JP2010234648A - Method of manufacturing 2-color molding decorative article - Google Patents

Method of manufacturing 2-color molding decorative article Download PDF

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JP2010234648A
JP2010234648A JP2009085142A JP2009085142A JP2010234648A JP 2010234648 A JP2010234648 A JP 2010234648A JP 2009085142 A JP2009085142 A JP 2009085142A JP 2009085142 A JP2009085142 A JP 2009085142A JP 2010234648 A JP2010234648 A JP 2010234648A
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primary
mold
decorative
resin
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Koichi Hamaoka
弘一 浜岡
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Nissha Printing Co Ltd
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<P>PROBLEM TO BE SOLVED: To provide a method of manufacturing a 2-color molding decorative article, which prevents appearance defects. <P>SOLUTION: The 2-color molding decorative article is formed by: forming a primary molding cavity by closing a primary molding cavity mold in which a primary decorative sheet is disposed and a core mold; forming the primary molding decorative article in which a primary decorative layer is laminated on the surface of a primary molding resin part, by injecting into the primary molding cavity the primary molding resin containing a high temperature conductivity object; opening the primary molding cavity mold and the core mold, in a state that the core mold holds the primary molding decorative article; switching a mold opposing to the core mold from the primary molding cavity mold to a secondary molding cavity mold; forming a secondary molding cavity by closing the secondary molding cavity mold and the core mold holding the primary molding decorative article; and injecting the secondary molding resin into the secondary molding cavity to form the 2-color molding decorative article in which the secondary molding resin part is laminated on the surface of the primary molding decorative article. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、AV機器や家電製品のフロントパネルやケース、ボタン、自動車の計器パネルやボタン等に用いられる、2層の樹脂の間に加飾層が設けられることにより深み感を備えた2色成形加飾品の製造方法に関する。   The present invention provides two colors with a sense of depth by providing a decorative layer between two layers of resin used in front panels and cases of AV equipment and home appliances, buttons, automotive instrument panels and buttons, etc. The present invention relates to a method for producing molded decorative articles.

従来の2色成形加飾品の製造方法として、
コア型101と、基体シート112上に1次加飾層113が積層された1次加飾シート111が配置される1次成形用キャビティ型102と、2次成形用キャビティ型103とを備える2色成形加飾金型を用い、
1次加飾シート111が配置された1次成形用キャビティ型102とコア型101とを型閉めして1次成形用キャビティ104を形成し、1次成形用キャビティ104内に1次成形樹脂131を射出して1次成形樹脂部132の表面に1次加飾層113が積層された1次成形加飾品133を形成し(図6(a)参照)、
コア型101が1次成形加飾品133を保持する状態で1次成形用キャビティ型102とコア型101とを型開きし、コア型101と対向する金型を1次成形用キャビティ型102から2次成形用キャビティ型103に切り替え、2次成形用キャビティ型103と1次成形加飾品133を保持するコア型101とを型閉めして2次成形用キャビティ105を形成し(図6(b)参照)、
2次成形用キャビティ105内に2次成形樹脂141を射出して1次成形加飾品133の表面に2次成形樹脂部142が積層された2色成形加飾品143を形成する(図6(c)参照)技術が、特許文献1に開示されている。
As a manufacturing method of conventional two-color molded decorative products,
2 comprising a core mold 101, a primary molding cavity mold 102 in which a primary decorative sheet 111 in which a primary decorative layer 113 is laminated on a base sheet 112 is disposed, and a secondary molding cavity mold 103. Using color molding decorative mold,
The primary molding cavity mold 102 on which the primary decorative sheet 111 is disposed and the core mold 101 are closed to form the primary molding cavity 104, and the primary molding resin 131 is formed in the primary molding cavity 104. To form a primary molded decorative product 133 in which the primary decorative layer 113 is laminated on the surface of the primary molded resin portion 132 (see FIG. 6A).
The primary mold cavity mold 102 and the core mold 101 are opened in a state where the core mold 101 holds the primary molded decorative article 133, and the mold facing the core mold 101 is moved from the primary mold cavity mold 102 to 2. Switching to the secondary molding cavity mold 103, the secondary molding cavity mold 103 and the core mold 101 holding the primary molding decoration 133 are closed to form the secondary molding cavity 105 (FIG. 6B). reference),
The secondary molding resin 141 is injected into the secondary molding cavity 105 to form a two-color molded decorative article 143 in which the secondary molded resin portion 142 is laminated on the surface of the primary molded decorative article 133 (FIG. 6 (c). The technology is disclosed in Patent Document 1.

特許3472403号公報Japanese Patent No. 3472403

基体シート112は樹脂製のフィルムであるため金型に比べ熱伝導率が劣るものの、通常25〜300μm程度の薄いものである。そのため、1次成形樹脂131の射出の際(図6(a)参照)、1次加飾層113に伝導する熱は基体シート112を通して1次成形用キャビティ型102の方に放散させることができる。その結果、1次加飾層113は1次成形樹脂131によって加熱されて軟化することなく1次成形樹脂131の流動抵抗にも耐えて位置を保持することでき、1次成形加飾品133の外観に問題は生じない。   Since the base sheet 112 is a resin film, its thermal conductivity is inferior to that of the mold, but it is usually as thin as about 25 to 300 μm. Therefore, when the primary molding resin 131 is injected (see FIG. 6A), heat conducted to the primary decorative layer 113 can be dissipated toward the primary molding cavity mold 102 through the base sheet 112. . As a result, the primary decorative layer 113 can withstand the flow resistance of the primary molded resin 131 without being heated and softened by the primary molded resin 131, and can maintain the position. There will be no problem.

しかし、同じく金型に比べ熱伝導率が劣る1次成形樹脂部132は通常500μm以上の厚みを持つものである。そのため、2次成形樹脂141の射出の際(図6(c)参照)、1次加飾層113に伝導する熱を1次成形樹脂部132を通してコア型101の方に放散させることができない。その結果、1次加飾層113は2次成形樹脂141によって加熱されて軟化して2次成形樹脂141の流動抵抗に逆らえず流れてしまい、2色成形加飾品143の外観不良が生じる問題があった(図7参照)。   However, the primary molded resin portion 132, which is similarly inferior in thermal conductivity to the mold, usually has a thickness of 500 μm or more. Therefore, when the secondary molding resin 141 is injected (see FIG. 6C), heat conducted to the primary decoration layer 113 cannot be dissipated toward the core mold 101 through the primary molding resin portion 132. As a result, the primary decorative layer 113 is heated and softened by the secondary molding resin 141 and flows without resisting the flow resistance of the secondary molding resin 141, resulting in the appearance defect of the two-color molded decorative product 143. (See FIG. 7).

