JP2010119975A - Method of manufacturing in-mold coated article - Google Patents

Method of manufacturing in-mold coated article Download PDF

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JP2010119975A
JP2010119975A JP2008297361A JP2008297361A JP2010119975A JP 2010119975 A JP2010119975 A JP 2010119975A JP 2008297361 A JP2008297361 A JP 2008297361A JP 2008297361 A JP2008297361 A JP 2008297361A JP 2010119975 A JP2010119975 A JP 2010119975A
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mold
coated
coating
magnetic
paint
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Akiyuki Iimuro
暁之 飯室
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Nissha Printing Co Ltd
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Nissha Printing Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method of manufacturing in-mold coated article capable of forming a design based on orientation of a magnetic material on a desired place irrespective of a shape on the back surface of an object to be coated. <P>SOLUTION: An in-mold coated mold provided with an object to be coated retention mold 11 and a coating film formation mold 12 in which a magnet 21 is arranged is used, the object 1 to be coated is set to the object to be coated retention mold 11, thereafter, the object to be coated retention mold 11 and the coating film formation mold 12 are closed, a coating cavity 22 for coating the object 1 to be coated with a magnetic paint 2 containing the magnetic material is formed between the object 1 to be coated and the coating film formation mold 12, the magnetic paint 2 is injected into the coating cavity 22, thereafter, an orientation pattern of the magnetic material is formed by the magnet 21, thereafter, the magnetic paint 2 is solidified and, thereby, the magnetic paint 2 is integrally applied on the object 1 to be coated. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、主として自動車の内装パーツや携帯電話・携帯メディアプレーヤー、その他の電化製品類の外装パーツに利用できる、磁性材料が所望の配向パターンを形成するように磁性塗料を被塗物に一体被覆させる型内塗装品の製造方法に関する。   The present invention is mainly used for interior parts of automobiles, exterior parts of mobile phones / portable media players, and other electrical appliances, and a magnetic coating is integrally coated on an object so that a magnetic material forms a desired orientation pattern. The present invention relates to a method for manufacturing an in-mold coated product.

従来、自動車、家電その他電化製品の外装パーツなどに使用される樹脂成形品などの被塗物について、磁性材料を含む磁性塗料を塗布し、磁力を印加することで磁性材料を配向させて独特な外観の意匠を形成する技術があった(特許文献1、2参照)。この技術においては被塗物101の背面に磁石111を配置した状態で被塗物101の表面に磁性塗料102をスプレー塗装などで塗布すると、磁石が配置された付近の磁性塗料102に磁性材料の配向パターンが形成される(図2参照)。   Conventionally, for coating objects such as resin molded products used for exterior parts of automobiles, home appliances and other electrical appliances, a magnetic paint containing a magnetic material is applied and magnetic material is oriented by applying magnetic force to make it unique. There has been a technique for forming an appearance design (see Patent Documents 1 and 2). In this technique, when the magnetic paint 102 is applied to the surface of the article 101 with the magnet 111 on the back surface of the article 101 by spray coating or the like, the magnetic material 102 is applied to the magnetic paint 102 near the magnet. An alignment pattern is formed (see FIG. 2).

特開2003−176452号公報Japanese Patent Laid-Open No. 2003-176252 特開平5−31460号公報JP-A-5-31460

しかし、被塗物101の背面が複雑な構造になっている場合、例えばリブやボスなどの突起が立っていて凹凸形状が形成されている場合にはその部分に磁石111を配置することができないため、磁力を印加できる範囲に制限が生じる。また、被塗物101の厚みそのものが大きい場合は磁石111と被塗物表面の磁性塗料102との距離が離れ、十分な磁力がかけられない場合もあった。また、磁性材料にはしばしば金属粉が使用されるが、比重が大きくなることから塗装したあと硬化する前に磁性塗料102が液ダレを起こしやすいという問題もあった。   However, when the back surface of the article 101 has a complicated structure, for example, when protrusions such as ribs and bosses are standing and an uneven shape is formed, the magnet 111 cannot be disposed at that portion. For this reason, the range in which the magnetic force can be applied is limited. In addition, when the thickness of the object 101 is large, the distance between the magnet 111 and the magnetic paint 102 on the surface of the object is so large that a sufficient magnetic force may not be applied. In addition, metal powder is often used as the magnetic material, but since the specific gravity increases, there is also a problem that the magnetic coating material 102 is liable to sag before being cured after being coated.

