JP2010186172A - Plastic optical fiber cable - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a POF cable which is suitable for an optical information communication such as a home network and an office network, is excellent in color hue and flexibility, gives small leakage of light even when installed in a curved state, and suitable for use in the information communication in a short or intermediate distance. <P>SOLUTION: The plastic optical fiber cable is composed of a plastic optical fiber and a coating layer coating the plastic optical fiber. The outer diameter of the plastic optical fiber cable is 1 to 3 mm, the coating layer is composed of at least two layers of a light leakage prevention layer containing 0.3 to 2.5 mass% black pigment in a resin and a colored outer layer containing 3 to 10 mass% color pigment other than black in the resin, and the ratio of the thickness of the light leakage prevention layer to that of the colored outer layer is 50:50 to 15:85. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a plastic optical fiber cable suitable for optical information communication in a home network in a home, an office network, and the like, and suitable for use in information communication over short and medium distances.

  Conventionally, silica-based optical fibers capable of excellent light transmission over a wide wavelength range are known as optical fibers, and they have been put to practical use mainly in trunk systems, but these silica-based optical fibers are expensive and workable. Is low. Therefore, a plastic optical fiber (hereinafter abbreviated as “POF”) having advantages such as cheaper, lighter, larger diameter, and easy to process and handle end faces has been developed. It has been put to practical use in the field of wiring for short / medium distance communications such as OA and LAN.

  POF is used as a signal transmission line in combination with a visible red light source such as an LED. When POF is used as an indoor wiring, it is generally laid in a bent state in a narrow space. For this reason, there is a demand for a combined light loss between the POF and the light emitting / receiving element and a small light loss due to bending.

  Further, the POF used for such applications is usually used in the form of a POF cable in which a POF strand is coated with a resin. In particular, for POF cables used in home networks for homes and offices, light-colored cables such as white are often preferred from the viewpoint of design, and light leakage due to bending of red LED light when laid However, there is a problem in that light from the side surface invades the transmission of light.

  In order to solve such problems, many techniques relating to POF cables in which a resin to be coated around the POF is selected or a colored outer layer is provided have been reported.

  For example, Patent Document 1 and Patent Document 2 propose a POF cable excellent in preventing light from entering from the side surface by providing a black inner layer and a colored outer layer on the outer periphery of the POF. Patent Documents 1 and 2 describe a colored POF cable centered on a polyamide-based resin. However, in the case of indoor wiring that has a large bending elastic modulus and is often laid in a bent state, a polyamide-based resin is not used. There was a problem that it was difficult to handle. In addition, in order to reduce the penetration of light from the side into the POF cable, it is necessary to make the black layer of the inner layer a certain thickness or more, the color tone of the POF cable is lowered, and a desired light color POF cable is obtained. There was no problem.

JP 11-242142 A JP-A-10-307218

  An object of the present invention is to provide a POF cable that is excellent in color tone and flexibility, has little light leakage even when laid in a bent state, and is suitable for use in information communication over short and medium distances.

  The present inventors can solve the problem by providing at least two layers of a POF coating layer of a light leakage prevention layer containing a black pigment and a colored outer layer containing a color pigment other than black at a specific thickness ratio. Heading The present invention has been completed.

  Here, the plastic optical fiber cable of the present invention is a plastic optical fiber cable comprising a plastic optical fiber and a coating layer covering the plastic optical fiber, and the outer diameter of the plastic optical fiber cable is in the range of 1 to 3 mm. And at least 2 of a light leakage preventing layer containing 0.3 to 2.5% by mass of a black pigment in the resin and a colored outer layer containing 3 to 10% by mass of a color pigment other than black in the resin. It consists of a layer, The ratio of the thickness of the said light leakage prevention layer and the said colored outer layer exists in the range of 50: 50-15: 85, It is characterized by the above-mentioned.

  According to the present invention, it is possible to provide a POF cable for information communication that has a good appearance such as designability (colorability) and has little light leakage even in a bent state, and more preferably, a light color POF cable, particularly a white POF cable. Can provide.

