JP2009297085A - Liquid cosmetic container - Google Patents

Liquid cosmetic container Download PDF

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JP2009297085A
JP2009297085A JP2008151952A JP2008151952A JP2009297085A JP 2009297085 A JP2009297085 A JP 2009297085A JP 2008151952 A JP2008151952 A JP 2008151952A JP 2008151952 A JP2008151952 A JP 2008151952A JP 2009297085 A JP2009297085 A JP 2009297085A
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liquid cosmetic
water
sealing plug
liquid
time
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JP5118559B2 (en
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Koichi Ishida
行一 石田
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Tokiwa Corp
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Tokiwa Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a liquid cosmetic container capable of preventing the leakage of a liquid cosmetic in a period before the time of starting use for the first time by a simple configuration. <P>SOLUTION: While the leakage of the liquid cosmetic L in the period before the time of starting the use for the first time is prevented by a sealing plug 10 provided on the side of the opening 7d of a flow path 7c by dissolving a water-soluble polymer in water and evaporating moisture, the liquid cosmetic L extruded by an operation by a user is made to enter many fine holes in the sealing plug 10 and a large part of the sealing plug 10 is brought into contact with the liquid cosmetic L at the start of the use for the first time. As a result, the entire sealing plug 10 is softened and easily extruded together with the liquid cosmetic L and the use for the first time is made possible. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、液状化粧料容器に関する。   The present invention relates to a liquid cosmetic container.

従来、輸送時や使用時における落下や振動による液状化粧料の容器からの漏出を防止する液状化粧料容器(液体塗布具)として、以下の特許文献1に記載のものが知られている。この液状化粧料容器にあっては、容器本体と先端の塗布体との間に、内壁面から中心に向かって三個以上の突起が延びるように構成された塗布液供給体を、液漏れ抑制機構を兼ねる部品として備えている。
特開2002−10829号公報
Conventionally, the thing of the following patent documents 1 is known as a liquid cosmetics container (liquid applicator) which prevents the leakage of the liquid cosmetics from a container by the fall and vibration at the time of transportation or use. In this liquid cosmetic container, an application liquid supply body configured such that three or more protrusions extend from the inner wall surface toward the center between the container main body and the application body at the tip, and the liquid leakage is suppressed. It is provided as a part that doubles as a mechanism.
JP 2002-10829 A

ここで、輸送時、保管時等の初回使用開始時までの時期において液状化粧料の漏出を防止するものとしては、簡易な構成が望まれるが、上記公報にあっては、その後の使用時の漏出防止にも兼用とされる塗布液供給体を用いているため、構成が複雑である。   Here, in order to prevent leakage of liquid cosmetics during the period up to the start of the first use such as during transportation and storage, a simple configuration is desired. Since the coating liquid supply body that is also used for preventing leakage is used, the configuration is complicated.

本発明は、このような課題を解決するために成されたものであり、初回使用開始時までの時期における液状化粧料の漏出を簡易な構成で防止できる液状化粧料容器を提供することを目的とする。   The present invention has been made to solve such problems, and an object of the present invention is to provide a liquid cosmetic container capable of preventing leakage of the liquid cosmetic at a time until the first use start with a simple configuration. And

本発明による液状化粧料容器は、内部の収容室に収容した液状化粧料を流路を通して開口から外部に押し出し出現可能とする液状化粧料容器において、水溶性高分子を水に溶解し水分を蒸発させて成る密閉栓を、流路の開口側に有することを特徴としている。   The liquid cosmetic container according to the present invention is a liquid cosmetic container that allows a liquid cosmetic contained in an internal storage chamber to appear by being pushed out from an opening through a flow path, and evaporates water by dissolving a water-soluble polymer in water. It is characterized by having a sealing plug formed on the opening side of the flow path.