本発明は上記の問題が発生しないようにするための型内塗装品の製造方法を提供することを目的とする。   It is an object of the present invention to provide a method for manufacturing an in-mold coated product so as not to cause the above-described problems.

本発明は前記目的を達成するため、以下のような特徴を備える。   In order to achieve the above object, the present invention has the following features.

本発明の型内塗装品の製造方法は、被塗物保持金型と磁石が配置された塗膜形成金型とを備える型内塗装金型を用い、被塗物保持金型に被塗物をセットした後、被塗物保持金型と塗膜形成金型とを型閉じして、磁性材料を含有する磁性塗料で被塗物を塗装するための塗装キャビティを被塗物と塗膜形成金型との間に形成し、塗装キャビティ内に磁性塗料を注入後、磁石により磁性材料の配向パターンを形成した後、磁性塗料を固化させることにより、磁性塗料を被塗物に一体被覆させることを特徴とする。   The method for producing an in-mold coated product of the present invention uses an in-mold coating mold that includes a coating object holding mold and a coating film forming mold on which magnets are arranged, and the article to be coated is applied to the coating object holding mold. After setting the coating, the coating object holding mold and the coating film forming mold are closed, and a coating cavity for coating the coating object with a magnetic paint containing magnetic material is formed. Formed between the mold, injecting the magnetic paint into the coating cavity, forming an orientation pattern of the magnetic material with a magnet, and then solidifying the magnetic paint to coat the magnetic paint on the object to be coated It is characterized by.

また、上記の発明において、少なくとも裏面に凹凸形状が形成された位置と反対側の被塗物の表面位置に磁性材料の配向パターンを形成してもよい。   In the above invention, an orientation pattern of the magnetic material may be formed at least on the surface position of the object to be coated on the opposite side to the position where the uneven shape is formed on the back surface.

本発明の型内塗装品の製造方法は、以上のとおりの工程を有するので、次のような優れた効果を有する。   Since the method for producing an in-mold coated product of the present invention includes the steps as described above, it has the following excellent effects.

本発明は、塗装キャビティ内に磁性材料を含む磁性塗料を注入後、塗膜形成金型側に配置された磁石により磁性材料の配向パターンを形成した後、磁性塗料を固化させることにより、磁性塗料を被塗物に一体被覆する。したがって、被塗物の表側から磁力を印加する形になるので、被塗物裏面の形状に関係なく、所望の場所に磁性材料の配向による意匠を形成することができる。また、密閉された塗装キャビティに塗料を充填する方式であるため、顔料の比重に関わらず液ダレを起こすことがない。   According to the present invention, after injecting a magnetic paint containing a magnetic material into a coating cavity, an orientation pattern of the magnetic material is formed by a magnet disposed on the coating film forming mold side, and then the magnetic paint is solidified, thereby Is integrally coated on the workpiece. Therefore, since magnetic force is applied from the front side of the object to be coated, a design based on the orientation of the magnetic material can be formed at a desired place regardless of the shape of the back surface of the object to be coated. In addition, since it is a system in which a coating is filled in a sealed coating cavity, dripping does not occur regardless of the specific gravity of the pigment.

図面を参照しながらこの発明の実施の形態について詳しく説明する。   Embodiments of the present invention will be described in detail with reference to the drawings.

本発明に使用される被塗物1の材質としては、アルミニウムなどの非磁性金属、プラスチック、セラミックなどを使用できる。また金属材質のものでも後述する磁石が強力なものを用いれば適用可能である。これらは予め前処理や下地塗装等が施されていてもよい。これら被塗物の裏面には例えばボス4、リブ、爪部などの凹凸形状が形成されていてもよい(図1参照)。   As the material of the article 1 to be used in the present invention, nonmagnetic metals such as aluminum, plastics, ceramics and the like can be used. Moreover, even if it uses a metal material, it is applicable if a magnet having a strong magnet described later is used. These may be subjected to pretreatment or base coating in advance. Irregular shapes such as bosses 4, ribs, and claw portions may be formed on the back surfaces of these objects to be coated (see FIG. 1).

