JP2008200974A - Manufacturing method for rubber cylinder, manufacturing method for rubber tube, and vulcanization mold - Google Patents

Manufacturing method for rubber cylinder, manufacturing method for rubber tube, and vulcanization mold Download PDF

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JP2008200974A
JP2008200974A JP2007039056A JP2007039056A JP2008200974A JP 2008200974 A JP2008200974 A JP 2008200974A JP 2007039056 A JP2007039056 A JP 2007039056A JP 2007039056 A JP2007039056 A JP 2007039056A JP 2008200974 A JP2008200974 A JP 2008200974A
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rubber
mandrel
cylinder
rubber cylinder
cylindrical
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Shizuo Yokobori
志津雄 横堀
Kazuharu Uetsubo
一晴 上坪
Mitsuo Oshikata
満男 押方
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Toyo Tire Corp
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Toyo Tire and Rubber Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method for a rubber tube, which also enables the manufacture of a medium-length rubber cylinder, while adopting a vulcanization molding system for covering an unvulcanized rubber cylinder with an outer mold and pressurizing it from the inside. <P>SOLUTION: A mandrel 7 is constituted by arranging a tubular rubber 5 around a metal tube 6. In the tubular rubber 5, two reinforcing cord layers 11 are provided by circumferentially arranging a reinforcing cord 12 while inclining it. The directions of the inclinations of the reinforcing cords 12 of the respective layers 11a and 11b are set to cross each other. The diameter of the tubular rubber 5 is reduced while angles (θ) of the inclinations of the reinforcing cords 12 are changed by pulling both ends of the tubular rubber 5. An unvulcanized rubber tube 8 is molded around the mandrel 7, and inserted into a vulcanizing pan 9. The reduction of the diameter of the tubular rubber 5 is released, and the unvulcanized rubber tube 8 is pressurized by being pressed against an inner peripheral surface of the vulcanizing pan 9. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、例えばゴムチューブなどを製造するためのゴム製筒体の製造方法、ゴムチューブの製造方法及び加硫成形型に関するものである。   The present invention relates to a method for producing a rubber cylinder, a method for producing a rubber tube, and a vulcanization mold for producing a rubber tube, for example.

一般に、ゴムチューブなどのゴム製筒体は、未加硫ゴム筒を成型し、これを加圧しつつ加熱することにより加硫成形して製造される。未加硫ゴム筒の加硫成形には、例えば内側にマンドレルを配置して外側から加圧する方法として、布締め方式、外バッグ方式、あるいは二つ割り外金型方式などが採用される。   Generally, a rubber cylinder such as a rubber tube is manufactured by molding an unvulcanized rubber cylinder and vulcanizing and molding it by heating it while applying pressure. For vulcanization molding of an unvulcanized rubber cylinder, for example, a cloth fastening method, an outer bag method, a split outer mold method, or the like is employed as a method of placing a mandrel on the inside and pressurizing from the outside.

未加硫ゴム筒を外側から加圧する方法のうち、布締め方式や外バッグ方式は、成形するゴム製筒体の外径精度が低くなりやすく、所望の表面光沢を得ることもできない。また、二つ割り外金型方式は、未加硫ゴム筒の未加硫ゴム量を多めに設定しておくことにより、外金型を組み立てて加圧しつつ、外金型の割り面から余分な未加硫ゴムを流出させるものであり、成形するゴム製筒体が長くなるほど、未加硫ゴム量の調節が難しく、しかも、外面未加硫ゴムが割り面から不均一に流出することにより、埋設した補強繊維を露出させるおそれがある。   Among the methods of pressurizing the unvulcanized rubber cylinder from the outside, the cloth fastening method and the outer bag method tend to lower the outer diameter accuracy of the rubber cylinder to be molded, and cannot obtain the desired surface gloss. In addition, the split outer mold method sets a larger amount of unvulcanized rubber in the unvulcanized rubber cylinder, so that the outer mold can be assembled and pressurized, and excess uncut rubber can be removed from the split surface of the outer mold. Vulcanized rubber flows out. The longer the rubber cylinder to be molded, the more difficult it is to adjust the amount of unvulcanized rubber. There is a risk that exposed reinforcing fibers may be exposed.

一方、未加硫ゴム筒を外金型で覆って内側から加圧する加硫成形方法として、例えば特許文献1に開示されるような、内バッグと外金型とを用いる方法を採用することがある。この方法は、外金型を使用する分、成形後のゴム製筒体の外径精度が高く、所望の表面光沢を得ることもでき、しかも、外金型に割り面が不要であるため、未加硫ゴムの流出による補強繊維の露出もない。ただ、中尺以上のゴム製筒体を成形する場合には、加硫成形型をセットする際に、内バッグを中尺の未加硫ゴム筒に挿入することができないため、この方法を採用することはできない。   On the other hand, as a vulcanization molding method in which an unvulcanized rubber cylinder is covered with an outer mold and pressurized from the inside, a method using an inner bag and an outer mold as disclosed in Patent Document 1, for example, may be adopted. is there. Since this method uses an outer mold, the outer diameter accuracy of the rubber cylinder after molding is high, a desired surface gloss can be obtained, and a split surface is unnecessary for the outer mold, There is no exposure of reinforcing fibers due to the outflow of unvulcanized rubber. However, when molding a medium-sized or larger rubber cylinder, this method is used because the inner bag cannot be inserted into the medium-sized unvulcanized rubber cylinder when setting the vulcanization mold. I can't do it.

これに対して、芯材の周りに筒状ゴムを配置してマンドレルを構成し、このマンドレルの周りに未加硫ゴム筒を成型して、この未加硫ゴム筒をマンドレルと共に外金型に挿入して加圧するという方法が考えられる。この方法は、筒状ゴムを中心軸方向に圧縮して拡径することにより、内バッグ方式と同様、未加硫ゴム筒を内側から加圧するものであり、しかも、中尺のゴム製筒体の成形においても、加硫成形型のセットが容易である。
特開平5−237848
On the other hand, a cylindrical rubber is arranged around the core material to form a mandrel, an unvulcanized rubber cylinder is molded around the mandrel, and the unvulcanized rubber cylinder is put together with the mandrel into an outer mold. A method of inserting and pressurizing can be considered. This method is to pressurize the unvulcanized rubber cylinder from the inside as in the case of the inner bag system by compressing and expanding the diameter of the cylindrical rubber in the direction of the central axis. In this molding, it is easy to set a vulcanization mold.
JP-A-5-237848

ところが、上記の芯材と筒状ゴムとからなるマンドレルは、未加硫ゴム筒及び筒状ゴムが長いほど、筒状ゴムと芯材あるいは未加硫ゴム筒との摩擦が大きいため、筒状ゴムの両端に力を加えて中心軸方向に圧縮しようとしても、その圧縮力が中央部にまで伝わらず、筒状ゴムの中央部を十分に拡径して未加硫ゴム筒を加圧することができない。   However, the mandrel composed of the core material and the cylindrical rubber has a longer friction between the cylindrical rubber and the core material or the unvulcanized rubber cylinder as the unvulcanized rubber cylinder and the cylindrical rubber are longer. Applying force to both ends of the rubber to compress it in the direction of the central axis, the compression force is not transmitted to the central part, and the central part of the cylindrical rubber is sufficiently expanded to pressurize the unvulcanized rubber cylinder I can't.

