JP2009214359A - Mold releasing film - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a mold releasing film lightly peeled when peeled with peeling force and excelling in holding power during preservation and also excelling in atmospheric exposure resistance and non-migration property. <P>SOLUTION: This mold releasing film is formed by coating at least one side of a polyester film with a coating material mainly composed of a curable silicone. The coating material includes, as main components, a solvent-type silicone whose content percentage of a vinyl group in a polysiloxane chain containing the vinyl group is 3% or more in units of siloxane; a non-solvent type silicone whose viscosity is 1000 mPa s or less and whose content percentage of a vinyl group in a polysiloxane chain containing the vinyl group is 3% or more in units of siloxane; and a reactive double peeling regulator. An SiH/Vi ratio in the coating material is 2.5-7. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  Due to its excellent properties, the release film based on polyester film is used for manufacturing various display components such as liquid crystal polarizing plates, retardation plate components, PDP components, and organic EL components. Are used for various optical applications. Among them, particularly for release films for liquid crystal polarizing plates, there is a rapid increase in production with the remarkable growth of the LCD market in recent years. In addition, along with lowering the price of LCDs, it has become a major issue to improve the manufacturing yield and increase the manufacturing speed in order to reduce the cost of the members.

  The demand for high-speed manufacturing has been extended to the process of attaching a polarizing plate to a liquid crystal panel. In order to shorten the tact time at the time of attaching the LCD polarizing plate to the liquid crystal panel, it is required to increase the peeling speed of the release film, and the conventional peeling speed of several m / min to 20 m / min or more has been put into practical use. If the peeling force at the time of high-speed peeling of 20 m / min or more is high, when the release film is peeled off from the LCD polarizing plate, the suction force on the deflection plate fixing side is lost, and the problem that the position of the deflection plate is displaced occurs. Once a problem occurs, the automation line stops and a reduction in productivity is forced. A measure to increase the suction force on the fixed side can be considered, but there is a limit because a trace remains on the deflecting plate.

  Thus, while light peeling is required at the time of peeling, it must be in close contact with the adhesive layer with sufficient holding power in the process until peeling. In particular, when the polarizing plate is cut or punched, or due to the difference in the degree of expansion and contraction of the material due to changes in temperature and humidity during storage, it tends to cause creaking and floating, which leads to a decrease in productivity.

In conventional films, it is not always sufficient to achieve both the light peeling at the time of peeling at a high speed and the relatively heavy peeling at a low speed, which is closely related to the holding force. When the design of the layer was changed, the transferability due to the components not fixed to the polymer, the air exposure property of heavy peeling due to contact with the release surface deteriorated, and the performance was not always sufficient.
JP 2001-290141 A JP 2001-47580 A

  The present invention has been made in view of the above-mentioned circumstances, and the problem to be solved is that peeling at high speed corresponding to actual peeling is light, and peeling at low speed deeply related to holding force during storage is compared. The purpose of the present invention is to provide a release film that is heavy, less affected by atmospheric exposure, and excellent in non-migration.

  As a result of intensive investigations in view of the above-described actual situation, the present inventor has found that the above-described problems can be solved by using silicone having a specific structure and configuration as a paint, and has completed the present invention.

  That is, the gist of the present invention is a release film in which a coating mainly composed of curable silicone is applied to at least one surface of a polyester film, and the coating material contains a vinyl group in a polysiloxane chain containing a vinyl group. A solvent-type silicone having a siloxane unit of 3% or more and a solvent-free type having a viscosity of 1000 mPa · s or less and a vinyl group-containing polysiloxane chain content of 3% or more of siloxane units. It exists in the release film characterized by containing silicone and a reactive heavy peeling regulator as a main component, and SiH / Vi ratio in a coating material being 2.5-7.

