JP2010014851A5 - - Google Patents

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Publication number
JP2010014851A5
JP2010014851A5 JP2008173122A JP2008173122A JP2010014851A5 JP 2010014851 A5 JP2010014851 A5 JP 2010014851A5 JP 2008173122 A JP2008173122 A JP 2008173122A JP 2008173122 A JP2008173122 A JP 2008173122A JP 2010014851 A5 JP2010014851 A5 JP 2010014851A5
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Japan
Prior art keywords
magnetic carrier
particles
resin composition
fine particles
coating
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JP2008173122A
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Japanese (ja)
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JP2010014851A (en
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Priority to JP2008173122A priority Critical patent/JP2010014851A/en
Priority claimed from JP2008173122A external-priority patent/JP2010014851A/en
Publication of JP2010014851A publication Critical patent/JP2010014851A/en
Publication of JP2010014851A5 publication Critical patent/JP2010014851A5/ja
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Claims (6)

性コア粒子の表面に樹脂組成物の被覆層を有する磁性キャリアであって、前記磁性キャリアが、下記の関係式(A)を満足することを特徴とする磁性キャリア。
700≦Et100(mJ)≦950・・・・・(A)
[前記式(A)におけるEt100(mJ)は、回転式ブレードを備えた粉体流動性分析装置において、プロペラ型ブレードの最外縁部の周速を100mm/secで回転させながら前記磁性キャリアが満たされた測定容器内の磁性キャリア粉体層中に垂直に侵入させ、前記粉体層の底面から100mmの位置から測定を開始し、底面から10mmの位置までブレードを進入させた時に得られる、回転トルクと垂直荷重の総和を表している。]
A magnetic carrier having a coating layer on the surface in the resin composition of the magnetic core particles, the magnetic carrier and the magnetic carrier, and satisfies the following relational expression (A).
700 ≦ Et100 (mJ) ≦ 950 (A)
[Et100 (mJ) in the above formula (A) is a powder flowability analyzer equipped with a rotary blade, and the magnetic carrier is filled while rotating the peripheral speed of the outermost edge of the propeller blade at 100 mm / sec. Rotation obtained by vertically intruding into the magnetic carrier powder layer in the measured container, starting measurement from a position of 100 mm from the bottom surface of the powder layer, and entering the blade to a position of 10 mm from the bottom surface. Represents the sum of torque and vertical load. ]
前記磁性キャリアは、フロー式粒子像分析装置で測定される円形度分布において、円形度0.950以下の粒子の存在率が、2.0個数%以下であることを特徴とする請求項1に記載の磁性キャリア。 2. The magnetic carrier according to claim 1, wherein the abundance ratio of particles having a circularity of 0.950 or less is 2.0% by number or less in a circularity distribution measured by a flow particle image analyzer. The magnetic carrier described. 前記被覆層は、微粒子を含有し、前記微粒子の個数平均粒径が80nm以上300nm以下であることを特徴とする請求項1または2に記載の磁性キャリア。 The magnetic carrier according to claim 1, wherein the coating layer contains fine particles, and the number average particle diameter of the fine particles is 80 nm or more and 300 nm or less. 前記微粒子が、ゾルゲル法により製造されたシリカ微粒子を含有することを特徴とする請求項3に記載の磁性キャリア。 The magnetic carrier according to claim 3, wherein the fine particles contain silica fine particles produced by a sol-gel method. 前記磁性キャリアは、前記樹脂組成物を磁性コア粒子の表面に被覆処理した粒子の表面に、被覆処理装置を用いて、前記微粒子を固着処理して形成された前記被覆層を有するものであり、
該被覆処理装置は、複数の攪拌部材が表面に設置された回転体と、前記攪拌部材に対して間隙を隔てて位置する内周部を有したケーシングとを備えており、前記複数の攪拌部材のうちの一部の攪拌部材により、前記樹脂組成物を磁性コア粒子の表面に被覆処理した粒子と前記微粒子とが、前記回転体の軸方向の一方向に送られる、送りと、前記複数の攪拌部材のうちの他の一部の攪拌部材により、前記樹脂組成物を磁性コア粒子の表面に被覆処理した粒子と前記微粒子とが、前記回転体の軸方向の前記一方向とは逆の方向に戻される、戻し、とが行われることによって、固着処理ることを特徴とする請求項3または4に記載の磁性キャリア。
The magnetic carrier has the coating layer formed by fixing the fine particles on the surface of the particles obtained by coating the resin composition on the surface of the magnetic core particles using a coating processing apparatus,
The coating apparatus is provided with a rotating body in which a plurality of agitating members are disposed on the surface, and a casing having an inner periphery which is located at a gap with respect to the agitating member, said plurality of agitating members by a part of the agitating member of the resin composition and the a particles coated treated surface of the magnetic core particles particles, Ru sent in one direction in the axial direction of the rotating body, and feeding said plurality The particles obtained by coating the resin composition on the surface of the magnetic core particles by the other part of the stirring members of the stirring members and the fine particles are opposite to the one direction in the axial direction of the rotating body. passed back in a direction, returning, by the city is performed, the magnetic carrier according to claim 3 or 4, wherein that you fixing process.
前記樹脂組成物は、下記式(A1)で示される構造を有するモノマーと、下記式(A2)又は下記式(A3)で示される構造を有するマクロモノマーとを共重合成分とする共重合体を含有する樹脂組成物であることを特徴とする請求項1乃至5のいずれか1項に記載の磁性キャリア。
Figure 2010014851
Figure 2010014851
Figure 2010014851
Figure 2010014851
Figure 2010014851
The resin composition comprises a copolymer having a monomer having a structure represented by the following formula (A1) and a macromonomer having a structure represented by the following formula (A2) or the following formula (A3) as a copolymerization component. magnetic carrier according to any one of claims 1 to 5, characterized in that a resin composition containing.
Figure 2010014851
Figure 2010014851
Figure 2010014851
Figure 2010014851
Figure 2010014851
JP2008173122A 2008-07-02 2008-07-02 Magnetic carrier and image forming method using the magnetic carrier Pending JP2010014851A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008173122A JP2010014851A (en) 2008-07-02 2008-07-02 Magnetic carrier and image forming method using the magnetic carrier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2008173122A JP2010014851A (en) 2008-07-02 2008-07-02 Magnetic carrier and image forming method using the magnetic carrier