本発明は、未加硫ゴム筒を外金型で覆って内側から加圧する加硫成形方式を採用しつつ、中尺のゴム製筒体をも製造することのできるゴム製筒体の製造方法、ゴムチューブの製造方法及び加硫成形型の提供を目的とする。   The present invention relates to a method for producing a rubber cylinder capable of producing a medium-sized rubber cylinder while adopting a vulcanization molding method in which an unvulcanized rubber cylinder is covered with an outer mold and pressurized from the inside. Another object is to provide a rubber tube manufacturing method and a vulcanization mold.

上記目的を達成するため、本発明に係るゴム製筒体の製造方法は、マンドレルの周りに未加硫ゴム筒を成型して加硫成形するものであり、そのマンドレルは、芯材の周りに筒状ゴムを配置してなり、この筒状ゴムに、補強コードをマンドレル中心軸に対して傾斜させつつ周方向かつ偶数列に配列すると共に、対をなす列の補強コードの傾斜方向を互いに交差するよう設定してなる補強コード層を設けている。   In order to achieve the above object, a method for manufacturing a rubber cylinder according to the present invention is to vulcanize and mold an unvulcanized rubber cylinder around a mandrel, and the mandrel is around a core material. Cylindrical rubber is arranged, and in this cylindrical rubber, reinforcing cords are inclined with respect to the central axis of the mandrel and arranged in circumferential and even rows, and the reinforcing cords in a pair of rows intersect with each other in the inclination direction. A reinforcing cord layer is provided so as to be set.

ゴム製筒体を製造する手順を具体的に説明すると、まず、筒状ゴムの両端を引っ張ることにより、マンドレル中心軸に対する補強コードの傾斜角度を変化させながら、筒状ゴムをマンドレル中心軸方向に引き伸ばしつつ縮径させる。次いで、マンドレルの周りに未加硫ゴム筒を成型して、これらを加硫缶に挿入した後、筒状ゴムの引き伸ばしを解除して拡径することにより、未加硫ゴム筒を加硫缶の内周面に押し付けて加圧しつつ加熱して加硫成形する。その後、筒状ゴムを再び引き伸ばしつつ縮径させて、マンドレル及び加硫缶からゴム製筒体を取り出す。   The procedure for manufacturing the rubber cylinder will be described in detail. First, by pulling both ends of the cylindrical rubber, the cylindrical rubber is moved in the mandrel central axis direction while changing the inclination angle of the reinforcement cord with respect to the mandrel central axis. Reduce diameter while stretching. Next, after molding unvulcanized rubber cylinders around the mandrel and inserting them into the vulcanized can, the unvulcanized rubber cylinder is vulcanized by releasing the expansion of the cylindrical rubber and expanding the diameter. The vulcanization molding is carried out by applying pressure to the inner peripheral surface of the steel and heating it. Thereafter, the tubular rubber is reduced in diameter while being stretched again, and the rubber cylinder is taken out from the mandrel and the vulcanizing can.

上記構成によれば、引き伸ばして縮径させた筒状ゴムの周りに未加硫ゴムを成型するので、これを外金型としての加硫缶に容易に挿入することができる。しかも、筒状ゴムをその引き伸ばしの解除により拡径して、未加硫ゴム筒を加硫成形した後、再び筒状ゴムを引き伸ばして縮径させるので、加硫成形後のゴム製筒体の取り出しを容易にすることができる。   According to the above configuration, since the unvulcanized rubber is molded around the cylindrical rubber that has been stretched and reduced in diameter, it can be easily inserted into a vulcanizing can as an outer mold. Moreover, the diameter of the cylindrical rubber is expanded by releasing the expansion, and after the unvulcanized rubber cylinder is vulcanized and molded, the cylindrical rubber is stretched again to reduce the diameter. Removal can be facilitated.

さらに、マンドレルの筒状ゴムに補強コード層を設けるので、中尺のゴム製筒体を成形するよう筒状ゴムを中尺に設定したとしても、筒状ゴムの両端を引っ張る力を、芯材あるいは未加硫ゴム筒との摩擦に抗して、マンドレル中心軸方向における中央部にまで伝えることができる。しかも、対をなす列の補強コードの傾斜方向を互いに交差させるので、補強コードのいわゆるパンタグラフ作用により、筒状ゴムの両端から中央部に至る全体を引き伸ばしつつ縮径、あるいは引き伸ばしを解除しつつ拡径することができる。   Furthermore, since a reinforcing cord layer is provided on the cylindrical rubber of the mandrel, even if the cylindrical rubber is set to a medium size so as to form a medium-sized rubber cylinder, the force pulling both ends of the cylindrical rubber is reduced by the core material. Alternatively, it can be transmitted to the central part in the mandrel central axis direction against friction with the unvulcanized rubber cylinder. In addition, since the inclination directions of the reinforcing cords in a pair of rows intersect each other, the so-called pantograph action of the reinforcing cords expands the entire length from both ends of the cylindrical rubber to the center while reducing the diameter or releasing the expansion. Can be calibrated.

マンドレル及び未加硫ゴム筒を加硫缶に挿入した後、筒状ゴムの引き伸ばしを解除すると共に、筒状ゴムをマンドレル中心軸方向に圧縮して拡径することにより、未加硫ゴム筒を加硫缶の内周面に押し付けて加圧するようにすれば、筒状ゴムの引き伸ばしを解除するだけの場合よりも、未加硫ゴム筒をより強く加圧してゴムの物性を高めることができる。   After inserting the mandrel and unvulcanized rubber cylinder into the vulcanized can, release the expansion of the cylindrical rubber, and compress the cylindrical rubber in the direction of the central axis of the mandrel, thereby expanding the diameter of the unvulcanized rubber cylinder. If pressure is applied by pressing against the inner peripheral surface of the vulcanized can, the physical properties of the rubber can be improved by pressing the unvulcanized rubber cylinder more strongly than simply releasing the expansion of the cylindrical rubber. .