FIG. 1 is a cross-sectional view of a POF cable. FIG. 2 is a cross-sectional view of a two-core parallel POF cable. FIG. 3 is a cross-sectional view of another structure of the two-core parallel POF cable.

  Hereinafter, an embodiment of the present invention will be described with reference to FIG.

  FIG. 1 is a cross-sectional view showing an embodiment of a POF cable according to the present invention. A light leakage prevention layer 13 is formed on the outer periphery of the POF 12 including the core 11A and the sheath 11B formed on the outer periphery thereof, and a colored outer layer 14 is formed on the outer side thereof.

  Here, as the POF 12, a known one can be used in addition to the configuration shown in FIG. 1, for example, a GI POF in which the refractive index of the core 11A continuously decreases from the center toward the outer periphery, and from the center toward the outside. A multilayer POF in which the refractive index of the core 11A gradually decreases, a multi-core POF in which a plurality of cores 11A are surrounded by a sheath, and the like are listed. In particular, it is more preferable to use a multilayer POF in order to increase the bandwidth of the POF and perform high-speed signal transmission.

  For the core 11A, various highly transparent polymers are used, and are not particularly limited, but a polymer containing a methyl methacrylate unit as a constituent unit is preferably used. More preferably, it is a methyl methacrylate homopolymer, a polymer having a methyl methacrylate unit as a main constituent unit, or a polymer having a fluorinated alkyl methacrylate unit as a main constituent unit. Among these, a methyl methacrylate homopolymer is Particularly preferable from the viewpoint of excellent heat resistance and transparency.

  The sheath formed on the outer periphery of the core may be formed from one layer or may be formed from a plurality of layers of two or more layers. As the resin forming the sheath, a known material as a sheath material of POF such as a fluorinated methacrylate polymer, a vinylidene fluoride polymer, a tetrafluoroethylene polymer, or the like can be appropriately selected. In particular, a fluorinated methacrylate polymer is preferable because it is easy to adjust the refractive index and is excellent in flexibility and workability while having good transparency and heat resistance.

Such POF 12 can be produced by a known method such as a melt spinning method. Further, when the POF 12 is used in an environment having a large temperature difference, it is more preferable to perform an annealing process by continuous or batch processing in order to suppress pistoning.
The POF cable according to the present invention may be a multi-core parallel cable in which a plurality of plastic optical fibers are arranged in parallel at a constant interval.
When the POF cable is used for communication, it is necessary to connect one end of the POF cable to the light source system and connect the other end to the light receiving system. In that case, when performing bidirectional communication, bidirectional communication can be easily performed by using two POF cables so that such a light source-light receiving system is prepared. Therefore, a two-core POF cable as shown in FIGS. 2 and 3 may be used by using two POFs.
FIG. 2 is a cross-sectional view of a two-core parallel POF cable in which the colored outer layers 14 of the two POF cables are joined. In order to manufacture a POF cable having such a structure, for example, a light leakage prevention layer 13 is formed on the outer periphery of the POF 12 using a crosshead die extrusion coating apparatus, and then a batch type two-core die / nipple is provided. It can be obtained by coating the colored outer layer 14 with a crosshead.
FIG. 3 is a cross-sectional view of another structure of the two-core parallel POF cable, in which the light leakage prevention layer 13 and the colored outer layer 14 of the two POF cables are combined. In order to manufacture a POF cable having such a structure, the POF 12 can be coated using, for example, a crosshead die extrusion coating apparatus having a die / nipple for two layers and two cores. If such an apparatus is used, it becomes possible to coat | cover the coating resin which forms the light leakage prevention layer 13 and the colored outer layer 14 simultaneously on the outer periphery of a POF strand simultaneously using one crosshead die.

