JP2009202516A - Manufacturing method of tube and tube - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method of a tube, the resin content of which can be reduced during the manufacturing process. <P>SOLUTION: This manufacturing method includes a process for obtaining an intermediate molded body 6 by winding a fiber-reinforced resin member 4 including a fiber and a matrix resin around a mandrel 2, a tape winding process for winding a textile tape 8 under tension around the outer peripheral surface of the intermediate molded body 6, a curing process for curing the matrix resin in the intermediate molded body 6 wound with the textile tape 8, and a process for obtaining a cured tube by drawing out the mandrel 2 and removing the textile tape 8 thereof after the curing process. Preferably, the tensile stress T1 given to the textile tape 8 in the tape winding process is set to be ≥5 Mpa and ≤150 Mpa. In this manufacturing method, the matrix resin can be effectively drawn out after the winding process. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to a method for producing a tubular body made of a fiber reinforced resin and a tubular body produced by the production method.

  In recent years, with the increase in powerless elderly people and female golfers, it has been desired to develop a golf club shaft (hereinafter also simply referred to as a shaft) that can extend a flight distance even with a slight force. In particular, the weight reduction of the shaft is considered as one of the effective means for solving this problem, and various efforts have been made.

  In terms of materials, first, in terms of materials, there is a change from steel to CFRP (carbon fiber reinforced plastic). In addition, even with the same CFRP, the strength of the entire shaft is improved by improving the strength of the carbon fiber, changing the physical properties of the resin, or improving the adhesion strength between the carbon fiber and the resin. Reduced. Further, as a structural effort, the weight of the strength improvement has been reduced by orienting or laminating fibers at an angle that improves the strength to improve the strength.

  Fiber-reinforced resin tubular bodies (hereinafter also referred to as FRP tubular bodies) are used in various applications. As a method for producing an FRP tubular body, a production method using a wrapping tape is known. In this manufacturing method, after a sheet-like FRP material is wound around a mandrel (core metal), a resin tape is wound while applying a predetermined tension. This resin tape is generally called a wrapping tape. A molding pressure is applied by the wrapping tape.

This wrapping tape is finally removed. In order to facilitate this removal, a wrapping tape with high releasability is preferable. Japanese Patent Application Laid-Open No. 2002-144439 discloses a wrapping tape whose inner surface is a woven pattern for the purpose of improving the releasability. Specifically, a wrapping tape in which a woven fabric and a resin film are integrated is disclosed.
JP 2002-144439 A

  In order to reduce the weight of the CFRP shaft, as described above, the strength of the fiber or resin or the adhesion between the fiber and the resin is increased to increase the strength of the entire shaft and reduce the weight of the strength improvement. Has been. And the weight reduction of the shaft has been achieved by the method. However, there is a limit to the development to improve the strength and reduce the weight accordingly. On the other hand, there is no limit to the needs of golfers, and it is required to extend the flight distance as much as possible. One of the means for increasing the flight distance is the weight reduction of the shaft, and the demand for the weight reduction of the shaft is not exhausted. In order to realize this requirement, a method has been adopted in which the minimum strength necessary for the shaft is maintained, and characteristics (flex and torque) related to the shaft rigidity are sacrificed. However, the weight reduction by this method has also reached its limit, and the decrease in rigidity has also hindered the club function. It is important how to further reduce the weight while maintaining the rigidity of the shaft.

  As a means for realizing weight reduction while maintaining the rigidity of the shaft, it is conceivable to use CFRP having a high fiber content. That is, by increasing the content of fibers mainly responsible for the strength and rigidity of the tubular body as a molded product, the strength and rigidity per unit weight are increased and the weight can be reduced. However, since molding with CFRP having a high fiber content is insufficient for the production of tack, it is difficult to mold and air easily enters between the fiber-reinforced resin member layers. In this case, since the material itself contains a large amount of air, a large amount of air enters the entire tubular body. This air becomes a void and may reduce the strength and durability of the tubular body.

  Thus, it is difficult to maintain strength and rigidity at the same time while reducing the weight.

  In the above-mentioned prior art wrapping tape, the elongation rate differs between the woven fabric and the resin film. Therefore, when the tension is applied, the woven fabric and the resin film are partially separated, the tape is twisted, or the tape is bent. Or the molding pressure may vary. Due to these phenomena, the surface of the FRP tubular body is likely to be non-uniform, and defective products are likely to occur or the strength is not uniform.

  By the way, a lightweight and high-strength FRP tubular body is useful in various applications. In this FRP tubular body, for example, a golf club shaft, weight reduction is desired. A lightweight golf club shaft can contribute to an increase in head speed and flight distance. In the present invention, a manufacturing method for obtaining a lightweight FRP tubular body based on a completely new technical idea has been found. In this manufacturing method, the winding process of the wrapping tape is different from the conventional one. In this manufacturing method, the resin contained in the fiber reinforced resin can be absorbed by the wrapping tape.

  The objective of this invention exists in provision of the manufacturing method of the tubular body which can reduce resin content rate during a manufacturing process.

The method for producing an FRP tubular body according to the present invention includes:
(1) A step of obtaining an intermediate molded body by winding a fiber reinforced resin member containing fibers and a matrix resin around a mandrel. (2) Tape winding for winding a wrapping tape while applying tension to the outer peripheral surface of the intermediate molded body. Step (3) a curing step of curing the matrix resin by heating the intermediate molded body around which the wrapping tape is wound; and
(4) The method includes the step of drawing the mandrel and removing the wrapping tape after the curing step to obtain a cured tubular body. In this manufacturing method, the wrapping tape is a woven tape.

  Preferably, the tensile stress T1 applied to the fabric tape in the tape winding step is 5 (Mpa) or more and 150 (Mpa) or less.

