JP2010039060A5 - - Google Patents

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JP2010039060A5
JP2010039060A5 JP2008199717A JP2008199717A JP2010039060A5 JP 2010039060 A5 JP2010039060 A5 JP 2010039060A5 JP 2008199717 A JP2008199717 A JP 2008199717A JP 2008199717 A JP2008199717 A JP 2008199717A JP 2010039060 A5 JP2010039060 A5 JP 2010039060A5
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meth
colored curable
curable resin
resin composition
acrylate
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JP2010039060A (en
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Description

Figure 2010039060
Figure 2010039060

(式(1)中、R 、及びR 〜R は各々独立して、水素原子又は炭素数1〜3のアルキル基を示し、R及びRは各々独立して、水素原子又は炭素数1〜3のアルキル基を表すか、或いは互いに連結して環を形成する。)
(In formula (1), R 1 and R 3 to R 5 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R 7 and R 8 each independently represent a hydrogen atom or Represents an alkyl group having 1 to 3 carbon atoms, or is linked to each other to form a ring.)

Figure 2010039060
Figure 2010039060

(式(1)中、R 、及びR 〜R は各々独立して、水素原子又は炭素数1〜3のアルキル基を示し、R及びRは各々独立して、水素原子又は炭素数1〜3のアルキル基を
表すか、或いは互いに連結して環を形成する。)
式(1)において、RとRが連結して形成される環は、脂肪族環であるのが好ましく、飽和又は不飽和の何れでもよく、炭素数は5〜6であるのが好ましい。
中でも、一般式(1)で表される構造としては、下記式(1a)、(1b)、又は(1c)で表される構造が好ましい。
(In formula (1), R 1 and R 3 to R 5 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R 7 and R 8 each independently represent a hydrogen atom or Represents an alkyl group having 1 to 3 carbon atoms, or is linked to each other to form a ring.)
In the formula (1), the ring formed by linking R 7 and R 8 is preferably an aliphatic ring, which may be saturated or unsaturated, and preferably has 5 to 6 carbon atoms. .
Especially, as a structure represented by General formula (1), the structure represented by following formula (1a), (1b), or (1c) is preferable.

Claims (15)

