JP2009156513A - Endothermic gas generating device - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an endothermic gas generating device, detecting the damage occurrence of retort at an early point in an operating state of the device. <P>SOLUTION: This endothermic gas generating device 1, having the retort 3 and a heater 4 in a furnace body 2, further has: a carbon dioxide gas concentration measuring device 21 for measuring a carbon dioxide gas concentration U of the atmosphere in the furnace body 2; and a determining device 25 for determining that the retort 3 has damage when a measurement value U of the carbon dioxide gas concentration with the carbon dioxide gas concentration measuring device 21 becomes more than a set value U<SB>0</SB>. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to an endothermic gas generator that generates an endothermic gas used as an atmosphere gas for heat treatment.

In a heat treatment furnace that performs heat treatment such as non-oxidation heat treatment, bright heat treatment, and carburization treatment on an object such as steel, carbon monoxide, hydrogen, and nitrogen are used as gases for forming a reducing (non-oxidation) atmosphere. An endothermic gas as a main component is used. As an apparatus for generating this endothermic gas, a retort filled with a catalyst and a heater for heating this retort are generally provided in the furnace body, and a hydrocarbon gas such as propane, butane or natural gas and air are provided. An endothermic gas generator (also referred to as a shift furnace) that generates an endothermic gas by circulating a mixed gas through the retort and heating it at a high temperature is used (see, for example, Patent Documents 1 to 3).
No. 8-982 Japanese Patent No. 2701334 JP 2002-356663 A

  However, in the above endothermic gas generator, damage to the retort made of heat-resistant metal, such as cracks and pinholes that communicate between the retort and the furnace body, may occur due to long-term use of the apparatus. When this retort damage occurs, the gas in the retort leaks into the furnace and burns, causing further damage to the retort itself and the furnace body. Because it was detected by the occurrence of abnormalities such as heater disconnection, furnace temperature overheating, and flame ejection from the furnace body during operation of the equipment, it was decided to detect the occurrence of damage after a considerable amount of time had elapsed since the occurrence of retort damage. Therefore, it was not possible to prevent the damage of each part of the apparatus from being enlarged.

  An object of the present invention is to provide an endothermic gas generator capable of detecting the occurrence of damage to the retort at an early stage in the operating state of the apparatus.

  In order to achieve the above object, the inventors conducted a detailed investigation and analysis on how the atmospheric gas components in the furnace body during operation of the endothermic gas generator fluctuate due to the occurrence of damage to the retort. It has been found that the occurrence of damage to the retort can be detected based on the fluctuation of the atmospheric gas component. Specifically, when the retort is damaged, the generated gas (endothermic gas) in the retort leaks into the furnace, and the carbon monoxide in the generated gas becomes carbon dioxide in the high-temperature furnace. The hydrogen in the furnace becomes water vapor, and the oxygen concentration in the furnace decreases with these oxidations. When the oxygen concentration is further reduced, the carbon monoxide concentration in the unoxidized state increases due to insufficient oxidation of carbon monoxide in the product gas. However, when the damage is in the vicinity of the inlet of the retort, the same phenomenon as the generation of carbon dioxide gas and the decrease in oxygen concentration occurs due to the leakage of the hydrocarbon gas as the raw material gas. It has been found that the occurrence of retort damage can be detected by detecting the variation of the atmospheric gas components in the furnace body, and the present invention has been completed based on this finding.

  That is, the endothermic gas generator according to claim 1 is an endothermic gas generator provided with a retort and a heater in the furnace, and the carbon dioxide concentration measuring device for measuring the carbon dioxide concentration in the atmosphere in the furnace, And a determination device that determines that the retort is damaged when a measured value of the carbon dioxide concentration by the carbon dioxide concentration measuring device is equal to or greater than a set value.

