JP2009203456A5 - Water electrolysis gas mixed fuel generator - Google Patents

Water electrolysis gas mixed fuel generator Download PDF

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JP2009203456A5
JP2009203456A5 JP2008290940A JP2008290940A JP2009203456A5 JP 2009203456 A5 JP2009203456 A5 JP 2009203456A5 JP 2008290940 A JP2008290940 A JP 2008290940A JP 2008290940 A JP2008290940 A JP 2008290940A JP 2009203456 A5 JP2009203456 A5 JP 2009203456A5
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water electrolysis
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electrolysis gas
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本発明は、塩基性電解液を用いた水電解によって得られる水電解ガスと液化天然ガスや液化石油ガス等の気体化石燃料とを混合することにより得られる水電解ガス混合燃料の生成装置に関する。 The present invention relates to an apparatus for producing a water electrolysis gas mixed fuel obtained by mixing a water electrolysis gas obtained by water electrolysis using a basic electrolyte and a gas fossil fuel such as liquefied natural gas or liquefied petroleum gas.

本発明の課題は、塩基性電解液における水電解で生成された水電解ガスと気体化石燃料とを混合することにより水電解ガス混合燃料を生成する装置を提供することである。発明者らは、水電解ガスと気体化石燃料を混合する装置について種々研究を重ねた結果、二酸化炭素の排出量が低減されると共に原料となる気体化石燃料の消費量の大幅な低減が可能で、強力な火力が持続的に得られる燃料を生成できる装置を開発するに至ったものである。 The subject of this invention is providing the apparatus which produces | generates water electrolysis gas mixed fuel by mixing the water electrolysis gas produced | generated by the water electrolysis in basic electrolyte solution, and gaseous fossil fuel. The inventors have conducted various studies on a device that mixes water electrolysis gas and gaseous fossil fuel, and as a result, carbon dioxide emissions are reduced and consumption of gaseous fossil fuel as a raw material can be greatly reduced. This has led to the development of a device that can produce fuel that can continuously obtain powerful thermal power.

本発明に係る水電解ガス混合燃料は、塩基性電解液を用いた水電解により生成された水電解ガスと気体化石燃料を気泡状で導入し、アルカン系、アルコール系、エーテル系物質等の有機化合物から選ばれた液体Lを内部に収容した混合槽11において、前記導入された水電解ガスと気体化石燃料とが均一混合されるように混合を繰り返し実行し、前記水電解ガスと気体化石燃料の気泡が容易に通過できない程度の複数の細孔が形成された仕切板であって、前記混合槽内部に収容された液体Lに浸漬され、かつ当該仕切板の外周面が混合槽内壁に接近した状態で水平方向に設置された複数の仕切板51、52、53が取付けられた昇降可能な可動構造に構成された昇降可動部15を備え、前記水電解ガスと気体化石燃料の気泡が前記仕切板の下面側に多数集合して上方層への移動が停滞する、又は気泡が当該細孔を通過し上方層へ移動することにより生じる前記仕切板が取付けられた昇降可動部15の上昇又は下降の変位を検知して、水電解ガス及び気体化石燃料の混合槽内への供給の停止又は開始(再開)、供給量、所定成分比を制御して、前記水電解ガスと気体化石燃料との混合を繰り返し実行することにより生成される The water electrolysis gas mixed fuel according to the present invention introduces water electrolysis gas generated by water electrolysis using a basic electrolyte and gas fossil fuel in the form of bubbles, and organics such as alkanes, alcohols, ethers, etc. In the mixing tank 11 in which the liquid L selected from the compound is accommodated, mixing is repeatedly performed so that the introduced water electrolysis gas and gas fossil fuel are uniformly mixed, and the water electrolysis gas and gas fossil fuel are mixed. The partition plate is formed with a plurality of pores to the extent that the bubbles cannot easily pass through, and is immersed in the liquid L accommodated inside the mixing tank, and the outer peripheral surface of the partition plate approaches the inner wall of the mixing tank In this state, a vertically movable unit 15 configured in a vertically movable structure having a plurality of partition plates 51, 52, 53 installed in a horizontal direction is provided, and the water electrolysis gas and gas bubbles of the fossil fuel are Under the divider Ascending or descending displacement of the elevating movable unit 15 to which the partition plate is attached is generated by a large number of gathering on the side and the movement to the upper layer stagnant, or the bubbles passing through the pores and moving to the upper layer. Detect and stop or start (restart) the supply of water electrolysis gas and gas fossil fuel into the mixing tank, control the supply amount, and the predetermined component ratio, and repeat the mixing of the water electrolysis gas and gas fossil fuel. Generated by executing .

