JP2009149740A - Fuelization method for high moisture content organic waste and biomass fuel - Google Patents

Fuelization method for high moisture content organic waste and biomass fuel Download PDF

Info

Publication number
JP2009149740A
JP2009149740A JP2007327673A JP2007327673A JP2009149740A JP 2009149740 A JP2009149740 A JP 2009149740A JP 2007327673 A JP2007327673 A JP 2007327673A JP 2007327673 A JP2007327673 A JP 2007327673A JP 2009149740 A JP2009149740 A JP 2009149740A
Authority
JP
Japan
Prior art keywords
organic waste
water content
mass
less
drying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2007327673A
Other languages
Japanese (ja)
Other versions
JP5547371B2 (en
Inventor
Kanehiro Saito
兼広 斉藤
Yukio Oka
幸夫 岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Osaka Cement Co Ltd
Original Assignee
Sumitomo Osaka Cement Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Osaka Cement Co Ltd filed Critical Sumitomo Osaka Cement Co Ltd
Priority to JP2007327673A priority Critical patent/JP5547371B2/en
Publication of JP2009149740A publication Critical patent/JP2009149740A/en
Application granted granted Critical
Publication of JP5547371B2 publication Critical patent/JP5547371B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation

Abstract

<P>PROBLEM TO BE SOLVED: To provide a fuelization method for a high moisture content organic waste, by which chlorine and/or chlorine compounds included in a high moisture content organic waste containing livestock excrement and food waste can be effectively removed, the moisture content can be reduced and a decomposition rate of organic substances can be suppressed to not more than 20 mass%, and to provide a biomass fuel. <P>SOLUTION: The fuelization method for a high moisture content organic waste comprises: dehydrating a high moisture content organic waste by a dehydrating device 18 to obtain a dechlorinated organic waste; drying the dechlorinated organic waste with natural energy by a solar drying equipment 21A; and subsequently drying the waste with fermentation heat energy by a fermentation equipment 22A to obtain a dry dechlorinated organic waste having a chlorine concentration of not more than 3,000 ppm, a moisture content of not more than 35 mass%, and a decomposition rate of organic substances of not more than 20 mass%. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、高含水率有機廃棄物の燃料化方法及びバイオマス燃料に関し、更に詳しくは、豚糞、牛糞、鶏糞等の畜糞尿を含む家畜排泄物、あるいは百貨店、スーパーマーケット、コンビニエンスストア等にて廃棄される食品廃棄物等を含有し、しかも水分を多量に含む高含水率有機廃棄物に含まれる塩素および/または塩素化合物を効果的に除去するとともに、含水率を低減しかつ有機物の分解率を20質量%以下に抑制可能な高含水率有機廃棄物の燃料化方法、及び高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去するとともに、含水率を低減しかつ有機物の分解率を20質量%以下に抑制したバイオマス燃料に関するものである。   The present invention relates to a method for fuelizing high-moisture content organic waste and biomass fuel. More specifically, the present invention relates to livestock excreta containing livestock excrement such as pig excrement, cattle excrement and chicken excrement, or disposal at department stores, supermarkets, convenience stores, etc. It effectively removes chlorine and / or chlorine compounds contained in organic waste with a high water content that contains a large amount of water and contains a large amount of water, while reducing the water content and reducing the decomposition rate of organic matter. High moisture content organic waste fueling method that can be suppressed to 20% by mass or less, and chlorine and / or chlorine compounds contained in high moisture content organic waste, while reducing moisture content and organic matter decomposition rate It is related with the biomass fuel which suppressed 20 mass% or less.

従来、鶏糞、牛糞、豚糞等の畜糞尿を含む家畜排泄物、あるいは百貨店、スーパーマーケット、コンビニエンスストア、飲食店等にて廃棄される売れ残り弁当や各種残飯等の食品廃棄物は、そのままの状態もしくは発酵させた状態で肥料として利用するのが一般的であるが、焼却炉等を用いて焼却することで減容化し、得られた焼却灰を肥料として利用することもある。
特に、近年、家畜排泄物の管理に関する適正化法が施行されたことにもより、畜糞尿を含む家畜排泄物の多くが肥料化されることが予想される一方、農地の減少傾向により使用される肥料の総量も減少傾向にある。そこで、家畜排泄物や食品廃棄物等の有機廃棄物を有効利用するために、肥料以外の用途の多角化が急務になっており、エネルギーとしての利用もその一つである。
Conventionally, livestock excrement including livestock excrement such as chicken dung, cow dung, pig dung, etc., or food waste such as unsold lunch boxes and various leftover foods discarded at department stores, supermarkets, convenience stores, restaurants, etc. Although it is common to use it as a fertilizer in a fermented state, it may be reduced in volume by incineration using an incinerator or the like, and the incinerated ash obtained may be used as a fertilizer.
In particular, in recent years, due to the enforcement of the Optimization Act on the management of livestock excreta, most of the livestock excreta including livestock excreta are expected to be fertilized, but they are used due to the decreasing trend of farmland. The total amount of fertilizer is also decreasing. Therefore, diversification of uses other than fertilizer is urgently required to effectively use organic waste such as livestock excrement and food waste, and use as energy is one of them.

一般に、家畜排泄物は35質量%以下の低含水率状態では高位の発熱量を有するものであるが、低含水率状態とするためには、長時間の自然乾燥や化石燃料を用いた加熱乾燥を必要とするために、エネルギーとしての利用はごく一部では行われているものの総体的には進んでいない。
現在行われている家畜排泄物のエネルギー利用としては、鶏糞を発電や廃棄物ボイラーの燃料として用いたり、牛や豚の糞尿をメタン発酵させてメタンガスを主成分とするバイオガスを生成させ、このバイオガスを燃料として用いる等がある。
In general, livestock excrement has a high calorific value in a low moisture content state of 35% by mass or less, but in order to achieve a low moisture content state, natural drying for a long time or heat drying using fossil fuels. However, the use of energy as an energy source has been carried out to some extent but has not progressed overall.
Current energy use of livestock excreta includes the use of chicken manure as a fuel for power generation and waste boilers, and methane fermentation of cattle and swine manure to produce biogas consisting mainly of methane gas. For example, biogas is used as fuel.

このような家畜排泄物や食品廃棄物等の有機廃棄物を有効利用するための様々な方法や装置が提案されており、例えば、次のような提案がなされている。
(1)鶏糞、家畜糞等の含水廃棄処理物を、蒸気管と燃焼室を備えた熱風炉と多段式の乾燥炭化炉との間に発生蒸気の循環系統を配設して密閉系内で熱源を循環させながら炭化物及び灰化物を生成する方法(特許文献1)。
この方法では、乾燥炭化炉から炭化物を、熱風炉から灰化物を、それぞれ回収することで、二次利用可能な炭化物及び灰化物を同時に資源回収するとともに、省資源化と無公害化の推進を図っている。
(2)畜糞を乾燥させる乾燥機と、乾燥された畜糞を小粒と大粒に分離する分離機と、分離された小粒の乾燥畜糞を焼却処理する焼却炉と、乾燥未完了の畜糞を破砕して金属類の混入異物を露出するとともに、この混入異物を磁石を介して除去する磁石付振動式篩とを有する畜糞乾燥焼却装置(特許文献2)。
この装置では、畜糞原料に混入している石、金属などの金属類異物を簡単容易に撤去することで、金属類異物に起因する機械のトラブルを未然に回避するとともに、この畜糞を焼却処理することにより発生する熱を有効利用している。
特開2004−330092号公報 特開2005−156085号公報
Various methods and apparatuses for effectively using organic waste such as livestock excrement and food waste have been proposed. For example, the following proposals have been made.
(1) Dispose of hydrated waste products such as chicken manure and livestock manure in a closed system by arranging a circulation system of generated steam between a hot-blast furnace equipped with a steam pipe and a combustion chamber and a multistage drying carbonization furnace. A method of generating carbide and ash while circulating a heat source (Patent Document 1).
In this method, by collecting carbide from the dry carbonization furnace and ashing from the hot air furnace respectively, the resources and secondary utilizable carbides and ashing can be recovered at the same time, and resource saving and pollution-free promotion are promoted. I am trying.
(2) A drier for drying livestock excrement, a separator for separating dried livestock feces into small and large grains, an incinerator for incinerating the separated dry livestock feces, and crushing unfinished livestock feces A livestock dung drying and incineration apparatus having a magnetized vibrating sieve that exposes foreign matters mixed with metals through magnets (Patent Document 2).
In this device, metal foreign matters such as stones and metals mixed in livestock excrement materials can be easily removed to avoid machine troubles caused by metal foreign matters and to incinerate the livestock excrement. The heat generated by this is used effectively.
JP 2004-330092 A Japanese Patent Laid-Open No. 2005-156085

