JP2010059150A - Agrochemical composition for paddy - Google Patents
Agrochemical composition for paddy Download PDFInfo
- Publication number
- JP2010059150A JP2010059150A JP2009180973A JP2009180973A JP2010059150A JP 2010059150 A JP2010059150 A JP 2010059150A JP 2009180973 A JP2009180973 A JP 2009180973A JP 2009180973 A JP2009180973 A JP 2009180973A JP 2010059150 A JP2010059150 A JP 2010059150A
- Authority
- JP
- Japan
- Prior art keywords
- water
- composition
- agrochemical
- paddy
- soluble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012872 agrochemical composition Substances 0.000 title claims abstract description 21
- -1 alkylbenzene sulfonate Chemical class 0.000 claims abstract description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000003905 agrochemical Substances 0.000 claims abstract description 24
- 239000000126 substance Substances 0.000 claims abstract description 18
- 150000003839 salts Chemical class 0.000 claims abstract description 12
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 62
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 18
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000000575 pesticide Substances 0.000 claims description 9
- 239000001103 potassium chloride Substances 0.000 claims description 9
- 235000011164 potassium chloride Nutrition 0.000 claims description 9
- 239000010881 fly ash Substances 0.000 claims description 6
- 229920000881 Modified starch Polymers 0.000 claims description 5
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 230000005484 gravity Effects 0.000 claims description 5
- 239000000230 xanthan gum Substances 0.000 claims description 5
- 235000010493 xanthan gum Nutrition 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 229940082509 xanthan gum Drugs 0.000 claims description 5
- 239000004368 Modified starch Substances 0.000 claims description 4
- 235000019426 modified starch Nutrition 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 239000010865 sewage Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 abstract description 25
- 241000196324 Embryophyta Species 0.000 abstract description 14
- 239000004480 active ingredient Substances 0.000 abstract description 13
- 241000195493 Cryptophyta Species 0.000 abstract description 5
- 238000004090 dissolution Methods 0.000 abstract description 2
- 238000003892 spreading Methods 0.000 abstract description 2
- 230000003631 expected effect Effects 0.000 abstract 1
- 238000009472 formulation Methods 0.000 description 22
- 235000002639 sodium chloride Nutrition 0.000 description 16
- 238000002156 mixing Methods 0.000 description 15
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 13
- 239000008187 granular material Substances 0.000 description 13
- 229940068984 polyvinyl alcohol Drugs 0.000 description 11
- 229920002472 Starch Polymers 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 239000008107 starch Substances 0.000 description 9
- 235000019698 starch Nutrition 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 7
- SFHYNDMGZXWXBU-LIMNOBDPSA-N 6-amino-2-[[(e)-(3-formylphenyl)methylideneamino]carbamoylamino]-1,3-dioxobenzo[de]isoquinoline-5,8-disulfonic acid Chemical compound O=C1C(C2=3)=CC(S(O)(=O)=O)=CC=3C(N)=C(S(O)(=O)=O)C=C2C(=O)N1NC(=O)N\N=C\C1=CC=CC(C=O)=C1 SFHYNDMGZXWXBU-LIMNOBDPSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 239000012868 active agrochemical ingredient Substances 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000004375 Dextrin Substances 0.000 description 5
- 229920001353 Dextrin Polymers 0.000 description 5
- 235000019425 dextrin Nutrition 0.000 description 5
- MZHCENGPTKEIGP-RXMQYKEDSA-N (R)-dichlorprop Chemical compound OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-RXMQYKEDSA-N 0.000 description 4
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 240000007594 Oryza sativa Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 241000254158 Lampyridae Species 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 230000002363 herbicidal effect Effects 0.000 description 3
- 229910001562 pearlite Inorganic materials 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- FICWGWVVIRLNRB-UHFFFAOYSA-N Flucetosulfuron Chemical compound COCC(=O)OC(C(C)F)C1=NC=CC=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 FICWGWVVIRLNRB-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- 239000005576 Mecoprop-P Substances 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 235000012255 calcium oxide Nutrition 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 230000007721 medicinal effect Effects 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- ROGDGDPDLIVQFZ-OGFXRTJISA-N (2r)-2-(4-chloro-2-methylphenoxy)propanoic acid;n-methylmethanamine Chemical compound CNC.OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1C ROGDGDPDLIVQFZ-OGFXRTJISA-N 0.000 description 1
- WNTGYJSOUMFZEP-SSDOTTSWSA-N (R)-mecoprop Chemical compound OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-SSDOTTSWSA-N 0.000 description 1
- XUHGTGGPZFJRMF-UHFFFAOYSA-N 1,3-dihydropyrazole-2-carboxylic acid Chemical compound OC(=O)N1CC=CN1 XUHGTGGPZFJRMF-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- DHYXNIKICPUXJI-UHFFFAOYSA-N 1-(2,4-dichlorophenyl)-n-(2,4-difluorophenyl)-5-oxo-n-propan-2-yl-1,2,4-triazole-4-carboxamide Chemical compound C=1C=C(F)C=C(F)C=1N(C(C)C)C(=O)N(C1=O)C=NN1C1=CC=C(Cl)C=C1Cl DHYXNIKICPUXJI-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- KNGWEAQJZJKFLI-UHFFFAOYSA-N 2,2-dimethyl-4h-1,3-benzodioxine-6-carbaldehyde Chemical compound O=CC1=CC=C2OC(C)(C)OCC2=C1 KNGWEAQJZJKFLI-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- 239000002794 2,4-DB Substances 0.000 description 1
- UFBJCMHMOXMLKC-UHFFFAOYSA-N 2,4-dinitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O UFBJCMHMOXMLKC-UHFFFAOYSA-N 0.000 description 1
- BDQWWOHKFDSADC-UHFFFAOYSA-N 2-(2,4-dichloro-3-methylphenoxy)-n-phenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C)OC1=CC=C(Cl)C(C)=C1Cl BDQWWOHKFDSADC-UHFFFAOYSA-N 0.000 description 1
- IUQJDHJVPLLKFL-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetate;dimethylazanium Chemical compound CNC.OC(=O)COC1=CC=C(Cl)C=C1Cl IUQJDHJVPLLKFL-UHFFFAOYSA-N 0.000 description 1
- FDMDZIBZKGXZPT-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetic acid;2-(2-hydroxyethylamino)ethanol Chemical compound OCCNCCO.OC(=O)COC1=CC=C(Cl)C=C1Cl FDMDZIBZKGXZPT-UHFFFAOYSA-N 0.000 description 1
- HXMBBZAHRWCZOX-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetic acid;propan-2-amine Chemical compound CC(C)[NH3+].[O-]C(=O)COC1=CC=C(Cl)C=C1Cl HXMBBZAHRWCZOX-UHFFFAOYSA-N 0.000 description 1
- ROKVVMOXSZIDEG-UHFFFAOYSA-N 2-(3,5,6-trichloropyridin-2-yl)oxyacetate;triethylazanium Chemical compound CCN(CC)CC.OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl ROKVVMOXSZIDEG-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- PKAUICCNAWQPAU-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)acetic acid;n-methylmethanamine Chemical compound CNC.CC1=CC(Cl)=CC=C1OCC(O)=O PKAUICCNAWQPAU-UHFFFAOYSA-N 0.000 description 1
- WNTGYJSOUMFZEP-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-UHFFFAOYSA-N 0.000 description 1
- UWHURBUBIHUHSU-UHFFFAOYSA-N 2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoic acid Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 UWHURBUBIHUHSU-UHFFFAOYSA-N 0.000 description 1
- QZSFJRIWRPJUOH-UHFFFAOYSA-N 2-ethylhexyl 2-(2,4-dichlorophenoxy)acetate Chemical group CCCCC(CC)COC(=O)COC1=CC=C(Cl)C=C1Cl QZSFJRIWRPJUOH-UHFFFAOYSA-N 0.000 description 1
- IDGRPSMONFWWEK-UHFFFAOYSA-N 2-ethylhexyl 2-(4-chloro-2-methylphenoxy)acetate Chemical group CCCCC(CC)COC(=O)COC1=CC=C(Cl)C=C1C IDGRPSMONFWWEK-UHFFFAOYSA-N 0.000 description 1