  The POF cable of the present invention comprises POF and a coating layer covering the POF. The coating layer is composed of at least two layers, a light leakage prevention layer and a colored outer layer. The light leakage prevention layer is not particularly limited, but is preferably the innermost layer of the coating layers, that is, the layer in contact with POF.

  The coating material used as the light leakage preventing layer and the colored outer layer is not particularly limited as long as it has an appropriate flexibility and a good moldability in the coating process and has an appropriate melting point. , Vinyl chloride resin, polypropylene resin, urethane resin and the like. For these coating materials, the same resin may be used for the light leakage prevention layer and the colored outer layer, or different resins may be used. Among these, polyethylene resin and vinyl chloride resin can be preferably used in terms of ease of coating, production cost, and the like, and more preferably, low density polyethylene (for example, high pressure method low density polyethylene) can be used. . The resin density of this low density polyethylene is typically in the range of 0.910 to 0.930 (see JIS K6748: 1995). The measurement of the resin density is typically based on JIS K-0061 1992 and JIS K-7112 1980, using the density gradient tube method, for example, density gradient tube method direct reading specific gravity measurement manufactured by Shibayama Scientific Instruments Co., Ltd. It can be measured using a device.

  The light leakage prevention layer contains at least a black pigment in the resin, and contains 0.3 to 2.5% by mass of the black pigment in the total amount of the light leakage prevention layer. Although it does not restrict | limit especially as a black pigment, Carbon black is preferable from a viewpoint of providing the function which prevents the light leakage from POF to a coating layer, and prevents the incidence of external light inside POF. The lower limit of the black pigment content is preferably 0.3% by mass or more, more preferably 0.4% by mass or more, and particularly preferably 0.45% by mass or more from the viewpoint of preventing light leakage. In addition, the upper limit of the black pigment content is 2.5% by mass or less from the viewpoint of cable strength, the aspect of suppressing optical property deterioration due to the pigment migration into the POF, and the design aspect of color development of the cable. Preferably, 1.5 mass% or less is more preferable, and 0.6 mass% or less is particularly preferable.

  The colored outer layer contains at least a colored pigment other than black in the resin, and contains 3 to 10% by mass of the colored pigment other than black in the total amount of the colored outer layer. The function of the colored outer layer is to impart distinguishability, designability, etc. to the POF cable. The lower limit of the content of the color pigment other than black is preferably 3% or more. If the amount of the color pigment is less than 3%, when the ratio of the layer ratio of the light leakage prevention layer and the colored outer layer described later is set to a certain value or less, the black color of the base can be seen through and the color tone of the POF cable is deteriorated. It is not preferable. The lower limit of the content of the color pigment other than black is particularly preferably 4% or more. Further, the upper limit of the content of the color pigment other than black is preferably 10% by mass or less. If the coloring pigment is added in an amount exceeding 10% by mass, the strength of the cable is lowered, and the coating layer is cracked and leaks when laid in a bent state over a long period of time, which is not preferable. The upper limit of the content of color pigments other than black is particularly preferably 7% by mass or less.

  In addition, the POF cable is usually a fiber optic cable with a plug in which a plug is attached to the end of the cable for joining a light source as a signal source, a housing of a unit incorporated in a detector, or another POF cable. used. This plug includes a plug main body and a stopper that is attached to the plug main body and fixes the POF cable, and has a hole diameter of about 1 to 3 mm, particularly generally about 1.50 mm. Therefore, the outer diameter of one POF cable is preferably 1 to 3 mm, particularly 1.48 to 1.52 mm, and if it is more than that, it becomes difficult to connect to a plug having a hole diameter of about 1.50 mm. Therefore, considering that the outer diameter of general POF is 1.0 mm, the thickness of the coating layer is preferably 0.24 to 0.26 mm. Furthermore, in the present invention, since it has a light leakage preventing layer for preventing light leakage when bent and laid and a colored outer layer for imparting design properties, the characteristics are not impaired within the thickness range of this coating layer. It is necessary to determine an appropriate thickness ratio of both layers.

