JP2010069781A - Method for production of thickness-biased resin sheet - Google Patents

Method for production of thickness-biased resin sheet Download PDF

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JP2010069781A
JP2010069781A JP2008241181A JP2008241181A JP2010069781A JP 2010069781 A JP2010069781 A JP 2010069781A JP 2008241181 A JP2008241181 A JP 2008241181A JP 2008241181 A JP2008241181 A JP 2008241181A JP 2010069781 A JP2010069781 A JP 2010069781A
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roller
resin sheet
sheet
peeling
mold
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Takuhiro Hayashi
卓弘 林
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Fujifilm Corp
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Fujifilm Corp
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Priority to PCT/JP2009/065303 priority patent/WO2010032613A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/222Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length characterised by the shape of the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/365Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using pumps, e.g. piston pumps
    • B29C48/37Gear pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • B29C48/9135Cooling of flat articles, e.g. using specially adapted supporting means
    • B29C48/914Cooling of flat articles, e.g. using specially adapted supporting means cooling drums
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • B29C48/9135Cooling of flat articles, e.g. using specially adapted supporting means
    • B29C48/915Cooling of flat articles, e.g. using specially adapted supporting means with means for improving the adhesion to the supporting means
    • B29C48/9155Pressure rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2793/00Shaping techniques involving a cutting or machining operation
    • B29C2793/009Shaping techniques involving a cutting or machining operation after shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0019Combinations of extrusion moulding with other shaping operations combined with shaping by flattening, folding or bending
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0022Combinations of extrusion moulding with other shaping operations combined with cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/297Feeding the extrusion material to the extruder at several locations, e.g. using several hoppers or using a separate additive feeding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/375Plasticisers, homogenisers or feeders comprising two or more stages
    • B29C48/387Plasticisers, homogenisers or feeders comprising two or more stages using a screw extruder and a gear pump
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • B29L2007/008Wide strips, e.g. films, webs

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for production of a thickness-biased resin sheet excellent in appearance. <P>SOLUTION: The method for production of a thickness-biased resin sheet includes: an extrusion process 112 for extruding a molten resin from a die 12 in a sheet-like form; a sheet-molding process 114 for molding a resin sheet 14 by holding the extruded molten resin sheet 14a between a die roller 16 and a nip roller 18, transferring the surface processed form of the die roller 16 to the molten resin sheet 14a, and cooling and solidifying; a peeling process 115 for peeling the resin sheet 14 from a peeling roller 20; and a conveying process 117 for conveying the resin sheet 14 while drawing by a drawing roller 24. In such processes, when the maximum value of a clearance between the nip roller 18 and the die roller 16 is defined as a [mm], and that of the clearance between the die roller 16 and the peeling roller 20 as b [mm], a and b satisfy a≤b≤a+0.3. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、偏肉樹脂シートの製造方法に係り、特に、各種表示装置の背面に配される導光版や各種光学素子に使用するのに好適な偏肉樹脂シートの製造方法に関する。   The present invention relates to a method for manufacturing an uneven thickness resin sheet, and more particularly to a method for manufacturing an uneven thickness resin sheet suitable for use in a light guide plate and various optical elements disposed on the back surface of various display devices.

一般に、樹脂シートの押出成形においては、Tダイから押し出された溶融樹脂シートは冷却ローラにより冷却され、その後、引取ローラにより引き取られながら搬送部での空冷により冷却・固化し、切断機で幅方向に切断されてシート状に成形される。   In general, in the extrusion molding of a resin sheet, the molten resin sheet extruded from the T-die is cooled by a cooling roller, and then cooled and solidified by air cooling in a conveying portion while being taken up by a take-up roller, and then in a width direction by a cutting machine. And is formed into a sheet shape.

成形されるシートの形状が平板である場合には、反りや厚みムラがなく外観に優れるシートを成形するために、冷却ローラの本数や配列、大きさ、温度、ローラ間のクリアランスなどが樹脂材料や樹脂シートの厚みによって適宜調整されている。   When the shape of the sheet to be molded is a flat plate, the number and arrangement of cooling rollers, size, temperature, clearance between the rollers, etc. are resin materials in order to form a sheet with excellent warp and uneven thickness and excellent appearance. It is adjusted as appropriate according to the thickness of the resin sheet.

例えば、下記の特許文献1には、3本の冷却ローラで構成される樹脂シートの押出成形において、最初に接触する1対のローラで加圧・挟持されて所定の厚みとし、その後さらに樹脂シート温度を最適化して1対のローラで加圧・挟持することで、外観に優れる樹脂シートを得る方法が開示されている。また、下記の特許文献2、3には、最初に溶融樹脂シートが接触する1対のローラのみで樹脂シートを加圧・挟持し、最後に接触する冷却ローラでは加圧せずに、外観に優れる樹脂シートを得る方法が記載されている。
特開平10−100230号公報 特公平2−61899号公報 特開平8−25458号公報
For example, in the following Patent Document 1, in the extrusion molding of a resin sheet composed of three cooling rollers, a predetermined thickness is obtained by pressing and sandwiching with a pair of rollers that first contact each other, and then further resin sheet There is disclosed a method for obtaining a resin sheet having an excellent appearance by optimizing the temperature and pressing and clamping with a pair of rollers. In Patent Documents 2 and 3 below, the resin sheet is pressed and sandwiched by only a pair of rollers that first contact the molten resin sheet, and the cooling roller that contacts last does not pressurize, A method for obtaining an excellent resin sheet is described.
Japanese Patent Laid-Open No. 10-100230 Japanese Examined Patent Publication No. 2-61899 JP-A-8-25458

しかしながら、特許文献1〜3に記載されている製造方法は、平板状の樹脂シートの押出成形に関するものであり、幅方向に厚みを有する偏肉樹脂シートを製造する方法については記載されていなかった。偏肉樹脂シートの製造は、ニップローラ、型ローラ、剥離ローラの3本の冷却ローラで構成されるが、型ローラと剥離ローラで樹脂シートの加圧・挟持を行うと、偏肉樹脂シートは幅方向に厚み分布を有しており、樹脂シートの温度が厚肉部が高温であり、薄肉部が低温となるため、この境界でスジが発生するという問題があった。逆に、型ローラと剥離ローラのクリアランスを広げすぎると樹脂シートと剥離ローラの隙間に空気を巻き込んでしまうため、外観不良が発生するという問題があった。   However, the production methods described in Patent Documents 1 to 3 relate to extrusion molding of a flat resin sheet, and have not been described about a method of producing an uneven resin sheet having a thickness in the width direction. . The manufacture of the uneven thickness resin sheet is made up of three cooling rollers, a nip roller, a mold roller, and a peeling roller. If the resin sheet is pressed and sandwiched between the mold roller and the release roller, the uneven thickness resin sheet has a width. The resin sheet has a thickness distribution in the direction, and the temperature of the resin sheet is high in the thick part and low in the thin part, so that there is a problem that streaks occur at this boundary. On the contrary, if the clearance between the mold roller and the peeling roller is excessively widened, air is caught in the gap between the resin sheet and the peeling roller, which causes a problem of appearance failure.