本発明は上記の問題が発生しないようにするための2色成形加飾品の製造方法を提供することを目的とする。   An object of the present invention is to provide a method for producing a two-color molded decorative product so as not to cause the above problem.

本発明は前記目的を達成するため、以下のような特徴を備える。   In order to achieve the above object, the present invention has the following features.

本発明の2色成形加飾品の製造方法は、コア型と、基体シート上に1次加飾層が積層された1次加飾シートが配置される1次成形用キャビティ型と、2次成形用キャビティ型とを備える2色成形加飾金型を用い、
1次加飾シートが配置された1次成形用キャビティ型とコア型とを型閉めして1次成形用キャビティを形成し、1次成形用キャビティ内に高熱伝導率物を含有する1次成形樹脂を射出して1次成形樹脂部の表面に1次加飾層が積層された1次成形加飾品を形成し、
コア型が1次成形加飾品を保持する状態で1次成形用キャビティ型とコア型とを型開きし、コア型と対向する金型を1次成形用キャビティ型から2次成形用キャビティ型に切り替え、2次成形用キャビティ型と1次成形加飾品を保持するコア型とを型閉めして2次成形用キャビティを形成し、
2次成形用キャビティ内に2次成形樹脂を射出して1次成形加飾品の表面に2次成形樹脂部が積層された2色成形加飾品を形成することを特徴とする。
The manufacturing method of the two-color molded decorative article of the present invention includes a core mold, a primary mold cavity mold in which a primary decorative sheet in which a primary decorative layer is laminated on a base sheet, and secondary molding. Using a two-color molded decorative mold with a cavity mold for
The primary molding cavity mold and the core mold on which the primary decorative sheet is disposed are closed to form a primary molding cavity, and the primary molding contains a high thermal conductivity material in the primary molding cavity. The resin is injected to form a primary molded decorative product in which a primary decorative layer is laminated on the surface of the primary molded resin portion,
The primary mold cavity mold and the core mold are opened while the core mold holds the primary molded decorative product, and the mold facing the core mold is changed from the primary mold cavity mold to the secondary mold cavity mold. Switch to form a secondary molding cavity by closing the secondary molding cavity mold and the core mold holding the primary molded decorative product,
A secondary molding resin is injected into the secondary molding cavity to form a two-color molded decorative article having a secondary molded resin portion laminated on the surface of the primary molded decorative article.

また、上記の発明において、1次加飾シートとして転写シートを使用し、1次成形用キャビティ型とコア型との型開きから、2次成形用キャビティ型と1次成形加飾品を保持するコア型との型閉めまでの間に、1次成形加飾品から1次加飾シートの基体シートを剥離してもよい。   Moreover, in said invention, the core which uses a transfer sheet as a primary decorating sheet, and hold | maintains the secondary mold | type cavity type | mold and the primary molding decorating product from the mold opening of a primary mold | type cavity mold and a core type | mold. The base sheet of the primary decorative sheet may be peeled from the primary molded decorative product until the mold is closed.

また、上記の発明において、基体シート上に2次加飾層が積層された2次加飾シートが2次成形用キャビティ型に配置される2色成形加飾金型を用い、
2次加飾シートが配置された2次成形用キャビティ型と1次成形加飾品を保持するコア型とを型閉めして2次成形用キャビティを形成し、
2次成形用キャビティ内に2次成形樹脂を射出して1次成形加飾品の表面に2次成形樹脂部と2次加飾層とが順次積層された2色成形加飾品を形成してもよい。
Further, in the above invention, a secondary decorative sheet in which a secondary decorative layer is laminated on a base sheet is used as a two-color molded decorative mold arranged in a secondary mold cavity mold,
Closing the secondary mold cavity mold in which the secondary decorative sheet is arranged and the core mold holding the primary molded decorative article to form a secondary mold cavity,
Even if a secondary molding resin is injected into the secondary molding cavity to form a two-color molded decorative product in which a secondary molded resin portion and a secondary decorative layer are sequentially laminated on the surface of the primary molded decorative product. Good.

また、上記の発明において、2次加飾シートとして転写シートを使用し、2色成形加飾品の形成後、2色成形加飾品から2次加飾シートの基体シートを剥離してもよい。   In the above invention, a transfer sheet may be used as the secondary decorative sheet, and the base sheet of the secondary decorative sheet may be peeled from the two-color molded decorative product after the two-color molded decorative product is formed.

本発明の2色成形加飾品の製造方法は、高熱伝導率物を含有する1次成形樹脂部の表面に1次加飾層が積層された1次成形加飾品を形成する。したがって、1次成形樹脂部の熱伝導率が向上するので、2次成形樹脂の射出の際、1次加飾層に伝導する熱は1次成形樹脂部を通してコア型の方に放散させることができる。その結果、1次加飾層は2次成形樹脂によって加熱されて軟化することなく2次成形樹脂の流動抵抗にも耐えて位置を保持することでき、2色成形加飾品の外観不良の防止ができる。   The manufacturing method of the two-color molded decorative article of the present invention forms a primary molded decorative article in which a primary decorative layer is laminated on the surface of a primary molded resin portion containing a high thermal conductivity material. Accordingly, since the thermal conductivity of the primary molding resin portion is improved, the heat conducted to the primary decorative layer can be dissipated toward the core mold through the primary molding resin portion when the secondary molding resin is injected. it can. As a result, the primary decorative layer can withstand the flow resistance of the secondary molding resin without being heated and softened by the secondary molding resin, and the position can be maintained, thereby preventing the appearance defect of the two-color molded decorative product. it can.