ところで、上述したように、家畜排泄物や食品廃棄物等の有機廃棄物を有効利用するための様々な方法や装置が提案されているが、これらの方法や装置においても、次のような問題点があった。
鶏糞をエネルギー源として利用しようとした場合、鶏糞のエネルギー利用を阻んでいる主たる点は、塩素含有量が高いという点である。鶏糞の塩素含有量が高いと、この塩素成分のために燃焼装置が腐食したり、あるいは低融点塩素化合物が発生して配管等の様々な箇所で閉塞等の様々なトラブルが発生する虞があるという問題点があった。
また、この鶏糞を、例えば、セメント焼成設備に燃料として投入した場合、それに含まれる塩素成分がセメントクリンカに混入してセメントの品質を低下させる虞がある。また、塩素成分がセメント焼成設備を腐食させる等のトラブルが発生する虞があるために、セメントの操業に悪影響を及ぼす虞がある。
By the way, as described above, various methods and apparatuses for effectively using organic waste such as livestock excrement and food waste have been proposed. However, these methods and apparatuses also have the following problems. There was a point.
When trying to use chicken manure as an energy source, the main point that hinders the energy use of chicken manure is the high chlorine content. If the chlorine content of chicken manure is high, the combustion component may corrode due to this chlorine component, or low melting point chlorine compounds may be generated, causing various troubles such as blockage in various places such as piping. There was a problem.
Moreover, when this chicken manure is thrown into a cement baking equipment as a fuel, for example, the chlorine component contained in it may mix in a cement clinker and may reduce the quality of cement. In addition, since the chlorine component may cause troubles such as corrosion of the cement firing facility, there is a possibility that the cement operation may be adversely affected.

また、牛や豚の糞尿がエネルギー利用され難いのは、鶏糞と同様に塩素含有量が高いことと、含水率が80%前後と高いために、燃料として用いた場合、燃焼時に発生する熱エネルギーが糞尿に含まれる水分の蒸発潜熱に奪われてしまい、燃料としてのエネルギーの有効利用を図ることが難しいからである。
このように、様々な理由から、家畜排泄物や食品廃棄物等を含む有機廃棄物のエネルギー源としての有効利用ははかばかしくないのが現状である。
Also, it is difficult to use energy from cattle and swine manure because of the high chlorine content and high water content of around 80%, similar to chicken manure, the thermal energy generated during combustion when used as fuel. This is because it is deprived of the latent heat of vaporization of water contained in manure and it is difficult to effectively use energy as fuel.
Thus, for various reasons, the effective use of organic waste including livestock excrement and food waste as an energy source is not ridiculous.

本発明は、上記の課題を解決するためになされたものであって、豚糞、牛糞、鶏糞等の畜糞尿を含む家畜排泄物、売れ残り弁当や各種残飯等の食品廃棄物等を含有し、しかも水分を多量に含む高含水率有機廃棄物に含まれる塩素および/または塩素化合物を効果的に除去するとともに、含水率を低減しかつ有機物の分解率を20質量%以下に抑制することができる高含水率有機廃棄物の燃料化方法、及び高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去するとともに、含水率を低減しかつ有機物の分解率を20質量%以下に抑制したバイオマス燃料を提供することを目的とする。   The present invention was made in order to solve the above-mentioned problem, and contains livestock excreta including livestock excrement such as pig excrement, cattle excrement, and chicken excrement, food waste such as unsold lunches and various leftover foods, etc. In addition, chlorine and / or chlorine compounds contained in high water content organic waste containing a large amount of water can be effectively removed, the water content can be reduced, and the decomposition rate of organic substances can be suppressed to 20% by mass or less. A method for converting high water content organic waste into fuel, and removing chlorine and / or chlorine compounds contained in high water content organic waste, reducing the water content, and suppressing the organic matter decomposition rate to 20% by mass or less. The purpose is to provide biomass fuel.

本発明者等は、上記課題を解決するために鋭意研究を重ねた結果、家畜排泄物、食品廃棄物のいずれか一方または双方を含有する高含水率有機廃棄物に脱水処理を施せば、この高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去して塩素濃度が3000ppm以下と極めて低い脱塩素有機廃棄物を得ることができ、さらに、この脱塩素有機廃棄物に、自然エネルギー、発酵熱エネルギーのいずれか一方による乾燥または加熱乾燥、及び前記自然エネルギー、前記発酵熱エネルギーのいずれか他方による乾燥または加熱乾燥、を順次施せば、塩素濃度が3000ppm以下、含水率が35質量%以下、有機物の分解率が20質量%以下の乾燥脱塩素有機廃棄物を得ることができ、バイオマス燃料等のエネルギー源として、さらにはセメント焼成設備のバイオマス燃料として有効利用することができ、しかもセメント焼成設備の操業やセメント品質に悪影響を及ぼす虞が無いことを見出し、本発明を完成するに至った。   As a result of intensive studies to solve the above problems, the present inventors have conducted a dehydration treatment on a high water content organic waste containing either or both of livestock excrement and food waste. Chlorine and / or chlorine compounds contained in organic waste with a high water content can be removed to obtain a dechlorinated organic waste with a very low chlorine concentration of 3000 ppm or less. When the drying or heating drying by either one of the fermentation heat energy and the natural energy or the drying or heating drying by the other of the fermentation heat energy are sequentially performed, the chlorine concentration is 3000 ppm or less and the water content is 35% by mass. In the following, dry dechlorinated organic waste with an organic matter decomposition rate of 20% by mass or less can be obtained. It can be effectively used as a biomass fuel of the cement burning facility, yet found that there is no possibility of adversely affecting the operation and cement quality of the cement burning facility, which resulted in the completion of the present invention.

すなわち、本発明の高含水率有機廃棄物の燃料化方法は、家畜排泄物、食品廃棄物のいずれか一方または双方を含有する高含水率有機廃棄物を燃料化するための方法であって、前記高含水率有機廃棄物に脱水処理を施すことにより、この高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去して脱塩素有機廃棄物とし、次いで、この脱塩素有機廃棄物に、自然エネルギー、発酵熱エネルギーのいずれか一方による乾燥または加熱乾燥、及び前記自然エネルギー、前記発酵熱エネルギーのいずれか他方による乾燥または加熱乾燥、を順次施すことにより、塩素濃度が3000ppm以下、含水率が35質量%以下、有機物の分解率が20質量%以下の乾燥脱塩素有機廃棄物とすることを特徴とする。   That is, the method for fuelizing a high water content organic waste of the present invention is a method for fuelizing a high water content organic waste containing either one or both of livestock excrement and food waste, By dehydrating the high water content organic waste, chlorine and / or chlorine compounds contained in the high water content organic waste are removed to form dechlorinated organic waste, and then this dechlorinated organic waste In addition, a chlorine concentration of 3000 ppm or less is obtained by sequentially applying drying or heating drying with either one of natural energy or fermentation heat energy, and drying or heating drying with either the natural energy or the fermentation heat energy. A dry dechlorinated organic waste having a rate of 35% by mass or less and an organic decomposition rate of 20% by mass or less is characterized.

この高含水率有機廃棄物の燃料化方法では、高含水率有機廃棄物に脱水処理を施すことにより、この高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去して塩素濃度が3000ppm以下の脱塩素有機廃棄物とする。
次いで、この脱塩素有機廃棄物に、自然エネルギー、発酵熱エネルギーのいずれか一方による乾燥または加熱乾燥、及び前記自然エネルギー、前記発酵熱エネルギーのいずれか他方による乾燥または加熱乾燥、を順次施すことにより、この脱塩素有機廃棄物に加わる自然エネルギー及び発酵熱エネルギーの双方のエネルギー量を調整して含水率を35質量%以下に調整するとともに、この脱塩素有機廃棄物に含まれる有機物の分解率を20質量%以下に抑え、バイオマス燃料としての十分な発熱量を確保する。
In this high water content organic waste fuel conversion method, the high water content organic waste is dehydrated to remove chlorine and / or chlorine compounds contained in the high water content organic waste, thereby reducing the chlorine concentration. Use dechlorinated organic waste of 3000 ppm or less.
Next, the dechlorinated organic waste is sequentially subjected to drying or heating drying by either one of natural energy or fermentation heat energy, and drying or heating drying by any one of the natural energy or fermentation heat energy. In addition to adjusting the amount of both natural energy and fermentation heat energy added to the dechlorinated organic waste, the water content is adjusted to 35% by mass or less, and the decomposition rate of the organic matter contained in the dechlorinated organic waste is adjusted. Suppressed to 20% by mass or less to secure a sufficient calorific value as biomass fuel.

