JP2010124748A - Method for producing flavor-stabilized fermented malt beverage - Google Patents

Method for producing flavor-stabilized fermented malt beverage Download PDF

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JP2010124748A
JP2010124748A JP2008302523A JP2008302523A JP2010124748A JP 2010124748 A JP2010124748 A JP 2010124748A JP 2008302523 A JP2008302523 A JP 2008302523A JP 2008302523 A JP2008302523 A JP 2008302523A JP 2010124748 A JP2010124748 A JP 2010124748A
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wort
fermented malt
flavor
activated carbon
malt beverage
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Kiyoaki Yano
聖明 矢野
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Kirin Brewery Co Ltd
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<P>PROBLEM TO BE SOLVED: To provide a method for producing a fermented malt beverage, suppressing deteriorated smell by reducing the content of a deteriorated smell-causing substance in the fermented malt beverage, inhibiting the reduction of its extract part by the reduction treatment as much as possible, inhibiting the cost up by the loss of the extract and without affecting the other flavor. <P>SOLUTION: This production process of the fermented malt beverage is provided by treating secondary squeezed wort prepared in a brewed wort-filtering process by using activated charcoal having 1.5 to 2.0 nm mean pore diameter under the conditions of 1.5 to 3 g/L adding amount, ≥78°C wort temperature and ≥1 min reaction-treating time to reduce the potential content of the deteriorated smell-causing substance, trans-2-nonenal and produce the flavor-stabilized fermented malt beverage. By this method, the deteriorated smell-causing substance is reduced, only the deteriorated smell is reduced without affecting the other flavor, and also without inviting the cost up by the loss of the extract, and it is possible to produce the flavor-stabilized fermented malt beverage. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法、特に、発酵麦芽飲料中の劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減することで、劣化臭を抑制し、低減化処理によるエキス分の低減化を極力抑えて、エキス損失によるコスト高を抑制し、その他の香味に影響を及ぼさない発酵麦芽飲料の製造方法に関する。   The present invention relates to a method for producing a fermented malt beverage in which the content of deteriorated odor causing substance trans-2-nonenal potential is reduced and the flavor is stabilized, in particular, the deteriorated odor causing substance trans-2-nonenal potential in fermented malt beverage Of fermented malt beverage that suppresses deterioration odor, suppresses reduction of extract content by reduction process, suppresses cost increase due to loss of extract, and does not affect other flavors. It relates to a manufacturing method.

ビールや発泡酒等の発酵麦芽飲料は時間の経過とともに香味の劣化が進行し、新鮮なビールの本来の香味が損なわれる。麦芽発酵飲料の香味劣化については、これまで多くの研究がなされており、アミノ酸および糖のメイラード反応およびストレッカー分解、脂肪酸の酸化、高級アルコールの酸化、等の反応が原因として提唱されている(Vanderhaegen. B. et al., Food Chemistry, 95, p 357-381,2006)。その中で、脂肪酸の酸化に関わる指標物質としてトランス−2−ノネナール(T2N)が知られている。トランス−2−ノネナールはビール貯蔵中に増加し(Schieberle, P., Zeitschrift fuer Lebensmittel Untersuchung und Forshung, 193, 558-565, 1991)、ビール中の含量が閾値を超えるため(Hashimoto, N., Journal of the American Society of Brewing Chemists, 35, 1977, 145-150)、ビールの劣化指標と考えられている。   Fermented malt beverages such as beer and sparkling liquor deteriorate in flavor over time, and the original flavor of fresh beer is impaired. Much research has been conducted on the flavor deterioration of malt fermented beverages, and it has been proposed because of reactions such as Maillard reaction of amino acids and sugars and Strecker degradation, oxidation of fatty acids, oxidation of higher alcohols, etc. ( Vanderhaegen. B. et al., Food Chemistry, 95, p 357-381, 2006). Among them, trans-2-nonenal (T2N) is known as an indicator substance related to fatty acid oxidation. Trans-2-nonenal increases during beer storage (Schieberle, P., Zeitschrift fuer Lebensmittel Untersuchung und Forshung, 193, 558-565, 1991) and the content in beer exceeds the threshold (Hashimoto, N., Journal of the American Society of Brewing Chemists, 35, 1977, 145-150).

そこで、先に、安井らは、製品の保存により生じる製品ビール中のトランス−2−ノネナール量を推測するには、濾過麦汁中のトランス−2−ノネナールの前駆体を把握することが重要であることをつきとめ、該トランス−2−ノネナールの前駆体を、一定のpHに調整した濾過麦汁を一定時間煮沸したときのトランス−2−ノネナール量、すなわちトランス−2−ノネナール ポテンシャル(NP)として把握して、該数値が劣化臭の指標として有効であることを開示した(WO01/085899)。   Therefore, in order to estimate the amount of trans-2-nonenal in product beer generated by product preservation, Yasui et al. First, it is important to grasp the precursor of trans-2-nonenal in filtered wort. As a result, the trans-2-nonenal precursor was converted into trans-2-nonenal potential (NP) when the filtered wort adjusted to a constant pH was boiled for a certain time. It has been grasped and disclosed that the numerical value is effective as an indicator of a deterioration odor (WO01 / 088589).

そして、安井らは、ビールの劣化臭生成の抑制についての研究の過程で、ビール製造工程中におけるトランス−2−ノネナール前駆体の挙動を詳細に検討したところ、二番搾り工程で、濾過麦汁中の糖含量は濾過液量の増加に概ね比例して漸次低下するが、トランス−2−ノネナール ポテンシャル(NP含量)は糖分の低下に相関することなく、高い値で推移することを突き止めた。そこで、発酵麦芽飲料の製造における仕込麦汁の濾過工程において、二番搾り麦汁における劣化臭原因物質の低減化処理を、トランス−2−ノネナール ポテンシャルを指標として行い、全濾過麦汁中のトランス−2−ノネナール ポテンシャルを所定量(糖度11゜p換算で、少なくとも1ppb)低減させるように、二番搾り麦汁における劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量の低減化を行うことにより、劣化臭原因物質を低減し、しかも、糖分の低下を実用上問題とならない程度に抑えた、トランス−2−ノネナール ポテンシャルの含有量を低減した発酵麦芽飲料用麦汁の製造方法を開示した(WO01/085899:特許第3831256号公報)。   And Yasui et al. Examined the behavior of the trans-2-nonenal precursor in the beer manufacturing process in detail in the process of studying the suppression of beer odor generation, and in the second squeezing process, filtered wort The sugar content in the sample gradually decreased in proportion to the increase in the amount of filtrate, but it was found that the trans-2-nonenal potential (NP content) remained high without correlating with the decrease in sugar content. Therefore, in the filtration process of the prepared wort in the production of fermented malt beverage, the degradation odor-causing substance in the second wort is reduced using the trans-2-nonenal potential as an index, and the trans By reducing the content of the trans-2-nonenal potential in the second squeezed wort so as to reduce the -2-nonenal potential by a predetermined amount (at least 1 ppb in terms of sugar content of 11 ° p) , And disclosed a method for producing wort for fermented malt beverages with a reduced content of trans-2-nonenal potential, which has reduced degradation odor-causing substances and reduced the sugar content to a level that does not cause any practical problems ( WO 01/085899: Japanese Patent No. 383256).

