JP2009181782A - Closed battery - Google Patents
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- JP2009181782A JP2009181782A JP2008019187A JP2008019187A JP2009181782A JP 2009181782 A JP2009181782 A JP 2009181782A JP 2008019187 A JP2008019187 A JP 2008019187A JP 2008019187 A JP2008019187 A JP 2008019187A JP 2009181782 A JP2009181782 A JP 2009181782A
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- insulating member
- electrode lead
- battery
- out pin
- plate
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- 229910052751 metal Inorganic materials 0.000 claims abstract description 20
- 239000002184 metal Substances 0.000 claims abstract description 20
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 8
- 229910001416 lithium ion Inorganic materials 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000004734 Polyphenylene sulfide Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000009422 external insulation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229920011301 perfluoro alkoxyl alkane Polymers 0.000 description 2
- 229920013653 perfluoroalkoxyethylene Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 239000004813 Perfluoroalkoxy alkane Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009421 internal insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Sealing Battery Cases Or Jackets (AREA)
Abstract
Description
本発明は、密閉型電池に関し特に密閉の信頼性を向上した密閉型電池に関する。 The present invention relates to a sealed battery, and more particularly, to a sealed battery with improved sealing reliability.
近年の携帯電子技術のめざましい発達により、携帯電話やノートブックコンピューターなどの電子機器は高度情報化社会を支える基盤技術として認識されている。これらの電子機器の高機能化に関する研究開発は精力的に進められており、高機能化による消費電力の増加に伴い、駆動時間の長期化が課題とされてきた。一定水準以上の駆動時間を確保するためには、駆動電源として用いられる二次電池の高エネルギー密度化が必須条件である。上述の様な電池技術の動向の中で、特に角型の電池缶を電池外装容器として用いた密閉型電池などが重要視されている。 Due to the remarkable development of portable electronic technology in recent years, electronic devices such as mobile phones and notebook computers are recognized as basic technologies that support an advanced information society. Research and development related to the enhancement of the functions of these electronic devices has been energetically advanced, and with the increase in power consumption due to the enhancement of functions, it has been a problem to extend the driving time. In order to ensure a driving time above a certain level, it is an essential condition to increase the energy density of a secondary battery used as a driving power source. Among the battery technology trends as described above, a sealed battery using a rectangular battery can as a battery outer container is regarded as important.
図3は従来の密閉型電池を説明する図であり、図3(a)は斜視図、図3(b)は電極導出ピン部の断面図、図3(c)はヘッダ部の分解斜視図、図3(d)はヘッダに使用される外部絶縁部材の断面図である。 3A and 3B are diagrams illustrating a conventional sealed battery. FIG. 3A is a perspective view, FIG. 3B is a cross-sectional view of an electrode lead-out pin portion, and FIG. 3C is an exploded perspective view of a header portion. FIG. 3D is a cross-sectional view of an external insulating member used for the header.
図3に示した密閉型電池は、アルミニウムまたはその合金を電池外装容器とした密閉型電池であり、ヘッダ部はアルミニウムまたはその合金からなる金属板3に設けた貫通孔10に上部からプロピレン、フッ素樹脂等からなる板状の外部絶縁部材4を取り付け、外部絶縁部材4の中心部に設けた管状部42に、鉄、ニッケル、それらの合金等の導電性の良好な金属からなる電極導出ピン6を貫通させ、電池外装容器の内部には、板状の内部絶縁部材5、導電タブ接続板11が装着されており、電極導出ピン6の柱状部62の先端をかしめ加工することによってヘッダ7が形成される。
The sealed battery shown in FIG. 3 is a sealed battery in which aluminum or an alloy thereof is used as a battery outer container, and a header portion is formed from propylene, fluorine from the top in a
作製されたヘッダ7の導電タブ接続板11には、導電タブ13を接合して電池要素との間で導電接続を形成する。その後にヘッダ7を電池外装容器の開口部に装着して周囲をレーザ溶接により封口する。その結果、ヘッダは、その組立時に電極導出ピン6のかしめによって、絶縁部材と接触する各部材とが密着され、また周囲はレーザ溶接により封口されるため、気密が保持される。
A
しかし、密閉型電池に過酷な使用条件を想定した試験を行うと、ヘッダ部から漏液が稀に発生することがあった。そこで、こうした問題を解決するために、特許文献1には電極導出ピンのフランジ部の絶縁部材との接触面に凸部を有する技術が提案されている。また、特許文献2では、外部絶縁部材の電極導出ピンとの接触面、及び金属板との接触面のそれぞれに環状の凸条部を成形し、気密特性を向上させる技術が提案されている。
However, when a sealed battery is tested under severe operating conditions, liquid leakage sometimes occurs from the header portion. Therefore, in order to solve such a problem,
しかしながら、特許文献1で提案の技術では、絶縁部材に電極導出ピンのフランジ部の凸部が食い込んだ際に、絶縁部材にひび割れが生じて、時間の経過後には気密不良が生じたり、あるいは、かしめ時に加わる圧力が大きい場合には、絶縁部材に割れが生じる恐れがある。また、特許文献2で提案の技術では、環状の凸状部45(図3参照)が絶縁部材に対して、小さな凸部を高精度に成形する必要があるため、小さな溝部を有する成形金型の作製、維持等の製造面での保守作業が煩雑となっていた。
However, in the technique proposed in
本発明の課題は、絶縁性、気密性に優れ、使用する外部絶縁部材の経時変化が小さく、信頼性、生産性に優れた密閉型電池を提供するものである。 An object of the present invention is to provide a sealed battery that is excellent in insulation and airtightness, has little change with time in an external insulating member to be used, and is excellent in reliability and productivity.