本発明はこのような事情に鑑みてなされたものであり、外観に優れる偏肉樹脂シートの製造方法を提供することを目的とする。   This invention is made | formed in view of such a situation, and it aims at providing the manufacturing method of the uneven thickness resin sheet which is excellent in an external appearance.

本発明の請求項1は前記目的を達成するために、溶融した樹脂をダイからシート状に押し出す押出工程と、押し出した溶融樹脂シートを型ローラとニップローラで挟み、該型ローラの表面の加工形状を該溶融樹脂シートに転写し、冷却固化することにより樹脂シートを成形するシート成形工程と、前記樹脂シートを剥離ローラから剥離する剥離工程と、前記樹脂シートを引取ローラで引っ張り搬送する搬送工程と、を有し、前記樹脂シートの幅方向における前記ニップローラと型ローラのクリアランスの最大値をa[mm]、該型ローラと前記剥離ローラのクリアランスの最大値をb[mm]としたとき、aとbがa≦b≦a+0.3を満たすことを特徴とする偏肉樹脂シートの製造方法を提供する。   In order to achieve the above object, claim 1 of the present invention is an extrusion process for extruding molten resin from a die into a sheet, and sandwiching the extruded molten resin sheet between a mold roller and a nip roller, and the processed shape of the surface of the mold roller A sheet forming step of forming a resin sheet by transferring the resin sheet to the molten resin sheet, and cooling and solidifying; a peeling step of peeling the resin sheet from a peeling roller; and a transporting step of pulling and transporting the resin sheet by a take-up roller; When the maximum value of the clearance between the nip roller and the mold roller in the width direction of the resin sheet is a [mm], and the maximum value of the clearance between the mold roller and the peeling roller is b [mm], And b satisfy a ≦ b ≦ a + 0.3, and a method for producing an uneven thickness resin sheet is provided.

請求項1によれば、型ローラと剥離ローラのクリアランスbの下限をニップローラと型ローラのクリアランスa以上としたため、型ローラと剥離ローラで樹脂シートが加圧されることがない。また、上限を(a+0.3)以下とニップローラと型ローラにより形成された樹脂シートの膜厚aより0.3mm広くしただけであるため、空気を巻き込むことがないので、外観不良の抑制された良好な偏肉樹脂シートを製造することができる。   According to the first aspect, since the lower limit of the clearance b between the mold roller and the peeling roller is equal to or larger than the clearance a between the nip roller and the mold roller, the resin sheet is not pressed by the mold roller and the peeling roller. Further, since the upper limit is only (a + 0.3) or less and 0.3 mm wider than the film thickness a of the resin sheet formed by the nip roller and the mold roller, air is not entrained, so that appearance defects are suppressed. A good uneven thickness resin sheet can be produced.

なお、本発明は、形成される偏肉樹脂シートの反転型が型ローラに形成されているため、型ローラとニップローラおよび剥離ローラのクリアランスが幅方向において異なってくる。そのため、本発明においては、幅方向における型ローラとニップローラのクリアランスの最大値をa、型ローラと剥離ローラのクリアランスをbとしている。   In the present invention, since the inverted mold of the uneven thickness resin sheet to be formed is formed on the mold roller, the clearance between the mold roller, the nip roller, and the peeling roller is different in the width direction. Therefore, in the present invention, the maximum clearance between the mold roller and the nip roller in the width direction is a, and the clearance between the mold roller and the peeling roller is b.

請求項2は請求項1において、前記樹脂シートの幅方向における厚み分布の、最厚部と最薄部の厚みの差が0.5mm以上5mm以下であることを特徴とする。   A second aspect is characterized in that, in the first aspect, the difference in thickness between the thickest portion and the thinnest portion of the thickness distribution in the width direction of the resin sheet is 0.5 mm or more and 5 mm or less.

請求項2によれば、樹脂シートの幅方向における厚み分布の最厚部と最薄部の厚みの差が0.5mm以上5mm以下とすることにより、型ローラとニップローラの間を好ましいクリアランスで樹脂シート全体を搬送することができる。   According to claim 2, the difference in thickness between the thickest part and the thinnest part of the thickness distribution in the width direction of the resin sheet is 0.5 mm or more and 5 mm or less, so that the resin between the mold roller and the nip roller has a preferable clearance. The entire sheet can be conveyed.

請求項3は請求項1または2において、前記樹脂シートの幅方向における厚み分布が200mm以上のピッチの周期性を有することを特徴とする。   A third aspect is characterized in that, in the first or second aspect, the thickness distribution in the width direction of the resin sheet has a periodicity of a pitch of 200 mm or more.

本発明によれば、幅方向における型ローラとニップローラのクリアランスの最大値を上記範囲とすることにより、樹脂シートの幅方向における厚み分布が200mm以上のピッチの周期性を有する樹脂シートに対しても好適に用いることができる。   According to the present invention, by setting the maximum clearance between the mold roller and the nip roller in the width direction within the above range, the thickness distribution in the width direction of the resin sheet can be applied to a resin sheet having a periodicity with a pitch of 200 mm or more. It can be used suitably.

本発明の偏肉樹脂シートの製造方法によれば、面状不良の発生が抑制された外観に優れた偏肉樹脂シートを製造することができる。   According to the manufacturing method of the uneven thickness resin sheet of this invention, the uneven thickness resin sheet excellent in the external appearance by which generation | occurrence | production of planar defect was suppressed can be manufactured.

以下、添付図面に従って、本発明に係る偏肉樹脂シートの製造方法の好ましい実施の形態について説明する。   Hereinafter, preferred embodiments of a method for producing an uneven thickness resin sheet according to the present invention will be described with reference to the accompanying drawings.

図1は、本発明に係る樹脂シートの製造方法の全体工程図であり、図2は各工程における装置構成を示す概念図である。   FIG. 1 is an overall process diagram of a method for producing a resin sheet according to the present invention, and FIG. 2 is a conceptual diagram showing an apparatus configuration in each process.