WO01/085899WO01 / 085899 特許第3831256号公報Japanese Patent No. 383256 Food Chemistry, 95, p 357-381,2006Food Chemistry, 95, p 357-381,2006 Zeitschrift fuer Lebensmittel Untersuchung und Forshung, 193, 558-565, 1991Zeitschrift fuer Lebensmittel Untersuchung und Forshung, 193, 558-565, 1991 Journal of the American Society of Brewing Chemists, 35, 1977, 145-150Journal of the American Society of Brewing Chemists, 35, 1977, 145-150

本発明の課題は、発酵麦芽飲料中の劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減することで、劣化臭を抑制し、低減化処理によるエキス分の低減化を極力抑えて、エキス損失によるコスト高を抑制し、その他の香味に影響を及ぼさない発酵麦芽飲料の製造方法を提供することにある。   The problem of the present invention is to reduce the content of the degradation odor causing substance trans-2-nonenal potential in the fermented malt beverage, thereby suppressing the degradation odor and suppressing the reduction of the extract by the reduction treatment as much as possible. An object of the present invention is to provide a method for producing a fermented malt beverage that suppresses high costs due to loss of extract and does not affect other flavors.

本発明者は、発酵麦芽飲料の製造において、発酵麦芽飲料中の劣化臭原因物質の含有量を低減し、低減化処理によるエキス分の低減化を極力抑えて、エキス損失によるコスト高を抑制し、かつその他の香味に影響を及ぼさない発酵麦芽飲料を製造する方法について、鋭意検討する中で、安井らが先に開示した、二番搾り麦汁における劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量の低減化を行うことにより、劣化臭原因物質を低減化する方法(特許第3831256号公報)において、特定の平均細孔直径の活性炭を用い、該活性炭の添加量、麦汁温度、及び反応処理時間における特定の条件下で処理を行なうことにより、極めて短時間かつ特異的に、トランス−2−ノネナール ポテンシャルの含有量の低減化を行うことができ、過剰にエキス分が吸着されるのを抑え、エキス損失によるコスト高を抑制し、その他の香味に影響を及ぼさない発酵麦芽飲料を製造することができることを見い出し、本発明を完成するに至った。   In the production of fermented malt beverages, the present inventor reduces the content of the deterioration odor-causing substance in the fermented malt beverages, suppresses the reduction of the extract by the reduction process as much as possible, and suppresses the high cost due to the extract loss. In addition, while earnestly examining the method for producing a fermented malt beverage that does not affect other flavors, Yasui et al. Previously disclosed a degradation odor-causing substance trans-2-nonenal potential in No. 2 squeezed wort. In the method of reducing the deterioration odor-causing substance by reducing the content (Japanese Patent No. 383256), activated carbon having a specific average pore diameter is used, the added amount of the activated carbon, wort temperature, and To reduce the content of trans-2-nonenal potential in a very short time and specifically by performing the treatment under specific conditions during the reaction treatment time. It has been found that it is possible to produce a fermented malt beverage that suppresses excessive adsorption of the extract, suppresses the high cost due to loss of the extract, and does not affect other flavors, and has completed the present invention. It was.

本発明は、発酵麦芽飲料の製造工程において、仕込麦汁濾過工程において調製された二番搾り麦汁を、平均細孔直径1.5−2.0nmの活性炭を用いて、添加量1.5−3g/L、麦汁温度78℃以上、反応処理時間1分以上の条件で、処理することを特徴とする劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料を製造する方法からなる。   In the production process of the fermented malt beverage, the present invention uses an activated carbon having an average pore diameter of 1.5 to 2.0 nm to the second squeezed wort prepared in the charged wort filtration step. -3g / L, wort temperature of 78 ° C or higher, reaction time of 1 minute or longer, reduced odor-causing substance trans-2-nonenal potential content is reduced, and flavor is stabilized Comprising a method for producing a fermented malt beverage.

すなわち、麦汁濾過工程で発生する二番搾り中のトランス−2−ノネナール ポテンシャル含量は、撒き湯による洗い出し効果により、二番搾り麦汁中のエキス分の抽出量が漸次低減化するのに対して、一番搾りと同等の含量があり(WO01/085899)、該二番搾り麦汁を、同じ仕込や、別の仕込に用いた場合、香味安定性の低下を招くことになる。二番搾り麦汁中のトランス−2−ノネナール ポテンシャルにより、全麦汁中のトランス−2−ノネナール ポテンシャル含量が増大するのを防止するために、二番搾り麦汁を発酵麦芽飲料の製造に用いない方法もあるが、二番搾り麦汁中に抽出されるエキスを利用できないことによる、エキスの損失の問題点がある。そこで、安井らは、二番搾り麦汁を活性炭処理することにより、エキスの損失を最小限にし、実用上問題にならないエキスの損失としながらも、麦汁のトランス−2−ノネナール ポテンシャルを低減できることを見い出し、開示した(WO01/085899)。   In other words, the trans-2-nonenal potential content during the second squeezing that occurs in the wort filtration process is due to the fact that the extract amount of the second squeezed wort gradually decreases due to the washing-out effect of boiling water. In addition, there is a content equivalent to the first squeezed (WO01 / 085899), and when the second squeezed wort is used for the same preparation or another preparation, the flavor stability is lowered. In order to prevent the trans-2-nonenal potential in the second wort from increasing the trans-2-nonenal potential content in the whole wort, the second wort is used for the production of fermented malt beverages. Although there is no method, there is a problem of loss of the extract due to the fact that the extract extracted in the second squeezed wort cannot be used. Therefore, Yasui et al. Can reduce the trans-2-nonenal potential of wort by treating the second wort with activated carbon while minimizing the loss of the extract and making the loss of the extract not a practical problem. Has been found and disclosed (WO 01/085899).

二番搾り麦汁を、同じ仕込で用いる場合、麦汁中の香味劣化物質含量の増加により、香味安定性の低下につながり、特に、二番搾り麦汁を別のバッチの仕込に用いる場合においては、香味劣化物質の上乗せが生じ、香味安定性の低下につながることとなる。したがって、発酵麦芽飲料の製造に用いる、二番搾り麦汁中のトランス−2−ノネナール ポテンシャル含量は可能な限り低くする必要があるが、同時に、発酵麦芽飲料の香味強度が微妙に影響を受けることは避けられない。したがって、二番搾り麦汁を活性炭処理することにより、麦汁中の香味劣化物質含量を最大限、低減し、しかも、発酵麦芽飲料の香味を極力保持させる、二番搾り麦汁の活性炭の処理条件の確立が要求される。そこで、鋭意検討の結果、上記のとおり、活性炭のスペック(平均細孔径)、及び使用条件(添加量、反応温度、反応時間、処理済二番搾りの添加場所)を特定することにより、それらの要求を満足できる条件があることを見い出し、本発明の劣化臭原因物質の含有量を最大限低減し、しかも、極力香味を保持し、安定化した発酵麦芽飲料の製造方法の開発に成功した。   When using the second brewed wort in the same preparation, the increase in the content of flavor degrading substances in the wort leads to a decrease in flavor stability, especially when using the second brewed wort for the preparation of another batch Is added to the flavor-degrading substance, leading to a decrease in flavor stability. Therefore, the trans-2-nonenal potential content in the second squeezed wort used for the production of fermented malt beverages should be as low as possible, but at the same time the flavor intensity of the fermented malt beverages will be subtly affected. Is inevitable. Therefore, by treating the second squeezed wort with activated carbon, the content of flavor-degrading substances in the wort is reduced to the maximum, and the flavor of the fermented malt beverage is kept as much as possible, and the second squeezed wort activated carbon is treated. Establishing conditions is required. Then, as a result of earnest examination, as above-mentioned, by specifying the specification (average pore diameter) of activated carbon, and use conditions (addition amount, reaction temperature, reaction time, addition place of treated second squeeze), those The present inventors have found that there are conditions that can satisfy the requirements, and have succeeded in developing a method for producing a fermented malt beverage that can reduce the content of the deterioration odor-causing substance of the present invention as much as possible, and retain the flavor as much as possible.