  Preferably, the number L1 of wrapping layers of the fabric tape wound in the tape winding step is one or more layers at all points from the tip end position Tp1 of the tubular body to the butt end position Bt1 of the tubular body.

  Preferably, when the fiber content of the intermediate molded body is S1 (mass%) and the fiber content of the cured tubular body is S2 (mass%), the difference (S2-S1) is 3 mass% or more and 25 or more. It is below mass%.

  The tubular body according to the present invention is a tubular body produced by any of the production methods described above.

  The resin content can be reduced during the production process, and a lightweight tubular body can be obtained.

  Hereinafter, the present invention will be described in detail based on preferred embodiments with appropriate reference to the drawings.

  In the manufacturing method according to the present invention, a fiber reinforced resin tubular body (FRP tubular body) is obtained. FIG. 1 is a diagram for explaining a manufacturing method according to an embodiment of the present invention. Here, a golf club shaft manufacturing method will be described as an example of a tubular body manufacturing method. In this manufacturing method, first, a mandrel 2 and a fiber reinforced resin member 4 are prepared. The mandrel 2 is also called a cored bar. A typical mandrel 2 is made of a metal such as steel. The central axis of the mandrel 2 is a substantially straight line. The cross-sectional shape of the mandrel 2 is a circle. The mandrel 2 has a taper. Due to this taper, the mandrel 2 is made thinner toward one end thereof. The mandrel 2 may be partially parallel. In other words, the mandrel 2 may partially have a portion having a constant diameter. The diameter of the entire mandrel 2 may be constant.

  The mandrel 2 forms a hollow portion of the finally obtained tubular body. The shape of the hollow portion of the tubular body is determined by the shape of the mandrel 2. As will be described later, the mandrel 2 is pulled out in a later step. A mold release agent is preferably applied to the surface of the mandrel 2 so that this drawing is easy.

  In this manufacturing method, first, a step of winding a fiber reinforced resin member around a mandrel is performed. Hereinafter, this process is also referred to as a winding process.

  Prior to the winding step, a fiber reinforced resin member is prepared. In the present embodiment, the fiber reinforced resin member is in the form of a sheet. In the present embodiment, the fiber reinforced resin member is a prepreg 4. This manufacturing method in which the sheet-like fiber reinforced resin member is wound is also referred to as a sheet winding manufacturing method. Examples of the fiber reinforced resin member include prepreg 4 and fibers impregnated with a liquid resin. An example of a manufacturing method using this fiber is a so-called filament winding manufacturing method. This manufacturing method can also be applied to a filament winding manufacturing method.

  The prepreg 4 includes fibers and a matrix resin. This fiber is a carbon fiber. The carbon fibers of the prepreg 4 are oriented in one direction. As will be described later, fibers other than carbon fibers may be used. Carbon fiber is preferable from the viewpoint of a high-strength and lightweight tubular body. In the winding process, the matrix resin is not completely cured. Therefore, the prepreg 4 has flexibility. This flexibility allows the prepreg 4 to be wound around the mandrel 2. As will be described later, the matrix resin is not limited and is preferably an epoxy resin.

  Prior to the winding step, the prepreg 4 is cut into a desired shape. In the embodiment of FIG. 1, six prepregs 4 are used. In the embodiment of FIG. 1, sheets s <b> 1 to s <b> 6 are shown as examples of the cut prepreg 4. The prepreg 4 includes so-called angle layer sheets s1, s2, straight layer sheets s3, s5, s6, and a hoop layer sheet s4. The prepreg 4 includes full length sheets s1 to s5 provided over the entire length of the shaft, and a partial sheet s6 provided in a part of the shaft in the longitudinal direction. The specification of the prepreg 4 is not limited. The shape, thickness, fiber type, fiber content, etc. of the prepreg 4 are not limited.

  In the winding step, the sheets s1 to s6 are sequentially wound around the mandrel 2. Although not shown, prior to winding, the sheet s2 is bonded to the sheet s1. The laminated sheet group is wound around the mandrel 2. In this bonding, the sheet s2 is turned over. By this turning over, the fibers of the sheet s1 and the fibers of the sheet s2 are oriented in opposite directions. In FIG. 1, the angles described in the sheets s1 to s6 indicate the angles formed by the shaft axis direction and the fiber orientation direction.

  The sheets s1 to s6 are wound by, for example, human power. A winding machine (also called a rolling machine) may be used. The intermediate molded body 6 is obtained by the winding process. The intermediate molded body 6 is constituted by a wound prepreg 4. The cross section of the intermediate molded body 6 is formed of a spiral layer. This layer is formed by the prepreg 4.

  Next, a tape winding process is performed. In this tape winding step, a wrapping tape is wound around the outer peripheral surface of the intermediate molded body 6. 2 and 3 are partially sectional perspective views showing a state of the tape winding process. 2 and 3, the intermediate molded body 6 is simply shown as a single layer. Actually, the intermediate molded body 6 is composed of a plurality of layers as described above. In the present application, the tape winding process is also simply referred to as a winding process.

  The wrapping tape in the tape winding process is the fabric tape 8. In this embodiment, only a woven tape is used as the wrapping tape. In the tape winding process, only the fabric tape 8 is wound. The fabric tape 8 is a tape based on a fabric. The fabric tape 8 may have a coating agent or the like on the surface of a substrate that is a fabric.

  The state of the tape winding process is shown in FIG. In the tape winding step, the fabric tape 8 is directly wound around the outer peripheral surface of the intermediate molded body 6. The outer peripheral surface of the intermediate molded body 6 and the fabric tape 8 are in contact with each other. The fabric tape 8 is in contact with the outer peripheral surface of the intermediate molded body 6.