このように、自然エネルギー及び発酵熱エネルギーの双方のエネルギー量を調整することにより、塩素濃度が3000ppm以下、含水率が35質量%以下、有機物の分解率が20質量%以下の乾燥脱塩素有機廃棄物を得ることが可能になる。
このようにして得られた乾燥脱塩素有機廃棄物は、塩素濃度及び含水率が極めて低くかつ高位の発熱量を有しており、燃焼効率が高いバイオマス燃料として有効利用することが可能である。
また、この乾燥脱塩素有機廃棄物をセメント焼成設備に燃料として投入した場合においても、セメントの操業や品質に悪影響を及ぼす虞が無い。
In this way, by adjusting the energy amounts of both natural energy and fermentation heat energy, dry dechlorinated organic waste having a chlorine concentration of 3000 ppm or less, a water content of 35% by mass or less, and an organic matter decomposition rate of 20% by mass or less. You can get things.
The dry dechlorinated organic waste thus obtained has an extremely low chlorine concentration and water content and a high calorific value, and can be effectively used as a biomass fuel with high combustion efficiency.
Further, even when this dry dechlorinated organic waste is introduced as fuel into a cement firing facility, there is no possibility of adversely affecting cement operation and quality.

前記高含水率有機廃棄物の含水率は60質量%以上であることが好ましい。
この高含水率有機廃棄物の含水率を60質量%以上とすることにより、高含水率有機廃棄物に含まれる塩素および/または塩素化合物が水に溶解することで効果的に除去され、よって、塩素濃度が3000ppm以下と極めて低い脱塩素有機廃棄物を容易かつ安価に得ることが可能になる。
The water content of the high water content organic waste is preferably 60% by mass or more.
By setting the water content of the high water content organic waste to 60% by mass or more, chlorine and / or chlorine compounds contained in the high water content organic waste are effectively removed by dissolving in water. It becomes possible to easily and inexpensively obtain dechlorinated organic waste having a chlorine concentration of 3000 ppm or less.

前記乾燥脱塩素有機廃棄物に、分級、粉砕、解砕のいずれか1つまたは2つ以上を行うことが好ましい。
乾燥脱塩素有機廃棄物は、乾燥処理の後では、通常、球状、塊状(ブロック状)、板状等、比較的大きな形状を有している。そこで、乾燥処理した乾燥脱塩素有機廃棄物に対して、分級、粉砕、解砕のいずれか1つまたは2つ以上を行うことにより、燃焼効率の高い所望の形状の粉粒体とすることが可能になる。
The dry dechlorinated organic waste is preferably subjected to any one or more of classification, pulverization, and pulverization.
The dried dechlorinated organic waste usually has a relatively large shape such as a spherical shape, a block shape (block shape), or a plate shape after the drying treatment. Therefore, by carrying out any one or more of classification, pulverization, and pulverization on the dried and dechlorinated organic waste that has been dried, it is possible to obtain a granular material having a desired shape with high combustion efficiency. It becomes possible.

本発明のバイオマス燃料は、家畜排泄物、食品廃棄物のいずれか一方または双方を含有する高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去し、乾燥または加熱乾燥してなるバイオマス燃料であって、
塩素濃度が3000ppm以下、含水率が35質量%以下かつ有機物の分解率が20質量%以下であることを特徴とする。
Biomass fuel of the present invention is a biomass obtained by removing chlorine and / or chlorine compounds contained in a high water content organic waste containing either or both of livestock excrement and food waste, and drying or heat drying the biomass. Fuel,
The chlorine concentration is 3000 ppm or less, the moisture content is 35 mass% or less, and the decomposition rate of organic substances is 20 mass% or less.

このバイオマス燃料では、塩素濃度を3000ppm以下かつ含水率を35質量%以下としたことにより、燃料として用いた場合においても、燃焼時に発生する熱エネルギーがバイオマス燃料に含まれる水分の蒸発潜熱に奪われてしまう虞が無くなり、燃料としてのエネルギーの有効利用を図ることが可能になる。
また、有機物の分解率を20質量%以下としたことにより、バイオマス燃料としての十分な発熱量が確保される。
また、塩素濃度が3000ppm以下と極めて低いので、燃焼装置等においても腐食や配管等の閉塞等のトラブルが発生する虞がなく、また、セメント焼成設備に投入した場合においても、セメントの操業や品質に悪影響を及ぼす虞が無い。
In this biomass fuel, the chlorine concentration is set to 3000 ppm or less and the moisture content is set to 35 mass% or less, so that even when used as fuel, the thermal energy generated during combustion is lost to the latent heat of evaporation of moisture contained in the biomass fuel. This eliminates the risk that the energy will be lost and makes it possible to effectively use the energy as fuel.
Moreover, sufficient calorific value as biomass fuel is ensured by setting the decomposition rate of organic matter to 20 mass% or less.
In addition, since the chlorine concentration is as low as 3000 ppm or less, there is no risk of problems such as corrosion or blockage of pipes in the combustion equipment, etc., and even when it is put into cement firing equipment, the operation and quality of the cement There is no risk of adverse effects.

本発明の高含水率有機廃棄物の燃料化方法によれば、高含水率有機廃棄物に脱水処理を施すことにより、この高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去して脱塩素有機廃棄物とし、次いで、この脱塩素有機廃棄物に、自然エネルギー、発酵熱エネルギーのいずれか一方による乾燥または加熱乾燥、及び前記自然エネルギー、前記発酵熱エネルギーのいずれか他方による乾燥または加熱乾燥、を順次施すことにより、塩素濃度が3000ppm以下、含水率が35質量%以下、有機物の分解率が20質量%以下の乾燥脱塩素有機廃棄物とするので、塩素濃度及び含水率が極めて低くかつ高位の発熱量を有する乾燥脱塩素有機廃棄物を得ることができる。したがって、燃焼効率が高いバイオマス燃料を提供することができる。
また、乾燥または加熱乾燥に、太陽熱等の自然エネルギーや有機廃棄物の発酵熱エネルギーを用い、化石燃料を用いないので、省エネルギー効果が大きく、しかも環境負荷が小さい。
また、この乾燥脱塩素有機廃棄物をセメント焼成設備に燃料として投入した場合においても、セメントの操業や品質への悪影響を防止することができる。
According to the high water content organic waste fueling method of the present invention, the high water content organic waste is dehydrated to remove chlorine and / or chlorine compounds contained in the high water content organic waste. The dechlorinated organic waste is then dried or heat-dried by any one of natural energy and fermentation heat energy, and dried by any one of the natural energy and fermentation heat energy. By sequentially performing heating and drying, the chlorine concentration and moisture content are extremely low because the chlorine concentration is 3000 ppm or less, the moisture content is 35% by mass or less, and the organic material decomposition rate is 20% by mass or less. Dry dechlorinated organic waste having a low and high calorific value can be obtained. Therefore, biomass fuel with high combustion efficiency can be provided.
Moreover, since natural energy such as solar heat or fermentation heat energy of organic waste is used for drying or heating and drying, and fossil fuel is not used, the energy saving effect is large and the environmental load is small.
Moreover, even when this dry dechlorinated organic waste is introduced as fuel into a cement firing facility, adverse effects on cement operation and quality can be prevented.

本発明のバイオマス燃料によれば、塩素濃度を3000ppm以下、含水率を35質量%以下かつ有機物の分解率を20質量%以下としたので、燃焼効率が高く、省エネルギー効果が大きく、しかも環境負荷が小さいバイオマス燃料を提供することができる。
また、このバイオマス燃料を燃焼する燃焼装置等においても腐食や配管等の閉塞等のトラブルを防止することができ、このバイオマス燃料をセメント焼成設備に投入した場合においても、燃焼効率が低下する虞がなく、セメントの操業や品質に悪影響を及ぼす虞も無い。
According to the biomass fuel of the present invention, the chlorine concentration is 3000 ppm or less, the moisture content is 35% by mass or less, and the organic matter decomposition rate is 20% by mass or less. Therefore, the combustion efficiency is high, the energy saving effect is great, and the environmental load is high. A small biomass fuel can be provided.
In addition, troubles such as corrosion and blockage of pipes can be prevented even in a combustion apparatus or the like that burns this biomass fuel, and even when this biomass fuel is put into a cement firing facility, the combustion efficiency may be reduced. And there is no risk of adverse effects on cement operation and quality.

本発明の高含水率有機廃棄物の燃料化方法及びバイオマス燃料の最良の形態について、図面に基づき説明する。
なお、本実施形態は、発明の趣旨をより良く理解させるために具体的に説明するものであり、特に指定のない限り、本発明を限定するものではない。
BEST MODE FOR CARRYING OUT THE INVENTION The best mode of the present invention for fueling a high water content organic waste and biomass fuel will be described with reference to the drawings.
The present embodiment is specifically described for better understanding of the gist of the invention, and does not limit the invention unless otherwise specified.

「高含水率有機廃棄物の燃料化設備」
図1は、本発明の一実施形態の高含水率有機廃棄物の燃料化方法に用いられる燃料化設備を示す模式図である。
図において、1は高含水率有機廃棄物を排出する排出源、2は高含水率有機廃棄物の脱塩設備、3は燃料化設備である。
"Fueling equipment for organic waste with high water content"
FIG. 1 is a schematic diagram showing a fueling facility used in a method for fuelizing a high water content organic waste according to an embodiment of the present invention.
In the figure, 1 is a discharge source for discharging high water content organic waste, 2 is a desalination facility for high water content organic waste, and 3 is a fueling facility.