少なくとも(A)顔料、(B)分散剤、(C)バインダー樹脂および(D)有機溶剤を含有し、
(B)分散剤が、側鎖にアミノ基を有するB−ブロックと、アミノ基を有さないA−ブロックからなり、アミン価が有効固形分換算で20mgKOH/g以上であるA−Bブロック共重合体および/またはA−B−Aブロック共重合体であり、
(C)バインダー樹脂の、GPCにて測定したポリスチレン換算の重量平均分子量が4,000以上50,000以下であり、かつ酸価が150mgKOH/g以下である樹脂(C1)を含有することを特徴とする、インクジェット法カラーフィルタ用着色硬化性樹脂組成物。
At least (A) a pigment, (B) a dispersant, (C) a binder resin and (D) an organic solvent,
(B) The AB block having a B-block having an amino group in the side chain and an A-block having no amino group and having an amine value of 20 mgKOH / g or more in terms of effective solid content. A polymer and / or an ABA block copolymer,
(C) The binder resin contains a resin (C1) having a polystyrene-equivalent weight average molecular weight measured by GPC of 4,000 or more and 50,000 or less and an acid value of 150 mgKOH / g or less. A colored curable resin composition for an ink jet color filter.
前記(C1)樹脂が、エポキシ基及び/又はカルボキシル基を有する、請求項1記載の着色硬化性樹脂組成物。   The colored curable resin composition according to claim 1, wherein the (C1) resin has an epoxy group and / or a carboxyl group. 前記(C1)樹脂が、(a)下記一般式(1)で表される構造を有するモノ(メタ)アクリレート、および(b)エポキシ基含有(メタ)アクリレートまたは(メタ)アクリル酸、を含むエチレン性不飽和基含有単量体を反応させて得られる(メタ)アクリル系共重合体である、請求項1または2記載の着色硬化性樹脂組成物。
Figure 2010039060
(式(1)中、R 、及びR 〜R は各々独立して、水素原子又は炭素数1〜3のアルキル基を示し、R及びRは各々独立して、水素原子又は炭素数1〜3のアルキル基を表すか、或いは互いに連結して環を形成する。)
The ethylene in which the (C1) resin contains (a) mono (meth) acrylate having a structure represented by the following general formula (1), and (b) epoxy group-containing (meth) acrylate or (meth) acrylic acid The colored curable resin composition according to claim 1 or 2, which is a (meth) acrylic copolymer obtained by reacting a polymerizable unsaturated group-containing monomer.
Figure 2010039060
(In formula (1), R 1 and R 3 to R 5 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R 7 and R 8 each independently represent a hydrogen atom or Represents an alkyl group having 1 to 3 carbon atoms, or is linked to each other to form a ring.)
前記(C1)樹脂が、(a)前記一般式(1)で表される構造を有するモノ(メタ)ア
クリレート、および(b1)エポキシ基含有(メタ)アクリレートを含む、エチレン性不飽和基含有単量体を重合して得られる(メタ)アクリル系共重合体である、請求項3に記載の着色硬化性樹脂組成物。
The (C1) resin contains (a) a mono (meth) acrylate having a structure represented by the general formula (1), and (b1) an epoxy group-containing (meth) acrylate. The colored curable resin composition according to claim 3, which is a (meth) acrylic copolymer obtained by polymerizing a monomer.
前記(C1)樹脂が、(a)前記一般式(1)で表される構造を有するモノ(メタ)アクリレート、および(b1)エポキシ基含有(メタ)アクリレートを含む、エチレン性不飽和基含有単量体を重合して幹樹脂を得、該幹樹脂における(b1)由来のエポキシ基の少なくとも一部に(c)不飽和一塩基酸を反応させ、生じた水酸基の少なくとも一部に(d)多塩基酸またはその無水物、を反応させて得られる(メタ)アクリル系共重合体である、請求項3に記載の着色硬化性樹脂組成物。   The (C1) resin contains (a) a mono (meth) acrylate having a structure represented by the general formula (1), and (b1) an epoxy group-containing (meth) acrylate. Polymers are obtained to obtain a trunk resin, and (c) an unsaturated monobasic acid is reacted with at least part of the epoxy group derived from (b1) in the trunk resin, and (d) at least part of the resulting hydroxyl group. The colored curable resin composition according to claim 3, which is a (meth) acrylic copolymer obtained by reacting a polybasic acid or an anhydride thereof. 前記(C1)樹脂の幹樹脂が、(a)前記一般式(1)で表される構造を有するモノ(メタ)アクリレート、(b1)エポキシ基含有(メタ)アクリレート、および(e1)芳香族炭化水素基を有するエチレン性不飽和単量体を重合してなる、請求項5記載の着色硬化性樹脂組成物。   The backbone resin of the (C1) resin is (a) a mono (meth) acrylate having a structure represented by the general formula (1), (b1) an epoxy group-containing (meth) acrylate, and (e1) aromatic carbonization. The colored curable resin composition according to claim 5, which is obtained by polymerizing an ethylenically unsaturated monomer having a hydrogen group. 前記(C1)樹脂が、(a)前記一般式(1)で表される構造を有するモノ(メタ)アクリレート、および(b2)(メタ)アクリル酸を含む、エチレン性不飽和基含有単量体を反応させて得られる(メタ)アクリル系共重合体である、請求項3に記載の着色硬化性樹脂組成物。   Ethylenically unsaturated group-containing monomer in which the (C1) resin contains (a) mono (meth) acrylate having the structure represented by the general formula (1) and (b2) (meth) acrylic acid The colored curable resin composition of Claim 3 which is a (meth) acrylic-type copolymer obtained by making this react. 前記(C1)樹脂が、(a)前記一般式(1)で表される構造を有するモノ(メタ)アクリレート、(b2)(メタ)アクリル酸、および(e1)芳香族炭化水素基を有するエチレン性不飽和単量体を反応させて得られる(メタ)アクリル系共重合体である、請求項7記載の着色硬化性樹脂組成物。   The (C1) resin is (a) mono (meth) acrylate having the structure represented by the general formula (1), (b2) (meth) acrylic acid, and (e1) ethylene having an aromatic hydrocarbon group. The colored curable resin composition according to claim 7, which is a (meth) acrylic copolymer obtained by reacting a polymerizable unsaturated monomer. (D)有機溶剤が、沸点180℃以上(圧力1013.25[hPa]条件下での沸点)である溶剤を含有することを特徴とする、請求項1ないし8のいずれか一項に記載の着色硬化性樹脂組成物。   The organic solvent (D) contains a solvent having a boiling point of 180 ° C. or higher (boiling point under a pressure of 101.25 [hPa] condition), according to any one of claims 1 to 8. Colored curable resin composition. (D)有機溶剤が、沸点180℃以上(圧力1013.25[hPa]条件下での沸点)である溶剤を50重量%以上含有することを特徴とする、請求項9記載の着色硬化性樹脂組成物。   10. The colored curable resin according to claim 9, wherein the organic solvent contains 50% by weight or more of a solvent having a boiling point of 180 ° C. or higher (boiling point under a pressure of 101.25 [hPa]). Composition. さらに(E)単量体を含有する、請求項1ないし10のいずれか一項に記載の着色硬化性樹脂組成物。   The colored curable resin composition according to any one of claims 1 to 10, further comprising (E) a monomer. さらに(F)重合開始剤を含有する、請求項1ないし11のいずれか一項に記載の着色硬化性樹脂組成物。   The colored curable resin composition according to any one of claims 1 to 11, further comprising (F) a polymerization initiator. 請求項1ないし12のいずれか一項に記載の着色硬化性樹脂組成物を用いて形成された画素を有するカラーフィルタ。   The color filter which has a pixel formed using the colored curable resin composition as described in any one of Claims 1 thru | or 12. 請求項13に記載のカラーフィルタと、液晶駆動用基板を対向させ、両者の間に液晶を封入してなることを特徴とする液晶表示装置。   14. A liquid crystal display device comprising: the color filter according to claim 13 and a liquid crystal driving substrate facing each other, and liquid crystal sealed therein. 請求項13に記載のカラーフィルタを備えた有機ELディスプレイ。   An organic EL display comprising the color filter according to claim 13.
JP2008199717A 2008-08-01 2008-08-01 Colored curable resin composition for color filter by ink-jet method, color filter, liquid crystal display and organic el display Withdrawn JP2010039060A (en)

