JP2010075644A - Mouthpiece softened with hot water and preventing setting of side in softening - Google Patents
Mouthpiece softened with hot water and preventing setting of side in softening Download PDFInfo
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- JP2010075644A JP2010075644A JP2008273572A JP2008273572A JP2010075644A JP 2010075644 A JP2010075644 A JP 2010075644A JP 2008273572 A JP2008273572 A JP 2008273572A JP 2008273572 A JP2008273572 A JP 2008273572A JP 2010075644 A JP2010075644 A JP 2010075644A
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- hot water
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- front stabilizer
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000003381 stabilizer Substances 0.000 claims abstract description 29
- 239000000463 material Substances 0.000 claims description 7
- 238000007665 sagging Methods 0.000 claims description 2
- 229920005989 resin Polymers 0.000 abstract description 13
- 239000011347 resin Substances 0.000 abstract description 13
- 229920001169 thermoplastic Polymers 0.000 abstract description 12
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 12
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 210000004513 dentition Anatomy 0.000 description 5
- 210000000214 mouth Anatomy 0.000 description 5
- 230000036346 tooth eruption Effects 0.000 description 5
- 238000012790 confirmation Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000002265 prevention Effects 0.000 description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920013716 polyethylene resin Polymers 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 210000003254 palate Anatomy 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
Abstract
Description
本発明は、熱可塑性弾性樹脂性の熱湯軟化式マウスピースに関する。The present invention relates to a thermoplastic elastic resinous hot water softening mouthpiece.
従来の熱可塑性弾性樹脂性の熱湯軟化式マウスピースは熱湯で軟化後、箸などで取り出し、上顎歯列に装着・咬合させることで、歯列の形状と咬合関係を記録させる方式なので、熱湯軟化時にマウスピース側面にへたり現象が生じることを防ぐ為、マウスピース側面(上顎頬側部分)に少なくても1.5mm以上(最厚部)の肉厚を確保しておく必要があった。The conventional thermoplastic elastic resin hot water softening mouthpiece is softened with hot water, taken out with chopsticks, etc., and attached to the maxillary dentition so that it records the shape and occlusal relationship of the dentition. In order to prevent a sag phenomenon on the side of the mouthpiece from time to time, it was necessary to secure a wall thickness of at least 1.5 mm (the thickest part) on the side of the mouthpiece (upper cheek side).
このようにして、成型された従来の熱可塑性弾性樹脂性の熱湯軟化式マウスピースを熱湯で軟化後、箸などで取り出し、上顎歯列に装着・咬合させることで完成させると、上顎頬側部分が分厚くなり装着感が悪いという欠点があった。特に上顎頬側部分の前歯部分が分厚くなり唇が痛いというような欠点があった。In this way, when the molded conventional thermoplastic elastic resin hot water softening mouthpiece is softened with hot water, taken out with chopsticks, etc. and completed by attaching and biting to the maxillary dentition, the upper jaw buccal side part However, there was a drawback that it became thick and the wearing feeling was bad. In particular, there was a defect that the front teeth of the upper cheek side became thick and the lips hurt.
そこで本発明では、熱可塑性弾性樹脂性の熱湯軟化式マウスピースでありながら、完成後は、上顎頬側部分が分厚くなく装着感が良く、しかも唇も痛くないというマウスピースの提供を目的とした。Therefore, the present invention aims to provide a mouthpiece that is a thermoplastic elastic resin hot water softening mouthpiece, and that after completion, the upper cheek side portion is not thick and has a good wearing feeling, and the lips do not hurt. .
本発明者は、上記目的を連成するために研究を行った結果、熱可塑性弾性樹脂を用いた熱湯軟化式マウスピースの頬側部分側面に熱湯で軟化されないフロントスタビライザー(可撤性シール)を設けることを見いだし、本発明を完成するに至った。The present inventor conducted research to combine the above objectives, and as a result, a front stabilizer (removable seal) that is not softened with hot water on the cheek side portion side surface of a hot water softening mouthpiece using a thermoplastic elastic resin. As a result, the present invention has been completed.