本発明の2色成形加飾品の製造方法により2色成形加飾品を形成する工程を示す断面図である。It is sectional drawing which shows the process of forming a two-color molded ornament by the manufacturing method of the two-color molded ornament of this invention. 本発明の2色成形加飾品の製造方法に用いる1次加飾シートおよび2次加飾シートの断面図である。It is sectional drawing of the primary decorating sheet and secondary decorating sheet used for the manufacturing method of the two-color molded decorating product of this invention. 本発明の2色成形加飾品の製造方法により2色成形加飾品を形成する一工程を示す断面図である。It is sectional drawing which shows one process of forming a two-color molded decorative article by the method for producing a two-color molded decorative article of the present invention. 本発明の2色成形加飾品の製造方法により形成した2色成形加飾品を示す断面図である。It is sectional drawing which shows the two-color molded decorations formed with the manufacturing method of the two-color molded decorations of this invention. 本発明の2色成形加飾品の製造方法により2色成形加飾品を形成する工程を示す断面図である。It is sectional drawing which shows the process of forming a two-color molded ornament by the manufacturing method of the two-color molded ornament of this invention. 従来の2色成形加飾品の製造方法により2色成形加飾品を形成する工程を示す断面図である。It is sectional drawing which shows the process of forming a two-color molded ornament by the manufacturing method of the conventional two-color molded ornament. 従来の2色成形加飾品の製造方法により形成した2色成形加飾品を示す断面図である。It is sectional drawing which shows the two-color molded ornament formed by the manufacturing method of the conventional two-color molded ornament.

図面を参照しながらこの発明の実施の形態について詳しく説明する。   Embodiments of the present invention will be described in detail with reference to the drawings.

まず、本発明の2色成形加飾品の製造方法に使用する、2色成形加飾金型、1次加飾シート11(および2次加飾シート21)、1次成形樹脂31、2次成形樹脂41について説明する。   First, the two-color molded decorative mold, the primary decorative sheet 11 (and the secondary decorative sheet 21) used in the method for producing a two-color molded decorative product of the present invention, the primary molded resin 31 and the secondary molded. The resin 41 will be described.

2色成形加飾金型は、コア型1と、1次成形用キャビティ型2と、2次成形用キャビティ型3とを備えるものである(図1参照)。コア型1は、最終形成される2色成形加飾品43の裏面形状を形成するために用いられる。1次成形用キャビティ型2は、1次成形樹脂部32の表面に1次加飾層13が積層され2色成形加飾品43の下地となる1次成形加飾品33の表面形状を形成するために用いられる。1次成形用キャビティ型2は、コア型1との型閉めにより1次成形用キャビティ型4を形成する。1次成形用キャビティ型2は、基体シート12上に1次加飾層13が積層された1次加飾シート11が配置される。2次成形用キャビティ型3は、1次成形加飾品33の表面に2次成形樹脂部42が積層された2色成形加飾品43の表面形状を形成するために用いられる。2次成形用キャビティ型3は、1次成形用キャビティ型2よりも外形形状を大きくし、1次成形加飾品33と接しない部分が形成できるように設計する。この接しない部分が2次成形用キャビティ5に該当する。   The two-color molding decorative mold includes a core mold 1, a primary molding cavity mold 2, and a secondary molding cavity mold 3 (see FIG. 1). The core mold 1 is used to form the back surface shape of the two-color molded decorative article 43 to be finally formed. In the primary molding cavity mold 2, the primary decorative layer 13 is laminated on the surface of the primary molded resin portion 32 to form the surface shape of the primary molded decorative product 33 that becomes the base of the two-color molded decorative product 43. Used for. The primary molding cavity mold 2 forms the primary molding cavity mold 4 by closing the mold with the core mold 1. In the primary mold cavity mold 2, a primary decorative sheet 11 in which a primary decorative layer 13 is laminated on a base sheet 12 is disposed. The secondary mold cavity mold 3 is used to form the surface shape of the two-color molded decorative product 43 in which the secondary molded resin portion 42 is laminated on the surface of the primary molded decorative product 33. The cavity mold 3 for secondary molding is designed to have a larger outer shape than the cavity mold 2 for primary molding and to form a portion that does not contact the primary molded decorative product 33. This non-contact portion corresponds to the secondary molding cavity 5.

1次加飾シート11(2次加飾シート21)は、少なくとも基体シート12(基体シート22)上に1次加飾層13(2次加飾層23)が積層され、必要に応じて剥離層14(剥離層24)や接着層15(接着層25)などが設けられるものである(図2参照)。   The primary decorative sheet 11 (secondary decorative sheet 21) has a primary decorative layer 13 (secondary decorative layer 23) laminated on at least the base sheet 12 (base sheet 22), and is peeled off as necessary. Layer 14 (peeling layer 24), adhesive layer 15 (adhesive layer 25), and the like are provided (see FIG. 2).

基体シート12(基体シート22)としては、ポリエステル系樹脂、ポリプロピレン系樹脂、塩化ビニル樹脂、ポリエチレン樹脂、ポリエチレンテレフタレート樹脂、ポリカーボネート樹脂、ナイロン樹脂、ビニロン樹脂、アセテート樹脂、ポリエチレン系樹脂、ポリアミド系樹脂、ポリアクリル系樹脂、ポリ塩化ビニル系樹脂などのプラスチックシートを使用することができる。基体シート12(基体シート22)の厚さとしては、10〜500μmのものを使用するとよい。   As the base sheet 12 (base sheet 22), polyester resin, polypropylene resin, vinyl chloride resin, polyethylene resin, polyethylene terephthalate resin, polycarbonate resin, nylon resin, vinylon resin, acetate resin, polyethylene resin, polyamide resin, Plastic sheets such as polyacrylic resin and polyvinyl chloride resin can be used. The thickness of the base sheet 12 (base sheet 22) may be 10 to 500 μm.

