JP2010017103A - Environment improving device for crawl - Google Patents

Environment improving device for crawl Download PDF

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JP2010017103A
JP2010017103A JP2008178490A JP2008178490A JP2010017103A JP 2010017103 A JP2010017103 A JP 2010017103A JP 2008178490 A JP2008178490 A JP 2008178490A JP 2008178490 A JP2008178490 A JP 2008178490A JP 2010017103 A JP2010017103 A JP 2010017103A
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photocatalyst
ginger
photocatalyst member
rope
substantially cylindrical
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Kiyoshi Kato
清 加藤
Tsukasa Ohara
司 大原
Yoshihiro Okubo
嘉洋 大久保
Toshiro Nasu
敏朗 那須
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Kinki University
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a crawl environment improving device continuously developing adhesion prevention effect and fungicidal effect over a long period at a low cost without polluting the environment in water. <P>SOLUTION: A plurality of first cords 10 are bound with a plurality of second cords 11, a first photocatalyst member 13 has a nearly cylindrical form to pass the first cord 10 therethrough, a second photocatalyst member 13 has a nearly cylindrical base part to pass the first cord 10 therethrough and an engaging part formed on the base part, and a third photocatalyst member 19 has a connection part 18 to connect a pair of the nearly cylindrical body parts 17a, 17b to pass the second cord 11 therethrough. Since the first to the third photocatalyst members 13, 16, 19 have the above structure, the displacement of each photocatalyst member 13, 16, 19 relative to the cords 10, 11 is prevented even in the case of swinging the crawl by wave or sea current, and the photocatalyst members can be arranged uniformly over the whole installed area in high density to realize the adhesion prevention effect on aquatic life and fungicidal effect. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、魚介類の養殖などのための生簀への水生生物の付着を抑制し、水中環境を改善するために好適に実施することができる光触媒を用いた生簀環境改善装置に関する。   The present invention relates to a ginger environment improving apparatus using a photocatalyst that can be suitably implemented to suppress the attachment of aquatic organisms to a ginger for aquaculture and the like, and to improve the aquatic environment.

魚類、甲殻類、貝類、藻類などの養殖のための生簀の養殖領域を周囲の水域から区画する養殖網には、長期間の使用によって、藻類、フジツボなどの水生生物が付着する。養殖網に付着した水生生物は、養殖網の網目を通過する水の流れを妨げ、養殖領域内の水質を悪化させ、寄生虫やバクテリアの繁殖を招来して、良好な養殖環境を損なうおそれがある。   Aquatic organisms such as algae and barnacles adhere to the aquaculture nets that divide the aquaculture area for fish, crustaceans, shellfish, algae and the like from the surrounding water area over a long period of time. Aquatic organisms adhering to the aquaculture net may impede the flow of water through the aquaculture net, worsen the water quality in the aquaculture area, and lead to the growth of parasites and bacteria, which may damage the good aquaculture environment. is there.

そのため、従来から、養殖網に有機スズ化合物または生物由来の忌避成分などの付着阻害物質を含有する塗料を塗布し、養殖網に水生生物が付着することを防止する技術が提案されているが、塗料含有物質の溶出または剥離によって水中環境が汚染されるとともに、水生生物の付着防止効果が短期間しか持続しないという問題がある。   Therefore, conventionally, a technique has been proposed in which an aquatic organism is prevented from adhering to the aquaculture net by applying a coating containing an adhesion inhibitor such as an organotin compound or a biological repellent component to the aquaculture net. There is a problem that the aquatic environment is polluted by elution or peeling of the paint-containing substance and the aquatic organism adhesion preventing effect lasts only for a short period.

またこの従来技術では、付着阻害物質を含有する塗料は高価であり、また発生したバクテリアに対する殺菌効果が低いため、安価に長期間にわたって付着防止効果および殺菌効果を持続させることができる技術が望まれている。   Further, in this conventional technique, since the paint containing an adhesion inhibitor is expensive and has a low bactericidal effect against the generated bacteria, a technique capable of maintaining the adhesion preventing effect and bactericidal effect over a long period of time is desired. ing.

特開2006−160665号公報JP 2006-160665 A

本発明の目的は、安価なコストで、水中環境を汚染せず、長期間にわたる付着防止効果および殺菌効果を持続することができる生簀環境改善装置を提供することである。   An object of the present invention is to provide a ginger environment improving apparatus capable of maintaining an adhesion preventing effect and a sterilizing effect over a long period of time at a low cost without polluting the underwater environment.

本発明は、索条と、
索条が挿通され、基材の表面に光触媒機能を有する物質を含む光触媒層が設けられる略円筒状の複数の光触媒部材とを含むことを特徴とする生簀環境改善装置である。
The present invention comprises a rope,
A ginger environment improving device comprising a plurality of photocatalyst members having a substantially cylindrical shape in which a rope is inserted and a photocatalyst layer including a substance having a photocatalytic function is provided on a surface of a base material.

本発明に従えば、基材の表面に光触媒層が設けられる複数の略円筒状の光触媒部材に索条を挿通した構成とされるので、索条の一端部を水中に設置されている既存の生簀設備に結束するなどして容易に取り付けることができる。前記生簀は、水中に設置される養殖網に限るものではなく、地上に構築される水槽であってもよい。   According to the present invention, since the rope is inserted into a plurality of substantially cylindrical photocatalyst members provided with a photocatalyst layer on the surface of the base material, one end of the rope is installed in water. It can be attached easily by binding to ginger equipment. The ginger is not limited to an aquaculture net installed in water, but may be a water tank constructed on the ground.

前記光触媒機能を有する物質としては、たとえば酸化チタンを挙げることができる。酸化チタンは、そのバンドギャップ以上のエネルギを持つ波長帯域が約300〜400nmの近紫外線などの光を照射すると、光励起によって伝導帯に電子を生じ、価電子帯に正孔を生じ、この光励起して生じた電子の持つ強い還元力および正孔の持つ強い酸化力を利用して殺菌作用を達成し、また有機物の分解、脱臭の各作用が達成される。これによって水に含まれる藻類、菌類などの有害物質を死滅させ、有害な物質を分解して水を長期間にわたって清浄化し、養殖網または水槽などの生簀への藻類およびフジツボなどの水生生物の付着を防止して、長期にわたって良好な生簀環境を維持することができる。   Examples of the substance having a photocatalytic function include titanium oxide. Titanium oxide emits electrons in the conduction band by photoexcitation and generates holes in the valence band by photoexcitation when irradiated with light such as near-ultraviolet light whose energy is equal to or greater than its band gap. Bactericidal action is achieved by utilizing the strong reducing power of the electrons generated by this and the strong oxidizing power of the holes, and the actions of decomposition and deodorization of organic substances are achieved. This kills harmful substances such as algae and fungi contained in the water, decomposes the harmful substances and cleans the water for a long period of time, and attaches algae and aquatic organisms such as barnacles to ginger such as aquaculture nets or aquariums Can be maintained and a good ginger environment can be maintained over a long period of time.

