JP2008188892A - Method of molding plastic joint molding and mold for it - Google Patents

Method of molding plastic joint molding and mold for it Download PDF

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JP2008188892A
JP2008188892A JP2007026191A JP2007026191A JP2008188892A JP 2008188892 A JP2008188892 A JP 2008188892A JP 2007026191 A JP2007026191 A JP 2007026191A JP 2007026191 A JP2007026191 A JP 2007026191A JP 2008188892 A JP2008188892 A JP 2008188892A
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resin member
mold
molding
soft
soft resin
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Toshio Isshiki
利男 一色
Kenji Isshiki
健二 一色
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ISSHIKI SEISAKUSHO KK
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ISSHIKI SEISAKUSHO KK
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined

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  • Injection Moulding Of Plastics Or The Like (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method of molding a joint molding rarely causing separation of a hard resin member from a soft resin member and a mold for the method. <P>SOLUTION: The method is used to mold a plastic joint molding in which a hard resin member is joined with a soft resin member and comprises the hard resin member arranging process of arranging a hard resin member having been injection-molded in a mold for molding of a soft resin member and the soft resin member injecting process of injecting a soft resin member into the cavity of the mold. The mold for molding a joint molding is capable of preventing detachment by causing a soft resin member to penetrate a through-hole of the hard resin member and to mount the soft resin member securely and has a fixing implement, a holder, a flash-preventive pressing implement and a protruding device. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、硬度の異なるプラスチック成形品を重ねあわせ形成したプラスチック接合成形品の成形方法および硬質樹脂部材と軟質樹脂部材を積層成形するためのプラスチック接合成形品の成形用の金型に関する。   The present invention relates to a method for molding a plastic bonded product in which plastic molded products having different hardnesses are overlapped, and a mold for molding a plastic bonded molded product for laminating a hard resin member and a soft resin member.

使用目的に合わせて硬度の異なるプラスチック樹脂部材を複数枚重ね合わせて硬度の異なるプラスチックの積層したプラスチックの合成体を成形することが試みられている。身体に接触する部分に軟質樹脂部材を外面の当接面に硬質樹脂部材を配置した構造のプラスチック合成品が使用されている。外部からの衝撃に耐えられる当接面には硬度のある硬質樹脂部材を利用した外側保護部を用い、また、身体等に接触する可能性のある部分には比較的柔らかい内側部材として軟質樹脂部材を利用し、これを一体とした製品がプラスチック成形できることが望ましい。
軟質樹脂部材と硬質樹脂部材を一体成形することは、可能であるが、溶融温度の異なる熱可塑性樹脂を硬化させて形成する場合、一度の成形では困難であった。このような2重構造のプラスチックの積層体を作成する場合、まず溶融温度の高い樹脂素材を事前の第一次工程として片方の樹脂部材を射出成形して用意し、第二次の工程として既に射出成形して安定状態となっている樹脂部材を第二次工程の金型のキャビティ内に配置して別の樹脂部材を金型内に射出成形することが考えられる。(特許文献1乃至2参照)
Attempts have been made to mold a plastic composite in which a plurality of plastic resins having different hardnesses are laminated by overlapping a plurality of plastic resin members having different hardnesses in accordance with the purpose of use. A plastic composite having a structure in which a soft resin member is disposed on a portion in contact with the body and a hard resin member is disposed on an abutting surface of the outer surface is used. A contact surface that can withstand external impacts uses an outer protective part that uses a hard resin member with hardness, and a soft resin member as a relatively soft inner member for a part that may come into contact with the body or the like It is desirable that a product in which this is integrated can be plastic molded.
Although it is possible to integrally mold the soft resin member and the hard resin member, it is difficult to perform molding once when the thermoplastic resin having different melting temperatures is cured. When creating such a double-layered plastic laminate, first prepare a resin material with a high melting temperature by injection molding one resin member as a prior primary process, and already as a secondary process. It is conceivable that the resin member that is in a stable state after injection molding is placed in the mold cavity of the secondary process and another resin member is injection molded into the mold. (See Patent Documents 1 and 2)

安定状態となっている樹脂部材が加熱によって軟化するのでこのような簡便な方法では限られた硬度と溶融温度の樹脂素材しか利用できず、比較的硬めの製品しかできないのが実情であった。また従来例では、外側の硬質樹脂部材の選択は比較的自由であるが内側の衝撃吸収用の樹脂としてはエラストマのような軟質樹脂部材を利用することができず、使用に耐える適度な硬さのプラスチックの異なる硬度のプラスチックを積層した合成体を作成することは困難であった。
プラスチック製の合成体は、スポーツの保護具として利用されている。例えばサッカーのスネ当てであるシンガードにあっては、外部側に硬質樹脂が使用され、硬質樹脂でできた板部の内側面に軟質の樹脂部材からなる衝撃吸収部が設けられている。(特許文献3参照)。
Since the resin member in a stable state is softened by heating, such a simple method can use only a resin material having limited hardness and melting temperature, and can only produce a relatively hard product. In addition, in the conventional example, the selection of the outer hard resin member is relatively free, but a soft resin member such as an elastomer cannot be used as the inner shock absorbing resin, and it has an appropriate hardness to withstand use. It was difficult to produce a composite of different plastics of different hardness.
A plastic composite is used as a protective device for sports. For example, in a shin guard that is a sneak pad for soccer, a hard resin is used on the outside, and an impact absorbing portion made of a soft resin member is provided on the inner surface of the plate made of the hard resin. (See Patent Document 3).

そこで、プラスチックの成形を可能にした硬度を改良した、軟質樹脂部材を接触面に装備したプラスチック製の接合成品の成形方法および接合成品の安価なる安定提供が待たれていた。   Therefore, there has been a demand for a method for forming a plastic contact synthetic product having a soft resin member provided on the contact surface with improved hardness that enables plastic molding and a stable and inexpensive provision of the contact composite product.

