JP2008274035A5 - - Google Patents
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- JP2008274035A5 JP2008274035A5 JP2007116557A JP2007116557A JP2008274035A5 JP 2008274035 A5 JP2008274035 A5 JP 2008274035A5 JP 2007116557 A JP2007116557 A JP 2007116557A JP 2007116557 A JP2007116557 A JP 2007116557A JP 2008274035 A5 JP2008274035 A5 JP 2008274035A5
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- JP
- Japan
- Prior art keywords
- polyphenylene ether
- resin composition
- based resin
- parts
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011342 resin composition Substances 0.000 claims description 28
- 238000004519 manufacturing process Methods 0.000 claims description 25
- 229920001955 polyphenylene ether Polymers 0.000 claims description 25
- -1 phosphate ester compound Chemical class 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 229920001400 block copolymer Polymers 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- 229920000265 Polyparaphenylene Polymers 0.000 claims description 6
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 238000011144 upstream manufacturing Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 238000004898 kneading Methods 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 229920001890 Novodur Polymers 0.000 claims description 2
- 230000032683 aging Effects 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 2
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims 1
Description
即ち、本発明は、
［１］（Ａ）ポリフェニレンエーテル粉体６０〜９８質量部と（Ｂ）スチレン系樹脂１〜２５質量部、（Ｃ）水添ブロック共重合体１〜２０質量部含有する樹脂組成物であって上記樹脂組成物を押出機を用いて溶融混練する際に、押出機のバレル全長を１００％としたときに、上流側から４５〜７５％を、未溶融混合ゾーンとして、未溶融混合ゾーンの後にバレル全長の５〜３０％を溶融混練ゾーンとして得られることを特徴とするポリフェニレンエーテル系樹脂組成物の製造方法。
［２］（Ａ）、（Ｂ）、（Ｃ）成分の合計１００質量部に対して、（Ｄ）リン酸エステル系化合物３〜３０質量部配合することを特徴とする請求項１記載のポリフェニレンエーテル系樹脂組成物の製造方法。
［３］（Ａ）ポリフェニレンエーテル粉体、（B）スチレン系樹脂、（Ｃ）水添ブロック共重合体を押出機の上流側にある第１原料供給口より供給後、（Ｄ）リン酸エステル系化合物を下流側の第２原料供給口より供給することを特徴とする請求項２記載のポリフェニレンエーテル系樹脂組成物の製造方法。
［４］（Ｄ）リン酸エステル系化合物を供給する第２原料供給口を未溶融混合ゾーンとすることを特徴とする請求項２または３記載のポリフェニレンエーテル系樹脂組成物の製造方法。
［５］未溶融混合ゾーンのバレル温度を押出機の上流側から０〜３５％を２００℃以下に設定することを特徴とする請求項１〜４のいずれか１項に記載のポリフェニレンエーテル系樹脂組成物の製造方法。
［６］押出機のスクリュー回転数を６００〜１５０ｒｐｍとすることを特徴とする請求項１〜５のいずれか１項に記載のポリフェニレンエーテル系樹脂組成物の製造方法。
［７］ダイ出口から押出される樹脂組成物の温度を３００〜３８０℃とすることを特徴とする請求項１〜６のいずれか１項に記載のポリフェニレンエーテル系樹脂組成物の製造方法。
［８］（Ｂ）スチレン系樹脂がポリスチレンおよびゴム補強ポリスチレンからなり、ゴム補強ポリスチレンが５重量部以下であることを特徴とする請求項１〜７のいずれか１項に記載のポリフェニレンエーテル系樹脂組成物の製造方法。
［９］（Ｄ）リン酸エステル系化合物が、下記一般式（Ｉ）または式（II）で示される縮合燐酸エステル系化合物であることを特徴とする請求項２〜８のいずれか１項に記載のポリフェニレンエーテル系樹脂組成物の製造方法。
That is, the present invention
[1] A resin composition containing (A) 60 to 98 parts by mass of polyphenylene ether powder, (B) 1 to 25 parts by mass of a styrene resin, and (C) 1 to 20 parts by mass of a hydrogenated block copolymer. When melt-kneading the resin composition using an extruder, when the total barrel length of the extruder is 100%, 45 to 75% from the upstream side is set as an unmelted mixing zone after the unmelted mixing zone. A method for producing a polyphenylene ether-based resin composition, wherein 5 to 30% of the total barrel length is obtained as a melt-kneading zone.
[2] The polyphenylene according to claim 1, wherein 3 to 30 parts by mass of (D) a phosphoric ester compound is added to 100 parts by mass of the total of components (A), (B) and (C). A method for producing an ether-based resin composition.
[3] After (A) polyphenylene ether powder, (B) styrene resin, and (C) hydrogenated block copolymer are supplied from the first raw material supply port on the upstream side of the extruder, (D) phosphate ester 3. The method for producing a polyphenylene ether-based resin composition according to claim 2, wherein the compound is supplied from a second raw material supply port on the downstream side.
