JP2008240091A - Sintered metal component and product to which the sintered metal component is attached - Google Patents
Sintered metal component and product to which the sintered metal component is attached Download PDFInfo
- Publication number
- JP2008240091A JP2008240091A JP2007083971A JP2007083971A JP2008240091A JP 2008240091 A JP2008240091 A JP 2008240091A JP 2007083971 A JP2007083971 A JP 2007083971A JP 2007083971 A JP2007083971 A JP 2007083971A JP 2008240091 A JP2008240091 A JP 2008240091A
- Authority
- JP
- Japan
- Prior art keywords
- sintered metal
- product
- metal part
- metal
- charm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 239000002184 metal Substances 0.000 title claims abstract description 183
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- 239000000843 powder Substances 0.000 claims abstract description 23
- 239000002245 particle Substances 0.000 claims abstract description 21
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 238000005245 sintering Methods 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 239000003205 fragrance Substances 0.000 claims description 43
- 238000000034 method Methods 0.000 claims description 34
- 238000005034 decoration Methods 0.000 claims description 9
- 239000011148 porous material Substances 0.000 claims description 8
- 238000003466 welding Methods 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000011800 void material Substances 0.000 abstract description 3
- 238000005553 drilling Methods 0.000 abstract 1
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 238000005219 brazing Methods 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000007769 metal material Substances 0.000 description 5
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- 238000004519 manufacturing process Methods 0.000 description 2
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- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 description 2
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Images
Landscapes
- Adornments (AREA)
- Cosmetics (AREA)
- Powder Metallurgy (AREA)
Abstract
Description
本発明は、香料が含浸可能な焼結金属部品、およびこの焼結金属部品が取り付けられた製品に関する。さらに詳しくは、宝飾品（ジュエリー）、装身具、装飾品、日用品、置物などの室内の装飾品に取り付けて使用できる香料が含浸可能な焼結金属部品、および香料が含浸可能な焼結金属部品が取り付けられた製品に関する。 The present invention relates to a sintered metal part that can be impregnated with a fragrance and a product to which the sintered metal part is attached. More specifically, there are sintered metal parts that can be impregnated with perfumes that can be used by attaching to indoor ornaments such as jewelry (jewelry), jewelry, ornaments, daily necessities, figurines, and sintered metal parts that can be impregnated with perfumes. Related to the installed product.
ネックレス、ブレスレット、イヤリング、ピアス、指輪、タイピン、タイバーヘアクリップなどの宝飾品、装身具、室内の装飾品に適所に配置される置物には、極めて多くの種類がある。これら商品は、その商品価値を高める目的で、種々の斬新なデザインが施されている。さらに付加価値を高める目的で、香りを付与した装飾品技術が提案されている（特許文献１、特許文献２、特許文献３）。これら特許文献に記載の技術による製品は、石膏鋳型に粉末金属を充填し焼結させているので、製品の空孔部（または空隙部）を形成し、これら空孔部に香料を含浸させて、香る製品とする技術が提案されている。しかしながら、これら提案された方法によると、得られた製品の表面が粗く外観が劣る、空孔部の孔が大きくなり易いので香りの持続性（保香性）に劣る、鋳型では最大径が５ｍｍ以下の小型の製品を製造することは困難である、置物に応用することができない、などの欠点があった。
本発明は、このような状況にあって、製品の空孔率（または空隙率）を比較的高く、香料の保香性に優れ、小型の製品でも製造でき香る装飾品技術を提供することを目的として、鋭意検討した結果本発明を完成するに至ったものである。すなわち、本発明の目的は、次のとおりである。
１．空孔率（または空隙率）が高く、香料を含浸させることが可能な焼結金属部品を提供すること。
２．最大径が５ｍｍ以下の小型の製品にも適用可能で、必要がある時に焼結金属部品に香料を含浸させ、香りを放つことができる焼結金属部品を提供すること。
３．上の焼結金属部品を製品の一部に取り付け、必要がある時に焼結金属部品に香料を含浸させ、香りを放つことができる製品を提供すること。
４．香りを放つことができる焼結金属部品を一体に取り付けた、宝飾品（ジュエリー）、装身具、装飾品、日用品、置物などを提供すること。
In such a situation, the present invention is to provide a decorative article technique in which the porosity (or porosity) of a product is relatively high, the fragrance is excellent in fragrance retention, and even a small product can be manufactured. As a result, the present invention has been completed as a result of extensive studies. That is, the object of the present invention is as follows.
1. To provide a sintered metal part having a high porosity (or porosity) and capable of being impregnated with a fragrance.
2. To provide a sintered metal part that can be applied to a small product having a maximum diameter of 5 mm or less, and can impregnate a sintered metal part with a fragrance when necessary to release a scent.
3. To provide a product in which the above sintered metal part is attached to a part of the product, and when necessary, the sintered metal part can be impregnated with a fragrance to give off a scent.
4). To provide jewelry (jewelry), jewelry, ornaments, daily necessities, figurines, etc., with sintered metal parts that can be scented.
上記課題を解決するため、第１発明では、平均粒子径が１０〜２００μｍの金属粉末を、加圧・圧縮し、加熱して焼結させた、空孔率が２０〜３５％の焼結金属であって、空孔部に液状の香料が含浸可能にされてなる焼結金属部品を提供する。 In order to solve the above problems, in the first invention, a sintered metal having a porosity of 20 to 35%, which is obtained by pressurizing and compressing a metal powder having an average particle diameter of 10 to 200 μm and heating and sintering the powder. Then, a sintered metal part is provided in which the pores can be impregnated with a liquid fragrance.
また、第２発明では、製品の適所に、平均粒子径が１０〜２００μｍの金属粉末を、加圧・圧縮し、加熱して焼結させた空孔率が２０〜３５％の焼結金属部品であって、空孔部に液状の香料が含浸可能とされた焼結金属部品が取り付けられてなることを特徴とする製品を提供する。 In the second invention, a sintered metal part having a porosity of 20 to 35% obtained by pressurizing and compressing a metal powder having an average particle diameter of 10 to 200 μm and heating and sintering the product at an appropriate place. The product is characterized in that a sintered metal part that can be impregnated with a liquid perfume is attached to the pores.