ここで、高含水率有機廃棄物とは、含水率が60質量%以上、より好ましくは70質量%以上、さらに好ましくは80質量%以上の有機廃棄物のことであり、例えば、豚舎、牛舎、鶏舎等の畜舎を水洗により洗浄した際に排出される豚糞尿、牛糞尿、鶏糞尿等の畜糞尿と多量の洗浄水とを含む排泄物含有処理水、豚糞尿、牛糞尿、鶏糞尿等の畜糞尿を等量以上かつ20倍量以下の水に投入・撹拌して得られる畜糞尿含有スラリー、使用済みの弁当容器や食品用容器を水洗により洗浄する際に排出される食品と多量の水とを含む食品廃棄物含有処理水、等が挙げられる。これらは、その用途や必要に応じて、1種のみ、または2種以上を混合して用いることができる。   Here, the high water content organic waste is an organic waste having a water content of 60% by mass or more, more preferably 70% by mass or more, and further preferably 80% by mass or more. Such as swine manure, cow manure, chicken manure, etc., excreta containing treated water, swine manure, cow manure, chicken manure, etc. Slurry containing livestock manure obtained by pouring and stirring livestock manure into equal to or greater than 20 times the amount of water, and food and large amounts of water discharged when washing used lunch containers and food containers by washing Food waste-containing treated water, and the like. These can be used singly or in combination of two or more as required.

排出源1は、上記の高含水率有機廃棄物を排出する源であり、例えば、豚の糞や尿を含む排泄物を水洗により洗浄した排泄物含有処理水を排出する豚舎、牛の糞や尿を含む排泄物を水洗により洗浄した排泄物含有処理水を排出する牛舎、鶏のケージ等を水洗により洗浄した排泄物含有処理水を排出する鶏舎等の畜舎、豚糞尿、牛糞尿、鶏糞尿等の畜糞尿を等量以上かつ20倍量以下の水に投入・撹拌して得られる畜糞尿含有スラリーの貯留槽、百貨店、スーパーマーケット、コンビニエンスストア等にて廃棄される食品廃棄物やその容器等を水洗により洗浄した食品廃棄物含有処理水を排出する食品廃棄処理施設等が挙げられる。
これらの各施設から排出される高含水率有機廃棄物は、その用途によっては、2種類以上を混合してもよい。
The discharge source 1 is a source that discharges the above-mentioned high water content organic waste. For example, a pig house that discharges excrement-containing treated water obtained by washing excrement including swine dung and urine with water, cow dung, Cattle barn that discharges excrement-containing treated water that has been washed by washing urine-containing excrement, livestock barn that discharges excrement-containing treated water that has been washed by washing chicken cages, etc., pig manure, cow manure, chicken manure A waste tank of animal manure containing slurry obtained by adding and agitation of animal excreta such as etc. into water of equal to or greater than 20 times the volume, food waste discarded in containers, department stores, supermarkets, convenience stores, etc. And food waste treatment facilities that discharge processed water containing food waste that has been washed with water.
Two or more types of high water content organic waste discharged from each facility may be mixed depending on the application.

脱塩設備2は、排出源1から排出される高含水率有機廃棄物を塩素濃度が3000ppm以下になるように脱塩処理するための設備であり、高含水率有機廃棄物を貯留する1次槽11と、この高含水率有機廃棄物を固液分離するスクリーン等からなる1次固液分離器12と、固液分離により生じた1次スラリー(水溶液)を貯留し流量を調整する調整槽13と、この1次スラリーを1次曝気処理する1次曝気槽14と、1次曝気処理されたスラリーを固液分離するスクリーン等からなる2次固液分離器15と、この固液分離により生じた2次スラリー(水溶液)を2次曝気処理する2次曝気槽16と、この2次曝気処理されたスラリーを膜浸漬処理により汚泥と処理水とに分離する膜浸漬槽17と、この汚泥を脱水処理して含水率が85質量%以下の脱塩素有機廃棄物と処理水とに分離する脱水処理装置18と、膜浸漬槽17及び脱水処理装置18から排出される処理水を一旦貯留し放流する処理水受槽19とにより構成されている。   The desalination facility 2 is a facility for desalinating the high water content organic waste discharged from the discharge source 1 so that the chlorine concentration is 3000 ppm or less, and stores the high water content organic waste. A tank 11, a primary solid-liquid separator 12 comprising a screen or the like for solid-liquid separation of this high water content organic waste, and an adjustment tank for storing a primary slurry (aqueous solution) generated by solid-liquid separation and adjusting the flow rate 13, a primary aeration tank 14 for subjecting the primary slurry to primary aeration, a secondary solid-liquid separator 15 comprising a screen or the like for solid-liquid separation of the slurry subjected to primary aeration treatment, and the solid-liquid separation. A secondary aeration tank 16 for secondary aeration treatment of the generated secondary slurry (aqueous solution), a membrane immersion tank 17 for separating the slurry subjected to the secondary aeration treatment into sludge and treated water by membrane immersion treatment, and the sludge Water content is 85 mass The dehydration treatment device 18 that separates into the following dechlorinated organic waste and treated water, and the treated water receiving tank 19 that temporarily stores and discharges the treated water discharged from the membrane immersion tank 17 and the dewatering treatment apparatus 18 are configured. Yes.

燃料化設備3は、脱塩設備2から送り出される塩素濃度が3000ppm以下の脱塩素有機廃棄物を燃料化するための設備であり、自然エネルギーを用いて乾燥または加熱乾燥する天日乾燥設備21A、21Bと、有機廃棄物の発酵過程にて発生する発酵熱を用いて乾燥または加熱乾燥を施す発酵設備22A、22Bと、発酵設備22Aあるいは天日乾燥設備21Bから取り出された固形状の乾燥脱塩素有機廃棄物に対して、分級、粉砕、解砕のいずれか1つまたは2つ以上を行うことにより直径10mm以下の粒子状とする分級機能を有する粉砕機23と、発酵設備22A、天日乾燥設備21B及び粉砕機23のうち1種以上の装置から排出される乾燥脱塩素有機廃棄物を仕様別や品種別に選別し保管する保管庫24とにより構成されている。   The fueling facility 3 is a facility for converting the dechlorinated organic waste having a chlorine concentration of 3000 ppm or less sent from the desalting facility 2 into fuel, and a sun drying facility 21A for drying or heat drying using natural energy. 21B, fermentation equipment 22A, 22B for drying or heat drying using fermentation heat generated in the fermentation process of organic waste, and solid dry dechlorination taken out from fermentation equipment 22A or sun drying equipment 21B A pulverizer 23 having a function of classifying particles with a diameter of 10 mm or less by performing any one or more of classification, pulverization, and pulverization on organic waste, fermentation equipment 22A, and sun drying It comprises a storage 24 for sorting and storing dry dechlorinated organic waste discharged from one or more of the equipment 21B and the pulverizer 23 according to specifications and varieties. .

この天日乾燥設備21Aと発酵設備22Aは、天日乾燥設備21A側が前段(前工程)となるように直列に配置され、一方、発酵設備22Bと天日乾燥設備21Bは、発酵設備22B側が前段(前工程)となるように直列に配置されている。
ここで、自然エネルギーを用いた乾燥とは、風力による乾燥等であり、また、自然エネルギーを用いた加熱乾燥とは、太陽熱による加熱乾燥、太陽熱及び風力を併用した加熱乾燥等である。
The sun drying equipment 21A and the fermenting equipment 22A are arranged in series so that the sun drying equipment 21A side is the previous stage (previous process), while the fermentation equipment 22B and the sun drying equipment 21B are the front stage of the fermentation equipment 22B. It arrange | positions in series so that it may become (pre-process).
Here, the drying using natural energy is drying by wind power or the like, and the heating drying using natural energy is heating drying by solar heat, heating drying using solar heat and wind power or the like.

天日乾燥設備21A、21Bは、脱塩素有機廃棄物の種類や量に応じて太陽熱単独、あるいは太陽熱及び自然の風力を用いて天日乾燥を行う設備であり、太陽熱及び風力を用いた天日乾燥器等が好適に用いられる。
発酵設備22A、22Bは、脱塩素有機廃棄物を発酵させる際に生じる発酵熱を用いて、この脱塩素有機廃棄物を乾燥または加熱乾燥させる設備であり、例えば、縦型密閉式発酵槽、横型開放式発酵槽、横型開放式堆肥舎等が好適に用いられる。
粉砕機23としては、分級機能を備えた自動乳鉢、スタンパ、ニーダー、ロールミル等が好適に用いられる。
The sun drying facilities 21A and 21B are facilities for performing sun drying using solar heat alone or solar heat and natural wind depending on the type and amount of dechlorinated organic waste. A dryer or the like is preferably used.
Fermentation equipment 22A, 22B is equipment which dries or heat-drys this dechlorination organic waste using fermentation heat generated when fermenting dechlorination organic waste, for example, a vertical closed type fermenter, a horizontal type An open-type fermenter, a horizontal open-type compost house, etc. are preferably used.
As the pulverizer 23, an automatic mortar, a stamper, a kneader, a roll mill or the like having a classification function is preferably used.