本発明において、用いる活性炭の形態は、粉末又はフィルター状の活性炭を挙げることができる。本発明の発酵麦芽飲料の製造方法においては、本発明の方法で処理した二番搾り麦汁を、麦汁濾過以降の仕込工程中の煮沸中或いは煮沸後に添加することにより、劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料を製造することができる。また本発明の方法で処理した二番搾り麦汁を、別のバッチの仕込工程中において、麦下し時の醸造用水として、麦汁濾過時の撒き湯として用いるか、或いは仕込工程中の煮沸中或いは煮沸後に添加することにより、劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料を製造することができる。本発明における発酵麦芽飲料としては、ビール、発泡酒等を挙げることができる。   In the present invention, examples of the activated carbon used include powdered or filter-like activated carbon. In the method for producing a fermented malt beverage of the present invention, the second squeezed wort treated by the method of the present invention is added during or after boiling in the charging process after filtration of wort, thereby causing a deteriorated odor causing substance trans -2-Nonenal Potential fermented malt beverage with reduced content of potential and stabilized flavor can be produced. Moreover, the second squeezed wort treated by the method of the present invention is used as brewing water at the time of brewing, as boiling water at the time of wort filtration, or boiling during the charging process in another batch charging process. By adding it during or after boiling, a fermented malt beverage having a reduced odor-causing substance trans-2-nonenal potential and a stabilized flavor can be produced. Examples of the fermented malt beverage in the present invention include beer and happoshu.

すなわち具体的には本発明は、(1)発酵麦芽飲料の製造工程において、仕込麦汁濾過工程において調製された二番搾り麦汁を、平均細孔直径1.5−2.0nmの活性炭を用いて、添加量1.5−3g/L、麦汁温度78℃以上、反応処理時間1分以上の条件で、処理することを特徴とする劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法や、(2)活性炭の形態が、粉末又はフィルター状活性炭であることを特徴とする上記(1)記載の劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法や、(3)二番搾り麦汁を上記(1)記載の条件で活性炭処理した後、該麦汁を、麦汁濾過以降の仕込工程中の煮沸中或いは煮沸後に添加することを特徴とする劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法からなる。   That is, the present invention specifically relates to (1) No. 2 squeezed wort prepared in the charged wort filtration step in the production process of fermented malt beverage, and activated carbon having an average pore diameter of 1.5 to 2.0 nm. Content of trans-2-nonenal potential, which causes deterioration odor, characterized in that it is treated under the conditions of an addition amount of 1.5-3 g / L, a wort temperature of 78 ° C. or more, and a reaction treatment time of 1 minute or more. The method for producing a fermented malt beverage with reduced flavor and stabilized flavor, and (2) the activated carbon is in the form of powder or filter-like activated carbon. -Nonenal Potential content is reduced and the flavor is stabilized. A method for producing a fermented malt beverage, or (3) after treating the second squeezed wort under the conditions described in (1) above, During the preparation process after wort filtration It consists of a method for producing a fermented malt beverage in which the content of degraded odor-causing substance trans-2-nonenal potential is reduced and the flavor is stabilized, which is added during or after boiling.

また本発明は、(4)二番搾り麦汁を請求項1記載の条件で活性炭処理した後、該麦汁を、別のバッチの仕込工程中において、麦下し時の醸造用水として、麦汁濾過時の撒き湯として用いるか、或いは仕込工程中の煮沸中或いは煮沸後に添加することを特徴とする劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法や、(5)発酵麦芽飲料が、ビール又は発泡酒であることを特徴とする上記(1)〜(4)のいずれか記載の劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法や、(6)上記(1)〜(5)のいずれか記載の発酵麦芽飲料の製造方法によって製造された劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料からなる。   In addition, the present invention provides (4) No. 2 squeezed wort after activated charcoal treatment under the conditions described in claim 1, and the wort is used as brewing water during mashing in another batch charging step. Fermented with reduced flavor and stabilized flavor, which is used as boiling water during juice filtration, or added during or after boiling in the charging process. The method for producing a malt beverage and (5) the fermented malt beverage is beer or sparkling liquor, wherein the degradation odor causing substance trans-2-nonenal potential is any one of the above (1) to (4) Degraded odor causing substance transformer produced by a method for producing a fermented malt beverage with reduced content and stabilized flavor, and (6) a method for producing a fermented malt beverage according to any one of (1) to (5) above -2-Nonena It consists of a fermented malt beverage with a reduced content of odor potential and a stabilized flavor.

本発明の発酵麦芽飲料の製造方法により、発酵麦芽飲料中の劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減することで、劣化臭を抑制し、低減化処理によるエキス分の低減化を極力抑えて、エキス損失によるコスト高を抑制し、その他の香味に影響を及ぼさない発酵麦芽飲料を提供することができる。特に、本発明の発酵麦芽飲料の製造方法により、二番搾り麦汁における劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量の低減を効果的に行う条件を明確化したことにより、有効な麦汁のエキス分回収を達成するとともに、劣化臭原因物質の効率的な低減を可能とし、安定化した香味の発酵麦芽飲料を製造することができ、高品質の発酵麦芽飲料を、経済的に優れた方法で提供することができる。   By reducing the content of the degradation odor-causing substance trans-2-nonenal potential in the fermented malt beverage by the production method of the fermented malt beverage of the present invention, the degradation odor is suppressed and the extract content is reduced by the reduction treatment. As a result, it is possible to provide a fermented malt beverage that suppresses the cost increase due to the loss of extract and does not affect other flavors. In particular, the method for producing a fermented malt beverage according to the present invention clarifies the conditions for effectively reducing the content of the degradation odor-causing substance trans-2-nonenal potential in the second squeezed wort. While recovering the juice extract, it is possible to efficiently reduce the odor-causing substances, produce a stable flavored fermented malt beverage, and economically superior high-quality fermented malt beverage Can be provided in different ways.