本発明の密閉型電池は、電池要素を収納する電池外装容器の開口部を金属板で封口する密閉型電池において、前記金属板に設けた電極導出ピン引き出し用の貫通孔の周囲を被覆する、板状部と下部に管状部を有する外部絶縁部材の、前記電極導出ピンの頭部と圧接する板状部の孔の周囲に環状の上部凸部を有し、前記外部絶縁部材の前記金属板と圧接する板状部の管状部の周囲に環状の下部厚肉部を有することを特徴とする。 The sealed battery of the present invention covers a periphery of a through hole for drawing out an electrode lead-out pin provided in the metal plate in a sealed battery in which an opening of a battery outer container that stores a battery element is sealed with a metal plate. An outer insulating member having a plate-like portion and a tubular portion at a lower portion, and having an annular upper convex portion around a hole of the plate-like portion pressed against the head of the electrode lead-out pin, and the metal plate of the outer insulating member An annular lower thick portion is provided around the tubular portion of the plate-like portion that is in pressure contact therewith.
また、前記外部絶縁部材の管状部の外壁からの下部厚肉部の幅(L1)が前記外部絶縁部材の管状部の外壁から前記外部絶縁部材の前記電極導出ピンの頭部と圧接する最外部までの距離(L2)の3%以上30%以下であることが好ましい。 In addition, the outermost portion where the width (L1) of the lower thick portion from the outer wall of the tubular portion of the outer insulating member is in pressure contact with the head of the electrode lead-out pin of the outer insulating member from the outer wall of the tubular portion of the outer insulating member The distance (L2) is preferably 3% or more and 30% or less.
本発明によれば、電極導出ピンと金属板との間に外部絶縁部材を介し、電極導出ピンをかしめて作製したヘッダが、電極導出ピンの頭部と圧接する外部絶縁部材の接触面に環状の上部凸部を設け、金属板と圧接する外部絶縁部材の接触面に環状の下部厚肉部を設けることにより、上部凸部および下部厚肉部が圧縮され、外部絶縁部材にて電池内部の気密性を確保する結果、苛酷な条件下で使用した場合にも気密性が優れた密閉型電池を提供することができる。また、環状の下部厚肉部を有する外部絶縁部材の製造は簡便に行えるため生産性の優れた密閉型電池を提供することができる。 According to the present invention, the header produced by caulking the electrode lead-out pin with the electrode lead-out pin and the metal plate interposed between the electrode lead-out pin and the contact surface of the external insulation member in pressure contact with the head of the electrode lead-out pin is annular. By providing the upper convex part and providing the annular lower thick part on the contact surface of the external insulating member that is in pressure contact with the metal plate, the upper convex part and the lower thick part are compressed, and the external insulating member As a result, it is possible to provide a sealed battery having excellent airtightness even when used under severe conditions. In addition, since an external insulating member having an annular lower thick portion can be easily manufactured, a sealed battery with excellent productivity can be provided.
次に、本発明の実施の形態について図面を参照して説明する。 Next, embodiments of the present invention will be described with reference to the drawings.