また本発明は、前記索条は、予め定める第1方向に相互に間隔をあけて配置される複数の第1索条と、前記第1方向に交差する第2方向に相互に間隔をあけて配置され、各第1索条に結束される複数の第2索条とを含み、
前記光触媒部材は、第1索条が挿通する略円筒状の基部と、基部に設けられ、第2索条に掛け止められる係合部とを有することを特徴とする。
Further, according to the present invention, the strips are spaced apart from each other in a second direction intersecting the first direction and a plurality of first strands that are spaced apart from each other in a predetermined first direction. Including a plurality of second strands arranged and bound to each first strand;
The photocatalyst member has a substantially cylindrical base portion through which the first rope is inserted, and an engagement portion provided on the base portion and hooked to the second rope.

本発明に従えば、複数の第1索条が複数の第2索条によって結束され、各光触媒部材は、第1索条が挿通する略円筒状の基部に、第2索条に掛け止められる係合部が設けられた構成であるので、生簀が波や海流などによって揺動しても、各光触媒部材が第1および第2索条に対してずれてしまうことが防がれ、設置された範囲全体に均等に光触媒部材を配置して、確実に付着防止効果および殺菌効果を実現することができる。   According to the present invention, a plurality of first strands are bundled by a plurality of second strands, and each photocatalytic member is hooked to the second strand on a substantially cylindrical base portion through which the first strands are inserted. Since the engagement portion is provided, each photocatalyst member is prevented from being displaced with respect to the first and second ropes even when the ginger is swung by waves or ocean currents. In addition, the photocatalyst member can be evenly arranged over the entire range, and the adhesion preventing effect and the sterilizing effect can be reliably realized.

また本発明は、前記索条は、予め定める第1方向に相互に間隔をあけて配置される複数の第1索条と、前記第1方向に交差する第2方向に相互に間隔をあけて配置され、各第1索条に結束される複数の第2索条とを含み、
前記光触媒部材は、第2索条が挿通する略円筒状の一対の本体部分と、各本体部分を相互に軸線方向に離間させた状態で連結し、第1索条に掛け止められる連結部分とを有することを特徴とする。
Further, according to the present invention, the strips are spaced apart from each other in a second direction intersecting the first direction and a plurality of first strands that are spaced apart from each other in a predetermined first direction. Including a plurality of second strands arranged and bound to each first strand;
The photocatalyst member is connected to a pair of substantially cylindrical main body portions through which the second strips are inserted, a connecting portion that is connected to each other with the main body portions spaced apart from each other in the axial direction, and is hooked to the first strips. It is characterized by having.

本発明に従えば、複数の第1索条が複数の第2索条によって結束され、各光触媒部材は、第2索条が挿通する略円筒状の一対の本体部分と、各本体部分を相互に軸線方向に離間させた状態で連結し、第1索条に掛け止められる連結部分とを有するので、各光触媒部材を第1索条に対して第2索条毎に位置決めし、生簀が波や海流などによって揺動しても、各光触媒部材が第1および第2索条に対してずれてしまうことが防がれ、設置された範囲全体に均等に光触媒部材を配置して、確実に付着防止効果および殺菌効果を実現することができる。   According to the present invention, a plurality of first strands are bound by a plurality of second strands, and each photocatalytic member has a pair of substantially cylindrical main body portions through which the second strands are inserted, and each main body portion mutually. Are connected in a state of being separated from each other in the axial direction, and are connected to the first rope, so that each photocatalyst member is positioned for each second rope with respect to the first rope, and the ginger is waved. Even if the photocatalyst member is swung by an ocean current or the like, it is prevented that each photocatalyst member is displaced with respect to the first and second ropes. An adhesion preventing effect and a sterilizing effect can be realized.

また本発明は、前記索条は、予め定める第1方向に相互に間隔をあけて配置される複数の第1索条と、前記第1方向に交差する第2方向に相互に間隔をあけて配置され、各第1索条に結束される複数の第2索条とを含み、
前記光触媒部材は、
第1索条が挿通される略円筒状の第1光触媒部材と、
前記第1索条が挿通する略円筒状の基部と、基部に設けられ、第2索条に掛け止められる係合部とを有する第2光触媒部材と、
第2索条が挿通する略円筒状の一対の本体部分と、各本体部分を相互に軸線方向に離間させた状態で連結し、第1索条に掛け止められる連結部分とを有する第3光触媒部材とを含むことを特徴とする。
Further, according to the present invention, the strips are spaced apart from each other in a second direction intersecting the first direction and a plurality of first strands that are spaced apart from each other in a predetermined first direction. Including a plurality of second strands arranged and bound to each first strand;
The photocatalyst member is
A substantially cylindrical first photocatalytic member into which the first rope is inserted;
A second photocatalyst member having a substantially cylindrical base portion through which the first strip is inserted, and an engaging portion provided on the base portion and latched on the second strand;
A third photocatalyst having a pair of substantially cylindrical main body portions through which the second rope is inserted, and a coupling portion that connects the main body portions with each other being separated from each other in the axial direction and is latched on the first rope. And a member.

本発明に従えば、複数の第1索条が複数の第2索条によって結束され、第1光触媒部材は、第1索条が挿通される略円筒状に形成され、第2光触媒部材は、第1索条が挿通する略円筒状の基部と、基部に設けられ、第2索条に掛け止められる係合部とを有し、第3光触媒部材は、第2索条が挿通する略円筒状の一対の本体部分と、各本体部分を相互に軸線方向に離間させた状態で連結し、第1索条に掛け止められる連結部分とを有する。このように各光触媒部材は、第1〜第3光触媒部材によって構成されるので、生簀が波や海流などによって揺動しても、各光触媒部材が第1および第2索条に対してずれてしまうことが防がれ、設置された範囲全体に均等に、しかも高密度で光触媒部材を配置することができ、より高い水生生物の付着防止効果および殺菌効果を実現することができる。   According to the present invention, the plurality of first strands are bundled by the plurality of second strands, the first photocatalytic member is formed in a substantially cylindrical shape through which the first strand is inserted, and the second photocatalytic member is A substantially cylindrical base portion through which the first rope is inserted, and an engagement portion provided at the base and hooked to the second rope, and the third photocatalyst member is a substantially cylinder through which the second rope is inserted. A pair of main body portions and a connection portion that is connected to each other in a state where the main body portions are spaced apart from each other in the axial direction, and is hooked on the first rope. Thus, since each photocatalyst member is comprised by the 1st-3rd photocatalyst member, even if a ginger rock | fluctuates by a wave, an ocean current, etc., each photocatalyst member will shift | deviate with respect to a 1st and 2nd strip. Therefore, the photocatalyst member can be arranged evenly and at a high density over the entire installed range, and a higher aquatic organism adhesion prevention effect and sterilization effect can be realized.

また本発明は、前記第1光触媒部材は、セラミックスの焼結体から成ることを特徴とする。   In the invention, it is preferable that the first photocatalyst member is made of a ceramic sintered body.