本発明に係る水電解ガス混合燃料は、水電解ガス及び気体化石燃料の混合槽内への供給の停止又は開始(再開)の制御が混合槽の内圧変化の検知により行なわれることにより生成されまた水電解ガスの混合槽内への供給停止の制御が混合槽の内圧が気体化石燃料の混合槽内への供給停止条件として設定された混合槽の内圧と同一に達したことを検知して行なわれ、水電解ガスの混合槽内への供給開始(再開)の制御が混合槽の内圧が当該設定内圧より低下したことを検知して行なわれることにより生成される The water electrolysis gas mixed fuel according to the present invention is generated by performing control of stopping or starting (restarting) the supply of water electrolysis gas and gas fossil fuel into the mixing tank by detecting the change in the internal pressure of the mixing tank, Also, the control of stopping the supply of water electrolysis gas into the mixing tank detects that the internal pressure of the mixing tank has reached the same pressure as the internal pressure of the mixing tank set as the supply stop condition for the fossil fuel mixing tank. It is generated by detecting that the internal pressure of the mixing tank has dropped below the set internal pressure, and controlling the start (resumption) of the supply of water electrolysis gas into the mixing tank.

次に、添付図を参照しつつ本発明に係る水電解ガス混合燃料の生成装置について開示する。図1(A)は本発明に係る水電解ガス混合燃料の生成装置を説明するための概略断面図であり、図1(B)は図1(A)のA−A矢視断面図である。図2は、本発明に係る水電解ガス混合燃料の生成装置及び関連する周辺装置を示すブロック図である。本発明に係る水電解ガス混合燃料の生成装置10は、図に示されるように、アルカン系、アルコール系、エーテル系物質等の有機化合物から選ばれた液体Lを内部に収容し、底部から導入される気泡状の水電解ガスと気体化石燃料との混合を繰り返し実行する混合槽11、この混合槽に対し塩基性電解液を用いた水電解により生成された水電解ガスを供給する水電解ガス供給手段12、混合槽に対し気体化石燃料を供給する化石燃料供給手段13、前記水電解ガスと気体化石燃料との混合が繰り返し実行され生成された水電解ガス混合燃料を燃料使用装置60へ排出する水電解ガス混合燃料排出手段14、とにより構成されている。
Next, a water electrolysis gas mixed fuel generating apparatus according to the present invention will be disclosed with reference to the attached drawings. FIG. 1 (A) is a schematic cross-sectional view for explaining a water electrolysis gas mixed fuel generating apparatus according to the present invention, and FIG. 1 (B) is a cross-sectional view taken along line AA in FIG. 1 (A). . FIG. 2 is a block diagram showing a water electrolysis gas mixed fuel generating device and related peripheral devices according to the present invention. As shown in the figure, a water electrolysis gas mixed fuel generation apparatus 10 according to the present invention contains a liquid L selected from an organic compound such as an alkane-based, alcohol-based, or ether-based substance inside, and is introduced from the bottom. The mixing tank 11 that repeatedly executes mixing of the bubbly water electrolysis gas and the gas fossil fuel, and the water electrolysis gas that supplies water electrolysis gas generated by water electrolysis using a basic electrolyte to the mixing tank Supply means 12, fossil fuel supply means 13 for supplying gas fossil fuel to the mixing tank, and water electrolyte gas mixed fuel generated by repeatedly mixing the water electrolysis gas and gas fossil fuel is discharged to the fuel use device 60. The water electrolysis gas mixed fuel discharging means 14 is configured.

Claims (10)