特許公開2002−361768号公報Japanese Patent Publication No. 2002-361768 特許公開2003−103561号公報Japanese Patent Publication No. 2003-103561 登録実用新案第3051104号公報Registered Utility Model No. 3051104

本発明は上記問題を解決するために、硬質樹脂部材と軟質樹脂部材が分離しないように接合するために、硬質樹脂部材を予め射出成形しておいて、軟質樹脂部材の射出成形にあたって、予め射出成形した硬質樹脂部材を軟質射出成形の金型のキャビティの中に配置して軟質樹脂素材を射出成形する方法をとることにより、軟質樹脂部材が硬質樹脂部材に設けられた貫通孔に入り込んで堅固に装着されることにより剥離することを防止できるプラスチック接合成形品を形成する方法およびそのための金型を提供することを目的としている。   In order to solve the above-described problem, the present invention is such that the hard resin member and the soft resin member are joined so that the hard resin member and the soft resin member are not separated from each other. By placing the molded hard resin member in the cavity of the soft injection mold and injecting the soft resin material, the soft resin member enters the through-hole provided in the hard resin member and is firmly fixed. An object of the present invention is to provide a method for forming a plastic bonded molded product that can be prevented from being peeled off by being attached to the mold, and a mold therefor.

上記課題を達成するために本発明に係るプラスチック接合成形品の成形方法は、硬質樹脂部材に軟質樹脂部材を接合するプラスチック接合成形品の成形方法であって、成形された硬質樹脂部材を軟質樹脂部材の成形用の金型内に配置する硬質樹脂部材配置工程と、軟質樹脂部材を金型のキャビティに射出する軟質樹脂部材射出工程と、からなる構成である。
また、軟質樹脂部材を金型に射出する軟質樹脂部材射出工程は、射出する軟質樹脂部材の樹脂温度を170度〜230度に設定する構成である。
さらに軟質樹脂部材射出工程は、軟質樹脂部材を硬質樹脂部材の周縁部に被覆する構成でもある。
In order to achieve the above object, a method for molding a plastic joint molded product according to the present invention is a method for molding a plastic joint molded product in which a soft resin member is joined to a hard resin member, and the molded hard resin member is a soft resin. This is a configuration comprising a hard resin member placement step for placing in a mold for molding a member and a soft resin member injection step for injecting a soft resin member into a cavity of the die.
The soft resin member injection step of injecting the soft resin member into the mold is configured to set the resin temperature of the soft resin member to be injected to 170 degrees to 230 degrees.
Further, the soft resin member injection step has a configuration in which the peripheral edge portion of the hard resin member is coated with the soft resin member.

また、硬質樹脂部材は、硬質樹脂部材は、硬質塩化ビニル樹脂、またはポリプロピレン(PP)・ポリエチレン(PE)等のオレフィン系樹脂、またはポリスチレン(PS)・アクリロニトリルブタジエンスチレン(ABS)等のスチレン系樹脂、さらにポリカーボネート(PC)・ポリカーボネートとABSのアロイ樹脂等のポリカーボネート系樹脂、さらにまたポリエチレンテレフタレート・ポリブチレンテレフタレート等のテレフタレート系樹脂のような熱可塑性樹脂素材、または熱硬化樹脂等の樹脂素材を射出成形する構成でもある。
さらに軟質樹脂部材は、軟質塩化ビニル樹脂、またはスチレン系エラストマー、塩ビ系エラストマー、オレフィン系エラストマー、ウレタン系エラストマー、ポリエステル系エラストマー、ニトリル系エラストマー、ポリアミド系エラストマー、フッ素系エラストマー等の熱可塑性エラストマー、からなる構成である。
The hard resin member is a hard vinyl chloride resin, an olefin resin such as polypropylene (PP) / polyethylene (PE), or a styrene resin such as polystyrene (PS) / acrylonitrile butadiene styrene (ABS). In addition, polycarbonate resin such as polycarbonate (PC) / polycarbonate and ABS alloy resin, thermoplastic resin material such as terephthalate resin such as polyethylene terephthalate / polybutylene terephthalate, or resin material such as thermosetting resin is injected. It is also the structure to shape | mold.
Further, the soft resin member is composed of a soft vinyl chloride resin or a thermoplastic elastomer such as a styrene elastomer, a vinyl chloride elastomer, an olefin elastomer, a urethane elastomer, a polyester elastomer, a nitrile elastomer, a polyamide elastomer, and a fluorine elastomer. It is the composition which becomes.

また、硬質樹脂部材は、周縁に1つ若しくは複数の孔を穿設した構成であり、周縁に本体に比べて薄く形成した周縁部を周設した構成である。さらに、硬質樹脂部材は、軟質樹脂部材の成形用の金型に確実に装着させるために、硬質樹脂部材を貫通する孔が一つ若しくは複数穿設されている構成である。   Further, the hard resin member has a configuration in which one or a plurality of holes are formed in the periphery, and a periphery in which the periphery is formed thinner than the main body is provided in the periphery. Further, the hard resin member has a structure in which one or a plurality of holes penetrating the hard resin member are formed so as to be securely attached to a mold for molding the soft resin member.

一方、軟質樹脂部材の射出成形用の金型は、成形機用の金型であって硬質樹脂部材を金型に固定する為の細棒状の固定具が軟質樹脂部材の成形用の金型のキャビティ(空洞部)に向かって水平方向に一つ若しくは複数立設されている構成である。
また、硬質樹脂部材が軟質樹脂部材の加圧射出時に金型内に加えられる圧力により変形すること又はズレることを防ぐために、硬質樹脂部材の周縁をキャビティ側に押圧保持する凸状の保持具がキャビティ(空洞部)に向かって水平方向に一つ若しくは複数立設されている構成である。
また、前記硬質樹脂部材の周縁部に軟質部材を被覆形成する際に生じる端縁の余分なバリの発生を防止するために、硬質樹脂部材の端部付近で被覆しない部分の裏面に当接し押圧する凸状のバリ防止押圧具がキャビティ(空洞部)に向かって水平方向に一つ若しくは複数立設されている構成である。
On the other hand, a mold for injection molding of a soft resin member is a mold for a molding machine, and a thin rod-shaped fixture for fixing a hard resin member to the mold is a mold for molding a soft resin member. One or more of them are erected in the horizontal direction toward the cavity (hollow part).
Further, in order to prevent the hard resin member from being deformed or displaced due to the pressure applied in the mold during the pressure injection of the soft resin member, there is a convex holder that presses and holds the periphery of the hard resin member toward the cavity. One or more of them are erected in the horizontal direction toward the cavity (hollow part).
In addition, in order to prevent the occurrence of excessive burrs on the edge that occurs when the soft member is coated on the peripheral edge of the hard resin member, it is pressed against the back surface of the portion not covered near the end of the hard resin member. In this configuration, one or a plurality of convex deburring prevention pressing tools are erected in the horizontal direction toward the cavity (hollow portion).