図1は本発明の密閉型電池を説明する図であり、図1(a)は斜視図、図1(b)は密閉型電池の電極導出ピンの周囲を示す断面図、図1(c)はヘッダの組立前の分解斜視図、図1(d)は外部絶縁部材の断面図である。本発明の密閉型電池は、アルミニウム、アルミニウム合金からなる角形の電池外装容器2にセパレータを介して正極と負極を積層して扁平に巻回した電池要素が収容されており、金属板3に外部絶縁部材4および内部絶縁部材5からなる絶縁部材と負極側の電極導出ピン6を一体化して構成したヘッダ7を、電池外装容器2の開口部に例えばレーザ溶接により取り付けたものであり、金属板3には安全弁8、電解液の注液孔9が設けられている。
FIG. 1 is a diagram for explaining a sealed battery according to the present invention, FIG. 1 (a) is a perspective view, FIG. 1 (b) is a sectional view showing the periphery of an electrode lead-out pin of the sealed battery, and FIG. Is an exploded perspective view before assembly of the header, and FIG. 1D is a cross-sectional view of the external insulating member. In the sealed battery of the present invention, a battery element in which a positive electrode and a negative electrode are laminated and wound flatly via a separator is accommodated in a rectangular battery
密閉型電池を封口するヘッダ7の金属板3に設けた電極導出ピン6引出し用の貫通孔10の周囲を金属板3の上下を覆うように配置された絶縁部材は、密閉型電池の外面に面した外部絶縁部材4と、密閉型電池の内面に位置する内部絶縁部材5から構成され、外部絶縁部材4に設けた中央部の孔に電極導出ピン6の柱状部62を貫通させ、金属板3の内部側に配置した内部絶縁部材5上に導電タブ接続板11を配置して柱状部62の先端をかしめることによりヘッダ7は形成される。また、導電タブ接続板11には、電池要素と接続される、絶縁被覆材12を設けた導電タブ13が接合される。
An insulating member arranged so as to cover the upper and lower sides of the
外部接続部材4には電極導出ピン6の頭部61との圧接面の板状部41の孔の周囲に環状の上部凸部43を設け、金属板3との圧接面の板状部41の管状部42の周囲に環状の下部厚肉部44を設けている。外部接続部材4に設けた上部凸部43と下部厚肉部44は電極導出ピン6の柱状部62をかしめる際に圧縮されて外部絶縁部材に接触する金属材料との間で優れた気密性を発揮する。
The
上部凸部の形状は連続した環状に形成したものであれば任意の形状でよい。また上部凸部の大きさは、電極導出ピンの大きさにより異なるが、電極導出ピンの柱状部の径が1〜3mm程度のものであれば高さ0.1〜0.2mm、幅0.1〜0.2mmとすることが好ましい。 The shape of the upper convex portion may be any shape as long as it is formed in a continuous annular shape. The size of the upper convex portion varies depending on the size of the electrode lead-out pin. If the diameter of the columnar portion of the electrode lead-out pin is about 1 to 3 mm, the height is 0.1 to 0.2 mm, the width is 0. It is preferable to set it as 1-0.2 mm.
図2は本発明の密閉型電池の外部絶縁部材の断面図である。外部絶縁部材4の下部厚肉部の高さは電極導出ピンの柱状部の径が1〜3mm程度のものであれば高さ0.1〜0.2mmとすることが好ましい。外部絶縁部材4の下部厚肉部の幅L1は外部絶縁部材の管状部42の外壁から外部絶縁部材の電極導出ピンの頭部と圧接する最外部までの距離(L2)の3%以上30%以下であることが好ましい。
FIG. 2 is a cross-sectional view of the external insulating member of the sealed battery of the present invention. The height of the lower thick portion of the
本発明において、内部絶縁部材、外部絶縁部材としては、電気絶縁性を有するものが使用でき、ポリフェニレンサルファイド(PPS)、テトラフルオロエチレン−パーフルオロアルコキシエチレン共重合体(PFA)、ポリプロピレン(PP)またはPPS、PFA、PPにエラストマーを含んだ電気絶縁性樹脂を挙げることができる。 In the present invention, as the internal insulation member and the external insulation member, those having electrical insulation can be used, such as polyphenylene sulfide (PPS), tetrafluoroethylene-perfluoroalkoxyethylene copolymer (PFA), polypropylene (PP) or An electrically insulating resin containing an elastomer in PPS, PFA, or PP can be used.