  As shown in FIG. 2, in the tape winding process, the fabric tape 8 is wound spirally. For the purpose of spirally winding, the axial direction of the intermediate molded body 6 and the longitudinal direction of the fabric tape 8 are not perpendicular to each other. The fabric tape 8 is wound around the intermediate molded body 6 without a gap. In order to eliminate the gap, the width W1 of the fabric tape 8 is wider than the winding pitch P1. The winding pitch P1 is indicated by a double arrow in FIG. That is, the fabric tape 8 is wound in a spiral shape while a part of the width direction is overlapped. The winding pitch P1 is constant. The winding pitch P1 is constant from the tip end to the butt end of the intermediate molded body 6. The fabric tape 8 is wound by a known lapping machine. The fabric tape 8 is wound over the entire length of the intermediate molded body 6. As a result of the tape winding step, the entire intermediate molded body 6 is covered with the fabric tape 8. Note that both ends (end of winding and end of winding) of the fabric tape 8 are fixed to the intermediate molded body 6 with an adhesive tape or the like. By fixing both ends, the winding of the fabric tape 8 is not naturally unwound.

  As will be described later, in the subsequent process, the resin contained in the intermediate molded body 6 moves to the fabric tape 8. That is, the resin contained in the intermediate molded body 6 is absorbed into the fabric tape 8 or passes through the fabric tape 8 and is discharged to the outside.

  From the viewpoint of increasing the amount of resin absorbed by the fabric tape 8, the number L1 of wrapping layers of the fabric tape 8 is preferably large. The number of wrapping layers L1 is the number of layers of the fabric tape 8 wound around the intermediate molded body 6. The number L1 of wrapping layers is determined at each point on the surface of the intermediate molded body 6. In the spiral winding described above, if the winding pitch P1 is larger than the width W1 of the fabric tape, the intermediate molded body 6 after the winding step has a portion where the number of wrapping layers L1 is zero and the number of wrapping layers L1. There is a portion where is one layer. Further, when the ratio (P1 / W1) is more than 0.5 and less than 1.0, the intermediate molded body 6 after the winding step has a portion in which the number of wrapping layers L1 is one layer and the number of wrapping layers L1. There will be a portion with two layers.

As a method for increasing the number of wrapping layers L1, the following (Method A) and (Method B) can be employed.
(Method A) The ratio (P1 / W1) of the winding pitch P1 to the width W1 of the fabric tape is reduced.
(Method B) A plurality of windings are performed.

  Since (Method A) can increase the number of wrapping layers L1 by one winding, it can contribute to the improvement of productivity. On the other hand, (Method B) is inferior in productivity compared with (Method A) because it is necessary to repeat the winding from the tip side to the butt side and / or the winding from the tip side to the bat side. From the viewpoint of productivity, (Method A) is preferable to (Method B). However, depending on the thickness, flexibility, and the like of the fabric tape 8, there may be a limit in reducing the ratio (P1 / W1) and increasing the number of wrapping layers L1. In this case, (Method B) can be used effectively.

  From the viewpoint of increasing the number of wrapping layers L1 and increasing the amount of absorbed resin, the ratio (P1 / W1) is preferably 0.70 or less, more preferably 0.50 or less, still more preferably 0.40 or less, and 0.33. The following is more preferable. In addition, when the ratio (P1 / W1) is excessively decreased and the number of wrapping layers L1 is excessively increased, productivity can be reduced while an increase in the amount of resin absorption is hardly observed. In this respect, the ratio (P1 / W1) is preferably equal to or greater than 0.05, more preferably equal to or greater than 0.07, and still more preferably equal to or greater than 0.10.

  The fabric tape 8 is wound while applying the tension F1. The intermediate molded body 6 is fastened by the fabric tape 8 by the tension F1. By wrapping the fabric tape 8, a fabric covering 12 is obtained. The fabric cover 12 is formed by covering the intermediate molded body 6 with a fabric tape 8.

  FIG. 3 is a partial cross-sectional perspective view showing a second winding state when the above (Method B) is employed. In the second winding, the fabric tape 10 is directly wound around the outer peripheral surface of the fabric covering 12. The outer peripheral surface of the fabric covering 12 and the fabric tape 10 abut. The fabric tape 10 is in contact with the outer peripheral surface of the fabric cover 12. That is, the fabric tape 10 is in contact with the fabric tape 8. The fabric tape 8 and the fabric tape 10 may be the same tape or different tapes.

  As shown in FIG. 3, in the second winding, the fabric tape 10 is wound spirally. This second winding can be performed in the same manner as the first winding described above. As will be described later, this second winding is preferably not performed from the viewpoint of productivity.

  The fabric tape 10 is wound while applying the tension F2. The fabric cover 12 is fastened by the fabric tape 10 by the tension F2. The tension F2 and the tension F1 may be the same or different.

  In addition, although the spiral pattern by the fabric tape 8 is formed in the surface of the textile covering body 12, description of the spiral pattern by this fabric tape 8 is abbreviate | omitted in FIG.

  In the embodiment of FIG. 3, the fabric tape is wound from the tip end to the butt end. In this embodiment, the winding is repeated twice. Thus, by repeating winding, the number L1 of wrapping layers can be adjusted, and the resin absorption amount can be adjusted. From the viewpoint of productivity, the number of times the fabric tape is wound in one direction (hereinafter also simply referred to as the number of windings) is preferably 3 times or less, more preferably 2 times or less, and particularly preferably 1 time. The “one direction” may be a direction from the tip side to the butt side, or a direction from the butt side to the tip side.