Hereinafter, the present invention will be described in more detail.
In the present invention, the polyester used for the polyester film may be a homopolyester or a copolyester. In the case of a homopolyester, those obtained by polycondensation of an aromatic dicarboxylic acid and an aliphatic glycol are preferred. Examples of the aromatic dicarboxylic acid include terephthalic acid and 2,6-naphthalenedicarboxylic acid, and examples of the aliphatic glycol include ethylene glycol, diethylene glycol, and 1,4-cyclohexanedimethanol. Representative polyesters include polyethylene terephthalate (PET), polyethylene-2,6-naphthalenedicarboxylate (PEN), and the like.

  On the other hand, in the case of a copolymerized polyester, a copolymer containing 30 mol% or less of the third component is preferable. Examples of the dicarboxylic acid component of the copolyester include one or two of isophthalic acid, terephthalic acid phthalate, 2,6-naphthalenedicarboxylic acid, adipic acid, sebacic acid, oxycarboxylic acid (for example, P-oxybenzoic acid, etc.) The glycol component includes one or more of ethylene glycol, diethylene glycol, propylene glycol, butanediol, 1,4-cyclohexanedimethanol, neopentyl glycol, and the like.

  In any case, the polyester referred to in the present invention is usually 80 mol% or more, preferably 90 mol% or more of polyethylene terephthalate having ethylene terephthalate units and polyethylene-2,6-naphthalate having ethylene-2,6-naphthalate units. Refers to a polyester that is the like.

  In the polyester layer in the present invention, it is preferable to blend particles for the main purpose of imparting slipperiness. The kind of the particle to be blended is not particularly limited as long as it is a particle capable of imparting slipperiness. Specific examples thereof include silica, calcium carbonate, magnesium carbonate, barium carbonate, calcium sulfate, calcium phosphate, and magnesium phosphate. , Particles of kaolin, aluminum oxide, titanium oxide and the like. Further, the heat-resistant organic particles described in JP-B-59-5216, JP-A-59-217755 and the like may be used. Examples of other heat-resistant organic particles include thermosetting urea resins, thermosetting phenol resins, thermosetting epoxy resins, benzoguanamine resins, and the like. Furthermore, precipitated particles obtained by precipitating and finely dispersing a part of a metal compound such as a catalyst during the polyester production process can also be used. On the other hand, the shape of the particles to be used is not particularly limited, and any of a spherical shape, a block shape, a rod shape, a flat shape, and the like may be used. Moreover, there is no restriction | limiting in particular also about the hardness, specific gravity, a color, etc. These series of particles may be used in combination of two or more if necessary.

  Moreover, it is preferable that the average particle diameter of the particle | grains contained in a polyester film in this invention satisfies 0.1-5 micrometers, More preferably, it is 0.5-3 micrometers, Most preferably, it is the range of 0.5-2 micrometers. . When the average particle size is less than 0.1 μm, the particles tend to aggregate and dispersibility becomes insufficient. On the other hand, when the average particle size exceeds 5 μm, the surface roughness of the film becomes too rough and is separated in the subsequent process. In some cases, such as when a mold layer is provided, problems may occur.

  Furthermore, the particle content in the polyester preferably satisfies 0.01 to 5% by weight, more preferably 0.01 to 3% by weight. When the particle content is less than 0.01% by weight, the slipperiness of the film may be insufficient. On the other hand, when the content exceeds 5% by weight, the smoothness of the film surface is insufficient. It may become.

  In addition, conventionally known antioxidants, heat stabilizers, lubricants, dyes, pigments and the like can be added to the polyester film in the present invention within the range not impairing the gist of the present invention in addition to the above-mentioned particles.

  The thickness of the polyester film constituting the release film of the present invention is preferably a thin film in terms of cost, but on the other hand, it is necessary to ensure film flatness. When the thickness of the polyester film constituting the release film is too thin, the film flatness is often impaired by wrinkles due to heat treatment during processing. In addition, when a force is applied after being processed into a polarizing plate, a thin film may not have a sufficient protective function against an adhesive. From this viewpoint, the thickness of the polyester film constituting the release film in the present invention is preferably 12 to 125 μm, and more preferably 25 to 75 μm.