(実施例1)
長辺が34mm、短辺が6mmの長方形状のアルミニウム合金製の金属板の中央に設けた直径2.2mmの貫通孔にテトラフルオロエチレン−パーフルオロアルコキシエチレン共重合体からなる外部絶縁部材、および内部絶縁部材を装着し、直径1.6mmの孔を中央に有したニッケル板製の導電タブ接続板を内部絶縁部材面に配置して、柱状部の直径1.6mmのニッケル合金製の電極導出ピンを、外部絶縁部材の上部から貫通させて、電極導出ピンを上下からかしめてヘッダを製造した。
Example 1
An external insulating member made of a tetrafluoroethylene-perfluoroalkoxyethylene copolymer in a 2.2 mm diameter through hole provided in the center of a rectangular aluminum alloy metal plate having a long side of 34 mm and a short side of 6 mm; and A nickel tab conductive tab connecting plate with a 1.6 mm diameter hole in the center is placed on the inner insulating member surface, and the columnar part has a 1.6 mm diameter nickel alloy electrode lead-out. A header was manufactured by penetrating the pin from the top of the external insulating member and crimping the electrode lead-out pin from above and below.
なお、外部絶縁部材には、直径1.65mmの貫通孔を有し、厚さ0.3mmの板状部を有しており、電極導出ピンとの圧接面には板状部の孔の周囲に環状の上部凸部が、円弧状で幅が0.1mm 、高さ0.1mmで形成され、金属板との圧接面には板状部の管状部の周囲に環状の下部厚肉部が板状部と平行に0.1mm厚肉となり、下部厚肉部の幅L1は、外部絶縁部材の管状部の外壁から外部絶縁部材の電極導出ピンの頭部と圧接する最外部までの距離(L2)の5%(L1/L2=0.05)とした。 The external insulating member has a through hole having a diameter of 1.65 mm and a plate-like portion having a thickness of 0.3 mm. The pressure contact surface with the electrode lead-out pin is around the hole of the plate-like portion. An annular upper convex portion is formed in an arc shape with a width of 0.1 mm and a height of 0.1 mm. On the pressure contact surface with the metal plate, an annular lower thick portion is formed around the tubular portion of the plate-like portion. The width L1 of the lower thick portion is parallel to the shape portion, and the width L1 of the lower thick portion is the distance (L2) from the outer wall of the tubular portion of the external insulating member to the outermost portion in pressure contact with the head of the electrode lead-out pin of the external insulating member ) 5% (L1 / L2 = 0.05).
得られたヘッダを使用して大きさが34mm×6mm×50mmのリチウムイオン電池を1000個作製した。 1000 lithium ion batteries having a size of 34 mm × 6 mm × 50 mm were produced using the obtained header.
(実施例2)
L1/L2=0.08となるように成形した外部絶縁部材を用いた他は実施例1と同様にリチウムイオン電池を1000個作製した。
(Example 2)
1000 lithium ion batteries were produced in the same manner as in Example 1 except that an external insulating member molded so that L1 / L2 = 0.08 was used.
(実施例3)
L1/L2=0.1となるように成形した外部絶縁部材を用いた他は実施例1と同様にリチウムイオン電池を1000個作製した。
(Example 3)
1000 lithium ion batteries were produced in the same manner as in Example 1 except that an external insulating member formed so that L1 / L2 = 0.1 was used.
(実施例4)
L1/L2=0.2となるように成形した外部絶縁部材を用いた他は実施例1と同様にリチウムイオン電池を1000個作製した。
Example 4
1000 lithium ion batteries were produced in the same manner as in Example 1 except that an external insulating member formed so that L1 / L2 = 0.2 was used.
(実施例5)
L1/L2=0.3となるように成形した外部絶縁部材を用いた他は実施例1と同様にリチウムイオン電池を1000個作製した。
(Example 5)
1000 lithium ion batteries were produced in the same manner as in Example 1 except that an external insulating member formed so that L1 / L2 = 0.3 was used.
(実施例6)
L1/L2=0.03となるように成形した外部絶縁部材を用いた他は実施例1と同様にリチウムイオン電池を1000個作製した。
(Example 6)
1000 lithium ion batteries were produced in the same manner as in Example 1 except that an external insulating member molded so that L1 / L2 = 0.03 was used.
(実施例7)
L1/L2=1.05となるように成形した外部絶縁部材を用いた他は実施例1と同様にリチウムイオン電池を1000個作製した。
(Example 7)
1000 lithium ion batteries were produced in the same manner as in Example 1 except that an external insulating member formed so that L1 / L2 = 1.05 was used.
