JP2008180448A - Saturated steam producing method and its device, and steam heating method and its device - Google Patents

Saturated steam producing method and its device, and steam heating method and its device Download PDF

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JP2008180448A
JP2008180448A JP2007014454A JP2007014454A JP2008180448A JP 2008180448 A JP2008180448 A JP 2008180448A JP 2007014454 A JP2007014454 A JP 2007014454A JP 2007014454 A JP2007014454 A JP 2007014454A JP 2008180448 A JP2008180448 A JP 2008180448A
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steam
saturated
primary
saturated steam
heating
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Kazumasa Hirayama
一政 平山
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TML KK
株式会社 T.M.L
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株式会社 T.M.L
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a producing method and its device for low temperature saturated steam, and to provide a steam heating device for heating, such as for food processing, using the saturated steam. <P>SOLUTION: A primary steam generating means is provided for producing primary steam from a primary liquid used as a matrix for primitively producing steam, a container for saturated steam is provided with a secondary liquid used as a matrix for producing saturated steam, and a steam jetting means is provided for jetting the primary steam into the secondary liquid. Besides, the steam jetting means is characterized in that it has a steam jetting part with opposing rims forming a jetting gap formed in parallel with each other. Alternatively, it is characterized in that saturated steam is produced by jetting primary steam produced from a primary liquid used as a matrix for primitively producing steam into a secondary liquid used as a matrix for producing saturated steam, and passing it through the secondary liquid. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、飽和蒸気を発生させる飽和蒸気生成の方法及びその装置と、その飽和蒸気を用いた蒸気加熱方法及びその装置例えば食品加工用の蒸気加熱装置と、に関する。 The present invention relates to a saturated steam generation method and apparatus for generating saturated steam, and a steam heating method and apparatus using the saturated steam, for example, a steam heating apparatus for food processing.

従来から、ボイラ等の蒸気発生装置、例えば、食品加熱用の蒸気発生装置が開発され市販されている。
これらの蒸気発生装置では、蒸気の発生効率を高めるために蒸気圧を高く高圧に設定している。この高圧蒸気をそのまま食品加熱に使用するには、食品を加熱する空間領域に、できるだけ減圧した蒸気を供給する必要がある。高圧蒸気の温度は食品加熱に必要な温度に較べて高すぎるため、温度を低下させねばならないからである。例えば、45〜95度程度の低温蒸気が適当である。
Conventionally, steam generators such as boilers, for example, steam generators for heating foods have been developed and marketed.
In these steam generators, the steam pressure is set high and high in order to increase the efficiency of steam generation. In order to use this high-pressure steam as it is for food heating, it is necessary to supply steam that is depressurized as much as possible to the space area where the food is heated. This is because the temperature of the high-pressure steam is too high compared to the temperature required for food heating, and the temperature must be lowered. For example, low temperature steam of about 45 to 95 degrees is appropriate.

しかし、高圧蒸気を減圧させると、蒸気の一部が過熱化してしまい、蒸気圧が低下しても蒸気温度は低下しないという不都合な現象が生じ得る。
蒸気温度を低下させないと、高温(過熱化)の蒸気がそのまま食品に接触して、水分を奪ったり、乾き焼けさせたり、硬化させたりするという不都合が生じ、食品加工上好ましくない。
However, when the high-pressure steam is depressurized, a part of the steam is overheated, and an undesirable phenomenon may occur in which the steam temperature does not decrease even if the steam pressure decreases.
If the steam temperature is not lowered, the high temperature (superheated) steam comes into contact with the food as it is, resulting in inconveniences such as depriving of moisture, drying and baking, and curing, which is not preferable for food processing.

本発明は、上記不都合を解消するため、低温の飽和蒸気を継続的に安定して供給できる飽和蒸気の生成方法及びその装置と、その飽和蒸気を用いた加熱用の、例えば、食品加工用等の蒸気加熱方法及びその装置の提供を目的とする。 The present invention eliminates the above-mentioned inconveniences, and a method and apparatus for producing saturated steam capable of continuously and stably supplying low-temperature saturated steam, and for heating using the saturated steam, for example, for food processing, etc. An object of the present invention is to provide a steam heating method and apparatus therefor.

請求項1の飽和蒸気生成装置の発明は、蒸気が原始的に生成される母体となる一次液体から一次蒸気を生成する一次蒸気発生手段と、飽和蒸気が生成される母体となる二次液体を備えた飽和蒸気用容器と、前記二次液体中に前記一次蒸気を噴出させる蒸気噴出手段とを備えたことを特徴とする。 The invention of the saturated vapor generating device of claim 1 includes a primary vapor generating means for generating primary vapor from a primary liquid which is a base from which steam is originally generated, and a secondary liquid which is a base from which saturated steam is generated. A saturated steam container provided, and a steam jetting means for jetting the primary steam into the secondary liquid.

請求項2の飽和蒸気生成装置の発明は、蒸気噴出手段は、噴出間隙を形成する相対の縁が平行に形成された蒸気噴出部を有することを特徴とする。   The invention of the saturated steam generation device according to claim 2 is characterized in that the steam jetting means has a steam jetting portion in which relative edges forming the jetting gap are formed in parallel.