従来の熱可塑性弾性樹脂を用いた熱湯軟化式マウスピースを熱湯で軟化すると、マウスピースを構成している咬合面部分・頬側部分側面・口蓋側部分側面のすべてが同時に軟化されるので、頬側部分側面を少なくても1.5mm以上の肉厚にしておかないと、へたり現象が生じ頬側部分側面が内側に垂れてしまい口腔内に挿入することが難しい。Softening a hot water softening mouthpiece using conventional thermoplastic elastic resin with hot water softens all the occlusal surface, cheek side surface, and palate side surface of the mouthpiece at the same time. If the side portion side surface is not made at least 1.5 mm thick, a sag phenomenon occurs and the cheek side portion side surface hangs inward, making it difficult to insert into the oral cavity.
従来の熱可塑性弾性樹脂を用いた熱湯軟化式マウスピース頬側部分側面の厚さを1.5mm以下にしても、熱湯で軟化されない、しかも口腔内に挿入した時に大きく変形しないシール状のフロントスタビライザー(可撤性シール)を設け、従来通りの方法でマウスピースを作成すると、頬側部分側面のへたり現象が阻止されるので口腔内に容易に挿入することが可能である。Hot water softening type mouthpiece using conventional thermoplastic elastic resin Even if the thickness of cheek side part side surface is 1.5mm or less, it is not softened with hot water, and it is a sealed front stabilizer that does not deform greatly when inserted into the oral cavity When a mouthpiece is prepared by a conventional method by providing a (removable seal), it is possible to easily insert the mouthpiece into the oral cavity because the sag phenomenon on the side surface of the cheek side is prevented.
このようにして作成されたマウスピースから、フロントスタビライザー(可撤性シール)を取り外し完成させると、マウスピース頬側部分側面の肉厚を薄くすることが出来る。熱湯で軟化されないフロントスタビライザー(可撤性シール)とマウスピース頬側部分側面との接着具合は、マウスピースを熱湯に浸した時に剥離してはならず、マウスピースが常温で硬化した時には簡単に剥離することができなければならない。When the front stabilizer (removable seal) is removed and completed from the mouthpiece thus created, the thickness of the side surface of the mouthpiece cheek side can be reduced. The adhesion between the front stabilizer (removable seal) that is not softened with hot water and the mouthpiece cheek side surface should not be peeled off when the mouthpiece is immersed in hot water, but easily when the mouthpiece is cured at room temperature Must be able to peel.
このように側面の厚さを薄くした熱可塑性弾性樹脂を用いた熱湯軟化式マウスピースは、90℃以上の高温の湯で短時間軟化(1分以内)する場合に比べ、70℃程度の湯で長時間軟化(2分程度)したほうが、へたり現象が生じにくい。The hot water softening mouthpiece using the thermoplastic elastic resin having a thin side surface in this way has a temperature of about 70 ° C. compared to softening for a short time (within 1 minute) with hot water of 90 ° C. or higher. When it is softened for a long time (about 2 minutes), the sag phenomenon is less likely to occur.
このようにして完成されたマウスピースは、完成時にマウスピース頬側部分側面を薄くすることができるので、装着感が良く、しかも唇も痛くない。Since the mouthpiece completed in this way can be thinned on the side of the mouthpiece buccal side at the time of completion, the feeling of wearing is good and the lips do not hurt.
発明の実施の形態を実施例にもとづき図面を参照して説明するが、これらの実施例に限定されるものではない。Embodiments of the invention will be described with reference to the drawings based on examples, but are not limited to these examples.
図1は本発明に係るフロントスタビライザー(可撤性シール)2付き熱湯軟化式マウスピースの全体を示す上部平面図、図2は斜視図、図3は分解図である。FIG. 1 is an upper plan view showing an entire hot water softening mouthpiece with a front stabilizer (removable seal) 2 according to the present invention, FIG. 2 is a perspective view, and FIG. 3 is an exploded view.