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JP2010039060A5 true JP2010039060A5 (en) 2011-09-08

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CN102858826B (en) * 2010-04-14 2015-05-20 日本曹达株式会社 Production method for block copolymer and copolymer precursor
JP2012212054A (en) * 2011-03-31 2012-11-01 Toyo Ink Sc Holdings Co Ltd Colored composition for color filter, and color filter
KR101859710B1 (en) * 2010-06-08 2018-05-21 토요잉크Sc홀딩스주식회사 Coloring composition for color filter and color filter
JP5724274B2 (en) * 2010-09-29 2015-05-27 大日本印刷株式会社 Red pigment dispersion for color filter, red photosensitive resin composition for color filter, color filter, and liquid crystal display device
JP6536025B2 (en) * 2013-12-06 2019-07-03 東洋インキScホールディングス株式会社 Colored composition for color filter, and color filter
JP6517066B2 (en) * 2014-03-31 2019-05-22 三井化学株式会社 Resin composition and use thereof
JP6834264B2 (en) * 2015-09-15 2021-02-24 Jsr株式会社 Curable compositions, cured films, display devices and solid-state imaging devices, and compounds
JP7479189B2 (en) 2020-05-07 2024-05-08 サカタインクス株式会社 Pigment dispersion composition for black matrix, and pigment dispersion resist composition for black matrix

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