請求項3の発明は、請求項2に記載の飽和蒸気生成装置において、二次液体中に設置される蒸気噴出手段に導入される一次蒸気は、噴出間隙の全域から均等に蒸気が噴出される蒸気圧であることを特徴とする。 According to a third aspect of the present invention, in the saturated vapor generating apparatus according to the second aspect, the primary vapor introduced into the vapor ejection means installed in the secondary liquid is uniformly ejected from the entire area of the ejection gap. It is characterized by a vapor pressure.

請求項4の発明は、請求項2又は請求項3に記載の飽和蒸気生成装置において、噴出間隙は円周状に形成されたことを特徴とする。 According to a fourth aspect of the present invention, in the saturated steam generation device according to the second or third aspect, the ejection gap is formed in a circumferential shape.

請求項5の発明は、請求項2乃至請求項4の何れかに記載の飽和蒸気生成装置において、噴出間隙は複数段にわたって形成されたことを特徴とする。 According to a fifth aspect of the present invention, in the saturated steam generator according to any one of the second to fourth aspects, the ejection gap is formed in a plurality of stages.

請求項6の蒸気加熱装置の発明は、請求項1乃至請求項5の何れかに記載の飽和蒸気生成装置を備えたことを特徴とする。 The invention of the steam heating device according to claim 6 is characterized by comprising the saturated steam generating device according to any one of claims 1 to 5.

請求項7の発明は、請求項6に記載の蒸気加熱装置において、飽和蒸気生成装置からの飽和蒸気が導入される蒸気室と、導入された飽和蒸気で加熱される加熱目的物載置部とを備えたことを特徴とする。 The invention of claim 7 is the steam heating device according to claim 6, wherein a steam chamber into which saturated steam from the saturated steam generating device is introduced, and a heating object mounting portion heated by the introduced saturated steam; It is provided with.

請求項8の発明は、請求項6又は請求項7の何れかに記載の蒸気加熱装置において、飽和蒸気生成装置からの飽和蒸気は噴霧手段を介して蒸気室内に噴霧されることを特徴とする。   The invention according to claim 8 is the steam heating apparatus according to claim 6 or 7, wherein the saturated steam from the saturated steam generating device is sprayed into the steam chamber through the spraying means. .

請求項9の発明は、請求項7又は請求項8に記載の蒸気加熱装置において、蒸気室の底に層状に溜まる空気を排出する空気排気手段を備え、加熱目的物載置部が空気の溜まる層より高い部位に設置されたことを特徴とする。 A ninth aspect of the present invention is the steam heating apparatus according to the seventh or eighth aspect, further comprising air exhaust means for exhausting the air accumulated in a layered manner at the bottom of the steam chamber, wherein the heating object placing portion accumulates air. It is characterized by being installed at a location higher than the layer.

請求項10の発明は、請求項7乃至請求項8の何れかに記載の蒸気加熱装置において、蒸気室の底は外部開放であることを特徴とする。 According to a tenth aspect of the present invention, in the steam heating apparatus according to any one of the seventh to eighth aspects, the bottom of the steam chamber is open to the outside.

請求項11の発明は、請求項7乃至請求項10の何れかに記載の食品加工用の蒸気加熱装置において、蒸気室への蒸気供給量調整手段と、蒸気室内の蒸気温度測定手段と、前記蒸気温度測定手段からの温度情報に基づいて前記蒸気供給量調整手段を制御する加熱制御手段とを備えたことを特徴とする。   The invention of claim 11 is the steam heating apparatus for food processing according to any one of claims 7 to 10, wherein the steam supply amount adjusting means to the steam chamber, the steam temperature measuring means in the steam chamber, Heating control means for controlling the steam supply amount adjusting means based on temperature information from the steam temperature measuring means is provided.

請求項12の発明は、請求項11に記載の食品加工用の蒸気加熱装置において、蒸気が原始的に生成される母体となる一次液体と飽和蒸気が生成される母体となる二次液体とは、双方又は何れか一方が食品加工用液体組成物であることを特徴とする。   The invention according to claim 12 is the steam heating apparatus for food processing according to claim 11, wherein the primary liquid that is a matrix from which steam is originally generated and the secondary liquid that is a matrix from which saturated steam is generated are defined. Both or any one of them is a liquid composition for food processing.

請求項13の飽和蒸気生成方法の発明は、蒸気が原始的に生成される母体となる一次液体から生成された一次蒸気を、飽和蒸気が生成される母体となる二次液体中に噴出させて、前記二次液体中を通過させることにより飽和蒸気を生成させることを特徴とする。 In the invention of the saturated vapor generation method according to claim 13, the primary vapor generated from the primary liquid serving as a base from which steam is originally generated is ejected into the secondary liquid serving as a base from which saturated steam is generated. The saturated vapor is generated by passing through the secondary liquid.

請求項14の食品加工用の蒸気加熱方法の発明は、請求項13の方法による飽和蒸気を用いて食品を加熱することを特徴とする。 The invention of the steam heating method for food processing of claim 14 is characterized in that the food is heated using saturated steam by the method of claim 13.