  After the winding process, a curing process is performed. In this curing step, the matrix resin is cured in the intermediate molded body 6 around which the fabric tape 8 is wound. This curing process is a heating process. Heating is performed by a heating furnace. The heating temperature and the heating time are appropriately set according to the specifications of the matrix resin. The heating process (curing process) preferably includes a first stage heated at a predetermined temperature and a second stage heated at a higher temperature than the first stage. When an epoxy resin is used as the matrix resin, the heating step (curing step) includes a first step of heating at a temperature of 60 ° C. to 115 ° C. for 10 minutes to 120 minutes, and after this first step. And a second stage of heating at a temperature of 120 ° C. to 200 ° C. for 60 minutes to 240 minutes. By the first step, the viscosity of the resin is reduced and the fluidity of the resin is increased. Due to the second stage, curing of the epoxy resin can proceed effectively.

  This first stage heating facilitates the flow of the resin and facilitates the transfer of the resin to the woven tape. From the viewpoint of increasing the flow time of the resin and increasing the migration of the resin to the woven tape, the heating time in the first stage is more preferably 15 minutes or more, and further preferably 20 minutes or more. From the viewpoint of increasing the resin flow time to increase the migration of the resin to the woven tape, the first stage heating temperature is more preferably 100 ° C. or less, and still more preferably 90 ° C. or less.

  After the curing step, the mandrel 2 is pulled out and the fabric tape is removed to obtain a cured tubular body. Either the mandrel 2 can be pulled out or the fabric tape can be removed first. From the viewpoint of workability, the fabric tape is preferably removed after the mandrel 2 is pulled out.

  Usually, finishing processing is given to the above-mentioned hardening tubular body, and the tubular body of the final product is completed. This finishing process may include cutting of both ends, surface polishing, painting, and the like.

  In addition, from the viewpoint of suppressing wrinkles generated on the fabric tape 8, a coating agent may be provided on the inner surface of the fabric tape 8. The inner surface of the fabric tape 8 is a surface that comes into contact with the intermediate molded body 6. The coating agent is preferably a fluorine compound or a silicon compound.

  As described above, in the present invention, the resin contained in the fiber reinforced resin member can be transferred to the fabric tape 8 during the manufacturing process. The fabric tape 8 has gaps and holes between the woven fibers. Therefore, the fabric tape 8 can absorb and / or transmit resin. The fabric tape 8 makes it easy for the matrix resin to be discharged to the outside of the molded body, and the fiber content of the tubular body can be improved. Thereby, the weight reduction of a tubular body is achieved.

  As a means for increasing the fiber content of the FRP tubular body, it is conceivable to use a fiber reinforced resin member having a high fiber content. A high fiber content means a low resin content. A fiber reinforced resin member having a low resin content has low tackiness (adhesiveness). This is because tackiness is caused by the resin. Therefore, the fiber reinforced resin member having a low resin content has low adhesion between the fiber reinforced resin members. Such a fiber-reinforced resin member having low adhesiveness is easy to be unwound once wound. In such a fiber reinforced resin member having low tackiness, it is difficult to wind the mandrel 2 and wrinkles are likely to occur during winding. Moreover, since adhesiveness is bad, it becomes easy to contain air between the layers of the fiber reinforced resin member layer wound by the spiral shape, and the intensity | strength and durability of a tubular body are impaired. A fiber-reinforced resin member having low adhesiveness tends to cause a decrease in productivity and a molding failure.

  In the initial stage of heating in the curing step, the resin (matrix resin) in the fiber reinforced resin member is fluidized by heat. At this time, air contained in the fiber reinforced resin member or air existing between the layers (air pool) can move and permeate through the fluidized matrix resin and be discharged to the outside. In the fiber reinforced resin member having a low resin content, since the resin portion is small, the movement and permeation of air accompanying the fluidization of the matrix resin hardly occur.

  As described above, in a tubular body using a fiber reinforced resin member having a high fiber content, air tends to be contained due to a decrease in tackiness, and air is not easily lost due to fluidization of the matrix resin. For this reason, voids are likely to remain in the molded tubular body, and the durability tends to decrease.

  In the production method of the present invention, the woven tape 8 is wound directly around the outer side of the intermediate molded body while applying tension. By this manufacturing method, the resin contained in the fiber reinforced resin member is absorbed by the fabric tape 8 during the heating process. By this absorption, the fiber content of the FRP tubular body can be increased without using a fiber reinforced resin member having a high fiber content. Therefore, a fiber-reinforced resin member having a high tackiness can be used, and air escape due to fluidization of the matrix resin is likely to occur. Furthermore, the fabric tape 8 can also absorb or transmit air contained in the intermediate molded body 6. As a result, air that causes voids can easily escape and the strength of the FRP tubular body can be improved. In addition, the woven tape 8 can apply a large pressure to the intermediate molded body 6 by setting the number of wrapping layers L1 to a plurality. For this reason, the air which causes a void becomes easier to escape, and the strength of the FRP tubular body can be improved.

  Absorption of the resin by the fabric tape 8 is performed after winding the fiber reinforced resin member. In the present invention, an FRP tubular body having a high fiber content can be obtained without using a fiber reinforced resin member having excessively low adhesiveness. That is, in the present invention, the fiber-reinforced resin member can be easily wound and the fiber content can be improved. Since the fiber content is improved during the manufacturing process, weight reduction is achieved while maintaining moldability and productivity.

  As described above, in the wrapping tape described in JP-A-2002-144439, the woven fabric and the resin film are integrated. In this tape, there is a possibility that the resin is absorbed by the fabric portion. In practice, however, this integrated tape has been found to have a low resin absorption effect.