本発明に従えば、前記第1光触媒部材がセラミックスの焼結体から成るので、多数の光触媒部材を焼成炉等によって工業的に焼成し、容易にかつ安価に耐久性の高い光触媒部材を製造することができる。これによって、広範囲に構築された生簀であっても、低コストで水生生物の付着防止効果および殺菌効果を実現することができる。   According to the present invention, since the first photocatalyst member is made of a ceramic sintered body, a large number of photocatalyst members are industrially fired in a firing furnace or the like to easily and inexpensively produce a highly durable photocatalyst member. be able to. Thereby, even if it is a ginger constructed | assembled extensively, the adhesion prevention effect and disinfection effect of aquatic organisms are realizable at low cost.

また本発明は、前記第1光触媒部材は、アルミニウム合金から成ることを特徴とする。
本発明に従えば、前記第1光触媒部材がアルミニウム合金から成るので、多数の光触媒部材を金型成型によって製造することができる。このような金型成型は、光触媒部材の形状決定上の自由度が高く、表面の凹凸などの起伏を設けて受光面積を大きくし、光触媒機能を向上することができる。
In the present invention, the first photocatalyst member is made of an aluminum alloy.
According to the present invention, since the first photocatalyst member is made of an aluminum alloy, a large number of photocatalyst members can be manufactured by molding. Such mold molding has a high degree of freedom in determining the shape of the photocatalyst member, and can provide undulations such as surface irregularities to increase the light receiving area and improve the photocatalytic function.

また本発明は、前記第2光触媒部材は、合成樹脂から成ることを特徴とする。
本発明に従えば、前記第2光触媒部材が合成樹脂から成るので、第1索条が挿通する略円筒状の基部に第2索条に掛け止められる係合部が設けられる光触媒部材を、たとえば射出成型などによって容易かつ安価に製造することができ、これによって製造コストを低減することができる。
In the invention, it is preferable that the second photocatalyst member is made of a synthetic resin.
According to the present invention, since the second photocatalyst member is made of a synthetic resin, a photocatalyst member provided with an engaging portion that is hooked on the second rope on a substantially cylindrical base portion through which the first rope is inserted, for example, It can be manufactured easily and inexpensively by injection molding or the like, thereby reducing the manufacturing cost.

また本発明は、前記第3光触媒部材は、合成樹脂から成ることを特徴とする。
本発明に従えば、前記第3光触媒部材が合成樹脂から成るので、第2索条が挿通する略円筒状の一対の本体部分を相互に軸線方向に離間させた状態で連結部分によって連結された光触媒部材を、たとえば射出成型などによって容易かつ安価に製造することができ、これによって製造コストを低減することができる。
In the present invention, the third photocatalyst member is made of a synthetic resin.
According to the present invention, since the third photocatalyst member is made of a synthetic resin, the pair of substantially cylindrical main body portions through which the second ropes are inserted are connected by the connecting portions in a state where they are separated from each other in the axial direction. The photocatalyst member can be easily and inexpensively manufactured by, for example, injection molding, thereby reducing the manufacturing cost.

本発明によれば、基材の表面に光触媒層が設けられる複数の略円筒状の光触媒部材に索条を挿通した構成であるので、既存の養殖網および水槽などの生簀設備に容易に設けることができ、安価なコストで水生生物の付着防止効果および殺菌効果を長期に持続させて、生簀の環境を改善することができる生簀環境改善装置を実現することができる。   According to the present invention, since the line is inserted through a plurality of substantially cylindrical photocatalyst members provided with a photocatalyst layer on the surface of the substrate, it can be easily provided in existing aquaculture equipment such as aquaculture nets and water tanks. Therefore, it is possible to realize a ginger environment improving device that can improve the environment of the ginger by maintaining the aquatic organism adhesion preventing effect and the sterilizing effect for a long period of time at a low cost.

図1は本発明に実施の一形態の生簀環境改善装置1を示す斜視図であり、図2は生簀環境改善装置1を生簀2に設置した状態を示す斜視図である。たとえば海中に設置される生簀2の養殖網3は、海中で魚、甲殻類などを養殖するための養殖領域を規定し、この養殖領域を清浄な環境に維持するために、前記養殖網3には生簀環境改善装置1が設けられる。   FIG. 1 is a perspective view showing a ginger environment improving apparatus 1 according to an embodiment of the present invention, and FIG. 2 is a perspective view showing a state where the ginger environment improving apparatus 1 is installed in a ginger 2. For example, an aquaculture net 3 for ginger 2 installed in the sea defines an aquaculture area for aquaculture of fish, crustaceans, etc. in the sea, and in order to maintain this aquaculture area in a clean environment, Is provided with a ginger environment improving device 1.

養殖網3は、4つの周壁および底部を有し、直方体の養殖領域を形成し、海水が養殖網3の各網目4を自由に通過する。本実施の形態では、養殖網は菱目編地から成る。養殖網3の周壁の上部には、複数の浮子5が互いに間隔をあけて連結され、養殖網3の下端部が海中に垂下して、前述した直方体状の養殖領域を周囲から区画し、太陽光、蛍光灯、水銀灯、白熱灯などの光源から直接に、または光ファイバを介して間接に、紫外線を含む光が照射される。このような養殖領域を規定する養殖網3には、本実施形態の生簀環境改善装置1が全周にわたって外囲するように設けられる。なお、図2は、図解を容易にするため、養殖網3の一側壁だけに生簀環境改善装置1が装着された状態を示している。   The aquaculture net 3 has four peripheral walls and a bottom, forms a rectangular aquaculture area, and seawater freely passes through each mesh 4 of the aquaculture net 3. In the present embodiment, the aquaculture net is composed of a knitted knitted fabric. A plurality of floats 5 are connected to the upper part of the peripheral wall of the aquaculture net 3 with a space between them, and the lower end of the aquaculture net 3 hangs down into the sea to divide the above-described rectangular parallelepiped culture area from the surroundings. Light including ultraviolet rays is irradiated directly from a light source such as light, a fluorescent lamp, a mercury lamp, an incandescent lamp, or indirectly through an optical fiber. In the aquaculture net 3 that defines such an aquaculture area, the ginger environment improving apparatus 1 of the present embodiment is provided so as to surround the entire circumference. 2 shows a state in which the ginger environment improving device 1 is attached only to one side wall of the aquaculture net 3 for easy illustration.