本発明は、以下詳細に説明するとおりであり、次のような特別に有利な効果を奏し、その産業上の利用価値は極めて大である。
１．本発明の第一発明に係る焼結金属部品は、空孔率（または空隙率）が高く、多量の香料を含浸させることが可能で、あたかも金属が香ると認識され、しかも香りの持続性（保香性）にも優れている。
２．本発明の第一発明に係る焼結金属部品は、微細な金属粉末を焼結させており、その表面の微細な空隙は、肉眼では視認できないので、外観が美麗である。
３．本発明の第一発明に係る金属部品は、最大径が５ｍｍ以下の小型の製品にも取り付けできるので、その応用範囲は極めて大である。
４．本発明の第一発明に係る焼結金属部品は、他の製品と組み合わせて使用可能できるので、この焼結金属部品に香料を含浸させた際には、組み合された製品、例えば、宝飾品（ジュエリー）、装身具、装飾品、日用品、置物などに香りを付与することができるので、製品の商品価値を高めることができる。
５．本発明の第二発明に係る製品は、焼結金属部品に香料を含浸させた香料が完全に揮発（飛散）し、香りがなくなった場合には繰り返し香料を含浸させることができるので、商品価値が極めて高い。
The present invention is as described in detail below, has the following particularly advantageous effects, and its industrial utility value is extremely large.
1. The sintered metal part according to the first invention of the present invention has a high porosity (or porosity), can be impregnated with a large amount of fragrance, is recognized as if the metal is fragrant, and the scent persistence ( Excellent in fragrance retention.
2. The sintered metal part according to the first aspect of the present invention is formed by sintering a fine metal powder, and fine voids on the surface thereof cannot be visually recognized with the naked eye, so the appearance is beautiful.
3. Since the metal part according to the first invention of the present invention can be attached to a small product having a maximum diameter of 5 mm or less, its application range is extremely large.
4). Since the sintered metal part according to the first invention of the present invention can be used in combination with other products, when the sintered metal part is impregnated with a fragrance, the combined product, for example, jewelry. (Jewelry), accessories, ornaments, daily necessities, figurines and the like can be given fragrance, so that the product value of the product can be increased.
5. The product according to the second invention of the present invention is a commercial value because the perfume impregnated with the sintered metal part is completely volatilized (scattered) and the perfume can be repeatedly impregnated when the scent disappears. Is extremely high.
以下、本発明を詳細に説明する。本発明の第一発明に係る、焼結金属部品は、微細な粒子状金属を焼結させたものであって、粒子間に生じる空隙部（空孔部）に液状の香料を保持するように機能する。焼結金属部品として使用される金属としては、鉄、鉄を主成分とし他の成分との合金が挙げられる。鉄と合金ができる成分としては、例えば、炭素、珪素、クロム、マンガン、ニッケル、タングステンなどとの合金が挙げられる。非鉄金属としては、マグネシウム、アルミニウム、チタン、バナジウム、クロム、マンガン、コバルト、ニッケル、銅、亜鉛、ガリウム、ゲルマニウム、砒素、セレン、ジルコニウム、ニオビウム、モリブデン、ロジウム、パラジウム、銀、カドミウム、インジウム、スズ、アンチモン、テルル、タンタル、タングステン、白金、金、イリジウム、鉛、およびこれら金属の合金が挙げられる。本発明に係る焼結金属部品が調製できる金属は、上に例示したものに限定されるものではない。 Hereinafter, the present invention will be described in detail. The sintered metal part according to the first aspect of the present invention is obtained by sintering fine particulate metal so that a liquid fragrance is held in a void portion (hole portion) generated between particles. Function. Examples of the metal used as the sintered metal part include iron, an alloy containing iron as a main component and other components. Examples of components that can be alloyed with iron include alloys with carbon, silicon, chromium, manganese, nickel, tungsten, and the like. Non-ferrous metals include magnesium, aluminum, titanium, vanadium, chromium, manganese, cobalt, nickel, copper, zinc, gallium, germanium, arsenic, selenium, zirconium, niobium, molybdenum, rhodium, palladium, silver, cadmium, indium, tin , Antimony, tellurium, tantalum, tungsten, platinum, gold, iridium, lead, and alloys of these metals. The metal from which the sintered metal part according to the present invention can be prepared is not limited to those exemplified above.
微細な粒子状金属の平均粒子径は、１０〜２００μｍの範囲のものが好ましい。平均粒子径が１０μｍ未満であると、空孔部（空隙部）を高めることが困難となり、香料を含浸させ難くなる。平均粒子径が２００μｍを超えると、粒子間に生じる個々の空孔部が大きくなり、含浸させた液状の香料が飛散し易く、香料の保香性が劣る。焼結金属の平均粒子径は、ＪＩＳ標準ふるい（ＪＩＳ Ｚ８８０１）を使用して分級することができる。また、完成した焼結金属部品の平均粒子径は、その表面を顕微鏡で観察することによって確認することができる。 The average particle diameter of the fine particulate metal is preferably in the range of 10 to 200 μm. When the average particle size is less than 10 μm, it is difficult to increase the pores (voids) and it is difficult to impregnate the fragrance. When the average particle diameter exceeds 200 μm, the individual pores generated between the particles become large, the impregnated liquid fragrance is likely to be scattered, and the fragrance is poor in fragrance retention. The average particle diameter of the sintered metal can be classified using a JIS standard sieve (JIS Z8801). Moreover, the average particle diameter of the completed sintered metal part can be confirmed by observing the surface with a microscope.
焼結金属部品の空孔率（空隙率）は、粒子状金属の平均粒子径により変わるが、２０〜３５％の範囲で選ぶものとする。空孔率が２０％未満であると、含浸させることができる液状香料が少なく、芳香の持続性（保香性）に劣る。空孔率が３５％を超えると、この空孔率のものを製造するのが困難となる。より好ましい空孔率は、２５〜３５％である。空孔率は、粒子状金属の平均粒子径、加熱温度、加圧の有無などによって調節することができる。空孔率は、次式すなわち、｛（焼結金属部品の重さ）／（焼結金属部品と同じ体積の同種金属の重さ）｝×１００、によって計算することができる。 The porosity (porosity) of the sintered metal part varies depending on the average particle diameter of the particulate metal, but is selected in the range of 20 to 35%. When the porosity is less than 20%, there are few liquid fragrances that can be impregnated, and the fragrance sustainability (fragrance retention) is poor. If the porosity exceeds 35%, it becomes difficult to produce a product having this porosity. A more preferable porosity is 25 to 35%. The porosity can be adjusted by the average particle diameter of the particulate metal, the heating temperature, the presence or absence of pressurization, and the like. The porosity can be calculated by the following formula: {(weight of sintered metal part) / (weight of the same type of metal of the same volume as the sintered metal part)} × 100.
