquid that forms the vapor film is water.
JP2009083489A 2009-03-30 2009-03-30 Method for manufacturing metal wired flat glass Pending JP2010235356A (en)

Priority Applications (2)

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JP2009083489A JP2010235356A (en) 2009-03-30 2009-03-30 Method for manufacturing metal wired flat glass
PCT/JP2010/055510 WO2010113837A1 (en) 2009-03-30 2010-03-29 Method of producing metal wired flat glass

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103204618B (en) * 2013-03-06 2015-12-09 蚌埠凯盛工程技术有限公司 The tightness system of rolling press and transition roller table in a kind of rolled glass production line
WO2021223070A1 (en) * 2020-05-06 2021-11-11 China Triumph International Engineering Co., Ltd. Method for manufacture a glass with at least one electrically and/or thermally conductive feed-through, a glass with at least one electrically and/or thermally conductive feed-through and use of a glass with at least one electrically and/or thermally conductive feed-through

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001180949A (en) * 1999-12-28 2001-07-03 Asahi Glass Co Ltd Roll-molding method for sheet glass product
JP2004345923A (en) * 2003-05-23 2004-12-09 Nippon Sheet Glass Co Ltd Wired glass and its manufacturing method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001180949A (en) * 1999-12-28 2001-07-03 Asahi Glass Co Ltd Roll-molding method for sheet glass product
JP2004345923A (en) * 2003-05-23 2004-12-09 Nippon Sheet Glass Co Ltd Wired glass and its manufacturing method

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