  The reason why the absorption effect is low is considered as follows. The wrapping tape is wound in a spiral shape while being partially overlapped in the width direction. Therefore, the wrapping tape wound spirally has an overlapping portion where the wrapping tapes overlap each other. That is, in this overlapping portion, there is an inner wrapping tape (inner tape) in contact with the intermediate formed body and an outer wrapping tape (outer tape) located outside the inner tape. In the case of a conventional integrated wrapping tape, the resin film layer present on the inner tape is interposed between the outer tape and the intermediate molded body. This resin film layer is impermeable to resin and air. Therefore, in the case of the conventional integrated tape, the resin film layer of the inner tape inhibits the transfer of the resin and air to the fabric layer of the outer tape in the overlapping portion. As described above, in the conventional integrated tape, the resin and air hardly transfer to the fabric layer.

  Furthermore, in the tape in which the woven fabric and the resin film are integrated, since the gap between the woven fabric and the resin film is reduced, it is considered that the resin absorption effect is low. Furthermore, in the conventional integrated tape, a part of the adhesive layer existing between the woven fabric and the resin film layer penetrates into the woven fabric, and the gap of the woven fabric itself is reduced. The absorption effect of is considered to be low.

  On the other hand, in the present invention, the fabric tapes overlap each other in the overlapping portion. In this overlapping portion, there is no resin tape layer inside the fabric tape. Therefore, resin and air can transfer to the entire woven tape including the overlapping portion, and the resin and air can easily transfer to the woven tape.

  From the viewpoint of increasing the pressure on the intermediate molded body 6 and increasing the resin absorption of the fabric tape, the average number of wrapping layers La is preferably 1 or more, more preferably 2 or more, and more preferably 3 or more. More layers are more preferred. If the average number of wrapping layers La is excessively large, an increase in the cost of the fabric tape and an increase in labor for peeling the fabric tape may occur. Further, when the average number of wrapping layers La is excessively large, wrinkles are likely to occur on the surface of the intermediate molded body 6. From these viewpoints, the average number of wrapping layers La is preferably 15 layers or less, more preferably 12 layers or less, and still more preferably 10 layers or less.

The average number of wrapping layers La is a concept different from the number of wrapping layers L1 described above. While the number of wrapping layers L1 is determined at each point on the surface of the intermediate molded body 6, the average number of wrapping layers La can be understood as an average value of the number of wrapping layers L1. Specifically, the average number of wrapping layers La can be determined by the following calculation formula (1).
La = St / Sn (1)
However, in the formula (1), St is the total area of the inner surface of the fabric tape in a state wound (mm ^2), the surface area of the intermediate formed body 6 in the portion Sn is in contact with the fabric tape which is wound (mm ² ). This total area St is the product of the length Nt (mm) of the wound fabric tape and the width Wa (mm) of the fabric tape. That is, St = Nt × Wa. The length Nt is measured along the longitudinal direction of the fabric tape. The length Nt is substantially equal to or longer than the length Nk of the woven tape measured in the state unwound from the intermediate molded body 6. The case where Nt> Nk can be satisfied when the fabric tape is wound in a state of being stretched by tension. The width Wa is substantially equal to or narrower than the width W1 of the woven tape measured in a state of being unwound from the intermediate molded body 6. The case where W1> Wa is possible is a case where the fabric tape is wound in a state of being stretched by tension. The number of wrapping layers L1 is 0 or an integer of 1 or more, but the average number of wrapping layers La may not be an integer.

  For example, when the ratio (P1 / W1) is 0.5, W1 = Wa, and the number of windings is 1, the average number of wrapping layers La is two. If the error of the winding pitch P1 is ignored, the number of wrapping layers L1 is two in all points.

  The total area St and the surface area Sn are measured in a range from the tip end position Tp1 of the tubular body to the butt end position Bt1 of the tubular body. As described above, in the finishing process of manufacturing the tubular body, both ends of the cured tubular body may be cut. When the both ends are cut, the tip end position Tp1 of the tubular body is different from the tip end position Tp of the cured tubular body. In the case where the both end portions are not cut as described above, the tip end position Tp1 of the tubular body matches the tip end position Tp of the cured tubular body. Similarly, when both ends described above are cut, the butt end position Bt1 of the tubular body is different from the bat end position Bt of the cured tubular body. In the case where the both end portions are not cut as described above, the tip end position Tp1 of the tubular body matches the tip end position Tp of the cured tubular body. FIG. 1 shows a tip end position Tp1 and a butt end position Bt1 when both ends are cut.

  From the viewpoint of increasing the pressure on the intermediate molded body 6 and increasing the resin absorption amount of the fabric tape, the number of wrapping layers L1 is preferably one or more in all points from the tip end position Tp1 to the butt end position Bt1, Two or more layers are more preferable, three or more layers are more preferable, and five or more layers are still more preferable. When the number of wrapping layers L1 is excessively large, an increase in cost of the fabric tape and an increase in labor for peeling the fabric tape may occur. Moreover, when the number L1 of wrapping layers is excessively large, wrinkles are likely to occur on the surface of the intermediate molded body 6. From these viewpoints, the number L1 of wrapping layers is preferably 15 layers or less, more preferably 12 layers or less, and even more preferably 10 layers or less at all points from the tip end position Tp1 to the butt end position Bt1.

  Regardless of the value of the average number of wrapping layers La, when the number of windings is one, there are portions where the number of wrapping layers L1 is one at both ends of the wound portion. For example, even when the average number of wrapping layers La is two or more, as long as the number of windings is one, the number of wrapping layers L1 is one at the start and end of winding. There is a part. The portion Xt adjacent to the winding start point and having one wrapping layer number L1 tends to have less resin transfer to the fabric tape than the other portions. Therefore, a tubular body (shaft) formed by cutting off the portion Xt is more preferable. Similarly, the portion Yt adjacent to the winding end point and having the number of wrapping layers L1 of 1 tends to have less resin transfer to the woven tape than the other portions. Therefore, a tubular body (shaft) formed by cutting off the portion Yt is more preferable. In addition, even if the number of wrapping layers L1 is one, a portion having a portion where the number of wrapping layers L1 is two or more on both sides in the axial direction does not correspond to the portion Xt. Similarly, a portion having a portion where the number of wrapping layers L1 is two or more on both sides in the axial direction does not correspond to the portion Yt even if the number of wrapping layers L1 is one. The axial direction means the axial direction of the tubular body.

