JP2009221645A - Fiber having modified cross section, and makeup cosmetic - Google Patents

Fiber having modified cross section, and makeup cosmetic Download PDF

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JP2009221645A
JP2009221645A JP2008314458A JP2008314458A JP2009221645A JP 2009221645 A JP2009221645 A JP 2009221645A JP 2008314458 A JP2008314458 A JP 2008314458A JP 2008314458 A JP2008314458 A JP 2008314458A JP 2009221645 A JP2009221645 A JP 2009221645A
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cross
fiber
section
feeling
sectional shape
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JP5138564B2 (en
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Shoji Matsumoto
彰二 松本
Koji Kakumoto
幸治 角本
Takeshi Chizuka
健史 千塚
Takenori Domon
武徳 土門
Yuko Tsukamoto
祐子 塚本
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Unitika Fibers Ltd
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Unitika Fibers Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a fiber having modified cross section giving excellent light dispersion and reflection actions and skin feeling with glossy appearance when added into cosmetics and applied, and at the same time, having smooth use feeling without feeling of a foreign body, in addition, volume-up effects when used as mascara, and makeup cosmetics containing the fiber having the modified cross section. <P>SOLUTION: The fiber having modified cross section has a cross section of a filament vertically cut to the longitudinal fiber axis exhibiting a shape in which two circles having openings are connected at least one point. In the fiber, the openings of two circles are connected without being blocked, the maximum length connecting optional two points in a cross sectional shape is ≥1.1 times of the diameter of a circle having the maximum diameter, the maximum length is 5-100 μm, both two circles have each 30-140° angle of opening, and monofilament fineness is 1.0-7.0 dtex. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、化粧料に含有させることが好適な異形断面繊維に関するものであり、単糸の断面形状が開口部を有する2個の円形が連結した形状を呈することにより、光の拡散、反射作用に優れ、異物感のない滑らかな使用感を有する化粧料を得ることができる異形断面繊維に関するものである。   The present invention relates to a modified cross-section fiber that is preferably contained in cosmetics. The cross-sectional shape of a single yarn exhibits a shape in which two circular shapes having openings are connected, thereby diffusing and reflecting light. The present invention relates to a modified cross-section fiber that can provide a cosmetic material that is excellent in quality and has a smooth feeling of use with no foreign matter feeling.

また、本発明は、このような本発明の異形断面繊維を含有するメークアップ化粧料に関するものである。   Moreover, this invention relates to the makeup cosmetics containing such a modified cross-section fiber of this invention.

従来、ファンデーション等のメークアップ化粧料には、化粧効果を高めたり、滑らかな使用感を与えるために繊維が配合されている。特許文献1には、横断面に凹みのある異形断面繊維を分散されてなる化粧料が提案されている。   Conventionally, fibers are blended in makeup cosmetics such as foundations in order to enhance the makeup effect and give a smooth feeling of use. Patent Document 1 proposes a cosmetic material in which irregular cross-section fibers having dents in the cross section are dispersed.

特許文献1記載の異形断面繊維を使用することで、化粧料塗布時の繊維の不要な転がりを防止でき、繊維の凹みに化粧料が入り込むために繊維と塗布面との密着性を向上させることができ、塗布後の仕上がりの美しさを向上させることができるものである。   By using the modified cross-section fiber described in Patent Document 1, unnecessary rolling of the fiber at the time of applying the cosmetic can be prevented, and the adhesion between the fiber and the application surface can be improved because the cosmetic enters the fiber recess. And the beauty of the finish after application can be improved.

また、ファンデーションにおいては、しみ等の皮膚の好ましくない部分を隠蔽し、見ために美しく見えるようにするために、隠蔽製の高い粉体の開発が望まれ、微粒子二酸化チタンなどの素材が開発されてきた。その一方で、このような高隠蔽性による素肌感の喪失が次の開発すべき課題として挙げられている。   In addition, in the foundation, in order to conceal undesired parts of the skin such as stains and make them look beautiful for viewing, development of high powders made of concealment is desired, and materials such as fine particle titanium dioxide have been developed. I came. On the other hand, the loss of bare skin feeling due to such high concealment is cited as the next issue to be developed.

特許文献1記載の異形断面繊維においては、化粧料中に繊維を均一に分散させ、化粧料塗布時の繊維と化粧料、塗布面との密着性を向上させることはできたが、自然な素肌感を与えることは困難であった。   In the irregular cross-section fiber described in Patent Document 1, the fiber was uniformly dispersed in the cosmetic, and the adhesion between the fiber and the cosmetic when applying the cosmetic and the coated surface could be improved. It was difficult to give a feeling.

特許文献2には、井型断面形状の異形断面繊維を含有させた化粧料が提案されている。特許文献2記載の化粧料によると、井型断面繊維と特定の化合物の粒子を含有させることによって、塗布部位に照射された光を拡散、反射させる効果に優れ、光照射部位の明るさを高めることができ、生き生きとした表情感、若々しさの印象を高めることができるものである。   Patent Document 2 proposes a cosmetic containing a modified cross-section fiber having a well-shaped cross section. According to the cosmetics described in Patent Document 2, by including well-shaped cross-section fibers and particles of a specific compound, it is excellent in the effect of diffusing and reflecting the light irradiated on the application site, and increases the brightness of the light irradiation site. Can enhance the impression of vivid expression and youthfulness.

しかしながら、特許文献2記載の化粧料では、井型断面形状の異形断面繊維を使用しているため、繊維に直線部分が多く、肌に塗布した場合に異物感が生じ、滑らかな使用感が得られるものではなかった。   However, the cosmetic disclosed in Patent Document 2 uses irregular cross-section fibers having a well-shaped cross section, so that there are many straight portions in the fibers, and a foreign object sensation occurs when applied to the skin, resulting in a smooth feeling of use. It wasn't something that could be done.

また、マスカラ等の化粧料にもまつ毛を長く見せるロングラッシュ効果やまつ毛をボリュームアップさせる効果を得るために繊維が含有されている。このような化粧料においても滑らかな使用感、塗布後のつや感とボリューム感、仕上がりの美しさが求められているが、全ての要求を満たすものは得られていなかった。
特開2004−107237号公報 特開2006−52202号公報
Further, cosmetics such as mascara contain fibers in order to obtain a long lash effect that makes eyelashes look longer and an effect that makes eyelashes volume up. Such cosmetics are also required to have a smooth feeling of use, a feeling of gloss and volume after application, and a beautiful finish, but none satisfying all the requirements has been obtained.
JP 2004-107237 A JP 2006-52202 A

本発明は、上記の課題を解決するものであって、化粧料に含有させて塗布すると、光の拡散、反射作用に優れ、つや感のある素肌感を得ることができ、かつ異物感のない滑らかな使用感を有し、さらにはマスカラ等に使用する際にはボリュームアップ効果も有することができる異形断面繊維を提供すること及びこのような異形断面繊維を含有するメークアップ化粧料を提供することを技術的な課題とするものである。   The present invention solves the above problems, and when applied in cosmetics, the present invention is excellent in light diffusion and reflection, can provide a glossy bare skin feeling, and has no foreign body feeling. To provide a modified cross-section fiber that has a smooth feeling of use and can also have a volume-up effect when used in mascara and the like, and to provide a makeup cosmetic containing such a modified cross-section fiber. This is a technical issue.