アルカン系、アルコール系、エーテル系物質等の有機化合物から選ばれた液体を内部に収容し、供給される気泡状の水電解ガスと気体化石燃料との混合を繰り返し実行する混合槽と、前記混合槽に対し塩基性電解液を用いた水電解により生成された水電解ガスを気泡状で供給する水電解ガス供給手段と、前記混合槽に対し気体化石燃料を気泡状で供給する化石燃料供給手段と、前記水電解ガスと気体化石燃料との混合が繰り返し実行され生成された水電解ガス混合燃料を燃料使用装置へ排出する水電解ガス混合燃料排出手段と、を有する水電解ガス混合燃料の生成装置において、
前記水電解ガスと気体化石燃料の気泡が容易に通過できない程度の複数の細孔が形成された仕切板であって、前記混合槽内部に収容された液体に浸漬され、かつ当該仕切板の外周面が混合槽内壁に接近した状態で水平方向に設置された複数の仕切板が取付けられた昇降可能な可動構造に構成された昇降可動部と、
前記水電解ガス及び/又は気体化石燃料の混合槽への供給の停止又は開始、供給量、所定成分比を制御する制御手段と、
を備えたことを特徴とする水電解ガス混合燃料の生成装置。
A mixing tank that contains a liquid selected from organic compounds such as alkane-based, alcohol-based, and ether-based substances inside, and repeatedly performs mixing of the supplied bubbly water electrolysis gas and gas fossil fuel; and the mixing Water electrolysis gas supply means for supplying water electrolysis gas generated by water electrolysis using a basic electrolyte to the tank in the form of bubbles, and fossil fuel supply means for supplying gas fossil fuel in the form of bubbles to the mixing tank And water electrolysis gas mixed fuel discharge means for discharging the water electrolysis gas mixed fuel generated by repeatedly performing the mixing of the water electrolysis gas and the gas fossil fuel to the fuel use device. In the device
A partition plate in which a plurality of pores are formed so that bubbles of the water electrolysis gas and gas fossil fuel cannot easily pass therethrough, and the partition plate is immersed in the liquid contained in the mixing tank, and the outer periphery of the partition plate An elevating movable part configured in an elevating movable structure to which a plurality of partition plates installed in the horizontal direction are attached in a state where the surface is close to the inner wall of the mixing tank,
Control means for controlling stop or start of supply to the mixing tank of the water electrolysis gas and / or gas fossil fuel, supply amount, and predetermined component ratio;
An apparatus for producing a water-electrolyzed gas mixed fuel, comprising:
前記アルカン系、アルコール系、エーテル系物質等の有機化合物の液体が、ガソリン、エタノール、メチルアルコール、ジメチルエーテルから選ばれた液体のいずれかである、ことを特徴とする請求項1に記載の水電解ガス混合燃料の生成装置。   2. The water electrolysis according to claim 1, wherein the liquid of the organic compound such as the alkane-based, alcohol-based, or ether-based substance is any one selected from gasoline, ethanol, methyl alcohol, and dimethyl ether. Gas mixed fuel generator. 前記気体化石燃料が液化石油ガス(LPG)、液化天然ガス(LNG)、石炭乾留ガスから選ばれた気体化石燃料のいずれかである、ことを特徴とする請求項1または2のいずれかに記載の水電解ガス混合燃料の生成装置。   The fossil fuel is any one of fossil fuels selected from liquefied petroleum gas (LPG), liquefied natural gas (LNG), and coal dry distillation gas. Water electrolysis gas mixed fuel generator. 前記水電解ガス混合燃料の生成装置により生成される水電解ガス混合燃料が、前記アルカン系、アルコール系、エーテル系物質等の有機化合物の液体から気化するガスを含む、ことを特徴とする請求項1乃至3のいずれかに記載の水電解ガス混合燃料の生成装置。   The water electrolyzed gas mixed fuel produced by the water electrolyzed gas mixed fuel producing device includes a gas that is vaporized from a liquid of an organic compound such as the alkane-based, alcohol-based, or ether-based material. The apparatus for producing a water-electrolyzed gas mixed fuel according to any one of 1 to 3. 前記昇降可動部に取付けられた仕切板が3段に形成され、最下段の仕切板が厚さ0.5〜2.5mmで細孔径が0.5〜3.5mmであるステンレス製であり、その上段側の仕切板が細孔径が0.2〜1.5mmの平板状のメッシュ構造体である、ことを特徴とする請求項1乃至4のいずれかに記載の水電解ガス混合燃料の生成装置。   The partition plate attached to the elevating movable part is formed in three stages, and the lowermost partition plate is made of stainless steel having a thickness of 0.5 to 2.5 mm and a pore diameter of 0.5 to 3.5 mm, 5. The water electrolysis gas mixed fuel production according to any one of claims 1 to 4, wherein the upper partition plate is a flat mesh structure having a pore diameter of 0.2 to 1.5 mm. apparatus. 前記制御手段が、前記水電解ガスと気体化石燃料の気泡が前記仕切板の下面側に多数集合して上方層への移動が停滞する、又は気泡が当該細孔を通過し上方層へ移動することにより生じる前記仕切板が取付けられた昇降可動部の上昇又は下降の変位を検知して、水電解ガス及び気体化石燃料の混合槽内への供給の停止又は開始を制御する、ことを特徴とする請求項1乃至5のいずれかに記載の水電解ガス混合燃料の生成装置。   