Therefore, in order to obtain a sufficient light leakage effect and good design properties, the thickness ratio of the light leakage prevention layer to the colored outer layer (light leakage prevention layer: colored outer layer) is preferably in the range of 50:50 to 15:85.
The light leakage prevention layer is in the range of 37.5 to 125 μm, the colored outer layer is preferably in the range of 125 to 212.5 μm, the light leakage prevention layer is in the range of 40 to 120 μm, and the colored outer layer is in the range of 130 to 210 μm. Is more preferable, and the most preferable range is a thickness of 50 to 100 μm for the light leakage preventing layer and 150 to 200 μm for the colored outer layer. When the outer diameter of the POF is 1.0 mm and the outer diameter of the POF cable is 1.5 mm, the thickness ratio between the light leakage prevention layer and the colored outer layer, 50:50 to 15:85, 48:52 to It corresponds to 16:84, 40:60 to 20:80. When the thickness of the light leakage prevention layer is 37.5 μm or less, when the POF is bent and laid, not only a sufficient light blocking effect is obtained, but also the light is leaked. This is not preferable because it is difficult to obtain an outer diameter POF cable. In addition, although the light leakage prevention thickness is 125 μm or more, there is a light blocking effect, but considering the outer diameter of the POF cable, the colored outer layer to be coated becomes thinner and the underlying black color can be seen through. It is not preferable from the viewpoint of sex. In particular, since the white POF cable is preferred for a POF cable used for a home network in a home or an office network, the influence is remarkable.

  Furthermore, the average particle diameter of the color pigments other than black is preferably 0.15 μm to 5 μm (electron micrograph). The lower limit of the average particle diameter of the color pigments other than black is particularly preferably 0.20 μm or more from the viewpoint of pigment dispersibility and the bleeding out of the pigment to the POF cable surface. In addition, the upper limit of the average particle diameter is preferably 1 μm or less, particularly preferably 0.5 μm or less, in terms of the hiding power, the colored surface, and the surface state (bumps and bumps) of the POF cable. Here, the pigment hiding power referred to in the present application is defined as a force capable of improving the color tone of the cable without minimizing the amount of the pigment added to the coating resin and transmitting the base black. If the particle diameter is small, when compared with pigments of the same weight, the hiding power increases because the specific surface area increases.

The color pigment satisfying these conditions is not particularly limited as long as it is a color pigment other than black, and known ones from inorganic pigments and organic pigments can be used. For example, titanium dioxide, zinc oxide, etc. as white pigments, azo organic pigments, yellow lead, chrome yellow, zinc yellow, etc. as yellow pigments, green pigments such as ultramarine blue and cobalt blue as blue pigments Examples thereof include chromium oxide and cobalt green. In particular, as the white pigment, titanium dioxide and zinc oxide are preferable, and titanium dioxide is particularly preferable from the viewpoint of the concealment rate and coloring power. Further, ultramarine blue is preferable as the blue pigment, and chromium oxide is particularly preferable as the green pigment from the viewpoint of the concealment ratio and coloring power.
In addition, although the inorganic pigment said here can be divided into various kinds in the structure, any may be used. For example, regarding titanium dioxide, there are a rutile type and an anatase type depending on the crystal structure, and any type can be used.

  EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated, the scope of the present invention is not limited to these Examples. Each evaluation method in the examples is as follows.

[Transmission loss]
The transmission loss (dB / km) was measured by a 25m-5m cutback method. Light having a measurement wavelength of 650 nm and an incident light NA (numerical aperture) of 0.1 was used. In addition, the measurement was performed by fixing to a fixing jig having a bending radius of 25 mm at a position 3 m from the light source.

[Light leakage observation (light intensity relative value)]
A POF cable having a length of 5 m connected to a red light emitting LED light source (center wavelength: 630 nm) having a voltage of 5.02 V and a current of 0.1 A was set on a bending jig having a bending radius of φ = 25 mm at a portion of about 18 cm from the light source. The light leaked from the bent part of the POF cable was fixed with a spectrophotometer PMA-11 manufactured by Hamamatsu Photonics at a position 3.5 mm from the bent part, and the amount of leaked light was measured. The amount of light leaked was calculated as a relative value using the amount of light leaked from the POF cable produced in Comparative Example 1 described later as a reference value (100%).