本発明者らは、上記のような課題を解決すべく検討した結果、本発明に到達した。
すなわち、本発明は以下の(1)、(2)を要旨とするものである。
(1)繊維軸方向に対して垂直に切断した単糸の断面形状が、開口部を有する2個の円形が少なくとも1点で連結した形状を呈する異形断面繊維であって、2個の円形の開口部が閉塞することなく連結されており、断面形状における任意の2点を結ぶ最大長が最大径を有する円形の直径の1.1倍以上であり、かつ最大長が5〜100μm、2個の円形ともに開口角度が30〜140°であり、単糸繊度が1.0〜7.0dtexであることを特徴とする異形断面繊維。
(2)(1)記載の異形断面繊維を含有するメークアップ化粧料。
The inventors of the present invention have arrived at the present invention as a result of studies to solve the above problems.
That is, the gist of the present invention is the following (1) and (2).
(1) A cross-sectional shape of a single yarn cut perpendicular to the fiber axis direction is a modified cross-section fiber having a shape in which two circular shapes having openings are connected at least at one point, and the two circular shapes The openings are connected without blocking, the maximum length connecting any two points in the cross-sectional shape is 1.1 times or more of the circular diameter having the maximum diameter, and the maximum length is 5 to 100 μm, two An irregularly shaped cross-section fiber having an opening angle of 30 to 140 ° and a single yarn fineness of 1.0 to 7.0 dtex.
(2) A makeup cosmetic containing the modified cross-section fiber according to (1).

本発明の異形断面繊維は、単糸の断面形状が開口部を有する2個の円形が少なくとも1点で連結した形状を呈しており、曲線部分からなる形状であるため、光を照射すると、光の拡散、反射作用に優れるとともにぎらぎら感のないソフトな光沢感が得られる。このため、化粧料に含有させて塗布すると、つや感のある素肌感を得ることができる。そして、断面形状が直線部分を有していないため、素肌に塗布した際には異物感のない滑らかな使用感を有し、仕上がりの美しさも得られるものである。さらには断面形状が2個の円形が連結した形状であることから、嵩高性を有し、マスカラ等に使用する際にはボリュームアップ効果も奏することが可能となる。   The irregular cross-section fiber of the present invention has a cross-sectional shape of a single yarn in which two circular shapes having openings are connected at at least one point, and is a shape composed of a curved portion. It has an excellent diffusion and reflection effect, and a soft gloss without glare. For this reason, when it is made to contain in cosmetics and apply | coating, the glossy bare skin feeling can be obtained. And since a cross-sectional shape does not have a linear part, when it apply | coats to bare skin, it has a smooth feeling of use without a foreign material feeling, and the beauty of a finish is also acquired. Furthermore, since the cross-sectional shape is a shape in which two circles are connected, it is bulky, and when used in a mascara or the like, a volume-up effect can be achieved.

本発明のメークアップ化粧料は、本発明の異形断面繊維を含有するものであるため、つや感のある素肌感を得ることができ、素肌に塗布した際には異物感のない滑らかな使用感を有するファンデーションとなる。また、本発明の異形断面繊維は嵩高性も有するため、本発明のメークアップ化粧料は、優れたボリュームアップ効果を有するマスカラとすることができる。   Since the makeup cosmetic of the present invention contains the modified cross-section fiber of the present invention, it is possible to obtain a glossy feeling of the skin, and when applied to the bare skin, there is no sense of foreign matter and a smooth feeling of use. It becomes the foundation which has. Moreover, since the modified cross-section fiber of the present invention has bulkiness, the makeup cosmetic of the present invention can be a mascara having an excellent volume-up effect.

以下に、本発明について詳細に説明する。
本発明の異形断面繊維は、単糸の断面形状が以下に詳述する形状を呈するものであり、マルチフィラメント、モノフィラメントのいずれでもよい。
The present invention is described in detail below.
The irregular cross-section fiber of the present invention has a cross-sectional shape of a single yarn that will be described in detail below, and may be either a multifilament or a monofilament.

そして、本発明の異形断面繊維は化粧料中に含有させて用いることが好適なものである。化粧料としては、メークアップ化粧料が好ましく、中でもファンデーション、マスカラ、アイブロウ等が好適である。   And it is suitable to use the modified cross-section fiber of the present invention in cosmetics. As cosmetics, makeup cosmetics are preferable, and among them, foundation, mascara, eyebrow and the like are preferable.

本発明の異形断面繊維は、単糸を繊維軸方向に対して垂直に切断した断面形状が、開口部を有する2個の円形が少なくとも1点で連結しており、2個の円形の開口部が閉塞することなく連結されている。   The modified cross-section fiber of the present invention has a cross-sectional shape obtained by cutting a single yarn perpendicular to the fiber axis direction, and two circular shapes having openings are connected at least at one point, and the two circular openings Are connected without blocking.

開口部を有する円形とはC型の形状のものであり、2個のC型のものが連結しており、連結部が1点以上のものである。中でも連結部が2点であるものが好ましい。   The circular shape having the opening is a C-shaped shape, and two C-shaped ones are connected to each other, and the connecting part is one or more points. Among them, those having two connecting portions are preferable.

本発明の異形断面繊維の単糸の断面形状の実施態様としては、図1の(A)〜(F)の形状のものが挙げられる。(A)、(B)、(D)、(F)は連結部が2点のものであり、(C)、(E)は連結部が1点のものである。   As an embodiment of the cross-sectional shape of the single yarn of the odd-shaped cross-section fiber of the present invention, those having the shapes of (A) to (F) in FIG. (A), (B), (D), and (F) have two connecting portions, and (C) and (E) have one connecting portion.

そして、連結した形状において、2個の円形の開口部が閉塞することなく連結されている。つまり、図2に示すように開口部端部同士が連結した形状であると、開口部が閉塞されたものとなる。   In the connected shape, the two circular openings are connected without being closed. That is, as shown in FIG. 2, when the opening ends are connected, the opening is closed.

本発明の異形断面繊維は、図1に示すような形状であることにより、曲線部のみからなる複雑な形状となり、嵩高なものとなると同時に、形状の外周面のみならず、開口部端部、開口部内部でも照射された光が反射する部位が多くなり、光の拡散、反射作用に優れる。   The irregular cross-section fiber of the present invention is a shape as shown in FIG. 1, so that it becomes a complicated shape consisting of only a curved portion and becomes bulky, and at the same time, not only the outer peripheral surface of the shape, but also the end of the opening, Even in the inside of the opening, the portion where the irradiated light is reflected increases, and the light diffusion and reflection action is excellent.