The control means gathers a large number of bubbles of the water electrolysis gas and gas fossil fuel on the lower surface side of the partition plate and the movement to the upper layer is stagnated, or the bubbles pass through the pores and move to the upper layer. And detecting the displacement of the ascending / descending movable part to which the partition plate attached to the unit is attached is controlled to stop or start the supply of water electrolysis gas and gas fossil fuel into the mixing tank. The apparatus for producing a water electrolysis gas mixed fuel according to any one of claims 1 to 5. 前記制御手段が、混合槽の内圧の変化を検知して、水電解ガス及び気体化石燃料の混合槽内への供給の停止又は開始を制御する、ことを特徴とする請求項1乃至5のいずれかに記載の水電解ガス混合燃料の生成装置。   6. The control device according to claim 1, wherein the control means detects a change in the internal pressure of the mixing tank and controls the stop or start of the supply of water electrolysis gas and gas fossil fuel into the mixing tank. An apparatus for producing a water-electrolyzed gas mixed fuel according to claim 1. 前記制御手段が、混合槽の内圧が気体化石燃料の混合槽内への供給停止条件として設定された圧力と同一圧に達したことを検知して水電解ガスの混合槽内への供給を停止し、混合槽の内圧が当該設定圧より低下したことを検知して水電解ガスの混合槽内への供給を開始するように制御する、ことを特徴とする請求項1乃至5のいずれかに記載の水電解ガス混合燃料の生成装置。   The control means detects that the internal pressure of the mixing tank has reached the same pressure as the pressure set as the supply stop condition for the fossil fuel mixing tank, and stops the supply of water electrolysis gas into the mixing tank. And detecting that the internal pressure of the mixing tank is lower than the set pressure and controlling the start of the supply of water electrolysis gas into the mixing tank. The production apparatus of the water electrolysis gas mixed fuel of description. 前記水電解ガス供給手段に対し供給される水電解ガスの発生装置が、底部側に電解液導入口を有し、頂部側に電解液と生成ガスの混在物を取り出すための取出し口を有する電解槽であって、該電解槽内の底部側に配設された陽極板と、前記電解槽内の頂部側に配設された陰極板と、前記陽極板から前記陰極板へ向かう方向にアルカリ電解液を旋回流動させながら通流させるための電気的接続のない電解液旋回通流手段とを備えた水電解ガス生成用電解槽と、前記電解槽の上端の取出し口から取り出される水電解ガスと電解液の混在物を導入して、水電解ガスのガス成分と電解液との気液分離を行い当該ガス成分を外部に取り出し、電解液成分を残留せしめるための水電解ガス−電解液分離槽と、前記分離槽に残留せしめられた電解液を強制冷却するための電解液強制冷却手段と、当該電解液を前記電解槽側に環流させる電解液循環手段と、からなる水電解ガス発生装置である、ことを特徴とする請求項1乃至8のいずれかに記載の水電解ガス混合燃料の生成装置。   The electrolysis apparatus for generating water electrolysis gas supplied to the water electrolysis gas supply means has an electrolyte introduction port on the bottom side and an extraction port for taking out a mixture of the electrolyte and product gas on the top side. An anode plate disposed on the bottom side in the electrolytic cell; a cathode plate disposed on the top side in the electrolytic cell; and alkaline electrolysis in a direction from the anode plate toward the cathode plate. An electrolytic cell for water electrolysis gas generation having an electrolysis solution swirl flow means without electrical connection for allowing the liquid to flow while swirling, and a water electrolysis gas taken out from a take-out port at the upper end of the electrolytic cell Water electrolysis gas-electrolyte separation tank for introducing a mixture of electrolytes, separating the gas components of water electrolysis gas and electrolytes, taking out the gas components outside, and leaving the electrolyte components remaining And forced cooling of the electrolyte remaining in the separation tank. 9. A water electrolysis gas generator comprising: an electrolytic solution forced cooling means for carrying out the process; and an electrolytic solution circulation means for circulating the electrolytic solution to the electrolytic cell side. The production apparatus of the water electrolysis gas mixed fuel of description. 前記電解槽内の陽極板と陰極板との間に配設された電解液旋回通流手段が、所要枚数の金属板であってそれぞれの中心から外周側に外れて点対称に穿孔された2乃至6個の通流開口を有し、これら通流開口を所定角度ずつ順次変位させて配設することにより旋回流動を伴いながら電解液を通流させる構造である、ことを特徴とする請求項9に記載の水電解ガス混合燃料の生成装置。   The electrolyte swirl flow means disposed between the anode plate and the cathode plate in the electrolytic cell is a required number of metal plates which are perforated in a point-symmetric manner by deviating from the center to the outer peripheral side. It has a structure in which the electrolyte solution is allowed to flow with swirling flow by arranging thirty-six flow openings and sequentially disposing the flow openings by a predetermined angle. 10. The apparatus for producing a water-electrolyzed gas mixed fuel according to 9,
JP2008290940A 2008-02-01 2008-11-13 Device and method for generating water electrolytic gas mixed fuel Pending JP2009203456A (en)

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