  In the winding step, the fabric tape 8 may be reciprocated between the tip side and the bat side and wound. For example, the fabric tape 8 may be spirally wound from the butt side toward the tip side, and then the fabric tape 8 may be spirally wound from the tip side toward the bat side. The number of windings may be increased by such reciprocal winding. In this specification, even when one round of winding is performed by such round trip winding, the number of windings is defined as two. Even when the fabric tape 8 is wound once and again without being cut halfway, the number of times of winding is defined as two. As described above, from the viewpoint of productivity, the method of increasing the average number of wrapping layers La is preferably a method in which the number of windings is set to 1 and the ratio (P1 / W1) is reduced.

  As described above, the fabric tape 8 is wound while the tension F1 is applied. Here, the tensile stress T1 applied to the fabric tape 8 in the tape winding step is defined. The tensile stress T1 is a value obtained by dividing the tension F1 by the cross-sectional area Sd of the fabric tape 8. That is, [T1 = F1 / Sd]. This cross-sectional area Sd is measured in the fabric tape 8 in a state in which no tension is applied (free). This tensile stress T1 means a tensile stress that acts on the fabric tape 8 immediately before winding. This tensile stress T1 does not mean the tensile stress acting on the fabric tape 8 in the wound state.

  From the viewpoint of increasing the amount of resin transferred to the fabric tape 8 and suppressing the sagging of the fabric tape 8, the tensile stress T1 is preferably 5 Mpa or more, more preferably 10 Mpa or more, more preferably 20 Mpa or more, and more preferably 25 Mpa or more. Preferably, 30 Mpa or more is more preferable. From the viewpoint of suppressing the level difference generated on the surface of the tubular body and suppressing the polishing amount for smoothing the surface of the tubular body, the tensile stress T1 is preferably 150 Mpa or less, more preferably 100 Mpa or less, and further preferably 60 Mpa or less.

  In the present invention, the fiber content of the intermediate molded body 6 is S1 (mass%), and the fiber content of the cured tubular body is S2 (mass%). From the viewpoint of weight reduction, the difference (S2-S1) is preferably 3% by mass or more, more preferably 4% by mass or more, more preferably 5% by mass or more, and still more preferably 6% by mass or more. When the resin is excessively removed, the productivity tends to decrease due to difficulty in removing the fabric tape. In this respect, the difference (S2−S1) is preferably 25% by mass or less, more preferably 20% by mass or less, more preferably 15% by mass or less, and still more preferably 10% by mass or less.

  The fiber content S1 of the intermediate molded body 6 is not limited. From the viewpoint of increasing the rigidity and strength of the FRP tubular body, the fiber content S1 is preferably 50% by mass or more, more preferably 60% by mass or more, and still more preferably 70% by mass or more. From the viewpoint of increasing the productivity of the winding operation and suppressing the winding failure, the fiber content S1 is preferably 85% by mass or less, more preferably 80% by mass or less, and further preferably 75% by mass or less. The fiber content S1 of the intermediate molded body 6 is equal to the fiber content of the fiber reinforced resin member (prepreg 4). The fiber content S1 can be determined based on the product data of the fiber reinforced resin member (prepreg 4).

  The fiber content S2 of the cured tubular body is not limited. From the viewpoint of reducing the weight of the FRP tubular body, the fiber content S2 is preferably 60% by mass or more, more preferably 70% by mass or more, more preferably 75% by mass or more, and still more preferably 80% by mass or more. If the resin is excessively removed, the resin discharged from the intermediate molded body 6 makes it difficult to remove the wrapping tape, and thus the productivity is likely to be reduced. From this viewpoint, the fiber content S2 is preferably 95% by mass or less, more preferably 90% by mass or less, more preferably 85% by mass or less, and further preferably 83% by mass or less. The value of the fiber content S2 is calculated from the value of the fiber content S1, the mass of the intermediate molded body 6, and the mass of the removed resin.

  The fibers of the woven tape 8 are preferably nylon fibers and polyester fibers in consideration of releasability, tightening force, strength, and the like. The thickness d1 of the fabric tape 8 is not limited. From the viewpoint of increasing the amount of resin absorbed by the fabric tape 8, the thickness d1 of the fabric tape 8 is preferably 50 μm or more, more preferably 70 μm or more, and even more preferably 90 μm or more. From the viewpoint of suppressing wrinkles and reducing the cost, the thickness d1 of the woven tape 8 is preferably 150 μm or less, more preferably 140 μm or less, and even more preferably 130 μm or less.

  In addition, from the viewpoint of increasing the resin absorption, the product (La × d1) of the average number of wrapping layers La and the thickness d1 (μm) of the fabric tape 8 is preferably 100 or more, more preferably 200 or more, and 300 or more. Is more preferable, and 500 or more is more preferable. From the viewpoint of productivity, this product (La × d1) is preferably 10,000 or less, more preferably 5000 or less, more preferably 1500 or less, and still more preferably 1200 or less.

  The width W1 of the fabric tape 8 is not limited. From the viewpoint of increasing the amount of resin that can be absorbed by the fabric tape 8 while increasing productivity, the width W1 of the fabric tape 8 is preferably 5 mm or more, more preferably 7 mm or more, and even more preferably 10 mm or more. From the viewpoint of suppressing generation of wrinkles and facilitating tightening of the intermediate molded body 6, the width W1 of the fabric tape 8 is preferably 35 mm or less, more preferably 30 mm or less, and even more preferably 25 mm or less.