本発明の第一発明に係る焼結金属部品は、次の方法で製造される。まず、金属微粉末を型に入れ、押圧して微粉末粒子同士を密着させる。押圧する際の圧力は、金属の種類、粒子の平均粒子径によって異なり、５０Ｐａ〜１０００ＭＰａの範囲で選ぶことができる。焼結金属部品を取り付ける製品が金属材料よりなるときは、この金属材料製品の適所に穿設した孔を型とすることもできる。金属微粉末を入れる型は、製造しようとする焼結金属部品に応じて、最小径が１．０ｍｍ、最大径が２０ｍｍの範囲で選ぶことができる。最小径が１．０ｍｍ未満であると、含浸させる香料が制限され、保香性が劣るので好ましくない。金属微粉末を入れる型の平面形状は、円形、楕円形、多角形、星型、＋（プラス）型、十字（クロス）型、魚型、動物型、動物の角型、昆虫型、花びら型、木の葉型、などが挙げられる。金属微粉末を入れる型の深さ（外観が板状を呈する部品では厚さ）は、上記最小径の寸法、焼結金属部品の用途などに応じて、１．０ｍｍ〜１５ｍｍの範囲で選ぶことができる。型の深さが１．０ｍｍ未満であると、含浸させる香料が制限され、香りの持続性が劣るので好ましくない。型の深さが１５ｍｍを超えると、金属微粉末を均一に焼結することが困難となるので好ましくない。 The sintered metal part according to the first aspect of the present invention is manufactured by the following method. First, the metal fine powder is put into a mold and pressed to bring the fine powder particles into close contact with each other. The pressure at the time of pressing varies depending on the type of metal and the average particle diameter of the particles, and can be selected in the range of 50 Pa to 1000 MPa. When the product to which the sintered metal part is to be attached is made of a metal material, a hole drilled at an appropriate position of the metal material product can be used as a mold. The mold into which the metal fine powder is put can be selected in a range of a minimum diameter of 1.0 mm and a maximum diameter of 20 mm according to the sintered metal part to be manufactured. If the minimum diameter is less than 1.0 mm, the perfume to be impregnated is limited, and the aroma retaining property is inferior. The planar shape of the metal powder is circular, oval, polygonal, star, + (plus), cross (cross), fish, animal, animal horn, insect, and petal. , Leaf type, and the like. The depth of the mold that contains the metal fine powder (thickness for parts that have a plate-like appearance) should be selected in the range of 1.0 mm to 15 mm, depending on the minimum diameter, the use of sintered metal parts, etc. Can do. If the depth of the mold is less than 1.0 mm, the perfume to be impregnated is limited, and the sustainability of the scent is inferior. If the depth of the mold exceeds 15 mm, it is difficult to uniformly sinter the metal fine powder, which is not preferable.
焼結金属部品を製造する際には、ついで、粒子状金属の粒子表面が溶融する温度以上の温度に加熱する。加熱温度は、粒子状金属の溶融温度に応じて適温を選ぶものとする。加熱方法は、（１）型から取り出した粒子状金属を、例えば、金属の融点以上の一定温度に維持するように設定した電気炉、または、経過時間とともに温度が変化するタイムスケジュールを設定した電気炉に入れて加熱する方法、（２）型から取り出した粒子状金属を、一定温度に設定した加熱ゾーンを有する加熱炉内、または、温度傾斜を設けて設定した加熱ゾーンを有する加熱炉内を移動させて加熱する方法、（３）型が金属材料製の製品よりなるときは、型に金属微粉末を充填した状態で焼結工程に付し、金属微粉末の焼結と金属材料製品よりなる型とを溶着する方法、などが挙げられる。加熱時間は、粒子状金属の溶融温度と電気炉、加熱ゾーンの設定温度、移動速度に応じて選ぶことができる。得られた焼結金属部品は、使用時に空気中の酸素などとの化学反応によって表面が変色し易い金属製のものは、焼結金属部品表面の微細孔を塞がないようにして、塗布膜を形成するのが好ましい。 When manufacturing a sintered metal part, it is then heated to a temperature equal to or higher than the temperature at which the particle surface of the particulate metal melts. As the heating temperature, an appropriate temperature is selected according to the melting temperature of the particulate metal. The heating method is (1) for example, an electric furnace set to maintain the particulate metal taken out from the mold at a constant temperature equal to or higher than the melting point of the metal, or an electric set with a time schedule in which the temperature changes with time. (2) In a heating furnace having a heating zone in which a particulate metal taken out from the mold is set to a constant temperature, or in a heating furnace having a heating zone set by providing a temperature gradient Method of moving and heating (3) When the mold is made of a metal material product, it is subjected to a sintering process with the metal powder filled in the mold. And the like, and the like. The heating time can be selected according to the melting temperature of the particulate metal, the electric furnace, the set temperature of the heating zone, and the moving speed. The obtained sintered metal part is made of a metal whose surface is likely to be discolored by chemical reaction with oxygen in the air during use. Is preferably formed.
塗布膜は、（１）焼結金属部品にメッキする方法、（２）焼結金属部品を適切な金属を溶解した溶液に浸漬、塗布、噴霧などの方法により薄膜を形成し、溶媒を飛散させる方法などによればよい。塗布膜を形成する金属の種類は、焼結金属部品の金属の種類、この焼結金属部品を取り付ける製品の金属の種類に応じて、適切な種類を選択すればよく、メッキする金属、溶液に溶解した液に浸漬、塗布、噴霧する金属を選ぶことができる。金属を溶解した溶液の濃度は、焼結金属部品の表面に形成しようとする薄膜の厚さに応じて、適宜変えることができる。 The coating film is formed by (1) a method of plating on a sintered metal part, (2) a thin film is formed by immersing, coating, spraying, etc. the sintered metal part in a solution in which an appropriate metal is dissolved, and the solvent is scattered. The method may be used. The type of metal that forms the coating film can be selected according to the type of metal of the sintered metal part and the type of metal of the product to which the sintered metal part is attached. The metal to be immersed, applied and sprayed in the dissolved liquid can be selected. The concentration of the solution in which the metal is dissolved can be appropriately changed according to the thickness of the thin film to be formed on the surface of the sintered metal part.