[Light leakage observation (visual judgment)]
In order to determine whether or not light leaks, fix fixture POF cables with a bending radius of 20 mm and 30 mm in a dark room with 3m square covered with a light-shielding sheet with a light transmittance of 0.0%, and acclimatize the eyes for 10 minutes in the dark room. After that, light leakage was judged visually. Judgment was evaluated as ◯ (passed) for those that were not visually confirmed, △ (impossible) for light leakage that could be confirmed with close eyes, and X (impossible) for light leakage that could be confirmed immediately. Depending on the degree of light leakage, more severe ones were marked with xx.

[Cable color tone]
The color of the cable recorded the closest color number of the German standard color chart RAL DESIGN System. The color tone of the POF cable produced in Comparative Example 1 described later is the reference color RAL9003 (signal white), and in the order from white to black, then RAL9016 (traffic white), RAL7047 (telegrey 4), RAL7040 (window gray) And ranked. The color tone of the cable was also confirmed by visual inspection without comparing with the standard color chart.

[Example 1]
As a core material, a homopolymer (PMMA) of methyl methacrylate (MMA), a sheath material has a two-layer structure, and 2,1,2-trifluoroethyl methacrylate (3FM) / 1,1,2, as a first sheath layer , 2-perfluorodecyl methacrylate (17FM) / MMA / methacrylic acid (MAA) = 31/50/18/1 (wt%) copolymer, vinylidene fluoride / tetrafluoroethylene = 80 / as the second sheath layer 20 (mol%), melted, concentrically stacked in order from the center, and composite-spun, POF having a core diameter of 970 μm, a first sheath layer of 5 μm, and a second sheath layer of 10 μm and an outer diameter of 1.0 mm Got.

Then, the polyethylene as the light leakage prevention layer (manufactured by Ube Industries, Ltd.: UBE Polyethylene UBEC180, resin density of 0.924 g / cm ³⁾ carbon black (manufactured by Mitsubishi Chemical Corporation: Mitsubishi Carbon Black Generic Color (RCF) # 45L, the average particle diameter of 24nm ) Was used in an amount of 0.45% by mass. As the colored outer layer, polyethylene (trade name: UBE polyethylene UBEC180, manufactured by Ube Industries, Ltd.) containing 5% by mass of titanium dioxide (Ishihara Sangyo Co., Ltd .: CR-60) having an average particle size of 0.21 μm was used. . These were supplied to a resin-coated crosshead type coating device, and both coating materials were sequentially coated on the outer periphery of the POF to obtain a POF cable having an outer diameter of 1.5 mm. At this time, the thickness of the light leakage preventing layer was 100 μm, and the thickness of the colored outer layer was 150 μm. The POF cable thus obtained was evaluated by the above evaluation method, and the results are shown in Table 1. As can be seen from Table 1, the transmission loss was excellent, the amount of light leakage at the bent portion was small, and no light leakage was confirmed by visual judgment. Also, the color of the cable was excellent.

[Examples 2 to 4]
A POF cable was produced in the same manner using the same coating material as in Example 1 except that the amount and thickness of the pigment added to the light leakage prevention layer and the colored outer layer were changed to the conditions shown in Table 1. Various characteristics of the obtained POF cable were evaluated, and the results are shown in Table 1. The POF cables obtained in Examples 2 to 4 had a small amount of light leakage at the bent portion, and no light leakage was confirmed by visual judgment. The color of the POF cable was also beautiful white. The results are shown in Table 1.