そして、本発明の異形断面繊維の断面形状においては、直線部分を有しておらず、曲線部のみからなり、曲線部分で光が反射、拡散されることにより、ぎらぎら感が生じず、ソフトな光の拡散、反射が得られ、ファンデーション等に含有させると、つや感とともにナチュラルな素肌感をも有するものとなる。   And in the cross-sectional shape of the irregular cross-section fiber of the present invention, it does not have a straight portion, it consists only of a curved portion, and light is reflected and diffused at the curved portion, so that a glare feeling does not occur and is soft. Light diffusion and reflection can be obtained, and when it is contained in a foundation or the like, it has a natural skin feeling as well as a glossy feeling.

図2に示すような形状であると、嵩高なものとはなるが、照射された光を反射する部位が外周面のみになり、光の拡散、反射作用に劣るものとなり、つや感やナチュラルな素肌感を得ることができない。   The shape as shown in FIG. 2 is bulky, but the portion that reflects the irradiated light is only the outer peripheral surface, which is inferior in light diffusion and reflection action, and is glossy and natural. I cannot get a feeling of bare skin.

さらに、本発明の異形断面繊維は、2個の円形が組み合わさった曲線部分からなる形状のもので、直線部分を有していないので、素肌に塗布した際には異物感がなく、滑らかな使用感のものとなり、仕上がりの美しさも得られるものである。   Furthermore, the irregular cross-section fiber of the present invention has a shape composed of a curved portion in which two circular shapes are combined, and does not have a straight portion. It becomes a feeling of use, and the beauty of the finish is also obtained.

また、円形が組み合わさった曲線部分のみからなる形状であるため、素肌に塗布した際にも素肌に接する繊維の面が多くないことから、密着感がなく、隠蔽感も生じないため、ナチュラルな素肌感を得ることができるものとなる。   In addition, since it is a shape that consists only of curved parts combined with a circle, there are not many fibers in contact with the bare skin even when applied to the bare skin, so there is no adhesion and no concealment, so it is natural. A feeling of bare skin can be obtained.

そして、2個の円形の開口角度は30〜140°であり、中でも50〜120°が好ましい。本発明でいう開口角度とは、図3に示すように、円形の中心点Oから2つの開口部端部M、Nに向かって引いた線がなす角度θをいうものである。   And the opening angle of two circular is 30-140 degrees, and 50-120 degrees is especially preferable. The opening angle in the present invention means an angle θ formed by a line drawn from a circular center point O toward two opening end portions M and N, as shown in FIG.

開口角度が30°未満であると、上記したような光の反射、拡散作用を得ることができず、ファンデーションに含有させた際に、つや感やナチュラルな素肌感を得ることができない。一方、開口角度が140°を超えると、開口部が広くなりすぎることから、この繊維を含有させた化粧料を素肌に塗布すると異物感が生じるものとなる。   When the opening angle is less than 30 °, it is impossible to obtain the light reflection and diffusion actions as described above, and when it is contained in the foundation, it is not possible to obtain a glossy feeling or a natural skin feeling. On the other hand, when the opening angle exceeds 140 °, the opening becomes too wide, so that a foreign material sensation occurs when the cosmetic containing this fiber is applied to the bare skin.

また、本発明の異形断面繊維の断面形状においては、図1(A)〜(D)に示すように2個の円形の大きさが等しいものであっても、図1(E)〜(F)に示すように2個の円形の大きさが異なるものであってもよい。そして、2個の開口部が開口する向きも開口部を閉塞することがなければ特に限定するものではない。   Further, in the cross-sectional shape of the irregular cross-section fiber of the present invention, even if the two circular sizes are equal as shown in FIGS. 1 (A) to 1 (D), FIGS. The size of the two circles may be different as shown in FIG. The direction in which the two openings are opened is not particularly limited as long as the opening is not blocked.

本発明の異形断面繊維の断面形状において、中でも2個の円形が連結した形状が線対称又は点対称であることが好ましい。線対称又は点対称であるとバランスの取れた断面形状なり、光の反射、拡散をよりバランスのよいソフトなものとすることが可能となり、また、化粧料中の分散もより均一なものとなり、異物感が少なくなり、使用感や仕上がりも良好となる。   In the cross-sectional shape of the irregular cross-section fiber of the present invention, it is preferable that the shape in which two circles are connected is line symmetric or point symmetric. If it is line symmetric or point symmetric, it becomes a balanced cross-sectional shape, it becomes possible to make light reflection and diffusion more balanced and soft, and the dispersion in cosmetics becomes more uniform, The feeling of foreign matter is reduced, and the feeling of use and finish are also good.

さらに、本発明の異形断面繊維は、2個の円形が連結した断面形状において、任意の2点を結ぶ最大長Lが最大径Rを有する円形の直径より大きく、かつ最大長Lが5〜100μmである。   Further, in the modified cross-section fiber of the present invention, in the cross-sectional shape in which two circles are connected, the maximum length L connecting any two points is larger than the diameter of the circle having the maximum diameter R, and the maximum length L is 5 to 100 μm. It is.

つまり、本発明においては、嵩高性を有するものとするために、任意の2点を結ぶ最大長Lが最大径Rを有する円形の直径の1.1倍以上(L≧1.1R)のものとする。図4に示すような断面形状のものでは、最大長Lが最大径Rを有する円形の直径と同じ(L=R)であり、嵩高性に乏しいものとなる。嵩高性と光の反射、拡散効果を考慮すると、中でも最大長Lが最大径Rを有する円形の直径の1.2倍以上、さらには1.3倍以上であることが好ましい。   That is, in the present invention, in order to have bulkiness, the maximum length L connecting any two points is 1.1 times or more (L ≧ 1.1R) of the circular diameter having the maximum diameter R. And In the cross-sectional shape as shown in FIG. 4, the maximum length L is the same as the circular diameter having the maximum diameter R (L = R), and the bulkiness is poor. In consideration of bulkiness, light reflection and diffusion effects, the maximum length L is preferably 1.2 times or more, and more preferably 1.3 times or more the diameter of a circle having the maximum diameter R.

そして、最大長Lは5〜100μmであり、中でも20〜80μmであることが好ましい。さらに、単糸繊度は1.0〜7.0dtex、中でも2.0〜6.0dtexであることが好ましい。   And the maximum length L is 5-100 micrometers, and it is preferable that it is 20-80 micrometers especially. Furthermore, the single yarn fineness is preferably 1.0 to 7.0 dtex, and more preferably 2.0 to 6.0 dtex.