さらに、金型は、射出成形終了後に成形したプラスチック接合成形品を金型から確実に破損することなく剥離させるために、任意の操作で成形品が斜めに突き出されるように水平方向にピンを突出する突出装置をゲート付近に配備した構成でもある。また、軟質樹脂部材を金型に設置した前記硬質樹脂部材の横方向から射出できるように、金型の上方若しくは側面方向若しくは下方に軟質樹脂部材を射出するゲートを形成した構成か、または、軟質樹脂部材を金型に設置した前記硬質樹脂部材の被覆面の中央から射出できるように、金型の中央に軟質樹脂部材を射出するゲートを形成した構成であってもよい。   In addition, the mold has a horizontal pin so that the molded product can be ejected diagonally in any operation in order to ensure that the plastic joint molded product molded after the completion of injection molding is peeled from the mold without damage. It is also a configuration in which a protruding device that protrudes is arranged near the gate. Also, a structure in which a gate for injecting the soft resin member is formed on the upper side, the side surface, or the lower side of the mold so that the soft resin member can be injected from the lateral direction of the hard resin member installed in the mold, or soft The structure which formed the gate which inject | emits a soft resin member in the center of a metal mold | die so that the resin member can be injected from the center of the coating surface of the said hard resin member installed in the metal mold | die may be sufficient.

本発明にかかるプラスチック接合成形品の成形方法およびプラスチック接合成形品の成形用の金型は上記のような構成であるので、以下のような効果を奏する。
1.予め射出成形された硬質樹脂部材を軟質樹脂部材の射出成形する金型に装着してから軟質樹脂素材を金型のキャビティに射出するので軟質樹脂部材が射出の圧力で硬質樹脂部材に十分に密着接合するので硬質樹脂部材の内側に軟質部材が装着されるので、例えば肌に接触する面に軟質部材を当てれば十分の硬度と肌にやさしい接触が得られる。
2.硬質樹脂部材と軟質樹脂部材とを重ね合わせる工程の射出する軟質樹脂部材の樹脂温度を170度〜230度に設定しているので、軟質樹脂部材が可塑状態であるのに対して硬質樹脂部材が可塑状態に近づけることにより融着させることができる利点がある。
3.軟質樹脂部材を硬質樹脂部材の周縁部にも被覆しているので、硬質樹脂部材から軟質樹脂部材が剥がれ落ちることがない。
Since the molding method for plastic joint molded products and the mold for molding plastic joint molded products according to the present invention have the above-described configuration, the following effects can be obtained.
1. A soft resin material is injected into the mold cavity after mounting the pre-injected hard resin member to the mold for injection molding of the soft resin member, so the soft resin member is in close contact with the hard resin member by the injection pressure Since the soft members are attached to the inside of the hard resin member because they are joined, for example, if the soft member is applied to the surface in contact with the skin, sufficient hardness and contact friendly to the skin can be obtained.
2. Since the resin temperature of the soft resin member to be injected in the process of superimposing the hard resin member and the soft resin member is set to 170 degrees to 230 degrees, the soft resin member is in a plastic state, whereas the hard resin member There exists an advantage which can be made to fuse | melt by approaching a plastic state.
3. Since the soft resin member is also coated on the peripheral portion of the hard resin member, the soft resin member is not peeled off from the hard resin member.

4.利用できる硬質樹脂素材としては、硬質塩化ビニル樹脂、またはポリプロピレン(PP)・ポリエチレン(PE)等のオレフィン系樹脂、またはポリスチレン(PS)・アクリルニトリルブタジエンスチレン(ABS)等のスチレン系樹脂、さらにポリカーボネート(PC)・ポリカーボネートとABSのアロイ樹脂等のポリカーボネート系樹脂、さらにまたポリエチレンテレフタレート・ポリブチレンテレフタレート等のテレフタレート系樹脂のような熱可塑性樹脂素材、または熱硬化樹脂等の樹脂素材が利用可能であるので、殆どの素材が便利である。
5.軟質樹脂素材としては、軟質塩化ビニル樹脂、またはスチレン系エラストマー、塩ビ系エラストマー、オレフィン系エラストマー、ウレタン系エラストマー、ポリエステル系エラストマー、ニトリル系エラストマー、ポリアミド系エラストマー、フッ素系エラストマー等の熱可塑性エラストマーが利用できるので充分に軟度の高い素材でも使用可能である。
4). Available hard resin materials include hard vinyl chloride resins, olefin resins such as polypropylene (PP) and polyethylene (PE), styrene resins such as polystyrene (PS) and acrylonitrile butadiene styrene (ABS), and polycarbonate. (PC) Polycarbonate resins such as polycarbonate and ABS alloy resins, and thermoplastic resin materials such as terephthalate resins such as polyethylene terephthalate and polybutylene terephthalate, or resin materials such as thermosetting resins can be used. So most materials are convenient.
5. As the soft resin material, soft vinyl chloride resin or thermoplastic elastomer such as styrene elastomer, vinyl chloride elastomer, olefin elastomer, urethane elastomer, polyester elastomer, nitrile elastomer, polyamide elastomer, fluorine elastomer, etc. is used. Because it can be used, it is possible to use even a sufficiently soft material.

6.硬質樹脂部材の周縁に複数の孔を穿設し、その孔の中に軟質樹脂部材を埋め込むので軟質樹脂部材は硬質樹脂部材から簡単には離れることはないので激しい運動の際にも防具として充分に機能を果たすことができる。
7.また、硬質樹脂部材の周縁に本体に比べて薄く形成した周縁部を周設する構成を採用した構成では、更に多くの軟質樹脂部材が周縁を取り囲むので、硬質樹脂部材から軟質樹脂部材が外れることはない。
8.さらに、孔を硬質樹脂部材の本体の中央に貫通する孔を穿孔する構成とすることにより軟質樹脂部材はその孔にも入ってさらに硬質樹脂部材から離れ難くなる。
9.軟質樹脂部材の金型のキャビティの中に硬質樹脂素材で形成された成形品を挿入させて固定するピンが立設されているので、硬質樹脂部材に設けられた孔にそのピンを挿入するだけの簡単な機構で硬質樹脂部材を金型内で固定することができる。
6). A plurality of holes are made in the periphery of the hard resin member, and the soft resin member is embedded in the hole, so the soft resin member is not easily separated from the hard resin member. Can fulfill the function.
7). Moreover, in the structure which employ | adopted the structure which arrange | positions the peripheral part formed thinly compared with the main body at the periphery of a hard resin member, since many soft resin members surround a periphery, a soft resin member remove | deviates from a hard resin member. There is no.
8). Furthermore, by adopting a configuration in which the hole is formed so as to penetrate the center of the main body of the hard resin member, the soft resin member also enters the hole and is further difficult to be separated from the hard resin member.
9. Since a pin for inserting and fixing a molded product made of a hard resin material is erected in the cavity of the mold of the soft resin member, just insert the pin into the hole provided in the hard resin member With this simple mechanism, the hard resin member can be fixed in the mold.