- LLWADFLAOKUBDR-UHFFFAOYSA-N 2-methyl-4-chlorophenoxybutyric acid Chemical compound CC1=CC(Cl)=CC=C1OCCCC(O)=O LLWADFLAOKUBDR-UHFFFAOYSA-N 0.000 description 1
- GPSGZZSRFJXXBA-UHFFFAOYSA-N 2-methylpropyl 2-(2,4-dichlorophenoxy)acetate Chemical group CC(C)COC(=O)COC1=CC=C(Cl)C=C1Cl GPSGZZSRFJXXBA-UHFFFAOYSA-N 0.000 description 1
- KDFDOINBXBEOLZ-UHFFFAOYSA-N 2-phenylpropan-2-amine Chemical class CC(C)(N)C1=CC=CC=C1 KDFDOINBXBEOLZ-UHFFFAOYSA-N 0.000 description 1
- BCIHMWNOJJYBSJ-UHFFFAOYSA-N 2-pyrimidin-2-yloxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1OC1=NC=CC=N1 BCIHMWNOJJYBSJ-UHFFFAOYSA-N 0.000 description 1
- NGBMMSDIZNGAOK-UHFFFAOYSA-N 2h-triazolo[4,5-d]pyrimidine-5-sulfonamide Chemical class NS(=O)(=O)C1=NC=C2NN=NC2=N1 NGBMMSDIZNGAOK-UHFFFAOYSA-N 0.000 description 1
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 description 1
- NGZWZIAGFHOSDS-UHFFFAOYSA-N 6-methylheptyl 4-amino-3,5,6-trichloropyridine-2-carboxylate Chemical group CC(C)CCCCCOC(=O)C1=NC(Cl)=C(Cl)C(N)=C1Cl NGZWZIAGFHOSDS-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- XKJMBINCVNINCA-UHFFFAOYSA-N Alfalone Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XKJMBINCVNINCA-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
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- 239000004005 microsphere Substances 0.000 description 1
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- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000005332 obsidian Substances 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
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- 239000004814 polyurethane Substances 0.000 description 1
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- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
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- OFCQYQOZASISIU-OGFXRTJISA-M potassium;(2r)-2-(4-chloro-2-methylphenoxy)propanoate Chemical compound [K+].[O-]C(=O)[C@@H](C)OC1=CC=C(Cl)C=C1C OFCQYQOZASISIU-OGFXRTJISA-M 0.000 description 1
- ORHJUFUQMQEFPQ-UHFFFAOYSA-M potassium;2-(4-chloro-2-methylphenoxy)acetate Chemical compound [K+].CC1=CC(Cl)=CC=C1OCC([O-])=O ORHJUFUQMQEFPQ-UHFFFAOYSA-M 0.000 description 1
- WRBJKRRJBCSNLE-UHFFFAOYSA-M potassium;4-(2,4-dichlorophenoxy)butanoate Chemical compound [K+].[O-]C(=O)CCCOC1=CC=C(Cl)C=C1Cl WRBJKRRJBCSNLE-UHFFFAOYSA-M 0.000 description 1
- ZRHANBBTXQZFSP-UHFFFAOYSA-M potassium;4-amino-3,5,6-trichloropyridine-2-carboxylate Chemical compound [K+].NC1=C(Cl)C(Cl)=NC(C([O-])=O)=C1Cl ZRHANBBTXQZFSP-UHFFFAOYSA-M 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- WHOKDONDRZNCBC-UHFFFAOYSA-N propan-2-yl 2-(2,4-dichlorophenoxy)acetate Chemical group CC(C)OC(=O)COC1=CC=C(Cl)C=C1Cl WHOKDONDRZNCBC-UHFFFAOYSA-N 0.000 description 1
- LFULEKSKNZEWOE-UHFFFAOYSA-N propanil Chemical compound CCC(=O)NC1=CC=C(Cl)C(Cl)=C1 LFULEKSKNZEWOE-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- VTRWMTJQBQJKQH-UHFFFAOYSA-N pyributicarb Chemical compound COC1=CC=CC(N(C)C(=S)OC=2C=C(C=CC=2)C(C)(C)C)=N1 VTRWMTJQBQJKQH-UHFFFAOYSA-N 0.000 description 1
- USSIUIGPBLPCDF-KEBDBYFISA-N pyriminobac-methyl Chemical group CO\N=C(/C)C1=CC=CC(OC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OC USSIUIGPBLPCDF-KEBDBYFISA-N 0.000 description 1
- FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 description 1
- ALZOLUNSQWINIR-UHFFFAOYSA-N quinmerac Chemical compound OC(=O)C1=C(Cl)C=CC2=CC(C)=CN=C21 ALZOLUNSQWINIR-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229940032158 sodium silicate Drugs 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- STAPBGVGYWCRTF-UHFFFAOYSA-M sodium;2-(4-chloro-2-methylphenoxy)acetate Chemical compound [Na+].CC1=CC(Cl)=CC=C1OCC([O-])=O STAPBGVGYWCRTF-UHFFFAOYSA-M 0.000 description 1
- DHJHUXNTNSRSEX-UHFFFAOYSA-M sodium;2-(4-chloro-2-methylphenoxy)propanoate Chemical compound [Na+].[O-]C(=O)C(C)OC1=CC=C(Cl)C=C1C DHJHUXNTNSRSEX-UHFFFAOYSA-M 0.000 description 1
- PPKIJAQKBAYNNL-UHFFFAOYSA-M sodium;4-(2,4-dichlorophenoxy)butanoate Chemical compound [Na+].[O-]C(=O)CCCOC1=CC=C(Cl)C=C1Cl PPKIJAQKBAYNNL-UHFFFAOYSA-M 0.000 description 1
- GABUSZPTCJGKGB-UHFFFAOYSA-M sodium;4-(4-chloro-2-methylphenoxy)butanoate Chemical compound [Na+].CC1=CC(Cl)=CC=C1OCCCC([O-])=O GABUSZPTCJGKGB-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000006076 specific stabilizer Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 1
- 229940066528 trichloroacetate Drugs 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
本発明は、水田における様々な雑草を効果的に防除する水田用農薬組成物に関する。 The present invention relates to a paddy field agricultural chemical composition that effectively controls various weeds in paddy fields.
従来、農薬有効成分の効果を高める目的で、水田の水面に浮遊させるタイプの農薬組成物の研究が行われてきている。例えば、特許文献1には無機浮遊性物質の浮遊性を利用した各種農薬組成物を水溶性高分子の袋に入れ、手で水田に投げ込むなどの方法などが提案されている。 Conventionally, for the purpose of enhancing the effects of active ingredients of agricultural chemicals, researches on agricultural chemical compositions of the type suspended on the water surface of paddy fields have been conducted. For example, Patent Document 1 proposes a method in which various agricultural chemical compositions using the floatability of inorganic floatable substances are put in a water-soluble polymer bag and thrown into a paddy field by hand.
水田の雑草が高葉令に生長していた場合や施用する水面に藻が発生していた場合、それらが農薬組成物の拡散の障害となる。一方、農薬有効成分である後記式(I)で表される化合物を施用することにより、高葉令の雑草を含め、効果的に雑草が防除されることが知られているが、従前の水面に浮遊させるタイプの農薬組成物の農薬有効成分を単に式(I)の化合物に置き換えただけでは、水田全体に十分に拡散せず、期待する農薬の効果が得られない場合がある。このようなことから、より一層、拡散が速やかに進行する農薬組成物が求められている。 When paddy field weeds have grown to a high leaf age or when algae have developed on the surface of the water to be applied, they become obstacles to the diffusion of the agrochemical composition. On the other hand, it is known that weeds can be effectively controlled by applying a compound represented by the following formula (I) which is an active ingredient of agricultural chemicals, including high-weed weeds. Simply replacing the pesticide active ingredient of the type of pesticide composition that is suspended in water with the compound of formula (I) does not sufficiently diffuse throughout the paddy field, and the expected pesticide effect may not be obtained. For these reasons, there is a need for an agrochemical composition in which diffusion proceeds more rapidly.
本発明者らは、これらの問題点を解決すべく鋭意検討し、本発明を完成させた。
即ち本発明は、(a)式(I):
The present inventors diligently studied to solve these problems and completed the present invention.
That is, the present invention provides (a) Formula (I):
(式中、Rは水素原子又は−COCH2OCH3である)で表される化合物又はその塩、(b)アルキルベンゼンスルホン酸塩、(c)ポリアクリル酸塩、(d)水溶性担体及び(e)該水溶性担体の水溶速度より遅い水溶速度を有する空気保持性物質を含有する水田用農薬組成物に関する。また、当該組成物を水溶性フィルムで包装した水田用農薬パック剤にも関する。また、本発明は上記水田用農薬組成物或いは当該組成物を水溶性フィルムで包装した水田用農薬パック剤を、湛水下水田に直接施用する方法にも関する。 (Wherein R is a hydrogen atom or —COCH 2 OCH 3 ) or a salt thereof, (b) an alkylbenzene sulfonate, (c) a polyacrylate, (d) a water-soluble carrier and ( e) It relates to an agrochemical composition for paddy fields containing an air-retaining substance having a water solubility rate slower than that of the water-soluble carrier. The present invention also relates to an agrochemical pack for paddy fields in which the composition is packaged with a water-soluble film. The present invention also relates to a method of directly applying the paddy pesticide composition or the paddy pesticide pack agent in which the composition is packaged with a water-soluble film to a flooded sewage paddy field.
本発明により、雑草が高葉令に生長した水田或いは水面に藻が発生している水田であっても、水田全体に農薬有効成分である式(I)の化合物又はその塩が拡散し、優れた薬効を示す。 According to the present invention, even in a paddy field where weeds have grown to a high leaf age or a paddy field where algae is generated on the surface of the water, the compound of the formula (I) or a salt thereof, which is an active ingredient of agricultural chemicals, diffuses throughout the paddy field and is excellent. Show medicinal effects.