前記生簀環境改善装置1は、予め定める第1方向である略鉛直方向Yに延び、相互に間隔L1をあけて配置される複数の第1索条10と、前記第1方向に交差する第2方向である略水平方向Xに延び、相互に間隔L2をあけて配置され、各第1索条10に結束される複数の第2索条11とによって格子状に形成される網状体12と、第1索条10が挿通される略円筒状の第1光触媒部材13と、前記第1索条10が挿通する略円筒状の基部14と、基部14に設けられ、第2索条11に掛け止められる係合部15とを有する第2光触媒部材16と、第2索条11が挿通する略円筒状の一対の本体部分17a,17bおよび各本体部分17a,17bを相互に軸線方向に離間させた状態で連結し、第1索条10に掛け止められる連結部分18を有する第3光触媒部材19とを含む。   The ginger environment improving apparatus 1 extends in a substantially vertical direction Y, which is a first direction determined in advance, and a plurality of first ropes 10 arranged at intervals L1 and a second crossing the first direction. A net-like body 12 that extends in a substantially horizontal direction X that is a direction, is arranged with a distance L2 from each other, and is formed in a lattice shape by a plurality of second ropes 11 bound to each first rope 10; A substantially cylindrical first photocatalytic member 13 through which the first strip 10 is inserted, a substantially cylindrical base portion 14 through which the first strip 10 is inserted, and a base portion 14, which is hung on the second strip 11. The second photocatalyst member 16 having the engaging portion 15 to be stopped, the pair of substantially cylindrical main body portions 17a and 17b through which the second rope 11 is inserted, and the main body portions 17a and 17b are separated from each other in the axial direction. The connecting portion 18 that is connected to the first rope 10 And a third photocatalytic member 19.

第1および第2索条10,11を総称して「索条」と記す場合がある。また、第1〜第3光触媒部材13,16,19を総称して「光触媒部材」と記す場合がある。前記索条10,11は、ポリエチレン、ナイロンおよびポリエステルなどの合成樹脂から成る複数のモノフィラメントまたはマルチフィラメントを撚り合わせたロープまたは紐によって実現される。また、第1索条10と第2索条11とは有結節目によって互いに結束された構成であってもよく、無結節目によって一体に連なって結束された構成であってもよい。   The first and second strips 10 and 11 may be collectively referred to as “strip”. The first to third photocatalyst members 13, 16, and 19 may be collectively referred to as “photocatalyst members”. The ropes 10 and 11 are realized by a rope or string obtained by twisting a plurality of monofilaments or multifilaments made of synthetic resin such as polyethylene, nylon, and polyester. Further, the first rope 10 and the second rope 11 may be configured to be bound to each other by a knotted line, or may be configured to be integrally linked and bound by a knotless line.

図3は第1光触媒部材13の斜視図であり、図4は第1光触媒部材13の分解斜視図である。第1光触媒部材13は、中心軸線上に第1および第2索条10,11を挿通することができる挿通孔20が形成される略回転楕円体状の基部21と、基部21の外周面に接着剤によって固着される一対の半割れ状の外層片22a,22bと有する。基部21はセラミックスの焼結体から成る。各外層片22a,22bは、光触媒として機能する物質を含有する担持体としてのセラミックスの焼結体から成る。   FIG. 3 is a perspective view of the first photocatalyst member 13, and FIG. 4 is an exploded perspective view of the first photocatalyst member 13. The first photocatalyst member 13 has a substantially spheroidal base 21 formed with an insertion hole 20 through which the first and second strips 10 and 11 can be inserted on the central axis, and an outer peripheral surface of the base 21. It has a pair of half-cracked outer layer pieces 22a and 22b fixed by an adhesive. The base 21 is made of a ceramic sintered body. Each outer layer piece 22a, 22b is made of a ceramic sintered body as a carrier containing a substance that functions as a photocatalyst.

前記接着剤としては、水中で有機溶剤、揮発性有機化合物、化学薬品および可塑剤などに含まれるホルムアルデヒド等の有害物質が溶出しない耐水性に優れた接着剤が用いられる。   As the adhesive, an adhesive having excellent water resistance that does not elute harmful substances such as formaldehyde contained in organic solvents, volatile organic compounds, chemicals, plasticizers, and the like in water is used.

ここで、本実施形態において、光触媒機能とは、光触媒機能を有する物質として、たとえば、二酸化チタン、酸化亜鉛、炭化ケイ素等の無機材料にそのバンドギャップ以上のエネルギを持つ光を照射すると、その表面上に正孔・電子対が生成する現象をいう。光エネルギによって生じた正孔は、水と接することによって下記の反応を生じる。
2O+h+→OH+H+
Here, in this embodiment, the photocatalytic function is a surface having a photocatalytic function, for example, when an inorganic material such as titanium dioxide, zinc oxide, or silicon carbide is irradiated with light having energy greater than its band gap. This is a phenomenon in which hole-electron pairs are generated on the top. Holes generated by light energy cause the following reaction when in contact with water.
H 2 O + h + → OH + H +

また、電子が空気と接することによって下記の反応を生じる。
2+e-→O2 -
In addition, the following reaction occurs when electrons come into contact with air.
O 2 + e → O 2

発生したOH(水酸ラジカル)およびO2 -(活性酸素:スーパーオキサイドイオン)はオゾン以上の強い酸化作用を有している。この活性酸素は強い殺菌力を有しており、微生物の細胞膜を破壊する作用を発現する。この働きは活性酸素の寿命が非常に短いことから光触媒の表面のみで生じ、表面から離れた部位には影響を及ぼすことはない。 The generated OH (hydroxyl radical) and O 2 (active oxygen: superoxide ion) have a stronger oxidizing action than ozone. This active oxygen has a strong bactericidal power and expresses the action of destroying the cell membrane of microorganisms. This function occurs only on the surface of the photocatalyst because the lifetime of the active oxygen is very short, and does not affect the site away from the surface.

前記光触媒機能を有する物質としては、後述する酸化チタンを挙げることができる。酸化チタンは、そのバンドギャップ以上のエネルギを持つ波長帯域が約300〜400nmの近紫外線などの光を照射すると、光励起によって伝導帯に電子を生じ、価電子帯に正孔を生じ、この光励起して生じた電子の持つ強い還元力および正孔の持つ強い酸化力を利用して殺菌作用を達成し、また有機物の分解、脱臭の各作用が達成される。   Examples of the substance having a photocatalytic function include titanium oxide described later. Titanium oxide emits electrons in the conduction band by photoexcitation and generates holes in the valence band by photoexcitation when irradiated with light such as near-ultraviolet light whose energy is equal to or greater than its band gap. Bactericidal action is achieved by utilizing the strong reducing power of the electrons generated by this and the strong oxidizing power of the holes, and the actions of decomposition and deodorization of organic substances are achieved.

光触媒機能を有する物質の担持体としてのセラミックスは、立体的な網目構造を有する多孔質セラミックであって、直径が2〜3mmのマクロポアと、直径が2〜3μmのミクロポアとを有する構造体であり、金属酸化物系セラミックスおよび非酸化物系セラミックスの粉体、たとえば、金属酸化物系セラミックスとしてアルミナ、コージライト、ムライト、ジルコニア、シリカ、マグネシア等およびこれらの混合物、非酸化物系セラミックスとして、炭化ケイ素、窒化ケイ素から得られる多孔質セラミックスなどの粉体を好適に用いることができる。   A ceramic as a support for a substance having a photocatalytic function is a porous ceramic having a three-dimensional network structure, and has a macropore having a diameter of 2 to 3 mm and a micropore having a diameter of 2 to 3 μm. , Powders of metal oxide ceramics and non-oxide ceramics, for example, alumina, cordierite, mullite, zirconia, silica, magnesia etc. as metal oxide ceramics and mixtures thereof, carbonization as non-oxide ceramics Powders such as porous ceramics obtained from silicon and silicon nitride can be suitably used.