10.また、硬質樹脂部材が軟質樹脂素材を射出する際に金型内で変形したりずれるのを防ぐために、金型の硬質樹脂部材の周縁に保持ピンがキャビティ(空洞部)に向かって水平方向に一つ若しくは複数立設されているので簡単な構造で変形またはズレを防止することができる。
11.硬質樹脂部材の周縁に余分な軟質樹脂部材がバリとして入り込まないように硬質樹脂部材を強く金型に押し付けて軟質樹脂部材の流入を防いでいるので仕上がりが大変綺麗である。
12.完成品である接合成形品を金型から取り出す際に綺麗に剥離できるように軟質樹脂部材と金型との間に空気を導入する剥離のための突出装置が金型に設けられているので、充分柔らかい接合成形品であっても損傷することなく射出成形機の金型から剥離することができる。
13.軟質樹脂部材の射出ゲートは何処に設けてもよいが、圧力と破損の可能性を考えて、上端や側端に設けているので邪魔にならずに取出しが簡便である。
14.射出ゲートは、軟質樹脂部材の圧力を均等に及ぼすという観点から接合成形品の中央に設けることも可能である。
10. Also, in order to prevent the hard resin member from being deformed or displaced in the mold when injecting the soft resin material, a holding pin is placed horizontally on the periphery of the hard resin member of the mold toward the cavity (cavity). Since one or more of them are erected, deformation or displacement can be prevented with a simple structure.
11. The finish is very beautiful because the hard resin member is strongly pressed against the mold to prevent the excess soft resin member from entering the periphery of the hard resin member as a burr, thereby preventing the inflow of the soft resin member.
12 Since the mold is provided with a protruding device for peeling that introduces air between the soft resin member and the mold so that it can be peeled cleanly when taking out the finished joined product from the mold, Even a sufficiently soft bonded product can be peeled off from the mold of the injection molding machine without being damaged.
13. The injection gate of the soft resin member may be provided anywhere, but considering the possibility of pressure and breakage, it is provided at the upper end and the side end, so that it is easy to take out without obstructing.
14 The injection gate can also be provided in the center of the joint molded product from the viewpoint of applying the pressure of the soft resin member evenly.

以下に本発明に係るプラスチック接合成形品の成形方法およびそれに使用する形成用の金型の構成を図面に示す実施例に基づき詳細に説明する。図1は本発明のプラスチックプラスチック接合成形品の成形方法の工程を示すフローチャートであり、図2はプラスチック接合成形品の成形用の金型の平面図であり、図3は同じくプラスチック接合成形品の成形用の金型の平面図である。図4は軟質樹脂部材の金型に装着する硬質樹脂部材の斜視図であり、図5は同じく硬質樹脂部材の別の実施例の平面図であり、図6は硬質樹脂部材の部分断面図である。   Hereinafter, a method for molding a plastic bonded product according to the present invention and a configuration of a forming mold used therefor will be described in detail based on an embodiment shown in the drawings. FIG. 1 is a flowchart showing the steps of a method for molding a plastic-plastic joint molded product according to the present invention, FIG. 2 is a plan view of a mold for molding a plastic joint-molded product, and FIG. It is a top view of the metal mold | die for shaping | molding. 4 is a perspective view of a hard resin member mounted on a mold of a soft resin member, FIG. 5 is a plan view of another example of the hard resin member, and FIG. 6 is a partial cross-sectional view of the hard resin member. is there.

図1により本発明のプラスチック接合成形品の成形方法を詳細に説明する。
本発明のプラスチック接合成形品の成形方法10は、硬質樹脂部材配置工程20と、軟質樹脂部材射出工程30とからなる。
硬質樹脂部材配置工程20は、予め射出成形され、形状が安定している硬質樹脂部材を軟質樹脂部材の成形用金型に配置する工程20であり、硬質樹脂部材の射出成形については従来例による。この実施例では射出成形により皇室樹脂部材を成形しているが、成形方法には限定されない。硬質樹脂部材配置工程20で使用する硬質樹脂素材としては、ポリプロピレン、ナイロン、ポリウレタン、ポリエステル、ポリエチレン、ポリ塩化ビニル、ポリカボネード、または熱硬化性樹脂等の樹脂材を射出成形したものである。この実施例ではポリプロピレンを使用して射出成形を行っている。
With reference to FIG. 1, the method for molding a plastic bonded product of the present invention will be described in detail.
The plastic bonding molded product molding method 10 of the present invention includes a hard resin member placement step 20 and a soft resin member injection step 30.
The hard resin member placement step 20 is a step 20 in which a hard resin member that has been injection-molded in advance and has a stable shape is placed in a molding die for a soft resin member. . In this embodiment, the imperial resin member is molded by injection molding, but the molding method is not limited. As the hard resin material used in the hard resin member arranging step 20, a resin material such as polypropylene, nylon, polyurethane, polyester, polyethylene, polyvinyl chloride, polycarbonate, or thermosetting resin is injection-molded. In this embodiment, polypropylene is used for injection molding.