式(I)の化合物は、不斉炭素を2個含有するため、エリトロ(erythro)又はトレオ(threo)のような各異性体が存在するが、本発明における式(I)の化合物は、各異性体単独と、異性体混合物の双方を含む。
式(I)の化合物の塩としては、農業上許容されるものであればあらゆるものが含まれるが、例えばナトリウム塩、カリウム塩のようなアルカリ金属塩;マグネシウム塩、カルシウム塩のようなアルカリ土類金属塩;ジメチルアンモニウム塩、トリエチルアンモニウム塩のようなアンモニウム塩;塩酸塩、過塩素酸塩、硫酸塩、硝酸塩のような無機酸塩;酢酸塩、メタンスルホン酸塩のような有機酸塩などが挙げられる。
式(I)の化合物、即ち置換基Rが水素原子である化合物(化合物A1と略す)と、Rが−COCH2OCH3である化合物(化合物A2と略す)は、双方ともに本発明において望ましい効果を奏するが、なかでも、Rが−COCH2OCH3である化合物A2(一般名:フルセトスルフロン;flucetosulfuron)が、本発明においてより望ましい。
式(I)の化合物の農薬組成物中の配合割合は適宜選択できるが、通常、0.01から5.0 wt%、望ましくは0.1から2.0 wt%である。
Since the compound of formula (I) contains two asymmetric carbons, there are isomers such as erythro or threo, but the compound of formula (I) in the present invention It includes both isomers alone and isomer mixtures.
The salt of the compound of the formula (I) includes any agriculturally acceptable salt, for example, alkali metal salts such as sodium salt and potassium salt; alkaline earth such as magnesium salt and calcium salt Metal salts; ammonium salts such as dimethylammonium salt and triethylammonium salt; inorganic acid salts such as hydrochloride, perchlorate, sulfate and nitrate; organic acid salts such as acetate and methanesulfonate, etc. Is mentioned.
The compound of formula (I), that is, the compound in which the substituent R is a hydrogen atom (abbreviated as compound A1) and the compound in which R is —COCH 2 OCH 3 (abbreviated as compound A2) are both desirable effects in the present invention. Among them, compound A2 (generic name: flucetosulfuron) in which R is —COCH 2 OCH 3 is more preferable in the present invention.
The compounding ratio of the compound of formula (I) in the agricultural chemical composition can be appropriately selected, but is usually 0.01 to 5.0 wt%, preferably 0.1 to 2.0 wt%.
本発明で使用するアルキルベンゼンスルホン酸塩におけるアルキル部分としては、直鎖状のものでも、分枝状のものでもよく、例えば、メチル、エチル、プロピル、ブチル、ペンチル、ヘキシル、オクチル、ノニル、デシル、ウンデシル、ドデシルなどの炭素数1から12程度のものが挙げられる。また、アルキルベンゼンスルホン酸の塩としては、ナトリウム塩、カリウム塩、カルシウム塩などが挙げられる。その具体例としては、竹本油脂(株)製の『ニューカルゲンWG−3(商品名)』、第一工業製薬(株)製の『ネオゲンパウダー(商品名)』などが挙げられる。
アルキルベンゼンスルホン酸塩の農薬組成物中の配合割合は適宜選択できるが、通常、0.1から10.0 wt%、望ましくは0.5から6.0 wt%である。
The alkyl moiety in the alkylbenzene sulfonate used in the present invention may be linear or branched. For example, methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, nonyl, decyl, Examples include those having about 1 to 12 carbon atoms such as undecyl and dodecyl. Examples of the salt of alkylbenzene sulfonic acid include sodium salt, potassium salt, calcium salt and the like. Specific examples thereof include “New Calgen WG-3 (trade name)” manufactured by Takemoto Yushi Co., Ltd., “Neogen Powder (trade name)” manufactured by Daiichi Kogyo Seiyaku Co., Ltd., and the like.
The blending ratio of the alkylbenzene sulfonate in the agrochemical composition can be appropriately selected, but is usually 0.1 to 10.0 wt%, preferably 0.5 to 6.0 wt%.
本発明で使用するポリアクリル酸塩の塩としては、例えば、ナトリウム塩、カリウム塩などが挙げられる。その具体例としては、花王(株)製の『アグリゾールG-200(商品名)』、三洋化成工業(株)製の『トキサノンGR-31A(商品名)』、竹本油脂(株)製の『ニューカルゲンTG-33(商品名)』などが挙げられる。
ポリアクリル酸塩の農薬組成物中の配合割合は適宜選択できるが、通常0.1から10.0 wt%、望ましくは0.2から5.0 wt%である。
Examples of the polyacrylate salt used in the present invention include sodium salt and potassium salt. Specific examples include “Agrisol G-200 (trade name)” manufactured by Kao Corporation, “Toxanone GR-31A (trade name)” manufactured by Sanyo Chemical Industries, Ltd., “ New Calgen TG-33 (trade name) ”.
The blending ratio of the polyacrylate in the agrochemical composition can be appropriately selected, but is usually 0.1 to 10.0 wt%, preferably 0.2 to 5.0 wt%.
本発明で使用する水溶性担体としては、例えば、塩化カリウム、塩化ナトリウム、塩化アンモニウム、硫酸アンモニウム、硫酸ナトリウム、硝酸アンモニウム、重炭酸アンモニウム、ホウ酸ナトリウム、炭酸ナトリウム、炭酸カルシウム、尿素、砂糖などが挙げられ、これら1種又は2種以上を混合して使用してもよく、又、これらに限定されるものでもない。これらの中でも、塩化カリウムが望ましい。
水溶性担体の農薬組成物中の配合割合は適宜選択できるが、水溶性担体以外の配合成分の量が所望の配合割合となるよう、最終的に配合量を調整するものとしても利用でき、通常、45.0から99.78 wt%、望ましくは67.0から99.1 wt%である。
Examples of the water-soluble carrier used in the present invention include potassium chloride, sodium chloride, ammonium chloride, ammonium sulfate, sodium sulfate, ammonium nitrate, ammonium bicarbonate, sodium borate, sodium carbonate, calcium carbonate, urea, sugar and the like. These 1 type or 2 types or more may be mixed and used, and is not limited thereto. Of these, potassium chloride is desirable.
The blending ratio of the water-soluble carrier in the agrochemical composition can be selected as appropriate, but it can also be used as a final adjustment of the blending amount so that the amount of the blending component other than the water-soluble carrier becomes the desired blending ratio. 45.0 to 99.78 wt%, preferably 67.0 to 99.1 wt%.
本発明で使用する空気保持性物質としては、水に触れると膨潤する性質を持つものであり、例えば、キサンタンガム、アラビアガム、デキストリン、カルボキシメチルセルロースナトリウム、アルギン酸ナトリウム、ポリビニールアルコール、ケイ酸ナトリウム、ケイ酸カリウム、加工澱粉などが挙げられる。このうち、加工澱粉としては、例えば、エーテル化澱粉、エステル化澱粉、架橋澱粉、グラフト化澱粉、焙焼デキストリン、酵素変性デキストリン、可溶性澱粉、アルファー化澱粉などが挙げられる。空気保持性物質としては、これら1種又は2種以上を混合して使用してもよく、又これらに限定されるものでもない。但し、使用する上記の水溶性担体の水溶速度より遅い水溶速度をもつものを選択して使用しなければならない。本発明の農薬組成物(水溶性フィルムで包装する場合はその内容物)が水田に施用されると、一旦、水中に沈降する。その際、空気保持性物質が水を含んで膨潤或いはコロイド状となり、水溶性担体などの粒子間に存在する微細な空気泡を補足する。それと同時に農薬組成物の水溶性担体は水側に徐々に溶出し、農薬組成物が相対的に軽くなる為、浮上し、拡散する。また、空気保持性物質は農薬組成物を必要に応じて粒剤などへ成型する形態とする場合に結合剤を兼ねることもできる。上記水溶性担体に塩化カリウムを使用する場合、空気保持性物質の中でも、キサンタンガム、カルボキシメチルセルロースナトリウム、加工澱粉などが望ましい。
空気保持性物質の具体例としては、以下のものが挙げられる。
・ローディア日華(株)製の商品名:ロードポール23(キサンタンガム)
・第一工業製薬(株)の商品名:セロゲン703A(カルボキシメチルセルロースナトリウム)
・日澱化学(株)の商品名:アミコール6H(加工澱粉・酵素変性デキストリン)
空気保持性物質の農薬組成物中の配合割合は適宜選択できるが、通常0.01から30 wt%、望ましくは0.1から20 wt%である。
The air-retaining substance used in the present invention has a property of swelling when exposed to water. For example, xanthan gum, gum arabic, dextrin, sodium carboxymethylcellulose, sodium alginate, polyvinyl alcohol, sodium silicate, silica Examples include potassium acid and modified starch. Among these, examples of the processed starch include etherified starch, esterified starch, cross-linked starch, grafted starch, roasted dextrin, enzyme-modified dextrin, soluble starch, and pregelatinized starch. As the air retaining substance, one or a mixture of two or more of these may be used, and the present invention is not limited to these. However, it is necessary to select and use one having a water solubility rate slower than that of the above water-soluble carrier to be used. When the agricultural chemical composition of the present invention (its contents when packaged with a water-soluble film) is applied to paddy fields, it once settles in water. At that time, the air retaining substance becomes swollen or colloidal with water, and supplements fine air bubbles existing between particles such as a water-soluble carrier. At the same time, the water-soluble carrier of the pesticidal composition is gradually eluted to the water side, and the pesticidal composition becomes relatively light so that it floats and diffuses. In addition, the air-retaining substance can also serve as a binder when the agricultural chemical composition is molded into granules or the like as necessary. When potassium chloride is used as the water-soluble carrier, xanthan gum, sodium carboxymethyl cellulose, processed starch, etc. are desirable among air retaining substances.
Specific examples of the air retaining substance include the following.