[4] The method for producing a polyphenylene ether-based resin composition according to claim 2 or 3, wherein the second raw material supply port for supplying the (D) phosphate ester-based compound is an unmelted mixing zone.
[5] The polyphenylene ether resin according to any one of claims 1 to 4 , wherein the barrel temperature of the unmelted mixing zone is set to 200 ° C. or less from 0 to 35% from the upstream side of the extruder. A method for producing the composition.
[6] The method for producing a polyphenylene ether-based resin composition according to any one of claims 1 to 5 , wherein the screw speed of the extruder is 600 to 150 rpm.
[7] The method for producing a polyphenylene ether-based resin composition according to any one of claims 1 to 6 , wherein the temperature of the resin composition extruded from the die outlet is 300 to 380 ° C.
[8] The polyphenylene ether resin according to any one of claims 1 to 7 , wherein (B) the styrene resin is made of polystyrene and rubber reinforced polystyrene, and the rubber reinforced polystyrene is 5 parts by weight or less. A method for producing the composition.
[9] In any one of claims 2 to 8 , wherein (D) the phosphate ester compound is a condensed phosphate ester compound represented by the following general formula (I) or formula (II) : The manufacturing method of the polyphenylene ether-type resin composition of description.
（一般式（Ｉ）、（ＩＩ）中、Ｑ１、Ｑ２、Ｑ３、Ｑ４は、各々置換基であって各々独立に炭素数１から６のアルキル基を表し、Ｒ１、Ｒ２は各々置換基であってメチル基を表し、Ｒ３、Ｒ４は各々独立に水素原子またはメチル基を表す。ｎは１以上の平均値を有し、ｎ１、ｎ２は各々独立に０から２の整数を示し、ｍ１、ｍ２、ｍ３、ｍ４は各々独立に０から３の整数を示す。）
［１０］（Ｃ）水添ブロック共重合体の数平均分子量が１５０，０００〜３５０，０００であることを特徴とする請求項１〜７のいずれか１項に記載のポリフェニレンエーテル系樹脂組成物の製造方法。
［１１］（Ａ）ポリフェニレンエーテル粉体（Ｂ）スチレン系樹脂（Ｃ）水添ブロック共重合体の合計１００重量部に対して、（Ｅ）ポリオレフィンを０．５〜５質量部含有することを特徴とする請求項１〜８のいずれか１項に記載のポリフェニレンエーテル系樹脂組成物の製造方法。
［１２］１５０℃、２００時間エージング後のＩＺＯＤ保持率が６５％以上であることを特徴とする請求項１〜９のいずれか１項に記載のポリフェニレンエーテル系樹脂組成物。
［１３］請求項１記載の製造方法より得られた樹脂組成物から成形されたテレビ内部部品の偏向ヨーク。
(In the general formulas (I) and (II), Q1, Q2, Q3 and Q4 are each a substituent and each independently represents an alkyl group having 1 to 6 carbon atoms, and R1 and R2 are each a substituent. R3 and R4 each independently represents a hydrogen atom or a methyl group, n has an average value of 1 or more, n1 and n2 each independently represents an integer of 0 to 2, m1, m2 , M3 and m4 each independently represents an integer of 0 to 3.)
[ 10 ] The polyphenylene ether resin composition according to any one of claims 1 to 7 , wherein the number average molecular weight of the (C) hydrogenated block copolymer is from 150,000 to 350,000. Manufacturing method.
[ 11 ] (A) Polyphenylene ether powder (B) Styrenic resin (C) 0.5 to 5 parts by mass of (E) polyolefin is contained with respect to 100 parts by weight of the hydrogenated block copolymer. The manufacturing method of the polyphenylene ether-type resin composition of any one of Claims 1-8 characterized by the above-mentioned.
[ 12 ] The polyphenylene ether-based resin composition according to any one of claims 1 to 9 , wherein an IZOD retention after aging at 150 ° C. for 200 hours is 65% or more.
[ 13 ] A deflection yoke for television internal parts molded from the resin composition obtained by the manufacturing method according to claim 1.
Claims (13)
（一般式（Ｉ）、（ＩＩ）中、Ｑ１、Ｑ２、Ｑ３、Ｑ４は、各々置換基であって各々独立に炭素数１から６のアルキル基を表し、Ｒ１、Ｒ２は各々置換基であってメチル基を表し、Ｒ３、Ｒ４は各々独立に水素原子またはメチル基を表す。ｎは１以上の平均値を有し、ｎ１、ｎ２は各々独立に０から２の整数を示し、ｍ１、ｍ２、ｍ３、ｍ４は各々独立に０から３の整数を示す。） (D) The polyphenylene compound according to any one of claims 2 to 8 , wherein the phosphate ester compound is a condensed phosphate ester compound represented by the following general formula (I) or (II): A method for producing an ether-based resin composition.