本発明は、発酵麦芽飲料の製造工程において、仕込麦汁濾過工程において調製された二番搾り麦汁を、平均細孔直径1.5−2.0nmの活性炭を用いて、添加量1.5−3g/L、麦汁温度78℃以上、反応処理時間1分以上の条件で、処理することにより、劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料を製造する方法からなる。本発明の発酵麦芽飲料の製造方法において、仕込麦汁濾過工程において調製された二番搾り麦汁を、上記平均細孔直径の活性炭を用いて、上記の添加量、麦汁温度及び反応処理時間の条件で、処理する点を除いて、特許第3831256号の明細書に開示した発酵麦芽飲料の製造方法と異なるところはない。   In the production process of the fermented malt beverage, the present invention uses an activated carbon having an average pore diameter of 1.5 to 2.0 nm to the second squeezed wort prepared in the charged wort filtration step. -3 g / L, wort temperature of 78 ° C. or higher, reaction time of 1 minute or longer, by reducing the content of degraded odor-causing substance trans-2-nonenal potential and stabilizing the flavor It consists of a method for producing a malt beverage. In the method for producing a fermented malt beverage of the present invention, the amount of the second squeezed wort prepared in the charged wort filtration step, using the activated carbon having the average pore diameter, the above addition amount, wort temperature and reaction treatment time. There is no difference from the method for producing a fermented malt beverage disclosed in the specification of Japanese Patent No. 383256 except that it is processed under the above conditions.

すなわち、ビール等の発酵麦芽飲料の製造工程は、麦芽を調製する製麦工程、麦芽を糖化槽で糖化後濾過して濾過麦汁を得て、さらにホップを添加・煮沸して最終的な仕上り麦汁を得る仕込工程、該仕上り麦汁を酵母により発酵させる発酵工程、該発酵液を熟成する貯蔵工程に大別でき、上記仕込工程における仕込麦汁の濾過工程は、もろみの固形分による濾過層を形成させながら濾過を行ってエキス濃度16〜20%の濾過麦汁(通常一番搾り麦汁あるいは一番麦汁と呼ばれる)を得た後、80℃ぐらいの湯水を用いてもろみ濾過層に残るエキス分を溶出させエキス分1%程度までの濾過麦汁(通常二番搾り麦汁あるいは二番麦汁と呼ばれる)を得る工程からなり、これらを合わせた濾過麦汁は次の麦汁煮沸工程においてホップを添加して煮沸されることになる。したがって、本発明において「二番搾り麦汁」とは、一番搾りにより一番搾り麦汁を得た後の二番搾りにより得られる麦汁を意味する。「全濾過麦汁」とは、一番搾り麦汁と二番搾り麦汁とを合わせた麦汁をいい、また「発酵麦芽飲料用麦汁」における“麦汁”とは、これらの麦汁から調製された麦汁の意味で使用される。   That is, the manufacturing process of fermented malt beverages such as beer is a malting process for preparing malt, the wort is saccharified in a saccharification tank and filtered to obtain filtered wort, and further hops are added and boiled to obtain a final finish The wort charging process, the fermenting process for fermenting the finished wort with yeast, and the storage process for aging the fermented liquor can be broadly divided. Filtration is performed while forming a layer to obtain a filtered wort (usually called the first squeezed wort or the first wort) having an extract concentration of 16 to 20%, and then the mashing filter layer using hot water of about 80 ° C. The process is to obtain a filtered wort (usually called second wort or second wort) by eluting the remaining extract to about 1%, and the combined wort is the next wort Add hops in the boiling process It will be boiling. Therefore, in the present invention, “second squeezed wort” means wort obtained by second squeezing after first squeezing wort. “Whole filtered wort” refers to the wort that combines the most pressed wort and the second pressed wort, and “wort” in “fermented malt beverage wort” refers to these worts. It is used in the meaning of wort prepared from

本発明の発酵麦芽飲料用麦汁の製造方法としては、発酵麦芽飲料の製造における仕込麦汁の濾過工程において調製された二番搾り麦汁を、本発明で特定する平均細孔直径の活性炭を用いて、本発明で特定する添加量、麦汁温度及び反応処理時間の条件で処理する。本発明における二番搾り麦汁の処理においては、二番搾り麦汁中に溶出されるトランスー2−ノネナール ポテンシャル成分及び糖質等の経時変化を考慮して(図1に示されるように、二番搾り麦汁の終流近くにおいては、糖質等の溶出は減少するのに対して、トランスー2−ノネナール ポテンシャル成分は依然として溶出が続く)、活性炭による香味安定性以外の品質への影響を避けるため二番搾り麦汁の終流20−30%、更に好ましくは、10%程度を処理することにより、効果的な活性炭処理を行なうことができる。本発明は、発酵麦芽飲料の製造における仕込麦汁の濾過工程において調製された二番搾り麦汁を、本発明で特定する平均細孔直径の活性炭を用いて、本発明で特定する添加量、麦汁温度及び反応処理時間の条件で処理する点を除いて、通常の発酵麦芽飲料の製造製造方法と特に変わるところはない。上記発酵麦芽飲料としては、上面発酵ビール、下面発酵ビール等の各種ビール、ビールよりも使用麦芽比率が低い発泡酒を具体的に例示することができる。また、上記劣化臭原因物質としては特に制限されるものではないが、トランス−2−ノネナール及びトランス−2−ノネナールに変わりうる物質、すなわちNP成分を好適に例示することができる。また、上記二番搾り麦汁における劣化臭原因物質の低減化処理としては、NPを指標とする処理を挙げることができ、例えばNPは、pH4.0に調整した酢酸緩衝液に一定量(緩衝液の1/5量)の麦汁を添加して100、2時間の熱処理をし、生成したトランス−2−ノネナール量として求めることができる。   As a method for producing the wort for fermented malt beverages of the present invention, the second pressed wort prepared in the filtration step of the prepared wort in the production of fermented malt beverages is activated carbon having an average pore diameter specified in the present invention. It uses and processes on the conditions of the addition amount specified by this invention, wort temperature, and reaction processing time. In the processing of the second squeezed wort in the present invention, taking into account the time-dependent changes in the trans-2-nonenal potential component and sugars eluted in the second squeezed wort (as shown in FIG. Near the end of the squeezed wort, elution of saccharides, etc. decreases, but trans-2-nonenal potential components continue to elute), while avoiding effects on quality other than flavor stability due to activated carbon Therefore, an effective activated carbon treatment can be performed by treating the final squeezed wort of 20-30%, more preferably about 10%. The present invention uses the activated carbon of the average pore diameter specified in the present invention, the second squeezed wort prepared in the filtration step of the charged wort in the production of fermented malt beverage, the addition amount specified in the present invention, Except for the point of processing under conditions of wort temperature and reaction treatment time, there is no particular difference from the method for producing and producing a normal fermented malt beverage. Specific examples of the fermented malt beverage include various types of beer such as top fermented beer and bottom fermented beer, and sparkling liquor having a lower malt ratio than beer. Moreover, although it does not restrict | limit especially as said deterioration odor causative substance, The substance which can be changed into trans-2-nonenal and trans-2-nonenal, ie, NP component, can be illustrated suitably. In addition, examples of the process for reducing the deterioration odor-causing substance in the second squeezed wort include a process using NP as an index. For example, NP is added to an acetic acid buffer adjusted to pH 4.0 (buffer). The amount of trans-2-nonenal produced can be determined by adding 100% wort of the liquid and heat treatment for 100 hours for 2 hours.