・ Product name made by Rhodia Nikka Co., Ltd .: Roadpole 23 (Xanthan Gum)
-Product name of Daiichi Kogyo Seiyaku Co., Ltd .: Serogen 703A (Carboxymethylcellulose sodium)
・ Nippon Chemical Co., Ltd. product name: Amicol 6H (modified starch, enzyme-modified dextrin)
The mixing ratio of the air retaining substance in the agricultural chemical composition can be appropriately selected, but is usually 0.01 to 30 wt%, preferably 0.1 to 20 wt%.
本発明では、必要に応じて、水面浮遊性付与剤を使用しても良い。水面浮遊性付与剤は独立した1個または複数個の気室を有する物質である。具体的には、微粉炭を燃焼させた際に発生する石炭灰に含まれるフライアッシュ中空粒子、真珠岩や黒曜石からなるパーライト、シラスよりなる発泡シラス、アルミノシリケート系で焼成してなるフィライト、珪酸ソーダ或いは硼砂(ほうさ)を発泡させたマイクロバルーン、軽石、粒状珪藻土、粒状活性炭、木粉、コルク粉、フェノール樹脂からなるエコスフェアー、ポリウレタンからなるポリウレタンフォーム、ポリアクリロニトリルからなるマイクロスフェアーなどが挙げられる。本発明では、これら1種又は2種以上を混合して使用しても良く、混合する場合の割合も適宜選択できる。これらの中でも、かさ比重が1未満の閉鎖型無機中空体(以下、中空体)である、フライアッシュ中空粒子、パーライト、発泡シラス、フィライト、マイクロバルーンなどが望ましく、中でもフライアッシュ中空粒子が特に望ましい。中空体の平均粒子径は、400μm以下であることが望ましい。
フライアッシュ中空粒子としては、具体的には以下のようなものが挙げられる。
オーストラリア・エンバイロスフィアーズ製の商品名:イースフィアーズSL-150、イースフィアーズSLG、イースフィアーズSL-75、イースフィアーズSL-125、イースフィアーズSL180、イースフィアーズSL-300、イースフィアーズSL-350、イースフィアーズSL-500などが挙げられる。
水面浮遊性付与剤の農薬組成物中の配合割合は適宜選択できるが、通常1.0から50.0 wt%、望ましくは5.0から30.0 wt%である。
In the present invention, a water surface floatability imparting agent may be used as necessary. A water surface floatability imparting agent is a substance having one or more independent air chambers. Specifically, fly ash hollow particles contained in coal ash generated when pulverized coal is burned, pearlite made of pearlite or obsidian, foamed shirasu made of shirasu, phylite baked in aluminosilicate system, silicic acid Micro balloons made of foamed soda or borax, pumice, granular diatomaceous earth, granular activated carbon, wood powder, cork powder, ecosphere made of phenol resin, polyurethane foam made of polyurethane, microsphere made of polyacrylonitrile, etc. Can be mentioned. In the present invention, one or two or more of these may be mixed and used, and the ratio in the case of mixing can be appropriately selected. Among these, fly ash hollow particles, pearlite, expanded shirasu, phyllite, microballoon, etc., which are closed inorganic hollow bodies (hereinafter referred to as hollow bodies) having a bulk specific gravity of less than 1, are desirable, and fly ash hollow particles are particularly desirable. . The average particle size of the hollow body is desirably 400 μm or less.
Specific examples of the fly ash hollow particles include the following.
Product names manufactured by Envirospheres Australia: Spheres SL-150, Spheres SLG, Spheres SL-75, Spheres SL-125, Spheres SL180, Spheres SL-300, Spheres SL-350, Spheres SL-500 and so on.
The blending ratio of the water floatability imparting agent in the agrochemical composition can be appropriately selected, but is usually 1.0 to 50.0 wt%, preferably 5.0 to 30.0 wt%.
本発明では、必要に応じて、農薬有効成分の安定化剤を使用しても良い。例えば農薬有効成分の加水分解が問題となる場合においては、該農薬有効成分と、空気中の水分や農薬組成物中に混入している水分との接触を抑えることにより、農薬有効成分の経時変化(分解)を抑制する乾燥剤がそれに該当する。安定化剤としては、具体的には無水ホウ酸(別名酸化ホウ素、ホウ酸無水物:B2O3)、メタホウ酸(HBO2)、生石灰(CaO)、酸化バリウム(BaO)、ホウ酸(H3BO3)、酸化アルミニウム(Al2O3)、酸化マグネシウム(MgO)、アルミン酸ナトリウム(NaAlO2)、酸化鉄(FeO、α-Fe2O3、γ-Fe2O3、Fe3O4)、シリカゲル、無水塩化カルシウム、水素化カルシウム(CaH2)、水素化アルミニウムリチウム(LiAlH4)、無水硫酸ナトリウム、無水硫酸銅、無水硫酸カルシウム、無水硫酸マグネシウム、ゼオライト、無水ケイ酸カルシウム、酸化チタン、二酸化ケイ素、活性炭、アルミン酸ナトリウム、無水クエン酸のような乾燥剤などが挙げられる。安定化剤は、1種又は2種以上を混合して使用してもよい。2種以上混合する場合の割合も適宜選択できる。
安定化剤の農薬組成物中の配合割合は適宜選択できるが、通常0.1から20 wt%、望ましくは0.2から3.0 wt%の範囲である。
In this invention, you may use the stabilizer of an agrochemical active ingredient as needed. For example, when hydrolysis of an agrochemical active ingredient becomes a problem, the temporal change of the agrochemical active ingredient is suppressed by suppressing contact between the agrochemical active ingredient and moisture in the air or in the agrochemical composition. The desiccant which suppresses (decomposition) corresponds to it. Specific stabilizers include boric anhydride (also known as boron oxide, boric anhydride: B 2 O 3 ), metaboric acid (HBO 2 ), quicklime (CaO), barium oxide (BaO), boric acid ( H 3 BO 3 ), aluminum oxide (Al 2 O 3 ), magnesium oxide (MgO), sodium aluminate (NaAlO 2 ), iron oxide (FeO, α-Fe 2 O 3 , γ-Fe 2 O 3 , Fe 3 O 4 ), silica gel, anhydrous calcium chloride, calcium hydride (CaH 2 ), lithium aluminum hydride (LiAlH 4 ), anhydrous sodium sulfate, anhydrous copper sulfate, anhydrous calcium sulfate, anhydrous magnesium sulfate, zeolite, anhydrous calcium silicate, Examples thereof include desiccants such as titanium oxide, silicon dioxide, activated carbon, sodium aluminate, and anhydrous citric acid. You may use a stabilizer 1 type or in mixture of 2 or more types. The ratio in the case of mixing 2 or more types can also be selected as appropriate.
The blending ratio of the stabilizer in the agrochemical composition can be appropriately selected, but is usually in the range of 0.1 to 20 wt%, preferably 0.2 to 3.0 wt%.
本発明では、必要に応じて、上記した成分以外の補助剤も使用することができる。製剤に使用する補助剤としては、カオリナイト、セリサイト、珪藻土、消石灰、タルク、ホワイトカーボン、カオリン、ベントナイト、クレー、重曹、芒硝、ゼオライト、澱粉のような固形担体;水、トルエン、キシレン、ソルベントナフサ、ジオキサン、アセトン、イソホロン、メチルイソブチルケトン、クロロベンゼン、シクロヘキサン、ジメチルスルホキシド、N,N−ジメチルホルムアミド、ジメチルアセトアミド、N−メチル−2−ピロリドン、アルコールのような溶剤;脂肪酸塩、安息香酸塩、ポリカルボン酸塩、アルキル硫酸エステル塩、アルキル硫酸塩、アルキルアリール硫酸塩、アルキルジグリコールエーテル硫酸塩、アルコール硫酸エステル塩、アルキルスルホン酸塩、アルキルナフタレンスルホン酸塩、アリールスルホン酸塩、リグニンスルホン酸塩、アルキルジフェニルエーテルジスルホン酸塩、ポリスチレンスルホン酸塩、アルキルリン酸エステル塩、アルキルアリールリン酸塩、スチリルアリールリン酸塩、ポリオキシエチレンアルキルエーテル硫酸エステル塩、ポリオキシエチレンアルキルアリールエーテル硫酸塩、ポリオキシエチレンアルキルアリールエーテル硫酸エステル塩、ポリオキシエチレンアルキルエーテルリン酸塩、ポリオキシエチレンアルキルアリールリン酸エステル塩、ポリオキシエチレンアリールエーテルリン酸エステル塩、ナフタレンスルホン酸塩ホルマリン縮合物、アルキルベンゼンスルホン酸塩ホルマリン縮合物、アルキルナフタレンスルホン酸塩ホルマリン縮合物のような陰イオン系の界面活性剤;ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、脂肪酸ポリグリセライド、脂肪酸アルコールポリグリコールエーテル、アセチレングリコール、アセチレンアルコール、オキシアルキレンブロックポリマー、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンスチリルアリールエーテル、ポリオキシエチレングリコールアルキルエーテル、ポリエチレングリコール、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリオキシプロピレン脂肪酸エステルのような非イオン系の界面活性剤;オリーブ油、カポック油、ひまし油、シュロ油、椿油、ヤシ油、ごま油、トウモロコシ油、米ぬか油、落花生油、綿実油、大豆油、菜種油、亜麻仁油、きり油、液状パラフィンのような植物油や鉱物油などが挙げられる。これら補助剤の各成分は、本発明の目的から逸脱しないかぎり、1種又は2種以上を適宜選択して使用することができる。 In the present invention, auxiliary agents other than the above-described components can be used as necessary. Adjuvants used in the formulation include solid carriers such as kaolinite, sericite, diatomaceous earth, slaked lime, talc, white carbon, kaolin, bentonite, clay, baking soda, sodium sulfate, zeolite, starch; water, toluene, xylene, solvent Solvents such as naphtha, dioxane, acetone, isophorone, methyl isobutyl ketone, chlorobenzene, cyclohexane, dimethyl sulfoxide, N, N-dimethylformamide, dimethylacetamide, N-methyl-2-pyrrolidone, alcohols; fatty acid salts, benzoates, Polycarboxylate, alkyl sulfate, alkyl sulfate, alkyl aryl sulfate, alkyl diglycol ether sulfate, alcohol sulfate, alkyl sulfonate, alkyl naphthalene sulfonate, aryl sulfo Sulfonate, lignin sulfonate, alkyl diphenyl ether disulfonate, polystyrene sulfonate, alkyl phosphate ester salt, alkyl aryl phosphate, styryl aryl phosphate, polyoxyethylene alkyl ether sulfate ester, polyoxyethylene Alkyl aryl ether sulfates, polyoxyethylene alkyl aryl ether sulfates, polyoxyethylene alkyl ether phosphates, polyoxyethylene alkyl aryl phosphates, polyoxyethylene aryl ether phosphates, naphthalene sulfonate formalin Anionic surfactants such as condensates, alkylbenzenesulfonate formalin condensates, alkylnaphthalenesulfonate formalin condensates; sorbitan fatty acid ester Glycerin fatty acid ester, fatty acid polyglyceride, fatty acid alcohol polyglycol ether, acetylene glycol, acetylene alcohol, oxyalkylene block polymer, polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene styryl aryl ether, polyoxyethylene Nonionic surfactants such as glycol alkyl ether, polyethylene glycol, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxypropylene fatty acid ester; Olive oil, kapok oil, castor oil, palm oil, camellia oil, palm oil, sesame oil, corn , Rice bran oil, peanut oil, cottonseed oil, soybean oil, rapeseed oil, linseed oil, tung oil, vegetable oils and mineral oils such as liquid paraffin. Each component of these adjuvants can be used by appropriately selecting one or two or more types without departing from the object of the present invention.
