JP2008308564A - Soil-activating agent - Google Patents

Soil-activating agent Download PDF

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JP2008308564A
JP2008308564A JP2007157042A JP2007157042A JP2008308564A JP 2008308564 A JP2008308564 A JP 2008308564A JP 2007157042 A JP2007157042 A JP 2007157042A JP 2007157042 A JP2007157042 A JP 2007157042A JP 2008308564 A JP2008308564 A JP 2008308564A
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soil
microorganisms
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planting
chlorine dioxide
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Minoru Toyoshima
稔 豊島
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Abstract

<P>PROBLEM TO BE SOLVED: To activate soil by effectively sterilizing harmful microorganisms in an early stage while the microorganisms useful for planting is left to remain in the soil. <P>SOLUTION: The soil-activating agent is obtained by adding 0.5-1 mass% of sodium hydrogencarbonate and 0.01-0.05 mass% of citric acid to an aqueous solution of chlorine dioxide in the concentration of 500-700 ppm. The soil-activating agent is sprinkled over the soil in a ratio of about 2,000-2,500 liters per Tan (about 992 m<SP>2</SP>), and thereby, the microorganisms in the soil can be selectively sterilized, and the soil for planting can be activated in an early stage. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は土壌活性化剤、特に、健全な植栽ができるように土壌を活性化する土壌活性化剤及び活性化方法に関する。   The present invention relates to a soil activator, and more particularly, to a soil activator and an activation method for activating soil so that healthy planting can be performed.

土壌中には、植物栽培上から有効な細菌や放線菌などの微生物の他、糸状菌などの有害な微生物が生息している。
これらの微生物は、植物の根系と深い関わり合いがあり、本来的には上記有効な微生物と有害な微生物の拮抗関係が望ましいが、土壌処理に際して除菌剤の殺菌力の弱いものでは有害な微生物を充分に除去することができない。
逆に、クロルピクリンやトラペックサイド油剤などの強力な除菌剤では、植栽に有効な微生物までも同時に除去してしまう欠点があった。また、有害微生物の耐性化によって、殺菌効果は著しく低下しつつあり、環境汚染や人体への影響も顕著になっている。
そして、平成18年の農薬取締法の改正に伴う規制強化によって、病害が多発化しており、植栽作業面からも問題が大きくなり、複雑化している。
In the soil, harmful microorganisms such as filamentous fungi live in addition to microorganisms such as bacteria and actinomycetes effective in plant cultivation.
These microorganisms are closely related to the root system of plants, and inherently, the antagonistic relationship between the above-mentioned effective microorganisms and harmful microorganisms is desirable. Cannot be removed sufficiently.
On the other hand, with strong sterilizing agents such as chlorpicrin and trapecside oil, there was a drawback that even microorganisms effective for planting were removed at the same time. In addition, the sterilization effect has been remarkably reduced due to the resistance of harmful microorganisms, and the environmental pollution and the influence on the human body have become remarkable.
And with the strengthening of regulations accompanying the amendment of the Agricultural Chemicals Control Law in 2006, diseases are becoming more frequent, and problems are growing and complicated from the planting work side.

本発明者は、先に、濃度500〜700ppmの二酸化塩素水溶液を、1反当り2000〜2500Lの割合で土壌に散布することによって、植栽用土壌を活性化する方法を提供し、これによって大きな効果を挙げてきた。(特許文献1)
そして、その後の普及の段階において、生産者の圃場の一部に土壌疲弊化に伴って病害の温床となっている土壌が見受けられ、こうした圃場の健全化を図るためにこれを使用した場合に、回復力が見られるものの早期の解決には至らないこともあり、継続的な使用によって徐々に土壌を健全化して行く他ないこともあった。
特許第2686591号公報
The present inventor previously provided a method for activating planting soil by spraying a 500 to 700 ppm concentration of chlorine dioxide aqueous solution on the soil at a rate of 2000 to 2500 L per reaction. Has been effective. (Patent Document 1)
In the subsequent stage of dissemination, some of the farmer's fields have soil that has become a hotbed of disease due to soil exhaustion, and when this is used to improve the health of these fields, Although there was resilience, it could not lead to an early solution, and there was no other choice but to gradually improve the soil through continuous use.
Japanese Patent No. 2686591

本発明者は、上記した状況から、先に提供した発明を更に改良し、植栽上有用な微生物を土壌中に残存させながら、早期に、有害な微生物を効果的に除菌して、土壌を活性化することができることと、土壌中に存在している有効微生物を速やかに増殖活性化させることによって、植栽上健全な土壌を維持、持続させると共に、人畜無害の土壌活性除菌剤を提供しようとするものである。   From the above-mentioned situation, the present inventor further improved the invention provided earlier, effectively sterilizing harmful microorganisms at an early stage while allowing microorganisms useful for planting to remain in the soil, Can be activated, and the effective microorganisms present in the soil can be rapidly proliferated and activated to maintain and sustain a healthy soil for planting. It is something to be offered.