フロントスタビライザー(可撤性シール)2を除くマウスピース本体部分は、一般的な熱湯軟化式マウスピースに使用されているエチレン−ビニル−アセテート共重合体等の材質が好ましい。フロントスタビライザー(可撤性シール)2は薄い紙状のシール(1mm以下)であり、熱湯で軟化されない性状であり、且つマウスピースを熱湯に浸したときに剥離してはならず、マウスピースの完成後に簡単に剥がせることが条件となり、軟化したマウスピースを口腔内に挿入したり咬合した時に伸びたり大きく変形してはならない。紙又は樹脂を含有した合成紙を用いる場合は、簡単に洗い流せる性状で毒性の低い接着剤を用い、ポリエチレン樹脂やPET樹脂等のプラスティックを主原料とするシールを用いる場合は、マウスピース下部と圧接すると気密性による接着力が生じるので接着剤は使用してもしなくても良い。The mouthpiece main body portion excluding the front stabilizer (removable seal) 2 is preferably made of a material such as an ethylene-vinyl-acetate copolymer used in a general hot water softening mouthpiece. The front stabilizer (removable seal) 2 is a thin paper-like seal (1 mm or less) that is not softened with hot water and must not be peeled off when the mouthpiece is immersed in hot water. It must be easily peeled off after completion and should not stretch or deform significantly when the softened mouthpiece is inserted or bitten into the oral cavity. When using synthetic paper containing paper or resin, use a low-toxic adhesive that can be easily washed away, and when using a seal made mainly of plastics such as polyethylene resin or PET resin, press the lower part of the mouthpiece. Then, an adhesive force due to airtightness is generated, so that an adhesive may or may not be used.
図1、図2、図3に示すマウスピース本体部分1は上顎歯列を覆うように中空の略馬蹄形をなし、この形状及び熱湯軟化時の性状及び硬化後の性状は従来の熱可塑性マウスピースと基本的に同一である。The
さらに、フロントスタビライザー(可撤性シール)2を作成するには、抜き型を用いた公知の作成方法があり、完成後のマウスピース本体部分に貼付ければ良い。Furthermore, in order to produce the front stabilizer (removable seal) 2, there is a known production method using a punching die, which may be applied to the mouthpiece body portion after completion.
図4は図2A−Aの断面図であり、マウスピース本体頬側部分側面1aに貼りついたフロントスタビライザー(可撤性シール)2が存在する。FIG. 4 is a cross-sectional view of FIG. 2A-A, and there is a front stabilizer (removable seal) 2 attached to the mouthpiece body cheek side
さらに発明の実施の形態を実施例にもとづき図面を参照して説明するが、これらの実施例に限定されるものではない。Further, embodiments of the invention will be described based on examples with reference to the drawings, but the invention is not limited to these examples.
図5は第2発明におけるフロントスタビライザー(可撤性シール)2付き熱湯軟化式マウスピースの全体を示す上部平面図、図6は斜視図、図7は分解図である。FIG. 5 is an upper plan view showing the entire hot water softening mouthpiece with a front stabilizer (removable seal) 2 in the second invention, FIG. 6 is a perspective view, and FIG. 7 is an exploded view.