本発明の製造方法は、中心軸方向長さ(L)と外径(D)との比(L/D)を3〜20の範囲に設定したゴム製筒体の製造に採用するのが好適である。   The production method of the present invention is preferably employed for the production of a rubber cylinder in which the ratio (L / D) of the length (L) to the outer diameter (D) in the central axis direction is set in the range of 3-20. It is.

つまり、(L/D)が3未満であれば、筒状ゴムに補強コード層を設けなくても、その中央部まで十分に縮径及びその解除による拡径をすることができるため、筒状ゴムに補強コード層を設けることによる効果を得ることができない。一方、(L/D)が20を超過すると、筒状ゴムの縮径に伴って芯材との摩擦が極端に大きくなるため、筒状ゴムの中央部にまで引張力を伝えることができず、引き伸ばしによる縮径及びその解除による拡径をすることができない。   In other words, if (L / D) is less than 3, the cylindrical rubber can be sufficiently reduced in diameter and expanded by its release without providing a reinforcing cord layer on the cylindrical rubber. The effect of providing the reinforcing cord layer on the rubber cannot be obtained. On the other hand, if (L / D) exceeds 20, the friction with the core material becomes extremely large with the diameter reduction of the cylindrical rubber, so that the tensile force cannot be transmitted to the central part of the cylindrical rubber. It is not possible to reduce the diameter by stretching and to increase the diameter by releasing it.

未加硫ゴム筒に補強繊維を埋設したものは、その製造に本発明の方法を採用するのが好適である。つまり、本発明の製造方法では、中尺のゴム製筒体の製造においても、その未加硫ゴム筒を外金型としての加硫缶で覆いつつ内側から加圧するので、所望の外径精度及び表面光沢を得るのに二つ割りの外金型を使用する必要がない。そのため、未加硫ゴム筒に補強繊維を埋設したとしても、外金型の割り面からの外面未加硫ゴムの不均一な流出による補強繊維の露出を生じさせることがない。   It is preferable to employ the method of the present invention for the production of the unvulcanized rubber cylinder in which the reinforcing fiber is embedded. That is, in the production method of the present invention, even in the production of a medium-sized rubber cylinder, the unvulcanized rubber cylinder is pressurized from the inside while being covered with a vulcanization can as an outer mold, so that the desired outer diameter accuracy is achieved. And it is not necessary to use a split outer mold to obtain surface gloss. Therefore, even if the reinforcing fibers are embedded in the unvulcanized rubber cylinder, the reinforcing fibers are not exposed due to the non-uniform outflow of the outer unvulcanized rubber from the split surface of the outer mold.

上記の製造方法は、空気ばねのダイヤフラムやタイヤ、配管継手など、あらゆるゴム製筒体の製造に採用することができるが、一般に中心軸方向長さ(L)と外径(D)との比(L/D)の大きいゴムチューブは、その製造に本発明の製造方法を採用するのが特に好適である。   The manufacturing method described above can be used to manufacture all types of rubber cylinders such as air spring diaphragms, tires, and pipe joints, but generally the ratio between the length in the central axis direction (L) and the outer diameter (D). For the rubber tube having a large (L / D), it is particularly preferable to employ the production method of the present invention for its production.

また、本発明は、上記の製造方法に使用する加硫成形型を提供する。すなわち、本発明は、周囲に未加硫ゴム筒を成型するマンドレルと、該マンドレルと共に挿入された未加硫ゴム筒を加圧及び加熱する加硫缶とを備え、前記マンドレルは、芯材の周りに筒状ゴムを配置してなり、該筒状ゴムに、補強コードをマンドレル中心軸に対して傾斜させつつ周方向かつ偶数列に配列すると共に、対をなす列の補強コードの傾斜方向を互いに交差するよう設定してなる補強コード層が設けられたことを特徴とする加硫成形型を提供する。   The present invention also provides a vulcanization mold used in the above production method. That is, the present invention includes a mandrel that forms an unvulcanized rubber cylinder around the mandrel, and a vulcanization can that pressurizes and heats the unvulcanized rubber cylinder inserted together with the mandrel. Cylindrical rubber is arranged around, and the reinforcing cords are arranged in the circumferential direction and even rows while inclining the reinforcing cords with respect to the central axis of the mandrel, and the inclination directions of the reinforcing cords in a pair of rows are arranged. Provided is a vulcanization molding die provided with a reinforcing cord layer set so as to cross each other.

この加硫成形型の構成を採用することにより、上記のゴム製筒体及びゴムチューブの製造方法の構成を採用することによる効果と同じ効果を得ることができる。なお、補強コードとしては、加硫成形時の温度に耐え得る耐熱性のものであればよいが、筒状ゴムの中央部にまで引張力を伝えるには、引っ張りに対する伸びの小さなものが好ましく、アラミッドコードやスチールコードを例示できる。特に、スパナイズドヤーンであるアラミッド中繊維コードは、接着剤などの処理が不要であり、好適である。   By adopting the configuration of the vulcanization mold, it is possible to obtain the same effect as that obtained by adopting the configuration of the rubber cylinder and the rubber tube manufacturing method. In addition, as the reinforcement cord, any heat-resistant material that can withstand the temperature at the time of vulcanization molding may be used, but in order to transmit the tensile force to the central portion of the cylindrical rubber, a material having a small elongation with respect to tension is preferable, Examples include aramid cords and steel cords. In particular, an aramid fiber cord that is a spun yarn is suitable because it does not require treatment with an adhesive or the like.

マンドレルの両端よりも中央ほど、マンドレル中心軸に対する補強コードの傾斜角度を大きく設定すれば、筒状ゴムをその全長に渡って均一に縮径及びその解除による拡径をすることができる。つまり、筒状ゴムの中央部は、芯材などとの摩擦の影響によって、両端から受けた引張力が小さくなりやすいので、この中央部における補強コードの傾斜角度を大きく設定して、引張力に対する中央部の剛性を両端部よりも小さくすることにより、筒状ゴムの縮径及び拡径を全長に渡って均一にすることができる。   If the inclination angle of the reinforcing cord with respect to the mandrel central axis is set larger toward the center than both ends of the mandrel, the cylindrical rubber can be uniformly reduced in diameter over its entire length and expanded by releasing it. In other words, since the tensile force received from both ends tends to be small due to the influence of friction with the core material etc. at the central part of the cylindrical rubber, the inclination angle of the reinforcing cord at this central part is set large, By making the rigidity of the central portion smaller than both end portions, it is possible to make the diameter reduction and diameter expansion of the cylindrical rubber uniform over the entire length.