軟質樹脂部材射出工程30は、予め射出成形されて形状が安定している硬質樹脂部材40を軟質樹脂部材50の成形用の金型に配置してから軟質樹脂素材を軟質樹脂部材の成形用の金型に射出成形する工程である。
軟質樹脂素材を金型60のキャビティに射出する工程であり、射出成形を行う軟質樹脂素材としては、主に熱可塑性エラストマーであり、スチレン系エラストマー、塩ビ系エラストマー、オレフィン系エラストマー、ウレタン系エラストマー、ポリエステル系エラストマー、ニトリル系エラストマー、ポリアミド系エラストマー、フッ素系エラストマー、が使用される可能性がある。ただし、この実施例ではスチレン系エラストマーを採用している。
In the soft resin member injection step 30, the hard resin member 40, which has been injection molded in advance and has a stable shape, is placed in a mold for molding the soft resin member 50, and then the soft resin material is molded into the soft resin member. This is a process of injection molding into a mold.
This is a step of injecting a soft resin material into the cavity of the mold 60, and the soft resin material for injection molding is mainly a thermoplastic elastomer, such as a styrene elastomer, a vinyl chloride elastomer, an olefin elastomer, a urethane elastomer, Polyester elastomers, nitrile elastomers, polyamide elastomers, and fluorine elastomers may be used. However, in this embodiment, a styrene elastomer is employed.

硬質樹脂部材に軟質樹脂部材を射出成形することは、従来では成形温度の関係で、実現不可能であった。軟質樹脂部材の温度を上げて射出成形を行うと硬質樹脂部材が変形してしまい、逆に温度を下げて射出成形を行うのでは軟質樹脂部材が完全に融着しないことが多く、剥離の原因となる不完全な製品となる可能性が高かった。
本発明のプラスチック接合成形品の成形方法では、詳細にはポリプロピレンを射出成形した硬質樹脂部材40に、190度〜230度の範囲に設定した軟質樹脂部材50を射出成形することにより、硬質樹脂部材が変形せず、確実に融着させることを可能としている。この設定温度は硬質樹脂部材としてポリプロピレン、軟質樹脂部材としてスチレン系エラストマーを選択した場合に実験の結果として得られた許容温度であり、この温度以外でも組み合わせによって他にも適宜に融着する可能性も考えられる。
Conventionally, injection molding of a soft resin member to a hard resin member has been impossible due to the molding temperature. If the temperature of the soft resin member is raised and injection molding is performed, the hard resin member will be deformed. Conversely, if the temperature is lowered and injection molding is performed, the soft resin member is often not completely fused, causing peeling. There was a high possibility of becoming an incomplete product.
More specifically, in the method for molding a plastic bonded product according to the present invention, the hard resin member 50 is injection-molded with the soft resin member 50 set in a range of 190 to 230 degrees on the hard resin member 40 obtained by injection-molding polypropylene. Is not deformed and can be reliably fused. This set temperature is the allowable temperature obtained as a result of the experiment when polypropylene is selected as the hard resin member and styrene elastomer is selected as the soft resin member. Is also possible.

本発明では硬質樹脂部材40に軟質樹脂部材50を確実に融着させるために、硬質樹脂部材の形状を特殊な構造とすることで分離したり破損することのない接合成形品11の完成品の形成を実現可能にしている。軟質樹脂部材射出工程30で射出成形する際に、軟質樹脂部材は流体であるため、硬質樹脂部材の形状によって様々な形状の被覆を可能としている。製品としては、使用中に被覆した軟質樹脂部材が硬質樹脂部材から剥離しないことが最重要課題であり、これを実現するために硬質樹脂部材の周縁に孔を設けて、軟質樹脂部材を硬質樹脂部材の中に埋め込むと同時に周縁を上下両側および端面から被覆することにより剥離しにくい融着を実現している。図4に示すように、この接合を実現するために硬質樹脂部材40の周縁に貫通孔42を穿孔してこの孔にも軟質樹脂部材が流入することにより、より確実に硬質樹脂部材を融着させることを可能にしている。また別の貫通孔43を設けて、軟質樹脂部材を部分的に流入させることも可能である。
さらに、周縁を硬質樹脂部材の中心よりも周縁を薄く設定した周縁部44をもうけ、周縁部44にも孔42を設けることにより軟質樹脂部材を周縁だけ両面に成形されるようにすることも可能である。
In the present invention, in order to surely fuse the soft resin member 50 to the hard resin member 40, a finished product of the joined molded product 11 which is not separated or damaged by making the shape of the hard resin member a special structure. Making it feasible. When injection molding is performed in the soft resin member injection step 30, since the soft resin member is a fluid, various shapes of coating are possible depending on the shape of the hard resin member. As a product, the most important issue is that the soft resin member coated during use does not peel off from the hard resin member. To achieve this, a hole is provided in the periphery of the hard resin member to replace the soft resin member with the hard resin. At the same time as embedding in the member, the peripheral edge is covered from both the upper and lower sides and the end face, thereby realizing fusion that is difficult to peel off. As shown in FIG. 4, in order to realize this joining, a through hole 42 is drilled in the periphery of the hard resin member 40, and the soft resin member flows into this hole, so that the hard resin member is more securely fused. It is possible to make it. It is also possible to provide another through hole 43 and allow the soft resin member to partially flow.
Furthermore, it is also possible to form a soft resin member on both sides only by providing a peripheral edge 44 whose peripheral edge is thinner than the center of the hard resin member and providing a hole 42 in the peripheral edge 44. It is.

次に、本発明のプラスチック接合成品の金型について詳細に説明する。金型60は固定側60aと可動側60bに分けられる。この実施例では可動側に硬質樹脂部材40をキャビティとなる空洞(間隙)を置いて配置する構成である。可動側の金型には、硬質樹脂部材を確実に固定するための固定具62が設けられ、この実施例では確実に固定するために4本の固定具62が配置されている。この固定具は、固定側の金型のキャビティに向かって略水平方向に立設され、硬質樹脂部材40に設けられた孔42に係合して固定する。   Next, the mold of the plastic contact composite product of the present invention will be described in detail. The mold 60 is divided into a fixed side 60a and a movable side 60b. In this embodiment, the hard resin member 40 is arranged on the movable side with a cavity (gap) serving as a cavity. The movable mold is provided with a fixture 62 for securely fixing the hard resin member, and in this embodiment, four fixtures 62 are arranged to securely fix the hard resin member. This fixing tool is erected in a substantially horizontal direction toward the cavity of the mold on the fixed side, and engages with and fixes the hole 42 provided in the hard resin member 40.