本発明は、種々研究、改良の結果、濃度500〜700ppmの範囲にある二酸化塩素の水溶液に、炭酸水素ナトリウムを0.5〜1質量%添加し、更にクエン酸を0.01〜0.05質量%添加することによって、土壌活性化剤を得るものである。
この土壌活性化剤は、1反当り2000〜2500リットルの割合で土壌に散布することにより、土壌中の微生物を選択的に除菌し、植栽用土壌の活性化を行うことができる。
In the present invention, as a result of various studies and improvements, 0.5 to 1% by mass of sodium hydrogen carbonate is added to an aqueous solution of chlorine dioxide having a concentration of 500 to 700 ppm, and citric acid is further added to 0.01 to 0.05. A soil activator is obtained by adding mass%.
This soil activator can selectively disinfect microorganisms in the soil and activate the soil for planting by spraying on the soil at a rate of 2000 to 2500 liters per counterweight.

本発明は、濃度500〜700ppmの範囲にある二酸化塩素の水溶液に、0.5〜1質量%の炭酸水素ナトリウムと0.01〜0.05質量%のクエン酸を添加した土壌活性化剤であって、これを1反当り2000〜2500リットルの割合で土壌に散布することにより、土壌のpH値を安定化させることができて二酸化塩素の反応性を高め、土壌環境の悪い圃場においても、植栽上有用な微生物を土壌中に残存させながら、早期に、有害な微生物を効果的に除菌して、土壌を活性化することができ、かつ土壌中に存在している有用微生物を速やかに増殖活性化させることによって、植栽上健全な土壌を維持、持続させることができる。また、この土壌活性化剤は、人畜に対して無害であって、安全に使用することができる。   The present invention is a soil activator obtained by adding 0.5 to 1% by mass of sodium bicarbonate and 0.01 to 0.05% by mass of citric acid to an aqueous solution of chlorine dioxide having a concentration of 500 to 700 ppm. And, by spraying this on the soil at a rate of 2000-2500 liters per reaction, the pH value of the soil can be stabilized and the reactivity of chlorine dioxide can be increased, even in fields with poor soil environment, While leaving microorganisms useful for planting in the soil, it is possible to effectively sterilize harmful microorganisms at an early stage and activate the soil, and promptly remove the useful microorganisms present in the soil. By making it grow and activate, it is possible to maintain and maintain a healthy soil for planting. Moreover, this soil activator is harmless to human livestock and can be used safely.

二酸化塩素は、種々の方法で作ることが可能であるが、例えば、亜塩素酸ナトリウムに塩素ガスを反応させて作ることができる。この二酸化塩素は非常に水に溶け易く、強力な酸化作用が見られるが、低濃度で使用すれば安全であるので、従来、紙、パルプ、油脂類、デンプン、小麦粉の漂白や、食品の加工消毒添加物、プール、浴場、浄水場での水消毒剤などとして、広く使用されている。   Chlorine dioxide can be produced by various methods. For example, it can be produced by reacting chlorine gas with sodium chlorite. This chlorine dioxide is very soluble in water and has a strong oxidizing action, but it is safe to use at low concentrations, so it has traditionally been bleaching paper, pulp, oils, starches, flour, and food processing It is widely used as a disinfectant additive, water disinfectant in pools, baths and water purification plants.

上記二酸化塩素は、水に溶かして濃度500〜700ppmの水溶液の状態で使用するが、この二酸化塩素には炭酸水素ナトリウムとクエン酸が加えられる。
添加するこの炭酸水素ナトリウムの濃度は約0.5〜1質量%にするとよく、またクエン酸の濃度は約0.01〜0.05質量%にするとよい。
上記炭酸水素ナトリウムとクエン酸の併用により、土壌のpH値は約8.29〜8.49に安定化することができるようになり、このことが二酸化塩素の作用を更に効果的にしているものと推測される。
The chlorine dioxide is dissolved in water and used in the form of an aqueous solution having a concentration of 500 to 700 ppm. Sodium bicarbonate and citric acid are added to the chlorine dioxide.
The concentration of the sodium hydrogen carbonate to be added is preferably about 0.5 to 1% by mass, and the concentration of citric acid is preferably about 0.01 to 0.05% by mass.
The combined use of sodium hydrogen carbonate and citric acid makes it possible to stabilize the pH value of the soil to about 8.29 to 8.49, which makes the action of chlorine dioxide more effective. It is guessed.