多孔質セラミックの製造方法としては、たとえば、材料をシルト状または泥水状とし、これをフォーム剤に含浸させ、1500℃程度の高温で焼結させる。また、光触媒機能を有する物質としては、二酸化チタン(TiO2)、酸化亜鉛(Zn2O)、炭化ケイ素(SiC)、二硫化モリブデン(MoS2)、酸化第二鉄(Fe23)、酸化第二インジウム(In23)、三酸化タングステン(WO3)などの光触媒半導体と称される材料を使用することができるが、太陽光などの自然光で光触媒機能を発現する二酸化チタン、酸化亜鉛、炭化ケイ素などが好ましい。これらは、1種を用いてもよく、その光触媒機能を損なわない限りにおいて、2種以上を混合して用いてもよく、さらに、これらを主材とする合金として用いてもよい。特に、水に不溶であり、化粧品や歯磨きの材料としても用いられる二酸化チタンは、安全性も確認されており、バンドギャップが3eVであって、400nm以下の波長の光、即ち、太陽光で励起されて光触媒機能を発現させることができる。 As a method for producing the porous ceramic, for example, the material is made into a silt or muddy water, impregnated in a foam agent, and sintered at a high temperature of about 1500 ° C. In addition, as a substance having a photocatalytic function, titanium dioxide (TiO 2 ), zinc oxide (Zn 2 O), silicon carbide (SiC), molybdenum disulfide (MoS 2 ), ferric oxide (Fe 2 O 3 ), Materials called photocatalytic semiconductors such as indium oxide (In 2 O 3 ) and tungsten trioxide (WO 3 ) can be used, but titanium dioxide that exhibits photocatalytic function under natural light such as sunlight, oxidized Zinc, silicon carbide and the like are preferred. These may be used alone, or may be used as a mixture of two or more as long as the photocatalytic function is not impaired, and may be used as an alloy containing these as a main material. In particular, titanium dioxide, which is insoluble in water and used as a cosmetic or toothpaste material, has been confirmed to be safe, has a band gap of 3 eV, and is excited by light having a wavelength of 400 nm or less, that is, sunlight. Thus, the photocatalytic function can be expressed.

多孔質セラミックの表面に光触媒物質を担持させる方法としては、ゾル−ゲル法、スプレードライ法、溶射法などを採用することができる。ゾル−ゲル法による具体的な適用方法としては、多孔質セラミックをエタノールで洗浄し、乾燥して清浄にしたものを、チタンイソプロポキシド/エタノール溶液中に浸漬しながら加水分解を行い、溶液から取り出して乾燥する。   As a method for supporting the photocatalytic substance on the surface of the porous ceramic, a sol-gel method, a spray drying method, a thermal spraying method, or the like can be employed. As a specific application method by the sol-gel method, a porous ceramic washed with ethanol, dried and cleaned is immersed in a titanium isopropoxide / ethanol solution, and then hydrolyzed. Remove and dry.

前記多孔質セラミックスは、カオリナイトまたはモンモリロナイトを多く含んだ粘土を原料とし、焼成炉内で1100〜1300℃の温度で焼成することによって得られる。このような多孔質セラミックスは、無機系抗菌剤として、ゼオライト、シリカゲル、ガラス、リン酸カルシウム、リン酸ジルコニウム、ケイ酸塩、酸化チタン、酸化亜鉛ウィスカー、チタン酸カリウムウィスカーおよびアルミナのうちから選ばれる一種が用いられてもよく、また有機系抗菌剤として、2−(4−チアゾリル)ベンズイミダゾ−ルなどイミダゾ−ル誘導体、シクロフルアニドなどN−ハロアルキルチオ系化合物、10、10’−オキシビスフェノキサアルシンなどフェニルエーテル誘導体、セシルジメチルエチルアンモニウムブロミドなど第4級アンモニウム塩および2、3、5、6テトラコロル−4−(メチルスルホニル)ピリジンなどスルホン誘導体、アミド類、トリアジン誘導体、トリアゾール誘導体、メチロール基含有化合物、活性ハロゲン含有化合物、活性化されたN−S結合含有化合物、イソチアゾロン系および有機ヨウ素系のうちから選ばれた1種または複数種が用いられてもよい。   The porous ceramics can be obtained by using a clay containing a large amount of kaolinite or montmorillonite as a raw material and firing it at a temperature of 1100 to 1300 ° C. in a firing furnace. Such a porous ceramic is a kind selected from zeolite, silica gel, glass, calcium phosphate, zirconium phosphate, silicate, titanium oxide, zinc oxide whisker, potassium titanate whisker and alumina as an inorganic antibacterial agent. In addition, as an organic antibacterial agent, imidazole derivatives such as 2- (4-thiazolyl) benzimidazole, N-haloalkylthio compounds such as cyclofluoride, 10, 10′-oxybisphenoxa Contains phenyl ether derivatives such as arsine, quaternary ammonium salts such as cecildimethylethylammonium bromide, and sulfone derivatives such as 2, 3, 5, 6 tetracolol-4- (methylsulfonyl) pyridine, amides, triazine derivatives, triazole derivatives, and methylol groups. Compounds, active halogen-containing compound, activated N-S bond-containing compounds, one or more may be used selected from among isothiazolone and organic iodine.

図5は第2光触媒部材16を示す斜視図であり、図6は第2光触媒部材16の背面図である。前記第2光触媒部材16は、第1索条10が挿通する挿通孔28を有する略円筒状の基部25と、基部25に設けられ、第2索条11に掛け止められる係合部26とを有する。前記係合部26は、基端部が基部25の軸線方向中央部近傍に一体的に連なり、遊端部が相互に近接して配置される略C字状の係合片27a,27bから成る。   FIG. 5 is a perspective view showing the second photocatalyst member 16, and FIG. 6 is a rear view of the second photocatalyst member 16. The second photocatalyst member 16 includes a substantially cylindrical base portion 25 having an insertion hole 28 through which the first rope 10 is inserted, and an engagement portion 26 that is provided in the base portion 25 and is latched on the second rope 11. Have. The engaging portion 26 is composed of substantially C-shaped engaging pieces 27a and 27b in which the base end portion is integrally connected to the vicinity of the central portion in the axial direction of the base portion 25 and the free end portions are disposed close to each other. .