また、可動側金型60bには、軟質樹脂部材の射出成形時に硬質樹脂部材が変形若しくはズレを防止するための凸状の保持具66が硬質樹脂部材40を側面から押圧するように形成されている。保持具を設けずに射出成形を行うと、硬質樹脂部材も変形及びズレが生じてしまう場合がある。これを防止し、不良率を下げる効果がある。
さらに、可動側金型60bには、裏面から表面に渡って接合される軟質樹脂部材のバリを防止するために、硬質樹脂部材を裏面から固定側金型方向に押圧するバリ防止押圧部64を複数設けている。図4に開示されている形状の硬質樹脂部材で、周縁だけに軟質樹脂部材を接合させる際に、裏面から押圧することにより、表面の不必要な部分には軟質樹脂部材が接合されないように防止することが可能となる。
Further, the movable mold 60b is formed with a convex holder 66 for pressing the hard resin member 40 from the side surface to prevent the hard resin member from being deformed or displaced during injection molding of the soft resin member. Yes. If injection molding is performed without providing a holder, the hard resin member may also be deformed and misaligned. This has the effect of preventing this and reducing the defect rate.
Further, the movable side mold 60b has a burr prevention pressing portion 64 that presses the hard resin member in the direction of the fixed side mold from the back surface in order to prevent the burr of the soft resin member joined from the back surface to the front surface. There are several. When the soft resin member having the shape disclosed in FIG. 4 is joined only to the periphery, pressing from the back surface prevents the soft resin member from being joined to unnecessary portions of the surface. It becomes possible to do.

さらに、射出成形終了後に成形したプラスチック接合成品を確実に破損することなく剥離させるために、任意の操作で水平方向にピンを突出する突出装置68を設けている。この実施例では、ゲート付近のバリ防止押圧部内部に突出装置68が設けられており、この突出装置により、突出させた際にプラスチック接合成品が斜めに剥がれるため、容易に空気が軟質樹脂部材と金型の間に流入することにより簡単に取り出すことを可能としている。本発明では、軟質樹脂部材にエラストマを採用しているため、水平方向の引っ張り強度は非常に強いものとなっている。従って、空隙を強制的に設けることにより、容易に取り出すことが可能となる。   Furthermore, in order to peel the plastic contact product molded after the completion of the injection molding without causing damage, a projecting device 68 for projecting the pin in the horizontal direction by an arbitrary operation is provided. In this embodiment, a protrusion device 68 is provided inside the burr prevention pressing portion in the vicinity of the gate, and when the protrusion device is protruded by this protrusion device, the plastic contact product is peeled off obliquely, so that the air can be easily separated from the soft resin member. It can be easily taken out by flowing between the molds. In the present invention, since the elastomer is used for the soft resin member, the tensile strength in the horizontal direction is very strong. Therefore, it can be easily taken out by forcibly providing the gap.

次に、本発明のプラスチック接合成品の成形方法を動作手順によって詳細に説明する。
まず、射出成形を行い安定した硬質樹脂部材40を可動側金型60bにセットする。この実施例の硬質樹脂部材は、ポリプロピレンを成形した部材となっており、薄く設定され、さらに複数の孔が穿設された周縁が設けられ、さらに、可動側金型に確実に固定されるための固定具が挿入される孔が4箇所形成されている。この4箇所の孔に固定具を挿入し、成形時に動かないように確実な固定を行う。
Next, the method for molding a plastic contact composite product of the present invention will be described in detail by operating procedures.
First, injection molding is performed and a stable hard resin member 40 is set on the movable mold 60b. The hard resin member of this embodiment is a member molded from polypropylene, is set thin, has a peripheral edge with a plurality of holes, and is securely fixed to the movable mold. Four holes into which the fixtures are inserted are formed. A fixing tool is inserted into these four holes, and fixed securely so as not to move during molding.

また、この金型では、硬質樹脂部材を側面から保持する保持具が3箇所設けられており、確実に固定することにより、保持具が側面から当接する構成である。また、裏面ではバリ防止部が当接する構成でもある。
次に、この状態で軟質樹脂部材の射出成形を行う。この実施例ではスチレン系エラストマーを使用している。スチレン系エラストマーを190度〜230度に設定することにより、硬質樹脂部材が融解せず、確実に接合させることができるためである。固定された硬質樹脂部材に、金型のゲートから軟質樹脂部材が射出される。その時に、射出された軟質樹脂部材50は、硬質樹脂部材40の裏面全体に接合するだけでなく、周縁の孔42により、周縁の表面に流入し、周縁を覆い接合する。周縁を覆う際に、可動側金型に設けられたバリ防止押圧具64により、周縁付近では固定側金型に押圧されている状態であるため、軟質樹脂部材が周縁から広がらずに確実に周縁だけを接合させることが可能である。
この周縁の孔42により、裏面から表面に軟質樹脂部材50が固定されるので、単に裏面から表面に接合させる構造よりも、成形後に軟質樹脂部材が硬質樹脂部材から剥がれることを防止する効果がある。
Further, in this mold, there are provided three holders for holding the hard resin member from the side surface, and the holder comes into contact with the side surface by being securely fixed. In addition, the burr preventing portion is in contact with the back surface.
Next, injection molding of the soft resin member is performed in this state. In this embodiment, a styrene elastomer is used. This is because by setting the styrene-based elastomer at 190 to 230 degrees, the hard resin member does not melt and can be reliably bonded. A soft resin member is injected from the gate of the mold onto the fixed hard resin member. At that time, the injected soft resin member 50 is not only bonded to the entire back surface of the hard resin member 40 but also flows into the peripheral surface through the peripheral hole 42 and covers the peripheral edge. When covering the periphery, the burr prevention pressing tool 64 provided on the movable mold is pressed against the fixed mold in the vicinity of the periphery, so that the soft resin member does not spread from the periphery without fail. It is possible to join only.
Since the soft resin member 50 is fixed from the back surface to the front surface by the peripheral hole 42, there is an effect of preventing the soft resin member from being peeled off from the hard resin member after molding, rather than a structure in which the back surface is simply joined to the front surface. .