また、本発明の目的に適合するかぎり、前記した農薬有効成分以外に更に他の除草有効成分を含有することができ、これにより適用草種の範囲、薬剤処理の時期、除草活性等を、より好ましい方向へ改良できる場合がある。当該他の除草有効成分としては、例えば以下のような化合物(一般名:一部ISO申請中を含む、又は開発コード)が例示できるが、特に記載がない場合であってもこれら化合物に塩、アルキルエステル、水和物、異なる結晶形態、各種構造異性体等が存在する場合は、当然それらも含まれる。例えば、2,4−D、2,4−Dブトチル、2,4−Dブチル、2,4−Dジメチルアンモニウム、2,4−Dジオールアミン、2,4−Dエチル、2,4−D−2−エチルヘキシル、2,4−Dイソブチル、2,4−Dイソオクチル、2,4−Dイソプロピル、2,4−Dイソプロピルアンモニウム、2,4−Dナトリウム、2,4−Dイソプロパノールアンモニウム、2,4−Dトロールアミン、2,4−DB、2,4−DBブチル、2,4−DBジメチルアンモニウム、2,4−DBイソオクチル、2,4−DBカリウム、2,4−DBナトリウム、ジクロロプロップ、ジクロロプロップブトチル、ジクロロプロップジメチルアンモニウム、ジクロロプロップイソオクチル、ジクロロプロップカリウム、ジクロロプロップ−P、ジクロロプロップ−Pジメチルアンモニウム、ジクロロプロップ−Pカリウム、ジクロロプロップ−Pナトリウム、MCPA、MCPAブトチル、MCPAジメチルアンモニウム、MCPA−2−エチルヘキシル、MCPAカリウム、MCPAナトリウム、MCPAチオエチル、MCPB、MCPBエチル、MCPBナトリウム、メコプロップ、メコプロップブトチル、メコプロップナトリウム、メコプロップ−P、メコプロップ−Pブトチル、メコプロップ−Pジメチルアンモニウム、メコプロップ−P−2−エチルヘキシル、メコプロップ−Pカリウム、ナプロアニリド、クロメプロップのようなフェノキシ系化合物;ピクロラム、ピクロラムジメチルアンモニウム、ピクロラムイソオクチル、ピクロラムカリウム、ピクロラムトリイソプロパノールアンモニウム、ピクロラムトリイソプロピルアンモニウム、ピクロラムトロールアミン、トリクロピル、トリクロピルブトチル、トリクロピルトリエチルアンモニウムのような芳香族カルボン酸系化合物;リニュロンのような尿素系化合物;シメトリン、プロメトリン、ジメタメトリン、トリアジフラムのようなトリアジン系化合物;プロパニルのようなアニリド系化合物;スエップのようなカーバメート系化合物;ニトロフェン、クロメトキシフェン、ビフェノックス、アシフルオルフェン、アシフルオルフェンナトリウム、オキシフルオルフェン、フルオログリコフェンエチル、フルオログリコフェンのようなジフェニルエーテル系化合物;ピラゾリネート、ピラゾキシフェン、ベンゾフェナップのようなピラゾール系化合物;シハロホップブチル、メタミホッププロピル、メタミホップのようなアリールオキシフェノキシプロピオン酸系化合物;プロホキシジムのようなシクロヘキサンジオン系化合物;ベンスルフロンメチル、ベンスルフロン、メトスルフロンメチル、メトスルフロン、シノスルフロン、ピラゾスルフロンエチル、ピラゾスルフロン、アジムスルフロン、イマゾスルフロン、シクロスルファムロン、ハロスルフロンメチル、ハロスルフロン、エトキシスルフロン、オルソスルファムロン、TH−547のようなスルホニルウレア系化合物;ペノクススラムのようなトリアゾロピリミジンスルホンアミド系化合物;ビスピリバックナトリウム、ピリミノバックメチル、ピリベンゾキシム、ピリフタリド、ピリミスルファンのようなピリミジニルサリチル酸系化合物;オリザリン、ペンディメタリン、ブトラリンのようなジニトロアニリン系化合物;ブタミホス、アニロホス、ピペロホスのような有機リン酸系化合物;ダイムロン、クミルロン、ブロモブチドのようなクミルアミン系化合物;ブタクロール、プレチラクロール、テニルクロールのようなクロロアセトアミド系化合物;モリネート、ジメピペレート、ピリブチカルブ、エスプロカルブ及びチオベンカルブのようなチオカーバメート系化合物;キンクロラック;キンメラック;ピリデート;ベンタゾン;ベンタゾンナトリウム;オキサジアルギル;オキサジアゾン;カルフェントラゾンエチル;ペントキサゾン;ピラクロニル;フルリドン;ジフルフェニカン;メトキシフェノン;クロマゾン;メソトリオン;テフリルトリオン;ベンゾビシクロン;シンメチリン;ジチオピル;エトベンザミド;メフェナセット;フルフェナセット;カフェンストロール;フェントラザミド;オキサジクロメフォン;インダノファン;ベンフレセート;TCAナトリウム;トリクロロ酢酸;HOK−201;キノクラミン:アミノシクロピラクロールなどが使用される。 Moreover, as long as it meets the purpose of the present invention, other herbicidal active ingredients can be further contained in addition to the above-mentioned agrochemical active ingredients, thereby further increasing the range of applicable grass species, the timing of chemical treatment, herbicidal activity, etc. In some cases, it can be improved in a preferred direction. Examples of the other herbicidal active ingredients include the following compounds (generic names: partially including those currently in ISO application or development code), but even if not specifically described, these compounds have salts, If alkyl esters, hydrates, different crystal forms, various structural isomers, etc. are present, they are naturally included. For example, 2,4-D, 2,4-D butyl, 2,4-D butyl, 2,4-D dimethylammonium, 2,4-D diolamine, 2,4-D ethyl, 2,4-D 2-ethylhexyl, 2,4-D isobutyl, 2,4-D isooctyl, 2,4-D isopropyl, 2,4-D isopropyl ammonium, 2,4-D sodium, 2,4-D isopropanol ammonium, 2 , 4-Dtrolamine, 2,4-DB, 2,4-DBbutyl, 2,4-DBdimethylammonium, 2,4-DBisooctyl, 2,4-DB potassium, 2,4-DB sodium, dichloro Prop, dichloropropbutyl, dichloropropdimethylammonium, dichloropropisooctyl, dichloroprop potassium, dichloroprop-P, dichloro Prop-P dimethylammonium, dichloroprop-P potassium, dichloroprop-P sodium, MCPA, MCPA butyl, MCPA dimethylammonium, MCPA-2-ethylhexyl, MCPA potassium, MCPA sodium, MCPA thioethyl, MCPB, MCPB ethyl, MCPB sodium, Phenoxy compounds such as mecoprop, mecoprop butyl, mecoprop sodium, mecoprop-P, mecoprop-P butyl, mecoprop-P dimethylammonium, mecoprop-P-2-ethylhexyl, mecoprop-P potassium, naproanilide, clomeprop; , Picloramdimethylammonium, picloramisooctyl, piclorampotassium, picloramtriisopropa Aromatic carboxylic acid compounds such as chlorammonium, picloramtriisopropylammonium, picloramtrolamine, triclopyr, triclopyrbutyl, triclopyrtriethylammonium; urea compounds such as linuron; simethrin, promethrin, Triazine compounds such as dimetamethrin and triadifram; Anilide compounds such as propanil; Carbamate compounds such as Swep; Nitrophen, Chlomethoxyphen, Biphenox, Acifluorfen, Acifluorfen sodium, Oxyfluorfen, Fluoroglycophene ethyl Diphenyl ether compounds such as fluoroglycophene; pyrazole compounds such as pyrazolinate, pyrazoxifene, benzophenap; Aryloxyphenoxypropionic acid compounds such as lohopbutyl, metamihoppropyl, metamihop; cyclohexanedione compounds such as propoxydim; bensulfuron methyl, bensulfuron, metsulfuron methyl, metsulfuron, synosulfuron, pyrazosulfuron ethyl, pyrazosulfuron Sulfonylurea compounds such as azimusulfuron, imazosulfuron, cyclosulfamuron, halosulfuronmethyl, halosulfuron, ethoxysulfuron, orthosulfamlon, TH-547; triazolopyrimidine sulfonamide compounds such as penoxsulam; Pyrimidinyl salicylic acid such as sodium buckle, pyriminobacmethyl, pyribenzoxime, pyriftalide, pyrimisulfurphan Compounds; Dinitroaniline compounds such as oryzalin, pendimethalin and butralin; Organophosphate compounds such as butamifos, anilophos and piperophos; Cumylamine compounds such as diimron, cumylron and bromobutide; Like butachlor, pretilachlor and tenylchlore Thiochloroacetamide compounds; thiocarbamate compounds such as molinate, dimethylpiperate, pyributicarb, esprocarb, and thiobencarb; quinchlorac; quinmerac; pyrmedate; bentazone; Fluridone; diflufenican; methoxyphenone; chromazone; mesotrione; tefryltrione; Bishikuron; cinmethylin; dithiopyr; Etobenzamido; mefenacet; flufenacet; cafenstrole; fentrazamide; oxadiazole chromate von; indanofan; benfuresate; TCA sodium; trichloroacetate; HOK-201; quinoclamine: an amino cyclo Pila crawl are used.