  In this invention (inventions of claims 1 to 4), "heater" refers to a radiant heater such as an electric heater or a radiant tube, excluding burner heaters that change the atmosphere in the furnace. And

  According to the first aspect of the present invention, the carbon dioxide gas that is a concentration measurement target does not exist in the furnace of the endothermic gas generator that is operating in a state where there is no damage to the retort, and the generation is caused by damage to the retort. Since it is generated only by the oxidation of carbon monoxide in the gas and hydrocarbons in the raw material gas, the retort of the retort can be detected quickly and accurately by comparing the measured carbon dioxide concentration with a small carbon dioxide concentration set value close to zero. Damage occurrence can be detected.

  According to a second aspect of the present invention, there is provided an endothermic gas generator having a retort and a heater in the furnace, an oxygen concentration measuring device for measuring the oxygen concentration of the atmosphere in the furnace, and an oxygen concentration by the oxygen concentration measuring device. And a determination device that determines that the retort is damaged when the measured value is equal to or less than a set value.

  According to the second aspect of the present invention, the oxygen whose concentration is to be measured is the oxygen concentration (21%) of the atmosphere around the furnace body in the furnace body of the endothermic gas generator in operation in a state where the retort is not damaged. ) And is reduced by being consumed by the oxidation of carbon monoxide and hydrogen in the product gas and the oxidation of hydrocarbons in the raw material gas due to damage of the retort. The occurrence of retort damage can be detected at an early stage by comparing the measured oxygen concentration with the oxygen concentration set value that is a predetermined amount smaller than the oxygen concentration in the atmosphere.

  The endothermic gas generator according to claim 3 is an endothermic gas generator provided with a retort and a heater in a furnace body, a moisture concentration measuring apparatus for measuring the moisture concentration of the atmosphere in the furnace body, and the moisture concentration measurement. And a determination device that determines that the retort is damaged when the measured value of the moisture concentration by the device exceeds a set value.

  According to the third aspect of the present invention, the moisture whose concentration is to be measured is approximately equal to the moisture concentration of the atmosphere around the furnace body in the furnace body of the endothermic gas generator in operation in a state where there is no damage to the retort. Since it has a water concentration and increases due to oxidation of hydrogen in the product gas due to damage to the retort, the measured water concentration is compared with a water concentration set value that is a predetermined amount greater than the water concentration in the atmosphere. Thus, the occurrence of retort damage can be detected at an early stage.

  The endothermic gas generator according to claim 4 is an endothermic gas generator provided with a retort and a heater in the furnace body, and a carbon monoxide concentration measuring device for measuring the carbon monoxide concentration in the atmosphere in the furnace body; And a determination device that determines that the retort is damaged when a measured value of the carbon monoxide concentration by the carbon monoxide concentration measurement device is equal to or greater than a set value.

  According to the invention of claim 4, carbon monoxide which is a concentration measurement target does not exist in the furnace body of the endothermic gas generator in operation in a state where the retort is not damaged, and the carbon monoxide which is being measured is damaged by the retort. When the oxygen concentration is decreased by being consumed by the oxidation of carbon monoxide and hydrogen in the product gas and the oxidation of hydrocarbons in the raw material gas, the concentration increases as unoxidized carbon monoxide, By comparing the measured carbon monoxide concentration with a small carbon monoxide concentration set value close to zero, the occurrence of retort damage can be detected quickly and accurately.

  As described above, according to the present invention, during the operation of the endothermic gas generator, the occurrence of retort damage is detected at an early stage by detecting the fluctuation state of the atmospheric gas component that fluctuates due to the occurrence of damage to the retort. Can be detected.

In addition to the above effects, according to the first aspect of the present invention, as a measurement / judgment target gas for detecting the occurrence of retort damage, it exists in the atmosphere in the furnace body and around the furnace body in a state without retort damage. Since carbon dioxide gas that is not used is used, occurrence of retort damage can be detected with high accuracy based on a low concentration set value U ₀ close to zero, and retort damage can be detected particularly early.