上記トランス−2−ノネナール ポテンシャルを指標として、すなわち、麦芽発酵飲料の所定の工程においてトランス−2−ノネナール ポテンシャル含量を測定して、本願発明の条件により、二番搾り麦汁におけるトランス−2−ノネナール ポテンシャル含量の低減化処理を施すことにより、効果的に劣化臭の生成が抑制された麦芽発酵飲料を製造することが可能となる。例えば、麦汁の糖度を11゜p(プラトー)に調整した全濾過麦汁中のNP含量は、ビールの種類によっても異なるが通常7〜10ppb程度であり、この全濾過麦汁中のNP含量を少なくとも1ppb低減させることにより、劣化臭の生成が抑制された麦芽発酵飲料を製造することが実質的に可能となる。   Using the trans-2-nonenal potential as an index, that is, measuring the trans-2-nonenal potential content in a predetermined step of the malt fermented beverage, and according to the conditions of the present invention, trans-2-nonenal in the second squeezed wort By performing the potential content reduction treatment, it is possible to produce a malt fermented beverage in which the generation of a deteriorated odor is effectively suppressed. For example, the NP content in the total filtered wort in which the sugar content of the wort is adjusted to 11 ° p (plateau) is usually about 7 to 10 ppb, although it varies depending on the type of beer. The NP content in the total filtered wort By reducing at least 1 ppb, it becomes substantially possible to produce a malt fermented beverage in which the generation of a deteriorated odor is suppressed.

本発明においては、発酵麦芽飲料の製造工程において、仕込麦汁濾過工程において調製された二番搾り麦汁を、平均細孔直径1.5−2.0nmの活性炭を用いて、添加量1.5−3g/L、麦汁温度78℃以上、反応処理時間1分以上の条件で処理することにより、トランス−2−ノネナール ポテンシャル成分を活性炭に吸着させることによりトランス−2−ノネナール ポテンシャルの含有量を効果的に除去・低減しすることができるが、用いる活性炭としては、粉末又はフィルター状の形態の活性炭を用いることができる。用いる活性炭が粉状の場合は活性炭カラムに充填して通過させることにより、またフィルター状の形態の活性炭の場合はそのまま濾過することにより、トランス−2−ノネナール ポテンシャル成分を麦汁中から除去・低減することができる。   In this invention, in the manufacturing process of fermented malt drink, the addition amount 1. is used for the second squeezed wort prepared in the preparation wort filtration process using activated carbon with an average pore diameter of 1.5-2.0 nm. The content of trans-2-nonenal potential by adsorbing the trans-2-nonenal potential component to activated carbon by treatment under the conditions of 5-3 g / L, wort temperature of 78 ° C or higher, and reaction time of 1 minute or longer. Can be effectively removed / reduced, but as the activated carbon to be used, activated carbon in the form of powder or filter can be used. If activated charcoal used is in powder form, it is filled and passed through an activated carbon column. If activated carbon is in the form of a filter, the trans-2-nonenal potential component is removed and reduced from the wort by filtering as it is. can do.

本発明の劣化臭の生成が抑制されたビール、発泡酒等の発酵麦芽飲料としては、以上詳述した発酵麦芽飲料用麦汁の製造方法により製造された麦汁を発酵させることにより得られるものであれば特に制限されるものではないが、本願発明の条件で活性炭処理した二番搾り麦汁を、引き続いて仕込工程に用いる場合には、二番搾り麦汁を本願発明の条件で活性炭処理した後、該麦汁を、麦汁濾過以降の仕込工程中の煮沸中或いは煮沸後に添加することが好ましい。また、本願発明の条件で活性炭処理した二番搾り麦汁を、別のバッチの仕込工程に用いる場合には、二番搾り麦汁を本願発明の条件で活性炭処理した後、該麦汁を、別のバッチの仕込工程中において、麦下し時の醸造用水として、麦汁濾過時の撒き湯として若しくは麦汁煮沸中、或いは麦汁煮沸後に添加するのが好ましい。   As fermented malt beverages such as beer and sparkling liquor in which the generation of the deteriorated odor of the present invention is suppressed, those obtained by fermenting wort produced by the above-described method for producing wort for fermented malt beverages If it is not particularly limited, but the second squeezed wort treated with activated carbon under the conditions of the present invention, and subsequently used in the charging step, the second squeezed wort is treated with activated carbon under the conditions of the present invention. Then, it is preferable to add the wort during or after boiling in the charging step after wort filtration. In addition, when using the second squeezed wort treated with activated carbon under the conditions of the present invention for the charging process of another batch, after the second squeezed wort is activated carbon treated under the conditions of the present invention, In another batch charging step, it is preferably added as brewing water at the time of lowering the wheat, as boiling water at the time of wort filtration, during boiling of wort, or after boiling of wort.

以下、実施例により本発明をより具体的に説明するが、本発明の技術的範囲はこれらの例示に限定されるものではない。   EXAMPLES Hereinafter, although an Example demonstrates this invention more concretely, the technical scope of this invention is not limited to these illustrations.

[麦汁濾過における糖度、NPの経時変化]   [Change in sugar content and NP over time in wort filtration]

(トランス−2−ノネナール ポテンシャル(NP)の測定)
以下の実施例におけるNP含量の測定は、酢酸と酢酸ナトリウムとを用いてpH4.0に調整した0.2M酢酸緩衝液に1/5量の麦汁を添加し、栓をして100℃、2時間の熱処理をし、室温まで冷却後、Verhagenらの方法(J. Chromatgr., 393 (1987) 85-96)に従って、トランス−2−ノネナールを、Sep-Pak社製C18カートリッジで固相抽出し、ダンシルヒドラジンで誘導体化後、カラムスイッチング法を用いたHPLC(ヒューレットパッカード社製「HP1100」)で分析することにより行った。なお、カラムスイッチング法においては、100×4.6mm分取用カラム(YMC-Pack社製「ODS-AM」)を流速1.0ml/minで用い、250×4.6mm分離用カラム(YMC-Pack社製「ODS-AM」)を流速0.85ml/minで用いた。
(Measurement of trans-2-nonenal potential (NP))
In the following examples, the NP content was measured by adding 1/5 amount of wort to 0.2 M acetic acid buffer adjusted to pH 4.0 using acetic acid and sodium acetate, plugging it to 100 ° C, After heat treatment for 2 hours and cooling to room temperature, trans-2-nonenal was solid-phase extracted with Sep-Pak C18 cartridge according to the method of Verhagen et al. (J. Chromatgr., 393 (1987) 85-96). Then, after derivatization with dansyl hydrazine, the analysis was performed by HPLC (“HP1100” manufactured by Hewlett-Packard) using a column switching method. In the column switching method, a 100 × 4.6 mm preparative column (“ODS-AM” manufactured by YMC-Pack) was used at a flow rate of 1.0 ml / min, and a 250 × 4.6 mm separation column (YMC- Pack "ODS-AM") was used at a flow rate of 0.85 ml / min.