断面形状の大きさをこのような範囲のものとすることにより、上記したような嵩高性と光の反射、拡散効果を良好なものとすることができる。最大長が5μm未満であったり、単糸繊度が1.0dtex未満であると、これらの効果に乏しいものとなり、一方、最大長が100μmを超えたり、単糸繊度が7.0dtexを超えると、素肌に付与した際に異物感のあるものとなる。   By setting the size of the cross-sectional shape within such a range, the above-described bulkiness, light reflection and diffusion effects can be improved. When the maximum length is less than 5 μm or the single yarn fineness is less than 1.0 dtex, these effects are poor. On the other hand, when the maximum length exceeds 100 μm or the single yarn fineness exceeds 7.0 dtex, When applied to the bare skin, it has a foreign body feel.

また、本発明の異形断面繊維は、上記したような形状による嵩高性を有するものとなることで、マスカラに含有させるとロングラッシュ効果やボリュームアップ効果が得られるものである。   Further, the irregular cross-section fiber of the present invention has a bulkiness due to the shape as described above, and when it is contained in mascara, a long lash effect and a volume-up effect can be obtained.

本発明の異形断面繊維は、単糸の断面形状の成形性の観点から、熱可塑性樹脂を用いて溶融紡糸して得られたものであることが好ましい。つまり、本発明の異形断面繊維は、所望の断面形状を得られるように穿孔した紡糸孔(スリット)を有する紡糸口金を用い、熱可塑性樹脂を溶融紡糸して得ることが好ましい。   The deformed cross-section fiber of the present invention is preferably obtained by melt spinning using a thermoplastic resin from the viewpoint of moldability of a single yarn cross-sectional shape. That is, the irregular cross-section fiber of the present invention is preferably obtained by melt spinning a thermoplastic resin using a spinneret having a spinning hole (slit) perforated so as to obtain a desired cross-sectional shape.

熱可塑性樹脂としては、ポリアミド、ポリエステル、ポリウレタン、ポリオレフィンなどが挙げられる。中でも肌への刺激がソフトとなるため、ポリアミドを用いることが好ましい。   Examples of the thermoplastic resin include polyamide, polyester, polyurethane, and polyolefin. Among them, it is preferable to use polyamide because the skin irritation becomes soft.

また、これらの熱可塑性樹脂においては、本発明の効果を損なわない範囲であれば、必要に応じて、熱安定剤、結晶核剤、艶消剤、顔料、耐候剤、耐光剤、滑剤、酸化防止剤、抗菌剤、香料、可塑剤、染料、界面活性剤、難燃剤、表面改質剤、各種無機及び有機電解質、その他類似の添加剤を添加することができる。   Further, in these thermoplastic resins, as long as the effects of the present invention are not impaired, a thermal stabilizer, a crystal nucleating agent, a matting agent, a pigment, a weathering agent, a light-proofing agent, a lubricant, an oxidation agent, and the like, if necessary. Inhibitors, antibacterial agents, fragrances, plasticizers, dyes, surfactants, flame retardants, surface modifiers, various inorganic and organic electrolytes, and other similar additives can be added.

本発明の異形断面繊維は、メークアップ化粧料に含有させる際の繊維の長さは、20〜1000μmが好ましく、中でも100〜500μmとすることが好ましい。   The length of the fiber when the modified cross-section fiber of the present invention is contained in the makeup cosmetic is preferably 20 to 1000 μm, and more preferably 100 to 500 μm.

繊維長が20μmより短い場合、光の拡散、反射効果やボリュームアップ効果が不十分となりやすい。一方、繊維長が1000μmより長い場合は、塗布時に異物感を感じるものとなり、仕上がりの美しさにも劣るものとなりやすい。   When the fiber length is shorter than 20 μm, the light diffusion, reflection effect and volume increase effect tend to be insufficient. On the other hand, when the fiber length is longer than 1000 μm, a feeling of foreign matter is felt at the time of application, and the finished product tends to be inferior.

そして、本発明のメークアップ化粧料は、本発明の異形断面繊維を含有するものである。メークアップ化粧料としては、中でもファンデーション、マスカラ、アイブロウ等が好ましい。   And the makeup cosmetics of this invention contain the unusual cross-section fiber of this invention. As makeup cosmetics, among them, foundation, mascara, eyebrow and the like are preferable.

これらのメークアップ化粧料には、本発明の異形断面繊維が0.1〜15質量%含有されていることが好ましく、中でも1〜10質量%含有されていることが好ましい。   These makeup cosmetics preferably contain 0.1 to 15% by mass of the irregular cross-section fiber of the present invention, and more preferably 1 to 10% by mass.

本発明のメークアップ化粧料中の本発明の異形断面繊維の含有量が0.1質量%より少ない場合は、光の拡散、反射効果やボリュームアップ効果が不十分となりやすい。一方、本発明の異形断面繊維の含有量が15質量%より多い場合は、塗布時に異物感を感じるものとなり、仕上がりの美しさにも劣るものとなりやすい。   When the content of the modified cross-section fiber of the present invention in the makeup cosmetic of the present invention is less than 0.1% by mass, the light diffusion, reflection effect and volume increase effect tend to be insufficient. On the other hand, when the content of the modified cross-section fiber of the present invention is more than 15% by mass, a feeling of foreign matter is felt at the time of application, and the finished product tends to be inferior.

次に、本発明の異形断面繊維の製造方法について一例を用いて説明する。
熱可塑性樹脂としてナイロン6を用い、通常のエクストルーダー型溶融紡糸装置を用い、所望の断面形状のものが得られるように紡糸孔を穿孔した紡糸口金を用いて、256℃で溶融紡糸する。紡糸された糸条を冷却、固化した後、一旦巻取り、又は巻き取ることなく、延伸を行い、必要に応じて延伸時に熱処理を行いながら、巻き取ることにより異形断面繊維を得る。そして、得られた異形断面繊維は、化粧料中に含有させる際には、ギロチンカッター等を用いて所望の繊維長にカットして用いる。
Next, the manufacturing method of the irregular cross-section fiber of this invention is demonstrated using an example.
Nylon 6 is used as a thermoplastic resin, and melt spinning is performed at 256 ° C. using a spinneret having a spinning hole drilled so as to obtain a desired cross-sectional shape using a normal extruder-type melt spinning apparatus. After the spun yarn is cooled and solidified, it is stretched without being wound or wound once, and a modified cross-section fiber is obtained by winding while performing a heat treatment at the time of stretching as necessary. And when making the obtained irregular cross-section fiber contain in cosmetics, it cuts into desired fiber length using a guillotine cutter etc., and uses it.

なお、本発明のメークアップ化粧料は、本発明の異形断面繊維を含有するものであるが、ファンデーション、マスカラ、アイブロウ等においては、ミキサーで混合しながら含有させることが好ましい。   In addition, although the makeup cosmetics of this invention contain the unusual cross-section fiber of this invention, in a foundation, a mascara, an eyebrow etc., it is preferable to make it contain, mixing with a mixer.

