JP2009136204A - Emulsified composition for adding wheat flour, and emulsified oil-and-fat composition - Google Patents

Emulsified composition for adding wheat flour, and emulsified oil-and-fat composition Download PDF

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JP2009136204A
JP2009136204A JP2007315537A JP2007315537A JP2009136204A JP 2009136204 A JP2009136204 A JP 2009136204A JP 2007315537 A JP2007315537 A JP 2007315537A JP 2007315537 A JP2007315537 A JP 2007315537A JP 2009136204 A JP2009136204 A JP 2009136204A
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composition
emulsified
fatty acid
polyhydric alcohol
oil
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Masayuki Norimoto
正幸 則本
Kuniyoshi Mori
國好 森
Takehito Tabata
勇仁 田端
Masaji Mishina
雅示 三品
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Cosmos Technical Center Co Ltd
Nikko Chemicals Co Ltd
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Cosmos Technical Center Co Ltd
Nikko Chemicals Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an emulsified oil-and-fat composition and an emulsified composition each of which is easily dispersed in water, homogeneously permeating into dough, to improve the texture of starchy food, wherein the emulsified composition has low viscosity and which is less apt to change in the viscosity, even in terms of aging, and satisfactorily exhibits its functions, even if it is compounded at a high concentration. <P>SOLUTION: The emulsified oil-and-fat composition and the emulsified composition, each of which is to be added in wheat flour contain polyhydric alcohol fatty acid ester whose main constituent is palmitic acid, as an emulsifier, and are produced, based on finding that the compositions are suitable for quality improvement in texture and the like of starchy food, in particular, the emulsified composition has low viscosity which will not increase, even with aging, does not gelatinize, even when added to the wheat flour at a high concentration, and is easy to disperse so as to make smooth dough. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

食用に供する乳化油脂組成物及び、乳化組成物に関する。パン、ケーキ、麺などに使用する小麦粉に配合し、低粘性で取り扱いやすい新規な組成の乳化油脂組成物及び乳化組成物である。   The present invention relates to an emulsified oil and fat composition to be edible and an emulsified composition. It is an emulsified oil and fat composition and an emulsified composition having a novel composition that is blended in wheat flour used for bread, cakes, noodles, etc.

本発明の乳化油脂組成物及び乳化組成物はケーキ、麺、アイスクリームなどの食品を製造する際に使用する。一般に、小麦粉に添加してボリューム、延展性、風合いなどを上げるために、蔗糖ステアリン酸エステル、ポリグリセリンステアリン酸エステル、グリセリンモノステアリン酸エステル、及びグリセリンモノステアリン酸エステルの琥珀酸、酒石酸などとのエステルである有機酸モノグリ、ステアリン酸ソルビタンエステル、レシチン、及び油脂含む乳化組成物が用いられている。   The emulsified oil / fat composition and the emulsified composition of the present invention are used for producing foods such as cakes, noodles, and ice creams. In general, sucrose stearate, polyglyceryl stearate, glyceryl monostearate, and glyceryl monostearate with succinic acid, tartaric acid, etc. to add to wheat flour to increase volume, spreadability, texture, etc. An emulsified composition containing an organic acid monogly ester, stearic acid sorbitan ester, lecithin, and an oil is used.

ところが、親水性蔗糖ステアリン酸エステル、ポリグリセリンステアリン酸エステルは水溶性で使用しやすいという利点がある反面、味、風味に劣る。また親油性のグリセリンモノステアリン酸エステル、ポリグリセリンステアリン酸エステル、蔗糖ステアリン酸エステル、ソルビタンステアリン酸エステルなどは水に溶解しないため、単独では使用し難く親水性蔗糖脂肪酸エステル、ポリグリセリン脂肪酸エステルなどと組み合わせて、もしくは油脂を配合して水に分散して使用されている。これらの分散物は低粘性で澱粉と混和しやすいものが必要である。しかしこれらの配合物を高濃度にすると、低粘性とすることが難しく種々の工夫がなされている。   However, hydrophilic sucrose stearate and polyglycerin stearate have the advantage of being water-soluble and easy to use, but are inferior in taste and flavor. In addition, since lipophilic glyceryl monostearate, polyglycerin stearate, sucrose stearate, sorbitan stearate, etc. do not dissolve in water, it is difficult to use alone, and hydrophilic sucrose fatty acid ester, polyglycerin fatty acid ester, etc. They are used in combination or mixed with oils and fats and dispersed in water. These dispersions should have low viscosity and be easily miscible with starch. However, when these blends are made to have a high concentration, it is difficult to reduce the viscosity, and various ideas have been made.

