JP2010005516A - Penetration type purification method for soil, river, and polluted water - Google Patents
Penetration type purification method for soil, river, and polluted water Download PDFInfo
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- JP2010005516A JP2010005516A JP2008166432A JP2008166432A JP2010005516A JP 2010005516 A JP2010005516 A JP 2010005516A JP 2008166432 A JP2008166432 A JP 2008166432A JP 2008166432 A JP2008166432 A JP 2008166432A JP 2010005516 A JP2010005516 A JP 2010005516A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/20—Sludge processing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Abstract
Description
本発明は、地球環境の保全のための汚染土壌・屁泥・汚濁水の自然循環機能を活用した浄化を
目的とする環境技術に関する。
The present invention relates to an environmental technology for purifying by utilizing a natural circulation function of contaminated soil, sludge, and polluted water for the preservation of the global environment.
従来の環境汚染物の浄化法は、おおむね積極物理的な浄化法である。 この欠点は、環境改善に多くの資源・エネルギーが必要でその実施コストも巨額である。 これらは地球環境維持に自然循環の法則適用手段が最適であると最近注目され始めたが、実施技術がなく、従来は物理的以外方法がなかった。 Conventional purification methods for environmental pollutants are generally positive physical purification methods. The disadvantage is that it requires a lot of resources and energy to improve the environment and its implementation cost is huge. These have recently begun to attract attention that the means of applying the laws of natural circulation are optimal for maintaining the global environment, but there is no implementation technique and there has been no method other than physical in the past.
環境汚染物の土壌汚染、河川・湖の汚泥の自然循環浄化は周期を考慮すれば、有機物を微生物分解して植物に吸収させる光・水による地表循環と、高温・高圧での長期間の深層地下による物質の安定化の2つの法則がある。何れも水を媒体とすることから、これらの技術基本となる水の浸透を得るための手段である透水管、高圧深層地下注水管の開発が重要である。 Considering the cycle of soil contamination of environmental pollutants and natural circulation purification of sludge in rivers and lakes, surface circulation with light and water that decomposes organic matter into microorganisms and absorbs them into plants, and long-term deep layers at high temperature and high pressure There are two laws of material stabilization by underground. Since all use water as a medium, it is important to develop a permeation pipe and a high-pressure deep underground water injection pipe, which are means for obtaining water penetration, which is the basis of these technologies.
本発明は自然循環法則を利用した汚染土壌・汚泥・汚染水の浄化法の技術開発に成功した。 この基本技術の構成は、有機物汚染土壌が浸透水による微生物分解・植物吸収、非分解物質が浸透水による洗浄と汚染物の深層地下へ注入、これら手段が当社の熟知する油田の原油生産技術”残留石油の回収技術”に類似であることから、油田技術を応用した技術開発を実施した。 The present invention has succeeded in developing a technology for purifying contaminated soil, sludge, and contaminated water using the law of natural circulation. The basic technology consists of organic polluted soil with microbial degradation and plant absorption by permeated water, non-degraded material washed with permeated water and injecting the pollutant into the deep underground. Since it is similar to “residual oil recovery technology”, technology development applying oilfield technology was implemented.
本発明の成果は、自然循環法則の短期循環法則である有機物の微生物分解と植物吸収の浄化法や、他の長期(1万年から100万年)循環の深層地下での有害化学物質の安定分解(無機化)などを可能にする方法である。その結果、従来の地上による積極分解などの手段に比べて大幅なコスト軽減と二次的汚染処理問題も解消することが判明した。
The achievements of the present invention include the microbial degradation of organic matter and the plant absorption purification method, which are short-term circulation laws of the natural circulation law, and other long-term (10,000 to 1,000,000 years) circulation of harmful chemical substances in the deep underground. It is a method that enables decomposition (mineralization) and the like. As a result, it was found that significant cost reduction and secondary pollution treatment problems can be resolved compared to conventional means such as active decomposition on the ground.