基体シート12(基体シート22)を剥離する場合には1次加飾シート11(2次加飾シート21)は転写シートとなる。この場合、必要に応じて剥離層14(剥離層24)を形成してもよい。剥離層14(剥離層24)は基体シート12(基体シート22)から剥離して被転写物の最外面となる層である。剥離層14(剥離層24)の材質としては、アクリル系樹脂、ポリエステル系樹脂、ポリ塩化ビニル系樹脂、セルロース系樹脂、ゴム系樹脂、ポリウレタン系樹脂、ポリ酢酸ビニル系樹脂などのほか、塩化ビニル−酢酸ビニル共重合体系樹脂、エチレン−酢酸ビニル共重合体系樹脂などのコポリマーを用いるとよい。後述するように2次加飾シート21を使用して2色成形加飾品43を形成し、2色成形加飾品43の最外面となる剥離層24に硬度が必要な場合には、紫外線硬化性樹脂などの光硬化性樹脂、電子線硬化性樹脂などの放射線硬化性樹脂、熱硬化性樹脂などを選定して用いるとよい。剥離層14(剥離層24)の形成方法としては、グラビアコート法、ロールコート法、コンマコート法などのコート法、グラビア印刷法、スクリーン印刷法などの印刷法がある。   When the base sheet 12 (base sheet 22) is peeled off, the primary decorating sheet 11 (secondary decorating sheet 21) becomes a transfer sheet. In this case, you may form the peeling layer 14 (peeling layer 24) as needed. The peeling layer 14 (peeling layer 24) is a layer that peels from the base sheet 12 (base sheet 22) and becomes the outermost surface of the transfer object. Examples of the material of the release layer 14 (release layer 24) include acrylic resin, polyester resin, polyvinyl chloride resin, cellulose resin, rubber resin, polyurethane resin, polyvinyl acetate resin, and vinyl chloride. -Copolymers such as vinyl acetate copolymer resin and ethylene-vinyl acetate copolymer resin may be used. As will be described later, when the secondary decorative sheet 21 is used to form a two-color molded decorative product 43 and the release layer 24 that is the outermost surface of the two-color molded decorative product 43 requires hardness, ultraviolet curable A photocurable resin such as a resin, a radiation curable resin such as an electron beam curable resin, a thermosetting resin, or the like may be selected and used. As a method for forming the release layer 14 (release layer 24), there are a coating method such as a gravure coating method, a roll coating method and a comma coating method, a printing method such as a gravure printing method and a screen printing method.

1次加飾層13(2次加飾層23)の材質としては、ポリビニル系樹脂、ポリアミド系樹脂、ポリエステル系樹脂、アクリル系樹脂、ポリウレタン系樹脂、ポリビニルアセタール系樹脂、ポリエステルウレタン系樹脂、セルロースエステル系樹脂、アルキド樹脂などの樹脂をバインダーとし、適切な色の顔料または染料を着色剤として含有する着色インキを用いるとよい。1次加飾層13(2次加飾層23)の形成方法としては、グラビア印刷法、スクリーン印刷法、オフセット印刷法などの通常の印刷法などを用いるとよい。加飾層4の厚さとしては、1〜20μmが好ましい。20μmを超えると、2次成形樹脂41の射出の際に、1次加飾層13に伝導する熱が1次成形樹脂部32を通してコア型1の方に放散することが難しくなり、その結果、1次加飾層13が軟化して2次成形樹脂41の流動抵抗に耐えきれず、2色成形加飾品43の外観不良が発生する恐れが生じる。1μmより薄いと意匠に必要な隠蔽が得られない。1次加飾層13(2次加飾層23)は着色インキに限らず、金属蒸着層等を形成して金属光沢のある意匠表現をする場合もある。金属蒸着層の材質としては、アルミ、クロム、銅、スズなどを用いる。金属蒸着層の形成は、真空蒸着法、スパッタリング法、イオンプレーティング法などを用いればよい。   As a material of the primary decoration layer 13 (secondary decoration layer 23), polyvinyl resin, polyamide resin, polyester resin, acrylic resin, polyurethane resin, polyvinyl acetal resin, polyester urethane resin, cellulose A colored ink containing a resin such as an ester resin or an alkyd resin as a binder and a pigment or dye of an appropriate color as a colorant may be used. As a method for forming the primary decorative layer 13 (secondary decorative layer 23), a normal printing method such as a gravure printing method, a screen printing method, or an offset printing method may be used. As thickness of the decoration layer 4, 1-20 micrometers is preferable. If it exceeds 20 μm, it becomes difficult for the heat conducted to the primary decorative layer 13 to be dissipated toward the core mold 1 through the primary molding resin portion 32 when the secondary molding resin 41 is injected. The primary decorative layer 13 is softened and cannot withstand the flow resistance of the secondary molded resin 41, so that the appearance defect of the two-color molded decorative product 43 may occur. If it is thinner than 1 μm, the concealment necessary for the design cannot be obtained. The primary decorative layer 13 (secondary decorative layer 23) is not limited to colored ink, but may form a metal vapor deposition layer or the like to express a design with metallic luster. Aluminum, chromium, copper, tin, or the like is used as the material for the metal deposition layer. The metal vapor deposition layer may be formed by using a vacuum vapor deposition method, a sputtering method, an ion plating method, or the like.

また、接着層15(接着層25)を必要に応じて形成してもよい。接着層15(接着層25)は、1次成形樹脂部32(2次成形樹脂部42)に接着させるための層である。1次成形樹脂部32(2次成形樹脂部42)の材質がポリアクリル系樹脂の場合は、1次成形樹脂部32(2次成形樹脂部42)の材質としてポリアクリル系樹脂を用いるとよい。また、1次成形樹脂部32(2次成形樹脂部42)の材質がポリフェニレンオキシド・ポリスチレン系樹脂、ポリカーボネート系樹脂、スチレン共重合体系樹脂、ポリスチレン系ブレンド樹脂の場合は、これらの樹脂と親和性のあるポリアクリル系樹脂、ポリスチレン系樹脂、ポリアミド系樹脂などを、接着層15(接着層25)の材質として使用すればよい。接着層15(接着層25)の形成方法としては、グラビアコート法、ロールコート法、コンマコート法などのコーティングや、グラビア印刷、スクリーン印刷法などを用いるとよい。接着層15(接着層25)の乾燥膜厚は、1〜5μmとするのが一般的である。   Moreover, you may form the contact bonding layer 15 (adhesion layer 25) as needed. The adhesive layer 15 (adhesive layer 25) is a layer for adhering to the primary molding resin part 32 (secondary molding resin part 42). When the material of the primary molding resin part 32 (secondary molding resin part 42) is a polyacrylic resin, it is preferable to use a polyacrylic resin as the material of the primary molding resin part 32 (secondary molding resin part 42). . Also, when the material of the primary molding resin part 32 (secondary molding resin part 42) is polyphenylene oxide / polystyrene resin, polycarbonate resin, styrene copolymer resin, or polystyrene blend resin, it has an affinity for these resins. Polyacrylic resin, polystyrene-based resin, polyamide-based resin, or the like having a certain property may be used as the material for the adhesive layer 15 (adhesive layer 25). As a method for forming the adhesive layer 15 (adhesive layer 25), a coating such as a gravure coating method, a roll coating method, or a comma coating method, a gravure printing, a screen printing method, or the like may be used. The dry film thickness of the adhesive layer 15 (adhesive layer 25) is generally 1 to 5 μm.