射出成形後に硬質樹脂部材40と軟質樹脂部材50が接合したプラスチック接合成品は、可動側金型に密着している状態となる。人の力で強制的に引っ張り剥がすことは可能であるが、確実に安定していない軟質樹脂部材を破損させてしまう虞がある。
また、この実施例で使用しているエラストマーは、密着した状態では簡単に剥がれないことがあるが、吸盤と同様に、空気を流入させることにより簡単に剥がすことができる。そこで、この実施例では、ゲート付近に設けられるバリ防止押圧具の2箇所を中空に設定し、内部にピンが設けられた突出装置を設けることにより、任意、若しくは自動で突出させてプラスチック接合成品を斜めに押し出し、空気を流入させて簡単に取り出せることを可能としている。
The plastic contact synthesized product in which the hard resin member 40 and the soft resin member 50 are joined after the injection molding is in a state of being in close contact with the movable side mold. Although it is possible to forcibly pull it off by human power, there is a risk of damaging a soft resin member that is not stable.
In addition, the elastomer used in this example may not be easily peeled off when in close contact, but can be easily peeled off by inflowing air, similar to the suction cup. Therefore, in this embodiment, two parts of the burr prevention pressing tool provided in the vicinity of the gate are set to be hollow, and a protruding device having a pin provided therein is provided, so that it can be protruded arbitrarily or automatically, and the plastic contact product. Can be easily taken out by injecting air and injecting air.

この実施例では、硬質樹脂部材50の側面方向に設けられたゲート70により軟質樹脂部材を射出させてプラスチック接合成品を製造する方法としているが、ゲートを硬質樹脂部材の裏面中央部から射出する構成とすることにより、確実に成形させることも可能である。   In this embodiment, the plastic resin composite product is manufactured by injecting the soft resin member with the gate 70 provided in the side surface direction of the hard resin member 50. However, the structure in which the gate is injected from the center of the back surface of the hard resin member. By doing so, it is possible to surely form.

プラスチックプラスチック接合成形品の成形方法の工程を示すフローチャートFlow chart showing the steps of molding method for plastic-plastic joint molding プラスチック接合成形品の成形用の金型の平面図Top view of mold for molding plastic joint molding プラスチック接合成形品の成形用の金型の平面図Top view of mold for molding plastic joint molding 軟質樹脂部材の金型に装着する硬質樹脂部材の斜視図A perspective view of a hard resin member mounted on a mold of a soft resin member 同じく硬質樹脂部材の別の実施例の平面図Plan view of another embodiment of the same rigid resin member 硬質樹脂部材の部分断面図Partial sectional view of hard resin member

符号の説明Explanation of symbols

10 プラスチック接合成形品の成形方法
11 接合成形品
20 硬質樹脂部材配置工程
30 軟質樹脂部材射出工程
40 硬質部材
42 貫通孔
43 貫通孔
44 周縁部
50 軟質樹脂部材
60 金型
60a 固定側金型
60b 移動側金型
62 固定具
64 バリ防止押圧部
66 保持具
68 突出装置
70 ゲート
DESCRIPTION OF SYMBOLS 10 Molding method of plastic joint molding 11 Joint molding 20 Hard resin member arrangement | positioning process 30 Soft resin member injection | emission process 40 Hard member 42 Through-hole 43 Through-hole 44 Peripheral part 50 Soft resin member 60 Mold 60a Fixed side metal mold | die 60b Movement Side mold 62 Fixing tool 64 Anti-burr pressing part 66 Holding tool 68 Protruding device 70 Gate

Claims (14)