(比較例1)
外部絶縁板の板状部の管状部の周囲に環状の下部厚肉部を形成しない以外は実施例1と同様にリチウムイオン電池を1000個作製した。
(Comparative Example 1)
1000 lithium ion batteries were produced in the same manner as in Example 1 except that the annular lower thick part was not formed around the tubular part of the plate-like part of the external insulating plate.
作製した電池について、通常の使用状態を超える苛酷な条件である100℃ において12時間加熱した後にリトマス試験紙をかざして漏液試験を行った結果を表1に示す。 Table 1 shows the results of the liquid leakage test conducted on the manufactured battery after heating at 100 ° C., which is a severe condition exceeding the normal use condition, for 12 hours and holding the litmus paper.
表1に示すように、本発明の密閉型電池は、苛酷な条件下で使用された場合にも優れた気密性を発揮することがわかる。 As shown in Table 1, it can be seen that the sealed battery of the present invention exhibits excellent airtightness even when used under severe conditions.
1 密閉型電池
2 電池外装容器
3 金属板
4 外部絶縁部材
41 板状部
42 管状部
43 上部凸部
44 下部厚肉部
5 内部絶縁部材
6 電極導出ピン
61 頭部
62 柱状部
7 ヘッダ
8 安全弁
9 注液孔
10 貫通孔
11 導電タブ接続板
12 絶縁被覆材
13 導電タブ
L1 下部厚肉部の幅
L2 管状部外壁から金属板と圧接する最外部までの距離
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CN102610783A (en) * | 2011-01-20 | 2012-07-25 | 株式会社杰士汤浅国际 | Electric storage device |
US9379372B2 (en) | 2011-04-14 | 2016-06-28 | Gs Yuasa International Ltd. | Battery and method of manufacturing the same |
US9685643B2 (en) | 2010-12-28 | 2017-06-20 | Gs Yuasa International Ltd. | Electric storage device |
WO2017115856A1 (en) * | 2015-12-28 | 2017-07-06 | 株式会社Gsユアサ | Sealing member, electricity storage element and method for manufacturing electricity storage element |
DE102017200823A1 (en) | 2016-01-21 | 2017-07-27 | Gs Yuasa International Ltd. | Energy storage device, energy storage device and method for producing the energy storage device |
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JP2005056649A (en) * | 2003-08-01 | 2005-03-03 | Hitachi Maxell Ltd | Sealed battery |
JP2006216411A (en) * | 2005-02-04 | 2006-08-17 | Nec Tokin Tochigi Ltd | Sealed battery |
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JP2005056649A (en) * | 2003-08-01 | 2005-03-03 | Hitachi Maxell Ltd | Sealed battery |
JP2006216411A (en) * | 2005-02-04 | 2006-08-17 | Nec Tokin Tochigi Ltd | Sealed battery |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9685643B2 (en) | 2010-12-28 | 2017-06-20 | Gs Yuasa International Ltd. | Electric storage device |
CN102610783A (en) * | 2011-01-20 | 2012-07-25 | 株式会社杰士汤浅国际 | Electric storage device |
KR20120084680A (en) * | 2011-01-20 | 2012-07-30 | 가부시키가이샤 지에스 유아사 | Electric storage device |
JP2012164634A (en) * | 2011-01-20 | 2012-08-30 | Gs Yuasa Corp | Electric storage element |
KR101968713B1 (en) * | 2011-01-20 | 2019-04-12 | 가부시키가이샤 지에스 유아사 | Electric storage device |
EP2479815B1 (en) * | 2011-01-20 | 2019-06-05 | GS Yuasa International Ltd. | Electric storage device |
US10714715B2 (en) | 2011-01-20 | 2020-07-14 | Gs Yuasa International Ltd. | Electric storage device |
US9379372B2 (en) | 2011-04-14 | 2016-06-28 | Gs Yuasa International Ltd. | Battery and method of manufacturing the same |
WO2017115856A1 (en) * | 2015-12-28 | 2017-07-06 | 株式会社Gsユアサ | Sealing member, electricity storage element and method for manufacturing electricity storage element |
DE102017200823A1 (en) | 2016-01-21 | 2017-07-27 | Gs Yuasa International Ltd. | Energy storage device, energy storage device and method for producing the energy storage device |
US10998538B2 (en) | 2016-01-21 | 2021-05-04 | Gs Yuasa International Ltd. | Energy storage device, energy storage apparatus and method of manufacturing energy storage device |
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