フロントスタビライザー(可撤性シール)2を除くマウスピース本体部分1及び本体内側部分3は、一般的なエチレン−ビニル−アセテート共重合体等の材質が好ましい。The mouthpiece
フロントスタビライザー(可撤性シール)2は薄い紙状のシール(1mm以下)であり、熱湯で軟化されない性状であり、且つマウスピースを熱湯に浸したときに剥離してはならず、マウスピースの完成後に簡単に剥がせることが条件となり、軟化したマウスピースを口腔内に挿入したり咬合した時に伸びたり大きく変形してはならない。紙叉は樹脂を含有した合成紙を用いる場合は、簡単に洗い流せる性状で毒性の低い接着剤を用い、ポリエチレン樹脂やPET樹脂等のプラスティックを主原料とするシールを用いる場合は、マウスピース下部と圧接すると気密性による接着力が生じるので接着剤は使用してもしなくても良い。The front stabilizer (removable seal) 2 is a thin paper-like seal (1 mm or less) that is not softened with hot water and must not be peeled off when the mouthpiece is immersed in hot water. It must be easily peeled off after completion and should not stretch or deform significantly when the softened mouthpiece is inserted or bitten into the oral cavity. When using paper forks or synthetic paper containing resin, use a low-toxic adhesive that can be easily washed away, and when using a seal made mainly of plastics such as polyethylene resin or PET resin, Adhesive force due to hermeticity is generated when pressed, so that an adhesive may or may not be used.
マウスピース本体部分1は上顎歯列を覆うように中空の略馬蹄形をなし、この形状及び熱湯軟化時の性状及び硬化後の性状は従来の熱可塑性マウスピースと基本的に同一であるが、本体内側部分3は熱湯軟化時にマウスピース本体部分1より流動性が高くなければならない。The
さらに、フロントスタビライザー(可撤性シール)2を作成するには、抜き型を用いた公知の作成方法があり、完成後のマウスピース本体部分に貼付ければ良い。Furthermore, in order to produce the front stabilizer (removable seal) 2, there is a known production method using a punching die, which may be applied to the mouthpiece body part after completion.
図8は図6B−Bの断面図であり、マウスピース本体頬側部分側面1aに貼りついたフロントスタビライザー(可撤性シール)2が存在する。FIG. 8 is a cross-sectional view of FIG. 6B-B, and there is a front stabilizer (removable seal) 2 attached to the mouthpiece body cheek side
図9は第3発明における変色により示温する温度管理用示温材4であり、マウスピース軟化用容器に張り付けるか、浮かべるか、マウスピース本体に張り付けることで、おおよその軟化適正湯温を確認することができる。FIG. 9 is a temperature control
以下に実施例において本発明を具体的に説明するが、これらの実施例に限定されるものではない。図1、図2、図3に示すマウスピース本体部分1は熱湯軟化時にマウスピース全体が同一の流動性を示すマウスピースであり、材料は東ソー株式会社のウルトラセンを使用し、フロントスタビライザー(可撤性シール)2には厚み0.04mmのあらかじめ片面に接着剤が塗布してある合成紙を使用した。EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples. The
製品1の各部のサイズ及び重量
マウスピース本体部分1、
縱58mm×横69mm×高さ23mmの中空の略馬蹄形を呈し咬合面の厚み2.5mm、重量6.5g
マウスピース頬側部分側面1aの肉厚0.8mm
フロントスタビライザー(可撤性シール)2、
縱10mm×横70mmの中心部分にV字の切れ込みを持つ長方形を呈したシール、厚み0.04mm、Size and weight of each part of
縱 58mm × W 69mm × H 23mm, hollow, almost horseshoe shape, occlusal surface thickness 2.5mm, weight 6.5g
Mouthpiece
Front stabilizer (removable seal) 2,
シ ー ル 10mm x 70mm wide seal with a rectangular shape with a V-shaped cut at the center, thickness 0.04mm,
製造方法は、マウスピース本体部分1は金型をもちいた射出成型法を用い、フロントスタビライザー(可撤性シール)2は金属製の抜型を用いプレス加工法で作成し、完成したマウスピース本体頬側部分側面1aにフロントスタビライザー(可撤性シール)2を貼付けた。The
(1)マウスピース本体頬側部分側面1aのへたり防止確認試験
製品1のマウスピースと製品1のマウスピースからフロントスタビライザー(可撤性シール)2を取り外した製品それぞれ10検体を70℃の熱湯に2分間浸し、マウスピース本体頬側部分側面1aが内側へどの程度へたるかを試験し、2mm以上傾かないものを合格とした。(1) Mouthpiece body cheek side
合格は○不合格は×で表記した
製品1はすべて合格であり、コントロール群の製品1からフロントスタビライザー(可撤性シール)2を取り外した製品はすべて不合格であることから、製品1のマウスピース本体頬側部分側面1aのへたり防止確認試験は合格と判定した。Pass is indicated by ○. Fail is indicated by ×.