硬質樹脂部材に軟質樹脂部材を接合するプラスチック接合成形品の成形方法において、
成形された硬質樹脂部材を軟質樹脂部材の成形用の金型内に配置する硬質樹脂部材配置工程と、
軟質樹脂部材を金型のキャビティに射出する軟質樹脂部材射出工程と、
からなることを特徴とするプラスチック接合成形品の成形方法。
In a molding method of a plastic bonded product that joins a soft resin member to a hard resin member,
A hard resin member placement step of placing the molded hard resin member in a mold for molding the soft resin member;
A soft resin member injection step of injecting the soft resin member into the mold cavity;
A method for molding a plastic bonded product, comprising:
前記軟質樹脂部材を金型に射出する軟質樹脂部材射出工程は、射出する軟質樹脂部材の樹脂温度を170度〜230度に設定することを特徴とする請求項1記載のプラスチック接合成形品の成形方法。   2. The molding of a plastic bonded product according to claim 1, wherein in the step of injecting the soft resin member into the mold, the resin temperature of the soft resin member to be injected is set to 170 degrees to 230 degrees. Method. 前記軟質樹脂部材射出工程は、軟質樹脂部材を硬質樹脂部材の周縁部に被覆することを特徴とする請求項1記載のプラスチック接合成形品の成形方法。   The method for molding a plastic bonded product according to claim 1, wherein in the soft resin member injection step, the peripheral edge portion of the hard resin member is coated with the soft resin member. 前記硬質樹脂部材は、硬質塩化ビニル樹脂、またはポリプロピレン(PP)・ポリエチレン(PE)を含むオレフィン系樹脂、またはポリスチレン(PS)・アクリロニトリルブタジエンスチレン(ABS)を含むスチレン系樹脂、さらにポリカーボネート(PC)・ポリカーボネートとABSのアロイ樹脂を含むポリカーボネート系樹脂、さらにまたポリエチレンテレフタレート・ポリブチレンテレフタレートを含むテレフタレート系樹脂のような熱可塑性樹脂素材、または熱硬化性樹脂の樹脂素材を射出成形したことを特徴とする請求項1記載のプラスチック接合成形品の成形方法。   The hard resin member includes a hard vinyl chloride resin, an olefin resin including polypropylene (PP) / polyethylene (PE), a styrene resin including polystyrene (PS) / acrylonitrile butadiene styrene (ABS), and a polycarbonate (PC). -It is characterized by injection molding of a thermoplastic resin material such as polycarbonate resin including polycarbonate and ABS alloy resin, and also terephthalate resin including polyethylene terephthalate and polybutylene terephthalate, or a thermosetting resin resin material. The method for forming a plastic bonded product according to claim 1. 前記軟質樹脂部材は、軟質塩化ビニル樹脂、またはスチレン系エラストマー、塩ビ系エラストマー、オレフィン系エラストマー、ウレタン系エラストマー、ポリエステル系エラストマー、ニトリル系エラストマー、ポリアミド系エラストマー、フッ素系エラストマーを含む熱可塑性エラストマー、であることを特徴とする請求項1記載のプラスチック接合成形品の成形方法。   The soft resin member is a soft vinyl chloride resin or a thermoplastic elastomer including a styrene elastomer, a vinyl chloride elastomer, an olefin elastomer, a urethane elastomer, a polyester elastomer, a nitrile elastomer, a polyamide elastomer, and a fluorine elastomer. The method for molding a plastic bonded product according to claim 1, wherein: 前記硬質樹脂部材は、周縁に1つ若しくは複数の孔を穿設したことを特徴とする請求項1記載のプラスチック接合成形品の成形方法。   The method for molding a plastic bonded product according to claim 1, wherein the hard resin member has one or a plurality of holes formed in a peripheral edge. 前記硬質樹脂部材は、周縁に本体に比べて薄く形成した周縁部を周設したことを特徴とする請求項1記載のプラスチック接合成形品の成形方法。   The method for molding a plastic bonded product according to claim 1, wherein the hard resin member is provided with a peripheral edge portion formed thinner than a main body at a peripheral edge. 前記硬質樹脂部材は、軟質樹脂部材の成形用の金型に確実に装着させるために、硬質樹脂部材を貫通する孔が一つ若しくは複数穿設されていることを特徴とする請求項1記載のプラスチック接合成形品の成形方法。 2. The hard resin member according to claim 1, wherein one or a plurality of holes penetrating the hard resin member are formed in order to securely attach the hard resin member to a mold for molding the soft resin member. Molding method for plastic bonded products. 軟質樹脂部材の射出成形用の金型は、成形機用の金型であって硬質樹脂部材を金型に固定する為の細棒状の固定具が軟質樹脂部材の成形用の金型のキャビティ(空洞部)に向かって水平方向に一つ若しくは複数立設されていることを特徴とするプラスチック接合成形品の成形用の金型。   The mold for injection molding of the soft resin member is a mold for a molding machine, and a thin rod-shaped fixture for fixing the hard resin member to the mold is a cavity of the mold for molding the soft resin member ( A mold for molding a plastic bonded product, characterized in that one or a plurality thereof are erected in the horizontal direction toward the cavity). 前記軟質樹脂部材の射出成形用の金型は、硬質樹脂部材が軟質樹脂部材の加圧射出時に金型内に加えられる圧力により変形すること又はズレることを防ぐために、硬質樹脂部材の周縁をキャビティ側に押圧保持する凸状の保持具がキャビティ(空洞部)に向かって水平方向に一つ若しくは複数立設されていることを特徴とするプラスチック接合成形品の成形用の金型。   The mold for injection molding of the soft resin member has a cavity around the periphery of the hard resin member in order to prevent the hard resin member from being deformed or displaced due to pressure applied in the mold during the pressure injection of the soft resin member. A mold for molding a plastic bonded product, characterized in that one or a plurality of convex holders that are pressed and held on the side are erected in a horizontal direction toward a cavity (hollow part). 前記軟質樹脂部材の射出成形用の金型は、前記硬質樹脂部材の周縁部に軟質部材を被覆形成する際に生じる端縁の余分なバリの発生を防止するために、前記硬質樹脂部材の端部付近で被覆しない部分の裏面に当接し押圧する凸状のバリ防止押圧具がキャビティ(空洞部)に向かって水平方向に一つ若しくは複数立設されていることを特徴とするプラスチック接合成形品の成形用の金型。   The mold for injection molding of the soft resin member is formed on the end of the hard resin member in order to prevent the occurrence of excessive burrs on the edge generated when the soft member is coated on the periphery of the hard resin member. One or a plurality of convex deburring prevention pressing tools that are in contact with and pressed against the back surface of the portion not covered in the vicinity of the portion are erected in the horizontal direction toward the cavity (cavity portion). Mold for molding. 前記軟質樹脂部材の射出成形用の金型は、射出成形終了後に成形したプラスチック接合成形品を金型から確実に破損することなく剥離させるために、任意の操作で成形品が斜めに突き出されるように水平方向にピンを突出する突出装置をゲート付近に配備したことを特徴とする請求項9乃至11記載のプラスチック接合成形品の成形用の金型。 In the mold for injection molding of the soft resin member, the molded product is protruded obliquely by an arbitrary operation in order to peel the plastic joint molded product molded after the injection molding without damaging the mold. 12. A mold for molding a plastic joint molded product according to claim 9, wherein a projecting device for projecting the pin in the horizontal direction is provided in the vicinity of the gate. 前記軟質樹脂部材を金型に設置した前記硬質樹脂部材の横方向から射出できるように、金型の上方若しくは側面方向若しくは下方に軟質樹脂部材を射出するゲートを形成したことを特徴とする請求項9乃至11記載のプラスチック接合成形品の成形用の金型。   The gate for injecting the soft resin member to the upper side, the side surface direction, or the lower side of the mold is formed so that the soft resin member can be injected from a lateral direction of the hard resin member installed in the mold. A mold for molding a plastic bonded product according to 9 to 11. 請求項1記載のプラスチック接合成形品の成形方法において、前記軟質樹脂部材を金型に設置した前記硬質樹脂部材の被覆面の中央から射出できるように、金型の中央に軟質樹脂部材を射出するゲートを形成したことを特徴とする請求項9乃至11記載のプラスチック接合成形品の成形用の金型。   The method for molding a plastic bonded product according to claim 1, wherein the soft resin member is injected into the center of the mold so that the soft resin member can be injected from the center of the coated surface of the hard resin member installed in the mold. 12. A mold for molding a plastic bonded product according to claim 9, wherein a gate is formed.
JP2007026191A 2007-02-05 2007-02-05 Method of molding plastic joint molding and mold for it Pending JP2008188892A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101314691B1 (en) 2012-05-24 2013-10-07 주식회사 용산 Method of making plastic article laminated with velour cloth by press molding
JP2015127380A (en) * 2013-11-29 2015-07-09 宇部興産株式会社 Polyamide elastomer and molded product produced using the same
JP2018079650A (en) * 2016-11-18 2018-05-24 いすゞ自動車株式会社 Molding method of multilayer molded product

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101314691B1 (en) 2012-05-24 2013-10-07 주식회사 용산 Method of making plastic article laminated with velour cloth by press molding
JP2015127380A (en) * 2013-11-29 2015-07-09 宇部興産株式会社 Polyamide elastomer and molded product produced using the same
JP2018079650A (en) * 2016-11-18 2018-05-24 いすゞ自動車株式会社 Molding method of multilayer molded product

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