請求項15の発明は、請求項13に記載の食品加工用の蒸気加熱方法において、蒸気が原始的に生成される母体となる一次液体と飽和蒸気が生成される母体となる二次液体との双方又は何れか一方を食品加工用液体組成物とすることを特徴とする。   According to a fifteenth aspect of the present invention, in the steam heating method for food processing according to the thirteenth aspect, a primary liquid that is a base from which steam is originally generated and a secondary liquid that is a base from which saturated steam is generated Both or any one of them is a liquid composition for food processing.

請求項1乃至請求項5の発明によれば、何れも、飽和蒸気を継続的に安定して供給できる飽和蒸気生成装置を提供できる。 According to the first to fifth aspects of the present invention, it is possible to provide a saturated steam generating device that can continuously and stably supply saturated steam.

請求項2乃至請求項5の発明によれば、何れも、噴出口が無数に形成されたことになるので、飽和蒸気を効率よく発生させることができる。 According to the second to fifth aspects of the present invention, innumerable jets are formed in any of the above, so that saturated steam can be generated efficiently.

請求項6の発明によれば、何れも、継続的に安定して供給できる飽和蒸気を用いた蒸気加熱装置を提供できる。 According to the sixth aspect of the present invention, it is possible to provide a steam heating apparatus using saturated steam that can be continuously and stably supplied.

請求項7乃至請求項10の発明によれば、何れも、継続的に安定して供給できる飽和蒸気を用いて効率よく加熱することができる。 According to the seventh to tenth aspects of the present invention, any of them can be efficiently heated using saturated steam that can be supplied continuously and stably.

請求項11の発明によれば、食品加工用に適し、継続的に安定して供給できる飽和蒸気を、所望の温度を維持しつつ用いることのできる食品加工用の蒸気加熱装置を提供できる。 According to the eleventh aspect of the present invention, there can be provided a steam heating apparatus for food processing, which is suitable for food processing and can use saturated steam that can be continuously and stably supplied while maintaining a desired temperature.

請求項12の発明によれば、継続的に安定して供給できる飽和蒸気による加熱加工と同時に効果的に食品加工を施すことができる食品加工用の蒸気加熱装置を提供できる。 According to invention of Claim 12, the steam heating apparatus for food processing which can perform food processing effectively simultaneously with the heat processing by the saturated steam which can be supplied stably stably can be provided.

請求項13の発明によれば、安定して供給できる加熱用の低温の飽和蒸気を生成することができる。 According to invention of Claim 13, the low temperature saturated steam for a heating which can be supplied stably can be produced | generated.

請求項14の発明によれば、安定して供給できる食品加工用の低温の飽和蒸気を生成することができる。 According to invention of Claim 14, the low temperature saturated steam for food processing which can be supplied stably can be produced | generated.

請求項15の発明によれば、安定して供給できる飽和蒸気による加熱加工と同時に効果的に食品加工を施すことができる。 According to the fifteenth aspect of the present invention, food processing can be effectively performed simultaneously with heat processing using saturated steam that can be stably supplied.

以下、本発明を、食品加工用の低温飽和蒸気を生成する飽和蒸気生成装置を備えた食品加工用の蒸気加熱装置を例にして、図1乃至図6に基づいて説明する。   Hereinafter, the present invention will be described based on FIG. 1 to FIG. 6 by taking as an example a steam heating apparatus for food processing provided with a saturated steam generating apparatus for generating low-temperature saturated steam for food processing.

図1は食品加工用の蒸気加熱装置の構成を示した概念図、図2は飽和蒸気生成装置の拡大図、図3は飽和蒸気生成装置の外観斜視図、図4は飽和蒸気生成装置の縦断面図、図5は飽和蒸気生成装置の第2の実施例を示す概念図、図6は飽和蒸気生成装置の第3の実施例を示す概念図である。   1 is a conceptual diagram showing the configuration of a steam heating apparatus for food processing, FIG. 2 is an enlarged view of a saturated steam generating apparatus, FIG. 3 is an external perspective view of the saturated steam generating apparatus, and FIG. 4 is a longitudinal section of the saturated steam generating apparatus. FIG. 5 is a conceptual diagram showing a second embodiment of the saturated steam generator, and FIG. 6 is a conceptual diagram showing a third embodiment of the saturated steam generator.

図1において、図示の食品加工用の蒸気加熱装置1は、一次蒸気発生手段10と飽和蒸気生成装置20と蒸気加熱装置30とで構成されている。 In FIG. 1, the illustrated steam heating apparatus 1 for processing food includes a primary steam generating means 10, a saturated steam generating apparatus 20, and a steam heating apparatus 30.

一次蒸気発生手段10は、蒸気が原始的に生成される母体となる一次液体11(図示せず)から一次蒸気を生成する手段であって、例えばボイラ等の蒸気を発生させる手段であればよい。
以下、この一次蒸気発生手段10を単に蒸気発生手段ともいう。
尚、ここで一次液体とは例えば水であり、或いは、後述する食品加工用液体組成物である。
The primary steam generation means 10 is a means for generating primary steam from a primary liquid 11 (not shown) that is a base from which steam is initially generated, and may be any means that generates steam such as, for example, a boiler. .
Hereinafter, the primary steam generating means 10 is also simply referred to as steam generating means.
Here, the primary liquid is, for example, water or a liquid composition for food processing described later.