筒状ゴムは、加硫成形時の温度に耐え得る耐熱性ゴムから形成したものであればよいが、この耐熱性ゴムとして、特に熱膨張率の高いシリコンゴムを採用すれば、加硫成形時の筒状ゴムの熱膨張により、未加硫ゴム筒をより強く加圧して、ゴムの物性を高めることができる。   The cylindrical rubber may be formed from a heat-resistant rubber that can withstand the temperature at the time of vulcanization molding. However, if silicon rubber having a high coefficient of thermal expansion is used as this heat-resistant rubber, the cylindrical rubber will be Due to the thermal expansion of the cylindrical rubber, the unvulcanized rubber cylinder can be more strongly pressurized and the physical properties of the rubber can be enhanced.

以上のとおり、本発明によると、芯材の周りに筒状ゴムを配置してマンドレルを構成すると共に、その筒状ゴムに補強コード層を設けるので、筒状ゴムの引き伸ばし及びその解除により、筒状ゴムを全長に渡って縮径及び拡径することができる。これにより、中尺のゴム製筒体の製造に、未加硫ゴム筒を外金型で覆って内側から加圧する加硫成形方式を採用することができ、成形後のゴム製筒体の外径精度を高めると共に、所望の表面光沢を得ることができる。   As described above, according to the present invention, the cylindrical rubber is arranged around the core material to form the mandrel, and the cylindrical rubber is provided with the reinforcing cord layer. The rubber can be reduced in diameter and expanded over the entire length. As a result, a vulcanization molding method in which an unvulcanized rubber cylinder is covered with an outer mold and pressed from the inside can be adopted for the production of a medium-sized rubber cylinder, and the rubber cylinder after molding is It is possible to improve the diameter accuracy and obtain a desired surface gloss.

以下、本発明に係るゴム製筒体の製造方法、ゴムチューブの製造方法及び加硫成形型を実施するための最良の形態について、図面を用いて説明する。   The best mode for carrying out a method for producing a rubber cylinder, a method for producing a rubber tube, and a vulcanization mold according to the present invention will be described below with reference to the drawings.

まず、本発明に係る方法で製造するゴム製筒体としてのゴムチューブの構成を説明する。図1は本発明に係る方法で製造するゴムチューブを示す図であり、上半分は断面図、下半分は側面図である。   First, the structure of the rubber tube as a rubber cylinder manufactured by the method according to the present invention will be described. FIG. 1 is a view showing a rubber tube manufactured by the method according to the present invention, wherein the upper half is a sectional view and the lower half is a side view.

ゴムチューブ1は、例えば生コンクリートなどを圧送するためのスクイーズ式ポンプに装備されるポンピングチューブとして使用されるものであり、中尺のゴム筒2に補強繊維3を埋設した構造とされ、その中心軸方向長さ(L)と外径(D)との比(L/D)が3〜20の範囲に設定される。   The rubber tube 1 is used, for example, as a pumping tube equipped in a squeeze pump for pumping ready-mixed concrete or the like. The rubber tube 1 has a structure in which a reinforcing fiber 3 is embedded in a medium-sized rubber cylinder 2 and its center. The ratio (L / D) between the axial length (L) and the outer diameter (D) is set in the range of 3-20.

次に、本発明に係るゴムチューブの製造方法を説明する。図2はマンドレルを示す図であり、上半分は断面図、下半分は側面図である。図2において、下半分の中央部は、筒状ゴムの外面ゴムを剥がして外面側及び内面側の補強コード層を示している。図3はゴムチューブの製造方法の前半の工程を示す図であり、図4はゴムチューブの製造方法の後半の工程を示す図である。   Next, the manufacturing method of the rubber tube which concerns on this invention is demonstrated. FIG. 2 is a view showing a mandrel, in which the upper half is a sectional view and the lower half is a side view. In FIG. 2, the center portion of the lower half shows the reinforcing cord layers on the outer surface side and the inner surface side by peeling the outer surface rubber of the cylindrical rubber. FIG. 3 is a diagram showing the first half of the rubber tube manufacturing method, and FIG. 4 is a diagram showing the second half of the rubber tube manufacturing method.

まず、本発明に係る加硫成形型の構成を説明する。   First, the configuration of the vulcanization mold according to the present invention will be described.

加硫成形型4は、十分な厚さの筒状ゴム5を芯材としての金属管6の周りに配置してなるマンドレル7と、マンドレル7の周囲に成型した未加硫ゴム筒8をマンドレル7と共に挿入する加硫缶9と、加硫缶9に挿入した未加硫ゴム筒8の端部を押さえる端部押さえ金具10とを備え、未加硫ゴム筒8を、筒状ゴム5を拡径して加圧しつつ、マンドレル7及び加硫缶9を介して内外から加熱して加硫成形するようになっている。   The vulcanization mold 4 includes a mandrel 7 in which a sufficiently thick cylindrical rubber 5 is disposed around a metal tube 6 as a core, and an unvulcanized rubber cylinder 8 molded around the mandrel 7 as a mandrel. 7 and a vulcanizing can 9 inserted into the vulcanizing can 9 and an end pressing metal fitting 10 for pressing the end of the unvulcanized rubber cylinder 8 inserted into the vulcanizing can 9. The unvulcanized rubber cylinder 8 is connected to the cylindrical rubber 5. While expanding and pressurizing, vulcanization molding is carried out by heating from inside and outside through the mandrel 7 and the vulcanizing can 9.