Since all
以下に実施例において本発明を具体的に説明するが、これらの実施例に限定されるものではない。図6におけるマウスピースは、マウスピース本体部分1に熱湯で軟化した時に、より流動性の高い本体内側部分3を有する多層型マウスピースで、材料は共に東ソー株式会社のウルトラセンを使用し、フロントスタビライザー(可撤性シール)2には厚み0.04mmのあらかじめ片面に接着剤が塗布してある合成紙を使用した。EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples. The mouthpiece in FIG. 6 is a multi-layered mouthpiece having a body
製品2の各部のサイズ及び重量
マウスピース本体部分1、
縱58mm×横69mm×高さ23mmの中空の略馬蹄形を呈し咬合面の厚み2.5mm、重量6.5g
マウスピース本体頬側部分側面1aの肉厚0.8mm
マウスピース本体内側部分3、
縦47mm×横63mm×高さ15mmの略馬蹄形の実体、重量3.2g
フロントスタビライザー(可撤性シール)2、
縱10mm×横70mmの中心部分にV字の切れ込みを持つ長方形を呈したシール、厚み0.04mm、Size and weight of each part of
縱 58mm × W 69mm × H 23mm, hollow, almost horseshoe shape, occlusal surface thickness 2.5mm, weight 6.5g
Mouthpiece body
Mouthpiece body
Substantial horseshoe-shaped body measuring 47 mm long x 63 mm wide x 15 mm high, weighing 3.2 g
Front stabilizer (removable seal) 2,
シ ー ル 10mm x 70mm wide seal with a rectangular shape with a V-shaped cut at the center, thickness 0.04mm,
マウスピース本体部分1は製品1と同様に作成し、本体内側部分3を金型で成型し、表面を加熱溶解後、接着圧接し、フロントスタビライザー(可撤性シール)2を製品1と同様に貼付けた。The
(1)マウスピース本体頬側部分側面1aのへたり防止確認試験
製品2のマウスピースと製品2のマウスピースからフロントスタビライザー(可撤性シール)2を取り外した製品それぞれ10検体を70℃の熱湯に2分間浸し、マウスピース本体頬側部分側面1aが内側へどの程度へたるかを試験し、2mm以上傾かないものを合格とした。(1) Mouthpiece body cheek side
合格は○不合格は×で表記した
製品2はすべて合格であり、コントロール群の製品2からフロントスタビライザー(可撤性シール)2を取り外した製品はすべて不合格であることから、製品2のマウスピース本体頬側部分側面1aのへたり防止確認試験は合格と判定した。Pass is indicated by ○. Fail is indicated by ×.
Since all
以下に実施例において本発明を具体的に説明するが、これらの実施例に限定されるものではない。図9における温度管理用示温材は、常温で赤色を呈するが70℃以上になると半分が黒色に変色し示温し、片面に接着剤が塗布してある日油技研工業株式会社の温度管理用示温材4を使用した。EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples. The temperature control temperature indicator in FIG. 9 is red at normal temperature, but when it reaches 70 ° C. or more, half of the color changes to black and the temperature is indicated.