このような第2光触媒部材16は、合成樹脂から成り、熱可塑性合成樹脂としては、フッ素樹脂、アクリル樹脂、ポリアミド樹脂、塩化ビニル樹脂、ポリカーボネート樹脂、ポリオレフィン系樹脂、エポキシ樹脂、ポリアセタール樹脂、ポリエステル樹脂、ポリエーテルイミド樹脂、ポリエーテルスルホン樹脂、ポリエーテルエーテルケトン樹脂、ポリフェニレンスルフィド樹脂、ポリスルホン樹脂、ポリアリレート樹脂、ポリエチレンナフタレート樹脂、ポリメチルペンテン樹脂、ABS樹脂、酢酸ビニル樹脂およびポリスチレン樹脂のうちの一種を選択的に用いることができる。また、熱硬化性合成樹脂としては、メラミン樹脂、フェノール樹脂、ユリア樹脂、フラン樹脂、アルキッド樹脂、不飽和ポリエステル樹脂、ジアリルフタレート樹脂、エポキシ樹脂、ケイ素樹脂、ポリウレタン樹脂、ポリイミド樹脂およびポリパラバン酸樹脂のうちの一種を選択的に用いることができる。   The second photocatalyst member 16 is made of a synthetic resin, and the thermoplastic synthetic resin includes a fluororesin, an acrylic resin, a polyamide resin, a vinyl chloride resin, a polycarbonate resin, a polyolefin resin, an epoxy resin, a polyacetal resin, and a polyester resin. , Polyetherimide resin, polyethersulfone resin, polyetheretherketone resin, polyphenylene sulfide resin, polysulfone resin, polyarylate resin, polyethylene naphthalate resin, polymethylpentene resin, ABS resin, vinyl acetate resin and polystyrene resin One kind can be selectively used. Thermosetting synthetic resins include melamine resin, phenol resin, urea resin, furan resin, alkyd resin, unsaturated polyester resin, diallyl phthalate resin, epoxy resin, silicon resin, polyurethane resin, polyimide resin and polyparabanic acid resin. One of them can be used selectively.

このような合成樹脂の表面に前記光触媒発生物質、たとえば酸化チタンを混入して、たとえばブロー成型することによって、第2光触媒部材16を製造することができる。光触媒機能を有する酸化チタンなどの物質と合成樹脂とが混合されて成形される構成を有する光触媒部材を用いることによって、酸化チタンなどの物質が剥離、除去されることはなく、長期間にわたって使用することができる。   The second photocatalyst member 16 can be manufactured by mixing the photocatalyst generating substance, for example, titanium oxide, on the surface of such a synthetic resin and performing blow molding, for example. By using a photocatalyst member having a structure in which a synthetic resin is mixed with a substance such as titanium oxide having a photocatalytic function, the substance such as titanium oxide is not peeled off or removed, and is used for a long period of time. be able to.

図7は第3光触媒部材19を示す斜視図である。前記第3光触媒部材19は、第2索条11が挿通する挿通孔27a,27bがそれぞれ形成される略円筒状の一対の本体部分17a,17bと、各本体部分17a,17bを相互に軸線方向に離間させた状態で連結し、第1索条10に掛け止められる連結部分18とを有する。このような第3光触媒部材19は、前述の第2光触媒部材16と同様な合成樹脂から成る。   FIG. 7 is a perspective view showing the third photocatalyst member 19. The third photocatalyst member 19 includes a pair of substantially cylindrical main body portions 17a and 17b in which insertion holes 27a and 27b through which the second strips 11 are inserted are respectively formed, and the main body portions 17a and 17b are axially connected to each other. And a connecting portion 18 that is connected to the first rope 10 and is latched. The third photocatalyst member 19 is made of a synthetic resin similar to the second photocatalyst member 16 described above.

本実施形態によれば、複数の第1索条10が複数の第2索条11によって結束され、第1光触媒部材13は、第1索条10が挿通される略円筒状に形成され、第2光触媒部材16は、第1索条10が挿通する略円筒状の基部25と、基部25に設けられ、第2索条11に掛け止められる係合部26とを有し、第3光触媒部材19は、第2索条11が挿通する略円筒状の一対の本体部分17a,17bと、各本体部分17a,17bを相互に軸線方向に離間させた状態で連結し、第1索条10に掛け止められる連結部分18とを有する。このように光触媒部材は、第1〜第3光触媒部材13,16,19によって構成されるので、生簀2が波や海流などによって揺動しても、各光触媒部材13,16,19が第1および第2索条10,11に対してずれてしまうことが防がれ、設置された範囲全体に均等に、しかも高密度で光触媒部材13,16,19を配置することができ、より高い水生生物の付着防止効果および殺菌効果を実現することができる。   According to the present embodiment, the plurality of first ropes 10 are bound by the plurality of second ropes 11, and the first photocatalytic member 13 is formed in a substantially cylindrical shape through which the first ropes 10 are inserted, and the first The two-photocatalyst member 16 has a substantially cylindrical base portion 25 through which the first rope 10 is inserted, and an engaging portion 26 provided on the base portion 25 and latched on the second rope 11, and the third photocatalyst member 19, a pair of substantially cylindrical main body portions 17a and 17b through which the second strip 11 is inserted, and the main body portions 17a and 17b are connected to each other in a state of being separated from each other in the axial direction. And a connecting portion 18 to be latched. Thus, since the photocatalyst member is composed of the first to third photocatalyst members 13, 16, and 19, each photocatalyst member 13, 16, and 19 is the first photocatalyst member even if the ginger 2 is swung by a wave or ocean current. And the second ropes 10 and 11 can be prevented from being displaced, and the photocatalyst members 13, 16 and 19 can be arranged evenly and at a high density in the entire installed range, and higher aquatic It is possible to realize the effect of preventing the attachment of organisms and the bactericidal effect.

また、前記第1光触媒部材13がセラミックスの焼結体から成るので、多数の光触媒部材を焼成炉等によって工業的に焼成し、容易にかつ安価に耐久性の高い光触媒部材を製造することができる。これによって、広範囲に構築された生簀であっても、低コストで水生生物の付着防止効果および殺菌効果を実現することができる。   In addition, since the first photocatalyst member 13 is made of a ceramic sintered body, a large number of photocatalyst members can be industrially fired in a firing furnace or the like, and a highly durable photocatalyst member can be easily manufactured at low cost. . Thereby, even if it is a ginger constructed | assembled extensively, the adhesion prevention effect and disinfection effect of aquatic organisms are realizable at low cost.

また、前記第1光触媒部材13がアルミニウム合金から成るので、多数の光触媒部材を金型成型によって製造することができる。このような金型成型は、光触媒部材の形状決定上の自由度が高く、表面の凹凸などの起伏を設けて受光面積を大きくし、光触媒機能を向上することができる。   Further, since the first photocatalyst member 13 is made of an aluminum alloy, a large number of photocatalyst members can be manufactured by molding. Such mold molding has a high degree of freedom in determining the shape of the photocatalyst member, and can provide undulations such as surface irregularities to increase the light receiving area and improve the photocatalytic function.

また、前記第2光触媒部材16が合成樹脂から成るので、射出成型などによって容易かつ安価に製造することができ、これによって製造コストを低減することができる。   Further, since the second photocatalyst member 16 is made of a synthetic resin, it can be easily and inexpensively manufactured by injection molding or the like, thereby reducing the manufacturing cost.