また、土壌においては、粘土などの土壌粒子の最小単位である一次粒子が集合して少し大きな二次粒子(微小団粒)を形成しており、これが更に集合して三次粒子(団粒)を形成している。細菌、放線菌などの有用な上記微生物は微小団粒の微細な小孔隙空間を住処としており、植物が植えられたときには植物根と共生関係を作り、根の届かない場所から水分や養分を供給するものと考えられている。
一方、糸状菌などの有害微生物は、上記した有用微生物よりも大きいので、多くは微小団粒と微小団粒の間の大孔隙空間を住処としている。
こうした土壌に対して上記本発明の活性化剤を使用した結果を観察すると、この活性化剤によって土壌のpHが調整され、また、酸素拡散誘導が起こると共に、上記糸状菌などの有害微生物に優先的に作用して、有害微生物の密度を低下させ、有用微生物に対する酸素供給が果たされて増殖活性を向上させ、併せて土壌の団粒構造化を促進させ、良好な土壌の生成に寄与しているものと考えられる。
Also, in soil, primary particles, which are the smallest unit of soil particles such as clay, aggregate to form slightly larger secondary particles (micro-aggregates), which further aggregate to form tertiary particles (aggregates). Forming. Useful microorganisms such as bacteria and actinomycetes live in a small pore space with minute aggregates. When plants are planted, they form a symbiotic relationship with plant roots and supply moisture and nutrients from places where roots cannot reach. It is thought to do.
On the other hand, harmful microorganisms such as filamentous fungi are larger than the above-mentioned useful microorganisms, and many of them live in the large pore space between the micro-aggregates.
When observing the results of using the activator of the present invention on such soil, the activator adjusts the pH of the soil, induces oxygen diffusion, and gives priority to harmful microorganisms such as the filamentous fungus. It acts effectively to reduce the density of harmful microorganisms, improve oxygen supply to useful microorganisms, improve the growth activity, and promote the formation of soil aggregates, contributing to the production of good soil. It is thought that.

濃度60,000ppmの二酸化塩素水溶液20リットルに、水を加えて2,000リットルになるように稀釈して、濃度600ppmの二酸化塩素水溶液を作り、これに14kg(0.7質量%)の炭酸水素ナトリウムと、0.6kg(0.03質量%)のクエン酸を加えて、土壌活性化剤を得た。   To 20 liters of 60,000 ppm chlorine dioxide solution, add water to dilute to 2,000 liters to make 600 ppm chlorine dioxide solution, and 14 kg (0.7 mass%) hydrogen carbonate Sodium and 0.6 kg (0.03% by mass) citric acid were added to obtain a soil activator.

上記土壌活性化剤の性能を見るために、下記する微生物培養試験を行った。
(微生物培養試験)
除菌処理前の土壌と、上記実施例の土壌活性化剤を、土壌1m当り約2.01〜2.52リットル(一反当り約2000〜2500リットル)の割合で散布し、散布後、二酸化塩素がほぼ消失するまで約2週間放置した除菌処理後の土壌をサンプリングし、これを稀釈平板法で測定した。
In order to see the performance of the soil activator, the following microorganism culture test was performed.
(Microbial culture test)
The soil before sterilization treatment and the soil activator of the above example were sprayed at a rate of about 2.01 to 2.52 liters per 1 m 2 of soil (about 2000 to 2500 liters per side). The soil after sterilization treatment which was allowed to stand for about 2 weeks until chlorine dioxide almost disappeared was sampled and measured by a dilution plate method.