筒状ゴム5は、加硫温度に耐え得る耐熱性を有すると共に、容易に変形する硬さで、かつ熱膨張率の高いシリコンゴムから形成され、マンドレル中心軸方向に十分に圧縮できるよう、周りに成型される未加硫ゴム筒8及び加硫缶9よりも長く設定されている。この筒状ゴム5は、例えば7mm程度の十分な厚さで、金属管6に沿ってマンドレル中心軸方向に引き伸ばして縮径し、また、この縮径の解除、マンドレル中心軸方向への圧縮、及び加硫成形時の熱膨張によって拡径するようになっている。   The cylindrical rubber 5 has heat resistance that can withstand the vulcanization temperature, is easily deformed, and is formed of silicon rubber having a high coefficient of thermal expansion, so that it can be sufficiently compressed in the central axis direction of the mandrel. It is set longer than the unvulcanized rubber cylinder 8 and the vulcanized can 9 that are molded into the same. The cylindrical rubber 5 has a sufficient thickness of, for example, about 7 mm, and is stretched in the mandrel central axis direction along the metal tube 6 to reduce the diameter, and the release of the reduced diameter, compression in the mandrel central axis direction, In addition, the diameter is expanded by thermal expansion during vulcanization molding.

筒状ゴム5の外面付近には、両端に加えた引張力を中央部にまで伝えるための補強コード層11が設けられている。   In the vicinity of the outer surface of the cylindrical rubber 5, a reinforcing cord layer 11 is provided for transmitting the tensile force applied to both ends to the central portion.

補強コード層11は、例えば太さ0.3mmのアラミッド中繊維からなる補強コード12をマンドレル中心軸に対して傾斜させつつ周方向かつ二層に、6本/cmの本数密度で配列してなり、各層11a、11bの補強コード12の傾斜方向が互いに交差するよう設定されている。マンドレル中心軸に対する補強コード12の傾斜角度(θ)は、筒状ゴム5の両端における傾斜角度(θ1、例えば46°)から中央における傾斜角度(θ2、例えば58°)の範囲で、マンドレル7の両端よりも中央ほど大きくなるよう設定されている(θ1≦θ≦θ2)。   The reinforcing cord layer 11 is formed by arranging reinforcing cords 12 made of, for example, 0.3 mm thick aramid middle fibers in a circumferential direction and two layers with a number density of 6 / cm while inclining with respect to the mandrel central axis. The inclination directions of the reinforcing cords 12 of the layers 11a and 11b are set to intersect each other. The inclination angle (θ) of the reinforcing cord 12 with respect to the central axis of the mandrel ranges from the inclination angle (θ1, for example, 46 °) at both ends of the cylindrical rubber 5 to the inclination angle (θ2, for example, 58 °) at the center. It is set to be larger toward the center than at both ends (θ1 ≦ θ ≦ θ2).

金属管6は、その内側にシリコンオイルやグリセリンなどの熱媒体を給入して循環させることにより、筒状ゴム5を介して、未加硫ゴム筒8を内側から加熱するようになっている。この金属管6は、その中央部の周りに配置される筒状ゴム5よりも十分に長く設定され、筒状ゴム5をマンドレル中心軸方向に引き伸ばす際、あるいは圧縮する際のガイドとしても機能する。   The metal pipe 6 heats the unvulcanized rubber cylinder 8 from the inside through the cylindrical rubber 5 by supplying and circulating a heat medium such as silicon oil or glycerin inside the metal pipe 6. . The metal tube 6 is set to be sufficiently longer than the cylindrical rubber 5 disposed around the central portion thereof, and functions as a guide when the cylindrical rubber 5 is stretched or compressed in the mandrel central axis direction. .

加硫缶9は、ゴムチューブ1の外径に等しい内径で、両端に接続フランジ13を有し、かつ全周に空洞14を有する二重管とされ、給入口(図示せず)から空洞14にシリコンオイルやグリセリンなどの熱媒体を給入して循環させることにより、未加硫ゴム筒8を外側から加熱するようになっている。この加硫缶9は、未加硫ゴム筒8をその全長に渡って収納可能なよう、未加硫ゴム筒8よりも長く設定される。   The vulcanizing can 9 is a double pipe having an inner diameter equal to the outer diameter of the rubber tube 1, having connection flanges 13 at both ends and having a cavity 14 on the entire circumference, and from the inlet (not shown) to the cavity 14. The unvulcanized rubber cylinder 8 is heated from the outside by supplying and circulating a heat medium such as silicon oil or glycerin. The vulcanized can 9 is set longer than the unvulcanized rubber cylinder 8 so that the unvulcanized rubber cylinder 8 can be accommodated over its entire length.

端部押さえ金具10は、筒状ゴム5の端部に設けられた筒状ゴム端部カラー15を押さえる断面L字形の筒状ゴム押さえ金具16と、未加硫ゴム筒8の端部形状を形成する端部カラー17と、端部カラー17を押さえる断面L字形の未加硫ゴム筒押さえ金具18と、筒状ゴム押さえ金具16のフランジを貫通すると共に加硫缶9の接続フランジ13に螺合される筒状ゴム押さえボルト19と、筒状ゴム押さえ金具16のフランジに螺合されると共に、先端を未加硫ゴム筒押さえ金具18のフランジに当接される未加硫ゴム筒押さえボルト20とから構成される。   The end holding metal fitting 10 has an L-shaped cylindrical rubber holding metal fitting 16 that holds the cylindrical rubber end collar 15 provided at the end of the cylindrical rubber 5 and the end shape of the unvulcanized rubber cylinder 8. An end collar 17 to be formed, an unvulcanized rubber cylinder pressing metal fitting 18 having an L-shaped cross section for holding the end collar 17, and a flange of the cylindrical rubber pressing metal fitting 16 are penetrated and screwed to the connection flange 13 of the vulcanizing can 9. The unvulcanized rubber cylinder retainer bolt that is screwed to the flange of the tubular rubber retainer bolt 19 and the tubular rubber retainer bracket 16 to be joined, and whose tip is brought into contact with the flange of the unvulcanized rubber cylinder retainer bracket 18. 20.

この端部押さえ金具10は、筒状ゴム押さえボルト19を調節して筒状ゴム5を引き伸ばし又は圧縮しつつ、未加硫ゴム筒押さえボルト20を調節して、未加硫ゴム筒8を所定の長さのまま押さえるようになっている。   The end holding metal fitting 10 adjusts the unvulcanized rubber cylinder holding bolt 20 and adjusts the unvulcanized rubber cylinder 8 while adjusting the cylindrical rubber holding bolt 19 to stretch or compress the cylindrical rubber 5. It is designed to hold down the length.

次に、上記の加硫成形型を使用したゴムチューブの製造方法を説明する。図3(a)に示すように、マンドレル7の筒状ゴム5は、自由状態において、その長さがL1で、外径がD1(例えばφ36mm)である。   Next, a method for producing a rubber tube using the above vulcanization mold will be described. As shown in FIG. 3A, the cylindrical rubber 5 of the mandrel 7 has a length L1 and an outer diameter D1 (for example, φ36 mm) in a free state.

