JP2010031099A5 - - Google Patents
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- JP2010031099A5 JP2010031099A5 JP2008192991A JP2008192991A JP2010031099A5 JP 2010031099 A5 JP2010031099 A5 JP 2010031099A5 JP 2008192991 A JP2008192991 A JP 2008192991A JP 2008192991 A JP2008192991 A JP 2008192991A JP 2010031099 A5 JP2010031099 A5 JP 2010031099A5
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《参考例１：ポリエステルアミド樹脂（Ｉ）の合成例》
機械式撹拌装置、温度計、脱水トラップ、コンデンサー及び乾燥窒素ガス導入口を備えたガラス製反応器に、炭素数３６のダイマー酸〔水添二量体化脂肪酸、ダイマー酸含有率９８％、クローダ（株）製プライポール１００９〕２部、アゼライン酸１８８部、ピペラジン１５８部を入れ、３時間かけて２３０℃まで昇温した。このとき約１５０℃付近から縮合水が流出してきた。２３０℃で１５０ｍｍＨｇまで減圧し、１時間保持した後にサンプリングしたところ酸価は３０であった。この反応混合物に更にアゼライン酸４２９部、シクロヘキサン−１，４−ジメタノール３４１部を添加したところ、内温が１５０℃まで低下した。再度２５０℃まで昇温し、５ｍｍＨｇで１時間、２ｍｍＨｇで１時間、１〜２ｍｍＨｇで３時間反応させ、安定剤であるＮ，Ｎ−ヘキサメチレンビス（３，５−ジ−ｔ−ブチル−４−ヒドロキシシンナマイド（チバスペシャリティケミカルズ製、イルガノックス１０９８）１部を添加した。反応混合物をサンプリングして粘度を測定したところ、２３０℃において６０Ｐａ・ｓであったため、反応を終了し、反応混合物をテフロン（登録商標）バット上に取り出して、目的とするポリエステルアミド樹脂（Ｉ）を得た。
<< Reference Example 1: Synthesis Example of Polyesteramide Resin (I) >>
In a glass reactor equipped with a mechanical stirrer, thermometer, dehydration trap, condenser and dry nitrogen gas inlet, a dimer acid having 36 carbon atoms (hydrogenated dimerized fatty acid, dimer acid content 98%, clada (Plypole 1009, manufactured by Co., Ltd.) 2 parts, 188 parts azelaic acid, and 158 parts piperazine were added and heated to 230 ° C. over 3 hours. At this time, the condensed water flowed out from about 150 ° C. When the pressure was reduced to 150 mmHg at 230 ° C. and held for 1 hour, the acid value was 30 when sampled. When 429 parts of azelaic acid and 341 parts of cyclohexane-1,4-dimethanol were further added to this reaction mixture, the internal temperature decreased to 150 ° C. The temperature was raised again to 250 ° C., and the mixture was reacted at 5 mmHg for 1 hour, 2 mmHg for 1 hour, and 1-2 mmHg for 3 hours, and the stabilizer N, N-hexamethylenebis (3,5-di-t-butyl-4 -1 part of hydroxycinnamide (manufactured by Ciba Specialty Chemicals, Irganox 1098) was added, and the viscosity was measured by sampling the reaction mixture. The product was taken out on a Teflon (registered trademark) vat to obtain a target polyesteramide resin (I).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008192991A JP5469828B2 (en) | 2008-07-28 | 2008-07-28 | Polyesteramide resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008192991A JP5469828B2 (en) | 2008-07-28 | 2008-07-28 | Polyesteramide resin composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010031099A JP2010031099A (en) | 2010-02-12 |
| JP2010031099A5 true JP2010031099A5 (en) | 2011-07-07 |
| JP5469828B2 JP5469828B2 (en) | 2014-04-16 |
Family
ID=41735972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008192991A Expired - Fee Related JP5469828B2 (en) | 2008-07-28 | 2008-07-28 | Polyesteramide resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5469828B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7271146B2 (en) * | 2017-12-28 | 2023-05-11 | 日鉄ケミカル＆マテリアル株式会社 | Dimer diamine composition, method for producing the same, and resin film |
| WO2019147457A2 (en) * | 2018-01-23 | 2019-08-01 | Eastman Chemical Company | Novel polyestermides, processes for the preparation thereof, and polyesteramide compositions |
| CN109742343A (en) * | 2018-12-20 | 2019-05-10 | 中南民族大学 | High-valued electrode active material of nylon engineering plastic and preparation method thereof |
| CN113767133A (en) * | 2019-04-30 | 2021-12-07 | 巴斯夫欧洲公司 | Flame-retardant polyamide |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10134816A (en) * | 1996-03-29 | 1998-05-22 | Sekisui Chem Co Ltd | Nonaqueous electrolyte secondary battery |
| JP2000048805A (en) * | 1998-07-29 | 2000-02-18 | Sekisui Chem Co Ltd | Manufacture of positive electrode or negative electrode for nonaqueous electrolyte secondary battery |
| JP2002003601A (en) * | 2000-06-23 | 2002-01-09 | T & K Toka Co Ltd | Polyesteramide copolymer and adhesive composition for laminate using it |
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2008
- 2008-07-28 JP JP2008192991A patent/JP5469828B2/en not_active Expired - Fee Related
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