また、前記第3光触媒部材19が合成樹脂から成るので、射出成型またはブロー成型などによって容易かつ安価に製造することができ、これによって製造コストを低減することができる。   Further, since the third photocatalyst member 19 is made of a synthetic resin, it can be manufactured easily and inexpensively by injection molding or blow molding, thereby reducing the manufacturing cost.

本発明は、水中に設置される養殖網に限るものではなく、地上に構築される水槽であってもよく、同様な効果を達成することができる。   The present invention is not limited to an aquaculture net installed in water, and may be a water tank constructed on the ground, and the same effect can be achieved.

図8は本発明に他の実施形態の光触媒部材30を示す斜視図であり、図9は図8の切断面線IX−IXから見た断面図であり、図10は第1索条10に光触媒部材30を係止するための係止部31の構成を示す図である。本実施形態の光触媒部材30は、前述の第1〜第3光触媒部材13,16,19の少なくとも1つに代えて用いることができる。この光触媒部材30は、略円筒状の本体32と、本体32の軸線方向中央部に、本体32の軸線に関して半径方向外方に突出して一体的に形成される係止部31とを有する。このような光触媒部材30は、前述の第1〜第3光触媒部材13,16,19のうちのいずれか1つと同様な材料および製造方法によって製造することができる。   FIG. 8 is a perspective view showing a photocatalyst member 30 according to another embodiment of the present invention, FIG. 9 is a cross-sectional view taken along the section line IX-IX of FIG. 8, and FIG. It is a figure which shows the structure of the latching | locking part 31 for latching the photocatalyst member. The photocatalyst member 30 of the present embodiment can be used in place of at least one of the first to third photocatalyst members 13, 16, and 19 described above. The photocatalyst member 30 includes a substantially cylindrical main body 32 and a locking portion 31 that is integrally formed by projecting radially outward with respect to the axis of the main body 32 at the central portion in the axial direction of the main body 32. Such a photocatalyst member 30 can be manufactured by the same material and manufacturing method as any one of the first to third photocatalyst members 13, 16, and 19 described above.

前記係止部31は、第1索条10の撚りのピッチL11に対して1.1〜1.4倍の距離L12の間に複数、たとえば5つの係止爪33が等間隔に形成される2つの噛合片34,35が前記半径方向の内外に間隔をあけて設けられ、撚り合わされた第1索条10に確実に各噛合片34,35の係止爪33を噛合させ、光触媒部材30を第1索条10に係止することができる。この光触媒部材30は、取付け対象として、前記第1索条10に限るものではなく、第2索条11に対しても同様に係止することができる。係止部31を第1索条10または第2索条11に噛み込ませて係止するにあたっては、第1索条10または第2索条11の撚りを部分的に戻して素線を弛緩させ、その状態で各噛合片34,35間に挿入し、弛緩させた素線に再び撚りかけることによって、各噛合片34,35の係止爪33が第1索条10または第2索条11に噛合し、強固に係止させることができる。   The locking portion 31 has a plurality of, for example, five locking claws 33 formed at equal intervals between a distance L12 that is 1.1 to 1.4 times the twisting pitch L11 of the first rope 10. Two meshing pieces 34 and 35 are provided at intervals in the radial direction inside and outside, and the locking claws 33 of the meshing pieces 34 and 35 are surely meshed with the twisted first rope 10, and the photocatalytic member 30. Can be locked to the first rope 10. The photocatalyst member 30 is not limited to the first rope 10 as an attachment target, and can be similarly locked to the second rope 11. In engaging the locking portion 31 with the first cable 10 or the second cable 11 and locking it, the strands of the first cable 10 or the second cable 11 are partially returned to relax the wire. In this state, the engaging claw 33 of each of the meshing pieces 34 and 35 is inserted between the meshing pieces 34 and 35 and twisted again on the loosened wire. 11 and can be firmly locked.

このような光触媒部材30を用いることによって、前述の第1〜第3光触媒部材13,16,19と同様な効果が達成されるとともに、第1索条10または第2索条11に対するずれを係止部31によって防止することができる。   By using such a photocatalyst member 30, the same effects as those of the first to third photocatalyst members 13, 16, and 19 are achieved, and the displacement with respect to the first rope 10 or the second rope 11 is concerned. This can be prevented by the stop 31.

本発明の他の実施形態において、前記第1光触媒部材13は、光触媒機能を有する物質として酸化チタンを用いる場合には、基材にコーティングするに際して、300℃〜400℃で熱処理を行うため、前記基材は耐熱性を有する鉄板、またはアルミニウム合金版を用い、その表面を凹凸加工した上で略回転楕円体状に打抜き加工し、この打抜き加工した基材に前記コーティングによって光触媒層である外層片22a,22bを形成し、これらの外層片22a,22bを基部21の表面に前記接着剤によって接着することによって、前記第1光触媒部材13が形成されてもよい。また前記第2および第3光触媒部材16,19についても、前記他の実施形態の第1光触媒部材と同様な手法によって形成されてもよい。   In another embodiment of the present invention, when the first photocatalyst member 13 uses titanium oxide as a substance having a photocatalytic function, the first photocatalyst member 13 is subjected to a heat treatment at 300 ° C. to 400 ° C. when coating the substrate. The base material is a heat-resistant iron plate or an aluminum alloy plate, the surface of which is processed to have a rough surface and then punched into a substantially spheroidal shape, and the outer layer piece which is a photocatalytic layer by the coating on the punched base material The first photocatalytic member 13 may be formed by forming 22a and 22b and adhering these outer layer pieces 22a and 22b to the surface of the base 21 with the adhesive. The second and third photocatalyst members 16 and 19 may also be formed by the same method as the first photocatalyst member of the other embodiment.

本発明に実施の一形態の生簀環境改善装置1を示す斜視図である。1 is a perspective view showing a ginger environment improving apparatus 1 according to an embodiment of the present invention. 生簀環境改善装置1を生簀2に設置した状態を示す斜視図である。It is a perspective view which shows the state which installed the ginger environment improvement apparatus 1 in the ginger 2. FIG. 第1光触媒部材13の斜視図である。3 is a perspective view of a first photocatalyst member 13. FIG. 第1光触媒部材13の分解斜視図である。3 is an exploded perspective view of a first photocatalyst member 13. FIG. 第2光触媒部材16を示す斜視図である。It is a perspective view which shows the 2nd photocatalyst member 16. FIG. 第2光触媒部材16の背面図である。FIG. 5 is a rear view of the second photocatalyst member 16. 第3光触媒部材19を示す斜視図である。It is a perspective view which shows the 3rd photocatalyst member 19. FIG. 本発明に他の実施形態の光触媒部材30を示す斜視図である。It is a perspective view which shows the photocatalyst member 30 of other embodiment in this invention. 図8の切断面線IX−IXから見た断面図である。It is sectional drawing seen from the cut surface line IX-IX of FIG. 第1索条10に光触媒部材30を係止するための係止部31の構成を示す図である。It is a figure which shows the structure of the latching | locking part 31 for latching the photocatalyst member 30 to the 1st rope.