  An embodiment of the invention described in claim 1 will be described below with reference to a first example shown in FIGS. In FIG. 1, 1 is an endothermic gas generator, 2 is a furnace body thereof, a U-shaped retort 3 filled with a nickel catalyst (not shown) in the furnace body 2, and electric heat for heating the retort. A heater 4 of the type is provided. A plurality of retorts 3 are arranged side by side, but only one is shown.

  Reference numeral 5 denotes a raw material gas supply path which is connected to one end of the retort 3 projecting outside the furnace body 2, and 6 is a generated gas delivery path which is also connected to the other end of the retort 3. A hydrocarbon gas supply path 7 and an air supply path 8 joined at the downstream portion are connected to the source gas supply path 5 via a roots blower 9. 10 and 11 are flow meters, 12 is a filter at the air inlet, and 13 is a valve that adjusts the flow rate of gas supplied from a hydrocarbon gas supply device (not shown) to adjust the mixing ratio of air and hydrocarbon gas. Reference numeral 14 denotes a cooler for gas cooling provided in the product gas delivery path 6, and the front end side of the product gas delivery path 6 is connected to a product gas use device such as an atmospheric heat treatment furnace (not shown) via an on-off valve 15. Yes.

On the other hand, reference numeral 20 denotes a retort damage detection device, which is a carbon dioxide concentration measuring device 21 that measures the carbon dioxide concentration U in the furnace body 2 and when the measured value of the carbon dioxide concentration by this measuring device is equal to or greater than a set value U _0. And a determination device 25 that determines that the retort 3 is damaged.

The carbon dioxide concentration measuring device 21 is configured by connecting a sampling tube 22 whose one end opens into the furnace body 2 to a carbon dioxide analyzer 24 that measures the carbon dioxide concentration via a gas suction pump 23. The determination device 25 compares the setting device 26 for setting the carbon dioxide concentration set value U ₀ , the carbon dioxide concentration measurement value U output from the carbon dioxide analyzer 24 and the set value U _0. The comparator 27 outputs a damage detection signal S ₁ when the measured value of the carbon dioxide gas concentration is equal to or greater than the set value U _{0. In} this example, the damage detection signal S ₁ is input to the alarm device 28. is there.

Next, FIG. 2 is a diagram schematically showing a change in carbon dioxide gas concentration in the furnace body 2 when the retort 3 is damaged during the operation of the endothermic gas generator 1. Although the concentration of carbon dioxide inside is zero, the retort damage at T ₁ is generated, the carbon monoxide and the raw material gas in the product gas leaking from the damaged portion into the furnace body 2 (endothermic gas) The hydrocarbon is oxidized in the furnace body at a high temperature to become carbon dioxide, and the concentration of carbon dioxide in the furnace body 2 increases as shown in the figure. Therefore, the setting device 26 is set by selecting a setting value U ₀ close to zero as the setting value of the carbon dioxide gas concentration.

In the apparatus having the above-described configuration, the endothermic gas generator 1 is configured to supply the source gas from the source gas supply path 5 into the retort 3 and circulate through the retort 3 heated by the heater 4 to generate the endothermic gas. During operation, the retort damage detector 20 is also continuously operated, and a part (small amount) of atmospheric gas in the furnace body 2 is continuously sucked by the pump 23 to monitor the carbon dioxide concentration (carbon dioxide gas by the carbon dioxide analyzer 24). Comparison between the measured density value U and the set value U ₀ in the comparator 27 is always performed. In this state, when the damage to the retort 3 at T ₁ is produced, since its concentration carbon dioxide gas is generated as described above increases, the measured value U of carbon dioxide concentration by carbon dioxide analyzer 24 is a set value U ₀ The determination device 25 detects the retort damage at the time T ₂ when the above is reached and issues a damage detection signal S _1, and the retort damage is notified by the sounding of the alarm device 28.