本発明の第一発明に係る焼結金属部品は、単独で使用されることはまれで、通常は他の製品に取り付けられて使用される。本発明において取り付けるとは、（イ）上記（３）の方法で金属微粉末の焼結と、金属製品製型との溶着を同時に行う方法、（ロ）あらかじめ作製した焼結金属部品を、製品の壁面に埋め込み固定する方法、（ハ）あらかじめ作製した焼結金属部品を、金属製製品の外側壁面に溶着またはロウ付けする方法、（ニ）あらかじめ作製した焼結金属部品を、製品の壁面に単に載置する方法、などが挙げられる。上記（ロ）ないし（ニ）の方法で取り付ける場合に必要があれば、焼結金属部品を切削加工して、大きさや形状を調整することができる。 The sintered metal part according to the first aspect of the present invention is rarely used alone, and is usually used by being attached to another product. Mounting in the present invention means (a) a method of simultaneously sintering metal fine powder and welding with a metal product mold by the above method (3), and (b) a sintered metal part produced in advance. (C) A method of welding or brazing a pre-fabricated sintered metal part to the outer wall surface of a metal product, (d) A pre-manufactured sintered metal part on the wall surface of the product For example, a method of simply placing it. If necessary in the case of attaching by the above methods (b) to (d), the sintered metal part can be cut to adjust the size and shape.
焼結金属部品を製品に取り付ける例を挙げると、製品が、後記する図１に斜視図として示したペンダントやぬいぐるみに飾る平面形状が十字（クロス）型を呈する小型チャーム（飾り）の場合は、上記（イ）の方法や、上記（ロ）の方法によることができるし、さらに、上記（ハ）の方法により、平面形状が十字（クロス）型を呈する小型チャームの交差部分に、平面形状が星形の焼結金属部品を、溶着またはロウ付けする方法も挙げられる。製品がライターの場合は、適度の大きさの五角形、六角形などの多角形、星型、楕円形などの焼結金属部品を、上記（ロ）の方法によってライターの外壁の適所に埋め込み固定する方法、上記（ハ）の方法によってライターの外壁の適所に溶着またはロウ付けする方法が挙げられる。製品が後記する図２に示した飾り（チャーム）の場合は、その表面または裏面に、上記（イ）ないし（ハ）の方法で取り付けることができる。製品が卓上ライターまたは置時計の場合は、これら製品の台座または壁面の適所に窪みを設け、この窪みに焼結金属部品を単に嵌合させる方法が挙げられる。 As an example of attaching a sintered metal part to a product, if the product is a small charm (decoration) in which the planar shape of the pendant or stuffed animal shown in FIG. According to the method (b) or (b) above, and the method (c) above, the plane shape is formed at the intersection of small charms having a cross shape of the plane shape. There is also a method of welding or brazing a star-shaped sintered metal part. If the product is a lighter, sinter metal parts such as pentagons, hexagons, etc. of appropriate size, star shapes, ellipses, etc. are embedded and fixed in place on the outer wall of the lighter by the method (b) above. And a method of welding or brazing to an appropriate position on the outer wall of the lighter by the method (c). In the case where the product is a decoration (charm) shown in FIG. 2 to be described later, it can be attached to the front surface or the back surface by the methods (a) to (c). In the case where the product is a table lighter or table clock, there is a method in which a recess is provided at an appropriate position on the base or wall surface of these products, and a sintered metal part is simply fitted into the recess.
本発明の第一発明に係る金属部品は、種々の製品に取り付けられる。金属部品が適用できる製品の材料（素材）は特に限定されるものではなく、金属製、木材製、合成樹脂製、皮革製、繊維製、およびこれらを組み合わせたものなどが挙げられる。製品としては、宝飾品（ジュエリー）、装身具、装飾品、置物などの室内の装飾品が挙げられる。宝飾品、装身具、装飾品の具体例としては、イヤリング類（ドロップイアリング、クリップ式イヤリング、ネジ式イヤリング、ピアスなど）、ネックレス類（各種ネックレス、ペンダント、ロケット、ドッグカラーなど）、ブレスレット類（ネームブレスレット、チャームブレスレット、バングルなど）、チャーム（飾り）類（ネームプレート、蹄鉄形チャーム、角形チャーム、ハート型チャーム、十字型チャーム、魚型チャーム、動物型チャーム、動物の角型チャーム、昆虫型チャーム、花びら型チャーム、木の葉型チャームなど）、指輪類（シグネットリング、バンド型リング、クラスリング、ソリテール型リング、結婚指輪、婚約指輪など）、ピン類（ブローチ、スチックピン、タイピン、カラーバー、タイバーなど）、ヘアピン、ヘアクリップ、髪どめ、名刺入れ、財布、札入れ、小銭入れ、カードケース、キーホルダー、メガネ、ライター、携帯電話、腕時計バンド、各種ストラップ、ジッパー、ブーツ、靴、バンド、ハンドバッグなどの各種バッグ、ポーチ、根付けなどが挙げられる。室内の装飾品としては、卓上ライター、卓上灰皿、花瓶、写真たて、オルゴール、宝石箱、各種トレイ、地球儀、電話台、ラジオ、テレビジョンなどが挙げられる。これらの他、自動車のステアリングホイール、ダッシュボードなどの内装品のほか、各種標章・紋章（エンブレム）、各種マグネット、カフスボタンなどの各種ボタン、各種ラベル、各種組みひも、スプーンなどの日用品が挙げられる。本発明に係る焼結金属部品が適用できる製品は、上に例示したものに限定されるものではない。 The metal component according to the first aspect of the present invention is attached to various products. The material (material) of the product to which the metal part can be applied is not particularly limited, and examples thereof include metal, wood, synthetic resin, leather, fiber, and combinations thereof. Examples of the products include indoor ornaments such as jewelry (jewelry), jewelry, ornaments, and ornaments. Specific examples of jewelry, jewelry, and ornaments include earrings (drop earrings, clip earrings, screw earrings, earrings, etc.), necklaces (various necklaces, pendants, rockets, dog collars, etc.), bracelets (names) Bracelet, charm bracelet, bangle, etc., charm (name plate, horseshoe-shaped charm, square charm, heart-shaped charm, cross-shaped charm, fish-shaped charm, animal-shaped charm, animal-shaped charm, insect-shaped charm) , Petal-type charm, leaf-type charm, etc.), rings (signet ring, band-type ring, class ring, solitaire-type ring, wedding ring, engagement ring, etc.), pins (brooch, stick pin, tie pin, color bar, tie bar, etc.) ), Hairpin, f Clips, hair holders, business card holders, wallets, wallets, coin purses, card cases, key chains, glasses, lighters, mobile phones, watch bands, various straps, zippers, boots, shoes, bands, handbags, various bags, pouches, Netsuke etc. are mentioned. Interior decorations include desk lighters, desk ashtrays, vases, photo frames, music boxes, jewelry boxes, various trays, globes, telephone stands, radios, televisions and more. In addition to these, interior items such as automobile steering wheels and dashboards, various marks and emblems, various magnets, various buttons such as cuff links, various labels, various braids, spoons and other daily necessities are listed. It is done. The products to which the sintered metal part according to the present invention can be applied are not limited to those exemplified above.