温度管理用示温材4、
縦5mm横10mm厚さ0.3mm
Length 5mm, width 10mm, thickness 0.3mm
本発明におけるマウスピースは、歯科医院で作成するオーダーメイドマウスピースでなく、大量且つ廉価に供給できる熱可塑性弾性樹脂を用いたマウスピースでありながら、頬側部分外側を薄くすることができるので、装着感が良く、しかも唇も痛くない。The mouthpiece in the present invention is not a custom-made mouthpiece created at a dental clinic, but a mouthpiece using a thermoplastic elastic resin that can be supplied in a large amount and at a low price, while the buccal side portion outside can be thinned, Wearing feeling is good and lips are not painful.
1 マウスピース本体部分
1a マウスピース本体頬側部分側面
2 フロントスタビライザー(可撤性シール)
3 マウスピース本体内側部分
4 温度管理用示温材1
3 Mouthpiece body
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP2008273572A JP5190737B2 (en) | 2008-09-26 | 2008-09-26 | A hot water softening mouthpiece that does not sag when softened. |
Applications Claiming Priority (1)
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JP2008273572A JP5190737B2 (en) | 2008-09-26 | 2008-09-26 | A hot water softening mouthpiece that does not sag when softened. |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20160070108A (en) * | 2013-10-11 | 2016-06-17 | 울트라덴트 프로덕츠, 인코포레이티드 | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
WO2021157723A1 (en) * | 2020-02-07 | 2021-08-12 | Eco-A株式会社 | Method for manufacturing mouthpiece disc and mouthpiece disc |
US11931220B2 (en) | 2013-03-08 | 2024-03-19 | Ultradent Products, Inc. | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
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JPH0274274A (en) * | 1988-09-08 | 1990-03-14 | Sunstar Inc | Mouth piece |
JPH0742647U (en) * | 1993-12-29 | 1995-08-11 | 竹内 正敏 | Mouth guard |
JP2003190185A (en) * | 2001-12-28 | 2003-07-08 | Nr Nippon Seitai Kogo Kenkyusho | Occlusion supporting device |
JP2005118513A (en) * | 2003-10-17 | 2005-05-12 | Kondo Tsuyako | Boiling water softening type dentition compatible mouthpiece prevented from leaving indentation of mated tooth with hot water heat and providing favorable fitting property |
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JPH0274274A (en) * | 1988-09-08 | 1990-03-14 | Sunstar Inc | Mouth piece |
JPH0742647U (en) * | 1993-12-29 | 1995-08-11 | 竹内 正敏 | Mouth guard |
JP2003190185A (en) * | 2001-12-28 | 2003-07-08 | Nr Nippon Seitai Kogo Kenkyusho | Occlusion supporting device |
JP2005118513A (en) * | 2003-10-17 | 2005-05-12 | Kondo Tsuyako | Boiling water softening type dentition compatible mouthpiece prevented from leaving indentation of mated tooth with hot water heat and providing favorable fitting property |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11931220B2 (en) | 2013-03-08 | 2024-03-19 | Ultradent Products, Inc. | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
KR20160070108A (en) * | 2013-10-11 | 2016-06-17 | 울트라덴트 프로덕츠, 인코포레이티드 | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
JP2016538902A (en) * | 2013-10-11 | 2016-12-15 | ウルトラデント プロダクツ インコーポレイテッド | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
KR20210002366A (en) * | 2013-10-11 | 2021-01-07 | 울트라덴트 프로덕츠, 인코포레이티드 | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
KR102203070B1 (en) | 2013-10-11 | 2021-01-15 | 울트라덴트 프로덕츠, 인코포레이티드 | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
US10913853B2 (en) | 2013-10-11 | 2021-02-09 | Ultradent Products, Inc. | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
KR102333608B1 (en) | 2013-10-11 | 2021-12-02 | 울트라덴트 프로덕츠, 인코포레이티드 | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
US11597841B2 (en) | 2013-10-11 | 2023-03-07 | Ultradent Products, Inc. | Wax-based compositions, articles made therefrom, and methods of manufacture and use |
WO2021157723A1 (en) * | 2020-02-07 | 2021-08-12 | Eco-A株式会社 | Method for manufacturing mouthpiece disc and mouthpiece disc |
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