1次成形樹脂31は、高熱伝導率物としてアルミニウム、タングステン、亜鉛、銀、金、白金、鉄、銅、カーボンなどを成形樹脂に混合させたものである。そのため、1次成形樹脂部32の熱伝導率は通常の樹脂成形品より高くなる。成形樹脂としては、通常の熱可塑性の射出成形樹脂やエンジニアリングプラスチックのほか、熱硬化性の成形樹脂材料など特に限定はされない。具体的には、アクリロニトリルブタジエンスチレン系樹脂(ABS系樹脂)、ポリアミド系樹脂、ポリエチレン系樹脂、ポリエステル系樹脂、ポリプロピレン系樹脂、ポリブチレンテレフタレート系樹脂、ポリカーボネート系樹脂(PC系樹脂)などが挙げられる。一般的なABS系樹脂やPC系樹脂の熱伝導率は0.1〜0.2W/m・Kであるが、高熱伝導率物を混合させることにより1次成形樹脂部32の熱伝導率を一桁以上向上させることができる。但し、過度に高熱伝導率物の比率を上げると耐衝撃性が失われてしまう問題が生じるので高熱伝導率物の配分比率には留意が必要である。   The primary molding resin 31 is obtained by mixing aluminum, tungsten, zinc, silver, gold, platinum, iron, copper, carbon, or the like as a high thermal conductivity material into a molding resin. Therefore, the thermal conductivity of the primary molded resin portion 32 is higher than that of a normal resin molded product. The molding resin is not particularly limited, such as a normal thermoplastic injection molding resin and engineering plastic, and a thermosetting molding resin material. Specific examples include acrylonitrile butadiene styrene resin (ABS resin), polyamide resin, polyethylene resin, polyester resin, polypropylene resin, polybutylene terephthalate resin, and polycarbonate resin (PC resin). . The heat conductivity of a general ABS resin or PC resin is 0.1 to 0.2 W / m · K. By mixing a high heat conductivity material, the heat conductivity of the primary molded resin portion 32 can be increased. It can be improved by an order of magnitude or more. However, if the ratio of the high thermal conductivity material is excessively increased, there is a problem that the impact resistance is lost. Therefore, attention should be paid to the distribution ratio of the high thermal conductivity material.

2次成形樹脂41としては、高熱伝導率物を含まない点で1次成形樹脂31と異なる他は1次成形樹脂31と同様の成形樹脂を使用できる。   As the secondary molding resin 41, a molding resin similar to the primary molding resin 31 can be used except that the secondary molding resin 41 is different from the primary molding resin 31 in that a high thermal conductivity material is not included.

上記の装置および材料を使用して、2色成形加飾品43を製造する方法を説明する。   A method for manufacturing the two-color molded decorative article 43 using the above-described apparatus and materials will be described.

まず、1次加飾シート11が配置された1次成形用キャビティ型2とコア型1とを型閉めして1次成形用キャビティ4を形成し、1次成形用キャビティ4内に高熱伝導率物を含有する1次成形樹脂31を射出して1次成形樹脂部32の表面に1次加飾層13が積層された1次成形加飾品33を形成する(図1(a)参照)。   First, the primary molding cavity mold 2 on which the primary decorative sheet 11 is disposed and the core mold 1 are closed to form a primary molding cavity 4, and a high thermal conductivity is formed in the primary molding cavity 4. The primary molded resin 31 containing the product is injected to form a primary molded decorative product 33 in which the primary decorative layer 13 is laminated on the surface of the primary molded resin portion 32 (see FIG. 1A).

ここで1次成型用キャビティ型2への1次加飾シート11を配置について詳しく説明する。   Here, the arrangement of the primary decorative sheet 11 on the cavity mold 2 for primary molding will be described in detail.

1次加飾シート11として基体シート12が剥離しないインサートシートを使用する場合、1次成形用キャビティ型2のキャビティ面には、1次加飾シート11の基体シート12側あるいは1次加飾層13側のどちらが配置されてもよい。このキャビティ面に基体シート12側を配置すると、後述の2次成形樹脂41の射出の際、基体シート12によりインキ流れを防ぐことができる。このキャビティ面に1次加飾層13側を配置すると、1次成形樹脂31が高熱伝導率物を含有して流動性が悪くなっていても1次成形樹脂31の射出の際、基体シート12によりインキ流れを防ぐことができる。ここで、1次加飾シート11として1次加飾層13が2枚のシートでサンドイッチされたものを使用すると、1次成形樹脂31と2次成形樹脂41との両方から1次加飾層13をシートで保護できるが、1.コストアップの問題と、2.シート厚み増により1次成形用キャビティ4や後述の2次成形用キャビティ5の厚みが減少して1次成形樹脂31や2次成形樹脂41の充填不良の問題の恐れがある点に留意する。   When an insert sheet from which the base sheet 12 is not peeled is used as the primary decorative sheet 11, the primary decorative cavity 11 has a cavity surface on the base sheet 12 side or the primary decorative layer. Either of the 13 sides may be arranged. If the base sheet 12 side is disposed on the cavity surface, the base sheet 12 can prevent ink flow when the secondary molding resin 41 described later is injected. When the primary decorative layer 13 side is arranged on the cavity surface, the base sheet 12 is injected during the injection of the primary molding resin 31 even if the primary molding resin 31 contains a high thermal conductivity material and the fluidity is deteriorated. Can prevent ink flow. Here, if the primary decorative layer 13 is sandwiched between two sheets as the primary decorative sheet 11, the primary decorative layer is formed from both the primary molded resin 31 and the secondary molded resin 41. 13 can be protected by a sheet. The problem of cost increase and 2. Note that the thickness of the primary molding cavity 4 and the later-described secondary molding cavity 5 is reduced by increasing the thickness of the sheet, which may cause a problem of poor filling of the primary molding resin 31 and the secondary molding resin 41.

1次加飾シート11として転写シートを使用する場合、1次成形用キャビティ型2のキャビティ面に1次加飾シート11の基体シート12側が配置して、基体シート12を剥離しても1次加飾層13が1次成形加飾品33上に残るようにする。   When a transfer sheet is used as the primary decorating sheet 11, the primary decorating sheet 11 is disposed on the side of the base sheet 12 on the cavity surface of the primary molding cavity mold 2, and the primary sheet is peeled off even if the base sheet 12 is peeled off. The decorative layer 13 is left on the primary molded decorative product 33.