(麦汁濾過における糖度、NPの経時変化)
麦芽100gに湯300ml(麦芽:湯=1:3)を加えて、50℃で30分間、65℃で60分間、続いて78℃で10分間の温度プログラムで糖化した麦汁もろみを濾紙(東洋濾紙「#2」)を敷いたロートで濾過し、濾過後の濾過層に420mlの撒き湯を70mlずつ6回に分けて行った。各濾過液(二番搾り)の糖度、NPを測定した。糖度は比重を測定し、換算表から糖度(゜p)を算出した。結果を図1に示す。また、同様にして、KLレベルのパイロットプラント糖化麦汁もろみをロイター槽で濾過し、濾過液の糖度、NPを経時的に測定した。結果を図2に示す。図1及び図2から、二番搾りにおいては、NPの低下は糖度の低下と比較して小さく、特に図2から、麦汁中の糖分は濾過液量の増加に概ね比例して漸次低下するが、NPは糖分の低下に相関することなく、高い値で推移することや、一番搾り麦汁と二番搾り麦汁におけるNP含量に差がないことから、
NPが濾過層(仕込粕)から溶出していることがわかった。
(Change in sugar content and NP over time in wort filtration)
Add 300 ml of hot water (malt: hot water = 1: 3) to 100 g of malt, filter the wort mash that has been saccharified with a temperature program of 30 ° C. for 30 minutes, 65 ° C. for 60 minutes, and then 78 ° C. for 10 minutes. The mixture was filtered through a funnel with filter paper “# 2”), and 420 ml of boiling water was divided into six portions of 70 ml each for the filtered layer after filtration. The sugar content and NP of each filtrate (second press) were measured. For the sugar content, the specific gravity was measured, and the sugar content (° p) was calculated from a conversion table. The results are shown in FIG. Similarly, KL level pilot plant saccharified wort mash was filtered through a Reuter tank, and the sugar content and NP of the filtrate were measured over time. The results are shown in FIG. From FIG. 1 and FIG. 2, in the second squeezing, the decrease in NP is small compared to the decrease in sugar content, and particularly from FIG. 2, the sugar content in wort gradually decreases in proportion to the increase in the amount of filtrate. However, since NP does not correlate with a decrease in sugar content, it shifts at a high value, and since there is no difference in the NP content in the first squeezed wort and the second squeezed wort,
It was found that NP was eluted from the filtration layer (feeding cake).

[活性炭の平均細孔径がNP吸着能に及ぼす影響]
麦芽100%の通常の二番搾り(糖度1.49°P)500mLを密閉可能な容器に取り、細孔径の異なる数種の活性炭をそれぞれ1.5g(乾物換算)添加し、80分間、78℃条件下で反応させた。反応中は容器を約20分に一度の頻度で、転倒操作を行い、二番搾りと活性炭の接触機会の頻度を高めた。その結果を、図3(活性炭の平均細孔径がNP吸着能に及ぼす影響)に示す。図3に示した通り、平均細孔直径が1.82nmでNPが最小となった。図3で得られたグラフの傾向から判断して、平均細孔直径は1.5−2.0nmが好ましいことが分かった。一方で、糖度に関しては、大きな変化は無く、エキス回収上、活性炭処理の影響は極めて限定的であることが分かった。なお、本結果を活性炭の比表面積当たりに換算しても、同様に、平均細孔直径1.82nmにおいてNPが最小となり、グラフの傾向も同等であった。
[Effect of activated carbon average pore size on NP adsorption capacity]
Take 500 mL of normal second squeezed malt (sugar content 1.49 ° P) 500 mL in a sealable container, add 1.5 g (in dry matter equivalent) of several kinds of activated carbons with different pore sizes, 80 minutes, 78 The reaction was performed under the condition of ° C. During the reaction, the container was tumbled about once every 20 minutes to increase the frequency of second squeezing and activated carbon contact opportunities. The results are shown in FIG. 3 (influence of the average pore diameter of activated carbon on the NP adsorption capacity). As shown in FIG. 3, the average pore diameter was 1.82 nm, and NP was minimized. Judging from the tendency of the graph obtained in FIG. 3, it was found that the average pore diameter is preferably 1.5 to 2.0 nm. On the other hand, regarding sugar content, there was no big change and it turned out that the influence of activated carbon treatment is very limited on extract collection. In addition, even if this result was converted to the specific surface area of the activated carbon, the NP was minimized at the average pore diameter of 1.82 nm, and the graph tendency was the same.

[活性炭の添加量がNP吸着能に及ぼす影響]
麦芽100%の通常の二番搾り(糖度1.50°P)500mLを密閉可能な容器に取り、活性炭を異なる量添加し、80分間、78℃条件下で反応させた。反応中は容器を約20分に一度の頻度で、転倒操作を行い、二番搾りと活性炭の接触機会の頻度を高めた。その結果、図4(活性炭の添加量がNP吸着能に及ぼす影響)に示す。図4に示した通り、添加量が1.5−3.0g/LでNPが最小値となり、活性炭の添加量は、1.5−3.0g/Lが好ましいことが分かった。糖度に関しては、大きな変化は無く、エキス回収上、活性炭処理の影響は極めて限定的であることが分かった。
[Effect of added amount of activated carbon on NP adsorption capacity]
500 mL of normal second squeezed malt (sugar content: 1.50 ° P) (500 mL) was placed in a sealable container, added with different amounts of activated carbon, and reacted at 78 ° C. for 80 minutes. During the reaction, the container was tumbled about once every 20 minutes to increase the frequency of second squeezing and activated carbon contact opportunities. As a result, it shows in FIG. 4 (influence which the addition amount of activated carbon has on NP adsorption capacity). As shown in FIG. 4, NP became the minimum value when the addition amount was 1.5-3.0 g / L, and it was found that the addition amount of activated carbon was preferably 1.5-3.0 g / L. There was no significant change in the sugar content, and it was found that the effect of the activated carbon treatment on the extract recovery was extremely limited.

[活性炭の反応温度がNP吸着能に及ぼす影響]
麦芽100%の通常の二番搾り(糖度1.50°P)500mLを密閉可能な容器に取り、活性炭を異なる量添加し、80分間、異なる温度条件下で反応させた。反応中は容器を約20分に一度の頻度で、転倒操作を行い、二番搾りと活性炭の接触機会の頻度を高めた。その結果を図5(活性炭の反応温度がNP吸着能に及ぼす影響)に示す。図5に示した通り、反応温度が78℃の時に最小値となり、グラフの傾向から、反応温度は70−90℃が好ましいことが分かった。一方で、糖度に関しては、大きな変化は無く、エキス回収上、活性炭処理の影響は極めて限定的であることが分かった。
[Effect of activated carbon reaction temperature on NP adsorption capacity]
500 mL of normal second squeezed malt 100% (sugar content 1.50 ° P) was placed in a sealable container, added with different amounts of activated carbon, and allowed to react for 80 minutes under different temperature conditions. During the reaction, the container was tumbled about once every 20 minutes to increase the frequency of second squeezing and activated carbon contact opportunities. The results are shown in FIG. 5 (effect of activated carbon reaction temperature on NP adsorption capacity). As shown in FIG. 5, the minimum value was obtained when the reaction temperature was 78 ° C., and it was found from the tendency of the graph that the reaction temperature was preferably 70 to 90 ° C. On the other hand, regarding sugar content, there was no big change and it turned out that the influence of activated carbon treatment is very limited on extract collection.