図1に示すように、本発明の樹脂シートの製造方法は、主として、原料の計量や混合を行う原料工程100、溶融した樹脂を連続してシート状(帯状)に押し出す押出工程112と、押し出した溶融樹脂シート14aを成形しながら冷却して固化するシート成形工程114と、樹脂シート14を剥離する剥離工程115と、固化した樹脂シート14を徐冷する徐冷工程116と、樹脂シート14を所定サイズ(長さ・幅)に裁切断する裁断・切断工程124とで構成される。   As shown in FIG. 1, the resin sheet manufacturing method of the present invention mainly includes a raw material process 100 for measuring and mixing raw materials, an extrusion process 112 for continuously extruding molten resin into a sheet (band), and extrusion. The molten resin sheet 14a is cooled and solidified while being molded, a sheet forming step 114, a peeling step 115 for peeling the resin sheet 14, a slow cooling step 116 for gradually cooling the solidified resin sheet 14, and a resin sheet 14 And a cutting / cutting step 124 for cutting to a predetermined size (length / width).

以下、図2を参照に本発明が適用される樹脂シートの製造装置の主要な構成を説明する。   Hereinafter, the main structure of the resin sheet manufacturing apparatus to which the present invention is applied will be described with reference to FIG.

図2に示すように、原料工程100では、原料サイロ128(又は原料タンク)及び添加物サイロ130(又は添加物タンク)から自動計量機132に送られた原料樹脂および添加物が自動計量され混合器134で原料樹脂と添加物が所定比率になるように混合される。   As shown in FIG. 2, in the raw material process 100, the raw resin and additive sent from the raw material silo 128 (or raw material tank) and additive silo 130 (or additive tank) to the automatic weighing machine 132 are automatically measured and mixed. In the vessel 134, the raw material resin and the additive are mixed at a predetermined ratio.

本発明に適用される原料樹脂の樹脂材料としては、熱可塑性樹脂を用いることができ、例えば、ポリメチルメタクリレート樹脂(PMMA)、ポリカーボネート樹脂(PC)、ポリスチレン樹脂(PS)、MS樹脂、AS樹脂、ポリプロピレン樹脂(PP)、ポリエチレン樹脂(PE)、ポリエチレンテレフタレート樹脂(PET)、ポリ塩化ビニル樹脂(PVC)、熱可塑性エラストマー、又はこれらの共重合体、シクロオレフィンポリマーなどが挙げられる。   As the resin material of the raw material resin applied to the present invention, a thermoplastic resin can be used, for example, polymethyl methacrylate resin (PMMA), polycarbonate resin (PC), polystyrene resin (PS), MS resin, AS resin. , Polypropylene resin (PP), polyethylene resin (PE), polyethylene terephthalate resin (PET), polyvinyl chloride resin (PVC), thermoplastic elastomer, or a copolymer thereof, cycloolefin polymer, and the like.

また、これらの熱可塑性樹脂に光拡散粒子を含んでもよく、光拡散粒子としては、例えば、シリコーンやシリカ、炭酸カルシウム、硫酸バリウム、水酸化アルミニウム、酸化チタン、ガラスビーズ、ケイ酸カルシウムなどの無機粒子やポリメチルメタクリレート粒子などが挙げられる。散乱粒子を添加する場合、最初に、原料樹脂に散乱粒子を所定濃度よりも高濃度に添加されたマスターペレットが造粒機で製造される。次いで、マスターバッチ方式を好適に採用することで、散乱粒子を所定濃度よりも高濃度に添加されたマスターペレットと散乱粒子が添加されていないベースペレットとが混合器134で所定比率混合される。散乱粒子以外の添加物を添加する場合も同様である。   Further, these thermoplastic resins may contain light diffusing particles. Examples of the light diffusing particles include inorganic materials such as silicone, silica, calcium carbonate, barium sulfate, aluminum hydroxide, titanium oxide, glass beads, and calcium silicate. Examples thereof include particles and polymethyl methacrylate particles. When adding scattering particles, first, master pellets in which scattering particles are added to a raw material resin at a concentration higher than a predetermined concentration are manufactured by a granulator. Next, by suitably adopting the master batch method, the master pellets to which the scattering particles are added at a higher concentration than the predetermined concentration and the base pellets to which the scattering particles are not added are mixed at a predetermined ratio by the mixer 134. The same applies when additives other than the scattering particles are added.

原料工程100で適切に計量・混合された原料樹脂は押出工程112に送られる。   The raw resin appropriately weighed and mixed in the raw material process 100 is sent to the extrusion process 112.

押出工程112では、混合器134で混合された原料樹脂がホッパー136を介して押出機138に投入される。原料樹脂が押出機138により混練りされながら溶融される。押出機138は単軸式押出機及び多軸式押出機の何れでもよく、押出機138の内部を真空にするベント機能を含むものが好ましい。押出機138で溶融された原料樹脂は、スクリューポンプ又はギアポンプなどの定量ポンプ140により供給管142を介してダイ12(例えばTダイ)に送られる。ダイ12からシート状に押し出された溶融樹脂シート14aは次にシート成形工程114に送られる。   In the extrusion step 112, the raw material resin mixed in the mixer 134 is charged into the extruder 138 through the hopper 136. The raw material resin is melted while being kneaded by the extruder 138. The extruder 138 may be either a single-screw extruder or a multi-screw extruder, and preferably includes a vent function that evacuates the interior of the extruder 138. The raw material resin melted by the extruder 138 is sent to a die 12 (for example, a T die) through a supply pipe 142 by a metering pump 140 such as a screw pump or a gear pump. The molten resin sheet 14 a extruded from the die 12 into a sheet is then sent to the sheet forming step 114.

シート成形工程114では、ダイ12から押し出された溶融樹脂シート14aが、型ローラ16とニップローラ18とで挟まれる。樹脂シート14が幅方向に厚み分布を持つ形状に成形されながら、冷却・固化される。固化した樹脂シート14は剥離ローラ20で剥離される(剥離工程)。シート成形工程114を経た樹脂シート14は次に徐冷工程116に送られる。   In the sheet forming step 114, the molten resin sheet 14 a extruded from the die 12 is sandwiched between the mold roller 16 and the nip roller 18. The resin sheet 14 is cooled and solidified while being formed into a shape having a thickness distribution in the width direction. The solidified resin sheet 14 is peeled off by the peeling roller 20 (peeling step). The resin sheet 14 that has undergone the sheet forming step 114 is then sent to a slow cooling step 116.