As described above, since the occurrence of damage to the retort 3 is detected when the carbon dioxide concentration in the atmosphere in the furnace body 2 exceeds the set value, the generated gas and the raw material gas leaked from the retort 3 due to damage Retort damage at an early stage of carbon dioxide generation by carbon monoxide and hydrocarbon combustion, that is, at an early stage after the occurrence of retort damage, before the furnace is filled with high concentration and burned vigorously The occurrence can be detected. Particularly in this example, carbon dioxide gas, which is a measurement / judgment target gas, does not exist in the furnace body without retort damage and in the atmosphere around the furnace body. Therefore, the occurrence of retort damage can be detected accurately based on the low concentration set value U ₀ close to zero, and the occurrence of damage can be detected in a short time after the occurrence of retort damage.

  Next, an embodiment of the invention described in claim 2 will be described with reference to a second example shown in FIGS. The apparatus of this example uses a retort damage detection device 30 whose measurement target is oxygen concentration instead of the retort damage detection device 20 whose measurement target is carbon dioxide concentration in the first example, and has other configurations. Since this is the same as the apparatus of the first example, the same parts as those in FIG. 1 are denoted by the same reference numerals as those in FIG. 1, and detailed description thereof will be omitted.

  That is, the retort damage detection device 30 includes an oxygen concentration measurement device 31 that measures the oxygen concentration in the furnace body 2 and that the retort 3 is damaged when the measured value of the oxygen concentration by the measurement device is equal to or less than a set value. And a determination device 35 for determination.

The oxygen concentration measuring device 31 is configured by connecting a sampling tube 32 whose one end opens into the furnace body 2 to an oxygen sensor 34 for measuring the oxygen concentration via a gas suction pump 33. The determination device 35 includes a setter 36 for setting a set value V ₀ which oxygen concentration is compared with the oxygen concentration measurement value V and the set value V ₀ to the output of the oxygen sensor 34, the oxygen concentration measurement When the value becomes equal to or less than the set value V ₀ , the comparator 37 outputs a damage detection signal S _{2. In} this example, the damage detection signal S ₂ is input to the alarm device 38.

Next, FIG. 4 is a diagram schematically showing a change in oxygen concentration in the furnace body 2 when the retort 3 is damaged during the operation of the endothermic gas generator 1. When the oxygen concentration while indicating approximately equal to the oxygen concentration Va (= 21%) of the surrounding atmosphere furnace, the retort damage occurs at time T _1, leakage from the damaged portion into the furnace body 2 As the carbon monoxide in the generated gas (endothermic gas) and the hydrocarbon in the raw material gas are oxidized in the high-temperature furnace to become carbon dioxide, and the hydrogen in the generated gas also becomes water vapor, the furnace The oxygen concentration in 2 decreases as shown. Therefore, as the oxygen concentration setting value, a setting value V ₀ smaller than the atmospheric oxygen concentration Va by a predetermined amount is selected and the setting device 36 is set.

In the apparatus having the above-described configuration, the endothermic gas generator 1 is configured to supply the source gas from the source gas supply path 5 into the retort 3 and circulate through the retort 3 heated by the heater 4 to generate the endothermic gas. During operation, the retort damage detection device 30 is also continuously operated, and a portion (small amount) of atmospheric gas in the furnace body 2 is continuously sucked by the pump 33 to monitor the oxygen concentration (the measured oxygen concentration value V by the oxygen sensor 34). performed constantly compared) in the comparator 37 with the set value V ₀ and. In this state, when the damage to the retort 3 at T ₁ is generated, due to the reduced oxygen concentration as described above, at the time T ₂ measured value V of the oxygen concentration by the oxygen sensor 34 reaches the set value V ₀ below determination device 35 detects the retort damage issues a damage detection signal S _2, retort damage is informed by sounding of the alarm device 38.