(In the general formulas (I) and (II), Q1, Q2, Q3 and Q4 are each a substituent and each independently represents an alkyl group having 1 to 6 carbon atoms, and R1 and R2 are each a substituent. R3 and R4 each independently represents a hydrogen atom or a methyl group, n has an average value of 1 or more, n1 and n2 each independently represents an integer of 0 to 2, m1, m2 , M3 and m4 each independently represents an integer of 0 to 3.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007116557A JP5196630B2 (en) | 2007-04-26 | 2007-04-26 | Process for producing polyphenylene ether resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007116557A JP5196630B2 (en) | 2007-04-26 | 2007-04-26 | Process for producing polyphenylene ether resin composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008274035A JP2008274035A (en) | 2008-11-13 |
| JP2008274035A5 true JP2008274035A5 (en) | 2010-04-22 |
| JP5196630B2 JP5196630B2 (en) | 2013-05-15 |
Family
ID=40052444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007116557A Active JP5196630B2 (en) | 2007-04-26 | 2007-04-26 | Process for producing polyphenylene ether resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5196630B2 (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0919730B1 (en) | 2008-10-24 | 2019-07-02 | Asahi Kasei Chemicals Corporation | CONNECTION STRUCTURE FOR A PHOTOVOLTAIC POWER GENERATION MODULE |
| JP2010245380A (en) * | 2009-04-08 | 2010-10-28 | Asahi Kasei Chemicals Corp | Film for solar cell back sheet, and solar cell back sheet and solar cell module using the same |
| TW201043460A (en) * | 2009-04-30 | 2010-12-16 | Mitsubishi Plastics Inc | Solar cell sheet and solar cell module |
| JP5461298B2 (en) * | 2009-06-30 | 2014-04-02 | 旭化成ケミカルズ株式会社 | Method for producing polyphenylene ether resin composition and molded body using the same |
| WO2012008006A1 (en) * | 2010-07-12 | 2012-01-19 | 三菱エンジニアリングプラスチックス株式会社 | Process for production of polyphenylene ether resin molded article |
| JP5875225B2 (en) * | 2010-12-22 | 2016-03-02 | 三菱エンジニアリングプラスチックス株式会社 | Connection structure for photovoltaic modules |
| JP5704936B2 (en) * | 2011-01-27 | 2015-04-22 | 旭化成ケミカルズ株式会社 | Heat resistant flame retardant resin composition and method for producing the same |
| US9231335B2 (en) | 2011-02-14 | 2016-01-05 | Asahi Kasei Chemicals Corporation | Connection structure for solar power generation module |
| US8653167B2 (en) * | 2011-05-26 | 2014-02-18 | Sabic Innovative Plastics Ip | Molding composition for photovoltaic junction boxes and connectors |
| WO2012176798A1 (en) | 2011-06-20 | 2012-12-27 | 旭化成ケミカルズ株式会社 | Polyphenylene ether resin composition and method for producing same |
| US8912261B2 (en) * | 2012-06-22 | 2014-12-16 | Sabic Global Technologies B.V. | Process for making particulate-free poly(phenylene ether) compositions and photovoltaic backsheet materials derived therefrom |
| JP2016110796A (en) * | 2014-12-04 | 2016-06-20 | 旭化成ケミカルズ株式会社 | Electric power feed/receive component |
| KR20170106493A (en) | 2015-04-27 | 2017-09-20 | 사빅 글로벌 테크놀러지스 비.브이. | Poly (phenylene ether) compositions and articles |
| JP6020703B2 (en) * | 2015-12-03 | 2016-11-02 | 三菱エンジニアリングプラスチックス株式会社 | Connection structure for photovoltaic modules |
| JP2018048227A (en) * | 2016-09-20 | 2018-03-29 | 旭化成株式会社 | Method for producing thermoplastic resin composition |
| JP6909568B2 (en) * | 2016-10-04 | 2021-07-28 | 旭化成株式会社 | Polyphenylene ether-based resin composition |
| JP7074121B2 (en) * | 2017-03-10 | 2022-05-24 | 日本ゼオン株式会社 | A method for producing a binder for an all-solid-state battery, a binder composition for an all-solid-state battery, and a binder composition for an all-solid-state battery. |
| JP7409900B2 (en) | 2019-04-19 | 2024-01-09 | 旭化成株式会社 | Method for producing polyphenylene ether resin composition |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4901065B2 (en) * | 2001-06-20 | 2012-03-21 | 旭化成ケミカルズ株式会社 | Thermoplastic resin composition |
| JP2005154753A (en) * | 2003-11-04 | 2005-06-16 | Asahi Kasei Chemicals Corp | Hydrogenated block copolymer and composition of the same |
| JP4684148B2 (en) * | 2005-03-29 | 2011-05-18 | 旭化成ケミカルズ株式会社 | Method for producing reinforced polyphenylene ether resin composition |
-
2007
- 2007-04-26 JP JP2007116557A patent/JP5196630B2/en active Active
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