  Next, although the manufacture example of the polyester film in this invention is demonstrated concretely, it is not limited to the following manufacture examples at all. That is, a method of using the polyester raw material described above and cooling and solidifying a molten sheet extruded from a die with a cooling roll to obtain an unstretched sheet is preferable. In this case, in order to improve the flatness of the sheet, it is necessary to improve the adhesion between the sheet and the rotary cooling drum, and an electrostatic application adhesion method and / or a liquid application adhesion method are preferably employed. Next, the obtained unstretched sheet is stretched in the biaxial direction. In that case, first, the unstretched sheet is stretched in one direction by a roll or a tenter type stretching machine. The stretching temperature is usually 70 to 120 ° C., preferably 80 to 110 ° C., and the stretching ratio is usually 2.5 to 7 times, preferably 3.0 to 6 times. Subsequently, the extending | stretching temperature orthogonal to the extending | stretching direction of the 1st step is 130-170 degreeC normally, and a draw ratio is 3.0-7 times normally, Preferably it is 3.5-6 times. Subsequently, heat treatment is performed at a temperature of 180 to 270 ° C. under tension or under relaxation within 30% to obtain a biaxially oriented film.

In the above-described stretching, a method of performing unidirectional stretching in two or more stages can be employed. In that case, it is preferable to carry out so that the draw ratios in the two directions finally fall within the above ranges. It is also possible to perform simultaneous biaxial stretching.

  The simultaneous biaxial stretching method is a method in which the unstretched sheet is usually stretched and oriented in the machine direction and the width direction at 70 to 120 ° C., preferably 80 to 110 ° C., and the stretching ratio is as follows. Is 4 to 50 times, preferably 7 to 35 times, and more preferably 10 to 25 times in terms of area magnification. Subsequently, heat treatment is performed at a temperature of 170 to 250 ° C. under tension or under relaxation within 30% to obtain a stretched oriented film.

  As for the simultaneous biaxial stretching apparatus using the above-described stretching method, a conventionally known stretching method such as a screw method, a pantograph method, a linear drive method, or the like can be adopted. The “screw method” is a method in which a clip is placed in the groove of the screw to increase the clip interval. The “pantograph method” is a method of expanding the clip interval using a pantograph. The “linear motor system” has an advantage that the clip interval can be arbitrarily adjusted by applying the linear motor principle and controlling the clips individually.

  Further, simultaneous biaxial stretching may be performed in two or more stages. In that case, stretching may be performed in one tenter or a plurality of tenters may be used in combination.

  In the present invention, when the polyester film constituting the release film is stretched by simultaneous biaxial stretching, conventionally, when the area magnification becomes large by sequential biaxial stretching, a problem such as breaking at the time of stretching occurs. However, since the film following property is good in the simultaneous biaxial stretching, the area magnification can be further increased in the film longitudinal direction and the width direction as compared with the sequential biaxial stretching. It is preferable because a polyester film having a small thickness can be produced.

  In addition, a so-called coating stretching method (in-line coating) for treating the film surface during the above-described stretching process of the polyester film can be performed. Although it is not limited to the following, for example, in the sequential biaxial stretching, in particular, the first-stage stretching is completed, and the coating treatment can be performed before the second-stage stretching.

  The release layer constituting the release film of the present invention is a curable silicone resin having releasability, which includes an addition reaction of a group having a vinyl group and a silicon-hydrogen bond in a curing process (so-called addition type silicone). is there.

  In the present invention, the silicone in which the content ratio of vinyl groups in the polysiloxane chain containing vinyl groups is 3% or more in terms of siloxane units refers to polysiloxanes having vinyl groups, which are often the main component in addition-type silicones, When the siloxane unit forming the skeleton (a unit containing one Si atom and generally represented by the following formula) is counted as one unit, the one containing a vinyl group is 3% or more.

  The energy source in the curing treatment is generally heat treatment, but ultraviolet irradiation and electron beam irradiation can be used in combination.

  The meaning of the solvent-type silicone in the present invention is a silicone called “gum” having a viscosity of about 1 million mPa · s or more, and generally dissolved in a solvent for easy handling. Supplied in. In an actual paint, the viscosity when a 30% toluene solution is used is about 1000 mPa · s or more, preferably 5000 mPa · s or more.