  As described above, since the occurrence of damage to the retort 3 is detected when the oxygen concentration in the atmosphere in the furnace body 2 is equal to or lower than the set value, the generated gas and the raw material gas leaked from the retort 3 due to the damage are detected. At an early stage of oxygen concentration reduction due to oxidation of carbon monoxide, hydrocarbons and hydrogen, that is, at an early stage after the occurrence of retort damage, before the furnace body is filled to a high concentration and burned vigorously. The occurrence of damage can be detected.

  Next, an embodiment of the invention described in claim 3 will be described with reference to a third example shown in FIGS. The apparatus of this example uses a retort damage detection apparatus 40 whose measurement target is water concentration instead of the retort damage detection apparatus 20 whose measurement target is carbon dioxide concentration in the first example, and has other configurations. Since this is the same as the apparatus of the first example, the same parts as those in FIG. 1 are denoted by the same reference numerals as those in FIG. 1, and detailed description thereof will be omitted.

  That is, the retort damage detection device 40 is configured to measure a moisture concentration measuring device 41 that measures the moisture concentration in the furnace body 2 (dew point in this example), and when the measured value of the moisture concentration by the measuring device exceeds a set value. And a determination device 45 that determines that the retort 3 is damaged.

The moisture concentration measuring device 41 is configured by connecting a sampling tube 42 whose one end opens into the furnace body 2 to a dew point meter 44 that measures the moisture concentration via a gas suction pump 43. The determining device 45 includes a setter 46 for setting the set value W ₀ of the moisture concentration is compared with the water content measurement W and the set value W ₀ of the output of the dew-point meter 44, a water content measurement When the value becomes equal to or greater than the set value W ₀ , the comparator 47 outputs a damage detection signal S _{3. In} this example, the damage detection signal S ₃ is input to the alarm device 48.

Next, FIG. 6 is a diagram schematically showing a change in the moisture concentration (dew point) in the furnace body 2 when the retort 3 is damaged during operation of the endothermic gas generator 1. Although the water concentration in the body 2 shows a value substantially equal to the moisture concentration Wa of the surrounding atmosphere furnace, the retort damage at T ₁ is generated, leaking from the damaged portion into the furnace body 2 produced Hydrogen in the gas (endothermic gas) is oxidized in the high temperature furnace body to become water vapor, and the moisture concentration in the furnace body 2 increases as shown in the figure. Therefore, the setter 46 is set by selecting a set value W ₀ (a high dew point) that is a predetermined amount larger than the above-described atmospheric water concentration Wa as the set value of the moisture concentration.

In the apparatus having the above-described configuration, the endothermic gas generator 1 is configured to supply the source gas from the source gas supply path 5 into the retort 3 and circulate through the retort 3 heated by the heater 4 to generate the endothermic gas. During operation, the retort damage detector 40 is also continuously operated, and a portion (small amount) of the atmospheric gas in the furnace body 2 is continuously sucked by the pump 43 to monitor the moisture concentration (the measured moisture concentration value W by the dew point meter 44). performed constantly compared) in the comparator 47 with the set value W ₀ and. In this state, when the damage to the retort 3 at T ₁ is generated, because the water concentration as described above increases, when T ₂ measured value W of the water concentration by the dew point meter 44 reaches the set value W ₀ or more The determination device 45 detects the retort damage and issues a damage detection signal S _3, and the retort damage is notified by the sounding of the alarm device 48.

  As described above, since the occurrence of damage to the retort 3 is detected when the moisture concentration in the atmosphere in the furnace body 2 is equal to or higher than the set value, the generated gas and the raw material gas leaked from the retort 3 due to damage are Retort damage detection is detected at an early stage of water vapor generation due to oxidation of hydrogen in the product gas, that is, at an early stage after occurrence of retort damage, before the furnace body is filled with high concentration and violently burns. It can be done. The moisture concentration may be measured / determined as humidity instead of being measured / determined as a dew point.