本発明の第一発明に係る焼結金属部品の製品への取り付けには、取り付ける製品（対象物）の種類、材料（素材）などにより適宜選ぶことができる。製品が金属製、木材製、合成樹脂製、皮革製の場合は、製品の壁面に埋め込んだり、製品の外側壁面に付着させたりすることができる。製品がライターの場合は、前記したとおり、外壁の適所に付着す方法、製品がオルゴール場合は蓋または外壁の適所に埋め込む方法、付着する方法、製品が繊維、織布、組みひもなど場合は、ストラップで金属部品を取り付けたチャーム（飾り）を吊下げる方法、ぬいぐるみの場合は目や鼻に埋め込んだり、ストラップで金属部品を取り付けたチャームを吊下げたりする方法、製品が自動車のステアリングホイールの場合は、ホイールの適所に取り付ける方法などによることができる。 The attachment of the sintered metal part according to the first aspect of the present invention to the product can be appropriately selected depending on the type of the product (object) to be attached, the material (raw material), and the like. When the product is made of metal, wood, synthetic resin, or leather, it can be embedded in the wall surface of the product or attached to the outer wall surface of the product. When the product is a lighter, as described above, the method of attaching to the appropriate position on the outer wall, the method of embedding in the appropriate position of the lid or outer wall when the product is music box, the method of attaching, the case where the product is fiber, woven fabric, braid, etc. How to hang a charm with metal parts attached with a strap, how to embed it in the eyes or nose if it is a stuffed toy, or how to hang a charm with metal parts attached with a strap, or when the product is a steering wheel of an automobile This can be done by attaching the wheel in place.
製品に焼結金属部品を埋め込む場合は、前記（イ）として記載したとおり、製品が金属材料よりなるときは、金属製製品に穿設した孔に金属微粉末を充填し、焼結と溶着とを同時に行うことができる。この手順を採用しない場合は、まず、製品の適所に孔を穿つ。この孔は、貫通孔でも、単なる窪みであってもよい。製品に孔を穿つ場所は、使用時に香りを効果的に感知できる場所を選ぶのが好ましい。例えば、クリップ式イヤリングにあっては金属性クリップの適所に、ペンダント型ネックレスにあってはペンダントの適所に、チャームブレスレットにあってはチャームの一個、または長い鎖を構成する鎖の一単位に、腕時計のバンドも長い鎖を構成する鎖の一単位とするのが好適である。孔の大きさ、形状、深さなどは特に制約はなく、焼結金属部品を嵌合することができればよく、焼結金属部品の大きさ、形状、厚さなどにより、適宜決定するのがよい。次いで、この孔に第一発明に係る焼結金属部品を取り付ける。 When embedding a sintered metal part in a product, as described in (a) above, if the product is made of a metal material, fill the holes drilled in the metal product with metal fine powder, sintering and welding, Can be performed simultaneously. If this procedure is not used, first make a hole in place in the product. This hole may be a through hole or a simple depression. The location where the product is perforated is preferably selected so that the scent can be sensed effectively during use. For example, in the case of clip-type earrings, in the proper place of metallic clips, in the case of pendant necklaces, in the proper place of pendants, in the case of charm bracelets, one piece of charm, or one unit of chain constituting a long chain, The wristwatch band is also preferably a unit of a chain constituting a long chain. There are no particular restrictions on the size, shape, depth, etc. of the hole, as long as the sintered metal part can be fitted, and it is appropriate to determine it appropriately according to the size, shape, thickness, etc. of the sintered metal part. . Next, the sintered metal part according to the first invention is attached to the hole.
焼結金属部品を埋め込む製品が金属材料よりなるものである場合の金属は、焼結金属部品用金属として例示したものから選ぶことができる。この際の金属製品および焼結金属部品を構成する金属は、双方の金属の融点差が、０〜５０℃の範囲内にあるもので組み合わせるのが好ましい。これは、双方の金属の融点差が小さいほど、双方の金属界面がほぼ同じ温度で溶融され、金属界面が好ましく溶着されるからである。金属製品および焼結金属部品を構成する金属を同種の金属によって構成すると、界面が一層好ましく溶着される。また、金属製品の双方の金属を、ロウ付けによって取り付ける際には、当該金属専用のロウ付けを行なうと、界面が一層好ましく溶着され、仕上げ製品を薬品で洗浄しても界面にロウ付け線が現れることもなく、好ましい。また、双方の金属を同種の貴金属によって構成すると、商品価値が高まりとりわけ好適である。 When the product in which the sintered metal part is embedded is made of a metal material, the metal can be selected from those exemplified as the metal for the sintered metal part. In this case, the metal product and the metal constituting the sintered metal part are preferably combined in such a way that the difference in melting point between the two metals is in the range of 0 to 50 ° C. This is because the smaller the melting point difference between the two metals, the more the both metal interfaces are melted at substantially the same temperature, and the metal interfaces are preferably welded. When the metal composing the metal product and the sintered metal part is composed of the same kind of metal, the interface is more preferably welded. In addition, when both metals of a metal product are attached by brazing, if the brazing dedicated to the metal is performed, the interface is more preferably welded, and even if the finished product is cleaned with chemicals, the brazing line is present at the interface. It does not appear and is preferable. Moreover, when both metals are comprised with the same kind of noble metal, the commercial value increases and it is particularly suitable.
第一発明に係る焼結金属部品を取り付けた製品には、焼結金属部品に香料を含浸させる。焼結金属部品に含浸させることができる香料は、匂い分子が鼻の受容細胞に達し、そこで相互作用を起こし、匂いを嗅いだ際に快感や癒し感を与えるものをいう。香料は天然香料でも合成香料でもよく、発散性香料薬であってもよい。通常は、複素の香料を組み合わせて使用される。発散性香料薬は、匂いを発散しこれを吸い込むことによって薬効がある香料をいう。香料の中でも、市販されているオードトワレ、オードパーヒューム、オーデコロンなどの香水の中から選び、使用することができる。 In the product to which the sintered metal part according to the first invention is attached, the sintered metal part is impregnated with a fragrance. Perfumes that can be impregnated into sintered metal parts are those in which odor molecules reach nasal receptor cells where they interact and give a pleasant or healing sensation when they smell. The fragrance may be a natural fragrance or a synthetic fragrance, and may be a divergent fragrance drug. Usually, complex fragrances are used in combination. A divergent fragrance medicine refers to a fragrance that has a medicinal effect by releasing an odor and inhaling it. Among the fragrances, it is possible to select from perfume such as eau de toilette, eau de perfume, and eau de cologne that are commercially available.