環境保全に関する本発明の汚染土壌・屁泥・汚濁水の浸透式浄化法および使用する透水管・高圧注水管について説明する。環境汚染は気体・液体・固体に分別されるが、それぞれ汚染物質の移動を考慮すれば液体と固体(水・土壌)は共通の浄化手段が取れる。地球上の物質は多くは水を媒体にできることから、水を基本として処理法を考えることにする。河川・湖・土壌の社会的認知度の高い事例を考える。中国の下水処理が未完成なことが原因の主に有機物による河川の汚染例、その排出先が湖などの場合は過剰な有機物の堆積からその扶養分による毒性があるアオコの多量発生、農家の蓄積する農薬による地下汚染、化学工場などの廃棄化学物質による地下汚染などがある。 The permeation purification method for contaminated soil, sludge, and polluted water according to the present invention relating to environmental conservation and the permeation pipe and high-pressure water injection pipe used will be described. Environmental pollution is separated into gas, liquid, and solid, but liquid and solid (water and soil) can take common purification measures if the movement of pollutants is considered. Since many substances on the earth can use water as a medium, we will consider treatment methods based on water. Consider cases with high social awareness of rivers, lakes and soils. Examples of pollution of rivers mainly due to organic matter due to incomplete sewage treatment in China, and when the discharge destination is lakes, etc. There are underground pollution due to accumulated pesticides and underground pollution due to waste chemicals from chemical factories.
これらの汚染解消には、汚染源を絶つ方法が最も有効であることは周知であるが、既に堆積した汚染物を自然分解するには、歴史的な時間を要する。一方、自然による植物・微生物の堆積もあることも周知。本発明は、自然の浄化機能を用いた地球環境保全が図れる人工的なシステムを考案した。このシステムの基本は、自然循環の浄化(1年サイクル)と非循環・過剰環境物質の深層地下での長期間分解(100万年単位の分解)から成る。 It is well known that the method of eliminating the pollution source is the most effective for eliminating these pollutions, but it takes a historical time to naturally decompose the already accumulated contaminants. On the other hand, it is also well known that there are also plant and microorganism deposits due to nature. The present invention has devised an artificial system that can protect the global environment using a natural purification function. The basis of this system consists of the purification of natural circulation (one year cycle) and the long-term decomposition of non-circulating / excess environmental substances in the deep underground (one million year decomposition).
有機物の微生物・植物による自然循環浄化法則の詳細について下記に示す。
Details of the law for natural circulation purification of organic matter by microorganisms and plants are shown below.
図1は、有機物汚泥を集積した堆積層に有酸素水を添加して微生物による汚泥の分解による窒素、燐酸、炭酸ガスなどの植物養分を放出し、植物には太陽光と水を与えて、葉緑素による働きで植物成長を図ることで自然循環浄化法則を促進させるモデルを示す。自然浄化効率は、植物とのコラボレーション効果が最も
効率的であることは、多くの研究者によって、実証されており、効率UPができる構造が重要となる。自然界の湖底に集積する汚泥物質は、微生物分解が出来ず湖底が無酸素状態となっている。汚染河川はこの状態を示している。また、湖の汚染は微生物による汚泥の分解が多くて、水中の養分過多が原因で水中直物のアオコの異常発生を生じている。すなわち、効率的な自然循環浄化を得るには、地上植物とのコラボレーションが不可欠といえる。このコラボレーションには、図1の右図に示す透水壁による汚水・汚泥との分離方式が効果的である。
Figure 1 shows the addition of aerobic water to the sedimentary layer where organic sludge is accumulated to release plant nutrients such as nitrogen, phosphoric acid, and carbon dioxide by the decomposition of sludge by microorganisms. A model that promotes the natural circulation purification law by promoting plant growth by the action of chlorophyll. The efficiency of natural purification has been proven by many researchers that the collaboration effect with plants is the most efficient, and a structure that can improve efficiency is important. The sludge material that accumulates on the lake bottom in nature cannot be decomposed by microorganisms and the bottom of the lake is in anoxic state. Contaminated rivers indicate this condition. In addition, the pollution of the lake is caused by the decomposition of sludge by microorganisms, and the abnormal occurrence of water fish in the water is caused by excessive nutrients in the water. In other words, it can be said that collaboration with above-ground plants is indispensable for efficient natural circulation purification. For this collaboration, the separation method of sewage and sludge by the permeable wall shown in the right figure of FIG. 1 is effective.