徐冷工程(又はアニーリング工程)116は、剥離ローラ20の下流における樹脂シート14の急激な温度変化を防止するために設けられたものである。樹脂シート14に急激な温度変化が生じた場合、例えば、樹脂シート14の表面近傍が弾性状態になっているにも拘わらず樹脂シート14の内部が塑性状態となり、この部分の硬化による収縮で樹脂シート14の表面形状が悪化するおそれがある。また、樹脂シート14の表裏面に温度差を生じた場合、樹脂シート14に反りが生じ易い。特に、図3(a)のシート断面形状のように幅方向において厚み分布がある樹脂シート14である場合、幅方向での温度分布が大きくなり樹脂シート14に反りが発生しやすくなる。   The slow cooling step (or annealing step) 116 is provided in order to prevent a rapid temperature change of the resin sheet 14 downstream of the peeling roller 20. When a sudden temperature change occurs in the resin sheet 14, for example, the inside of the resin sheet 14 becomes a plastic state despite the fact that the vicinity of the surface of the resin sheet 14 is in an elastic state. The surface shape of the sheet 14 may be deteriorated. Further, when a temperature difference is generated between the front and back surfaces of the resin sheet 14, the resin sheet 14 is likely to warp. In particular, when the resin sheet 14 has a thickness distribution in the width direction as in the sheet cross-sectional shape of FIG. 3A, the temperature distribution in the width direction becomes large and the resin sheet 14 is likely to warp.

徐冷工程116には、入口と出口を有するトンネル状の徐冷ゾーン154(又はアニーリングゾーン)が設けられている。   The slow cooling step 116 is provided with a tunnel-like slow cooling zone 154 (or annealing zone) having an inlet and an outlet.

徐冷ゾーン154の前半部に設ける加熱手段としては、複数のノズルより温度制御されたエア(温風)を樹脂シート14に向けて噴出させる構成、ニクロム線ヒータ、赤外線ヒータ、誘電加熱手段等により、樹脂シート14を加熱する構成等、公知の各種手段を採用することができ、樹脂シートが急冷されるのを防ぐことができる。   The heating means provided in the first half of the slow cooling zone 154 includes a structure in which air (hot air) whose temperature is controlled from a plurality of nozzles is jetted toward the resin sheet 14, a nichrome wire heater, an infrared heater, a dielectric heating means, etc. Various known means such as a structure for heating the resin sheet 14 can be employed, and the resin sheet can be prevented from being rapidly cooled.

また、徐冷ゾーン154の前半部には、樹脂シート14が徐冷搬送される際に、搬送を阻害しないように樹脂シート14に外力を加えて、樹脂シート14を本来の反りのない形状に保持するため、形状保持手段(不図示)を設けることができる。   In addition, when the resin sheet 14 is slowly cooled and conveyed, an external force is applied to the resin sheet 14 in the first half of the slow cooling zone 154 so that the resin sheet 14 is not warped. In order to hold, shape holding means (not shown) can be provided.

徐冷工程116を経た樹脂シート14は、引取ローラ24により樹脂シート14が引っ張られることにより切断工程124に搬送される(搬送工程117)。   The resin sheet 14 that has passed through the slow cooling step 116 is conveyed to the cutting step 124 by the resin sheet 14 being pulled by the take-up roller 24 (conveying step 117).

切断工程124は樹脂シート14を所定長さに切り揃える工程である。また、樹脂シート14の幅方向両端部分(耳部)を切除する工程を有することもできる。切断手段174としては、レーザーカッター、電子ビーム切断、超音波カッターなどを用いることができる。また、受け刃と押し当て刃とからなるギロチンタイプの切断手段を用いることもできる。   The cutting step 124 is a step of cutting the resin sheet 14 to a predetermined length. Moreover, it can also have the process of excising the width direction both ends (ear part) of the resin sheet 14. FIG. As the cutting means 174, a laser cutter, an electron beam cutting, an ultrasonic cutter, or the like can be used. A guillotine-type cutting means composed of a receiving blade and a pressing blade can also be used.

また、樹脂シートに形成された形状が複数の厚肉部を有している場合には、切断工程124において、その形状の継ぎ目で搬送方向に切断する工程も有することができる。   Further, when the shape formed on the resin sheet has a plurality of thick portions, the cutting step 124 can also include a step of cutting in the conveyance direction at the joint of the shape.

また、樹脂シート14は、シート成形工程114で所定の形状に成形されるが、樹脂シート14の両縁部は、その形状において中央部に比較して寸法精度が悪くなる。また、残留歪みも大きくなるので、切断することが好ましい。切断部分は、樹脂シート14の両端部各20〜30mm切断することが好ましい。樹脂シートの両縁部は図2に示すように、樹脂シートを搬送方向と直交する方向に切断する前に切断することもできるし、所定の形状にシートを切断した後、両端部を切断してもよい。   Moreover, although the resin sheet 14 is shape | molded by the predetermined | prescribed shape in the sheet | seat shaping | molding process 114, both edge parts of the resin sheet 14 become worse in dimensional accuracy compared with a center part in the shape. Moreover, since residual distortion also becomes large, it is preferable to cut | disconnect. The cut part is preferably cut at 20 to 30 mm at both ends of the resin sheet 14. As shown in FIG. 2, both edge portions of the resin sheet can be cut before cutting the resin sheet in a direction perpendicular to the conveying direction, or after cutting the sheet into a predetermined shape, both ends are cut. May be.

切断された樹脂シート14の一部は回収ボックス176で回収され、回収された樹脂は廃棄又は再利用される。   A part of the cut resin sheet 14 is collected in a collection box 176, and the collected resin is discarded or reused.

切断された枚葉の樹脂シート14は、ローラ194により駆動されるコンベアベルト196で、次の処理に搬送されると共に、樹脂シート14の幅方向から鼓状の部材192により走行中にズレない様に押さえられている。   The cut sheet resin sheet 14 is conveyed to the next processing by a conveyor belt 196 driven by a roller 194 and is not displaced during traveling by the drum-shaped member 192 from the width direction of the resin sheet 14. Is held down.

次に上記各工程のうち、本発明の特徴をなすシート成形工程114の詳細について図3および図4により説明する。   Next, among the above steps, details of the sheet forming step 114 that characterizes the present invention will be described with reference to FIGS.

樹脂シートの製造ライン10は、押出機138によって溶融された原料樹脂をシート状に賦形するためのダイ12と、表面に偏肉形状が形成された型ローラ16と、型ローラ16に対向配置されるニップローラ18と、型ローラ16に対向配置される剥離ローラ20と、樹脂シート14の温度を制御する加熱装置22と、により構成される。   The resin sheet production line 10 includes a die 12 for shaping the raw material resin melted by the extruder 138 into a sheet shape, a mold roller 16 having an uneven thickness formed on the surface, and a mold roller 16 facing the mold roller 16. The nip roller 18 is formed, the peeling roller 20 is disposed opposite to the mold roller 16, and the heating device 22 that controls the temperature of the resin sheet 14.