本発明の農薬組成物は、以下に説明するような方法によって例えば、粒剤とすることができる。(a)式(I)の化合物又はその塩、(b)アルキルベンゼンスルホン酸塩、(c)ポリアクリル酸塩、(d)水溶性担体、(e)該水溶性担体の水溶速度より遅い水溶速度を有する空気保持性物質、その他、必要に応じて、水面浮遊性付与剤、安定化剤、その他の補助剤を混合し、加水混練した後、造粒し、乾燥、整粒し、粒剤とする。造粒する際には、押し出し造粒機、転動造粒機、噴霧造粒機、流動層造粒機等を用いることができる。 The agrochemical composition of the present invention can be made into granules, for example, by a method as described below. (A) a compound of formula (I) or a salt thereof, (b) an alkylbenzene sulfonate, (c) a polyacrylate, (d) a water-soluble carrier, (e) a water-dissolution rate slower than that of the water-soluble carrier. Air-holding substance having other, if necessary, water surface floatation imparting agent, stabilizer, other auxiliary agents are mixed, hydro-kneaded, granulated, dried, granulated, and granulated To do. When granulating, an extrusion granulator, a rolling granulator, a spray granulator, a fluidized bed granulator, or the like can be used.
整粒された個々の粒の粒径は、取り扱いの便宜、組成物の崩壊性を考慮すると一般的には0.1から10 mm、好ましくは0.3から6 mm、さらに好ましくは0.3から2 mmの範囲である。また、粒1個当たり重量は1 g未満である。 The particle size of the individual sized particles is generally in the range of 0.1 to 10 mm, preferably 0.3 to 6 mm, more preferably 0.3 to 2 mm in consideration of disintegration of the composition for convenience of handling. is there. The weight per grain is less than 1 g.
本発明の農薬組成物はそのまま水田に10アール当たり10〜3,000g、好ましくは100〜1,000gの範囲で処理する方法や水溶性フィルムで10〜100gずつ包装してパック剤の形態とし、該パック剤を10アール当たり10〜3,000g、好ましくは100〜1,000gの範囲で水田畦畔から投げ込み施用する方法または水口若しくは給水筒に施用する方法等の簡便な方法で使用することができる。 The pesticide composition of the present invention is processed in a paddy field as it is in the range of 10 to 3,000 g per 10 ares, preferably 100 to 1,000 g, or packaged in the form of 10 to 100 g each with a water-soluble film to form a pack. The agent can be used by a simple method such as a method in which the agent is thrown from the shore of a paddy field within a range of 10 to 3,000 g, preferably 100 to 1,000 g per 10 ares, or a method in which the agent is applied to a water inlet or water pipe.
前記のように本発明の農薬組成物を水溶性フィルムで包装し、パック剤とするときに使用できる水溶性フィルムとしては、水田中に投入したときに、速やかに、例えば数秒〜24時間程度で溶解するものであれば、何れのものでもよい。例えば、ポリビニルアルコール、変性ポリビニルアルコール、水溶性ビニロン、水溶性デキストリン、ポリエチレングリコール、カルボキシメチルセルロース、ヒドロキシエチルセルロース、メチルセルロース、アルギン酸塩、ゼラチン、ペクチン、プルラン、ポリビニルピロリドン、ポリアクリル酸塩、ポリエチレンオキサイド、澱粉などを素材とした高分子フィルム;紙や繊維などに前記水溶性フィルムを塗布又は含浸処理したものなどが挙げられ、これら水溶性フィルムの膜厚は、10から80μm、望ましくは20から60μmが適当である。 As described above, the water-soluble film that can be used when the agricultural chemical composition of the present invention is packaged with a water-soluble film to form a pack agent, is quickly put into a paddy field, for example, about several seconds to 24 hours. Any one that dissolves may be used. For example, polyvinyl alcohol, modified polyvinyl alcohol, water-soluble vinylon, water-soluble dextrin, polyethylene glycol, carboxymethylcellulose, hydroxyethylcellulose, methylcellulose, alginate, gelatin, pectin, pullulan, polyvinylpyrrolidone, polyacrylate, polyethylene oxide, starch, etc. Polymer film made of a material such as paper or fiber coated with or impregnated with the water-soluble film. The film thickness of these water-soluble films is 10 to 80 μm, preferably 20 to 60 μm. is there.
本発明の農薬組成物は、水田に施用された際、一旦水中に沈降した後、徐々に全量が水面上に浮上し、界面活性剤の効力が中心となって農薬有効成分を極めて効果的に水田全域に拡散させることができる。また、本発明の農薬組成物をパック剤として施用すると、施用直後、パック剤は水面上にあるが、直ちに水溶性フィルムが溶解を始め、水溶性フィルムが溶解した部分から内包された農薬組成物が一旦水中に全量沈降する。その後、水溶性担体が溶解するにつれて、空気保持性物質や水面浮遊性付与剤などの働きにより、沈降した農薬組成物は徐々に水面に浮上し、界面活性剤の効力が中心となって農薬有効成分が速やかに拡散することにより、所望の効果を達成することができる。水面浮遊性付与剤が更に配合された場合、水面へ浮上する時間が短縮されることにより、水中より抵抗が少ない水面上を水中より速く拡散する。 When the agricultural chemical composition of the present invention is applied to paddy fields, it once settles in water, and then the whole amount gradually rises on the surface of the water. Can be spread throughout the paddy field. Also, when the agricultural chemical composition of the present invention is applied as a pack agent, immediately after application, the pack agent is on the water surface, but immediately the water-soluble film starts to dissolve, and the water-soluble film is encapsulated from the dissolved portion. Once settles in water. After that, as the water-soluble carrier dissolves, the settled pesticide composition gradually floats on the surface of the water due to the action of air retaining substances and water surface floatation imparting agents. Desired effects can be achieved by the rapid diffusion of the components. When the water surface floatability imparting agent is further blended, the time to float to the water surface is shortened, so that the water surface diffuses faster than the water surface with less resistance than water.
このように、本発明の農薬組成物は、局所散布するだけで、農薬有効成分が局所に滞留することなく水田全体に拡散し、イネに対する薬害を発生することなく有害生物を防除することができ、散布作業が大幅に省力化されたものである。また、浮遊性にすぐれた本発明の農薬組成物は、農薬有効成分が効率良く拡散するため、薬剤の処理地点にその痕跡が残らないという利点も有する。さらに本発明の農薬組成物は、前記したように簡便な方法で製造でき、製造コストも低く抑えられる。前述した種々の特徴、利点を有する本発明の農薬組成物は、極めて実用性の高いものである。 Thus, the agricultural chemical composition of the present invention can spread pesticide active ingredients throughout the paddy field without locally accumulating, and can control pests without causing phytotoxicity to rice, by local application. The spraying work is greatly labor-saving. Moreover, since the agricultural chemical active ingredient diffuses efficiently, the agricultural chemical composition of the present invention having excellent floatability also has an advantage that no trace remains at the treatment point of the drug. Furthermore, the agrochemical composition of the present invention can be produced by a simple method as described above, and the production cost can be kept low. The agrochemical composition of the present invention having the various features and advantages described above is extremely practical.