短期間に汚泥と汚水をポンプアップして透水壁の隔離部に移動、汚泥の圧縮と浄化水・浄化湖底が生成できる。(浄化が短時間で完工する)堆積汚泥に活性有酸素水を通過させることで、微生物が活性化されて分解養分は上部の植物に吸収される。(自然循環の浄化が始まる)浄化水の水位変化で有酸素水が汚泥に浸入、透水壁に付着する微生物の働きも加わり汚泥の浄化と湖水をより清水とする浄化作用が働く。透水壁を管状構造物にすれば、強固な壁面が得られる。さらに必要な場合には管の内部に活性炭など入れることで、初期の汚水浄化と微生物の活性化をもたらす。汚泥の分解が進行するに従い、追加汚泥の上部堆積ができる。また汚泥には上部から有酸素水である河川の引き込みなどは更なる効果を誘発させる。以上から、人工的な有機物の微生物・植物によるコラボレーション自然循環浄化法は、透水管による汚泥の集積と集積時の浄化、時間を掛けた汚泥の分解できる人工構造が提供できる。
In a short period of time, sludge and sewage can be pumped up and moved to the isolation part of the permeable wall, and sludge compression and purified water / purified lake bottom can be generated. By passing the active aerobic water through the deposited sludge (the purification is completed in a short time), the microorganisms are activated and the decomposed nutrients are absorbed by the upper plant. The change in the water level of purified water (starting the purification of natural circulation) enters the sludge and the action of microorganisms adhering to the permeable wall is also added, purifying the sludge and purifying the lake water. If the permeable wall is a tubular structure, a strong wall surface can be obtained. In addition, if necessary, activated carbon or the like is placed inside the tube, which leads to initial purification of sewage and activation of microorganisms. As sludge decomposition progresses, additional sludge can be deposited on top. In addition, the sludge draws a river that is aerobic water from the top, and induces further effects. From the above, the collaborative natural circulation purification method using microorganisms and plants of artificial organic matter can provide an artificial structure that can accumulate sludge with a permeation pipe, purify it during accumulation, and decompose sludge over time.
透水法による湖の汚泥浄化法の実施(透水浄化島の建設)について下記に示す。
The implementation of the lake sludge purification method (construction of a permeable purification island) by the permeable method is shown below.
図2は、透水法による湖の浄化島建設概要図である。基本構造は、図1の人工構造を採用した透水管を用いた人工浄化島建設概要図である。特徴は、汚泥・汚水を集積できる。別の場所に移動する必要がない。工期が短く、汚泥処理後には人工島としての不動産価値を生む。大規模な湖にも適用できる。特に浅い湖低には有効で植林による炭酸ガスの吸収効果も大きく、実用性が高い。人工島表面には、ガラス繊維と発泡プラスチックビーズからなる浮き表面層に植物を設けることが効果的である。なぜなら、植物の根が十分な固定を必要とすること、汚泥の分解と沈下にフロート機能がてきすることからである。人工島には、有酸素水でもある河川水をポンプ輸送して汚水の常時散布投入も可能である。すなわち、下水処理効果も期待できる。なお、人工島の大きさは、約10メートルから100メートル径が適当。人工島には風車による空圧ポンプによる汚泥への酸素供給も効果を発揮する。
FIG. 2 is a schematic diagram of the construction of the purification island of the lake by the permeability method. The basic structure is an outline diagram of the construction of an artificial purification island using a water permeable pipe employing the artificial structure of FIG. The feature is that sludge and sewage can be accumulated. There is no need to move to another location. The construction period is short, and after the sludge treatment, real estate value as an artificial island is created. Applicable to large lakes. It is especially effective for shallow lakes and has a large carbon dioxide absorption effect by afforestation, making it highly practical. It is effective to provide a plant on a floating surface layer made of glass fibers and foamed plastic beads on the surface of the artificial island. This is because the roots of plants need sufficient fixation, and the float function comes to the decomposition and settlement of sludge. On the artificial island, river water, which is also aerobic water, can be pumped and sewage can be constantly sprayed. That is, a sewage treatment effect can be expected. The size of the artificial island should be about 10 to 100 meters. On the artificial island, oxygen supply to sludge by pneumatic pumps with windmills is also effective.
分解化学物質の透水洗浄と深層地下への注入について下記に示す。
The following shows the water-permeable cleaning of the chemical decomposition and injection into the deep underground.