ダイ12より押し出したシート状の溶融樹脂シート14aを、型ローラ16と型ローラ16に対向配置されるニップローラ18とで挟圧し、型ローラ16表面の偏肉形状の反転型を樹脂シート14に転写して成形し、樹脂シート14を型ローラ16に対向配置される剥離ローラ20に巻き掛けることにより徐冷し、歪みが除去された状態で、搬送される。   The sheet-like molten resin sheet 14 a extruded from the die 12 is clamped between the mold roller 16 and the nip roller 18 disposed so as to face the mold roller 16, and the uneven-type inverted mold on the surface of the mold roller 16 is transferred to the resin sheet 14. Then, the resin sheet 14 is gradually cooled by being wound around a peeling roller 20 disposed opposite to the mold roller 16, and is conveyed in a state where distortion is removed.

本発明においては、ニップローラと型ローラのクリアランスおよび型ローラと剥離ローラのクリアランスが所定の関係を有するように配置することにより、外観に優れた偏肉樹脂シートを製造することができる。   In the present invention, by arranging the clearance between the nip roller and the mold roller and the clearance between the mold roller and the peeling roller so as to have a predetermined relationship, it is possible to manufacture an uneven-thickness resin sheet excellent in appearance.

図5は製造される偏肉樹脂シートが図3(a)に示される形状である場合の型ローラ16、ニップローラ18、剥離ローラ20のダイ12側から見た断面図である。本発明は偏肉樹脂シートの製造であるため、型ローラには、形成される偏肉樹脂シートの反転型が形成されている。そのため、型ローラは幅方向において、深さが異なってくるため、本発明においては、その最大値のクリアランスにおいて関係式を規定する。   FIG. 5 is a sectional view seen from the die 12 side of the mold roller 16, the nip roller 18, and the peeling roller 20 when the manufactured uneven thickness resin sheet has the shape shown in FIG. Since this invention is manufacture of the uneven thickness resin sheet, the reverse type | mold of the uneven thickness resin sheet formed is formed in the type | mold roller. Therefore, since the depth of the mold roller varies in the width direction, in the present invention, a relational expression is defined for the maximum clearance.

具体的には、図5に示す型ローラ16の場合、幅方向のローラ中央部において型ローラ16とニップローラ18のクリアランスが最大値となりこれをクリアランスa、同様に型ローラ16と剥離ローラ20のクリアランスは幅方向のローラ中央部において最大値となりこれをクリアランスbとし、a≦b≦a+0.3を満たすようにそれぞれのローラを配置する。上記条件を満たすように、ローラを配置することにより、ニップローラと型ラールのクリアランスにより、偏肉樹脂シートの厚みを決定することができ、その後の型ローラと剥離ローラとで、加圧されずに、かつ、剥離ローラと樹脂シートの間に空気を巻き込むことがないので、外観の良好なフィルムを製造することができる。ニップローラと型ローラのクリアランスの最大値aと、型ローラと剥離ローラのクリアランスの最大値bは、更に、a≦b≦a+0.2の関係を満たすことが好ましい。   Specifically, in the case of the mold roller 16 shown in FIG. 5, the clearance between the mold roller 16 and the nip roller 18 becomes the maximum value at the center of the roller in the width direction, and this is the clearance a, and similarly the clearance between the mold roller 16 and the peeling roller 20. Is the maximum value in the central portion of the roller in the width direction, this is defined as clearance b, and each roller is arranged so as to satisfy a ≦ b ≦ a + 0.3. By arranging the roller so as to satisfy the above conditions, the thickness of the uneven thickness resin sheet can be determined by the clearance between the nip roller and the mold lahr, and the subsequent mold roller and the peeling roller are not pressurized. And since air is not caught between a peeling roller and a resin sheet, a film with a favorable external appearance can be manufactured. It is preferable that the maximum value a of the clearance between the nip roller and the mold roller and the maximum value b of the clearance between the mold roller and the peeling roller further satisfy the relationship of a ≦ b ≦ a + 0.2.

この樹脂シートの製造において、ダイ12の樹脂シート14の押し出し速度は、0.1〜50m/分、好ましくは0.3〜30m/分の値が採用できる。したがって、型ローラ16の周速も略これに一致させる。なお、各ローラの速度ムラは、設定値に対して、1%以内に制御することが好ましい。   In the production of this resin sheet, the extrusion speed of the resin sheet 14 of the die 12 can be 0.1 to 50 m / min, preferably 0.3 to 30 m / min. Accordingly, the peripheral speed of the mold roller 16 is also substantially matched with this. In addition, it is preferable to control the speed unevenness of each roller within 1% with respect to the set value.

ニップローラ18の型ローラ16への押し付け圧は、線圧換算(各ニップローラの弾性変形による面接触を線接触と仮定して換算した値)で、0〜200kN/m(kgf/cm)とすることが好ましく、0〜100kN/m(kgf/cm)とするのがより好ましい。   The pressing pressure of the nip roller 18 against the mold roller 16 should be 0 to 200 kN / m (kgf / cm) in terms of linear pressure (value converted assuming that the surface contact due to elastic deformation of each nip roller is linear contact). Is more preferable, and 0 to 100 kN / m (kgf / cm) is more preferable.

型ローラの周速度は、特に限定されないが、1.0m/min以上5.0m/min以下であることが好ましく、より好ましくは1.2m/min以上2.0m/min以下である。型ローラの周速度を上記範囲とすることにより、型ローラとニップローラでニップする時間、型ローラで冷却・固化する時間を所望の時間に調節することができるので、良好な面状のシートを製造することができる。   Although the peripheral speed of a type | mold roller is not specifically limited, It is preferable that they are 1.0 m / min or more and 5.0 m / min or less, More preferably, they are 1.2 m / min or more and 2.0 m / min or less. By setting the peripheral speed of the mold roller within the above range, the time for nipping between the mold roller and the nip roller and the time for cooling and solidifying with the mold roller can be adjusted to the desired time, so a good sheet is produced. can do.

また、剥離ローラと型ローラの周速度は、剥離ローラの最外径の周速度が型ローラの最外径の周速度よりも大きいことが好ましい。剥離ローラの最外径の周速度を大きくすることにより、型ローラとニップローラで成形される偏肉樹脂シートを剥離ローラで引っ張りながら搬送することができるので、偏肉樹脂シートへの皺の発生を抑制することができる。   Moreover, it is preferable that the circumferential speed of the peeling roller and the mold roller is larger than the circumferential speed of the outermost diameter of the mold roller. By increasing the peripheral speed of the outermost diameter of the peeling roller, the uneven thickness resin sheet formed by the mold roller and the nip roller can be conveyed while being pulled by the peeling roller, so generation of wrinkles on the uneven thickness resin sheet is prevented. Can be suppressed.