  The woven structure of the fabric tape 8 is not limited. Examples of this weave structure include plain weave, satin weave and twill weave. When it is stretched excessively by tension, the amount of resin that can be absorbed by voids and fibers in which the resin can enter easily decreases. From the viewpoint of suppressing excessive stretching due to the tension, it is preferable that the woven structure has a thread oriented substantially parallel to the longitudinal direction of the fabric tape 8.

The fiber of the fiber reinforced resin member is not limited. As this fiber, an inorganic fiber, an organic fiber, and a metal fiber are illustrated. Examples of the inorganic fiber include carbon fiber, glass fiber, boron fiber, silicon carbide fiber, and alumina fiber. Examples of the organic fibers include polyethylene fibers and polyamide fibers. Multiple types of fibers may be combined. From the viewpoint of obtaining a lightweight tubular body while ensuring the rigidity required for the golf club shaft, the tensile elastic modulus of the fiber is preferably 5 t / mm ² or more, more preferably 10 t / mm ² or more, and 24 t / mm ² or more. Is more preferable. From the viewpoint of fiber availability, the tensile elastic modulus of the fiber is preferably 100 t / mm ² or less. This tensile elastic modulus is measured according to JIS R7601: 1986 “Carbon fiber test method”.

  Hereinafter, the effects of the present invention will be clarified by examples. However, the present invention should not be construed in a limited manner based on the description of the examples.

[Measurement of forward flex]
The upper side of the cured tubular body at a position 75 mm away from the butt end position Bt and the lower side of the position 215 mm away from the butt end position Bt were used as support points. With these two points supported, the axis direction of the cured tubular body was horizontal. Next, a weight of 2.7 kg was applied to the load point K separated by 1039 mm from the butt end position Bt. The cured tubular body was bent by the weight, and the load point K was moved downward. The amount of movement of the load point K in the vertical direction is shown in Table 2 below as the forward flex Fj.

[Wrinkle degree]
The degree of wrinkles (wrinkles) generated on the surface of the cured tubular body was evaluated by visual observation of the appearance. Evaluation was made according to the following five stages. This evaluation is shown in Table 2 below. The smaller the evaluation score, the higher the evaluation.
Evaluation 1: No wrinkles.
Evaluation 2: There are wrinkles having a length of 1 mm or more and less than 2 mm.
Evaluation 3: There are wrinkles having a length of 2 mm or more and less than 3 mm.
Evaluation 4: There are wrinkles having a length of 3 mm or more and less than 4 mm.
Evaluation 5: There are wrinkles having a length of 4 mm or more.

[Thickness of fabric tape]
The thickness d1 of the woven tape was measured using a digimetric micrometer according to JIS L 1096. After lapse of 10 seconds by applying a constant pressure of 240 g / cm ^2, it is measured under a pressure of 240 g / cm ² was made. Measurements were taken at five locations. The average value of the data at the five locations is shown in Table 2 below as “thickness d1”.

[Example 1]
After applying a release agent to the mandrel shown in FIG. 1, six prepregs were wound around this mandrel to obtain an intermediate molded body. The configuration of these six prepregs was as shown in FIG. The prepreg types and prepreg configurations of sheets s1 to s6 are shown in Table 1 below. The sheets s1 to s6 are all prepregs manufactured by Toray. The “tip ply number” in Table 1 indicates the number of windings of the prepreg at the tip end position Tp. The “fiber angle” in Table 1 is the orientation angle of the carbon fiber with respect to the shaft axis direction. In each prepreg, the matrix resin is an epoxy resin. The product number of each prepreg and the type of carbon fiber (product number) are as shown in Table 1.

  Next, a tape winding step of winding a fabric tape around the outer peripheral surface of the intermediate molded body was performed. The tape winding process was performed with a wrapping machine manufactured by Yokote Iron Works. In the winding process, the number of windings was one. The tape winding process was performed while applying a constant tension F1. The tension F1 was measured with a load cell manufactured by Nidec Sympos. Based on these tensions F1, the tensile stress T1 was calculated.

  In the tape winding process, only the fabric tape was wound. The product name “Nylon Taffeta” sold by Kinki Tape Co., Ltd. was used as this fabric tape. This nylon taffeta is a woven tape in which nylon fibers are woven in a plain weave. The type of nylon constituting this nylon fiber is nylon 6. The fabric tape had a width W1 of 15 mm and a thickness d1 of 100 μm. The tensile stress T1 in the tape winding process was 15 Mpa. The ratio (P1 / W1) was (1/15), ie about 0.06667. In the tape winding step, the winding pitch P1 was 2 mm.

  After the winding process, a curing process was performed. In this curing step, first, heating was performed at 80 ° C. for 30 minutes, and then heating was performed at 130 ° C. for 120 minutes.

  Next, the mandrel was pulled out. Next, the fabric tape was removed to obtain a cured tubular body according to Example 1.

  In Example 1, the fiber content S1 was 75% by mass. The fiber content S1 is a fiber content of the intermediate molded body made of the sheets s1 to s6. This fiber content was calculated from the fiber content of the prepreg. The fiber content S2 of the cured tubular body was calculated based on the mass Wt of the cured tubular body. The forward flex Fj was evaluated for this cured tubular body. The specifications and evaluation results of Example 1 are shown in Table 2 below.

[Examples 2 to 7]
A cured tubular body according to each example was obtained in the same manner as in Example 1 except that the tensile stress T1 and / or the ratio (P1 / W1) was changed as shown in Table 2. These specifications and evaluation results are shown in Table 2 below.