飽和蒸気生成装置20は、飽和蒸気が生成される母体となる二次液体21を備えた飽和蒸気用容器22と、この二次液体21中に前記の一次蒸気11を噴出させる蒸気噴出手段40とを備えている。   The saturated steam generation apparatus 20 includes a saturated steam container 22 including a secondary liquid 21 that is a base for generating saturated steam, and a steam ejection unit 40 that ejects the primary steam 11 into the secondary liquid 21. It has.

蒸気加熱装置30は、飽和蒸気生成装置20からの飽和蒸気が導入される蒸気室31と、この蒸気室31に導入された飽和蒸気で加熱される加熱目的物を載置するための加熱目的物載置部32とを備えている。   The steam heating device 30 includes a steam chamber 31 into which the saturated steam from the saturated steam generating device 20 is introduced, and a heating object for placing a heating object to be heated by the saturated steam introduced into the steam chamber 31. And a mounting portion 32.

図2乃至図4において、蒸気噴出手段40は、噴出間隙41を形成する相対の縁42,43が平行に形成された蒸気噴出部44を有している。
図示の噴出間隙41は円周状に形成されているが、必ずしもこのように長さ方向が無端である必要はなく、例えば、適当な長さ間隔をおいた両端を有する有端の長方形状や長孔形状等のスリット状に噴出間隙を形成してもよい(図示せず)。
2 to 4, the steam ejection means 40 has a steam ejection portion 44 in which relative edges 42 and 43 that form an ejection gap 41 are formed in parallel.
The illustrated ejection gap 41 is formed in a circumferential shape. However, the length direction does not necessarily have to be endless in this manner. For example, the ejection gap 41 is not limited to a rectangular shape having ends with appropriate length intervals. The ejection gap may be formed in a slit shape such as a long hole shape (not shown).

このように、縁42,43が平行な蒸気噴出部44を設けることにより、丸口等のノズル口を多数設けるよりも、無数に或いは無限にノズル口を設けたようになるために、無数の微細気泡を継続的かつ安定的に極めて効率よく二次液体21中に噴出させることができ、生成させることができる。
噴出させる気泡をより微細にするためには、噴出間隙41をより狭くすればよい。又、二次液体21中に微細気泡を更に効率的に噴出させるには、噴出間隙41を複数段にわたって形成するとよい。
In this way, by providing the steam ejection portion 44 with the edges 42 and 43 being parallel, it is possible to provide an infinite number of nozzle ports innumerably or infinitely, rather than providing a large number of nozzle ports such as round ports. Fine bubbles can be continuously and stably ejected into the secondary liquid 21 with extremely high efficiency, and can be generated.
In order to make the bubbles to be ejected finer, the ejection gap 41 may be made narrower. Further, in order to more efficiently eject fine bubbles into the secondary liquid 21, the ejection gap 41 may be formed in a plurality of stages.

蒸気噴出手段40の噴出間隙41は、二次液体21の組成成分にもよるが、例えば、平均で0.01mm以上1mm以下、好ましくはその下限が0.05mm以上でありその上限が、0.7mm以下、更に好ましくはその下限が0.1mm以上でありその上限が、0.5mm以下がよい。 The ejection gap 41 of the vapor ejection means 40 depends on the composition component of the secondary liquid 21, but is, for example, 0.01 mm or more and 1 mm or less on average, and preferably has a lower limit of 0.05 mm or more and an upper limit of 0.8 mm. 7 mm or less, more preferably the lower limit is 0.1 mm or more, and the upper limit is 0.5 mm or less.

又、この蒸気噴出手段40を構成する材料は、金属、プラスチック、木材、等その材料や材質を問わないが、耐熱性や耐腐食性を考慮すれば、金属或いは硬化プラスチック等が好ましい。 The material constituting the vapor jet means 40 may be any material or material such as metal, plastic, wood, etc. However, considering heat resistance and corrosion resistance, metal or cured plastic is preferable.

又、この蒸気噴出手段40を形成する方法も、何れの方法であるかを問わないが、図示のように、傘状に形成された2枚の円盤を内部に通気空間45が形成されるよう向かい合わせに近接させて一つの円周状の噴出間隙41を持つ噴出部44を形成するとよい。 The method of forming the vapor jet means 40 may be any method, but as shown in the figure, the ventilation space 45 is formed in the two disks formed in an umbrella shape. It is preferable to form an ejection portion 44 having one circumferential ejection gap 41 so as to be close to each other.