次に本発明の望ましい態様の一例を記載するが、本発明はこれらに限定されるものではない。
(i)(a)式(I)の化合物又はその塩、(b)アルキルベンゼンスルホン酸塩、(c)ポリアクリル酸塩、(d)水溶性担体、(e)該水溶性担体の水溶速度より遅い水溶速度を有する空気保持性物質及び(f)水面浮遊性付与剤を含有する水田用農薬組成物。
(ii)(a)が、化合物A2(フルセトスルフロン)である、(i)の組成物。
(iii)(d)が、塩化カリウムである、(i)の組成物。
(iv)(e)が、キサンタンガム、カルボキシメチルセルロースナトリウム及び加工澱粉からなる群より選ばれる少なくとも1つである、(i)の組成物。
(v)(f)が、かさ比重1未満の閉鎖型無機中空体である、(i)の組成物。
(vi)かさ比重1未満の閉鎖型無機中空体がフライアッシュ中空粒子である、(v)の組成物。
(vii)(i)の組成物を更に水溶性フィルムで包装した形態である、水田用農薬パック剤。
(viii)水溶性フィルムがポリビニールアルコール製フィルムである、(vii)の組成物。
(ix)(i)の組成物又は(vii)のパック剤を、湛水下水田に直接施用する方法。
Next, although an example of the desirable aspect of the present invention is described, the present invention is not limited to these.
(I) (a) a compound of formula (I) or a salt thereof, (b) an alkylbenzene sulfonate, (c) a polyacrylate, (d) a water-soluble carrier, (e) a water-soluble rate of the water-soluble carrier. An agrochemical composition for paddy fields comprising an air-retaining substance having a slow water-soluble rate and (f) a water surface floatability imparting agent.
(Ii) The composition of (i), wherein (a) is compound A2 (flucetosulfuron).
(Iii) The composition of (i), wherein (d) is potassium chloride.
(Iv) The composition of (i), wherein (e) is at least one selected from the group consisting of xanthan gum, sodium carboxymethylcellulose, and modified starch.
(V) The composition of (i), wherein (f) is a closed inorganic hollow body having a bulk specific gravity of less than 1.
(Vi) The composition according to (v), wherein the closed inorganic hollow body having a bulk specific gravity of less than 1 is fly ash hollow particles.
(Vii) An agrochemical pack for paddy fields, wherein the composition of (i) is further packaged with a water-soluble film.
(Viii) The composition of (vii), wherein the water-soluble film is a polyvinyl alcohol film.
(Ix) A method in which the composition of (i) or the pack agent of (vii) is applied directly to a flooded sewage paddy field.
本発明をより詳しく述べるため、以下に実施例を記載するが、これらは本発明を限定するものではない。
製剤実施例1a
化合物A2 0.44 g、ニューカルゲンWG-3(商品名)3.0 g、アミコール6H(商品名)1.0 g、無水ホウ酸1.0 g及び塩化カリウム92.06 gを混合し、ハンマータイプの粉砕機で粉砕した。そこへロードポール23(商品名)0.5 gを混合した後、セロゲン703A(商品名)の15 wt%水溶液6.7 g(セロゲン703A純分1.0 g)とアグリゾールG-200(商品名)1.0 gとの混合物を加え、更に造粒に適正な水を加えて5から10分間混練した後、孔径1.2 mmのスクリーンを付けたドームグラン型押出し造粒機で造粒し、60から70℃に設定した流動乾燥機にて乾燥した。得られた乾燥品を整粒し(12から24メッシュ:1410μmから710μm)、粒剤を得た。この粒剤の0.24 gをポリビニールアルコール製水溶性フィルム袋(フィルムは厚さ約40μmで縦1.5 cm、横2.0 cmの長方形の袋)に充填し、開口部をヒートシールし、パック剤を得た。
In order to describe the present invention in more detail, examples are described below, but these are not intended to limit the present invention.
Formulation Example 1a
Compound A2 0.44 g, Newkalgen WG-3 (trade name) 3.0 g, Amicol 6H (trade name) 1.0 g, boric anhydride 1.0 g and potassium chloride 92.06 g were mixed and pulverized with a hammer type pulverizer. After mixing 0.5 g of Roadpol 23 (trade name) there, 6.7 g of a 15 wt% aqueous solution of serogen 703A (trade name) (1.0 g of serogen 703A pure) and 1.0 g of Agrisol G-200 (trade name) Add the mixture, knead for 5 to 10 minutes with the appropriate water for granulation, granulate with a dome gran extrusion granulator with a screen with a pore size of 1.2 mm, and set the flow at 60 to 70 ° C It dried with the dryer. The obtained dried product was sized (12 to 24 mesh: 1410 μm to 710 μm) to obtain granules. 0.24 g of this granule is filled into a polyvinyl alcohol water-soluble film bag (film is a rectangular bag with a thickness of about 40 μm and a length of 1.5 cm and a width of 2.0 cm), and the opening is heat-sealed to obtain a pack. It was.
製剤実施例1b
製剤実施例1aで得られた粒剤の50 gをポリビニールアルコール製水溶性フィルム(フィルムは厚さ約40μmで縦10 cm、横8 cmの長方形の袋)に充填し、開口部をヒートシールし、パック剤を得た。
Formulation Example 1b
50 g of the granules obtained in Formulation Example 1a were filled into a water-soluble film made of polyvinyl alcohol (film is about 40 μm thick, rectangular bag 10 cm long and 8 cm wide), and the opening was heat sealed. And a pack was obtained.
製剤実施例2a
上記製剤実施例1aにおいて、塩化カリウムの配合量を、82.06 gとし、ロードポール23(商品名)0.5gと共に、イースフィアーズSL-150(商品名)を10.0 g加えること以外は製剤実施例1aと同様に製剤し、粒剤を得た。この粒剤の0.24 gをポリビニールアルコール製水溶性フィルム袋(フィルムは厚さ約40μmで縦1.5 cm、横2.0 cmの長方形の袋)に充填し、開口部をヒートシールし、パック剤を得た。
Formulation Example 2a
In Formulation Example 1a, the formulation amount of Potassium Chloride was 82.06 g, and with the addition of 0.5 g of Load Pol 23 (trade name) and 10.0 g of Spheres SL-150 (trade name), The same formulation was made to obtain granules. 0.24 g of this granule is filled into a polyvinyl alcohol water-soluble film bag (film is a rectangular bag with a thickness of about 40 μm and a length of 1.5 cm and a width of 2.0 cm), and the opening is heat-sealed to obtain a pack. It was.
製剤実施例2b
製剤実施例2aで得られた粒剤の50 gをポリビニールアルコール製水溶性フィルム袋(フィルムは厚さ約40μmで縦10 cm、横8 cmの長方形の袋)に充填し、開口部をヒートシールし、パック剤を得た。
Formulation Example 2b
50 g of the granules obtained in Formulation Example 2a were filled into a water-soluble film bag made of polyvinyl alcohol (the film is a rectangular bag with a thickness of about 40 μm and a length of 10 cm and a width of 8 cm), and the opening was heated. Sealed to obtain a pack.
製剤実施例3a
上記製剤実施例2aにおいて、塩化カリウムの配合量を72.06 gとし、イースフィアーズSL-150(商品名)の配合量を20.0 gにすること以外は製剤実施例2aと同様に製剤し、粒剤を得た。この粒剤の0.24 gをポリビニールアルコール製水溶性フィルム袋(フィルムは厚さ約40μmで縦1.5 cm、横2.0 cmの長方形の袋)に充填し、開口部をヒートシールし、パック剤を得た。
Formulation Example 3a
In the above Formulation Example 2a, the formulation was the same as Formulation Example 2a except that the blending amount of potassium chloride was 72.06 g, and the blending amount of Spheres SL-150 (trade name) was 20.0 g. Obtained. 0.24 g of this granule is filled into a polyvinyl alcohol water-soluble film bag (film is a rectangular bag with a thickness of about 40 μm and a length of 1.5 cm and a width of 2.0 cm), and the opening is heat-sealed to obtain a pack. It was.
製剤実施例3b
製剤実施例3aで得られた粒剤の50gをポリビニールアルコール製水溶性フィルム袋(フィルムは厚さ約40μmで縦10 cm、横8 cmの長方形の袋)に充填し、開口部をヒートシールし、パック剤を得た。
Formulation Example 3b
50 g of the granules obtained in Formulation Example 3a were filled into a water-soluble film bag made of polyvinyl alcohol (the film is a rectangular bag with a thickness of about 40 μm and a length of 10 cm and a width of 8 cm), and the opening was heat sealed. And a pack was obtained.