[Examples 5 to 7]
A POF cable was produced in the same manner using the same coating material as in Example 3 except that the type of titanium dioxide used in the colored outer layer was changed to that shown in Table 2. That is, 0.45% of carbon black was added to the light leakage prevention layer, and 5% of titanium oxide from the manufacturer shown in Table 2 was added to the colored outer layer. The thicknesses of the light leakage prevention layer and the colored outer layer were 80 μm and 170 μm, respectively. The obtained POF cable had a leaking light amount and a good color tone, both of which were not visually recognized, regardless of the type of pigment.

[Comparative Example 1]
A POF cable was produced in the same manner as in Example 1 except that the light leakage prevention layer was not provided and the addition amount of titanium dioxide was changed as shown in Table 1. The obtained POF cable was severely leaked when bent. The results are shown in Table 1.

[Comparative Examples 2 to 6]
A POF cable was obtained in the same manner as in Example 1 except that the addition amounts of carbon black and titanium dioxide were changed as shown in Table 1, and the thicknesses of the light leakage prevention layer and the colored outer layer were changed as shown in Table 1.

  In Comparative Examples 2 and 5, the obtained POF cable was conspicuous in light leakage from the bent portion, and the required POF cable could not be obtained. In Comparative Example 3, although the obtained POF cable did not leak light from the bent portion, the color tone of the cable was bad and the desired POF cable could not be obtained. Further, for Comparative Examples 4 and 6, although the obtained POF cable had little light leakage from the bent portion, light leakage could be confirmed by visual judgment.

表１に示したように、実施例１〜４で得られたＰＯＦケーブルは、屈曲部の漏れ光量も少なく、目視による判断では漏光が確認されなかった。またＰＯＦケーブルの色調も白色が発現し良好であった。

As shown in Table 1, the POF cables obtained in Examples 1 to 4 had a small amount of leakage light at the bent portion, and no leakage was confirmed by visual judgment. Also, the color tone of the POF cable was good with white color.

  On the other hand, the POF cable coated without the light leakage prevention layer as in Comparative Example 1 was able to exhibit white color tone, but the light leakage at the bent portion was intense, and the required POF cable could not be obtained. .

In addition, as shown in Comparative Examples 2 to 6, in the POF cable produced by changing the thickness ratio of the light leakage prevention layer and the colored outer layer and the content of the color pigment, there is much light leakage from the bent portion, and the color appearance of the cable appearance is A good white result could not be obtained because a beautiful white color could not be developed.
Furthermore, as shown in Examples 5-7, by using a pigment within a predetermined range even if the average particle diameter of the pigment (titanium dioxide) and the pigment structure of the colored outer layer are changed as shown in Table 2, a desired range can be obtained. I got a POF cable.

11A ... core 11B ... sheath 12 ... POF
13 ... Inner layer (light leakage prevention layer)
14 ... Outer coating layer (colored outer layer)

Claims (5)

A plastic optical fiber cable comprising a plastic optical fiber and a coating layer covering the plastic optical fiber,
The outer diameter of the plastic optical fiber cable is in the range of 1 to 3 mm,
The coating layer includes at least two layers of a light leakage preventing layer containing 0.3 to 2.5% by mass of a black pigment in the resin and a colored outer layer containing 3 to 10% by mass of a color pigment other than black in the resin. Become
A plastic optical fiber cable, wherein the thickness ratio between the light leakage preventing layer and the colored outer layer is in the range of 50:50 to 15:85.   The plastic optical fiber cable according to claim 1, wherein the colored pigment other than black contained in the colored outer layer is a white pigment.   The plastic optical fiber cable according to claim 1 or 2, wherein the resin used for the coating layer is at least one resin selected from the group consisting of polyethylene resin, vinyl chloride resin, polypropylene resin, and urethane resin.   The plastic optical fiber cable according to claim 3, wherein the resin used for the coating layer is low-density polyethylene.   The plastic optical fiber cable according to any one of claims 1 to 4, wherein the plastic optical fiber cable is a multi-core parallel cable in which a plurality of plastic optical fibers are arranged in parallel at regular intervals.

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