合成香料の代表的なものとして次のような化合物が挙げられるが、合成香料は、以下に例示したものに限定されるものではない。６−アセチル−１，１，２，４，４，７−ヘキサメチルテトラヒドロナフタリン、アミルシンナミックアルデヒド、安息香酸ベンジル、イソオイゲノール、イソカンフィルシクロヘキサノール、イソ吉草酸エチル、イソチオシアン酸アリル、イロン、γ−ウンデカラクトン、ウンデシルアルデヒド、エチルバニリン、エチレンドデカンジオエート、エチレンブラシレート、１０−オキサヘキサデカノリド、カプロン酸エチル、ガラクソリド、Ｌ−カルボン、ギ酸ゲラニル、ギ酸シトロネリル、ケイ皮アルコール、ケイ皮酸エチル、ゲラニオール、酢酸イソオイゲノール、酢酸シトロネリル、酢酸シンナミル、酢酸ジヒドロテルピニル、酢酸ジメチルベンジルカルビニル、酢酸テルビウム、酢酸トリシクロデセニル、酢酸ブチルシクロヘキシル、酢酸ベンジル、サリチル酸イソアミル、サリチル酸ベンジル、サリチル酸メチルなどが挙げられる。 Although the following compounds are mentioned as a typical thing of a synthetic | combination fragrance | flavor, A synthetic | combination fragrance | flavor is not limited to what was illustrated below. 6-acetyl-1,1,2,4,4,7-hexamethyltetrahydronaphthalene, amylcinnamic aldehyde, benzyl benzoate, isoeugenol, isocamphylcyclohexanol, ethyl isovalerate, allyl isothiocyanate, Iron, γ-undecalactone, undecylaldehyde, ethyl vanillin, ethylene dodecanedioate, ethylene brushate, 10-oxahexadecanolide, ethyl caproate, galaxolide, L-carvone, geranyl formate, citronellyl formate, cinnamic alcohol, Ethyl cinnamate, geraniol, isoeugenol acetate, citronellyl acetate, cinnamyl acetate, dihydroterpinyl acetate, dimethylbenzylcarbvinyl acetate, terbium acetate, tricyclodecenyl acetate, butylcyclohexyl acetate Benzyl acetate, isoamyl salicylate, benzyl salicylate, and the like methyl salicylate.
さらに、シクラメンアルデヒド、シクロペンタンデカノリド、シス−ジャスモン、シス−ヘキセノール、シトラール、シトロネラール、シトロネロール、ジヒドロジュアスミン酸メチル、ジヒドロジャスモン、ジメチルベンジルカルビノール、３，４−ジメトキシベンズアルデヒド、ジャスミンラクトン、デシルアルデヒド、テトラヒドロリナロール、テルピネオール、β−ナフチルエチルエーテル、β−ナフチルメチルエーテル、ノナラクトン、バニリン、ヒドロキシシトロネラール、４（３）−（４−ヒドロキシ−４−メチルペンチル）−３−シクロヘキセン−１−カルボキシアルデヒド、フェニルアセトアルデヒド、β−フェニルエチルアルコール、フェニル酢酸エチル、ｐ−ｔ−ブチル−α−メチルヒドロシンナミックアルデヒド、プロピオン酸イソアミル、プロピオン酸エチル、プロピオン酸ベンジル、ヘキシルシンナミックアルデヒド、ヘリオトロピン、ボルネオール、マルトール、ｐ−メチルアセトフェノン、Ｎ−メチルアントラニル酸メチル、ｐ−メチルフェニルアセトアルデヒド、メチルフェニルグリシッド酸エチル、メチルヨノン、Ｌ−メントール、α−ヨノン、酪酸、酪酸イソアミル、酪酸イソプロピル、酪酸エチル、酪酸ブチル、リナロール、リモネンおよびジペンテン、ローズフェノン、ロジンノールなどが挙げられる。 Furthermore, cyclamenaldehyde, cyclopentanedecanolide, cis-jasmon, cis-hexenol, citral, citronellal, citronellol, methyl dihydrojuasmate, dihydrojasmon, dimethylbenzylcarbinol, 3,4-dimethoxybenzaldehyde, jasmine lactone, decyl Aldehyde, tetrahydrolinalol, terpineol, β-naphthylethyl ether, β-naphthylmethyl ether, nonalactone, vanillin, hydroxycitronellal, 4 (3)-(4-hydroxy-4-methylpentyl) -3-cyclohexene-1- Carboxaldehyde, phenylacetaldehyde, β-phenylethyl alcohol, ethyl phenylacetate, pt-butyl-α-methylhydrocinnamic aldehyde, Isoamyl pionate, ethyl propionate, benzyl propionate, hexylcinnamic aldehyde, heliotropin, borneol, maltol, p-methylacetophenone, methyl N-methylanthranilate, p-methylphenylacetaldehyde, ethyl methylphenylglycidate, methylionone , L-menthol, α-ionone, butyric acid, isoamyl butyrate, isopropyl butyrate, ethyl butyrate, butyl butyrate, linalool, limonene and dipentene, rosephenone, rosinol and the like.
香料は、上記のとおり、複数のものを組み合わせて使用される。香料は、アルコール類、その他有機溶媒（混合物であってもよい）や水に溶解または分散させ、界面活性剤を加えて液状香料の表面張力を小さくして使用するのが好ましい。金属部品に含浸させるには、スプレー法、滴下法、ディッピング法などによることができる。香料は、常時香料を含浸させておく必要はなく、必要がある時に焼結金属部品に含浸させるのが好ましい。焼結金属部品に繰り返し含浸させることによって、香る焼結金属部品として長期間使用可能である。 A fragrance | flavor is used combining a plurality of things as above-mentioned. The fragrance is preferably used by dissolving or dispersing it in alcohols, other organic solvents (may be a mixture) or water, and adding a surfactant to reduce the surface tension of the liquid fragrance. In order to impregnate metal parts, a spray method, a dropping method, a dipping method, or the like can be used. The fragrance does not always need to be impregnated with the fragrance, and is preferably impregnated into the sintered metal part when necessary. By repeatedly impregnating the sintered metal part, it can be used for a long time as a fragrant sintered metal part.
以下、本発明を図面に基づいてさらに詳細に説明するが、本発明はその要旨を超えない限り、以下に記載した例に制限されるものではない。 Hereinafter, the present invention will be described in more detail with reference to the drawings. However, the present invention is not limited to the examples described below unless the gist of the present invention is exceeded.