このような技術課題を解決する組成物として、グリセリンステアリン酸エステルとHLBの低いポリグリセリンステアリン酸エステルを糖類中に分散して使用する方法が公示されている。(特許文献1)   As a composition for solving such technical problems, a method is disclosed in which glycerin stearic acid ester and polyglycerin stearic acid ester having a low HLB are dispersed in saccharides. (Patent Document 1)

しかしこのような目的として、従来多価アルコールパルミチン酸エステルを主たる乳化剤として使用することは記載されていない。
特開平7−184541号公報
However, the use of polyhydric alcohol palmitate as the main emulsifier has not been described for such purposes.
JP-A-7-184541

小麦粉添加剤としては、多価アルコール脂肪酸エステル、油脂などを用いて、水に容易く分散して、作業性を損なわず、生地に均等に浸透して、澱粉質の食品の風合いを改善することが望まれている。また少量の添加で品質改良の効果を計ることが難しいため、多量に使用してもこのような機能を損なわない組成物が望まれている。又乳化組成物は経時的に粘性が大きくなり、使えなくなるなどという課題がある。   As wheat flour additives, polyhydric alcohol fatty acid esters, fats and oils can be used to easily disperse in water and evenly penetrate the dough without impairing workability to improve the texture of starchy foods. It is desired. Further, since it is difficult to measure the effect of quality improvement by adding a small amount, a composition that does not impair such a function even when used in a large amount is desired. In addition, the emulsion composition has a problem that the viscosity increases with time and becomes unusable.

本発明者らは、一般的に使用されている多価アルコールステアリン酸エステルを多価アルコールパルミチン酸エステルとすることにより、低粘性の乳化組成物が得られることを見出した。そしてこの乳化組成物を小麦粉に多量に使用しても、小麦粉に配合してゲル化せず、分散し易く滑らかな生地となる事が解った。またこれらを乳化剤として使用した乳化組成物は経時的にも粘性の増加が見られないことが解って本発明を完成した。   The present inventors have found that a low-viscosity emulsified composition can be obtained by using a polyhydric alcohol stearic acid ester which is generally used as a polyhydric alcohol palmitic acid ester. And even if this emulsified composition was used in flour in large quantities, it was found that it was blended into flour and did not gel, resulting in a smooth dough that was easy to disperse. Further, it was found that the emulsified composition using these as emulsifiers did not increase in viscosity over time, and the present invention was completed.

原料粉、もしくはこれに加える水に添加して、ゲル化せず分散しやすく、混和し易く、生地が滑らかで、ボリューム感が得られ、風合いなど澱粉質食品の品質を改良することが出来る。   It can be added to the raw material powder or water added thereto, so that it is easy to disperse without gelation, is easy to mix, has a smooth dough, has a voluminous feel, and can improve the quality of starchy food such as texture.

主たる構成脂肪酸がパルミチン酸である多価アルコール脂肪酸エステルを構成する多価アルコールとしてはプロピレングリコール、グリセリン、ソルビトール、ポリグリセリン、蔗糖などが使用できる。好ましくはグリセリン、ポリグリセリンである。また本発明ではレシチン、リゾレシチンなどの食品添加物として使用されている乳化剤を併用することも可能である。   As the polyhydric alcohol constituting the polyhydric alcohol fatty acid ester whose main constituent fatty acid is palmitic acid, propylene glycol, glycerin, sorbitol, polyglycerin, sucrose and the like can be used. Preferred are glycerin and polyglycerin. In the present invention, an emulsifier used as a food additive such as lecithin and lysolecithin can be used in combination.

本発明の主たる構成脂肪酸がパルミチン酸である多価アルコール脂肪酸エステルの小麦粉に配合する量は特に限定されるものではないが、通常小麦粉に対して0.1%から5%配合する。   The amount of the polyhydric alcohol fatty acid ester whose main constituent fatty acid of the present invention is palmitic acid is not particularly limited, but is usually 0.1% to 5% based on the flour.