剥離ローラ20により型ローラ16から剥離された樹脂シート14は、徐冷ゾーン154で、徐々に冷却される。冷却された樹脂シート14は、樹脂シート14の下側(偏肉樹脂シートの凸部が形成されていない側)から加熱装置22により必要に応じて加熱を行い、樹脂シート14の切断部である端部を柔らかくし、切断手段174で切断した際の切り粉の発生を抑制している。また、樹脂シート14の端部を切断した後も、加熱装置22により、樹脂シート14を加熱することにより、樹脂シート14の搬送方向に切断する場合、搬送方向と直交する方向に切断する場合においても、切り粉の発生を抑制して切断することができる。   The resin sheet 14 peeled from the mold roller 16 by the peeling roller 20 is gradually cooled in the slow cooling zone 154. The cooled resin sheet 14 is heated by the heating device 22 from the lower side of the resin sheet 14 (the side where the uneven resin sheet protrusion is not formed) as necessary, and is a cut portion of the resin sheet 14. The end portion is softened and the generation of chips when cut by the cutting means 174 is suppressed. In addition, even after cutting the end portion of the resin sheet 14, when the resin sheet 14 is heated by the heating device 22 to be cut in the conveyance direction of the resin sheet 14, in the case of being cut in the direction orthogonal to the conveyance direction Can be cut while suppressing the generation of chips.

以下に実施例と比較例を挙げて本発明の特徴を具体的に説明する。なお、以下の実施例の材料、処理内容、処理手順などは、本発明の趣旨を逸脱しない限り適宜変更することができる。したがって、本発明の範囲は以下に示す具体例により限定的に解釈されるべきものではない。   The features of the present invention will be specifically described below with reference to examples and comparative examples. Note that materials, processing contents, processing procedures, and the like in the following embodiments can be changed as appropriate without departing from the spirit of the present invention. Therefore, the scope of the present invention should not be construed as being limited by the specific examples shown below.

[実施例1]
図4に示す装置を用いて偏肉樹脂シートの製造を行った。
[Example 1]
The uneven thickness resin sheet was manufactured using the apparatus shown in FIG.

PMMA(旭化成(株)製、80NH、ガラス転移温度110℃)を、温度255℃に設定したTダイより押し出し、ニップローラ、図5に示すような形状の型ローラ、剥離ローラ、徐冷ゾーンを経てシート状にし、偏肉樹脂シートの両端を切断して、シート幅方向の断面形状が図3(a)のような幅594mm、最薄部2.0mm、最厚部3.8mmの偏肉樹脂シートを得た。   PMMA (manufactured by Asahi Kasei Co., Ltd., 80NH, glass transition temperature 110 ° C.) is extruded from a T die set at a temperature of 255 ° C., passed through a nip roller, a mold roller having a shape as shown in FIG. 5, a peeling roller, and a slow cooling zone. Form a sheet and cut both ends of the uneven thickness resin sheet, and the cross-sectional shape in the sheet width direction is 594 mm wide, the thinnest part 2.0 mm, and the thickest part 3.8 mm as shown in FIG. A sheet was obtained.

シート成形工程において、ニップローラ、型ローラ、剥離ローラの表面温度はそれぞれ70℃、75℃、80℃であり、ニップローラのローラ径はφ350mm、剥離ローラのローラ径はφ500mm、型ローラの厚肉形成部のローラ径はφ345.6mm、薄肉形成部のローラ径はφ349.2mm、樹脂シートと非接触部のローラ径(最外径)はφ350mmとした。   In the sheet forming process, the surface temperatures of the nip roller, the mold roller, and the peeling roller are 70 ° C., 75 ° C., and 80 ° C., respectively, the roller diameter of the nip roller is φ350 mm, the roller diameter of the peeling roller is φ500 mm, and the thick roller forming portion The diameter of the roller was φ345.6 mm, the roller diameter of the thin-walled portion was φ349.2 mm, and the roller diameter (outermost diameter) of the non-contact portion with the resin sheet was φ350 mm.

この時、ニップローラと型ローラのクリアランスは、ローラ中央の最大部で3.90mm、ローラ端部の最小部で1.70mmであり、型ローラと剥離ローラのクリアランスは、ローラ中央の最大部で4.00mm、ローラ端部の最小部で1.80mmとした。ニップローラ、型ローラ、剥離ローラの周速度(最外径)はそれぞれ1.205m/min、1.209m/min、1.230m/minとした。ニップローラ、型ローラ、剥離ローラは硬質クロムメッキ処理を施した。   At this time, the clearance between the nip roller and the mold roller is 3.90 mm at the maximum portion at the center of the roller and 1.70 mm at the minimum portion at the end of the roller, and the clearance between the mold roller and the peeling roller is 4 at the maximum portion at the center of the roller. 0.000 mm, and 1.80 mm at the minimum end of the roller. The peripheral speeds (outermost diameters) of the nip roller, the mold roller, and the peeling roller were 1.205 m / min, 1.209 m / min, and 1.230 m / min, respectively. The nip roller, mold roller, and peeling roller were subjected to hard chrome plating.

偏肉樹脂シートの製造は、図4に示すように、型ローラおよび剥離ローラと接触している面と反対側のシート面を、シート表面から50mm離れた位置に遠赤外線セラミックヒータを表面温度500℃に設定して設置し、シートの両端からそれぞれ150mmの範囲を、型ローラと接触中に20秒間、剥離ローラと接触中に15秒間加熱した。   As shown in FIG. 4, the uneven thickness resin sheet is manufactured by placing a far-infrared ceramic heater at a surface temperature of 500 mm at a position 50 mm away from the surface of the sheet opposite to the surface in contact with the mold roller and the peeling roller. The temperature was set at a temperature of 150 ° C., and each 150 mm range from the both ends of the sheet was heated for 20 seconds during contact with the mold roller and for 15 seconds during contact with the peeling roller.

剥離ローラから200mmの位置で、超音波カッターを設置し、樹脂シート両端の厚み2.0mmの部分を切断し、偏肉樹脂シートを製造した。   An ultrasonic cutter was installed at a position 200 mm from the peeling roller, and the 2.0 mm thick portions at both ends of the resin sheet were cut to produce an uneven thickness resin sheet.

上記のクリアランスの時、外観が良好なシートを得ることができた。   At the time of the above clearance, a sheet having a good appearance could be obtained.

[実施例2]
実施例1の条件で、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を3.90mmとしたところ、外観が良好なシートを得ることができた。
[Example 2]
Under the conditions of Example 1, when the maximum clearance between the nip roller and the mold roller (roller center) was 3.90 mm and the maximum clearance between the mold roller and the peeling roller (roller center) was 3.90 mm, a sheet having a good appearance was obtained. I was able to.