上記のように噴出部44を円盤状に形成すると、噴出される一次蒸気11が前記通気空間45中を噴出間隙41に近づくにつれて、円盤構成部材及び当該円盤構成部材を介して、相対的に温度が低い二次液体21の冷却作用を受けて、噴出される一次蒸気11が次第に冷却されて行き、噴出される前に冷却される効果を生むので、噴射される一次蒸気11はその圧力が下がり微細な噴射流即ち微細気泡となって、二次液体21との接触効果が上がるだけでなく、噴出時の騒音や振動も抑制される。 When the ejection part 44 is formed in a disk shape as described above, the temperature of the primary steam 11 that is ejected approaches the ejection gap 41 in the ventilation space 45, and the relative temperature increases through the disk component and the disk component. The primary steam 11 that is ejected is gradually cooled by receiving the cooling action of the secondary liquid 21 that is low and produces the effect of being cooled before being ejected, so that the pressure of the ejected primary steam 11 decreases. A fine jet flow, that is, a fine bubble, not only improves the contact effect with the secondary liquid 21, but also suppresses noise and vibration during ejection.

又、上記のように噴出間隙41を形成すると、一次蒸気11が円盤の円周側から均等に噴射されるので、後述の図5や図6に示すノズル52の口という部分的に特定された部位ノズル口から一時に多量の一次蒸気11が噴射されることもなく、しかも、一次蒸気11が二次液体21中に効果的に分散して噴出され易くなる。
従って、例えば、噴射された一次蒸気11が筒状の塊となって二次液体21の水面まで突き抜けてしまうというような不都合な現象が抑制できる。
Further, when the ejection gap 41 is formed as described above, the primary steam 11 is evenly ejected from the circumferential side of the disk, so that it is partially specified as the mouth of the nozzle 52 shown in FIGS. 5 and 6 to be described later. A large amount of the primary vapor 11 is not ejected from the site nozzle port at a time, and the primary vapor 11 is effectively dispersed and easily ejected into the secondary liquid 21.
Therefore, for example, the inconvenient phenomenon that the injected primary vapor | steam 11 penetrates to the water surface of the secondary liquid 21 as a cylindrical lump can be suppressed.

二次液体21中に設置された蒸気噴出手段40に導入される一次蒸気圧は、全ての段の各噴出間隙41の全域即ち、全周から均等に蒸気が噴出されるに必要な蒸気圧であることが望ましい。
噴出間隙41の全域からの噴出が可能な蒸気圧が与えられれば、図2で示すように、噴出間隙41の延在方向が水平となるように蒸気噴出手段40を二次液体21中に設置するだけでなく、図4に示すように、噴出間隙41の延在方向が垂直となるように設置してもよく、要するに、二次液体21中に於ける噴出間隙41の傾き如何様でもよい。
The primary vapor pressure introduced into the vapor ejection means 40 installed in the secondary liquid 21 is a vapor pressure necessary for vapor to be uniformly ejected from the entire area of each ejection gap 41 of all stages, that is, from the entire circumference. It is desirable to be.
As shown in FIG. 2, when a vapor pressure capable of being ejected from the entire area of the ejection gap 41 is provided, the vapor ejection means 40 is installed in the secondary liquid 21 so that the extending direction of the ejection gap 41 is horizontal. In addition, as shown in FIG. 4, the ejection gap 41 may be installed so that the extending direction of the ejection gap 41 is vertical. In short, the inclination of the ejection gap 41 in the secondary liquid 21 may be arbitrary. .

上記のように、この飽和蒸気生成装置20によれば、蒸気が原始的に生成される母体となる一次液体から生成された一次蒸気11を、飽和蒸気が生成される母体となる二次液体21中に噴出させて、二次液体中21を通過させることにより低温の飽和蒸気を効率よく生成させることができる。   As described above, according to the saturated vapor generation apparatus 20, the primary liquid 11 generated from the primary liquid that is a base from which steam is originally generated is converted into the secondary liquid 21 that is the base from which the saturated vapor is generated. It is possible to efficiently generate a low-temperature saturated vapor by ejecting it into the secondary liquid 21 and passing it through the secondary liquid 21.

この場合、一次蒸気11を生成させた一次液体即ち蒸気発生組成物と同じ組成とした二次液体21中に、一次蒸気11を通過させて生成させた飽和蒸気を、蒸気室31内に導入することが好ましい。
この様な手段を用いることにより、蒸気室31内の飽和蒸気の化学的安定平衡を保持させることができる。
In this case, saturated steam generated by passing the primary steam 11 is introduced into the steam chamber 31 into the secondary liquid 21 having the same composition as the primary liquid that generated the primary steam 11, that is, the steam generating composition. It is preferable.
By using such means, the chemical stable equilibrium of the saturated steam in the steam chamber 31 can be maintained.

又、比較的高圧高温の一次蒸気11を比較的低温の二次液体21中に噴出させて通過させることにより、一次蒸気11の蒸気圧が減圧されると共に冷却されるため、このシステムを連続稼動させて、二次液体21の液面上に低温の飽和蒸気を効率よく継続的且つ安定的に生成させることができる。   Moreover, since the vapor pressure of the primary vapor | steam 11 is pressure-reduced and cooled by ejecting the primary vapor | steam 11 with a comparatively high pressure and high temperature in the secondary liquid 21 of a comparatively low temperature, this system is operated continuously. Thus, low-temperature saturated vapor can be efficiently and continuously generated stably on the liquid surface of the secondary liquid 21.