本発明でいう主たる構成脂肪酸がパルミチン酸である多価アルコール脂肪酸エステルは、その構成脂肪酸の低くても60%以上がパルミチン酸であるものを言い、本来は70%以上であることが望ましい。   The polyhydric alcohol fatty acid ester in which the main constituent fatty acid in the present invention is palmitic acid means that at least 60% of the constituent fatty acid is palmitic acid, and it is preferably 70% or more.

また更に、主たる構成脂肪酸がパルミチン酸であるグリセリン脂肪酸エステルにおいて、その組成がジエステルを多く含むと乳化組成物の粘性が下がることを見出した。そしてこの時ジエステル含量は30%以上、更には30%から55%が好ましい。   Furthermore, in the glycerol fatty acid ester whose main constituent fatty acid is palmitic acid, it has been found that the viscosity of the emulsion composition decreases when the composition contains a large amount of diester. At this time, the diester content is preferably 30% or more, more preferably 30% to 55%.

本発明では乳化剤のHLBを限定するものではない。幅広く適用が可能である。   In the present invention, the HLB of the emulsifier is not limited. Widely applicable.

また本乳化油脂組成物を使用した乳化組成物の作成に当たって使用する多価アルコールはグリセリンに限らず、蔗糖、マルトースなどの糖類、及びデキストリンなどが可能である。   In addition, the polyhydric alcohol used in the preparation of the emulsified composition using the emulsified oil / fat composition is not limited to glycerin, and can be sugars such as sucrose and maltose, and dextrin.

また食品で使用可能な水溶性高分子などを使用することができる。   In addition, water-soluble polymers that can be used in foods can be used.

以下に実施例を挙げて本発明を具体的に説明するが、本発明の技術的範囲がこれらに限定されるものではない。   EXAMPLES The present invention will be specifically described below with reference to examples, but the technical scope of the present invention is not limited to these examples.

次の処方で乳化剤とオリーブ油との混合することで乳化油脂組成物を作成した。また、この乳化油脂組成物を水分散して乳化組成物を作成した。   An emulsified oil / fat composition was prepared by mixing emulsifier and olive oil in the following formulation. Moreover, this emulsified fat composition was dispersed in water to prepare an emulsified composition.

1. 乳化油脂組成物処方
乳化剤 80(%)
オリーブ油 20
1. Emulsified oil composition formulation Emulsifier 80 (%)
Olive oil 20

乳化剤の種類として、グリセリンモノステアリン酸エステル、デカグリセリンモノステアリン酸エステル、グリセリンモノパルミチン酸エステル、ジグリセリンモノパルミチン酸エステル、デカグリセリンモノパルミチン酸エステルを選び、それぞれを使用した乳化油脂組成物の試料記号を(A)、(B)、(C)、(D)、(E)とした。   As the type of emulsifier, glycerin monostearic acid ester, decaglycerin monostearic acid ester, glycerin monopalmitic acid ester, diglycerin monopalmitic acid ester, decaglycerin monopalmitic acid ester are selected, and a sample of an emulsified oil composition using each of them The symbols were (A), (B), (C), (D), and (E).

2. 乳化油脂組成物を使用した乳化組成物処方
乳化油脂組成物 20.0(%)
デカグリンモノパルミチン酸エステル 1.0
マルトース 10.0
精製水 にて100とする。
2. Emulsified composition formulation using emulsified oil and fat composition Emulsified oil and fat composition 20.0 (%)
Decagulin monopalmitate 1.0
Maltose 10.0
Set to 100 with purified water.

3. 乳化組成物の作成法
精製水、マルトースを80℃に加温、攪拌し、均一溶液とし、これに同温度に加温した乳化油脂組成物を加えて、ホモミキサーにて乳化した。乳化後攪拌を続け室温に放置し、1日後、25℃での粘度を測定した。
3. Preparation Method of Emulsified Composition Purified water and maltose were heated to 80 ° C. and stirred to obtain a uniform solution, and the emulsified oil / fat composition heated to the same temperature was added thereto and emulsified with a homomixer. After emulsification, stirring was continued and allowed to stand at room temperature, and after 1 day, the viscosity at 25 ° C. was measured.