「高含水率有機廃棄物の燃料化方法」
本発明の高含水率有機廃棄物の燃料化方法は、図1に示す高含水率有機廃棄物の燃料化設備を用いて、家畜排泄物、食品廃棄物のいずれか一方または双方を含有する高含水率有機廃棄物を燃料化するための方法であり、この高含水率有機廃棄物に脱水処理を施すことにより、この高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去して脱塩素有機廃棄物とし、次いで、この脱塩素有機廃棄物に、自然エネルギー、発酵熱エネルギーのいずれか一方による乾燥または加熱乾燥、及び自然エネルギー、発酵熱エネルギーのいずれか他方による乾燥または加熱乾燥、を順次施すことにより、塩素濃度が3000ppm以下、含水率が35質量%以下、有機物の分解率が20質量%以下の乾燥脱塩素有機廃棄物とする方法である。
"Fueling method for organic waste with high water content"
The high water content organic waste fueling method of the present invention uses a high water content organic waste fueling facility shown in FIG. 1 and contains either or both of livestock excrement and food waste. This is a method for fueling organic waste with a high water content. By dehydrating this high water content organic waste, chlorine and / or chlorine compounds contained in this high water content organic waste are removed. It is dechlorinated organic waste, and then this dechlorinated organic waste is dried or heat-dried by either natural energy or fermentation heat energy, and dried or heat-dried by either natural energy or fermentation heat energy, In order to obtain a dry dechlorinated organic waste having a chlorine concentration of 3000 ppm or less, a moisture content of 35% by mass or less, and an organic matter decomposition rate of 20% by mass or less.

この高含水率有機廃棄物の燃料化方法について図1に基づき詳細に説明する。
排出源1から排出される上述した排泄物含有処理水、食品廃棄物含有処理水等の高含水率有機廃棄物を脱塩設備2の1次槽11に一旦貯留し、送液ポンプ(図示略)等を用いて1次固液分離器12に投入し、この高含水率有機廃棄物をケーキ(固形分)と1次スラリー(水溶液)に固液分離する。次いで、この固液分離により生じた1次スラリーを調整槽13に投入して貯留し、この1次スラリーを調整槽13の計量槽等の定量供給装置を介して1次曝気槽14に導入し、この1次スラリーに1次曝気処理を施す。
A method for converting this high water content organic waste into fuel will be described in detail with reference to FIG.
The high water content organic wastes such as the above-described excrement-containing treated water and food waste-containing treated water discharged from the discharge source 1 are temporarily stored in the primary tank 11 of the desalination facility 2, and a liquid feed pump (not shown) ) And the like to the primary solid-liquid separator 12, and this high water content organic waste is solid-liquid separated into a cake (solid content) and a primary slurry (aqueous solution). Next, the primary slurry generated by the solid-liquid separation is charged into the adjustment tank 13 and stored, and the primary slurry is introduced into the primary aeration tank 14 via a quantitative supply device such as a measurement tank of the adjustment tank 13. The primary slurry is subjected to a primary aeration process.

次いで、この1次曝気処理が施されたスラリーを、送液ポンプ(図示略)等を用いて2次固液分離器15に投入し、このスラリーをケーキ(固形分)と2次スラリー(水溶液)に分離し、この固液分離により生じた2次スラリーを2次曝気槽16に投入し、2次曝気処理を施す。次いで、この2次曝気処理されたスラリーを膜浸漬槽17に投入して膜浸漬処理を施し、汚泥と処理水とに分離する。次いで、この汚泥を脱水処理装置18に導入し、脱水処理を施す。   Next, the slurry that has been subjected to the primary aeration treatment is put into the secondary solid-liquid separator 15 using a liquid feed pump (not shown) or the like, and this slurry is added to the cake (solid content) and the secondary slurry (aqueous solution). The secondary slurry produced by the solid-liquid separation is put into the secondary aeration tank 16 and subjected to secondary aeration treatment. Next, the slurry subjected to the secondary aeration treatment is put into the membrane immersion tank 17 and subjected to the membrane immersion treatment, and separated into sludge and treated water. Next, the sludge is introduced into the dehydration apparatus 18 and subjected to a dehydration process.

これにより、高含水率有機廃棄物は、2段階の固液分離により効果的に脱塩処理が施され、塩素濃度が3000ppm以下、好ましくは2000ppm以下であり、かつ含水率が90質量%以下、好ましくは80質量%以下のケーキ状の脱塩素有機廃棄物となる。
この膜浸漬槽17及び脱水処理装置18から排出される処理水は、処理水受槽19に一旦貯留された後、放流される。
Thereby, the high water content organic waste is effectively desalted by two-stage solid-liquid separation, the chlorine concentration is 3000 ppm or less, preferably 2000 ppm or less, and the water content is 90% by mass or less. Preferably, it becomes a cake-like dechlorinated organic waste of 80% by mass or less.
The treated water discharged from the membrane immersion tank 17 and the dehydration processing apparatus 18 is temporarily stored in the treated water receiving tank 19 and then discharged.

一方、1次固液分離器12及び2次固液分離器15各々から取り出されたケーキは、さらに塩素濃度の低い脱水汚泥と混合して用いることができる。
また、塩素濃度が3000ppmを超えるものについては、再度、別途据え付けられた脱塩設備等を用いて脱塩処理を施した上で、上記のケーキ状の脱塩素有機廃棄物と混合して用いることができる。
On the other hand, the cake taken out from each of the primary solid-liquid separator 12 and the secondary solid-liquid separator 15 can be used by mixing with dehydrated sludge having a lower chlorine concentration.
For those with a chlorine concentration exceeding 3000 ppm, use a desalination facility that has been installed separately, and then mix with the above cake-like dechlorinated organic waste. Can do.

次いで、この脱塩素有機廃棄物を燃料化設備3に搬送し、燃料化する。
この脱塩素有機廃棄物を燃料化する方法としては、次の(1)、(2)のいずれかの方法がある。
(1)脱塩素有機廃棄物を天日乾燥設備21Aに搬入し、太陽熱や風力等の自然エネルギーを用いて乾燥または加熱乾燥し、得られた脱塩素有機廃棄物の乾燥物を発酵設備22Aに搬入し、この乾燥物の発酵過程にて発生する発酵熱を用いて乾燥または加熱乾燥し、乾燥脱塩素有機廃棄物とする。
(2)脱塩素有機廃棄物を発酵設備22Bに搬入し、この脱塩素有機廃棄物の発酵過程にて発生する発酵熱を用いて乾燥または加熱乾燥し、得られた脱塩素有機廃棄物の乾燥物を天日乾燥設備21Bに搬入し、太陽熱や風力等の自然エネルギーを用いて乾燥または加熱乾燥し、乾燥脱塩素有機廃棄物とする。
Next, the dechlorinated organic waste is transported to the fueling facility 3 and converted into fuel.
As a method of converting this dechlorinated organic waste into fuel, there is one of the following methods (1) and (2).
(1) Bring dechlorinated organic waste into solar drying equipment 21A, dry or heat dry using natural energy such as solar heat or wind power, and dry the resulting dechlorinated organic waste into fermentation equipment 22A It is carried in and dried or heat-dried using the heat of fermentation generated in the fermentation process of the dried product to obtain dried dechlorinated organic waste.
(2) Bring the dechlorinated organic waste into the fermentation facility 22B, and dry or heat dry using the fermentation heat generated in the fermentation process of the dechlorinated organic waste, and dry the resulting dechlorinated organic waste A thing is carried in to the sun drying equipment 21B, and dried or heat-dried using natural energy such as solar heat or wind power to obtain a dechlorinated organic waste.

この脱塩素有機廃棄物は、通常、4000〜4500kcal/kg程度の発熱量を有しているので、加熱乾燥工程で脱塩素有機廃棄物に含まれる有機物の分解率が20質量%を超えると、これに対応して発熱量が20質量%以上低下し、燃料としての価値を著しく損なうこととなる。
また、この脱塩素有機廃棄物を発酵熱のみで乾燥または加熱乾燥した場合においても、脱塩素有機廃棄物に含まれる有機物の分解率が20質量%を超えることとなり、同様に燃料としての価値を著しく損なうこととなる。
一方、脱塩素有機廃棄物を太陽熱や風力等の自然エネルギーのみで乾燥または加熱乾燥した場合、冬季や寒冷地での乾燥が困難である。
Since this dechlorinated organic waste usually has a calorific value of about 4000 to 4500 kcal / kg, when the decomposition rate of the organic matter contained in the dechlorinated organic waste exceeds 20% by mass in the heat drying step, Correspondingly, the calorific value is reduced by 20% by mass or more, and the value as a fuel is significantly impaired.
In addition, even when this dechlorinated organic waste is dried or heat-dried only with fermentation heat, the decomposition rate of the organic matter contained in the dechlorinated organic waste exceeds 20% by mass, and similarly has value as a fuel. It will be seriously damaged.
On the other hand, when dechlorinated organic waste is dried or heat-dried only by natural energy such as solar heat or wind power, it is difficult to dry it in winter or cold regions.