微生物・植物による自然循環浄化ができない化学物質は、透水洗浄法を用いて土壌洗浄を行う。 この方法には、有効な汚染化学物質を洗浄する界面活性剤・酸化凝集剤・その他付着剤などを併用する。図3は地中の汚染土壌に洗浄水の注水と透水管による抽出化学物質の排出と汚染物質の深層地下への注入の概略断面図である。土壌浄化は基本的には、潜在する化学物質は水溶性と見なせることから、洗浄は可能である。 洗浄には特定する汚染物質に効果がある物質を注入して、浸透による洗浄を行う。洗浄は縦型の排水と横型の排水があるが、何れも目的に応じて使用する。地中に含まれる有機ガスなどの補足には、地表にシートの付設で必要期間中回収する。 回収された化学物質の固形分を除去して深層地下での安定化に必要な薬剤を混合して高圧注入する。選択される深層地下の深さは、地域によってこと成るが、安定地盤の下とする。一般には700メートル以下(アメリカの例)が適当と思われる。これらの浸透洗浄・深層地下注入による地中汚染の方法は、次の特徴がある。
For chemical substances that cannot be circulated and purified by microorganisms and plants, wash the soil using a water-permeable cleaning method. In this method, a surfactant, an oxidizing flocculant, and other adhesives for cleaning effective pollutant chemical substances are used in combination. FIG. 3 is a schematic cross-sectional view of injection of washing water into the underground contaminated soil, discharge of the extracted chemical substance through the permeation pipe, and injection of the pollutant into the deep underground. Soil cleanup is basically possible because potential chemicals can be considered water-soluble. For cleaning, inject a substance effective for the specified pollutant and perform cleaning by infiltration. There are two types of cleaning, vertical drainage and horizontal drainage, both of which are used depending on the purpose. For supplementation of organic gas contained in the ground, a sheet is attached to the ground surface and collected for the required period. Remove the solid content of the collected chemicals, mix the chemicals necessary for stabilization in the deep underground, and inject high pressure. The depth of the deep underground selected will depend on the area, but below the stable ground. In general, 700 meters or less (American example) seems appropriate. These methods of underground pollution by infiltration and deep underground injection have the following characteristics.
自然循環浄化を地表環境で行わない。地下の高温・高圧条件で超時間を掛けて安定化を行う。従来の物理的な土壌の掘削・移動・処理を伴わないため、二次公害を出さない。工事が大掛かりではなく、廃棄物が出ない。何より工事費が安価となる。工期を短縮することが可能であるが、洗浄中にも別の建設工事を併用できる。また既存の建築物を損なうことなく洗浄・浄化できる。以上から、この透水式の透過洗浄法はきわめてメリットが大きい地中浄化方法といえる。
Natural circulation purification is not performed in the surface environment. Stabilize over a long time under high temperature and high pressure conditions underground. Because it does not involve conventional excavation, movement and treatment of physical soil, it does not cause secondary pollution. Construction is not overwhelming and no waste is generated. Above all, the construction cost is low. The construction period can be shortened, but another construction work can be used during cleaning. It can also be cleaned and purified without damaging existing buildings. From the above, this permeable permeation cleaning method can be said to be an underground purification method with great merit.
抽出された化学物質は、図4に示すように耐食高圧管により安定化地盤下に注入される。 一般には最大2300メートル以下が予想される。 関東地方では 1500メートルから2000メートルが適当と考えるが、詳細地質調査によって決定される。 抽出化学物質は地表タンクに集められ、安定化の物質を混合、固体物質を取り除いて高圧ポンプ(10メガパスカルから15メガパスカル)で注入する。深層地下に注入された化学物質は、100万年程度保留される。すなわち、化石燃料を抽出した石油の生産と反対の地表環境に余剰な物質の地下への返却を意味する。地下注入は炭酸ガス、核物質、劇物など適用しているので、地質調査によりその深度が定められる。この深層地下への化学物質の注入方式による特徴は次の通りである。
The extracted chemical substance is injected below the stabilized ground by a corrosion-resistant high-pressure tube as shown in FIG. Generally, a maximum of 2300 meters or less is expected. In the Kanto region, 1500 to 2000 meters is considered appropriate, but it is determined by a detailed geological survey. Extracted chemicals are collected in a surface tank, mixed with stabilizing materials, solid materials are removed and injected with a high pressure pump (10 to 15 megapascals). The chemicals injected into the deep underground are reserved for about 1 million years. In other words, it means the return of surplus material to the underground environment opposite to the production of oil from which fossil fuel is extracted. Underground injection uses carbon dioxide, nuclear material, deleterious substances, etc., and its depth is determined by geological survey. The characteristics of this chemical injection method into the deep underground are as follows.
