JP2010065139A5 - - Google Patents

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Publication number
JP2010065139A5
JP2010065139A5 JP2008232729A JP2008232729A JP2010065139A5 JP 2010065139 A5 JP2010065139 A5 JP 2010065139A5 JP 2008232729 A JP2008232729 A JP 2008232729A JP 2008232729 A JP2008232729 A JP 2008232729A JP 2010065139 A5 JP2010065139 A5 JP 2010065139A5
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Japan
Prior art keywords
meth
acrylate monomer
mass
parts
polymerization initiator
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JP2008232729A
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Japanese (ja)
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JP2010065139A (en
JP5532284B2 (en
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Priority to JP2008232729A priority Critical patent/JP5532284B2/en
Priority claimed from JP2008232729A external-priority patent/JP5532284B2/en
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Publication of JP2010065139A5 publication Critical patent/JP2010065139A5/ja
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Description

即ち、本発明の第一の要旨は、
重合容器に(メタ)アクリレート系モノマー(A)を供給し、臨界ミセル濃度未満となる条件で重合してシード粒子を製造し、次いで(メタ)アクリレート系モノマー(B)およびアゾ系ラジカル重合開始剤を、(メタ)アクリレート系モノマー(B)100質量部に対しラジカル重合開始剤を0.005〜0.040質量部の割合で供給して重合を行い、さらに、(メタ)アクリレート系モノマー(C)を供給して重合を行うラテックスの製造方法である。
また、本発明は、上記方法により得られるラテックスを噴霧乾燥して粉体を製造する方法、該製造方法で得られた粉体と可塑剤を含むアクリルゾル組成物、可塑剤が下記式(I)で表される前記アクリルゾル組成物である。
(1)
ただし、R1、R2は独立して炭化水素基を表す
また、本発明は、上記アクリルゾル組成物を含むテキスタイルインク、上記アクリルゾル組成物が塗布された物品である。
That is, the first gist of the present invention is:
(Meth) acrylate monomer (A) is supplied to the polymerization vessel and polymerized under conditions that result in a concentration lower than the critical micelle concentration to produce seed particles, and then (meth) acrylate monomer (B) and azo radical polymerization initiator Is carried out by supplying a radical polymerization initiator at a ratio of 0.005 to 0.040 parts by mass with respect to 100 parts by mass of (meth) acrylate monomer (B), and (meth) acrylate monomer (C ) Is a method for producing latex.
The present invention also provides a method for producing a powder by spray drying the latex obtained by the above method, an acrylic sol composition comprising the powder obtained by the production method and a plasticizer, and a plasticizer represented by the following formula (I It is the said acrylic sol composition represented by this.
(1)
However, R1 and R2 independently represent a hydrocarbon group. The present invention is a textile ink containing the acrylic sol composition and an article coated with the acrylic sol composition.

Claims (1)

重合容器に(メタ)アクリレート系モノマー(A)を供給し、臨界ミセル濃度未満となる条件で重合してシード粒子を製造し、次いで(メタ)アクリレート系モノマー(B)およびアゾ系ラジカル重合開始剤を、(メタ)アクリレート系モノマー(B)100質量部に対しラジカル重合開始剤を0.005〜0.040質量部の割合で供給して重合を行い、さらに、(メタ)アクリレート系モノマー(C)を供給して重合を行うラテックスの製造方法。 (Meth) acrylate monomer (A) is supplied to the polymerization vessel and polymerized under conditions that result in a concentration lower than the critical micelle concentration to produce seed particles, and then (meth) acrylate monomer (B) and azo radical polymerization initiator Is carried out by supplying a radical polymerization initiator at a ratio of 0.005 to 0.040 parts by mass with respect to 100 parts by mass of (meth) acrylate monomer (B), and (meth) acrylate monomer (C ) To produce a latex.
JP2008232729A 2008-09-10 2008-09-10 Method for producing latex and acrylic sol composition Active JP5532284B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008232729A JP5532284B2 (en) 2008-09-10 2008-09-10 Method for producing latex and acrylic sol composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2008232729A JP5532284B2 (en) 2008-09-10 2008-09-10 Method for producing latex and acrylic sol composition

Publications (3)

Publication Number Publication Date
JP2010065139A JP2010065139A (en) 2010-03-25
JP2010065139A5 true JP2010065139A5 (en) 2011-10-20
JP5532284B2 JP5532284B2 (en) 2014-06-25

Family

ID=42191000

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2008232729A Active JP5532284B2 (en) 2008-09-10 2008-09-10 Method for producing latex and acrylic sol composition

Country Status (1)

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JP (1) JP5532284B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7231986B2 (en) * 2018-03-20 2023-03-02 三菱ケミカルインフラテック株式会社 Resin composition and cured product thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001098129A (en) * 1999-09-30 2001-04-10 Kobayashi Kk Acrylic resin plastisol composition
JP2004217822A (en) * 2003-01-16 2004-08-05 Mitsubishi Rayon Co Ltd Plastisol, gelatinized material and molded article
JP4480374B2 (en) * 2003-09-10 2010-06-16 株式会社Adeka Acrylic sol composition
JP4247147B2 (en) * 2004-03-26 2009-04-02 積水化成品工業株式会社 Production method of monodisperse resin particles
JP2005320407A (en) * 2004-05-07 2005-11-17 Dainippon Ink & Chem Inc (meth)acrylic resin paste and molded product
JP2006219559A (en) * 2005-02-09 2006-08-24 Mitsubishi Rayon Co Ltd Acrylic polymer fine particle and plastisol composition using the same
CN101589105B (en) * 2007-01-23 2014-08-27 三菱丽阳株式会社 (meth)acrylic polymer particles, process for production thereof, plastisol compositions made by using the particles, and articles made by using the compositions

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