Publications (2)

Publication Number Publication Date
JP2010014851A JP2010014851A (en) 2010-01-21
JP2010014851A5 true JP2010014851A5 (en) 2011-08-11

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5473642B2 (en) * 2010-02-03 2014-04-16 キヤノン株式会社 Magnetic carrier and two-component developer
JP5540775B2 (en) * 2010-03-04 2014-07-02 富士ゼロックス株式会社 Electrostatic image developing carrier, electrostatic image developing developer, toner cartridge, process cartridge, and image forming apparatus
JP5549865B2 (en) * 2010-06-25 2014-07-16 株式会社リコー Coating coating solution for coating core material of electrophotographic carrier
JP5935424B2 (en) * 2012-03-19 2016-06-15 富士ゼロックス株式会社 Electrostatic charge image developing carrier, electrostatic charge image developing developer, toner cartridge, process cartridge, image forming apparatus, and image forming method
JP7106956B2 (en) * 2018-04-10 2022-07-27 富士フイルムビジネスイノベーション株式会社 Developer, developer manufacturing method, and image forming apparatus

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JP4121252B2 (en) * 2001-03-27 2008-07-23 株式会社リコー Electrostatic latent image developing carrier, developer, developing method and developing apparatus using the same
JP4590303B2 (en) * 2004-05-13 2010-12-01 キヤノン株式会社 Magnetic material-containing resin carrier and two-component developer
JP2007114766A (en) * 2005-09-21 2007-05-10 Fuji Xerox Co Ltd Developer for developing electrostatic charge image and image forming method
JP2007286092A (en) * 2006-04-12 2007-11-01 Fuji Xerox Co Ltd Carrier for electrostatic latent image development and developer for electrostatic latent image development
JP2007328035A (en) * 2006-06-06 2007-12-20 Fuji Xerox Co Ltd Electrostatic charge image developer, image forming method and device
JP2007328277A (en) * 2006-06-09 2007-12-20 Fuji Xerox Co Ltd Electrostatic latent image developing carrier and developer for electrostatic latent image development

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