  The solventless silicone used in the present invention is a silicone having a viscosity that can be applied without being diluted in a solvent, and consists of a short polysiloxane chain having a smaller molecule than the solvent type. For example, the gum has a degree of siloxane polymerization of several thousand to several tens of thousands, while the solventless type generally has several tens to several hundreds. The vinyl groups that serve as crosslinking reaction points for addition-type silicones are often located at the end and inside of the chain, but the vinyl group at the end is much faster than the inner vinyl group because it has less steric hindrance during the reaction. react. Accordingly, the solventless type silicone has an extremely high number of highly reactive terminal vinyl groups as compared with the solvent type, and therefore has an advantage that the curing speed is increased when it is used as a paint.

  On the other hand, it is inferior in the coating property at the time of applying to a polyester base material. It is easy to repel due to its low viscosity, and it is extremely difficult to obtain a good surface shape particularly in thin film coating usually performed in the production of polyester release films.

  In the present invention, taking advantage of such a solvent-free silicone and making up for the shortcomings, it is used in combination with a high viscosity solvent silicone. The mixing ratio is 10/90 to 95/5, preferably 40/60 to 90/10 in terms of the solid content weight (solvent type / solventless type).

  The reactive heavy release adjusting agent used in the present invention is a type of heavy release adjusting agent that reacts with the siloxane polymer of the release coating and is taken in when the coating is dried. The chemical structure is not particularly limited as long as it does not depart from the scope of the present invention, but preferred examples include those having a vinyl group as a reactive group and generally called MQ resin or MDQ resin. The mixing ratio can be arbitrarily adjusted in order to obtain a desired release, but in the weight of solid content, {heavy release regulator / (solvent-free type, sum of solvent-type silicone)} is 1/99 to 50/50. The ratio is preferably 2/98 to 30/70. When the amount is too large, the migration property is increased even though it is reactive, and in general, the release modifier often has a low viscosity, so that it is difficult to obtain a good surface shape.

  In the addition-type silicone used in the present invention, the content ratio (SiH / Vi ratio) of siloxane vinyl groups and ≡SiH groups and vinyl groups involved in the crosslinking reaction is important. Usually, the ≡SiH group is used so as to be excessive, and this ratio is often set to about 1.2 to 2.0 (Akihiko Ogawa, Convertec p.49 (1996)). Silicone having a vinyl group content of 3% or more in terms of siloxane units in the polysiloxane chain containing vinyl groups used in the present invention has a large absolute number of functional groups. Since the absolute number also increases, the excess rate is usually modest. However, the present inventor has found that when such a silicone is applied as a thin film to a polyester film, the preferred region is greatly different from that conventionally known. A preferred SiH / Vi ratio is 2.5-7, more preferably 3.0-5.0.

  Examples of the dilution solvent in the present invention include aromatic hydrocarbons such as toluene, aliphatic hydrocarbons such as hexane, heptane, and isooctane, esters such as ethyl acetate and butyl acetate, ethyl methyl ketone (MEK), and isobutyl methyl ketone. Examples thereof include ketones such as ethanol, alcohols such as ethanol and 2-propanol, and ethers such as diisopropyl ether and dibutyl ether, and are used singly or in combination in consideration of solubility, coating property, boiling point and the like.

  Further, in order to adjust the properties of the release layer, auxiliary agents such as a reaction regulator and an adhesion enhancer may be used in combination as long as the gist of the present invention is not impaired.

The coating amount of the release layer (after drying) is preferably 0.01 to 1 g / m ² , preferably 0.04 to 0.5 g / m ² , because the polyester film is flat. m ² , more preferably in the range of 0.06 to 0.3 g / m ² . When the coating amount of the release layer is too small, the peeling force may not be stable. On the other hand, when there is too much coating amount, there exists a concern of an increase in transferability and blocking.

  In the present invention, conventionally known coating methods such as multi-roll coating, reverse gravure coating, direct gravure coating, bar coating, and die coating can be used as a method for providing a release layer on the polyester film. As for the coating method, there is a description example in “Coating method” published by Yoji Harasaki in 1979.