このような液状化粧料容器によれば、水溶性高分子を水に溶解し水分を蒸発させることで、流路の開口側に設けられた密閉栓が、初回使用開始時までの時期の液状化粧料の漏出を防止する一方で、初回使用開始時にあっては、使用者の操作により押し出されてくる液状化粧料が密閉栓中の多数の微細な孔内に入り込み、密閉栓の大部分が液状化粧料と接触することとなる結果、当該密閉栓は全体的に軟らかくなって液状化粧料と共に容易に押し出され、初回の使用が可能とされる。このため、初回使用開始時までの時期における液状化粧料の漏出を簡易な構成で防止できる。   According to such a liquid cosmetic container, the water-soluble polymer is dissolved in water to evaporate the water, so that the sealing stopper provided on the opening side of the flow path is liquid cosmetic for the period up to the start of the first use. While preventing the leakage of the material, at the beginning of the first use, the liquid cosmetic extruded by the user's operation enters the numerous fine holes in the sealing plug, and most of the sealing plug is liquid. As a result of coming into contact with the cosmetic material, the sealing plug becomes soft as a whole and is easily pushed out together with the liquid cosmetic material so that it can be used for the first time. For this reason, it is possible to prevent leakage of the liquid cosmetic material in the period up to the start of the first use with a simple configuration.

因みに、初回使用開始時までの時期にあって輸送時や保管時等の振動により流路内に入り込んだ液状化粧料が密閉栓に接触した場合には、流路内の液状化粧料は、押し出されてくる液状化粧料とは異なり密閉栓中の多数の微細な孔内に入り込むことにはならず、密閉栓のうちの液状化粧料と接触する部分だけが表層的に軟らかく成るのに過ぎないので、液状化粧料の漏出を防止する機能は維持される。   By the way, when liquid cosmetics that have entered the flow path due to vibrations during transportation or storage are in contact with the sealing plug, the liquid cosmetic in the flow path is pushed out. Unlike the liquid cosmetics that come out, it does not enter into the numerous fine holes in the sealing plug, but only the portion of the sealing plug that comes into contact with the liquid cosmetic is soft on the surface. Therefore, the function of preventing leakage of the liquid cosmetic is maintained.

ここで、水溶性高分子は、薬事法に基づく全成分表示の観点からすると、収容室に収容されている液状化粧料が含有している原料とするのが好ましい。   Here, the water-soluble polymer is preferably a raw material contained in the liquid cosmetic contained in the accommodation chamber from the viewpoint of displaying all components based on the Pharmaceutical Affairs Law.

また、水溶性高分子を水に溶解した溶解液に開口を浸漬し、その後、水分を蒸発させることで密閉栓を形成する構成であると、容易に密閉栓を形成でき製造コストを低減できる。   Further, when the opening is soaked in a solution obtained by dissolving a water-soluble polymer in water and then the water is evaporated, the sealing plug can be easily formed and the manufacturing cost can be reduced.

このように本発明によれば、初回使用開始時までの時期における液状化粧料の漏出を簡易な構成で防止することが可能となる。   As described above, according to the present invention, it is possible to prevent leakage of the liquid cosmetic material in the period until the first use start with a simple configuration.

以下、本発明による液状化粧料容器の好適な実施形態について説明する。図1は、本発明の実施形態に係る液状化粧料容器を示す縦断面図、図2は、図1に示す液状化粧料容器に採用されたパイプ部材及び密閉栓の拡大縦断面図であり、本実施形態の液状化粧料容器は、液状化粧料を容器内部に収容すると共に適宜使用者の操作により押し出して使用可能とするものである。   Hereinafter, preferred embodiments of the liquid cosmetic container according to the present invention will be described. FIG. 1 is a longitudinal sectional view showing a liquid cosmetic container according to an embodiment of the present invention. FIG. 2 is an enlarged longitudinal sectional view of a pipe member and a sealing plug employed in the liquid cosmetic container shown in FIG. The liquid cosmetic container according to the present embodiment accommodates the liquid cosmetic inside the container and appropriately pushes it out by a user operation so that it can be used.