上記の(1)、(2)の方法では、太陽熱や風力等の自然エネルギーと、脱塩素有機廃棄物の発酵過程にて発生する発酵熱の双方を併用し、さらに、太陽熱や風力等の自然エネルギー量と、脱塩素有機廃棄物の発酵過程にて発生する熱量を調整することにより、得られた乾燥脱塩素有機廃棄物の含水率を35質量%以下に調整するとともに、脱塩素有機廃棄物に含まれる有機物の分解率を20質量%以下に抑え、燃料としての発熱量を十分に確保する。これにより、安定的に有用な発熱量を有するバイオマス燃料を作製することが可能である。   In the above methods (1) and (2), both natural energy such as solar heat and wind power and fermentation heat generated in the fermentation process of dechlorinated organic waste are used in combination. By adjusting the amount of energy and the amount of heat generated in the fermentation process of dechlorinated organic waste, the moisture content of the obtained dry dechlorinated organic waste is adjusted to 35% by mass or less, and dechlorinated organic waste The decomposition rate of the organic matter contained in is suppressed to 20% by mass or less, and a sufficient calorific value as fuel is ensured. Thereby, it is possible to produce a biomass fuel having a stable and useful calorific value.

この乾燥脱塩素有機廃棄物は、単に乾燥または加熱乾燥しただけでは、球状、塊状、板状等、比較的大きな形状をしていることが多い。用途によってはこのままの形状でもよいが、セメント焼成設備等にて用いる場合等では、燃焼効率を向上させるために、粉砕機23を用いて分級、粉砕、解砕のいずれか1つまたは2つ以上を行い、直径10mm以下の粒子状とする。
発酵設備22A、天日乾燥設備21B及び粉砕機23のうち1種以上の装置から取り出される乾燥脱塩素有機廃棄物は、保管庫24に搬入され、仕様別や品種別に選別され、保管される。
The dry dechlorinated organic waste often has a relatively large shape such as a spherical shape, a lump shape, or a plate shape when it is simply dried or heated and dried. Depending on the application, this shape may be used as it is. However, when used in cement firing facilities, etc., any one or more of classification, pulverization, and pulverization may be performed using the pulverizer 23 in order to improve combustion efficiency. To form particles having a diameter of 10 mm or less.
Dry dechlorinated organic waste taken out from one or more of the fermenting equipment 22A, the sun drying equipment 21B, and the pulverizer 23 is carried into the storage 24, and sorted and stored according to specifications and varieties.

このようにして得られた乾燥脱塩素有機廃棄物は、塩素濃度が3000ppm以下と極めて低く、含水率も35質量%以下と低く、有機物の分解率も20質量%以下に抑えられているので、高位の発熱量を有する乾燥脱塩素有機廃棄物を容易かつ安価に得ることができる。したがって、この乾燥脱塩素有機廃棄物を燃焼効率が高いバイオマス燃料として有効利用することができる。
このようにして得られた乾燥脱塩素有機廃棄物は、高位の発熱量を有しているので、セメント焼成設備のセメントキルンの窯尻部等に投入することによりセメント焼成用燃料として有効利用することができ、セメントの操業や品質への悪影響も無い。
The dry dechlorinated organic waste thus obtained has an extremely low chlorine concentration of 3000 ppm or less, a moisture content of 35 mass% or less, and a decomposition rate of organic substances of 20 mass% or less. Dry dechlorinated organic waste having a high calorific value can be obtained easily and inexpensively. Therefore, this dry dechlorinated organic waste can be effectively used as a biomass fuel with high combustion efficiency.
Since the dry dechlorinated organic waste obtained in this way has a high calorific value, it can be effectively used as a cement firing fuel by putting it in the kiln bottom of a cement kiln of a cement firing facility. Without adverse effects on cement operation and quality.

「バイオマス燃料」
本実施形態のバイオマス燃料は、上記の高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去し、乾燥または加熱乾燥してなるバイオマス燃料であって、その塩素濃度は3000ppm以下が好ましく、より好ましくは2000ppm以下、さらに好ましくは1000ppm以下である。
また、含水率は35質量%以下が好ましく、より好ましくは30質量%以下、さらに好ましくは20質量%以下である。
また、有機物の分解率は20質量%以下が好ましく、より好ましくは15質量%以下、さらに好ましくは10質量%以下である。
"Biomass fuel"
The biomass fuel of the present embodiment is a biomass fuel obtained by removing chlorine and / or chlorine compounds contained in the above high water content organic waste and drying or heat drying, and the chlorine concentration is preferably 3000 ppm or less. More preferably, it is 2000 ppm or less, More preferably, it is 1000 ppm or less.
The moisture content is preferably 35% by mass or less, more preferably 30% by mass or less, and still more preferably 20% by mass or less.
Further, the decomposition rate of the organic substance is preferably 20% by mass or less, more preferably 15% by mass or less, and still more preferably 10% by mass or less.

このバイオマス燃料は、上記の高含水率有機廃棄物に脱水処理を施すことにより、この高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去して脱塩素有機廃棄物とし、次いで、この脱塩素有機廃棄物に、自然エネルギー、発酵熱エネルギーのいずれか一方による乾燥または加熱乾燥、及び自然エネルギー、発酵熱エネルギーのいずれか他方による乾燥または加熱乾燥、を順次施すことにより、塩素濃度が3000ppm以下、含水率が35質量%以下、有機物の分解率が20質量%以下の乾燥脱塩素有機廃棄物とすることで、得ることができる。
なお、この乾燥脱塩素有機廃棄物を、例えば、ニーダー、ロールミル等の解砕手段を用いて直径10mm以下の粒子状に解砕すれば、燃焼効率が向上するので好ましい。
This biomass fuel is subjected to dehydration treatment on the high water content organic waste, thereby removing chlorine and / or chlorine compounds contained in the high water content organic waste to obtain dechlorinated organic waste, The dechlorinated organic waste is subjected to drying or heating drying with natural energy or fermentation heat energy, and drying or heating drying with natural energy or fermentation heat energy, in order to reduce the chlorine concentration. It can be obtained by making it a dry dechlorinated organic waste having 3000 ppm or less, a moisture content of 35% by mass or less, and a decomposition rate of organic matter of 20% by mass or less.
It is preferable to crush the dried dechlorinated organic waste into particles having a diameter of 10 mm or less using a crushing means such as a kneader or a roll mill because the combustion efficiency is improved.

以上説明したように、本実施形態の燃料化方法によれば、塩素濃度及び含水率が極めて低くかつ高位の発熱量を有する乾燥脱塩素有機廃棄物を容易かつ安価に得ることができる。したがって、この乾燥脱塩素有機廃棄物を燃焼効率が高いバイオマス燃料として有効利用することができる。
また、乾燥または加熱乾燥に、太陽熱等の自然エネルギーや有機廃棄物の発酵熱エネルギーを用い、化石燃料を用いないので、省エネルギー効果が大きく、しかも環境負荷が小さい。
このようにして得られた乾燥脱塩素有機廃棄物は、高位の発熱量を有しているので、セメント焼成設備のセメントキルンの窯尻部等に投入することによりセメント焼成用燃料として有効利用することができ、セメントの操業や品質への悪影響も無い。
As described above, according to the fueling method of the present embodiment, dry dechlorinated organic waste having an extremely low chlorine concentration and moisture content and a high calorific value can be obtained easily and inexpensively. Therefore, this dry dechlorinated organic waste can be effectively used as a biomass fuel with high combustion efficiency.
Moreover, since natural energy such as solar heat or fermentation heat energy of organic waste is used for drying or heating and drying, and fossil fuel is not used, the energy saving effect is large and the environmental load is small.
Since the dry dechlorinated organic waste obtained in this way has a high calorific value, it can be effectively used as a cement firing fuel by putting it in the kiln bottom of a cement kiln of a cement firing facility. Without adverse effects on cement operation and quality.

本実施形態のバイオマス燃料によれば、塩素濃度を3000ppm以下、含水率を35質量%以下、有機物の分解率を20質量%以下としたので、バイオマス燃料としての十分な発熱量を確保することができ、高位の発熱量を有する(燃焼効率が高い)燃料として有効利用することができる。
また、塩素濃度が3000ppm以下と極めて低いので、燃焼装置等においても腐食や配管等の閉塞等のトラブルが発生する虞がなく、また、セメント焼成設備に投入した場合においても、セメントの操業や品質に悪影響を及ぼす虞が無い。
このバイオマス燃料は、セメント焼成設備の燃料としての他、廃棄物発電用、廃棄物ボイラー用等、広範囲の燃料として利用が可能である。
According to the biomass fuel of the present embodiment, the chlorine concentration is 3000 ppm or less, the moisture content is 35 mass% or less, and the decomposition rate of the organic matter is 20 mass% or less, so that a sufficient calorific value as biomass fuel can be secured. And can be effectively used as a fuel having a high calorific value (high combustion efficiency).
In addition, since the chlorine concentration is as low as 3000 ppm or less, there is no risk of problems such as corrosion or blockage of pipes in the combustion equipment, etc., and even when it is put into cement firing equipment, the operation and quality of the cement There is no risk of adverse effects.
This biomass fuel can be used as a wide range of fuels for waste power generation, waste boilers, etc., as well as cement firing equipment fuels.