  Next, the fourth embodiment shown in FIGS. 7 to 8 is used to explain an embodiment of the present invention. The apparatus of this example uses a retort damage detection device 50 whose measurement target is carbon monoxide concentration instead of the retort damage detection device 20 whose measurement target is carbon dioxide concentration in the first example. Since the configuration is the same as that of the apparatus of the first example, the same parts as those in FIG. 1 are denoted by the same reference numerals as those in FIG.

  That is, the retort damage detection device 50 is configured to measure the carbon monoxide concentration measuring device 51 that measures the carbon monoxide concentration in the furnace body 2 and when the measured value of the carbon monoxide concentration by the measuring device is equal to or greater than a set value. And a determination device 55 that determines that the retort 3 is damaged.

The carbon monoxide concentration measuring device 51 is formed by connecting a sampling pipe 52 whose one end opens into the furnace body 2 to a CO gas analyzer 54 that measures the carbon monoxide concentration via a gas suction pump 53. . The determination device 55, compared with a setter 56 for setting the setting value X ₀ of the concentration of carbon monoxide, the carbon monoxide concentration measurement value X and the set value X ₀ output by the above CO gas analyzer 54 to, when the concentration of carbon monoxide measured value is the set value X ₀ or more, consists of a comparator 57 which outputs a flaw detection signal S _4, damage detection signal S ₄ in this example is input to the alarm 58 The configuration is as follows.

Next, FIG. 8 is a diagram schematically showing a change in the concentration of carbon monoxide in the furnace body 2 when the retort 3 is damaged during the operation of the endothermic gas generator 1, and in FIG. 4 of the second example. It is the diagram which combined the change of oxygen concentration with the broken line. Carbon monoxide concentration in the furnace body 2 in the state without a retort damage is zero, but when retort damage occurs at time T _1, was first leaked to the second embodiment and the same furnace body 2 from the damaged portion The carbon monoxide in the product gas (endothermic gas) and the hydrocarbon in the raw material gas are oxidized to carbon dioxide, and the hydrogen in the product gas is also oxidized in the high temperature furnace to become water vapor. As the oxygen concentration in 2 decreases from the atmospheric oxygen concentration Va as shown in the figure, the concentration of unoxidized carbon monoxide increases as shown in the figure as the oxidation process proceeds. So as the setting value of carbon monoxide density, should make the settings of the setter 56 selects the set value X ₀ is close to the concentration zero.

In the apparatus having the above-described configuration, the endothermic gas generator 1 is configured to supply the source gas from the source gas supply path 5 into the retort 3 and circulate through the retort 3 heated by the heater 4 to generate the endothermic gas. During operation, the retort damage detection device 50 is also continuously operated, and a part (small amount) of the atmospheric gas in the furnace body 2 is continuously sucked by the pump 53 to monitor the carbon monoxide concentration (one by the CO gas analyzer 54). performing the comparison) in the comparator 57 with the carbon oxides concentration measurement value X and the set value X ₀ at all times. In this state, after injury to retort 3 at T ₁ is generated, because the concentration of carbon monoxide as described above is increased from zero, the measured value X is the set value X of the carbon monoxide concentration with CO gas analyzer 54 ₀ above and is time T ₂ in the determination apparatus 55 emits a damage detection signal S ₄ detects the retort damage, retort damage is informed by sounding of alarm 58.

As described above, since the occurrence of damage to the retort 3 is detected when the carbon monoxide concentration in the atmosphere in the furnace body 2 exceeds the set value, the generated gas leaked from the retort 3 due to damage Retort damage at an early stage of carbon monoxide increase in the furnace, that is, at an early stage after the occurrence of retort damage, before the carbon monoxide flows out of the furnace and burns violently. The occurrence can be detected. In addition, since carbon monoxide, which is the object of measurement and judgment in this example, does not exist in the furnace body without retort damage and in the atmosphere around the furnace body, based on the low concentration set value X ₀ close to zero. The occurrence of damage to the retort can be detected with high accuracy, and the occurrence of damage to the retort can be reliably detected.