符号の説明Explanation of symbols

1 生簀環境改善装置
2 生簀
3 養殖網
5 浮子
10 第1索条
11 第2索条
13 第1光触媒部材
14 基部
15 係合部
16 第2光触媒部材
17a,17b 本体部分
18 連結部分
19 第3光触媒部材
20 挿通孔
21 基部
22a,22b 外層片
28 挿通孔
25 基部
26 係合部
27a,27b 係合片
30 光触媒部材
31 係止部
32 本体
33 係止部
34,35 噛合片
DESCRIPTION OF SYMBOLS 1 Ginger environment improvement apparatus 2 Ginger 3 Aquaculture net 5 Float 10 First rope 11 Second rope 13 First photocatalyst member 14 Base 15 Engagement part 16 Second photocatalyst member 17a, 17b Body part 18 Connection part 19 Member 20 Insertion hole 21 Base part 22a, 22b Outer layer piece 28 Insertion hole 25 Base part 26 Engagement part 27a, 27b Engagement piece 30 Photocatalyst member 31 Engagement part 32 Main body 33 Engagement part 34, 35 Engagement piece

Claims (8)

索条と、
索条が挿通され、基材の表面に光触媒機能を有する物質を含む光触媒層が設けられる略円筒状の複数の光触媒部材とを含むことを特徴とする生簀環境改善装置。
The striated wire,
A ginger environment improving apparatus comprising: a plurality of substantially cylindrical photocatalyst members each having a strip inserted therein and provided with a photocatalyst layer containing a substance having a photocatalytic function on a surface of a base material.
前記索条は、予め定める第1方向に相互に間隔をあけて配置される複数の第1索条と、前記第1方向に交差する第2方向に相互に間隔をあけて配置され、各第1索条に結束される複数の第2索条とを含み、
前記光触媒部材は、第1索条が挿通する略円筒状の基部と、基部に設けられ、第2索条に掛け止められる係合部とを有することを特徴とする請求項1に記載の生簀環境改善装置。
The strips are arranged at intervals in a second direction intersecting the first direction, and a plurality of first strands arranged in a predetermined first direction at intervals. Including a plurality of second strands bound to one strand,
2. The ginger according to claim 1, wherein the photocatalyst member has a substantially cylindrical base portion through which the first rope is inserted, and an engagement portion provided at the base portion and hooked to the second rope. Environmental improvement device.
前記索条は、予め定める第1方向に相互に間隔をあけて配置される複数の第1索条と、前記第1方向に交差する第2方向に相互に間隔をあけて配置され、各第1索条に結束される複数の第2索条とを含み、
前記光触媒部材は、第2索条が挿通する略円筒状の一対の本体部分と、各本体部分を相互に軸線方向に離間させた状態で連結し、第1索条に掛け止められる連結部分とを有することを特徴とする請求項1に記載の生簀環境改善装置。
The strips are arranged at intervals in a second direction intersecting the first direction, and a plurality of first strands arranged in a predetermined first direction at intervals. Including a plurality of second strands bound to one strand,
The photocatalyst member is connected to a pair of substantially cylindrical main body portions through which the second strips are inserted, a connecting portion that is connected to each other with the main body portions spaced apart from each other in the axial direction, and is hooked to the first strips. The ginger environment improving apparatus according to claim 1, wherein
前記索条は、予め定める第1方向に相互に間隔をあけて配置される複数の第1索条と、前記第1方向に交差する第2方向に相互に間隔をあけて配置され、各第1索条に結束される複数の第2索条とを含み、
前記光触媒部材は、
第1索条が挿通される略円筒状の第1光触媒部材と、
前記第1索条が挿通する略円筒状の基部と、基部に設けられ、第2索条に掛け止められる係合部とを有する第2光触媒部材と、
第2索条が挿通する略円筒状の一対の本体部分と、各本体部分を相互に軸線方向に離間させた状態で連結し、第1索条に掛け止められる連結部分とを有する第3光触媒部材とを含むことを特徴とする請求項1に記載の生簀環境改善装置。
The strips are arranged at intervals in a second direction intersecting the first direction, and a plurality of first strands arranged in a predetermined first direction at intervals. Including a plurality of second strands bound to one strand,
The photocatalyst member is
A substantially cylindrical first photocatalytic member into which the first rope is inserted;
A second photocatalyst member having a substantially cylindrical base portion through which the first strip is inserted, and an engaging portion provided on the base portion and latched on the second strip;
A third photocatalyst having a pair of substantially cylindrical main body portions through which the second rope is inserted, and a coupling portion that connects the main body portions while being spaced apart from each other in the axial direction and is latched on the first rope. The ginger environment improving apparatus according to claim 1, further comprising a member.
前記第1光触媒部材は、セラミックスの焼結体から成ることを特徴とする請求項4に記載の生簀環境改善装置。   5. The ginger environment improving apparatus according to claim 4, wherein the first photocatalyst member is made of a ceramic sintered body. 前記第1光触媒部材は、アルミニウム合金から成ることを特徴とする請求項4に記載の生簀環境改善装置。   The ginger environment improving device according to claim 4, wherein the first photocatalyst member is made of an aluminum alloy. 前記第2光触媒部材は、合成樹脂から成ることを特徴とする請求項4〜6のいずれか1つに記載の生簀環境改善装置。   The ginger environment improving device according to any one of claims 4 to 6, wherein the second photocatalytic member is made of a synthetic resin. 前記第3光触媒部材は、合成樹脂から成ることを特徴とする請求項4〜7のいずれか1つに記載の生簀環境改善装置。

The ginger environment improving device according to any one of claims 4 to 7, wherein the third photocatalyst member is made of a synthetic resin.

.
JP2008178490A 2008-07-08 2008-07-08 Environment improving device for crawl Pending JP2010017103A (en)

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Publication number Priority date Publication date Assignee Title
JP6903811B1 (en) * 2020-12-08 2021-07-14 マルハニチロ株式会社 Fish cage
JP2022055516A (en) * 2020-09-29 2022-04-08 和光技研株式会社 Culture service water sterilization tool

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006149363A (en) * 2004-11-08 2006-06-15 Kiyoshi Kato Photocatalytic sterilization net
JP2007151497A (en) * 2005-12-07 2007-06-21 Kiyoshi Kato Decorating tool for cleaning underwater environment and method for producing the same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006149363A (en) * 2004-11-08 2006-06-15 Kiyoshi Kato Photocatalytic sterilization net
JP2007151497A (en) * 2005-12-07 2007-06-21 Kiyoshi Kato Decorating tool for cleaning underwater environment and method for producing the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022055516A (en) * 2020-09-29 2022-04-08 和光技研株式会社 Culture service water sterilization tool
JP6903811B1 (en) * 2020-12-08 2021-07-14 マルハニチロ株式会社 Fish cage
JP2022090823A (en) * 2020-12-08 2022-06-20 マルハニチロ株式会社 Fish preserve

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