以下、実施例及び比較例により本発明を具体的に説明するが、本発明はこれらの実施例により限定されるものではない。   EXAMPLES Hereinafter, although an Example and a comparative example demonstrate this invention concretely, this invention is not limited by these Examples.

(実施例1)
含水率90質量%、塩素濃度8000ppm、発熱量4500kcal/kgの豚糞100kg及び脱塩処理を施した上水道水100Lを含む高含水率有機廃棄物を、脱水機を用いて脱水し、含水率70質量%、塩素濃度980ppmのケーキ33kgを得た。
次いで、このケーキを天日乾燥設備に搬入し、太陽熱及び風力を用いて天日乾燥を行い、含水率55質量%、塩素濃度980ppm、発熱量4500kcal/kgの乾燥脱塩素豚糞を得た。
Example 1
A high water content organic waste containing 100 kg of pig feces having a water content of 90% by mass, a chlorine concentration of 8000 ppm, a calorific value of 4500 kcal / kg and demineralized tap water is dehydrated using a dehydrator, and the water content is 70 A cake of 33 kg by mass and a chlorine concentration of 980 ppm was obtained.
Next, this cake was carried into a sun drying facility, and sun drying was performed using solar heat and wind power to obtain dry dechlorinated pig feces having a moisture content of 55% by mass, a chlorine concentration of 980 ppm, and a calorific value of 4500 kcal / kg.

次いで、この乾燥脱塩素豚糞を横型開放式堆肥舎に搬入し、発酵熱を用いて乾燥させ、含水率25質量%、塩素濃度1120ppm、発熱量3830kcal/kgの乾燥脱塩素豚糞12kgを得た。なお、発酵熱による有機物の分解率は15質量%であった。
また、この乾燥脱塩素豚糞をセメント焼成設備のセメントキルンの窯尻部に燃料として投入したところ、セメントキルンの燃焼効率が低下することはなく、セメントの操業や品質に影響は無かった。
Next, this dry dechlorinated pork droppings is carried into a horizontal open-type compost house and dried using fermentation heat to obtain 12 kg of dry dechlorinated pork droppings having a moisture content of 25% by mass, a chlorine concentration of 1120 ppm and a calorific value of 3830 kcal / kg. It was. In addition, the decomposition rate of the organic substance by fermentation heat was 15 mass%.
Moreover, when this dry dechlorinated swine dung was injected as fuel into the kiln bottom of the cement kiln of the cement firing facility, the combustion efficiency of the cement kiln was not lowered, and the cement operation and quality were not affected.

(比較例1)
含水率90質量%、塩素濃度8000ppm、発熱量4500kcal/kgの豚糞100kg及び脱塩処理を施した上水道水100Lを含む高含水率有機廃棄物を、脱水機を用いて脱水し、含水率70質量%、塩素濃度980ppmのケーキ33kgを得た。
次いで、このケーキを横型開放式堆肥舎に搬入し、発酵熱を用いて乾燥させ、乾燥脱塩素豚糞7kgを得た。
(Comparative Example 1)
A high water content organic waste containing 100 kg of pig feces having a water content of 90% by mass, a chlorine concentration of 8000 ppm, a calorific value of 4500 kcal / kg and demineralized tap water is dehydrated using a dehydrator, and the water content is 70 A cake of 33 kg by mass and a chlorine concentration of 980 ppm was obtained.
Next, this cake was carried into a horizontal open-type compost house and dried using fermentation heat to obtain 7 kg of dry dechlorinated pork droppings.

この乾燥脱塩素豚糞は、含水率が25質量%、塩素濃度が1790ppm、発熱量が2480kcal/kg、発酵熱による有機物の分解率が45質量%であった。
また、この乾燥脱塩素豚糞をセメント焼成設備のセメントキルンの窯尻部に燃料として投入したところ、セメントキルンの燃焼効率が低下し、セメントの操業に大きな影響があった。
The dry dechlorinated pork droppings had a water content of 25% by mass, a chlorine concentration of 1790 ppm, a calorific value of 2480 kcal / kg, and a decomposition rate of organic matter by fermentation heat of 45% by mass.
In addition, when this dry dechlorinated swine dung was introduced into the kiln bottom of the cement kiln of the cement firing facility as a fuel, the combustion efficiency of the cement kiln was lowered, and the cement operation was greatly affected.

(実施例2)
含水率90質量%、塩素濃度9000ppm、発熱量4200kcal/kgの牛糞100kg及び脱塩処理を施した上水道水100Lを含む高含水率有機廃棄物を、脱水機を用いて脱水し、含水率70質量%、塩素濃度1110ppmのケーキ33kgを得た。
次いで、このケーキを天日乾燥設備に搬入し、太陽熱及び風力を用いて天日乾燥を行い、含水率50質量%、塩素濃度1110ppm、発熱量4200kcal/kgの乾燥脱塩素牛糞を得た。
(Example 2)
A high water content organic waste containing 100 kg of cow dung having a water content of 90% by mass, a chlorine concentration of 9000 ppm, a calorific value of 4200 kcal / kg and demineralized tap water is dehydrated using a dehydrator, and the water content is 70 mass. %, 33 kg of a chlorine concentration of 1110 ppm was obtained.
Next, this cake was carried into a sun drying facility and sun dried using solar heat and wind power to obtain dry dechlorinated cow dung having a moisture content of 50 mass%, a chlorine concentration of 1110 ppm, and a calorific value of 4200 kcal / kg.

次いで、この乾燥脱塩素牛糞を縦型密閉式発酵槽に投入し、発酵熱及び風力を用いて加熱乾燥させ、含水率25質量%、塩素濃度1260ppm、発熱量3570kcal/kgの乾燥脱塩素牛糞を得た。なお、発酵熱による有機物の分解率は15質量%であった。
また、この乾燥脱塩素牛糞をセメント焼成設備のセメントキルンの窯尻部に燃料として投入したところ、セメントキルンの燃焼効率が低下することはなく、セメントの操業や品質に影響は無かった。
Next, this dried dechlorinated cow dung is put into a vertical closed fermenter and heated and dried using fermentation heat and wind power, and dried dechlorinated cow dung having a moisture content of 25 mass%, a chlorine concentration of 1260 ppm, and a calorific value of 3570 kcal / kg is obtained. Obtained. In addition, the decomposition rate of the organic substance by fermentation heat was 15 mass%.
Moreover, when this dry dechlorinated cow dung was introduced as fuel into the kiln bottom of the cement kiln of the cement firing facility, the combustion efficiency of the cement kiln was not lowered, and the cement operation and quality were not affected.

(比較例2)
含水率90質量%、塩素濃度9000ppm、発熱量4200kcal/kgの牛糞100kg及び脱塩処理を施した上水道水100Lを含む高含水率有機廃棄物を、脱水機を用いて脱水し、含水率70質量%、塩素濃度980ppmのケーキ33kgを得た。
次いで、このケーキに太陽熱による天日乾燥を300日間行い、乾燥脱塩素牛糞を得た。
この乾燥脱塩素牛糞は、含水率が40質量%と非常に多く、セメント焼成用燃料として用いることができないものであった。
(Comparative Example 2)
A high water content organic waste containing 100 kg of cow dung having a water content of 90% by mass, a chlorine concentration of 9000 ppm, a calorific value of 4200 kcal / kg and demineralized tap water is dehydrated using a dehydrator, and the water content is 70 mass. %, 33 kg of a cake having a chlorine concentration of 980 ppm was obtained.
Next, the cake was subjected to solar drying for 300 days to obtain dry dechlorinated cow dung.
This dry dechlorinated cow dung had a very high water content of 40% by mass and could not be used as a cement burning fuel.

本発明の一実施形態の高含水率有機廃棄物の燃料化方法に用いられる燃料化設備を示す模式図である。It is a schematic diagram which shows the fueling equipment used for the fueling method of the high water content organic waste of one Embodiment of this invention.