[Comparative Example 1]
Instead of the fabric tape, a resin film tape was wound. As this resin film tape, a tape made of a polypropylene film (PP film) was used. Specifically, the trade name “PT-30H” manufactured by Shin-Etsu Film Co., Ltd. was used as the PP film tape. The width of this tape was 25 mm. The ratio (P1 / W1) was set to (1/12), that is, about 0.08333. The tensile stress at the time of winding of this tape was 60 Mpa. About the others, it carried out similarly to Example 1, and obtained the hardening tubular body which concerns on the comparative example 1. The specifications and evaluation results of Comparative Example 1 are shown in Table 2 below.

[Comparative Example 2]
Instead of the fabric tape, a resin film tape was wound. As this resin film tape, a tape made of a polyethylene terephthalate film (PET film) was used. Specifically, the trade name “PET-25K” manufactured by Shin-Etsu Film Co., Ltd. was used as this PET film tape. The width of this tape was 15 mm. The ratio (P1 / W1) was set to (1/7), that is, about 0.1429. The tensile stress at the time of winding of this tape was 60 Mpa. About the others, it carried out similarly to Example 1, and obtained the hardening tubular body which concerns on the comparative example 2. The specifications and evaluation results of Comparative Example 2 are shown in Table 2 below.

[Comparative Example 3]
An integrated tape was wound instead of the fabric tape. This integrated tape is a tape in which a nylon taffeta having a width of 15 mm and a thickness of 100 μm and a PP film tape having a width of 15 mm and a thickness of 30 μm are integrated by heating and pressure bonding. The ratio (P1 / W1) was set to (1/7), that is, about 0.1429. The tensile stress at the time of winding of this tape was 60 Mpa. About the others, it carried out similarly to Example 1, and obtained the hardening tubular body which concerns on the comparative example 3. The specifications and evaluation results of Comparative Example 3 are shown in Table 2 below.

  As shown in Table 2, the example has a larger difference (S2-S1) than the comparative example. As described above, in the example, the amount of the resin excluded from the intermediate molded body during the manufacturing process is large.

  In the example, since the amount of resin decrease is large, the outer diameter of the cured tubular body is small. For this reason, the outer diameter of an Example is slightly smaller than the outer diameter of a comparative example. Due to the difference in outer diameter, the forward flex Fj of the example is larger than the forward flex Fj of the comparative example. However, since the fiber content is the same between the example and the comparative example, the difference in the forward flex Fj is slight. Then, regarding the value [1 / (Fj × Wt)] obtained by dividing the reciprocal (1 / Fj) of the forward flex Fj by the mass Wt of the cured tubular body, the example is larger than the comparative example. The greater the reciprocal (1 / Fj) of the forward flex Fj, the greater the rigidity of the cured tubular body. A large [1 / (Fj × Wt)] means that the rigidity per unit mass is improved. The example has a higher rigidity per unit mass than the comparative example.

  In Comparative Example 3, the tape was twisted in the tape winding process, and wrinkles were generated in the cured tubular body due to the twist.

  In Example 1, since the average number of wrapping layers La and the number of wrapping layers L1 are large, some wrinkles are generated. However, the wrinkles of Example 1 are better than the wrinkles of Comparative Example 3. In Examples 3 to 5, (S2-S1) is larger than Examples 6 and 7. This is an effect of increasing the average number of wrapping layers La.

In the golf club shaft, since the head is attached to the tip, the strength at the tip is particularly important. In Example 1 and Comparative Example 1, the void ratio Rb at the shaft tip was measured. As a result, the void ratio Rb of Comparative Example 1 was 0.8%, whereas the void ratio Rb of Example 1 was 0.3%, which was 63% lower than that of Comparative Example 1. In addition, this void ratio Rb calculated | required void area Sb and shaft cross-sectional area Sm from the image of the cross section of the point 90 mm away from the shaft front-end | tip, and computed it with the following formula.
Rb (%) = (Sb / Sm) × 100

  Thus, an Example is high evaluation compared with a comparative example. From this evaluation result, the superiority of the present invention is clear.

  The present invention can be applied to any FRP tubular body including a golf club shaft.

FIG. 1 is a view showing a mandrel and a prepreg that can be used in an embodiment of the present invention. FIG. 2 is a partial cross-sectional perspective view showing an example of the tape winding step in the present invention. FIG. 3 is a partial cross-sectional perspective view showing another example of the tape winding step in the present invention.

Explanation of symbols

2 ... Mandrel 4 ... Prepreg (fiber reinforced resin member)
6 ... Intermediate molded body 8 ... Textile tape 10 ... Textile tape 12 ... Textile covering s1, s2, s3, s4, s5, s6 ... Sheet made of prepreg

Claims (5)

Winding a fiber reinforced resin member containing fibers and a matrix resin around a mandrel to obtain an intermediate molded body;
A tape winding step of winding a wrapping tape while applying tension to the outer peripheral surface of the intermediate molded body,
A curing step of curing the matrix resin by heating the intermediate molded body around which the wrapping tape is wound;
Drawing the mandrel after the curing step and removing the wrapping tape to obtain a cured tubular body,
A method for producing a fiber-reinforced resin tubular body, wherein the wrapping tape is a woven tape.   The manufacturing method according to claim 1, wherein a tensile stress T1 applied to the fabric tape in the tape winding step is 5 (Mpa) or more and 150 (Mpa) or less.   The number L1 of wrapping layers of the fabric tape wound in the tape winding step is one or more layers at all points from the tip end position Tp1 of the tubular body to the butt end position Bt1 of the tubular body. The manufacturing method as described.   When the fiber content of the intermediate molded body is S1 (mass%) and the fiber content of the cured tubular body is S2 (mass%), the difference (S2-S1) is 3 mass% or more and 25 mass% or less. The method for producing a tubular body made of fiber-reinforced resin according to any one of claims 1 to 3.   A tubular body manufactured by the manufacturing method according to claim 1.

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