[実施例3]
実施例1の条件で、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を4.10mmとしたところ、外観が良好なシートを得ることができた。
[Example 3]
Under the conditions of Example 1, when the maximum clearance between the nip roller and the mold roller (roller center) is 3.90 mm and the maximum clearance between the mold roller and the peeling roller (roller center) is 4.10 mm, a sheet having a good appearance is obtained. I was able to.

[実施例4]
実施例1の条件で、ニップローラ、型ローラ、剥離ローラの周速度(最外径)をそれぞれ0.753m/min、0.755m/min、0.765m/minとし、ニップローラ、型ローラ、剥離ローラの表面温度はそれぞれ70℃、90℃、95℃とし、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を3.94mmとし、図4に示すように型ローラおよび剥離ローラと接触している面と反対側のシート面を、シート表面から50mm離れた位置に遠赤外線セラミックヒータを表面温度350℃に設定して設置し、シートの両端からそれぞれ150mmの範囲を型ローラと接触中に30秒間、剥離ローラと接触中に25秒間加熱した。
[Example 4]
Under the conditions of Example 1, the peripheral speeds (outermost diameters) of the nip roller, the mold roller, and the peeling roller were 0.753 m / min, 0.755 m / min, and 0.765 m / min, respectively. The surface temperature of each roller is 70 ° C., 90 ° C., and 95 ° C., the maximum clearance between the nip roller and the mold roller (roller center) is 3.90 mm, and the maximum clearance between the mold roller and the peeling roller (roller center) is 3.94 mm. As shown in FIG. 4, the far-infrared ceramic heater is set at a surface temperature of 350 ° C. at a position 50 mm away from the surface of the sheet opposite to the surface in contact with the mold roller and the peeling roller. A range of 150 mm from both ends was heated for 30 seconds during contact with the mold roller and for 25 seconds during contact with the peeling roller.

剥離ローラから200mmの位置で、超音波カッターを設置し、樹脂シート両端の厚み2.0mmの部分を切断し、偏肉樹脂シートを製造した。   An ultrasonic cutter was installed at a position 200 mm from the peeling roller, and the 2.0 mm thick portions at both ends of the resin sheet were cut to produce an uneven thickness resin sheet.

上記のクリアランスの時、外観が良好なシートを得ることができた。   At the time of the above clearance, a sheet having a good appearance could be obtained.

[実施例5]
実施例4の条件で、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を3.90mmとしたところ、外観が良好なシートを得ることができた。
[Example 5]
Under the conditions of Example 4, when the maximum clearance between the nip roller and the mold roller (roller center) was 3.90 mm and the maximum clearance between the mold roller and the peeling roller (roller center) was 3.90 mm, a sheet having a good appearance was obtained. I was able to.

[実施例6]
実施例4の条件で、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を4.10mmとしたところ外観が良好なシートを得ることができた。
[Example 6]
Under the conditions of Example 4, when the maximum clearance between the nip roller and the mold roller (roller center) is 3.90 mm and the maximum clearance between the mold roller and the peeling roller (roller center) is 4.10 mm, a sheet having a good appearance can be obtained. I was able to.

[比較例1]
実施例1の条件で、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を3.85mmとしたところ、ローラ間のニップ圧によりシート両端にスジが発生してしまった。
[Comparative Example 1]
Under the conditions of Example 1, the maximum clearance (roller center) between the nip roller and the mold roller was 3.90 mm, and the maximum clearance between the mold roller and the peeling roller (roller center) was 3.85 mm. Streaks have occurred at both ends.

[比較例2]
実施例1の条件で、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を4.25mmとしたところ、剥離ローラと樹脂シートの隙間に空気の巻き込みが発生し、斑模様の空気の跡が樹脂シートの表面に転写されてしまい面状が悪化した。
[Comparative Example 2]
Under the conditions of Example 1, the maximum clearance between the nip roller and the mold roller (roller center) was 3.90 mm, and the maximum clearance between the mold roller and the release roller (roller center) was 4.25 mm. As a result, air entrainment occurred, and traces of air spots were transferred to the surface of the resin sheet, resulting in deterioration of the surface shape.

[比較例3]
実施例1の条件で、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を4.3mmとしたところ、比較例2よりも剥離ローラと樹脂シートの隙間に空気の巻き込みが発生し、斑模様の空気の跡が樹脂シートの表面に転写されてしまい、面状が悪化した。
[Comparative Example 3]
Under the conditions of Example 1, the maximum clearance (roller center) between the nip roller and the mold roller was 3.90 mm, and the maximum clearance (roller center) between the mold roller and the release roller was 4.3 mm. The air entrained in the gap between the resin sheet and the spotted air marks were transferred to the surface of the resin sheet, and the surface condition deteriorated.

[比較例4]
実施例4の条件で、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を3.85mmとしたところ、ローラ間のニップ圧によりシート両端にスジが発生してしまった。
[Comparative Example 4]
Under the conditions of Example 4, the maximum clearance (center of the roller) between the nip roller and the mold roller was 3.90 mm, and the maximum clearance between the mold roller and the peeling roller (roller center) was 3.85 mm. Streaks have occurred at both ends.

[比較例5]
実施例4の条件で、ニップローラと型ローラの最大クリアランス(ローラ中央)を3.90mm、型ローラと剥離ローラの最大クリアランス(ローラ中央)を4.30mmとしたところ、剥離ローラと樹脂シートの隙間に空気の巻き込みが発生し、斑模様の空気の跡が樹脂シートの表面に転写されてしみ面状が悪化した。
[Comparative Example 5]
Under the conditions of Example 4, the maximum clearance between the nip roller and the mold roller (roller center) was 3.90 mm, and the maximum clearance between the mold roller and the release roller (roller center) was 4.30 mm. Air entrainment occurred, and the traces of air spots were transferred to the surface of the resin sheet, resulting in deterioration of the spot surface.

実施例1−6、比較例1−5の結果を図6に示す。なお、図中の記号は以下の意味を示す。   The results of Example 1-6 and Comparative Example 1-5 are shown in FIG. In addition, the symbol in a figure shows the following meaning.