以下、本発明を図面に基づいて説明する。図1は、ネックレスに平面形状が十字型チャームを取り付けた例であり、図２は十字型チャームの他の例の正面図であり、図３はチャーム（飾り）の例の斜視図であり、表面または裏面の適所に、焼結金属が貼り付け、これに香水を含浸させる。図４はチャームブレスレットの一例の正面図であり、このチャームの表面または裏面の適所に貼り付け、これに香水を含浸させることができる焼結金属であり、この焼結金属の厚さや大きさは、これを貼り付ける製品の大きさに応じて選ぶことができることは、前記したとおりである。図５は、金属枠に金属微粉末を充填した状態で焼結工程に付した焼結金属体の一例の正面図であり、図６は、金属枠に金属微粉末を充填した状態で焼結工程に付した焼結金属体の他の例の正面図である。 Hereinafter, the present invention will be described with reference to the drawings. FIG. 1 is an example in which a cross-shaped charm is attached to a necklace, FIG. 2 is a front view of another example of the cross-shaped charm, and FIG. 3 is a perspective view of an example of a charm (decoration). Sintered metal is affixed to a suitable place on the front or back surface and impregnated with perfume. FIG. 4 is a front view of an example of a charm bracelet, which is a sintered metal that can be attached to an appropriate position on the front or back surface of the charm and impregnated with perfume. The thickness and size of the sintered metal are as follows: As described above, it can be selected according to the size of the product to which this is applied. FIG. 5 is a front view of an example of a sintered metal body subjected to a sintering process in a state where the metal frame is filled with the metal fine powder, and FIG. 6 is a sintered state where the metal frame is filled with the metal fine powder. It is a front view of the other example of the sintered metal body attached | subjected to the process.
次に、本発明に係る焼結金属に香水を含浸させた例を説明する。図１において、十字型チャーム２は、銀（融点：９６２℃）よりなり、短軸３の長さが６．５ｍｍ、長軸４の長さが１３ｍｍ、軸の幅が２．５ｍｍ、厚さが１．２ｍｍの大きさである。この十字チャームの短軸、長軸には、図１に示したように、十字型チャーム２には、焼結金属部品５を形成する十字型の貫通孔を穿設した。この貫通孔に、平均粒子径が３０μｍの銀の粉末を充填し、９６０℃で３時間加熱して、銀の微粉末を焼結させて焼結金属部品５とし、同時にこの焼結金属部品５を十字型チャーム２に溶着させた。焼結金属部品５の空孔率は、３０％であった。得られた十字型チャーム２の焼結金属部品５に、図１に示したように、噴霧器６によって香水（シャネル社製、商品名：シャネル＃５）を噴霧法によって含浸させて、香る十字型チャーム２を得た。このチャームの香水の保香期間は、約３０日間だった。
Next, an example in which perfume is impregnated into the sintered metal according to the present invention will be described. In FIG. 1, the cross-shaped charm 2 is made of silver (melting point: 962 ° C.), the length of the
上記十字型チャーム２にオードトワレ（エスカーダ社製、商品名：センチメントフォーメン）を噴霧法によって含浸させて、香る十字型チャーム２を得た。このチャームの香水の保香期間は、約４週間だった。 The cross-shaped charm 2 was impregnated with Eau De Toilette (trade name: Sentiment For Men, manufactured by Escada Co., Ltd.) by a spraying method to obtain a fragrant cross-shaped charm 2. The charming period of this perfume was about 4 weeks.
上記十字型チャーム２に香水（ニコス社製、商品名：スカルプチャーオム）を噴霧法によって含浸させて、香る十字型チャーム２を得た。このチャームの香水の保香期間は、約１０日間であった。 The cross-shaped charm 2 was impregnated with perfume (manufactured by Nicos, trade name: sculpture homme) by a spray method to obtain a fragrant cross-shaped charm 2. The perfume retention period for this charm was about 10 days.
図２は、十字型チャームの他の例の正面図であり、図２において８は外枠、９は焼結金属部品で、個の部分に香水を含浸させることができる。図３は、チャームブレスレットの一例の正面図であり、図３において、（ａ）はネームプレート型、（ｂ）は蹄鉄型、（ｃ）は角型のチャーム（飾り）の例の斜視図である。これらチャームの表側または裏側の適所に、金属部品を埋め込みまたは貼り付け、これに香料を含浸させて香る金属部品とすることができる。図４に示した製品では、チャームブレスレット８を構成する鎖の一単位、または、チャーム９に金属部品を埋め込み、これに香料を含浸させて香る金属部品とすることができる。
FIG. 2 is a front view of another example of a cross-shaped charm. In FIG. 2, 8 is an outer frame, 9 is a sintered metal part, and perfume can be impregnated into individual parts. 3 is a front view of an example of a charm bracelet. In FIG. 3, (a) is a name plate type, (b) is a horseshoe type, and (c) is a perspective view of an example of a square type charm (decoration). is there. Metal parts can be embedded in or pasted at appropriate positions on the front side or back side of these charms and impregnated with a fragrance to form a fragrant metal part. In the product shown in FIG. 4, a metal part can be obtained by embedding a metal part in one unit of a chain constituting the
図５は、銀製の楕円形の金属枠１５（長径２５ｍｍ、幅１２ｍｍ、厚さ１．２ｍｍ）であって、表面側に凹状窪み１６を設けて外観がゼブラの模様１７を形成した。凹状窪み１６に平均粒子径が３０μｍの銀の粉末を充填し、９６０℃で３時間加熱して、銀の微粉末を焼結させて焼結金属部分を形成した。この凹状窪み１７の焼結金属部分に、香水（エスカーダ社製、商品名：センチメントメンズ）を噴霧法によって含浸させて、香るゼブラ状プレートを得た。このプレートの保香期間は、約３０日間であった。
FIG. 5 shows a silver oval metal frame 15 (major axis 25 mm,
図６は、銀製の楕円形の金属枠１８（長径２５ｍｍ、幅１２ｍｍ、厚さ１．２ｍｍ）であって、表面側に凹状窪み１９を形成したリザード（鰐の皮）の模様２０を形成した。凹状窪み１９に平均粒子径が３０μｍの銀の粉末を充填し、９６０℃で３時間加熱して、銀の微粉末を焼結させて焼結金属部分１８を形成した。この焼結金属部分１８に、香水（ニコス社製、商品名：ニコスフォーメン）を噴霧法によって含浸させて、香るゼブラ状プレートを得た。このプレートの保香期間は、約３０日間であった。
FIG. 6 shows a silver oval metal frame 18 (long diameter 25 mm,