まず、図3(b)に示すように、筒状ゴム5の外側の所定の位置に端部カラー17を配置する。それと共に、筒状ゴム5の両端をマンドレル中心軸方向に引っ張ることにより、筒状ゴム5の長さをL2まで引き伸ばしつつ、外径をD2(例えばφ34mm)まで縮径させる。   First, as shown in FIG. 3B, the end collar 17 is disposed at a predetermined position outside the cylindrical rubber 5. At the same time, by pulling both ends of the cylindrical rubber 5 in the mandrel central axis direction, the outer diameter of the cylindrical rubber 5 is reduced to D2 (for example, φ34 mm) while extending the length of the cylindrical rubber 5 to L2.

このとき、筒状ゴム5は、補強コード層11のパンタグラフ作用により、マンドレル中心軸に対する補強コード12の傾斜角度(θ)を変化させながら、マンドレル中心軸方向に引き伸ばされつつ縮径する。しかも、引張力が小さくなる中央部ほど、補強コード12の傾斜角度(θ)を大きくして、引っ張りに対する筒状ゴム5の剛性を小さくしているので、筒状ゴム5が全長に渡って均一に縮径する。   At this time, the cylindrical rubber 5 is reduced in diameter while being stretched in the mandrel central axis direction by changing the inclination angle (θ) of the reinforcing cord 12 with respect to the mandrel central axis by the pantograph action of the reinforcing cord layer 11. In addition, since the inclination angle (θ) of the reinforcing cord 12 is increased at the center portion where the tensile force is smaller, and the rigidity of the tubular rubber 5 against tension is reduced, the tubular rubber 5 is uniform over the entire length. Reduce to diameter.

次いで、図3(c)に示すように、筒状ゴム5の周りに内面未加硫ゴムを巻き付け、その外側に補強繊維3を配置して、その外側に外面未加硫ゴムを巻き付けることにより、補強繊維3を埋設した未加硫ゴム筒8を成型する。この未加硫ゴム筒8は、内径及び外径がゴムチューブ1よりも小さく、かつ、加硫成形後に所望の厚さのゴムチューブ1が得られる厚さに設定される。なお、筒状ゴム5は、図4(d)に示すように、引き伸ばしを解除することにより、長さがL1で外径がD1の自由状態に戻ろうとする。   Next, as shown in FIG. 3 (c), the inner surface unvulcanized rubber is wound around the cylindrical rubber 5, the reinforcing fiber 3 is arranged on the outer side, and the outer surface unvulcanized rubber is wound on the outer side. Then, the unvulcanized rubber cylinder 8 in which the reinforcing fiber 3 is embedded is molded. The unvulcanized rubber cylinder 8 has an inner diameter and an outer diameter smaller than those of the rubber tube 1 and is set to a thickness that can obtain the rubber tube 1 having a desired thickness after vulcanization molding. In addition, as shown in FIG.4 (d), the cylindrical rubber 5 tries to return to the free state of length L1 and outer diameter D1 by canceling | extracting extension.

図4(e)に示すように、マンドレル7及び未加硫ゴム筒8を加硫缶9に挿入する。このとき、筒状ゴム5の外径をD2まで縮径しているので、未加硫ゴム筒8の外径がゴムチューブ1の外径、すなわち加硫缶9の内径よりも小さく、その挿入が容易である。   As shown in FIG. 4 (e), the mandrel 7 and the unvulcanized rubber cylinder 8 are inserted into the vulcanizing can 9. At this time, since the outer diameter of the cylindrical rubber 5 is reduced to D2, the outer diameter of the unvulcanized rubber cylinder 8 is smaller than the outer diameter of the rubber tube 1, that is, the inner diameter of the vulcanized can 9, and its insertion Is easy.

さらに、加硫缶9に端部押さえ金具10を装着して、その未加硫ゴム筒押さえボルト20を調節して、未加硫ゴム筒8の端部を押さえる。また、金属管6及び加硫缶9に熱媒体を給入して循環させることにより、未加硫ゴム筒8を内外から加熱する。この加熱の開始と共に、端部押さえ金具10の筒状ゴム押さえボルト19を調節して筒状ゴム5の引き伸ばしを解除して、筒状ゴム5の長さをL1にしつつ外径をD1まで拡径した後、さらに筒状ゴム押さえボルト19を調節して筒状ゴム5の長さをL3まで圧縮しつつ外径を拡径させる。また、筒状ゴム5の熱膨張によって外径をD3(例えばφ38mm)まで拡径する。これにより、未加硫ゴム筒8が加熱されつつ、加硫缶9の内周面に押し付けられて加圧されて加硫成形される。   Further, the end holding metal fitting 10 is attached to the vulcanized can 9 and the unvulcanized rubber cylinder holding bolt 20 is adjusted to hold the end of the unvulcanized rubber cylinder 8. In addition, the unvulcanized rubber cylinder 8 is heated from inside and outside by supplying a heat medium to the metal tube 6 and the vulcanizing can 9 and circulating it. As the heating starts, the cylindrical rubber holding bolt 19 of the end holding metal fitting 10 is adjusted to release the expansion of the cylindrical rubber 5, and the outer diameter is expanded to D1 while the length of the cylindrical rubber 5 is set to L1. After the diameter, the cylindrical rubber pressing bolt 19 is further adjusted to expand the outer diameter while compressing the length of the cylindrical rubber 5 to L3. Further, the outer diameter of the cylindrical rubber 5 is expanded to D3 (for example, φ38 mm) by thermal expansion. As a result, the unvulcanized rubber cylinder 8 is heated and pressed against the inner peripheral surface of the vulcanizing can 9 to be vulcanized and molded.

その後、図4(f)に示すように、筒状ゴム5の長さを再びL2まで引き伸ばしつつ、外径をD2まで縮径させて、マンドレル7及び加硫缶9から加硫成形後のゴムチューブ1を取り出す。このとき、筒状ゴム5をD2まで縮径しているのでゴムチューブ1の取り出しが容易である。   Thereafter, as shown in FIG. 4 (f), the length of the cylindrical rubber 5 is again extended to L2, the outer diameter is reduced to D2, and the rubber after vulcanization molding from the mandrel 7 and the vulcanizing can 9 is obtained. Remove tube 1. At this time, since the diameter of the cylindrical rubber 5 is reduced to D2, the rubber tube 1 can be easily taken out.