[活性炭の反応時間がNP吸着能に及ぼす影響]
麦芽100%の通常の二番搾り(糖度1.48°P)500mLを密閉可能な容器に取り、活性炭を異なる量添加し、78℃で、異なる時間で反応させた。反応中は容器を約20分に一度の頻度で、転倒操作を行い、二番搾りと活性炭の接触機会の頻度を高めた。その結果を図6(活性炭の反応時間がNP吸着能に及ぼす影響)に示す。図6に示した通り、反応時間が1分で、反応時間0分の場合の94%のNPを除去でき、その後は反応時間に関わらず、ほぼNPの値は一定であることが分かった。従って、反応時間は1分以上が好ましいことが分かった。糖度に関しては、大きな変化は無く、エキス回収上、活性炭処理の影響は極めて限定的であることが分かった。
[Effect of activated carbon reaction time on NP adsorption capacity]
500 mL of ordinary second squeezed malt (sugar content: 1.48 ° P) (500 mL) was placed in a sealable container, added with different amounts of activated carbon, and reacted at 78 ° C. for different times. During the reaction, the container was tumbled about once every 20 minutes to increase the frequency of second squeezing and activated carbon contact opportunities. The results are shown in FIG. 6 (effect of activated carbon reaction time on NP adsorption capacity). As shown in FIG. 6, it was found that 94% of NP was removed when the reaction time was 1 minute and the reaction time was 0 minute, and thereafter the value of NP was almost constant regardless of the reaction time. Therefore, it was found that the reaction time is preferably 1 minute or longer. There was no significant change in the sugar content, and it was found that the effect of the activated carbon treatment on the extract recovery was extremely limited.

[二番搾りを活性炭処理し、同じ仕込に戻すことがビールのNPに及ぼす影響]
麦芽100%の通常の二番搾り麦汁の終流10%(糖度2.13°P)6.6Lを密閉可能な容器に取り、平均細孔径1.82nmの活性炭を19.8g加え、80分、78℃で反応させた。反応後、50分煮沸した一番搾り66Lに二番搾り麦汁を添加し、更に10分煮沸した。その後、ワールプール処理、麦汁冷却を行い、得られた冷却麦汁に通常の方法で酵母を添加し、発酵させた。発酵液をビール濾過し、壜詰めを行った。このようにして得られたビールのNPを測定したところ、二番搾りを活性炭処理せずに、麦汁濾過終了時点で一番搾りと二番搾りを混合して、その後の工程を行って試作したビールのNPと比較して、低い値が得られた(図7:二番搾りを活性炭処理し、同じ仕込に戻すことがビールのNPに及ぼす影響;図中、*1は、二番搾りを活性炭処理せずに、麦汁濾過終了時点で一番搾りと二番搾りを混合して60分煮沸させ、その後の工程を行って試作したビールを;*2は、二番搾りを活性炭処理し、処理後、当該二番搾りを50分煮沸した一番搾りに添加し、更に10分煮沸させ、その後の工程を行って試作したビールを示す。)。従って、活性炭処理済の二番搾りを同じ仕込の一番搾りに添加することで、通常の工程と比較して、ビールの香味安定性が改善することが分かった。また、該ビールの新鮮時の香味の違いをトライアングルテストで比較した結果(n=24)、有意さはなく、本発明による二番搾り麦汁の活性炭処理が他の香味に影響を及ぼさないことが分かった。
[Effect of squeezing second squeezed charcoal and returning it to the same charge on beer NP]
Take 6.6 L of the final 10% wrinkled wort of 100% malt (sugar content 2.13 ° P) in a sealable container, add 19.8 g of activated carbon with an average pore diameter of 1.82 nm, The reaction was allowed to proceed for 78 minutes at 78 ° C. After the reaction, the second squeezed wort was added to 66 L of the first squeezed for 50 minutes, and the mixture was further boiled for 10 minutes. Then, a whirlpool process and wort cooling were performed, yeast was added to the obtained cooled wort by a normal method, and it was made to ferment. The fermentation broth was filtered with beer and stuffed with straw. When the NP of the beer thus obtained was measured, the second squeezed was not treated with activated carbon, the first squeezed and the second squeezed were mixed at the end of the wort filtration, and the subsequent steps were performed to produce a prototype. Lower values were obtained compared to the NP of beer (Figure 7: Effect of second squeezing activated carbon treatment and returning to the same charge on the NP of beer; * 1 indicates second squeeze The beer produced by mixing the first squeezed and second squeezed at the end of wort filtration and boiled for 60 minutes without performing the activated charcoal treatment; Then, after the treatment, the second squeeze is added to the first squeeze that has been boiled for 50 minutes, and is further boiled for 10 minutes. Therefore, it was found that adding the second squeezed treated with activated carbon to the first squeeze of the same preparation improves the flavor stability of beer compared to the normal process. Moreover, as a result of comparing the difference in flavor of the beer with a triangle test (n = 24), there is no significance, and the activated carbon treatment of the second wort according to the present invention does not affect other flavors. I understood.

[二番搾りを活性炭処理し、異なる仕込に戻すことがビールのNPに及ぼす影響]
麦芽100%の通常の二番搾り麦汁の終流10%(糖度2.02°P)6.6Lを密閉可能な容器に取り、平均細孔径1.82nm の活性炭を19.8g加え、150分、78℃で反応させた。反応後、二番搾りを別の仕込の撒き湯として使用した。得られた二番搾り(糖度2.02°P)6.6Lに対しては、更に密閉容器に移した後、平均細孔径1.82nmの活性炭を19.8g加え、80分、78℃で反応させた。反応後、二番搾りを50分煮沸した一番搾り66Lに添加し、10分煮沸した。その後、ワールプール処理、麦汁冷却を行い、得られた冷却麦汁に通常の方法で酵母を添加し、発酵させた。発酵液をビール濾過し、壜詰めを行った。
[Effect of squeezing second squeezed charcoal and returning it to a different charge on NP of beer]
Take 6.6 L of 10% final wort of 100% malt (sugar content 2.02 ° P) in a sealable container, add 19.8 g of activated carbon with an average pore diameter of 1.82 nm, 150 The reaction was allowed to proceed for 78 minutes at 78 ° C. After the reaction, the second squeezed was used as another preparation of boiling water. For the second squeezed (sugar content 2.02 ° P) 6.6 L, after further moving to a sealed container, 19.8 g of activated carbon having an average pore diameter of 1.82 nm was added, and 80 minutes at 78 ° C. Reacted. After the reaction, the second squeezed squeezed was added to 66 L of the first squeezed for 50 minutes and boiled for 10 minutes. Then, a whirlpool process and wort cooling were performed, yeast was added to the obtained cooled wort by a normal method, and it was made to ferment. The fermentation broth was filtered with beer and stuffed with straw.