1次成形加飾品33の形成後、コア型1が1次成形加飾品33を保持する状態で1次成形用キャビティ型2とコア型1とを型開きし、コア型1と対向する金型を1次成形用キャビティ型2から2次成形用キャビティ型3に切り替え、2次成形用キャビティ型3と1次成形加飾品33を保持するコア型1とを型閉めして1次成形加飾品33の表面に間隙による2次成形用キャビティ5を形成する。(図1(b)参照)。   After forming the primary molding ornament 33, the mold for opening the primary molding cavity mold 2 and the core mold 1 in a state where the core mold 1 holds the primary molding decoration 33, and facing the core mold 1. Is switched from the primary molding cavity mold 2 to the secondary molding cavity mold 3 and the secondary molding cavity mold 3 and the core mold 1 holding the primary molding decoration 33 are closed to form the primary molding decoration. A secondary molding cavity 5 is formed on the surface 33 by a gap. (See FIG. 1 (b)).

ここで、1次加飾シート11として転写シートを使用し、1次成形用キャビティ型2とコア型1との型開きから、2次成形用キャビティ型3と1次成形加飾品33を保持するコア型1との型閉めまでの間に、1次成形加飾品33から1次加飾シート11の基体シート12を剥離してもよい。   Here, a transfer sheet is used as the primary decorative sheet 11, and the secondary molding cavity mold 3 and the primary molded decorative product 33 are held from the mold opening between the primary molding cavity mold 2 and the core mold 1. The base sheet 12 of the primary decorative sheet 11 may be peeled off from the primary molded decorative product 33 until the core mold 1 is closed.

2次成形用キャビティ5内に2次成形樹脂41を射出して1次成形加飾品33の表面に2次成形樹脂部42が積層された2色成形加飾品43を形成する(図1(c)参照)。1次成形樹脂部32の熱伝導率は通常の樹脂成形品より高いので、2次成形樹脂41の射出の際、1次加飾層13に伝導する熱は1次成形樹脂部32を通してコア型1の方に放散させることができる。その結果、1次加飾層13は2次成形樹脂41によって加熱されて軟化することなく2次成形樹脂41の流動抵抗にも耐えて位置を保持することでき、2色成形加飾品43の外観不良の防止ができる。   A secondary molding resin 41 is injected into the secondary molding cavity 5 to form a two-color molded decorative article 43 in which the secondary molded resin portion 42 is laminated on the surface of the primary molded decorative article 33 (FIG. 1 (c). )reference). Since the thermal conductivity of the primary molded resin portion 32 is higher than that of a normal resin molded product, the heat conducted to the primary decorative layer 13 is injected into the core mold through the primary molded resin portion 32 when the secondary molded resin 41 is injected. It can be dissipated towards one. As a result, the primary decorative layer 13 can withstand the flow resistance of the secondary molding resin 41 without being heated and softened by the secondary molding resin 41, and can maintain the position. Defects can be prevented.

最後にコア型1と2次成形用キャビティ3とを型開きすると、2色成形加飾品43を得ることができる(図4(a)参照)。   Finally, when the core mold 1 and the secondary molding cavity 3 are opened, a two-color molded decorative article 43 can be obtained (see FIG. 4A).

また、基体シート22上に2次加飾層23が積層された2次加飾シート21が2次成形用キャビティ型3に配置される2色成形加飾金型を用いて、2次加飾シート21が配置された2次成形用キャビティ型3と1次成形加飾品33を保持するコア型1とを型閉めして2次成形用キャビティ5を形成し、2次成形用キャビティ5内に2次成形樹脂41を射出して1次成形加飾品33の表面に2次成形樹脂部42と2次加飾層23とが順次積層された2色成形加飾品43を形成してもよい(図3、図4(b)参照)。   Further, the secondary decoration sheet 21 in which the secondary decoration layer 23 is laminated on the base sheet 22 is used for the secondary decoration using a two-color molding decoration mold in which the secondary molding cavity mold 3 is disposed. The secondary mold cavity mold 3 on which the sheet 21 is arranged and the core mold 1 holding the primary molded decorative product 33 are closed to form the secondary mold cavity 5, and the secondary mold cavity 5 is formed. The secondary molded resin 41 may be injected to form a two-color molded decorative product 43 in which the secondary molded resin portion 42 and the secondary decorative layer 23 are sequentially laminated on the surface of the primary molded decorative product 33 ( (Refer FIG. 3, FIG.4 (b)).

ここで、2次加飾シート21として転写シートを使用し、2色成形加飾品43の形成後、2色成形加飾品43から2次加飾シート21の基体シート22を剥離してもよい。もちろんこの場合は2次成形用キャビティ型3のキャビティ面には2次加飾シート21の基体シート22側が配置されるようにする。   Here, a transfer sheet may be used as the secondary decorative sheet 21, and the base sheet 22 of the secondary decorative sheet 21 may be peeled from the two-color molded decorative article 43 after the two-color molded decorative article 43 is formed. Of course, in this case, the base sheet 22 side of the secondary decorative sheet 21 is arranged on the cavity surface of the cavity mold 3 for secondary molding.

本発明がとりうるその他の態様を以下に説明する。   Other embodiments that the present invention can take are described below.

1次成形樹脂31の1次成形用キャビティ4内への樹脂流路はコア型1にあってもよいし(図1参照)、1次成形用キャビティ型2にあってもよい(図5参照)。2次成形樹脂41の2次成形用キャビティ5内への樹脂流路はコア型1にあってもよいし(図1参照)、2次成形用キャビティ型3にあってもよい(図5参照)。   The resin flow path of the primary molding resin 31 into the primary molding cavity 4 may be in the core mold 1 (see FIG. 1) or in the primary molding cavity mold 2 (see FIG. 5). ). The resin flow path of the secondary molding resin 41 into the secondary molding cavity 5 may be in the core mold 1 (see FIG. 1) or in the secondary molding cavity mold 3 (see FIG. 5). ).