上記構成によれば、筒状ゴム5に補強コード層11を設けるので、筒状ゴム5の両端に加えた力を中央部にまで伝えると共に、補強コード層11のパンタグラフ作用により、筒状ゴム5を縮径及び拡径させることができる。しかも、補強コード12の傾斜角度(θ)を筒状ゴム5の中央部ほど大きく設定するので、筒状ゴム5を全長に渡って均一に縮径及び拡径することができ、未加硫ゴム筒8を全長に渡って強くかつ均一に加圧することができる。   According to the above configuration, since the reinforcing cord layer 11 is provided on the cylindrical rubber 5, the force applied to both ends of the cylindrical rubber 5 is transmitted to the central portion, and the pantograph action of the reinforcing cord layer 11 causes the cylindrical rubber 5 to be transmitted. Can be reduced in diameter and expanded. Moreover, since the inclination angle (θ) of the reinforcing cord 12 is set to be larger toward the center of the cylindrical rubber 5, the cylindrical rubber 5 can be uniformly reduced in diameter and expanded over the entire length, and unvulcanized rubber. The cylinder 8 can be pressed strongly and uniformly over the entire length.

これにより、中心軸方向長さ(L)と外径(D)との比(L/D)が3〜20程度の小口径で中尺、かつ高品質のゴムチューブ1を製造することができる。また、筒状ゴム5を縮径した状態で加硫缶9に挿入し、かつ引き出すので加硫成形型4のセット及び取り外しを容易にすることができる。   As a result, it is possible to manufacture a rubber tube 1 having a medium size and high quality with a small diameter of about 3 to 20 (L / D) between the length (L) in the central axis direction and the outer diameter (D). . Moreover, since the cylindrical rubber 5 is inserted into the vulcanizing can 9 with a reduced diameter and pulled out, the vulcanizing mold 4 can be easily set and removed.

未加硫ゴム筒8を外金型としての加硫缶9で覆って内側から加圧するので、ゴムチューブ1の外径精度を高め、かつ所望の表面光沢を得ることができる。また、二つ割りの外金型を使用しないので、割り面からの未加硫ゴムの不均一な流出によって補強繊維3を露出させることがなく、補強繊維を有し、かつ外面ゴムの薄いゴムチューブを製造することができる。   Since the unvulcanized rubber cylinder 8 is covered with a vulcanizing can 9 as an outer mold and pressurized from the inside, the outer diameter accuracy of the rubber tube 1 can be increased and a desired surface gloss can be obtained. Further, since the split outer mold is not used, the reinforcing fiber 3 is not exposed by the non-uniform flow of the unvulcanized rubber from the split surface, and the rubber tube having the reinforcing fiber and having the thin outer rubber is formed. Can be manufactured.

二つ割りの外型が不要な分、加硫缶9が安価であり、しかも、安価かつ寿命の長いシリコンゴムからなる筒状ゴム5を使用するので、加硫成形型4の初期コスト及びその消耗品のコストを抑えることができる。   The vulcanizing can 9 is inexpensive because the split outer mold is unnecessary, and the cylindrical rubber 5 made of silicon rubber that is inexpensive and has a long life is used. Therefore, the initial cost of the vulcanizing mold 4 and its consumables Costs can be reduced.

なお、本発明は、上記の実施の形態に限定されるものではなく、本発明の範囲内において、適宜変更を加えることができる。例えば、ゴムチューブ1に代えて、空気ばねのダイヤフラムや、タイヤ、配管継手などの、あらゆるゴム製筒体を製造することができる。   In addition, this invention is not limited to said embodiment, A change can be suitably added within the scope of the present invention. For example, instead of the rubber tube 1, all rubber cylinders such as an air spring diaphragm, a tire, and a pipe joint can be manufactured.

補強コード層11は、1本の補強コード12をその傾斜角度(θ)を変化させながら繰り返し巻き付けて形成してもよく、数本の補強コード12をそのコード間隔を変化させつつ巻き付けて形成してもよい。また、二層の補強コード層11に代えて、補強コード12を偶数列に配列するようにしてもよい。この場合、補強コード11をマンドレル中心軸に対して傾斜させつつ周方向かつ偶数列に配列すると共に、対をなす列の補強コード12の傾斜方向(θ)を互いに交差するよう設定すればよい。   The reinforcing cord layer 11 may be formed by repeatedly winding one reinforcing cord 12 while changing the inclination angle (θ), or by forming several reinforcing cords 12 while changing the cord interval. May be. Further, instead of the two reinforcing cord layers 11, the reinforcing cords 12 may be arranged in even rows. In this case, the reinforcing cords 11 may be arranged in the circumferential direction and even rows while being inclined with respect to the central axis of the mandrel, and the inclination directions (θ) of the reinforcing cords 12 in a pair of rows may be set to intersect each other.

筒状ゴム5は、シリコンゴム以外の耐熱性ゴムから形成することもできる。補強コード12は、アラミッド中繊維からなるコードに代えて、伸びにくいスチールコードなどの他のコードを使用することもできる。   The cylindrical rubber 5 can also be formed from a heat resistant rubber other than silicon rubber. As the reinforcing cord 12, instead of a cord made of aramid medium fiber, other cords such as a steel cord which does not easily stretch can be used.

本発明に係る方法で製造するゴムチューブを示す図であり、上半分は断面図、下半分は側面図It is a figure which shows the rubber tube manufactured with the method which concerns on this invention, an upper half is sectional drawing, a lower half is a side view マンドレルを示す図であり、上半分は断面図、下半分は側面図It is a figure which shows a mandrel, an upper half is sectional drawing, a lower half is a side view ゴムチューブの製造方法の前半の工程を示す図The figure which shows the process of the first half of the manufacturing method of a rubber tube ゴムチューブの製造方法の後半の工程を示す図The figure which shows the process of the latter half of the manufacturing method of a rubber tube

符号の説明Explanation of symbols

1 ゴムチューブ
3 補強繊維
4 加硫成形型
5 筒状ゴム
6 金属管
7 マンドレル
8 未加硫ゴム筒
9 加硫缶
11 補強コード層
12 補強コード
DESCRIPTION OF SYMBOLS 1 Rubber tube 3 Reinforcing fiber 4 Vulcanization mold 5 Cylindrical rubber 6 Metal tube 7 Mandrel 8 Unvulcanized rubber cylinder 9 Vulcanized can 11 Reinforcement cord layer 12 Reinforcement cord