製剤比較例
化合物A2 0.44 g、ニューカルゲンEX-70(商品名・竹本油脂(株)製:ジオクチルスルホサクシネート)2.0g、アミコール6H(商品名)1.0 g及び塩化カリウム92.06 gを混合し、ハンマータイプの粉砕機で粉砕した。次にロードポール23(商品名)0.5 gを加え混合した後、造粒に適正な水を加えて5から10分間混練した後、孔径1.2 mmのスクリーンを付けたドームグラン型押出し造粒機で造粒し、60から70℃に設定した流動乾燥機にて乾燥した。得られた乾燥品を整粒し(12から24メッシュ:1410μmから710μm)、粒剤を得た。この粒剤の0.24 gをポリビニールアルコール製水溶性フィルム袋(フィルムは厚さ約40μmで縦 1.5cm、横 2.0cmの長方形の袋)に充填し、開口部をヒートシールし、パック剤を得た。
Formulation Comparative Example Compound A2 0.44 g, New Calgen EX-70 (trade name, manufactured by Takemoto Yushi Co., Ltd .: Dioctylsulfosuccinate) 2.0 g, Amicol 6H (trade name) 1.0 g and potassium chloride 92.06 g were mixed, and a hammer was mixed. It grind | pulverized with the type grinder. Next, after adding and mixing 0.5 g of load pole 23 (trade name), adding appropriate water to the granulation, kneading for 5 to 10 minutes, and then using a dome gran extrusion granulator equipped with a screen with a pore diameter of 1.2 mm. Granulated and dried in a fluid dryer set at 60 to 70 ° C. The obtained dried product was sized (12 to 24 mesh: 1410 μm to 710 μm) to obtain granules. 0.24 g of this granule is filled into a polyvinyl alcohol water-soluble film bag (the film is a rectangular bag with a thickness of about 40 μm and a length of 1.5 cm and a width of 2.0 cm), and the opening is heat sealed to obtain a pack agent. It was.
農薬有効成分の水中拡散性試験
縦0.12 m×横4 mの雨樋に土を詰め、入水し、代掻きをした後、ノビエ、ホタルイの各種子を播種し、水深を3.5 cmに保持した。代掻き1日後にウリカワの塊茎を埋め込み、2葉期のイネ(日本晴)を雨樋の端から40 cmおきに10株(1株あたり2本)移植した。ノビエが2.8-3.1葉期、ホタルイが2.5-3.0葉期、ウリカワが2.3-3.0葉期に達したとき、前記製剤実施例1a、2a又は3aで得られたパック剤を雨樋片端の水面に投下した。処理24時間後に施用地点から1 mおきに離れた地点における水深1.8 cmのところから水を採取し、液体クロマトグラフィーで化合物A2及びその加水分解物である化合物A1の合計濃度を測定した。
製剤比較例のパック剤についても、ノビエ、ホタルイ、ウリカワ及びイネを使用せずに行うこと以外は同様に試験を行い、化合物A1及びA2の合計濃度を測定した。結果を第1表に示す。なお、化合物A1及びA2が水中全体にわたり均一に拡散した場合の理論濃度は施用後の加水分解の程度により異なり、全てA1に加水分解している場合は53 ppb、全てA2の場合は63 ppbである。
また、処理30日後の植物の生育状態を、肉眼で観察調査(生育抑制率(%)0:無処理区並〜100:完全枯殺)し、結果を第2表に示す。
Diffusion test of active ingredients of pesticides in water After filling soil in a rain gutter measuring 0.12 m in length and 4 m in width, watering and pricking, various seeds of Novier and firefly were sown and the water depth was maintained at 3.5 cm. One day after the pricking, Urikawa tubers were embedded, and 2 leaves of rice (Nipponbare) were transplanted every 40 cm from the end of the rain gutter (2 lines per strain). When the nobies reached the 2.8-3.1 leaf stage, the firefly reached the 2.5-3.0 leaf stage, and the urikawa reached the 2.3-3.0 leaf stage, the pack obtained in the formulation example 1a, 2a or 3a was put on the water surface at one end of the rain gutter. Dropped. After 24 hours of treatment, water was collected from a point at a depth of 1.8 cm at a point 1 m away from the application point, and the total concentration of Compound A2 and its hydrolyzate Compound A1 was measured by liquid chromatography.
For the pack preparations of Comparative Formulation Examples, tests were conducted in the same manner except that nobier, firefly, urikawa and rice were not used, and the total concentrations of compounds A1 and A2 were measured. The results are shown in Table 1. The theoretical concentration when the compounds A1 and A2 diffuse uniformly throughout the water depends on the degree of hydrolysis after application, and is 53 ppb when all are hydrolyzed to A1, and 63 ppb when all are A2. is there.
Further, the growth state of the plant 30 days after the treatment was observed and observed with the naked eye (growth inhibition rate (%) 0: untreated area to 100: complete withering), and the results are shown in Table 2.
製剤比較例を施用した雨樋はイネや雑草がなく、雑草がある場合に比べ、拡散し易い条件下である。一方、製剤実施例1a、2a及び3aを施用した雨樋は、高葉令の雑草が存在し、農薬有効成分が拡散しにくい不利な条件下にもかかわらず、製剤比較例に比べ、施用後、短時間で農薬有効成分が遠くまで拡散していることが第1表からわかる。そして、拡散性に優れた製剤実施例1a、2a及び3aは、農薬の効果を広範囲にわたって発揮することが第2表からわかる。 The rain gutter applied with the preparation comparative example is free from rice and weeds and is more easily diffused than when there are weeds. On the other hand, the rain gutters applied with Formulation Examples 1a, 2a and 3a have higher leaf age weeds, and after application, compared to the Formulation Comparative Examples, despite disadvantageous conditions in which the active ingredients of agricultural chemicals are difficult to diffuse. From Table 1, it can be seen that the active ingredients of agricultural chemicals diffused far away in a short time. Table 2 shows that Formulation Examples 1a, 2a and 3a having excellent diffusibility exert the effect of agricultural chemicals over a wide range.
本発明により、雑草が高葉令に生長した水田或いは水面に藻が発生している水田であっても水田全体に農薬有効成分が拡散し、優れた薬効を示す農薬組成物が提供される。 INDUSTRIAL APPLICABILITY According to the present invention, an agrochemical composition having excellent medicinal effects can be provided by spreading an agrochemical active ingredient throughout the paddy field even if the weed has grown to a high leaf age or a paddy field where algae is generated on the water surface.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010059151A (en) * | 2008-08-07 | 2010-03-18 | Ishihara Sangyo Kaisha Ltd | Agrochemical composition for paddy |
JP2014159026A (en) * | 2013-01-22 | 2014-09-04 | Towa Koso Kk | Water purification method in closed water system utilizing microorganism |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05194105A (en) * | 1991-09-25 | 1993-08-03 | Sankyo Co Ltd | Agricultural chemical composition and its application |
JPH06157203A (en) * | 1992-09-17 | 1994-06-03 | Sankyo Co Ltd | Solid agricultural chemical formulation floating on water surface |
JPH06192004A (en) * | 1992-09-28 | 1994-07-12 | Sankyo Co Ltd | Agricultural chemical composition |
JPH09118602A (en) * | 1995-08-18 | 1997-05-06 | Nippon Kayaku Co Ltd | Water surface-floatable agrochemical preparation |
JPH09295903A (en) * | 1996-05-07 | 1997-11-18 | Kumiai Chem Ind Co Ltd | Granular agrochemical composition and its application |
JPH10109905A (en) * | 1996-10-03 | 1998-04-28 | Kumiai Chem Ind Co Ltd | Granular herbicide composition for rice paddies and its scattering method |
JP2001114605A (en) * | 1999-10-19 | 2001-04-24 | Takeda Chem Ind Ltd | Agrochemical solid preparation |
JP2001163705A (en) * | 1999-06-30 | 2001-06-19 | Ishihara Sangyo Kaisha Ltd | Self-diffusing granular agrochemical composition for paddy field and method of its application |
JP2002338403A (en) * | 2001-05-17 | 2002-11-27 | Shionogi & Co Ltd | Agrochemical preparation having water surface-floating property |
WO2006016527A1 (en) * | 2004-08-11 | 2006-02-16 | Kumiai Chemical Industry Co., Ltd. | Agricultural chemical composition |
-
2009
- 2009-08-03 JP JP2009180973A patent/JP5656373B2/en active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05194105A (en) * | 1991-09-25 | 1993-08-03 | Sankyo Co Ltd | Agricultural chemical composition and its application |
JPH06157203A (en) * | 1992-09-17 | 1994-06-03 | Sankyo Co Ltd | Solid agricultural chemical formulation floating on water surface |
JPH06192004A (en) * | 1992-09-28 | 1994-07-12 | Sankyo Co Ltd | Agricultural chemical composition |
JPH09118602A (en) * | 1995-08-18 | 1997-05-06 | Nippon Kayaku Co Ltd | Water surface-floatable agrochemical preparation |
JPH09295903A (en) * | 1996-05-07 | 1997-11-18 | Kumiai Chem Ind Co Ltd | Granular agrochemical composition and its application |
JPH10109905A (en) * | 1996-10-03 | 1998-04-28 | Kumiai Chem Ind Co Ltd | Granular herbicide composition for rice paddies and its scattering method |
JP2001163705A (en) * | 1999-06-30 | 2001-06-19 | Ishihara Sangyo Kaisha Ltd | Self-diffusing granular agrochemical composition for paddy field and method of its application |
JP2001114605A (en) * | 1999-10-19 | 2001-04-24 | Takeda Chem Ind Ltd | Agrochemical solid preparation |
JP2002338403A (en) * | 2001-05-17 | 2002-11-27 | Shionogi & Co Ltd | Agrochemical preparation having water surface-floating property |
WO2006016527A1 (en) * | 2004-08-11 | 2006-02-16 | Kumiai Chemical Industry Co., Ltd. | Agricultural chemical composition |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010059151A (en) * | 2008-08-07 | 2010-03-18 | Ishihara Sangyo Kaisha Ltd | Agrochemical composition for paddy |
JP2014159026A (en) * | 2013-01-22 | 2014-09-04 | Towa Koso Kk | Water purification method in closed water system utilizing microorganism |
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