本発明に係る焼結金属部品は、本発明の第一発明に係る金属部品は、種々の製品に取り付けられる。金属部品が適用できる製品の材料（素材）は特に限定されるものではなく、金属製、木材製、合成樹脂製、皮革製、繊維製、およびこれらを組み合わせたものなどが挙げられる。製品としては、宝飾品（ジュエリー）、装身具、装飾品、置物などの室内の装飾品が挙げられる。宝飾品、装身具、装飾品の具体例としては、イヤリング類（ドロップイアリング、クリップ式イヤリング、ネジ式イヤリング、ピアスなど）、ネックレス類（各種ネックレス、ペンダント、ロケット、ドッグカラーなど）、ブレスレット類（ネームブレスレット、チャームブレスレット、バングルなど）、チャーム（飾り）類（ネームプレート、蹄鉄形チャーム、角形チャーム、ハート型チャーム、十字型チャーム、魚型チャーム、動物型チャーム、動物の角型チャーム、昆虫型チャーム、花びら型チャーム、木の葉型チャームなど）、指輪類（シグネットリング、バンド型リング、クラスリング、ソリテール型リング、結婚指輪、婚約指輪など）、ピン類（ブローチ、スチックピン、タイピン、カラーバー、タイバーなど）、ヘアピン、ヘアクリップ、髪どめ、名刺入れ、財布、札入れ、小銭入れ、カードケース、キーホルダー、メガネ、ライター、携帯電話、腕時計バンド、各種ストラップ、ジッパー、ブーツ、靴、バンド、ハンドバッグなどの各種バッグ、ポーチ、根付けなどが挙げられる。室内の装飾品としては、卓上ライター、卓上灰皿、花瓶、写真たて、オルゴール、宝石箱、各種トレイ、地球儀、電話台、ラジオ、テレビジョンなどが挙げられる。これらの他、自動車のステアリングホイール、ダッシュボードなどの内装品のほか、各種標章・紋章（エンブレム）、各種マグネット、カフスボタンなどの各種ボタン、各種ラベル、各種組みひも、スプーンなどの日用品が挙げられる。これら製品は、必要がある時に焼結金属部品に香料を含浸させ、香りを放つことができる製品とすることができる。 The sintered metal component according to the present invention is attached to various products according to the first invention of the present invention. The material (material) of the product to which the metal part can be applied is not particularly limited, and examples thereof include metal, wood, synthetic resin, leather, fiber, and combinations thereof. Examples of the products include indoor ornaments such as jewelry (jewelry), jewelry, ornaments, and ornaments. Specific examples of jewelry, jewelry, and ornaments include earrings (drop earrings, clip earrings, screw earrings, earrings, etc.), necklaces (various necklaces, pendants, rockets, dog collars, etc.), bracelets (names) Bracelet, charm bracelet, bangle, etc., charm (name plate, horseshoe-shaped charm, square charm, heart-shaped charm, cross-shaped charm, fish-shaped charm, animal-shaped charm, animal-shaped charm, insect-shaped charm) , Petal-type charm, leaf-type charm, etc.), rings (signet ring, band-type ring, class ring, solitaire-type ring, wedding ring, engagement ring, etc.), pins (brooch, stick pin, tie pin, color bar, tie bar, etc.) ), Hairpin, f Clips, hair holders, business card holders, wallets, wallets, coin purses, card cases, key chains, glasses, lighters, mobile phones, watch bands, various straps, zippers, boots, shoes, bands, handbags, various bags, pouches, Netsuke etc. are mentioned. Interior decorations include desk lighters, desk ashtrays, vases, photo frames, music boxes, jewelry boxes, various trays, globes, telephone stands, radios, televisions and more. In addition to these, interior items such as automobile steering wheels and dashboards, various marks and emblems, various magnets, various buttons such as cuff links, various labels, various braids, spoons and other daily necessities are listed. It is done. These products can be made into products in which a sintered metal part can be impregnated with a fragrance when necessary to give off a scent.
１：ネックレス
２、８：平面形状が十字チャームの外枠
３：短軸
４：長軸
５、９：金属部品
６：噴霧器
７：香水
１０、１１、１２、１４：チャーム
１３：チャームブレスレット
１５、１８：金属枠
１６、１９：凹状窪み
１７、２０：焼結金属部分
1: Necklace 2, 8: Outer frame of cross-shaped charm 3: Short axis 4:
Claims (7)
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| JP2007083971A JP5443671B2 (en) | 2007-03-28 | 2007-03-28 | Perfumed jewelry, jewelry or ornaments |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2018011780A1 (en) * | 2016-07-10 | 2018-01-18 | Aab Co. Ltd | Perfumed jewelry |
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| JPS52150312A (en) * | 1976-06-08 | 1977-12-14 | Tokuriki Honten Kk | Process for production of perfumed porous material for precioussmetalladorned accessories |
| JPH04112675U (en) * | 1991-03-22 | 1992-09-30 | 株式会社資生堂 | Key holder equipped with a decorative member having a fragrance retaining part |
| JPH0563314U (en) * | 1992-02-07 | 1993-08-24 | 三菱マテリアル株式会社 | Precious metal jewelry with a name |
| JP2002129206A (en) * | 2000-10-27 | 2002-05-09 | Sm Aroma Co Ltd | Method for producing aromatic metal with various hue |
| JP2002363715A (en) * | 2001-05-28 | 2002-12-18 | Metallic Space Kk | Highly corrosion resistant, highly absorptive porous sintered alloy body and manufacturing method thereof |
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2007
- 2007-03-28 JP JP2007083971A patent/JP5443671B2/en not_active Expired - Fee Related
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|---|---|---|---|---|
| JPS52150312A (en) * | 1976-06-08 | 1977-12-14 | Tokuriki Honten Kk | Process for production of perfumed porous material for precioussmetalladorned accessories |
| JPH04112675U (en) * | 1991-03-22 | 1992-09-30 | 株式会社資生堂 | Key holder equipped with a decorative member having a fragrance retaining part |
| JPH0563314U (en) * | 1992-02-07 | 1993-08-24 | 三菱マテリアル株式会社 | Precious metal jewelry with a name |
| JP2002129206A (en) * | 2000-10-27 | 2002-05-09 | Sm Aroma Co Ltd | Method for producing aromatic metal with various hue |
| JP2002363715A (en) * | 2001-05-28 | 2002-12-18 | Metallic Space Kk | Highly corrosion resistant, highly absorptive porous sintered alloy body and manufacturing method thereof |
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| JPN6013040250; ｅｘｃｉｔｅニュース , 20060203 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018011780A1 (en) * | 2016-07-10 | 2018-01-18 | Aab Co. Ltd | Perfumed jewelry |
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