次に、本発明を実施例により具体的に説明する。なお、実施例中の各種の値の測定、評価は次のようにして行った。
〔開口角度、最大長、円形の直径〕
ニコン社製マイクロフォトS光学顕微鏡に顕微鏡写真撮影装置を取り付け、24本の単糸について、単糸の横断面形状を撮影し、それぞれの長さや角度を測定し、24本の平均値とした。
〔光の反射、拡散効果〕
得られたファンデーションを用い、同一モデルにメークアップを行い、写真に撮影し、専門パネラー5名が以下の4段階で評価した。
◎・・・つや感、素肌感が非常に優れている。
○・・・つや感、素肌感に優れている。
△・・・つや感、素肌感にやや優れている。
×・・・つや感、素肌感に劣る。
〔使用感〕
得られたファンデーション又はマスカラを用い、10名のモデルにメークアップを行い、塗布時の異物感の有無について以下の3段階で評価した。
◎・・・異物感を感じないが9名以上。
○・・・異物感を感じないが7〜8名。
△・・・異物感を感じないが4〜6名。
×・・・異物感を感じないが3名以下。
〔ボリュームアップ感〕
得られたマスカラを用い、10名のモデルにメークアップを行い、化粧後のボリュームアップ感の有無について以下の3段階で評価した。
◎・・・ボリュームアップ感を感じるが9名以上。
○・・・ボリュームアップ感を感じるが7〜8名。
△・・・ボリュームアップ感を感じるが4〜6名。
×・・・ボリュームアップ感を感じるが3名以下。
Next, the present invention will be specifically described with reference to examples. In addition, measurement and evaluation of various values in the examples were performed as follows.
[Aperture angle, maximum length, circular diameter]
A microphotograph photographing apparatus was attached to a Nikon Microphoto S optical microscope, and the cross-sectional shape of the single yarn was photographed for 24 single yarns, and the length and angle of each were measured, and the average value of the 24 yarns was obtained.
[Light reflection, diffusion effect]
Using the obtained foundation, the same model was made up and photographed, and five professional panelists evaluated it according to the following four levels.
◎ ・ ・ ・ Excellent gloss and feel.
○ ... Excellent gloss and skin feel.
Δ: Slightly excellent in feeling of gloss and bare skin.
X: Inferior to glossiness and bare skin feeling.
[Use feeling]
The obtained foundation or mascara was used to make up a model of 10 persons, and the presence or absence of a foreign object feeling during coating was evaluated in the following three stages.
◎ ・ ・ ・ No more foreigners but more than 9 people.
○ 7-7 people do not feel a foreign body feeling.
Δ: No sense of foreign body, but 4 to 6 persons.
X: No foreign body feeling but 3 or fewer.
[Volume up feeling]
Using the obtained mascara, 10 models were made up and evaluated for the presence or absence of volume up after makeup in the following three stages.
◎ ・ ・ ・ I feel a sense of volume up, but more than 9 people.
○ 7-7 people feel volume up.
Δ: 4-6 people feel volume up.
× ・ ・ ・ I feel a sense of volume up, but no more than 3 people.

実施例1
相対粘度(96%硫酸を溶媒とし、濃度1g/dl、温度25℃で測定した)3.50のポリアミド6に、顔料として赤色205号を20質量%添加し、ブレンドしてマスターチップを作製した。
このマスターチップと相対粘度3.50のナイロン6を質量比1:39で混合(繊維中の赤色203号の含有量が0.5質量%となるように)し、通常のエクストルーダー型溶融紡糸装置を使用して溶融紡糸を行った。このとき、単糸の断面形状が図1(C)の形状となるようにスリットを穿孔した紡糸口金を用いて、256℃で溶融紡糸した。そして、紡糸された糸条を冷却固化した後、第1ローラ(温度25℃)の表面速度を3111m/分、第2ローラ(温度110 ℃)の表面速度を4200m/分とし、延伸倍率1.35倍で延伸し、速度4000m/分で巻き取り、60dtex/24fのマルチフィラメントを得た。得られたマルチフィラメントの単糸の断面形状は図1(C)に示すもの(2個の円形は大きさ、開口角度が同じ)であり、連結部が1点、2個の円形の開口角度が50°、最大長が25μm、最大径を有する円形の直径20μm、単糸繊度2.5dtexであった。
そして、ギロチンカッターを用いてカットし、繊維長400μmの短繊維(成分A)とし、以下の処方1に示す成分と含有量からなるファンデーションを作製した。このとき、成分Bをヘンシェルミキサーで混合した後、0.9mm丸穴スクリーンを装着したパルベライザーで粉砕し、その後に成分Aを加えてヘンシェルミキサーで混合し、さらにヘンシェルミキサーで混合しながら成分Cを噴霧してコーティングを行い、ファンデーションを得た。
Example 1
A master chip was prepared by adding 20% by mass of Red No. 205 as a pigment to polyamide 6 having a relative viscosity (measured at 96% sulfuric acid as a solvent, concentration of 1 g / dl, temperature of 25 ° C.) 3.50. .
This master chip and nylon 6 having a relative viscosity of 3.50 are mixed at a mass ratio of 1:39 (so that the content of red No. 203 in the fiber is 0.5% by mass), and a normal extruder melt spinning is performed. The apparatus was used for melt spinning. At this time, melt spinning was performed at 256 ° C. using a spinneret having a slit perforated so that the cross-sectional shape of the single yarn became the shape shown in FIG. After spinning and solidifying the spun yarn, the surface speed of the first roller (temperature 25 ° C.) is 3111 m / min, the surface speed of the second roller (temperature 110 ° C.) is 4200 m / min, and the draw ratio is 1. The film was stretched 35 times and wound at a speed of 4000 m / min to obtain a 60 dtex / 24f multifilament. The cross-sectional shape of the obtained multifilament single yarn is as shown in FIG. 1C (the two circles have the same size and the same opening angle), and have one connecting point and two circular opening angles. Was 50 °, the maximum length was 25 μm, the circular diameter having the maximum diameter was 20 μm, and the single yarn fineness was 2.5 dtex.
And it cut using the guillotine cutter, it was set as the short fiber (component A) of fiber length 400 micrometers, and the foundation which consists of a component and content shown to the following prescription 1 was produced. At this time, after mixing the component B with a Henschel mixer, pulverizing with a pulverizer equipped with a 0.9 mm round hole screen, then adding the component A, mixing with the Henschel mixer, and further mixing the component C with the Henschel mixer. Coating was performed by spraying to obtain a foundation.