図1に示すように、液状化粧料容器100は、液状化粧料Lを収容する収容室1aを内部に備えた本体筒1と、この本体筒1の後端部に回転可能に装着された操作筒2とを使用者が相対回転すると、容器100内に構成された押出機構としての螺合機構3及び回り止め機構4に従い、移動体5が前進又は後進し、移動体5の先端のピストン6が本体筒1の先端側に向かって繰り出されることで、収容室1aの液状化粧料Lが先端側に向かって押し出され、この押し出される液状化粧料Lを、本体筒1の先端部のパイプ部材7を通して外部に出現させてブラシ8に吐出することで使用状態とするように構成されたものである。なお、押出機構は、ラチェット機構を有し移動体5及びピストン6の前進のみを許容する構成であっても良い。   As shown in FIG. 1, the liquid cosmetic container 100 includes a main body cylinder 1 having a storage chamber 1 a for storing the liquid cosmetic L therein, and an operation that is rotatably attached to the rear end portion of the main body cylinder 1. When the user relatively rotates the tube 2, the moving body 5 moves forward or backward in accordance with the screwing mechanism 3 and the rotation preventing mechanism 4 as the pushing mechanism formed in the container 100, and the piston 6 at the tip of the moving body 5 is moved forward. Is fed out toward the front end side of the main body cylinder 1, so that the liquid cosmetic L in the storage chamber 1 a is pushed out toward the front end side, and the liquid cosmetic L that is pushed out is used as a pipe member at the front end portion of the main body cylinder 1. 7 is made to appear in the outside through 7 and discharged to the brush 8 so as to be in a use state. In addition, the structure which has a ratchet mechanism and accept | permits only the advance of the mobile body 5 and the piston 6 may be sufficient as an extrusion mechanism.

上記パイプ部材7は、本体筒1の先端部に装着されたホルダ部7aと、このホルダ部7aの中央に設けられて前方に向かって延びるパイプ部7bとを備え、ホルダ部7aの後側から押し出されてくる液状化粧料Lを、パイプ部7b内に形成された流路7cを通して、その先端の開口7dから外部に出現可能とするものである。なお、ホルダ部7aとパイプ部7bとは別体でも一体成形品でも良い。   The pipe member 7 includes a holder portion 7a attached to the distal end portion of the main body cylinder 1, and a pipe portion 7b provided in the center of the holder portion 7a and extending forward, and from the rear side of the holder portion 7a. The liquid cosmetic L that is pushed out can appear outside through the opening 7d at the tip of the liquid cosmetic L through the flow path 7c formed in the pipe portion 7b. In addition, the holder part 7a and the pipe part 7b may be separate or integrally molded.

ここで、特に本実施形態にあっては、パイプ部材7の先端の開口7dを塞ぐ密閉栓10が、輸送時、保管時等の初回使用開始時までの時期における液状化粧料Lの漏出を防止するためのものとして設けられている。   Here, particularly in the present embodiment, the sealing plug 10 that closes the opening 7d at the tip of the pipe member 7 prevents the liquid cosmetic L from leaking out at the time until the first use is started, such as during transportation or storage. It is provided for the purpose of

この密閉栓10は、図2に示すように、ここでは、パイプ部材7の開口7dから先端内に進入すると共に開口7dから丸みを有して膨出する形状とされている。   As shown in FIG. 2, the sealing plug 10 has a shape that enters the tip from the opening 7 d of the pipe member 7 and bulges out from the opening 7 d.

そして、この密閉栓10は、水溶性高分子をその原料としている。   And this airtight stopper 10 uses the water-soluble polymer as the raw material.

水溶性高分子としては、具体的には、有機物を用いることが可能であり、有機物としては、天然高分子、半合成高分子、合成高分子を用いることが可能である。   Specifically, an organic substance can be used as the water-soluble polymer, and a natural polymer, a semi-synthetic polymer, or a synthetic polymer can be used as the organic substance.

また、天然高分子としては、例えば、グアーガム、ローカストビンガム、クインスシードガム、カラギーナン、ガラクタン、アラビアガム、トラガカントガム、ベクチン、マンナン、デンプン等の植物系(多糖類系)や、例えば、キサンタンガム、デキストラン等の微生物系(多糖類系)や、例えばゼラチン等の動物系(蛋白類系)を用いることが可能である。   Examples of natural polymers include guar gum, locust bin gum, quince seed gum, carrageenan, galactan, gum arabic, tragacanth gum, bectin, mannan, starch, and other plant systems (polysaccharides), for example, xanthan gum, dextran, etc. Microbial system (polysaccharide system) or animal system (protein system) such as gelatin can be used.