  Moreover, you may give surface treatments, such as a corona treatment and a plasma treatment, to the polyester film which comprises the release film in this invention previously. Furthermore, the polyester film constituting the release film in the present invention may be provided with a coating layer such as an adhesive layer and an antistatic layer in advance.

  According to the present invention, it is possible to provide a release film that is lightly peeled at the time of peeling of the peeling force, excellent in holding power during storage, and excellent in resistance to atmospheric exposure and non-migration, and its industrial value is extremely high. high.

  EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to a following example, unless the summary is exceeded. The measuring method used in the present invention is as follows.

(1) Measurement of peeling force A (peeling speed 0.3 m / min) After affixing an adhesive tape (“No. 31B” manufactured by Nitto Denko Corporation) to the release surface of the sample film, a size of 50 mm × 300 mm The peel force after standing for 1 hour at room temperature was measured. The peeling force was “Intesco Model 2001” manufactured by Intesco Co., Ltd., and 180 ° peeling was performed under the condition of a tensile speed of 0.3 (m / min).

(2) Measurement of peeling force B (peeling speed 30 m / min) After sticking an adhesive tape (“No. 31B” manufactured by Nitto Denko Corporation) on the release surface of the sample film, cut into a size of 50 mm × 300 mm The peel strength after standing at room temperature for 1 hour was measured. The peel strength was measured using a high-speed peel tester “TE-702 type” manufactured by Tester Sangyo Co., Ltd. 180 ° peeling was performed at a peeling speed of 30 (m / min) by a method of peeling the 31B adhesive tape side.

(3) Measurement of peeling force C (peeling force after exposure to the atmosphere) A sample film was cut to A4 size and suspended for 24 hours in a string passed into a laboratory (non-clean environment) adjusted to room temperature 23 ° C and humidity 50% RH Lower. Adhesive tape ("No. 502" light-colored release paper side manufactured by Nitto Denko Corporation is used) is attached to the release surface, then cut to a size of 50mm x 300mm, and peel strength after standing at room temperature for 1 hour Was measured. The peeling force was “Intesco Model 2001” manufactured by Intesco Co., Ltd., and 180 ° peeling was performed under the condition of a tensile speed of 0.3 (m / min).

(4) Measurement of peeling force D (atmosphere unexposed peeling force) Instead of hanging the sample film into the laboratory in the measurement of peeling force C, place it in the same laboratory without putting it in a polyethylene bag and touching the outside air. The peel force was measured in the same manner except that it was left for 24 hours.

(5) Transferability Evaluation Adhesion Rate of Release Film Sample film was cut to A4 size, and 75 μm thick biaxially stretched PET film (Mitsubishi Chemical Polyester Film Co., Ltd .: Diafoil T100-75) was stacked on the release surface. Pressing is performed at 60 ° C. and a pressure of 1 MPa for 2 hours. A 75 μm-thick film pressed against this release surface is used as a migration evaluation film.
Similarly, a 75 μm-thick biaxially stretched PET film (same) is pressed against an untreated PET film to obtain a reference film. Adhesive tape (“No. 31B” manufactured by Nitto Denko Corporation) is applied to the pressed surface of each film, then cut to a size of 50 mm × 300 mm, and the peel strength after standing for 1 hour at room temperature. It was measured. The peeling force was “Intesco Model 2001” manufactured by Intesco Co., Ltd., and 180 ° peeling was performed under the condition of a tensile speed of 0.3 (m / min).

Transferability evaluation adhesion rate (%) = (Peeling force of transferability evaluation film / Peeling force of reference film) × 100
In a film having a high migration property, a large amount of silicone adheres to the pressed film, so that the peeling force of the pressure-sensitive adhesive tape is reduced and the migration evaluation adhesion rate (%) is also reduced. 90% or more is preferable, and 95% or more is more preferable.
(6) Vinyl group content of siloxane in paint, ≡SiH group and vinyl group content ratio (SiH / Vi ratio)
The vinyl group content of siloxane in the paint and the content ratio of ≡SiH group and vinyl group (SiH / Vi ratio) were calculated by NMR analysis of the paint alone or a mixture.