(細菌・放線菌の試験条件)
除菌処理前の土壌と、除菌処理後の土壌を採取して夫々よく攪拌し、各10gずつ採って90mlの滅菌水に入れ、往復振とう機で10分間振とうする。この振とうしたものを1次稀釈(10倍)とする。この1次稀釈液をよく攪拌し、その10gをとって90mlの滅菌水に入れて2次稀釈(100倍)したものをよく攪拌し、逐次5次稀釈(100,000倍)まで繰返す。この5次稀釈したものを夫々エッグアルブミン培地にて、28℃で168時間培養し、土壌1g当りの細菌・放線菌数を測定した。なお、菌数の測定に当っては、カウントできる範囲があるので、カウントし易いように稀釈濃度が100,000倍〜1,000,000倍の範囲で計測した。
(Test conditions for bacteria and actinomycetes)
The soil before the sterilization treatment and the soil after the sterilization treatment are collected and stirred well, 10 g each is taken into 90 ml of sterilized water, and shaken for 10 minutes with a reciprocating shaker. This shake shall be the primary dilution (10 times). The primary dilution is thoroughly stirred, 10 g is taken into 90 ml of sterilized water, and the secondary dilution (100 times) is thoroughly stirred, and then repeated until the fifth dilution (100,000 times). Each of the fifth dilutions was cultured in an egg albumin medium at 28 ° C. for 168 hours, and the number of bacteria / actinomycetes per gram of soil was measured. In the measurement of the number of bacteria, since there is a range that can be counted, the dilution concentration was measured in the range of 100,000 times to 1,000,000 times so as to be easily counted.

(糸状菌の試験方法)
除菌処理前の土壌と、除菌処理後の土壌を採取し、上記細菌・放線菌の試験条件と同様にして3次稀釈(1,000倍)する。この3次稀釈したものを夫々ローズベンガル培地にて、28℃で72時間培養し、土壌1g当りの糸状菌数を測定した。なお、菌数の測定に当っては、カウントできる範囲があるので、カウントし易いように稀釈濃度が10倍〜10,000倍の範囲で計測した。
(Test method for filamentous fungi)
The soil before the sterilization treatment and the soil after the sterilization treatment are collected and subjected to the third dilution (1,000 times) in the same manner as the test conditions for the bacteria and actinomycetes. Each of the third dilutions was cultured in Rose Bengal medium at 28 ° C. for 72 hours, and the number of filamentous fungi per gram of soil was measured. In addition, since there is a range which can be counted in the measurement of the number of bacteria, the dilution concentration was measured in the range of 10 times to 10,000 times so as to be easily counted.

(試験結果)
上記微生物培養試験の結果は表1に示すとおりである。
(Test results)
The results of the microorganism culture test are shown in Table 1.

Figure 2008308564
Figure 2008308564

(考察)
微生物培養試験の結果によれば、土壌処理前に比べて、土壌処理後では、細菌数と放線菌数が減っているものの、なお多数の細菌と放線菌が残存している。その一方、糸状菌数は大幅に減少しており、処理後の残存量は極めて少なく、一般に土壌にとって有害とされている糸状菌を効果的に減少させていることが判る。
(Discussion)
According to the results of the microbial culture test, the number of bacteria and actinomycetes decreased after soil treatment compared to before soil treatment, but many bacteria and actinomycetes still remained. On the other hand, the number of filamentous fungi has been greatly reduced, the residual amount after treatment is extremely small, and it can be seen that filamentous fungi, which are generally considered harmful to the soil, are effectively reduced.

Claims (2)

濃度500〜700ppmの二酸化塩素水溶液に、0.5〜1質量%の炭酸水素ナトリウム及び0.01〜0.05質量%のクエン酸を添加した土壌活性化剤。 A soil activator obtained by adding 0.5 to 1% by mass of sodium hydrogen carbonate and 0.01 to 0.05% by mass of citric acid to an aqueous chlorine dioxide solution having a concentration of 500 to 700 ppm. 濃度500〜700ppmの二酸化塩素水溶液に、0.5〜1質量%の炭酸水素ナトリウム及び0.01〜0.05質量%のクエン酸を添加した土壌活性化剤を、1反当り2000〜2500リットルの割合で土壌に散布することにより、土壌中の微生物を選択的に除菌し、該土壌を植栽に使用することを特徴とする植栽用土壌の活性化方法。 A soil activator obtained by adding 0.5 to 1% by mass of sodium hydrogen carbonate and 0.01 to 0.05% by mass of citric acid to an aqueous chlorine dioxide solution having a concentration of 500 to 700 ppm is 2000 to 2500 liters per reaction. A method for activating soil for planting, characterized in that microorganisms in the soil are selectively sterilized by spraying on the soil at a ratio of 5%, and the soil is used for planting.
JP2007157042A 2007-06-14 2007-06-14 Soil-activating agent Pending JP2008308564A (en)

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