本発明に使用する型内塗装金型は、被塗物保持金型11と磁石21が配置された塗膜形成金型12とを備える。被塗物保持金型11は被塗物1と塗膜形成金型12との間で塗装キャビティ22を形成するように被塗物1を保持するものであり、塗膜形成金型12は被塗物1の表面に後述する磁性塗料2による塗膜を形成するものである(図1(a)〜(c)参照)。   The in-mold coating mold used in the present invention includes an object holding mold 11 and a coating film forming mold 12 on which a magnet 21 is arranged. The coating object holding die 11 holds the coating object 1 so as to form a coating cavity 22 between the coating object 1 and the coating film forming mold 12. A coating film is formed on the surface of the coating 1 by a magnetic coating 2 described later (see FIGS. 1A to 1C).

塗装キャビティ22は、後述する磁性材料を含有する磁性塗料2で被塗物1の表面を塗装するために形成されたキャビティである。塗装キャビティ22の形状は、磁性塗料2による塗膜の所望するパターンや厚みに応じて適宜設定する。塗装キャビティ22は被塗物1の表面全体に渡っていてもよいし、被塗物1の一部にのみ形成されていてもよい。塗装キャビティ22は塗膜の厚みが10μm〜100μm程度になるよう設定するのがよい。   The coating cavity 22 is a cavity formed for coating the surface of the article 1 with a magnetic paint 2 containing a magnetic material described later. The shape of the coating cavity 22 is appropriately set according to the desired pattern and thickness of the coating film made of the magnetic paint 2. The coating cavity 22 may extend over the entire surface of the object 1 or may be formed only on a part of the object 1. The coating cavity 22 is preferably set so that the thickness of the coating film is about 10 μm to 100 μm.

磁性塗料2の注入口は塗膜形成金型12側に設置してもよいし、被塗物保持金型11側にしてもよい。磁性塗料2の注入位置は、塗装キャビティ22の中央付近に設けてもよいが、ノズルピン後が残るため、外観が要求される場合には、鍵穴やエンブレム取り付け位置等を利用したり、製品の外側に仮製品部を設けてそこに注入位置を設置すればよい。   The inlet for the magnetic paint 2 may be installed on the coating film forming mold 12 side or on the article holding mold 11 side. The injection position of the magnetic paint 2 may be provided near the center of the coating cavity 22, but after the nozzle pin remains, if the appearance is required, the key hole or emblem mounting position can be used, or the outside of the product The provisional product part may be provided in the container and the injection position may be set there.

磁石21としては、永久磁石、電磁石、超伝導磁石などを用いることができる。磁石21は塗膜形成金型12のキャビティ面の任意の位置に設置できる。磁石21はキャビティ面に直接配置してもよいが、キャビティ面そのものは非磁性の薄い金属板で形成し、この金属板の裏面に別途磁石21を配置する構造にすると、塗膜表面に磁石の部材と非磁性の部材との境界線が現れることを防ぐことができ、より美麗な仕上げ状態を得ることができる。   As the magnet 21, a permanent magnet, an electromagnet, a superconducting magnet, or the like can be used. The magnet 21 can be installed at an arbitrary position on the cavity surface of the coating film forming mold 12. The magnet 21 may be disposed directly on the cavity surface. However, if the cavity surface itself is formed of a non-magnetic thin metal plate and the magnet 21 is separately disposed on the back surface of the metal plate, the magnet surface is formed on the coating film surface. It is possible to prevent the boundary line between the member and the nonmagnetic member from appearing, and to obtain a more beautiful finish state.

本発明に使用する磁性塗料2は、熱硬化性の塗料成分と磁性材料を主成分として含有する。磁性塗料2は、従来型のスプレーやディッピングで使用される塗料のようには揮発性有機溶剤を含んでいないか、含んでいても非常に少なくなっている。   The magnetic paint 2 used in the present invention contains a thermosetting paint component and a magnetic material as main components. The magnetic paint 2 does not contain or does not contain a volatile organic solvent like the paint used in conventional spraying and dipping.