〔処方1〕
成分A:ナイロン6短繊維 5質量%
成分B:シリコーン焼付け処理二酸化チタン 20質量%
シリコーン焼付け黄酸化鉄 5質量%
シリコーン焼付けベンガラ 0.5質量%
シリコーン焼付け群青 0.1質量%
セリサイト 30質量%
マイカ 19.4質量%
シリカ 10質量%
成分C:ジメチコン 5質量%
オレイン酸オクチルドデシル 5質量%
[Prescription 1]
Component A: Nylon 6 short fiber 5% by mass
Component B: Silicone baking treatment Titanium dioxide 20% by mass
Silicone-baked yellow iron oxide 5% by mass
Silicone baked bengara 0.5% by mass
Silicone baked ultramarine 0.1% by mass
Sericite 30% by mass
Mica 19.4% by mass
Silica 10% by mass
Component C: Dimethicone 5% by mass
Octyldodecyl oleate 5% by mass

実施例2〜6、比較例1〜4
紡糸口金のスリット形状を変更することにより、単糸の断面形状における開口角度、最大長、最大径を有する円形の直径、単糸繊度が表1に示すものとなるようにした以外は、実施例1と同様にしてマルチフィラメントを得、短繊維にした後、処方1によりファンデーションを得た。
Examples 2-6, Comparative Examples 1-4
Except for changing the slit shape of the spinneret so that the opening angle, the maximum length, the circular diameter having the maximum diameter, and the single yarn fineness in the cross-sectional shape of the single yarn are as shown in Table 1. In the same manner as in No. 1, multifilaments were obtained and made into short fibers, and then a foundation was obtained according to Formula 1.

実施例7
単糸の断面形状が図1(A)の形状となるようにスリットを穿孔した紡糸口金を用いた以外は実施例1と同様にしてマルチフィラメントを得た。このとき、得られたマルチフィラメントの単糸の断面形状は図1(A)に示すもの(2個の円形は大きさ、開口角度が同じ)であり、連結部が2点、2個の円形の開口角度が50°、最大長が30μm、最大径を有する円形の直径20μm、単糸繊度2.5dtexであった。そして、実施例1と同様にして短繊維にした後、処方1によりファンデーションを得た。
Example 7
A multifilament was obtained in the same manner as in Example 1, except that a spinneret having a slit perforated so that the cross-sectional shape of the single yarn became the shape shown in FIG. At this time, the cross-sectional shape of the obtained multifilament single yarn is as shown in FIG. 1A (the two circles have the same size and the same opening angle), and there are two connecting portions and two circles. The opening angle was 50 °, the maximum length was 30 μm, the circular diameter having the maximum diameter was 20 μm, and the single yarn fineness was 2.5 dtex. And it was made into the short fiber like Example 1, and the foundation was obtained by the prescription 1.

実施例8〜12、比較例5〜8
紡糸口金のスリット形状を変更することにより、単糸の断面形状における開口角度、最大長、最大径を有する円形の直径、単糸繊度が表1に示すものとなるようにした以外は、実施例7と同様にしてマルチフィラメントを得、短繊維にした後、処方1によりファンデーションを得た。
Examples 8-12, Comparative Examples 5-8
Except for changing the slit shape of the spinneret so that the opening angle, the maximum length, the circular diameter having the maximum diameter, and the single yarn fineness in the cross-sectional shape of the single yarn are as shown in Table 1. In the same manner as in No. 7, multifilaments were obtained and made into short fibers.

比較例9
単糸の断面形状が開口部を有する1個の円形からなるC型断面形状となるようにスリットを穿孔した紡糸口金を用いた以外は、実施例1と同様にしてマルチフィラメントを得た。このとき、得られたマルチフィラメントの単糸の断面形状はC型のものであり、開口角度が90°、最大長(直径)が25μm、単糸繊度2.5dtexであった。そして、実施例1と同様にして短繊維にした後、処方1によりファンデーションを得た。
Comparative Example 9
A multifilament was obtained in the same manner as in Example 1 except that a spinneret was used in which slits were perforated so that the single yarn had a circular C-shaped cross-section with an opening. At this time, the cross-sectional shape of the obtained multifilament single yarn was C type, the opening angle was 90 °, the maximum length (diameter) was 25 μm, and the single yarn fineness was 2.5 dtex. And it was made into the short fiber like Example 1, and the foundation was obtained by the prescription 1.

比較例10
単糸の断面形状が井型断面形状となるようにスリットを穿孔した紡糸口金を用いた以外は実施例1と同様にしてマルチフィラメントを得た。このとき、得られたマルチフィラメントの単糸の断面形状は井型のものであり、最大長が40μm、単糸繊度2.5dtexであった。そして、実施例1と同様にして短繊維にした後、処方1によりファンデーションを得た。
Comparative Example 10
A multifilament was obtained in the same manner as in Example 1 except that a spinneret with a slit perforated so that the cross-sectional shape of the single yarn had a well-shaped cross-sectional shape was used. At this time, the cross-sectional shape of the obtained multifilament single yarn was a well-shaped one, the maximum length was 40 μm, and the single yarn fineness was 2.5 dtex. And it was made into the short fiber like Example 1, and the foundation was obtained by the prescription 1.

参考例1
繊維を含有せず、以下の処方2に示す成分と含有量からなるファンデーションを作製した。
〔処方2〕
成分A:ナイロン6短繊維 0質量%
成分B:シリコーン焼付け処理二酸化チタン 20質量%
シリコーン焼付け黄酸化鉄 5質量%
シリコーン焼付けベンガラ 0.5質量%
シリコーン焼付け群青 0.1質量%
セリサイト 30質量%
マイカ 24.4質量%
シリカ 10質量%
成分C:ジメチコン 5質量%
オレイン酸オクチルドデシル 5質量%
Reference example 1
The foundation which consists of a component and content shown to the following prescription 2 without producing a fiber was produced.
[Prescription 2]
Component A: Nylon 6 short fiber 0% by mass
Component B: Silicone baking treatment Titanium dioxide 20% by mass
Silicone-baked yellow iron oxide 5% by mass
Silicone baked bengara 0.5% by mass
Silicone baked ultramarine 0.1% by mass
Sericite 30% by mass
Mica 24.4% by mass
Silica 10% by mass
Component C: Dimethicone 5% by mass
Octyldodecyl oleate 5% by mass

実施例1〜12、比較例1〜10、参考例1で得られた異形断面繊維、ファンデーションの評価結果を表1に示す。   Table 1 shows the evaluation results of the modified cross-section fibers and foundations obtained in Examples 1 to 12, Comparative Examples 1 to 10, and Reference Example 1.