尚、図5及び図6は、上記実施例とは別の蒸気噴出手段50の例を示すもので、蒸気管51の側面に多数の丸口のノズル52を列設したものである。図5はノズル52の口を上方(液面)に向けて設置した例、図6はノズル52の口を下方に向けて設置した例である。
二次液体21中における微細気泡の生成効率は、ノズル52の口を上方に向けるよりも、下方に向ける方がよい。ノズル52を下方にして一次蒸気11を可能な限り減圧して噴射させることにより、二次液体21との接触時間が長くなって低温の飽和蒸気の生成効率をより高めることができる。
5 and 6 show an example of the steam jetting means 50 different from the above-described embodiment, in which a large number of round nozzles 52 are arranged on the side surface of the steam pipe 51. FIG. 5 shows an example in which the mouth of the nozzle 52 is placed upward (liquid level), and FIG. 6 shows an example in which the mouth of the nozzle 52 is placed downward.
The generation efficiency of the fine bubbles in the secondary liquid 21 is preferably directed downward rather than facing the mouth of the nozzle 52 upward. By spraying the primary vapor 11 while reducing the pressure as much as possible with the nozzle 52 downward, the contact time with the secondary liquid 21 becomes longer and the generation efficiency of the low-temperature saturated vapor can be further increased.

図5及び図6の何れの例でも、ノズル52を噴出部とした蒸気噴出手段50では、上記実施例の蒸気噴出手段40に比べて微細気泡の生成効率、即ち、低温の飽和蒸気の生成効率は劣るものの、用途に応じては十分に実用的であり、上記実施例においても、蒸気噴出手段40に代えて蒸気噴出手段50を用いることもできる。
尚、図示の例では20Aパイプ(内径21.6mm)に、噴出部として3mm口径の穴(ノズル口)を36個列設したものである。
5 and 6, in the steam jetting means 50 using the nozzle 52 as the jetting part, compared with the steam jetting means 40 of the above embodiment, the generation efficiency of fine bubbles, that is, the generation efficiency of low-temperature saturated steam. Although it is inferior, it is sufficiently practical depending on the application, and in the above-described embodiment, the steam ejection means 50 can be used in place of the steam ejection means 40.
In the example shown in the figure, 36 holes (nozzle ports) having a diameter of 3 mm are arranged in a row on the 20A pipe (inner diameter 21.6 mm) as an ejection portion.

次に、図1において、上記飽和蒸気生成装置20で生成された低温の飽和蒸気を用いて食品を加熱する食品加工用の蒸気加熱装置30について説明する。   Next, referring to FIG. 1, a steam heating apparatus 30 for processing food that heats food using low temperature saturated steam generated by the saturated steam generating apparatus 20 will be described.

この蒸気加熱装置30は、前述の通り、蒸気室31内に加熱目的の食品36を置くための加熱目的物載置部32の他に、蒸気室31内の適所に蒸気温度測定手段34としての温度センサと、この蒸気温度測定手段(温度センサ)34からの温度情報に基づいて、蒸気室31への蒸気供給量を調整する蒸気供給量調整手段33としての電動可変弁を制御して、蒸気室31内の蒸気温度を制御する加熱制御手段35としての温度コントローラとを備えており、飽和蒸気生成装置20で生成された低温の飽和蒸気は、噴霧手段37を介して蒸気室31内に噴霧されている。 As described above, the steam heating device 30 is used as a steam temperature measuring means 34 in an appropriate place in the steam chamber 31 in addition to the heating object placing portion 32 for placing the food 36 to be heated in the steam chamber 31. Based on the temperature sensor and the temperature information from the steam temperature measuring means (temperature sensor) 34, the electric variable valve as the steam supply amount adjusting means 33 for adjusting the steam supply amount to the steam chamber 31 is controlled to control the steam. A temperature controller as a heating control means 35 for controlling the steam temperature in the chamber 31, and the low-temperature saturated steam generated by the saturated steam generator 20 is sprayed into the steam chamber 31 via the spray means 37. Has been.

このようにこの実施例では噴霧手段37として噴霧ノズルを用いて噴霧させているが、蒸気室31に、飽和蒸気生成装置20からの飽和蒸気を導入する際には、そのまま導入してもよい。
尚、この蒸気室31(室内空間領域)は、飽和蒸気(層)を所望の温度で安定的に保つ機能を備えていれば閉鎖空間であっても、一部が開放された空間領域であってもよい(図示せず)。
As described above, in this embodiment, spraying is performed using the spray nozzle as the spraying means 37. However, when the saturated steam from the saturated steam generating apparatus 20 is introduced into the steam chamber 31, it may be introduced as it is.
It should be noted that the steam chamber 31 (indoor space region) is a partially open space region provided that it has a function of stably maintaining the saturated steam (layer) at a desired temperature. (Not shown).

蒸気室31内の飽和蒸気の温度は必要に応じて前記加熱制御手段35により適宜調整されるが、食品加工の場合には、好ましくは低温度、より好ましくは大気圧下100℃以下の温度(より好ましくは加熱する物品(例えば食品)の硬化しない温度)に調整しておくことが好ましい。食品の加熱源としてこのような低温度の飽和蒸気を得ることができることは極めて理想的である。 The temperature of the saturated steam in the steam chamber 31 is appropriately adjusted by the heating control means 35 as necessary. In the case of food processing, it is preferably a low temperature, more preferably a temperature of 100 ° C. or less under atmospheric pressure ( More preferably, the temperature is adjusted to the temperature at which the article to be heated (for example, food) does not cure. It is extremely ideal that such low temperature saturated steam can be obtained as a food heating source.