4. 結果
上記処方で作れた乳化組成物の粘度を表1に示した。

Figure 2009136204
4). Results Table 1 shows the viscosities of the emulsified compositions made with the above formulation.
Figure 2009136204

本発明で言うグリセリンモノパルミチン酸エステル、ジグリセリンモノパルミチン酸エステル、デカグリセリンモノパルミチン酸エステルを乳化剤として用いた乳化組成物は何れも流れるような粘性を示し、お湯に分散しやすく、小麦粉に配合しやすいものであった。   The emulsified composition using glycerin monopalmitate, diglycerin monopalmitate, decaglycerin monopalmitate as an emulsifier as used in the present invention exhibits a flowing viscosity, is easy to disperse in hot water, and is blended in flour. It was easy to do.

実施例1で作成した乳化組成物を配合してパンを作成した。   Bread was prepared by blending the emulsified composition prepared in Example 1.

1. パンの生地の処方
小麦粉 70.0部
イースト菌 2.0
フード菌 0.1
乳化組成物 1.0
精製水 40.0
1. Bread dough flour 70.0 parts yeast 2.0
Food bacteria 0.1
Emulsified composition 1.0
Purified water 40.0

2. パン生地への配合試験
パン生地への配合結果を下表に示す。構成脂肪酸がパルミチン酸である多価アルコール脂肪酸エステルに優れた配合効果が認められた。

Figure 2009136204
2. Blending test to bread dough The blending results to bread dough are shown in the table below. The compounding effect which was excellent in the polyhydric alcohol fatty acid ester whose constituent fatty acid is palmitic acid was recognized.
Figure 2009136204

次のような高濃度に乳化剤を含有する乳化組成物を実施例1と同様な方法で作成した。この粘度を実施例1と同様にして測定した。   An emulsion composition containing an emulsifier at a high concentration as follows was prepared in the same manner as in Example 1. This viscosity was measured in the same manner as in Example 1.

本発明でいう構成脂肪酸がパルミチン酸である多価アルコール脂肪酸エステルが従来使用されている試料と比較して、低粘度の乳化組成物となること、経時的にも変化し難い事が解った。

Figure 2009136204
It was found that the polyhydric alcohol fatty acid ester in which the constituent fatty acid referred to in the present invention is palmitic acid is an emulsion composition having a low viscosity as compared with a sample conventionally used, and that it is difficult to change over time.
Figure 2009136204

下記のような処方で乳化組成物を作りこれを用いて麺を作成した。   An emulsified composition was prepared according to the following formulation, and noodles were prepared using the emulsion composition.

1. 乳化組成物の処方と粘度

Figure 2009136204
1. Formulation and viscosity of emulsified composition
Figure 2009136204

2. 本乳化組成物を次のような処方で小麦粉に配合して麺を作成した。
処方:小麦 100部、水 32部、食塩 2部、本乳化組成物 4部
2. This emulsified composition was blended into wheat flour with the following formulation to prepare noodles.
Formulation: 100 parts of wheat, 32 parts of water, 2 parts of salt, 4 parts of the emulsified composition

3. 結果
本発明品である構成脂肪酸がパルミチン酸である多価アルコール脂肪酸エステルを用いることで、混和性に優れ、弾力があり、表面の滑らかな生地が得られ、これを茹でると歯ざわりが良く、腰のある麺が得られた。
3. Results By using a polyhydric alcohol fatty acid ester whose constituent fatty acid is palmitic acid as the product of the present invention, a dough having excellent miscibility, elasticity and a smooth surface can be obtained. A noodle with a scent was obtained.