Example 1:
A release agent having the following composition is applied to a 38 μm thick biaxially stretched PET film (Mitsubishi Chemical Polyester Film Co., Ltd .: Diafoil T100-38) so that the coating amount (after drying) is about 0.12 (g / m 2). And then heat-treated at 150 ° C. for 10 seconds to obtain a release film.
<Releasing agent composition>
・ Viscosity in a 30% toluene solution is 8000 mPa · s, and a solvent-type silicone containing about 8% of a vinyl group as a siloxane unit in the main polymer (manufactured by Shin-Etsu Chemical Co., Ltd .: KS-3601, nonvolatile content 30%) 70 parts by weight・ Viscosity: 300 mPa ・ s, Solvent-free silicone containing about 5% vinyl groups in the main polymer in siloxane units (Shin-Etsu Chemical Co., Ltd .: KNS-3002, non-volatile content: 100%) 4.5 parts by weight Exfoliation regulator (manufactured by Shin-Etsu Chemical Co., Ltd .: KS-3800, non-volatile content 30%) 15 parts by weight. (CH ₃ ) ₃ SiO (—SiH (CH ₃ ) —O) _m —Si (CH ₃ ) ₃ Silicone represented (Gelest: HMS-991, viscosity: about 20 mPa · s) 2.4 parts by weight Platinum-containing catalyst (Shin-Etsu Chemical Co., Ltd .: catPL-50T) 1 part by weight (Mixing ratio 1: 1: 1) mixed solvent of en / MEK / isooctane was diluted with, to prepare a solid concentration of 2% by weight of the coating solution.

Example 2:
In Example 1, a release film was obtained in the same manner as in Example 1 except that the release agent composition was changed to the following release agent composition.
<Releasing agent composition>
・ Viscosity in a 30% toluene solution is 8000 mPa · s, and a solvent-type silicone containing about 8% of a vinyl group as a siloxane unit in the main polymer (manufactured by Shin-Etsu Chemical Co., Ltd .: KS-3601, nonvolatile content 30%) 70 parts by weight・ Viscosity: 300 mPa · s, Solvent-free silicone containing about 5% vinyl groups in the main polymer in siloxane units (Shin-Etsu Chemical Co., Ltd .: KNS-3002, nonvolatile content: 100%) 7.5 parts by weight Exfoliation regulator (manufactured by Shin-Etsu Chemical Co., Ltd .: KS-3800, non-volatile content 30%) 5 parts by weight. (CH ₃ ) ₃ SiO (—SiH (CH ₃ ) —O) _m —Si (CH ₃ ) ₃ Silicone represented (Gelest, Inc .: HMS-991, viscosity of about 20 mPa · s) 2.4 parts by weight, platinum-containing catalyst (Shin-Etsu Chemical Co., Ltd .: catPL-50T) 1 part by weight (Mixing ratio 1: 1: 1) mixed solvent of emissions / MEK / isooctane was diluted with, to prepare a solid concentration of 2% by weight of the coating solution.

Comparative Example 1:
In Example 1, a release film was obtained in the same manner as in Example 1 except that the release agent composition was changed to the following release agent composition.
<Releasing agent composition>
・ Viscosity in a 30% toluene solution is 8000 mPa · s, and a solvent-type silicone containing about 8% vinyl groups in the main polymer as siloxane units (manufactured by Shin-Etsu Chemical Co., Ltd .: KS-3601, non-volatile content: 30%) 100 parts by weight Platinum-containing catalyst (manufactured by Shin-Etsu Chemical Co., Ltd .: catPL-50T) 1 part by weight This is diluted with a toluene / MEK / isooctane mixed solvent (mixing ratio is 1: 1: 1), and the solid content concentration is 2% by weight. A coating solution was prepared.