上記熱硬化性の塗料成分としては、不飽和ポリエステル樹脂、エポキシアクリレートオリゴマー、ウレタンアクリレートオリゴマーなどの過酸化物触媒によって硬化が可能なバインダー成分を主体とする一液型塗料や、エポキシ樹脂/ポリアミン硬化系、ポリオール樹脂/ポリイソシアネート硬化系などの、金型注入直前に主剤/硬化剤を混合する二液型塗料などがあげられる。その中でも、アクリレート基を有するオリゴマー又は不飽和ポリエステル樹脂、あるいはこれらの成分と共重合可能なエチレン性不飽和モノマーのうちのいずれかと架橋効率が8以上である有機過酸化物開始剤を含有する一液型塗料は、硬化性・付着性・外観・耐候性に優れており、硬化時間を短縮でき、付着力・外観・耐候性の問題から型内被覆方法を適用できなかった樹脂成形材料にも適用可能である点で非常に良好である。また、紫外線や電子線により励起する反応開始剤を配合して、金型から型内塗装品3を取り出したあとにこれらエネルギー線を照射することで更に架橋密度を上昇させてもよい。   The thermosetting paint components include one-component paints mainly composed of binder components that can be cured by peroxide catalysts such as unsaturated polyester resins, epoxy acrylate oligomers, urethane acrylate oligomers, and epoxy resin / polyamine curing. And two-component paints such as a polyol resin / polyisocyanate curing system in which a main agent / curing agent is mixed immediately before mold injection. Among them, an oligomer containing an acrylate group or an unsaturated polyester resin, or an ethylenically unsaturated monomer copolymerizable with these components and an organic peroxide initiator having a crosslinking efficiency of 8 or more are contained. Liquid paints are excellent in curability, adhesion, appearance, and weather resistance, can shorten the curing time, and can be applied to resin molding materials for which in-mold coating methods cannot be applied due to problems with adhesion, appearance, and weather resistance. It is very good in that it can be applied. Further, a crosslinking agent may be further increased by blending a reaction initiator excited by ultraviolet rays or electron beams and irradiating these energy rays after taking out the in-mold coated product 3 from the mold.

上記磁性材料としては、ニッケルや鉄などの金属粉を使用できる。また、雲母やアルミニウム粉、アルミナフレーク、ガラスフレークなどの鱗片状顔料を母剤として、これらの表面に磁性金属が被覆された顔料を使用してもよい。   As said magnetic material, metal powders, such as nickel and iron, can be used. Further, pigments whose surfaces are coated with a magnetic metal may be used using scaly pigments such as mica, aluminum powder, alumina flakes, and glass flakes as a base agent.

本発明の型内塗装品の製造方法を説明する。   The method for producing the in-mold coated product of the present invention will be described.

まず、被塗物保持金型11に被塗物1をセットした後、被塗物保持金型11と塗膜形成金型12とを型閉じして、磁性材料を含有する磁性塗料2で被塗物1を塗装するための塗装キャビティ22を被塗物1と塗膜形成金型12との間に形成する(図1(a)参照)。   First, the article 1 is set in the article-holding mold 11, and then the article-holding mold 11 and the coating-film-forming mold 12 are closed and covered with a magnetic paint 2 containing a magnetic material. A coating cavity 22 for applying the coating 1 is formed between the coating 1 and the coating film forming mold 12 (see FIG. 1A).

次いで、この塗装キャビティ22内に磁性塗料2を注入後、磁石21により磁性材料の配向パターンを形成した後、磁性塗料2を固化させることにより、磁性材料が所望の配向パターンを形成するように磁性塗料2を被塗物1に一体被覆させることができる(図1(b)参照)。   Next, after injecting the magnetic paint 2 into the coating cavity 22, an orientation pattern of the magnetic material is formed by the magnet 21, and then the magnetic paint 2 is solidified so that the magnetic material forms a desired orientation pattern. The paint 2 can be integrally coated on the article 1 (see FIG. 1B).

磁性塗料2は、例えばポンプ31から塗料注入機32に供給され、塗料注入機32から1ショット分の正確な量が適度な圧力で塗装キャビティ22に注入される(図1(a)、(b)参照)。磁性塗料2の注入時間は1〜10秒程度で、磁性塗料2の材質や塗装キャビティ22の大きさなどによって適宜設定する。磁性塗料2の注入圧力は10〜400kgf/cm程度の範囲内で適宜設定すると良いが、塗膜中にバリや気泡を防止するためには圧力は高めに設定した方が好ましい。磁性塗料2の注入位置は、ノズル後が残るのを防止するため、鍵穴やエンブレム取り付け位置等を利用したり、製品の外側に仮製品部を設けてそこに設置するのが好ましい。 The magnetic paint 2 is supplied from, for example, a pump 31 to a paint injector 32, and an accurate amount for one shot is injected from the paint injector 32 into the paint cavity 22 with an appropriate pressure (FIGS. 1A and 1B). )reference). The injection time of the magnetic paint 2 is about 1 to 10 seconds, and is appropriately set depending on the material of the magnetic paint 2 and the size of the coating cavity 22. The injection pressure of the magnetic coating material 2 is suitably set within a range of about 10 to 400 kgf / cm 2 , but it is preferable to set the pressure higher in order to prevent burrs and bubbles in the coating film. In order to prevent the magnetic paint 2 from being injected after the nozzle, it is preferable to use a keyhole, an emblem mounting position, or the like, or provide a temporary product portion outside the product and install it there.