油脂を20%配合した乳化組成物を下記の処方で作成した。構成脂肪酸がパルミチン酸である多価アルコール脂肪酸エステルを用いた乳化組成物は粘性が低かった。またグリセリンジパルミチン酸エステルを配合することで優れた低粘性の乳化組成物となることが解った。また、構成脂肪酸がパルミチン酸である多価アルコール脂肪酸エステルを用いた乳化組成物は全て安定であった。

Figure 2009136204
親水性乳化剤:デカグリセリンモノパルミチン酸エステル
MGP:グリセリンモノパルミチン酸エステル
MGS:グリセリンモノステアリン酸エステル
DGP:グリセリンジパルミチン酸エステル(グリセリンジパルミチン酸エステルの含量45%、グリセリンモノパルミチン酸エステル35%、グリセリントリパルミチン酸エステル20%) An emulsified composition containing 20% oil was prepared with the following formulation. The emulsion composition using the polyhydric alcohol fatty acid ester whose constituent fatty acid is palmitic acid had low viscosity. Moreover, it turned out that it becomes an excellent low-viscosity emulsion composition by mix | blending glycerol dipalmitate. Moreover, all the emulsified compositions using the polyhydric alcohol fatty acid ester whose constituent fatty acid is palmitic acid were stable.
Figure 2009136204
Hydrophilic emulsifier: Decaglycerol monopalmitate MGP: Glycerol monopalmitate MGS: Glycerol monostearate DGP: Glycerol dipalmitate (content of glycerol dipalmitate 45%, glycerol monopalmitate 35%, Glycerol tripalmitate 20%)

水溶性高分子とパルミチン酸モノグリセリドを使用して、低粘性の乳化組成物を作成した。この乳化組成物は2ヶ月常温放置によっても、外観的な変化無く、小麦粉に本品を10%配合して、ゲル化せず、滑らかな麺生地が得られた。

Figure 2009136204
調製方法:カゼインナトリウム、もしくはアルギン酸ナトリウムとデキストリンを水に溶解し、これを70℃に加温し、ホモミキサー攪拌をしながら、同温度に加温した大豆油、パルミチン酸モノグリセリド溶液を加えて乳化した。乳化後は攪拌しながら冷却した。
MGP:グリセリンモノパルミチン酸エステル A low-viscosity emulsion composition was prepared using a water-soluble polymer and palmitic acid monoglyceride. Even when the emulsion composition was left at room temperature for 2 months, 10% of this product was blended with wheat flour and gelled, and a smooth noodle dough was obtained.
Figure 2009136204
Preparation method: Sodium caseinate or sodium alginate and dextrin is dissolved in water, and this is heated to 70 ° C., and stirred with homomixer, and added with soybean oil and palmitate monoglyceride solution heated to the same temperature to emulsify did. After emulsification, the mixture was cooled with stirring.
MGP: Glycerin monopalmitate

Claims (5)

乳化剤として主たる構成脂肪酸がパルミチン酸である多価アルコール脂肪酸エステルを含有することを特徴とする小麦粉添加用乳化油脂組成物。 An emulsified oil / fat composition for flour addition, comprising a polyhydric alcohol fatty acid ester whose main constituent fatty acid is palmitic acid as an emulsifier. 多価アルコール脂肪酸エステルの構成脂肪酸の60%以上がパルミチン酸であることを特徴とする請求項1に記載の小麦粉添加用乳化油脂組成物。 The emulsified oil composition for adding flour according to claim 1, wherein 60% or more of the constituent fatty acids of the polyhydric alcohol fatty acid ester is palmitic acid. 多価アルコール脂肪酸エステルを構成する多価アルコールがグリセリン及び/又はポリグリセリンからなることを特徴とする請求項1又は2記載の小麦粉添加用乳化油脂組成物。 The emulsified oil / fat composition for adding flour according to claim 1 or 2, wherein the polyhydric alcohol constituting the polyhydric alcohol fatty acid ester is composed of glycerin and / or polyglycerin. グリセリンジパルミチン酸エステルを主たる乳化剤とすることを特徴とする小麦粉添加用乳化油脂組成物。 An emulsified oil and fat composition for adding flour, characterized in that glycerin dipalmitate is the main emulsifier. 請求項1〜4のいずれかに記載の乳化剤と、水と、必要に応じて食用油脂とを用いた小麦粉添加用の乳化組成物。 The emulsified composition for flour addition using the emulsifier in any one of Claims 1-4, water, and edible oil and fat as needed.
JP2007315537A 2007-12-06 2007-12-06 Emulsified composition for adding wheat flour, and emulsified oil-and-fat composition Pending JP2009136204A (en)

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