このようにして得られたビールのNPを測定したところ、二番搾りを活性炭処理せずに、麦汁濾過終了時点で(同じ仕込の)一番搾りと二番搾りを混合して、その後60分煮沸し、通常の工程を行って試作したビールのNPと比較して、低い値が得られた。従って、活性炭処理済の二番搾りを異なる仕込の一番搾りに添加し、その仕込の二番搾りも活性炭処理することで、通常の工程と比較して、ビールの香味安定性が同等もしくは改善することが分かった。糖度に関しては、上記方法により得られたビールの方が、二番搾りを活性炭処理せずに、麦汁濾過終了時点で一番搾りと二番搾りを混合して、その後の工程を行って試作したビールよりも原麦汁エキス(アルコールに代謝されたエキスを含むビール中の総エキス)が高く、本方法により、二番搾りのエキスを回収でき、上記のビール香味安定性改善に加え、コスト改善にも寄与できることが分かった。   When the NP of the beer thus obtained was measured, the first squeeze and the second squeeze were mixed at the end of wort filtration without subjecting the second squeeze to activated carbon treatment, and then 60 Compared with NP of beer which was boiled and was subjected to a normal process, and a low value was obtained. Therefore, by adding the second squeezed treated with activated carbon to the first squeezed of different preparations, and treating the second squeezed of the prepared parts with activated carbon, the flavor stability of beer is equal or improved compared to the normal process. I found out that Regarding sugar content, the beer obtained by the above method is mixed with the first squeeze and the second squeeze at the end of wort filtration without subjecting the second squeeze to the activated carbon treatment, and the subsequent process is performed as a prototype. The original wort extract (total extract in beer including the extract metabolized to alcohol) is higher than the brewed beer, and the second squeezed extract can be recovered by this method, in addition to the above-mentioned beer flavor stability improvement, cost It was found that it can also contribute to improvement.

本発明の実施例の試験において、麦汁濾過における二番搾り麦汁の糖度、NPの経時変化を示す図である。In the test of the Example of this invention, it is a figure which shows the time-dependent change of the sugar content and NP of the second press wort in wort filtration. 本発明の実施例の試験において、麦汁濾過における濾過麦汁の糖度、NPの経時変化を示す図である。In the test of the Example of this invention, it is a figure which shows the time-dependent change of the sugar content of filtration wort and NP in wort filtration. 本発明の実施例の試験において、活性炭の平均細孔径がNP吸着能に及ぼす影響についての試験結果を示す図である。In the test of the Example of this invention, it is a figure which shows the test result about the influence which the average pore diameter of activated carbon has on NP adsorption ability. 本発明の実施例の試験において、活性炭の添加量がNP吸着能に及ぼす影響についての試験結果を示す図である。In the test of the Example of this invention, it is a figure which shows the test result about the influence which the addition amount of activated carbon has on NP adsorption ability. 本発明の実施例の試験において、活性炭の反応温度がNP吸着能に及ぼす影響についての試験結果を示す図である。In the test of the Example of this invention, it is a figure which shows the test result about the influence which the reaction temperature of activated carbon has on NP adsorption ability. 本発明の実施例の試験において、活性炭の反応時間がNP吸着能に及ぼす影響についての試験結果を示す図である。In the test of the Example of this invention, it is a figure which shows the test result about the influence which reaction time of activated carbon has on NP adsorption ability. 本発明の実施例の試験において、二番搾りを活性炭処理し、同じ仕込に戻すことがビールのNPに及ぼす影響についての試験結果を示す図である。In the test of the Example of this invention, it is a figure which shows the test result about the influence which squeezing the second squeeze process and returning to the same preparation has on NP of beer.

Claims (6)

発酵麦芽飲料の製造工程において、仕込麦汁濾過工程において調製された二番搾り麦汁を、平均細孔直径1.5−2.0nmの活性炭を用いて、添加量1.5−3g/L、麦汁温度78℃以上、反応処理時間1分以上の条件で、処理することを特徴とする劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法。 In the production process of fermented malt beverage, the second squeezed wort prepared in the charged wort filtration step is made using activated carbon having an average pore diameter of 1.5-2.0 nm, and the added amount is 1.5-3 g / L. In addition, fermented malt drink with reduced content of trans-2-nonenal potential and stabilized flavor, characterized by being processed under conditions of wort temperature of 78 ° C or higher and reaction time of 1 minute or longer Manufacturing method. 活性炭の形態が、粉末又はフィルター状活性炭であることを特徴とする請求項1記載の劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法。 The method for producing a fermented malt beverage having reduced degradation odor-causing substance trans-2-nonenal potential and stabilizing the flavor according to claim 1, wherein the activated carbon is in the form of powder or filter-like activated carbon. . 二番搾り麦汁を請求項1記載の条件で活性炭処理した後、該麦汁を、麦汁濾過以降の仕込工程中の煮沸中或いは煮沸後に添加することを特徴とする劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法。 The second squeezed wort is treated with activated carbon under the conditions described in claim 1, and then the wort is added during or after boiling in the charging process after wort filtration. 2-Nonenal The manufacturing method of the fermented malt drink which reduced content of potential and stabilized the flavor. 二番搾り麦汁を請求項1記載の条件で活性炭処理した後、該麦汁を、別のバッチの仕込工程中において、麦下し時の醸造用水として、麦汁濾過時の撒き湯として用いるか、或いは仕込工程中の煮沸中或いは煮沸後に添加することを特徴とする劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法。 After the second squeezed wort is treated with activated carbon under the conditions described in claim 1, the wort is used as brewing water at the time of mashing and as boiling water at the time of wort filtration during the charging process of another batch. Or a method for producing a fermented malt beverage in which the content of a deteriorated odor causing substance trans-2-nonenal potential is reduced and the flavor is stabilized, which is added during or after boiling in the preparation step. 発酵麦芽飲料が、ビール又は発泡酒であることを特徴とする請求項1〜4のいずれか記載の劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料の製造方法。 The fermented malt beverage is reduced in content of the degraded odor-causing substance trans-2-nonenal potential and stabilized in flavor, wherein the fermented malt beverage is beer or happoshu. A method for producing a beverage. 請求項1〜5のいずれか記載の発酵麦芽飲料の製造方法によって製造された劣化臭原因物質トランス−2−ノネナール ポテンシャルの含有量を低減し、香味を安定化した発酵麦芽飲料。
A fermented malt beverage in which the content of a degraded odor-causing substance trans-2-nonenal potential produced by the method for producing a fermented malt beverage according to any one of claims 1 to 5 is reduced and the flavor is stabilized.
JP2008302523A 2008-11-27 2008-11-27 Method for producing flavor-stabilized fermented malt beverage Pending JP2010124748A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020178637A (en) * 2019-04-26 2020-11-05 アサヒビール株式会社 Fermented malt beverage packed in gas-permeable container

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020178637A (en) * 2019-04-26 2020-11-05 アサヒビール株式会社 Fermented malt beverage packed in gas-permeable container

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