表1から明らかなように、実施例1〜12の異形断面繊維は、単糸の断面形状が本発明の形状を満足するものであったため、これらの異形断面繊維を含有させたファンデーションは、光の反射、拡散効果に優れ、良好なつや感と自然な素肌感を得ることができ、塗布時には異物感がなく、滑らかな使用感を有するものであった。
一方、比較例1、5の異形断面繊維は、開口角度が150°であったため、これらの異形断面繊維を含有させたファンデーションは、光の反射、拡散効果を有するものの、塗布時に異物感が感じられた。比較例2、6の異形断面繊維は、開口角度が20°であったため、これらの異形断面繊維を含有させたファンデーションは、塗布時の異物感は感じられないが、光の反射、拡散効果が不十分であり、良好なつや感と自然な素肌感を得ることができなかった。比較例3、7の異形断面繊維は、最大長が大きすぎたため、比較例4、8の異形断面繊維は単糸繊度が大きすぎたため、これらの異形断面繊維を含有させたファンデーションはいずれも塗布時に異物感が感じられるものであった。また、比較例9の異形断面繊維はC型のものであったため、光の反射、拡散効果が不十分であり、この異形断面繊維を含有させたファンデーションは良好なつや感と自然な素肌感を得ることができなかった。比較例10の異形断面繊維は井型のものであったため、ソフトな光の反射、拡散効果が得られず、この異形断面繊維を含有させたファンデーションはぎらぎら感のあるものとなり、良好なつや感と自然な素肌感を得ることができなかった。さらには塗布時に異物感が感じられるものであった。
As is clear from Table 1, the modified cross-section fibers of Examples 1 to 12 were those in which the cross-sectional shape of the single yarn satisfied the shape of the present invention. It was excellent in the reflection and diffusion effects of the film, was able to obtain a good gloss and a natural feeling of the skin, had no feeling of foreign matters during application, and had a smooth feeling of use.
On the other hand, the irregular cross-section fibers of Comparative Examples 1 and 5 had an opening angle of 150 °. Therefore, the foundation containing these irregular cross-section fibers has a light reflecting and diffusing effect, but feels a foreign object feeling during coating. It was. Since the irregular cross-section fibers of Comparative Examples 2 and 6 had an opening angle of 20 °, the foundation containing these irregular cross-section fibers did not feel a foreign object feeling at the time of application, but had a light reflection and diffusion effect. It was insufficient, and a good gloss and natural skin feeling could not be obtained. Since the maximum length of the irregular cross-section fibers of Comparative Examples 3 and 7 was too large, the monofilament fineness of the irregular cross-section fibers of Comparative Examples 4 and 8 was too large. Therefore, any foundation containing these irregular cross-section fibers was applied. Sometimes a foreign body sensation was felt. Further, since the irregular cross-section fiber of Comparative Example 9 was a C-type, the light reflection and diffusion effects were insufficient, and the foundation containing this irregular cross-section fiber had good gloss and natural skin feeling. Couldn't get. Since the modified cross-section fiber of Comparative Example 10 was a well-shaped fiber, a soft light reflection and diffusion effect could not be obtained, and the foundation containing this modified cross-section fiber had a glare feeling and a good gloss feeling. I could not get a natural skin feeling. Furthermore, a foreign material sensation was felt during application.

実施例13
相対粘度3.50のポリアミド6を通常のエクストルーダー型溶融紡糸装置を使用して溶融紡糸を行った。このとき、単糸の断面形状が図1(C)の形状となるようにスリットを穿孔した紡糸口金を用いて、256℃で溶融紡糸した。そして、紡糸された糸条を冷却固化した後、第1ローラ(温度25℃)の表面速度を3111m/分、第2ローラ(温度110℃)の表面速度を4200m/分とし、延伸倍率1.35倍で延伸し、速度4000m/分で巻き取り、60dtex/24fのマルチフィラメントを得た。得られたマルチフィラメントの単糸の断面形状は図1(C)に示すもの(2個の円形は大きさ、開口角度が同じ)であり、連結部が1点、2個の円形の開口角度が50°、最大長が25μm、最大径を有する円形の直径20μm、単糸繊度2.5dtexであった。
そして、ギロチンカッターを用いてカットし、繊維長1000μmの短繊維(成分D)とし、以下の処方3に示す成分Eと含有量からなるマスカラを得た。
Example 13
Polyamide 6 having a relative viscosity of 3.50 was melt-spun using an ordinary extruder-type melt spinning apparatus. At this time, melt spinning was performed at 256 ° C. using a spinneret having a slit perforated so that the cross-sectional shape of the single yarn became the shape shown in FIG. After spinning and solidifying the spun yarn, the surface speed of the first roller (temperature 25 ° C.) is 3111 m / min, the surface speed of the second roller (temperature 110 ° C.) is 4200 m / min, and the draw ratio is 1. The film was stretched 35 times and wound at a speed of 4000 m / min to obtain a 60 dtex / 24f multifilament. The cross-sectional shape of the obtained multifilament single yarn is as shown in FIG. 1C (the two circles have the same size and the same opening angle), and have one connecting point and two circular opening angles. Was 50 °, the maximum length was 25 μm, the circular diameter having the maximum diameter was 20 μm, and the single yarn fineness was 2.5 dtex.
And it cut using the guillotine cutter, it was set as the short fiber (component D) of fiber length 1000 micrometers, and the mascara which consists of the component E and content shown to the following prescription 3 was obtained.

〔処方3〕
成分D:ナイロン6短繊維 5.0質量%
成分E:ポリアクリル酸エステルエマルジョン 50.0質量%
ポリメタクリル酸 2.0質量%
トリエタノールアミン 2.5質量%
ブチレングリコール 3.0質量%
塩化ナトリウム 0.5質量%
防腐剤 0.2質量%
シリカ 2.0質量%
顔料 1.0質量%
香料 0.1質量%
精製水 33.7質量%
[Prescription 3]
Component D: Nylon 6 short fiber 5.0 mass%
Component E: Polyacrylic ester emulsion 50.0% by mass
Polymethacrylic acid 2.0% by mass
Triethanolamine 2.5% by mass
Butylene glycol 3.0% by mass
Sodium chloride 0.5% by mass
Preservative 0.2% by mass
Silica 2.0% by mass
Pigment 1.0% by mass
Fragrance 0.1% by mass
Purified water 33.7% by mass

実施例14〜18、比較例11〜13
紡糸口金のスリット形状を変更することにより、単糸の断面形状における開口角度、最大長、最大径を有する円形の直径、単糸繊度が表2に示すものとなるようにした以外は、実施例13と同様にしてマルチフィラメントを得、短繊維にした後、処方3によりマスカラを得た。
Examples 14-18, Comparative Examples 11-13
Examples except that the opening angle, the maximum length, the circular diameter having the maximum diameter, and the single yarn fineness in the cross-sectional shape of the single yarn are changed to those shown in Table 2 by changing the slit shape of the spinneret. A multifilament was obtained in the same manner as in No. 13 to make a short fiber, and then a mascara was obtained according to formulation 3.