Claims (8)

マンドレルの周りに未加硫ゴム筒を成型して加硫成形するゴム製筒体の製造方法であって、
前記マンドレルは、芯材の周りに筒状ゴムを配置してなり、該筒状ゴムに、補強コードをマンドレル中心軸に対して傾斜させつつ周方向かつ偶数列に配列すると共に、対をなす列の補強コードの傾斜方向を互いに交差するよう設定してなる補強コード層が設けられ、
前記筒状ゴムの両端を引っ張ることにより、マンドレル中心軸に対する前記補強コードの傾斜角度を変化させながら、筒状ゴムをマンドレル中心軸方向に引き伸ばしつつ縮径させ、次いで、マンドレルの周りに未加硫ゴム筒を成型してこれらを加硫缶に挿入した後、前記筒状ゴムの引き伸ばしを解除して拡径することにより、前記未加硫ゴム筒を加硫缶の内周面に押し付けて加圧しつつ加熱して加硫成形し、その後、前記筒状ゴムを再び引き伸ばしつつ縮径させて、マンドレル及び加硫缶からゴム製筒体を取り出すことを特徴とするゴム製筒体の製造方法。
A method for producing a rubber cylinder in which an unvulcanized rubber cylinder is molded around a mandrel and vulcanized,
The mandrel is formed by arranging a cylindrical rubber around a core material, and in the cylindrical rubber, reinforcing cords are arranged in a circumferential direction and even rows while being inclined with respect to the central axis of the mandrel, and a pair of rows. Reinforcement cord layer formed by setting the inclination directions of the reinforcement cords to cross each other is provided,
By pulling both ends of the cylindrical rubber, the diameter of the cylindrical rubber is reduced while extending in the direction of the central axis of the mandrel while changing the inclination angle of the reinforcing cord with respect to the central axis of the mandrel, and then unvulcanized around the mandrel. After the rubber cylinders are molded and inserted into the vulcanizing can, the unvulcanized rubber cylinder is pressed against the inner peripheral surface of the vulcanizing can by releasing the expansion of the cylindrical rubber and expanding the diameter. A method for producing a rubber cylinder, wherein the rubber cylinder is vulcanized by heating while pressing, and then the diameter of the cylindrical rubber is reduced while being stretched again, and the rubber cylinder is taken out of the mandrel and the vulcanizing can.
前記マンドレル及び未加硫ゴム筒を加硫缶に挿入した後、筒状ゴムの引き伸ばしを解除すると共に、筒状ゴムをマンドレル中心軸方向に圧縮して拡径することにより、前記未加硫ゴム筒を加硫缶の内周面に押し付けて加圧することを特徴とする請求項1に記載のゴム製筒体の製造方法。   After inserting the mandrel and the unvulcanized rubber cylinder into the vulcanized can, releasing the expansion of the cylindrical rubber and compressing the cylindrical rubber in the direction of the central axis of the mandrel to expand the diameter, the unvulcanized rubber 2. The method for producing a rubber cylinder according to claim 1, wherein the cylinder is pressed against the inner peripheral surface of the vulcanizing can and pressurized. 前記ゴム製筒体の中心軸方向長さ(L)と外径(D)との比(L/D)を3〜20の範囲に設定することを特徴とする請求項1又は2に記載のゴム製筒体の製造方法。   The ratio (L / D) between the length (L) in the central axis direction of the rubber cylinder and the outer diameter (D) is set in the range of 3 to 20, according to claim 1 or 2. Manufacturing method of rubber cylinder. 前記未加硫ゴム筒に補強繊維を埋設することを特徴とする請求項1、2又は3に記載のゴム製筒体の製造方法。   The method for producing a rubber cylinder according to claim 1, 2 or 3, wherein reinforcing fibers are embedded in the unvulcanized rubber cylinder. 請求項1〜4のいずれかに記載の方法によってゴムチューブを製造することを特徴とするゴムチューブの製造方法。   A rubber tube is manufactured by the method in any one of Claims 1-4, The manufacturing method of the rubber tube characterized by the above-mentioned. 周囲に未加硫ゴム筒を成型するマンドレルと、該マンドレルと共に挿入された未加硫ゴム筒を加圧及び加熱する加硫缶とを備え、前記マンドレルは、芯材の周りに筒状ゴムを配置してなり、該筒状ゴムに、補強コードをマンドレル中心軸に対して傾斜させつつ周方向かつ偶数列に配列すると共に、対をなす列の補強コードの傾斜方向を互いに交差するよう設定してなる補強コード層が設けられたことを特徴とする加硫成形型。   A mandrel that molds an unvulcanized rubber cylinder around the mandrel; and a vulcanization can that pressurizes and heats the unvulcanized rubber cylinder inserted together with the mandrel. The mandrel has a cylindrical rubber around the core. The reinforcing cords are arranged on the cylindrical rubber in a circumferential direction and even rows while being inclined with respect to the central axis of the mandrel, and the inclination directions of the reinforcing cords in a pair of rows are set to intersect each other. A vulcanization mold characterized in that a reinforcing cord layer is provided. 前記補強コードは、マンドレルの両端よりも中央ほど、マンドレル中心軸に対する傾斜角度が大きく設定されたことを特徴とする請求項6に記載の加硫成形型。   The vulcanization mold according to claim 6, wherein the reinforcing cord has a larger inclination angle with respect to the mandrel central axis toward the center than both ends of the mandrel. 前記筒状ゴムは、シリコンゴムから形成されたことを特徴とする請求項6又は7に記載の加硫成形型。   The vulcanization mold according to claim 6 or 7, wherein the cylindrical rubber is made of silicon rubber.
JP2007039056A 2007-02-20 2007-02-20 Manufacturing method for rubber cylinder, manufacturing method for rubber tube, and vulcanization mold Withdrawn JP2008200974A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105291317A (en) * 2015-11-12 2016-02-03 东华大学 Cylindrical die with variable external diameter
CN114670377A (en) * 2022-04-09 2022-06-28 河北圣耐普特矿山设备有限公司 Rubber casting pipeline vulcanization process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105291317A (en) * 2015-11-12 2016-02-03 东华大学 Cylindrical die with variable external diameter
CN114670377A (en) * 2022-04-09 2022-06-28 河北圣耐普特矿山设备有限公司 Rubber casting pipeline vulcanization process

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