2色成形加飾品43の製造においては、2色成形加飾金型がコア型1を複数備えるようにして、可動盤または可動盤についている回転盤が回転する二色成形用の射出成形機に配置できる(図示せず)。射出成形機内での金型配置として、表面形成金型1と塗膜形成金型2とを固定盤に固定し、コア型1が射出成形機の可動盤または可動盤についている回転盤に固定すればよい。また、コア型1を固定盤に固定し、表面形成金型1と塗膜形成金型2とを射出成形機の可動盤または可動盤についている回転盤に固定してもよい。このように設置すると、あるコア型1と1次成形用キャビティ型2によって1次成形加飾品33を形成する間、別の1次成形加飾品33を保持するコア型1と2次成形用キャビティ型3によって2色成形加飾品43を形成する、すなわち1次成形加飾品33の形成と同時に2色成形加飾品43の製造ができ、好適である。   In the production of the two-color molded decorative article 43, a two-color molded decorative mold is provided with a plurality of core molds 1, and the movable plate or the rotary plate attached to the movable plate rotates. Can be placed (not shown). As the mold arrangement in the injection molding machine, the surface forming mold 1 and the coating film forming mold 2 are fixed to a stationary platen, and the core mold 1 is fixed to the movable platen of the injection molding machine or the rotating plate attached to the movable platen. That's fine. Alternatively, the core mold 1 may be fixed to a stationary platen, and the surface forming mold 1 and the coating film forming mold 2 may be fixed to a movable plate of an injection molding machine or a rotating plate attached to the movable platen. When installed in this manner, the core mold 1 and the secondary molding cavity for holding another primary molding decoration 33 while the primary molding decoration 33 is formed by a certain core mold 1 and the primary molding cavity mold 2. The two-color molded decorative article 43 is formed by the mold 3, that is, the two-color molded decorative article 43 can be manufactured simultaneously with the formation of the primary molded decorative article 33, which is preferable.

コア型1と、1次成形用キャビティ型2と、2次成形用キャビティ型3とを備える2色成形加飾金型を用意し、ポリエチレンテレフタレート樹脂からなる基体シート12上に着色インキによる1次加飾層13が積層された転写シートである1次加飾シート11、および、高熱伝導率物としてアルミニウム粉を70wt%含有するABS系樹脂の1次成形樹脂31、透明なアクリル系樹脂の2次成形樹脂41を用いて2色成形加飾品43を形成した。   A two-color molding decorative mold including a core mold 1, a primary molding cavity mold 2, and a secondary molding cavity mold 3 is prepared, and a primary color ink is formed on a base sheet 12 made of polyethylene terephthalate resin. The primary decorative sheet 11 which is a transfer sheet on which the decorative layer 13 is laminated, the ABS resin primary molding resin 31 containing 70 wt% of aluminum powder as a high thermal conductivity material, and a transparent acrylic resin 2 A two-color molded decorative article 43 was formed using the next molding resin 41.

まず、基体シート12がキャビティ面に面するように1次加飾シート11が配置された1次成形用キャビティ型2とコア型1とを型閉めして1次成形用キャビティ4を形成し、1次成形用キャビティ4内に1次成形樹脂31を射出して1次成形樹脂部32の表面に1次加飾層13が積層された1次成形加飾品33を形成した(図1(a)参照)。   First, the primary molding cavity mold 2 and the core mold 1 in which the primary decorative sheet 11 is disposed so that the base sheet 12 faces the cavity surface are closed to form the primary molding cavity 4. The primary molding resin 31 is injected into the primary molding cavity 4 to form a primary molding decoration 33 in which the primary decoration layer 13 is laminated on the surface of the primary molding resin portion 32 (FIG. 1A )reference).

次に、コア型1が1次成形加飾品33を保持する状態で1次成形用キャビティ型2とコア型1とを型開きし、1次成形加飾品33から基体シート12を剥離した後、コア型1と対向する金型を1次成形用キャビティ型2から2次成形用キャビティ型3に切り替え、2次成形用キャビティ型3と1次成形加飾品33を保持するコア型1とを型閉めして2次成形用キャビティ5を形成した(図1(b)参照)。   Next, the cavity mold 2 for primary molding and the core mold 1 are opened while the core mold 1 holds the primary molded decorative article 33, and the base sheet 12 is peeled off from the primary molded decorative article 33. The mold opposite to the core mold 1 is switched from the primary molding cavity mold 2 to the secondary molding cavity mold 3 and the secondary molding cavity mold 3 and the core mold 1 holding the primary molding decoration 33 are molded. Closed to form a secondary molding cavity 5 (see FIG. 1B).

そして、2次成形用キャビティ5内に2次成形樹脂41を射出して1次成形加飾品33の表面に2次成形樹脂部42が積層された2色成形加飾品43を形成した(図1(c)参照)。   Then, the secondary molding resin 41 is injected into the secondary molding cavity 5 to form a two-color molded decorative article 43 in which the secondary molded resin portion 42 is laminated on the surface of the primary molded decorative article 33 (FIG. 1). (See (c)).

最後にコア型1と2次成形用キャビティ3とを型開きすると、2色成形加飾品43を得ることができた(図4(a)参照)。   Finally, when the core mold 1 and the secondary molding cavity 3 are opened, a two-color molded decorative product 43 can be obtained (see FIG. 4A).

2次成形樹脂41の射出の際、1次加飾層13に伝導する熱は1次成形樹脂部32を通してコア型1の方に放散させることができた。その結果、1次加飾層13は2次成形樹脂41によって加熱されて軟化することなく2次成形樹脂41の流動抵抗にも耐えて位置を保持することできたので、得られた2色成形加飾品43は1次加飾層13のインキ流れによる外観不良のない美麗な製品であった。   When the secondary molding resin 41 was injected, the heat conducted to the primary decorative layer 13 could be dissipated toward the core mold 1 through the primary molding resin portion 32. As a result, the primary decorative layer 13 was able to withstand the flow resistance of the secondary molding resin 41 without being heated and softened by the secondary molding resin 41, so that the obtained two-color molding was obtained. The decorative product 43 was a beautiful product having no appearance defect due to the ink flow of the primary decorative layer 13.