The present invention is not limited to the above examples. For example, the specific configurations of the carbon dioxide concentration measuring device 21, the oxygen concentration measuring device 31, the moisture concentration measuring device 41, the carbon monoxide concentration measuring device 51, and the like are other than those described above. Similarly, the specific configurations of the determination devices 25, 35, 45, and 55 may be other than those described above. Further, the damage detection signals S ₁ , S ₂ , S ₃ , and S ₄ by the determination devices 25, 35, 45, and 55 are output to the alarm device in the above example, and are also output to an indicator lamp that displays OK / NG. The output to the control device of the endothermic gas generator is used as an original signal for controlling the operation of an on-off valve for emergency operation provided in the raw material gas supply path of the endothermic gas generator, for example. Good.

1 is an equipment system diagram of an endothermic gas generator showing a first example of an embodiment of the present invention. It is a schematic diagram which shows the change of the carbon dioxide gas concentration in the furnace body of the endothermic gas generator of FIG. FIG. 3 is a view corresponding to FIG. 1 and showing a second example of the embodiment of the present invention. It is a schematic diagram which shows the change of the oxygen concentration in the furnace body of the endothermic gas generator of FIG. FIG. 3 is a view corresponding to FIG. 1 and showing a third example of the embodiment of the present invention. FIG. 6 is a schematic diagram showing a change in moisture concentration in the furnace of the endothermic gas generator of FIG. 5. FIG. 6 is a view corresponding to FIG. 1 and showing a fourth example of the embodiment of the present invention. It is a schematic diagram which shows the change of the carbon monoxide density | concentration in the furnace body of the endothermic gas generator of FIG.

Explanation of symbols

  DESCRIPTION OF SYMBOLS 1 ... Endothermic gas generator, 2 ... Furnace body, 3 ... Retort, 4 ... Heater, 20 ... Retort damage detector, 21 ... Carbon dioxide gas concentration measuring device, 24 ... Carbon dioxide analyzer, 25 ... Judgment device, 30 ... Retort damage detection device, 31 ... oxygen concentration measurement device, 34 ... oxygen sensor, 35 ... determination device, 40 ... retort damage detection device, 41 ... moisture concentration measurement device, 44 ... dew point meter, 45 ... determination device, 50 ... retort damage Detection device, 51... Carbon monoxide concentration measurement device, 54... CO gas analyzer, 55.

Claims (4)

  In an endothermic gas generator having a retort and a heater in the furnace, a carbon dioxide concentration measuring device for measuring the carbon dioxide concentration in the atmosphere in the furnace, and a measured value of the carbon dioxide concentration by the carbon dioxide concentration measuring device are set. An endothermic gas generator comprising: a determination device that determines that the retort is damaged when the value exceeds the value.   In an endothermic gas generator having a furnace with a retort and a heater, the oxygen concentration measuring device for measuring the oxygen concentration in the atmosphere in the furnace and the measured value of the oxygen concentration by the oxygen concentration measuring device are below a set value. An endothermic gas generator comprising: a determination device that determines that the retort is damaged when the retort is damaged.   In an endothermic gas generator having a furnace with a retort and a heater, the moisture concentration measuring device for measuring the moisture concentration of the atmosphere in the furnace body, and the measured value of the moisture concentration by the moisture concentration measuring device exceed a set value. An endothermic gas generator comprising: a determination device that determines that the retort is damaged when the retort is damaged.   In an endothermic gas generator having a retort and a heater in the furnace, a carbon monoxide concentration measuring device for measuring the carbon monoxide concentration in the atmosphere in the furnace, and the carbon monoxide concentration measured by the carbon monoxide concentration measuring device. An endothermic gas generator, comprising: a determination device that determines that the retort is damaged when a measured value is equal to or greater than a set value.

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