このような所望の温度で飽和蒸気を蒸気室31内に維持するには、室31内の食品加工空間領域内、この例では加熱目的物載置部32を包む領域の飽和蒸気の温度を温度センサ34で測定し、測定した温度情報に応じて、加熱制御手段35により蒸気供給量調整手段33を制御して、飽和蒸気生成装置20からの飽和蒸気の当該蒸気室31内への導入量等を適宜調整させている。 In order to maintain the saturated steam in the steam chamber 31 at such a desired temperature, the temperature of the saturated steam in the food processing space region in the chamber 31, in this example, the region surrounding the heating object mounting portion 32 is set to the temperature. In accordance with the temperature information measured by the sensor 34, the steam supply amount adjusting means 33 is controlled by the heating control means 35, and the amount of saturated steam from the saturated steam generating device 20 introduced into the steam chamber 31, etc. Is adjusted appropriately.

尚、温度センサ34で測定した温度情報に基づく温度調整は適宜の常套手段を用いればよい。
例えば、温度測定により測定した温度情報を入力し、所望温度との差を計算する演算器を備えた温度コントローラ(コンピュータ等)により解析し、その情報に基づいて、蒸気供給量調整手段33としての電動可変弁等を開閉させればよい。
Note that temperature adjustment based on the temperature information measured by the temperature sensor 34 may be performed using appropriate conventional means.
For example, the temperature information measured by the temperature measurement is input, analyzed by a temperature controller (computer or the like) provided with a computing unit that calculates the difference from the desired temperature, and based on the information, the steam supply amount adjusting means 33 is What is necessary is just to open and close an electric variable valve etc.

こうして、蒸気室31に飽和蒸気が導入されて行くと、室31内の加熱空間領域の上部から飽和蒸気(層)が満たされて行き、飽和蒸気導入前に室31内に存在した空気が飽和蒸気と空気との比重の差から、飽和蒸気層の下部に移動する。
この蒸気加熱装置30は、蒸気室30の底にこのようにして層状に溜まる空気38を排出する空気排気手段39を備えており、前記の加熱目的物載置部32はこの空気が溜まる層(空気層38)より高い部位に位置するよう予め設置されている。
尚、蒸気室31の底に、このような空気層38が形成されないように、蒸気室31の底の全部又は一部を外部開放としてもよい(図示せず)。
Thus, when saturated steam is introduced into the steam chamber 31, the saturated steam (layer) is filled from the upper part of the heating space region in the chamber 31, and the air present in the chamber 31 before the saturated steam is introduced is saturated. Due to the difference in specific gravity between steam and air, it moves to the lower part of the saturated steam layer.
This steam heating device 30 is provided with an air exhaust means 39 for discharging the air 38 thus stored in a layered manner at the bottom of the steam chamber 30, and the heating object mounting portion 32 has a layer (in which this air is stored ( It is installed in advance so as to be located at a higher position than the air layer 38).
Note that all or part of the bottom of the steam chamber 31 may be open to the outside so that such an air layer 38 is not formed at the bottom of the steam chamber 31 (not shown).

蒸気室31は、加熱目的物載置部32に配置した食品36を加熱するため、蒸気室31内の飽和蒸気を所望の温度で一定に維持する必要がある。
このため蒸気室31は閉鎖空間とするのがよいが、飽和蒸気から液化した液体(液体組成物)を自然除去するための廃液手段339として、上記の空気排気手段39とは別に廃液口を設けてもよい。
Since the steam chamber 31 heats the food 36 disposed on the heating object mounting unit 32, it is necessary to keep the saturated steam in the steam chamber 31 constant at a desired temperature.
Therefore, the vapor chamber 31 is preferably a closed space, but a waste liquid port is provided separately from the air exhaust means 39 as the waste liquid means 339 for naturally removing the liquid (liquid composition) liquefied from the saturated vapor. May be.

この場合、上述した空気(層)38は飽和蒸気との比重差により下方に移動するので、蒸気室31の下部から自然に排気されることが好ましく、蒸気室31が閉鎖領域として形成されている場合には、室31内下部に空気が逃げる空気排気手段39を設けておくとよい。この空気排気手段39には、食品36を加熱する際に生じるドリップなどの排出物質をも排除する役割も担わせることができる。 In this case, since the air (layer) 38 described above moves downward due to the specific gravity difference with the saturated steam, it is preferable that the air (layer) 38 is naturally exhausted from the lower part of the steam chamber 31, and the steam chamber 31 is formed as a closed region. In that case, an air exhaust means 39 for escaping air may be provided in the lower part of the chamber 31. The air exhaust means 39 can also play a role of eliminating exhaust substances such as drip generated when the food 36 is heated.