また、半合成高分子としては、例えば、メチルセルロース、エチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、カルボキシメチルセルロース、メチルヒドロキシプロピルセルロース等のセルロース系や、例えば、可溶性デンプン、カルボキシメチルデンプン、メチルデンプン等のデンプン系や、例えば、アルギン酸プロピレングリコールエステル、アルギン酸塩等のアルギン酸系や、その他多糖類系誘導体を用いることが可能である。   Examples of the semi-synthetic polymer include celluloses such as methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, and methylhydroxypropylcellulose, and starches such as soluble starch, carboxymethylstarch, and methylstarch. For example, it is possible to use alginic acid type | system | groups, such as a propylene glycol ester alginate and an alginate, and other polysaccharide derivatives.

また、合成高分子としては、例えば、ポリビニルアルコール、ポリビニルピロリドン、ポリビニルメチルエ−テル、カルボキシビニルポリマー、ポリアクリル酸ソーダ等のビニル系を用いることが可能である。   Moreover, as a synthetic polymer, it is possible to use vinyl systems such as polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl methyl ether, carboxyvinyl polymer, and sodium polyacrylate.

そして、ここでは、上記水溶性高分子のうち、容器100に収容された液状化粧料Lが含有している原料(1種類でも複数種類でも可)を用いて、密閉栓10が形成されている。   Here, among the water-soluble polymers, the sealing plug 10 is formed using a raw material (one type or plural types) contained in the liquid cosmetic L contained in the container 100. .

具体的には、上記原料を水に溶解した溶解液に、ホルダ部7a及びパイプ部7bを有するパイプ部材7を逆さにしてその開口7aを浸漬し、その後、引き上げて水分を蒸発させて図2に示すように密閉栓10を形成する。このように密閉栓10は容易に形成でき、製造コストの低減が図られている。   Specifically, the pipe member 7 having the holder portion 7a and the pipe portion 7b is turned upside down in a solution obtained by dissolving the above raw material in water, and the opening 7a is immersed therein. The sealing plug 10 is formed as shown in FIG. Thus, the sealing plug 10 can be easily formed, and the manufacturing cost is reduced.

そして、図1に示すように、密閉栓10を先端に有すると共にブラシ8等を装着したパイプ部材7を、押出機構、移動体5、ピストン6、液状化粧料L等を本体筒1及び操作筒2内に内蔵した組立体のその先端部に装着することによって、密閉栓10により液状化粧料Lを容器100内に密閉状態とした液状化粧料容器100が得られる。なお、液状化粧料Lはパイプ部材7のパイプ部7a内の先端まで進入していても、密閉栓10との間に空間を有するようにして収容室1aに収容されていても良い。   As shown in FIG. 1, a pipe member 7 having a sealing plug 10 at the tip and fitted with a brush 8 or the like is used for an extrusion mechanism, a moving body 5, a piston 6, a liquid cosmetic L, and the like. The liquid cosmetic container 100 in which the liquid cosmetic L is hermetically sealed in the container 100 by the sealing plug 10 is obtained by mounting the front end of the assembly built in 2. Note that the liquid cosmetic L may enter the pipe member 7 up to the tip in the pipe portion 7a, or may be accommodated in the accommodation chamber 1a so as to have a space with the sealing plug 10.

ここで、本実施形態の密閉栓10は、水溶性高分子を水に溶解し水分を蒸発させて成るものであるから、液状化粧料と接触すると、液状化粧料に含まれる水に溶けて軟らかくなる(本発明者らの実験によれば、水溶性高分子が液状化粧料と接触してから軟らかくなるまでおよそ30秒から1分程度である)。従って、初回使用開始時にあって使用者の操作により収容室1a内の液状化粧料Lが押し出される場合には、押し出されてくる液状化粧料Lが密閉栓10中の多数の微細な孔内に入り込み、密閉栓10の大部分が液状化粧料Lと接触することとなる結果、当該密閉栓10は全体的に軟らかくなって液状化粧料Lと共に容易に押し出され、初回の使用が可能となる。   Here, since the sealing plug 10 of the present embodiment is formed by dissolving a water-soluble polymer in water and evaporating the water, when it comes into contact with the liquid cosmetic, it melts in the water contained in the liquid cosmetic and is soft. (According to the experiments of the present inventors, it takes about 30 seconds to 1 minute until the water-soluble polymer comes into contact with the liquid cosmetic and becomes soft). Therefore, when the liquid cosmetic L in the storage chamber 1a is pushed out by the user's operation at the start of the first use, the liquid cosmetic L pushed out is put in many fine holes in the sealing plug 10. As a result, most of the sealing plug 10 comes into contact with the liquid cosmetic L. As a result, the sealing plug 10 becomes soft as a whole and is easily pushed out together with the liquid cosmetic L, and can be used for the first time.