比較例14
単糸の断面形状が開口部を有する1個の円形からなるC型断面形状となるようにスリットを穿孔した紡糸口金を用いた以外は、実施例13と同様にしてマルチフィラメントを得た。このとき、得られたマルチフィラメントの単糸の断面形状はC型のものであり、開口角度が90°、最大長(直径)が25μm、単糸繊度2.5dtexであった。そして、実施例13と同様にして短繊維にした後、処方3によりマスカラを得た。
Comparative Example 14
A multifilament was obtained in the same manner as in Example 13 except that a spinneret was used in which a slit was perforated so that the cross-sectional shape of the single yarn was a single C-shaped cross-section with an opening. At this time, the cross-sectional shape of the obtained multifilament single yarn was C type, the opening angle was 90 °, the maximum length (diameter) was 25 μm, and the single yarn fineness was 2.5 dtex. And after making it a short fiber like Example 13, the mascara was obtained by the prescription 3.

比較例15
単糸の断面形状が井型断面形状となるようにスリットを穿孔した紡糸口金を用いた以外は実施例13と同様にしてマルチフィラメントを得た。このとき、得られたマルチフィラメントの単糸の断面形状は井型のものであり、最大長が40μm、単糸繊度2.5dtexであった。そして、実施例13と同様にして短繊維にした後、処方3によりマスカラを得た。
Comparative Example 15
A multifilament was obtained in the same manner as in Example 13, except that a spinneret having a slit perforated so that the cross-sectional shape of the single yarn had a well-shaped cross-sectional shape was used. At this time, the cross-sectional shape of the obtained multifilament single yarn was a well-shaped one, the maximum length was 40 μm, and the single yarn fineness was 2.5 dtex. And after making it a short fiber like Example 13, the mascara was obtained by the prescription 3.

表2から明らかなように、実施例13〜18の異形断面繊維は、単糸の断面形状が本発明の形状を満足するものであったため、これらの異形断面繊維を含有させたマスカラは、ボリュームアップ効果に優れ、塗布時には異物感がなく、滑らかな使用感を有するものであった。
一方、比較例11の異形断面繊維は、開口角度が150°であったため、この異形断面繊維を含有させたマスカラは、塗布時に異物感が感じられるものであった。比較例12の異形断面繊維は、最大長が大きすぎたため、比較例13の異形断面繊維は単糸繊度が大きすぎたため、これらの異形断面繊維を含有させたマスカラは、塗布時に異物感が感じられるものであった。また、比較例14の異形断面繊維はC型のものであったため、この異形断面繊維を含有させたマスカラは、ボリュームアップ効果が不十分なものであった。比較例15の異形断面繊維は井型のものであったため、この異形断面繊維を含有させたマスカラはボリュームアップ効果が不十分で、異物感も感じるものであった。
As is apparent from Table 2, the modified cross-section fibers of Examples 13 to 18 had a cross-sectional shape of a single yarn satisfying the shape of the present invention, so that the mascara containing these modified cross-section fibers was a volume. It was excellent in the up effect, had no foreign material feeling during application, and had a smooth use feeling.
On the other hand, since the irregular cross-section fiber of Comparative Example 11 had an opening angle of 150 °, the mascara containing the irregular cross-section fiber felt a foreign body feeling during application. Since the irregular cross-section fiber of Comparative Example 12 has a maximum length that is too large, the irregular cross-section fiber of Comparative Example 13 has a single yarn fineness that is too large. It was Moreover, since the irregular cross-section fiber of Comparative Example 14 was a C-type, the mascara containing the irregular cross-section fiber had an insufficient volume-up effect. Since the irregular cross-section fiber of Comparative Example 15 was a well-shaped fiber, the mascara containing the irregular cross-section fiber had an insufficient volume-up effect and felt a foreign object feeling.

本発明の異形断面繊維の単糸の断面形状の実施態様を示す模式図である。It is a schematic diagram which shows the embodiment of the cross-sectional shape of the single yarn of the irregular cross-section fiber of this invention. 本発明以外の異形断面繊維の単糸の断面形状の実施態様を示す模式図である。It is a schematic diagram which shows the embodiment of the cross-sectional shape of the single yarn of the irregular cross-section fiber other than this invention. 本発明の異形断面繊維の開口角度を示す説明図である。It is explanatory drawing which shows the opening angle of the irregular cross-section fiber of this invention. 本発明以外の異形断面繊維の単糸の断面形状の実施態様を示す模式図である。It is a schematic diagram which shows the embodiment of the cross-sectional shape of the single yarn of the irregular cross-section fiber other than this invention.

Claims (2)

繊維軸方向に対して垂直に切断した単糸の断面形状が、開口部を有する2個の円形が少なくとも1点で連結した形状を呈する異形断面繊維であって、2個の円形の開口部が閉塞することなく連結されており、断面形状における任意の2点を結ぶ最大長が最大径を有する円形の直径の1.1倍以上であり、かつ最大長が5〜100μm、2個の円形ともに開口角度が30〜140°であり、単糸繊度が1.0〜7.0dtexであることを特徴とする異形断面繊維。 The cross-sectional shape of a single yarn cut perpendicular to the fiber axis direction is a modified cross-section fiber having a shape in which two circular shapes having openings are connected at least at one point, and the two circular openings are It is connected without closing, the maximum length connecting any two points in the cross-sectional shape is 1.1 times or more of the circular diameter having the maximum diameter, and the maximum length is 5 to 100 μm. An irregular cross-section fiber having an opening angle of 30 to 140 ° and a single yarn fineness of 1.0 to 7.0 dtex. 請求項1記載の異形断面繊維を含有するメークアップ化粧料。
A makeup cosmetic containing the modified cross-section fiber according to claim 1.
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JP2014205633A (en) * 2013-04-12 2014-10-30 ジェイオーコスメティックス株式会社 Cosmetic and cosmetic fiber

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JPH11181617A (en) * 1997-12-15 1999-07-06 Toray Ind Inc Fiber having modified cross section
JP2005132723A (en) * 2003-10-28 2005-05-26 Pola Chem Ind Inc Makeup cosmetic comprising modified cross-section fiber
JP2007051106A (en) * 2005-08-19 2007-03-01 Toray Ind Inc Eyelash cosmetic
JP2007262620A (en) * 2006-03-29 2007-10-11 Gunze Ltd Spinneret for modified cross section fiber, and modified cross section fiber

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JPH11181617A (en) * 1997-12-15 1999-07-06 Toray Ind Inc Fiber having modified cross section
JP2005132723A (en) * 2003-10-28 2005-05-26 Pola Chem Ind Inc Makeup cosmetic comprising modified cross-section fiber
JP2007051106A (en) * 2005-08-19 2007-03-01 Toray Ind Inc Eyelash cosmetic
JP2007262620A (en) * 2006-03-29 2007-10-11 Gunze Ltd Spinneret for modified cross section fiber, and modified cross section fiber

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Publication number Priority date Publication date Assignee Title
JP2014205633A (en) * 2013-04-12 2014-10-30 ジェイオーコスメティックス株式会社 Cosmetic and cosmetic fiber

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