1 コア型
2 1次成形用キャビティ型
3 2次成形用キャビティ型
4 1次成形用キャビティ
5 2次成形用キャビティ
11 1次加飾シート
12 基体シート
13 1次加飾層
14 剥離層
15 接着層
21 2次加飾シート
22 基体シート
23 2次加飾層
24 剥離層
25 接着層
31 1次成形樹脂
32 1次成形樹脂部
33 1次成形加飾品
41 2次成形樹脂
42 2次成形樹脂部
43 2色成形加飾品
101 コア型
102 1次成形用キャビティ型
103 2次成形用キャビティ型
104 1次成形用キャビティ
105 2次成形用キャビティ
111 1次加飾シート
112 基体シート
113 1次加飾層
131 1次成形樹脂
132 1次成形樹脂部
133 1次成形加飾品
141 2次成形樹脂
142 2次成形樹脂部
143 2色成形加飾品
1 Core mold 2 Cavity mold for primary molding 3 Cavity mold for secondary molding 4 Cavity for primary molding 5 Cavity for secondary molding 11 Primary decorative sheet 12 Base sheet 13 Primary decorative layer 14 Peeling layer 15 Adhesive layer 21 Secondary decorative sheet 22 Base sheet 23 Secondary decorative layer 24 Release layer 25 Adhesive layer 31 Primary molded resin 32 Primary molded resin part 33 Primary molded decorative product 41 Secondary molded resin 42 Secondary molded resin part 43 Two-color molded decorative article 101 Core mold 102 Primary molding cavity mold 103 Secondary molding cavity mold 104 Primary molding cavity 105 Secondary molding cavity 111 Primary decorative sheet 112 Base sheet 113 Primary decorative layer 131 Primary molded resin 132 Primary molded resin part 133 Primary molded decorative article 141 Secondary molded resin 142 Secondary molded resin part 143 Two-color molded decorative article

Claims (4)

コア型と、基体シート上に1次加飾層が積層された1次加飾シートが配置される1次成形用キャビティ型と、2次成形用キャビティ型とを備える2色成形加飾金型を用い、
1次加飾シートが配置された1次成形用キャビティ型とコア型とを型閉めして1次成形用キャビティを形成し、1次成形用キャビティ内に高熱伝導率物を含有する1次成形樹脂を射出して1次成形樹脂部の表面に1次加飾層が積層された1次成形加飾品を形成し、
コア型が1次成形加飾品を保持する状態で1次成形用キャビティ型とコア型とを型開きし、コア型と対向する金型を1次成形用キャビティ型から2次成形用キャビティ型に切り替え、2次成形用キャビティ型と1次成形加飾品を保持するコア型とを型閉めして2次成形用キャビティを形成し、
2次成形用キャビティ内に2次成形樹脂を射出して1次成形加飾品の表面に2次成形樹脂部が積層された2色成形加飾品を形成することを特徴とする2色成形加飾品の製造方法。
Two-color molding decorative mold comprising a core mold, a primary molding cavity mold in which a primary decorative sheet in which a primary decorative layer is laminated on a base sheet is disposed, and a secondary molding cavity mold Use
The primary molding cavity mold and the core mold on which the primary decorative sheet is disposed are closed to form a primary molding cavity, and the primary molding contains a high thermal conductivity material in the primary molding cavity. The resin is injected to form a primary molded decorative product in which a primary decorative layer is laminated on the surface of the primary molded resin portion,
The primary mold cavity mold and the core mold are opened while the core mold holds the primary molded decorative product, and the mold facing the core mold is changed from the primary mold cavity mold to the secondary mold cavity mold. Switch to form a secondary molding cavity by closing the secondary molding cavity mold and the core mold holding the primary molded decorative product,
A two-color molded decorative product, characterized in that a secondary molded resin is injected into the secondary molding cavity to form a two-color molded decorative product in which the secondary molded resin portion is laminated on the surface of the primary molded decorative product. Manufacturing method.
1次加飾シートとして転写シートを使用し、1次成形用キャビティ型とコア型との型開きから、2次成形用キャビティ型と1次成形加飾品を保持するコア型との型閉めまでの間に、1次成形加飾品から1次加飾シートの基体シートを剥離する請求項1に記載の2色成形加飾品の製造方法。   Using a transfer sheet as the primary decorative sheet, from the opening of the primary mold cavity mold and the core mold to the closing of the secondary mold cavity mold and the core mold holding the primary molded decorative product The method for producing a two-color molded decorative article according to claim 1, wherein the base decorative sheet is peeled from the primary molded decorative article. 基体シート上に2次加飾層が積層された2次加飾シートが2次成形用キャビティ型に配置される2色成形加飾金型を用い、
2次加飾シートが配置された2次成形用キャビティ型と1次成形加飾品を保持するコア型とを型閉めして2次成形用キャビティを形成し、
2次成形用キャビティ内に2次成形樹脂を射出して1次成形加飾品の表面に2次成形樹脂部と2次加飾層とが順次積層された2色成形加飾品を形成する請求項1または2に記載の2色成形加飾品の製造方法。
Using a two-color molded decorative mold in which a secondary decorative sheet in which a secondary decorative layer is laminated on a base sheet is disposed in a secondary mold cavity mold,
Closing the secondary mold cavity mold in which the secondary decorative sheet is arranged and the core mold holding the primary molded decorative article to form a secondary mold cavity,
The secondary molding resin is injected into the secondary molding cavity to form a two-color molded decorative article in which a secondary molded resin portion and a secondary decorative layer are sequentially laminated on the surface of the primary molded decorative article. A method for producing a two-color molded decorative article according to 1 or 2.
2次加飾シートとして転写シートを使用し、2色成形加飾品の形成後、2色成形加飾品から2次加飾シートの基体シートを剥離する請求項3に記載の2色成形加飾品の製造方法。   The transfer sheet is used as a secondary decorative sheet, and the base sheet of the secondary decorative sheet is peeled from the two-color molded decorative article after the two-color molded decorative article is formed. Production method.
JP2009085142A 2009-03-31 2009-03-31 Method of manufacturing 2-color molding decorative article Withdrawn JP2010234648A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101615323B1 (en) * 2015-07-10 2016-04-25 이중재 Method for forming plastic product which film is laid in
KR101615325B1 (en) * 2015-07-10 2016-04-25 이중재 Method for forming plastic product which film is laid in
KR20170104283A (en) * 2016-03-07 2017-09-15 이중재 Method and double injection mold for forming plastic product which film is laid in

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101615323B1 (en) * 2015-07-10 2016-04-25 이중재 Method for forming plastic product which film is laid in
KR101615325B1 (en) * 2015-07-10 2016-04-25 이중재 Method for forming plastic product which film is laid in
KR20170104283A (en) * 2016-03-07 2017-09-15 이중재 Method and double injection mold for forming plastic product which film is laid in
KR101895253B1 (en) 2016-03-07 2018-09-07 이정배 Method and double injection mold for forming plastic product which film is laid in

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