符号の説明Explanation of symbols

1 排出源
2 脱塩設備
3 燃料化設備
11 1次槽
12 1次固液分離器
13 調整槽
14 1次曝気槽
15 2次固液分離器
16 2次曝気槽
17 膜浸漬槽
18 脱水処理装置
19 処理水受槽
21A、21B 天日乾燥設備
22A、22B 発酵設備
23 粉砕機
24 保管庫
DESCRIPTION OF SYMBOLS 1 Discharge source 2 Desalination equipment 3 Fuelization equipment 11 Primary tank 12 Primary solid-liquid separator 13 Adjustment tank 14 Primary aeration tank 15 Secondary solid-liquid separator 16 Secondary aeration tank 17 Membrane immersion tank 18 Dehydration processing equipment 19 Treated water receiving tank 21A, 21B Sun drying equipment 22A, 22B Fermentation equipment 23 Crusher 24 Storage

Claims (4)

家畜排泄物、食品廃棄物のいずれか一方または双方を含有する高含水率有機廃棄物を燃料化するための方法であって、
前記高含水率有機廃棄物に脱水処理を施すことにより、この高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去して脱塩素有機廃棄物とし、
次いで、この脱塩素有機廃棄物に、自然エネルギー、発酵熱エネルギーのいずれか一方による乾燥または加熱乾燥、及び前記自然エネルギー、前記発酵熱エネルギーのいずれか他方による乾燥または加熱乾燥、を順次施すことにより、塩素濃度が3000ppm以下、含水率が35質量%以下、有機物の分解率が20質量%以下の乾燥脱塩素有機廃棄物とすることを特徴とする高含水率有機廃棄物の燃料化方法。
A method for fueling high water content organic waste containing either or both of livestock excrement and food waste,
By dehydrating the high water content organic waste, chlorine and / or chlorine compounds contained in the high water content organic waste are removed to obtain dechlorinated organic waste,
Next, the dechlorinated organic waste is sequentially subjected to drying or heating drying by either one of natural energy or fermentation heat energy, and drying or heating drying by any one of the natural energy or fermentation heat energy. A method for converting a high water content organic waste into a fuel, characterized in that it is a dry dechlorinated organic waste having a chlorine concentration of 3000 ppm or less, a water content of 35% by mass or less, and an organic matter decomposition rate of 20% by mass or less.
前記高含水率有機廃棄物の含水率は60質量%以上であることを特徴とする請求項1記載の高含水率有機廃棄物の燃料化方法。   2. The method for fuelizing a high water content organic waste according to claim 1, wherein the water content of the high water content organic waste is 60% by mass or more. 前記乾燥脱塩素有機廃棄物に、分級、粉砕、解砕のいずれか1つまたは2つ以上を行うことを特徴とする請求項1または2記載の高含水率有機廃棄物の燃料化方法。   The method for fuelizing a high water content organic waste according to claim 1 or 2, wherein the dry dechlorinated organic waste is subjected to any one or more of classification, pulverization, and pulverization. 家畜排泄物、食品廃棄物のいずれか一方または双方を含有する高含水率有機廃棄物に含まれる塩素および/または塩素化合物を除去し、乾燥または加熱乾燥してなるバイオマス燃料であって、
塩素濃度が3000ppm以下、含水率が35質量%以下かつ有機物の分解率が20質量%以下であることを特徴とするバイオマス燃料。
A biomass fuel obtained by removing chlorine and / or chlorine compounds contained in a high water content organic waste containing either or both of livestock excrement and food waste, and drying or heat drying,
A biomass fuel characterized by having a chlorine concentration of 3000 ppm or less, a water content of 35% by mass or less, and an organic matter decomposition rate of 20% by mass or less.
JP2007327673A 2007-12-19 2007-12-19 Method for converting high water content organic waste into fuel and biomass fuel Active JP5547371B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007327673A JP5547371B2 (en) 2007-12-19 2007-12-19 Method for converting high water content organic waste into fuel and biomass fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2007327673A JP5547371B2 (en) 2007-12-19 2007-12-19 Method for converting high water content organic waste into fuel and biomass fuel

Publications (2)

Publication Number Publication Date
JP2009149740A true JP2009149740A (en) 2009-07-09
JP5547371B2 JP5547371B2 (en) 2014-07-09

Family

ID=40919259

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007327673A Active JP5547371B2 (en) 2007-12-19 2007-12-19 Method for converting high water content organic waste into fuel and biomass fuel

Country Status (1)

Country Link
JP (1) JP5547371B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013181150A (en) * 2012-03-05 2013-09-12 Taiheiyo Cement Corp Method for utilizing feces and urine of pig
JP2013181149A (en) * 2012-03-05 2013-09-12 Taiheiyo Cement Corp Method for utilizing feces and urine of pig
JP2014200763A (en) * 2013-04-08 2014-10-27 清水建設株式会社 System and method for producing raw material using organic waste

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5727993A (en) * 1980-07-28 1982-02-15 Fuji Electric Co Ltd Organic waste composting treatment system
JPS6113905Y2 (en) * 1982-04-28 1986-04-30
JPH08176567A (en) * 1994-12-22 1996-07-09 Chichibu Onoda Cement Corp Production of solid fuel from waste and utilization of the same solid fuel
JPH11309495A (en) * 1998-04-30 1999-11-09 Mitsubishi Materials Corp Sludge treatment and fuel
JP2000017278A (en) * 1998-06-30 2000-01-18 Taiheiyo Cement Corp Preparation of refuse solid fuel
JP2003170147A (en) * 2001-12-05 2003-06-17 Takuma Co Ltd Apparatus and method of treating waste containing organic substance
JP2004188312A (en) * 2002-12-11 2004-07-08 Tokuyama Corp Method for processing food waste

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5727993A (en) * 1980-07-28 1982-02-15 Fuji Electric Co Ltd Organic waste composting treatment system
JPS6113905Y2 (en) * 1982-04-28 1986-04-30
JPH08176567A (en) * 1994-12-22 1996-07-09 Chichibu Onoda Cement Corp Production of solid fuel from waste and utilization of the same solid fuel
JPH11309495A (en) * 1998-04-30 1999-11-09 Mitsubishi Materials Corp Sludge treatment and fuel
JP2000017278A (en) * 1998-06-30 2000-01-18 Taiheiyo Cement Corp Preparation of refuse solid fuel
JP2003170147A (en) * 2001-12-05 2003-06-17 Takuma Co Ltd Apparatus and method of treating waste containing organic substance
JP2004188312A (en) * 2002-12-11 2004-07-08 Tokuyama Corp Method for processing food waste

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013181150A (en) * 2012-03-05 2013-09-12 Taiheiyo Cement Corp Method for utilizing feces and urine of pig
JP2013181149A (en) * 2012-03-05 2013-09-12 Taiheiyo Cement Corp Method for utilizing feces and urine of pig
JP2014200763A (en) * 2013-04-08 2014-10-27 清水建設株式会社 System and method for producing raw material using organic waste

Also Published As

Publication number Publication date
JP5547371B2 (en) 2014-07-09

Similar Documents

Publication Publication Date Title
JP5617242B2 (en) Organic waste desalting method, biomass manufacturing method, and biomass fuel
CN101844859B (en) Complete steam low-temperature thermally tempering and drying device and method for sludge
US20130026760A1 (en) Method for treating organic waste and method and apparatus for producing solid fuel/compost using zero discharge ace system
CN105399304B (en) Biological sludge drying and incineration circulation process method and its complete set of equipments
CN102374543A (en) Anaerobic fermentation-incineration combined treatment method for organic wastes
CN111023114A (en) Method for cooperatively treating municipal sludge and kitchen waste
KR102244259B1 (en) Apparatus and method for processing food waste energization
CN103990643A (en) Biomass waste low-temperature damp-hot carbonization treatment technology and device
JP5040641B2 (en) Organic waste slurry storage method and fuel conversion method, biomass fuel, and organic waste slurry storage device
CN108977251A (en) It is a kind of using house refuse preparation biomass can charcoal system and method
CN106734084A (en) A kind of solid waste substance treating method
JP2008212860A (en) Waste disposal facility
KR100851948B1 (en) Apparatus and method for drying organic sludge
CN201753303U (en) Steam low-temperature quenching and tempering complete sludge drying device
CN107597797A (en) The high instant joint disposal of wet basis Chinese medicine slag energy utilizes system and method
JP5547371B2 (en) Method for converting high water content organic waste into fuel and biomass fuel
JP2009242636A (en) Method for converting high water content organic waste into fuel and biomass fuel
JP2010084082A (en) Biomass fuel and method of manufacturing the same
CN211734134U (en) Livestock and poultry manure and domestic garbage comprehensive treatment system
JP2010234221A (en) Method of desalting high water content organic waste, method of turning it into fuel and biomass fuel
JP5633102B2 (en) Method for converting hydrous organic waste into fuel
CN103551367A (en) Integrated municipal solid waste treatment method
JP5349786B2 (en) Method for converting dehydrated organic waste into fuel and biomass fuel
JP5246788B2 (en) Method for producing moisture regulator, moisture regulator
RU2419594C1 (en) Method of animal farming wastes treatment and reclamation

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20100819

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20130215

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130219

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130422

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20130514

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130809

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20130816

A912 Re-examination (zenchi) completed and case transferred to appeal board

Free format text: JAPANESE INTERMEDIATE CODE: A912

Effective date: 20130906

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20140515

R150 Certificate of patent or registration of utility model

Ref document number: 5547371

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150