磁性塗料2の粘度としては、2000〜7000mPa・sの範囲内でパターンや厚みに応じて適宜設定する。とくに本発明の場合、被塗物保持金型11と塗膜形成金型12とはキャビティ以外にほとんど隙間がなくかつ強固な型締め圧で金型を固定できるので、磁性塗料2中の磁性材料として金属粉が使用されて比重が大きくなっても液ダレを起こすことがなく、磁性塗料2が漏れやすい非常に低い粘度であっても磁性塗料2が塗装キャビティ22から漏れることがない点で有利である。   As a viscosity of the magnetic coating material 2, it sets suitably according to a pattern and thickness within the range of 2000-7000 mPa * s. Particularly in the case of the present invention, the coating material holding mold 11 and the coating film forming mold 12 have almost no gap other than the cavity and can be fixed with a strong clamping pressure. As the metal powder is used, it does not cause dripping even when the specific gravity increases, and it is advantageous in that the magnetic paint 2 does not leak from the coating cavity 22 even if the magnetic paint 2 has a very low viscosity that easily leaks. It is.

被塗物保持金型11および塗膜形成金型12の金型温度は、金型温度調節機により設定する。金型温度調節機の媒体は水でも油でもよい。塗膜形成金型12の金型温度は、磁性塗料2の材質に応じて磁性塗料2が数秒以内に硬化する温度に設定する。   The mold temperatures of the article holding mold 11 and the coating film forming mold 12 are set by a mold temperature controller. The medium of the mold temperature controller may be water or oil. The mold temperature of the coating film forming mold 12 is set to a temperature at which the magnetic paint 2 is cured within a few seconds depending on the material of the magnetic paint 2.

最後に、被塗物保持金型11と塗膜形成金型12とを型開きすると型内塗装品3を取り出すことができる(図1(c)参照)。   Finally, when the article holding mold 11 and the coating film forming mold 12 are opened, the in-mold coated product 3 can be taken out (see FIG. 1C).

ここで、磁石21は塗膜形成金型12側に配置されていて被塗物1の表側から磁力を印加する形になるので、被塗物1の裏面に例えばボス4、リブ、爪部などの凹凸形状が形成されていても、被塗物裏面の形状に関係なく、所望の場所に磁性材料の配向パターンによる意匠を形成することができる。   Here, since the magnet 21 is disposed on the coating film forming mold 12 side and applies a magnetic force from the front side of the object 1 to be coated, for example, a boss 4, a rib, a nail portion, etc. on the back surface of the object 1 to be coated Even if the concavo-convex shape is formed, a design based on the orientation pattern of the magnetic material can be formed at a desired location regardless of the shape of the back surface of the object to be coated.

裏面外周部に筐体ハメ込み用のボスを備え、ボス形成位置と反対側の表面位置に磁性材料による配向パターンの意匠が形成された樹脂パーツを下記の手順により形成した。   A resin part provided with a boss for housing casing on the outer periphery of the back surface and having an orientation pattern design made of a magnetic material at the surface position opposite to the boss formation position was formed by the following procedure.