約700メートル以下の深層地下で廃棄物処理(安定化)できる。必要技術は油田技術が応用できる。汚染物の拡散防止が地下水圧の利用で簡単にできる。油田の注水技術と注水における環境に影響度がない等、多くの実績を活用できる。洗浄水は海水・工業用水など採用、地下で注入 水を洗浄して復流水の活用の可能性もある。その他の炭酸ガスを併用注入も可能である。透水管の付設、高圧注入管の付設をした後は自動で透水洗浄できるため、安価で簡単な工事である。
Waste can be treated (stabilized) in the deep underground below about 700 meters. Oilfield technology can be applied as necessary technology. Preventing the diffusion of contaminants can be done easily by using groundwater pressure. Many achievements can be utilized, such as no impact on the oil injection technology and the environment of water injection. Washing water such as seawater and industrial water is used, and there is a possibility of using the return water by washing the injected water underground. Other carbon dioxide can also be used in combination. After installing a water permeable pipe and a high pressure injection pipe, it can be automatically washed with water, making it cheap and simple.
土壌汚染の浸透式処理法の効率的実施システムについて下記に示す。
The following shows an efficient implementation system for the permeation treatment method for soil contamination.
土壌汚染の効率的な浄化には、コンピュータによるシミュレーションシステムの開発が必要である。 このシステムは、3次元の画像処理を含めた洗浄に関する解析である。現在稼働している医療画像処理システムなどは血液の血流を加味したシステムであり、応用できる。本発明は医療画像処理システムと油田の採油システムと同様な考えで、このシステムを進める。図5は 土壌汚染現場の最適透水法を設計するためのモデル説明である。破線は汚染土壌域を示し、●印は注水による汚染地域への地下水流入防止の注水透水管平面位置を示す。矢印は汚染物質の浸透方向を示す。
For efficient purification of soil contamination, it is necessary to develop a computer simulation system. This system is an analysis related to cleaning including three-dimensional image processing. The medical image processing system currently in operation is a system that takes into account the blood flow of blood and can be applied. The present invention advances this system with the same idea as a medical image processing system and an oil field extraction system. FIG. 5 is a model explanation for designing an optimum water permeability method for soil contaminated sites. The broken line indicates the contaminated soil area, and the ● mark indicates the plane position of the water injection permeation pipe to prevent the inflow of groundwater into the contaminated area. Arrows indicate the direction of contaminant penetration.
(1)透水管による注水による水圧カーテンを示す。 (2)は品種Bの化物質の洗浄注入、(4)は化学物質Aの洗浄抽出をそれぞれ示す。(3)は水圧カーテンによる汚染物質の洗浄ラインの状態、(5)は化学物質Cの抽出を示す。(6)は抽出した化学物質の深層地下への高圧注入を示す。図から、複数の濃度分布を持つ異なる化学物質に対して、それぞれ有効な複数の濃度分布を持つ。この効率的な生産システムはコンピュータ解析によって最適な圧力と位置・深さが計算できる。また、除染時間と濃度の予測も可能である。最適な注水位置と圧力、排水位置と圧力、有効な洗浄添加剤の効果など計算する必要があり、このシステムは効率的な除染には非常に有効である。
(1) A hydraulic curtain by water injection with a permeable pipe is shown. (2) shows cleaning injection of a chemical substance of type B, and (4) shows cleaning extraction of chemical substance A. (3) shows the state of the pollutant cleaning line by the hydraulic curtain, and (5) shows the extraction of the chemical substance C. (6) shows high-pressure injection of the extracted chemical into the deep underground. From the figure, there are a plurality of effective concentration distributions for different chemical substances having a plurality of concentration distributions. This efficient production system can calculate the optimal pressure, position and depth by computer analysis. It is also possible to predict decontamination time and concentration. It is necessary to calculate the optimal water injection position and pressure, drainage position and pressure, the effect of effective cleaning additives, etc. This system is very effective for efficient decontamination.
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CN103183458A (en) * | 2011-12-30 | 2013-07-03 | 天津生态城环保有限公司 | Processing method of heavy metal-contaminated sediment |
CN111233156A (en) * | 2018-11-29 | 2020-06-05 | 浙江问源环保科技股份有限公司 | Hard-substrate eutrophic water body treatment method and planting carrier |
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CN103183458A (en) * | 2011-12-30 | 2013-07-03 | 天津生态城环保有限公司 | Processing method of heavy metal-contaminated sediment |
CN111233156A (en) * | 2018-11-29 | 2020-06-05 | 浙江问源环保科技股份有限公司 | Hard-substrate eutrophic water body treatment method and planting carrier |
CN111233156B (en) * | 2018-11-29 | 2024-01-30 | 浙江问源环保科技股份有限公司 | Hard substrate eutrophic water treatment method and planting carrier |
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