一方、初回使用開始時までの時期にあって輸送時や保管時等の振動により流路7c内に入り込んだ液状化粧料Lが密閉栓10に接触した場合には、流路7c内の液状化粧料Lは、押し出されてくる液状化粧料Lとは異なり密閉栓10中の多数の微細な孔内に入り込むことにはならず、密閉栓10のうちの液状化粧料Lと接触する部分だけが表層的に軟らかく成るのに過ぎないので、液状化粧料の漏出を防止する機能は維持される。   On the other hand, when the liquid cosmetic L that has entered the flow path 7c due to vibration during transportation or storage is in contact with the sealing plug 10 until the first use starts, the liquid makeup in the flow path 7c. Unlike the liquid cosmetic L that is extruded, the material L does not enter the numerous fine holes in the sealing plug 10, and only the portion of the sealing plug 10 that contacts the liquid cosmetic L is used. Since it is only soft on the surface, the function of preventing leakage of the liquid cosmetic is maintained.

すなわち、本実施形態においては、水溶性高分子を水に溶解し水分を蒸発させることで流路7cの開口7d側に設けられた密閉栓10が、初回使用開始時までの時期の液状化粧料の漏出を防止する一方で、初回使用開始時にあっては、使用者の操作により押し出されてくる液状化粧料Lによって液状化粧料Lと共に容易に押し出され、初回の使用が可能とされる結果、初回使用開始時までの時期における液状化粧料Lの漏出を簡易な構成で防止できる。   In other words, in this embodiment, the sealing plug 10 provided on the opening 7d side of the flow path 7c by dissolving the water-soluble polymer in water and evaporating the water is a liquid cosmetic at a time until the start of the first use. On the other hand, at the beginning of the first use, the liquid cosmetic L extruded by the user's operation is easily extruded together with the liquid cosmetic L, and the first use is possible. Leakage of the liquid cosmetic L during the period up to the start of the first use can be prevented with a simple configuration.

因みに、本発明者は、前述したポリビニルアルコール又はポリビニルピロリドンを原料として、前述した方法により密閉栓10を得、当該密閉栓10によって、初回使用開始時までの時期の液状化粧料Lの漏出を防止する一方で、初回使用開始時の押し出されてくる液状化粧料Lによって、密閉栓10が容易に押し出され初回の使用が可能となることを確認した。   Incidentally, the present inventor obtained the sealing plug 10 by the above-mentioned method using the above-mentioned polyvinyl alcohol or polyvinylpyrrolidone as a raw material, and prevents leakage of the liquid cosmetic L at the time until the start of the first use by the sealing plug 10. On the other hand, it was confirmed that the hermetic stopper 10 was easily pushed out by the liquid cosmetic L pushed out at the start of the first use, and the first use was possible.

以上、本発明をその実施形態に基づき具体的に説明したが、本発明は上記実施形態に限定されるものではなく、例えば、上記実施形態においては、薬事法に基づく全成分表示の観点から特に好ましいとして、密閉栓10の原料を、容器100に収容された液状化粧料Lが含有している原料としているが、液状化粧料の原料であれば、容器100に収容された液状化粧料Lが含有していない原料とすることも可能であり、さらには、密閉栓10の原料は水溶性高分子であれば良い。   As described above, the present invention has been specifically described based on the embodiment, but the present invention is not limited to the above embodiment. For example, in the above embodiment, in particular, from the viewpoint of displaying all components based on the Pharmaceutical Affairs Law. Preferably, the raw material of the sealing plug 10 is a raw material contained in the liquid cosmetic L contained in the container 100. However, if the raw material for the liquid cosmetic is the liquid cosmetic L contained in the container 100, The raw material which does not contain can also be used, and the raw material of the sealing plug 10 may be a water-soluble polymer.