被塗物保持金型と電磁石が配置された塗膜形成金型とを備える型内塗装金型を準備し、被塗物として裏面外周部に筐体ハメ込み用のボスを備える黒色のポリカーボネート製樹脂パーツを、被塗物保持金型にセットした後、被塗物保持金型と塗膜形成金型とを型閉じして、磁性材料を含有する磁性塗料で被塗物を塗装するための塗装キャビティを被塗物と塗膜形成金型との間に形成した。そして、塗装キャビティ内に磁性塗料として粉末磁性材料(ステンレス製、鱗片形状、長手方向粒径10〜30μm)を10%混合した二液硬化のアクリルウレタン系のインキを注入した。磁性材料に対して塗膜形成金型に取り付けた電磁石によって配向パターンを形成した後、金型の熱(型温90℃設定)により磁性塗料を固化させ、型開きして型内塗装品を得た。塗膜形成金型に配置された電磁石はボス形成位置と反対側の樹脂パーツ表面位置付近に配置されており、得られた型内塗装品はボス形状の影響を受けずに磁性材料による所望の配向パターンが形成され、独特な意匠を備え、外観に優れたものであった。   Made of in-mold coating mold with coating object holding mold and coating film forming mold with electromagnet arranged, and made of black polycarbonate with boss for housing saddle on the back outer periphery as coating object After the resin parts are set in the object holding mold, the object holding mold and the coating film forming mold are closed, and the object to be coated with the magnetic paint containing the magnetic material. A coating cavity was formed between the object to be coated and the film forming mold. Then, a two-component curable urethane urethane ink in which 10% of a magnetic powder material (stainless steel, scale shape, longitudinal particle size of 10 to 30 μm) was mixed as a magnetic coating material was injected into the coating cavity. After an orientation pattern is formed on the magnetic material by an electromagnet attached to the coating film forming mold, the magnetic paint is solidified by the mold heat (mold temperature set at 90 ° C), and the mold is opened to obtain an in-mold coated product. It was. The electromagnet placed in the coating film forming mold is placed near the resin part surface position on the opposite side of the boss formation position. An orientation pattern was formed, a unique design was provided, and the appearance was excellent.

本発明の型内塗装品の製造方法を示す断面図である。It is sectional drawing which shows the manufacturing method of the in-mold coating goods of this invention. 従来の塗装品の製造方法を示す断面図である。It is sectional drawing which shows the manufacturing method of the conventional coating goods.

符号の説明Explanation of symbols

1 被塗物
2 磁性塗料
3 型内塗装品
4 ボス
11 被塗物保持金型
12 塗膜形成金型
21 磁石
22 塗装キャビティ
31 ポンプ
32 塗料注入機
101 被塗物
102 磁性塗料
111 磁石
DESCRIPTION OF SYMBOLS 1 Coated object 2 Magnetic paint 3 Coated product 4 Boss 11 Coated object holding mold 12 Coating film forming mold 21 Magnet 22 Painting cavity 31 Pump
32 Paint Injection Machine 101 Workpiece 102 Magnetic Paint 111 Magnet

Claims (2)

被塗物保持金型と磁石が配置された塗膜形成金型とを備える型内塗装金型を用い、
被塗物保持金型に被塗物をセットした後、被塗物保持金型と塗膜形成金型とを型閉じして、磁性材料を含有する磁性塗料で被塗物を塗装するための塗装キャビティを被塗物と塗膜形成金型との間に形成し、塗装キャビティ内に磁性塗料を注入後、磁石により磁性材料の配向パターンを形成した後、磁性塗料を固化させることにより、磁性塗料を被塗物に一体被覆させることを特徴とする型内塗装品の製造方法。
Using an in-mold coating mold comprising an object holding mold and a coating film forming mold on which magnets are arranged,
After setting the object to be coated in the object holding mold, the object holding mold and the coating film forming mold are closed, and the object to be coated is coated with a magnetic paint containing a magnetic material. A coating cavity is formed between an object to be coated and a coating film forming mold, magnetic paint is injected into the coating cavity, an orientation pattern of the magnetic material is formed by a magnet, and then the magnetic paint is solidified to solidify the magnetic coating. A method for producing an in-mold coated product, characterized in that a paint is integrally coated on an object to be coated.
少なくとも裏面に凹凸形状が形成された位置と反対側の被塗物の表面位置に磁性材料の配向パターンを形成する請求項1に記載の型内塗装品の製造方法。

The method for producing an in-mold coated product according to claim 1, wherein an orientation pattern of the magnetic material is formed at least on the surface position of the object to be coated opposite to the position where the uneven shape is formed on the back surface.

JP2008297361A 2008-11-20 2008-11-20 Method of manufacturing in-mold coated article Withdrawn JP2010119975A (en)

Priority Applications (1)

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Publications (1)

Publication Number Publication Date
JP2010119975A true JP2010119975A (en) 2010-06-03

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Country Status (1)

Country Link
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