<スジ>
○・・・スジがなく、良好な外観
×・・・スジのように見える面状不良発生
<斑模様>
○・・・斑模様がなく、良好な外観
△・・・剥離ロールと接する側のシート表面に、シート中央近傍に斑模様が発生
×・・・剥離ロールと接する側のシート表面に、全面的に斑模様が発生
図6に示すように、型ローラと剥離ローラのクリアランスbを、ニップローラと型ローラのクリアランスa以上(a+0.3)以下とした実施例1−6については、良好なシートを製造することができた。クリアランスbがクリアランスaより狭い比較例1、4はスジが発生しており、クリアランスbがクリアランスa+0.3より広い比較例2、3、5は、クリアランスbを広くするにつれ、斑模様の発生が顕著に見られた。
<Streak>
○ ・ ・ ・ No streak and good appearance × ・ ・ ・ Surface defect that looks like a streak
○: No speckled pattern, good appearance Δ: Spotted pattern is generated near the center of the sheet on the surface of the sheet in contact with the peeling roll ×: Entirely on the surface of the sheet in contact with the peeling roll As shown in FIG. 6, in Example 1-6 in which the clearance b between the mold roller and the peeling roller is greater than or equal to the clearance a between the nip roller and the mold roller (a + 0.3), a good sheet is formed. Could be manufactured. In Comparative Examples 1 and 4 where the clearance b is narrower than the clearance a, streaks occur, and in Comparative Examples 2, 3 and 5 where the clearance b is wider than the clearance a + 0.3, as the clearance b is widened, spots appear. It was noticeable.

また、型ローラの周速度は、1.209m/min、0.755m/minのいずれにおいても、良好なシートを得ることができ、型ローラの速度に影響されないことが確認できた。   In addition, it was confirmed that a good sheet could be obtained at a peripheral speed of the mold roller of either 1.209 m / min or 0.755 m / min, and that the speed of the mold roller was not affected.

本発明が適用される偏肉樹脂シートの製造方法のフローを説明する工程図である。It is process drawing explaining the flow of the manufacturing method of the uneven thickness resin sheet to which this invention is applied. 本発明が適用される偏肉樹脂シートの製造装置の概念図である。It is a conceptual diagram of the manufacturing apparatus of the uneven thickness resin sheet to which this invention is applied. 偏肉樹脂シートの形状の一例を示す断面図である。It is sectional drawing which shows an example of the shape of an uneven thickness resin sheet. 偏肉樹脂シートの製造装置のシート成形工程、剥離工程、徐冷工程および切断工程を示す構成図である。It is a block diagram which shows the sheet | seat shaping | molding process, peeling process, slow cooling process, and cutting process of the manufacturing apparatus of an uneven thickness resin sheet. 型ローラの形状の一例を示す断面図である。It is sectional drawing which shows an example of the shape of a type | mold roller. 実施例の結果を示す表図である。It is a table | surface figure which shows the result of an Example.

符号の説明Explanation of symbols

10…製造ライン、12…ダイ、14…樹脂シート、14a…溶融樹脂シート、16…型ローラ、18…ニップローラ、20…剥離ローラ、22…加熱装置、24…引取ローラ、100…原料工程、112…押出工程、114…シート成形工程、115…剥離工程、116…徐冷工程、117…搬送工程、124…切断工程、126…積載工程、128…原料サイロ、130…添加物サイロ、132…自動計量機、134…混合器、136…原料樹脂がホッパー、138…押出機、140…定量ポンプ、142…供給管、154…徐冷ゾーン、174…切断手段、176…回収ボックス、192…鼓状の部材、194…ローラ、196…コンベアベルト   DESCRIPTION OF SYMBOLS 10 ... Production line, 12 ... Die, 14 ... Resin sheet, 14a ... Molten resin sheet, 16 ... Mold roller, 18 ... Nip roller, 20 ... Peeling roller, 22 ... Heating device, 24 ... Take-off roller, 100 ... Raw material process, 112 ... extrusion process, 114 ... sheet forming process, 115 ... peeling process, 116 ... slow cooling process, 117 ... conveying process, 124 ... cutting process, 126 ... loading process, 128 ... raw material silo, 130 ... additive silo, 132 ... automatic Weighing machine, 134 ... mixer, 136 ... raw material hopper, 138 ... extruder, 140 ... metering pump, 142 ... supply pipe, 154 ... slow cooling zone, 174 ... cutting means, 176 ... collection box, 192 ... drum shape 194 ... roller, 196 ... conveyor belt

Claims (3)

溶融した樹脂をダイからシート状に押し出す押出工程と、
押し出した溶融樹脂シートを型ローラとニップローラで挟み、該型ローラの表面の加工形状を該溶融樹脂シートに転写し、冷却固化することにより樹脂シートを成形するシート成形工程と、
前記樹脂シートを剥離ローラから剥離する剥離工程と、
前記樹脂シートを引取ローラで引っ張り搬送する搬送工程と、を有し、
前記樹脂シートの幅方向における前記ニップローラと型ローラのクリアランスの最大値をa[mm]、該型ローラと前記剥離ローラのクリアランスの最大値をb[mm]としたとき、aとbがa≦b≦a+0.3を満たすことを特徴とする偏肉樹脂シートの製造方法。
An extrusion process of extruding the molten resin from the die into a sheet,
A sheet molding step of molding the resin sheet by sandwiching the extruded molten resin sheet between a mold roller and a nip roller, transferring the processed shape of the surface of the mold roller to the molten resin sheet, and cooling and solidifying;
A peeling step of peeling the resin sheet from the peeling roller;
A conveying step of pulling and conveying the resin sheet with a take-off roller,
When the maximum value of the clearance between the nip roller and the mold roller in the width direction of the resin sheet is a [mm] and the maximum value of the clearance between the mold roller and the peeling roller is b [mm], a and b are a ≦ a The manufacturing method of the uneven thickness resin sheet characterized by satisfy | filling b <= a + 0.3.
前記樹脂シートの幅方向における厚み分布の、最厚部と最薄部の厚みの差が0.5mm以上5mm以下であることを特徴とする請求項1に記載の偏肉樹脂シートの製造方法。   The method for producing an uneven thickness resin sheet according to claim 1, wherein a difference in thickness between the thickest part and the thinnest part of the thickness distribution in the width direction of the resin sheet is 0.5 mm or more and 5 mm or less. 前記樹脂シートの幅方向における厚み分布が200mm以上のピッチの周期性を有することを特徴とする請求項1または2に記載の偏肉樹脂シートの製造方法。   The thickness distribution in the width direction of the said resin sheet has the periodicity of the pitch of 200 mm or more, The manufacturing method of the uneven thickness resin sheet of Claim 1 or 2 characterized by the above-mentioned.
JP2008241181A 2008-09-19 2008-09-19 Method for production of thickness-biased resin sheet Abandoned JP2010069781A (en)

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Citations (1)

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JP2006056215A (en) * 2004-08-24 2006-03-02 Fuji Photo Film Co Ltd Resin sheet manufacturing method

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Publication number Priority date Publication date Assignee Title
JP2006056215A (en) * 2004-08-24 2006-03-02 Fuji Photo Film Co Ltd Resin sheet manufacturing method

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