Comparative Example 2:
In Example 1, a release film was obtained in the same manner as in Example 1 except that the release agent composition was changed to the following release agent composition.
<Releasing agent composition>
・ Viscosity in a 30% toluene solution is 15000 mPa · s, and a solvent-type silicone containing about 1% of a vinyl group as a siloxane unit in the main polymer (manufactured by Shin-Etsu Chemical Co., Ltd .: KS-3703, non-volatile content: 30%) 100 parts by weight _{· (CH 3) 3 SiO (} -SiH (CH 3) -O) m -Si (CH 3) silicone represented by ₃ (Gelest Inc.: HMS-991, a viscosity of about 20 mPa · s) 0.36 parts by weight Platinum-containing catalyst (manufactured by Shin-Etsu Chemical Co., Ltd .: catPL-50T) 1 part by weight This is diluted with a toluene / MEK / isooctane mixed solvent (mixing ratio is 1: 1: 1), and the solid content concentration is 2% by weight. A coating solution was prepared.

Comparative Example 3:
In Example 1, a release film was obtained in the same manner as in Example 1 except that the release agent composition was changed to the following release agent composition.
<Releasing agent composition>
A solvent-type silicone (Shin-Etsu Chemical Co., Ltd. product: KS-774, 30% non-volatile content) having a viscosity of 15000 mPa · s in a 30% toluene solution and containing about 0.8% of a vinyl group as a siloxane unit in the main polymer 90 10 parts by weight platinum-containing catalyst (Shin-Etsu Chemical Co., Ltd .: catPL-) 10 parts by weight Solvent-type release modifier (Shin-Etsu Chemical Co., Ltd .: X-92-183, non-volatile content 30%) 50T) 1 part by weight This was diluted with a mixed solvent of toluene / MEK / isooctane (mixing ratio was 1: 1: 1) to prepare a coating solution having a solid content concentration of 2% by weight.

Comparative Example 4:
In Example 1, a release film was obtained in the same manner as in Example 1 except that the release agent composition was changed to the following release agent composition.
<Releasing agent composition>
・ Solvent type silicone having a viscosity of 15000 mPa · s in a 30% toluene solution and containing about 0.4% of a vinyl group as a siloxane unit in the main polymer (manufactured by Shin-Etsu Chemical Co., Ltd .: KS-847H, nonvolatile content: 30%) 85 Part by weight / Solvent-type reactive release regulator (Shin-Etsu Chemical Co., Ltd .: KS-3800, non-volatile content 30%) 15 parts by weight / Platinum-containing catalyst (Shin-Etsu Chemical Co., Ltd .: catPL-50T) 1 part by weight Was diluted with a mixed solvent of toluene / MEK / isooctane (mixing ratio is 1: 1: 1) to prepare a coating solution having a solid content concentration of 2% by weight.
The characteristics of the films obtained in the above Examples and Comparative Examples are summarized in Table 1 below.

  The films of Example 1 and Example 2 are relatively heavy at low speeds, which are closely related to the holding power during storage, but are lightly peeled at high speeds corresponding to actual peeling. Small and excellent in non-migration. On the other hand, Comparative Example 1 having a small SiH / Vi ratio was not sufficient for both light peeling at high speed and relatively heavy peeling at low speed, and the air exposure was greatly reduced. In Comparative Example 2 where the vinyl group content is low, the difference between the low-speed and high-speed peel forces was large even when the SiH / Vi ratio was increased. Further, in Comparative Examples 3 and 4 in which a release adjusting agent is added to silicone having a low vinyl group content, it is still insufficient to achieve both a light release at a high speed and a relatively heavy release at a low speed. The characteristics also deteriorated.

  The film of the present invention can be suitably used as a release film, for example.

Claims (1)

A release film in which a coating mainly composed of curable silicone is applied to at least one surface of a polyester film, and the content of the vinyl group in a polysiloxane chain containing a vinyl group is 3% or more in siloxane units. A solvent-type silicone, a solvent-free silicone having a viscosity of 1000 mPa · s or less and a vinyl group-containing polysiloxane chain with a vinyl group content of 3% or more, and reactive heavy release adjustment A release film characterized by containing an agent as a main component and having a SiH / Vi ratio of 2.5 to 7 in the paint.