また、上記実施形態においては、特に好ましいとして、パイプ部材7及びブラシ8を有する液状化粧料容器100に対する適用を述べているが、パイプ部材7やブラシ8を有していない例えば先端に疣やスポンジ等の塗布具を有する液状化粧料容器に対しても適用可能である。   In the above-described embodiment, the application to the liquid cosmetic container 100 having the pipe member 7 and the brush 8 is described as being particularly preferable. The present invention can also be applied to a liquid cosmetic container having an applicator.

また、上記実施形態においては、特に好ましいとして、螺子による繰り出し機構を有する回転式の液状化粧料容器100に対する適用を述べているが、これとは相違する例えばノック式や、例えばチューブやソフトボトル等の単純なスクイーズ式の液状化粧料容器に対しても適用可能であり、要は、内部の収容室に収容した液状化粧料を流路を通して開口から外部に押し出し出現可能とする液状化粧料容器全てに対して適用可能である。   In the above embodiment, the application to the rotating liquid cosmetic container 100 having a screw feeding mechanism is described as being particularly preferable. However, for example, a knock type, a tube, a soft bottle, etc. The liquid squeeze container can be applied to a simple squeeze-type liquid cosmetic container. In short, all liquid cosmetic containers that allow the liquid cosmetic stored in the internal storage chamber to be pushed out from the opening through the channel and appear. Is applicable.

本発明の実施形態に係る液状化粧料容器を示す縦断面図である。It is a longitudinal cross-sectional view which shows the liquid cosmetics container which concerns on embodiment of this invention. 図1に示す液状化粧料容器に採用されたパイプ部材及び密閉栓の拡大縦断面図である。FIG. 2 is an enlarged longitudinal sectional view of a pipe member and a sealing plug employed in the liquid cosmetic container shown in FIG. 1.

符号の説明Explanation of symbols

1a…収容室、7c…流路、7d…開口、10…密閉栓、100…液状化粧料容器、L…液状化粧料。   DESCRIPTION OF SYMBOLS 1a ... Accommodating chamber, 7c ... Flow path, 7d ... Opening, 10 ... Seal plug, 100 ... Liquid cosmetic container, L ... Liquid cosmetic.

Claims (3)

内部の収容室に収容した液状化粧料を流路を通して開口から外部に押し出し出現可能とする液状化粧料容器において、
水溶性高分子を水に溶解し水分を蒸発させて成る密閉栓を、前記流路の開口側に有することを特徴とする液状化粧料容器。
In the liquid cosmetic container that allows the liquid cosmetic stored in the internal storage chamber to appear by being pushed out from the opening through the flow path,
A liquid cosmetic container comprising a sealing stopper formed by dissolving a water-soluble polymer in water and evaporating water on the opening side of the flow path.
前記水溶性高分子は、前記収容室に収容されている液状化粧料が含有している原料であることを特徴とする請求項1記載の液状化粧料容器。   2. The liquid cosmetic container according to claim 1, wherein the water-soluble polymer is a raw material contained in the liquid cosmetic contained in the storage chamber. 前記水溶性高分子を水に溶解した溶解液に前記開口を浸漬し、その後、水分を蒸発させることで前記密閉栓を形成することを特徴とする請求項1又は2記載の液状化粧料容器。   The liquid cosmetic container according to claim 1 or 2, wherein the sealing stopper is formed by immersing the opening in a solution obtained by dissolving the water-soluble polymer in water and then evaporating the water.
JP2008151952A 2008-06-10 2008-06-10 Liquid cosmetic container Expired - Fee Related JP5118559B2 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001180179A (en) * 1999-12-27 2001-07-03 Pentel Corp Liquid discharging implement
JP2004097820A (en) * 2002-09-06 2004-04-02 Geka Brush Gmbh Unit of vessel and applicator
JP2004174956A (en) * 2002-11-28 2004-06-24 Pentel Corp Applicator

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001180179A (en) * 1999-12-27 2001-07-03 Pentel Corp Liquid discharging implement
JP2004097820A (en) * 2002-09-06 2004-04-02 Geka Brush Gmbh Unit of vessel and applicator
JP2004174956A (en) * 2002-11-28 2004-06-24 Pentel Corp Applicator

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