更に、この食品加工用の蒸気加熱装置30においては、一次蒸気11が原始的に生成される母体となる一次液体と飽和蒸気が生成される母体となる二次液体21との双方又は何れか一方を、食品加工用の液体組成物(以下、食品加工用液体組成物という)とすることもできる。
この場合、一次蒸気11の発生母体となる一次液体としての食品加工用液体組成物としては、例えば、水やアルコール、或いは、有機酸又はこれらの混合物が好ましい。
Furthermore, in this steam heating apparatus 30 for processing food, either or either one of the primary liquid that is a base from which the primary steam 11 is originally generated and the secondary liquid 21 that is the base from which saturated steam is generated. Can be used as a food processing liquid composition (hereinafter referred to as a food processing liquid composition).
In this case, as a liquid composition for food processing as a primary liquid that becomes a base for generating the primary vapor 11, for example, water, alcohol, organic acid, or a mixture thereof is preferable.

このような一次蒸気の生成のためには、一次液体の沸点、又は水、
アルコール、又は有機酸の混合物を使用する場合、会合条件等を考慮して行う。
For the production of such primary vapor, the boiling point of the primary liquid, or water,
When alcohol or a mixture of organic acids is used, the association conditions are considered.

アルコールは、炭素数1〜5の直鎖又分岐鎖を有する低級アルコールが使用可能であり、その具体例としては、エタノール、プロパノール、ブタノール、ペンタノール、アリルアルコール、イソプロピルアルコール等が挙げられ、好ましくはエタノール、プロパノール、ブタノール、ペンタノールが挙げられる。 As the alcohol, a straight chain or branched lower alcohol having 1 to 5 carbon atoms can be used, and specific examples thereof include ethanol, propanol, butanol, pentanol, allyl alcohol, isopropyl alcohol, and the like. Includes ethanol, propanol, butanol, and pentanol.

又、これらのアルコールを含む飲用酒(ワイン、日本酒、ビール、ブランデー、焼酎、ジン、ウォッカ、リキュール等)を用いても良い。
有機酸の具体例としては、酢酸、リンゴ酸、酒石酸、クエン酸、ショウ酸、フマル酸、乳酸、プロピオン酸、酪酸などが挙げられ、好ましくは酢酸、リンゴ酸、クエン酸が挙げられる。
Drinking liquors containing these alcohols (wine, sake, beer, brandy, shochu, gin, vodka, liqueur, etc.) may also be used.
Specific examples of the organic acid include acetic acid, malic acid, tartaric acid, citric acid, succinic acid, fumaric acid, lactic acid, propionic acid, butyric acid, and preferably acetic acid, malic acid, and citric acid.

アルコール、有機酸を使用することにより、食品の安全性(殺菌性)が向上し、又、食品に所望の風味を添加することも可能となる。
特に、飲用酒を用いた場合、飲用酒に含まれる香味又は風味成分を食品に浸透又は付着させることができるので、消費者の嗜好に合致させた食品の製造が可能となる。
By using alcohol or organic acid, the safety (bactericidal property) of the food is improved, and a desired flavor can be added to the food.
In particular, when potable liquor is used, the flavor or flavor component contained in the potable liquor can penetrate or adhere to the food, making it possible to produce a food that matches consumer preferences.

他方、飽和蒸気生成装置20で用いられる二次液体21の食品加工用液体組成物としては、上記の一次液体即ち蒸気発生組成物と同一又は異なる、前記と同様の食品加工用液体組成物を適宜用いてもよいが、好ましくは同一のものがよい。 On the other hand, as the liquid composition for food processing of the secondary liquid 21 used in the saturated vapor generating apparatus 20, the same liquid composition for food processing as described above, which is the same as or different from the above-mentioned primary liquid, that is, the steam generating composition, is appropriately used. Although it may be used, the same one is preferable.

上記のようにして、食品36を飽和蒸気によって加熱する前後には、食品添加物及び/又は食品素材を食品36に予め適宜付与(添加、付着等)しておくことが好ましい。
このような前処理を施すことにより、消費者の嗜好に沿った加工食品を提供とすることができる。
As described above, before and after the food 36 is heated with saturated steam, it is preferable that a food additive and / or a food material is appropriately given (added, adhered, etc.) to the food 36 in advance.
By performing such pretreatment, processed foods that meet consumer preferences can be provided.

食品添加物や食品素材としては、調味料(グルタミン酸、イノシン酸、コハク酸、アミノ酸液、HVP、魚介エキス等)、酸味料(梅酢、よね酢、米酢、ポン酢、スダチ酢等)、保存料(うど抽出物、しらこたんぱく抽出物、ペクチン分解物等)、酵素(アミラーゼ、カタラーゼ、プロテアーゼ等)、乳化剤(ダイズサポニン、レシチン等)、製造用剤(くん液、トウガラシ水性抽出物、ニンニク抽出物、次亜塩素酸ナトリウム等)及びこれらの混合物の群から選択されるものが挙げられる。
又、加工される食品としては、肉類、魚類、野菜類等がある。
As food additives and food materials, seasonings (glutamic acid, inosinic acid, succinic acid, amino acid solution, HVP, seafood extract, etc.), acidulants (plum vinegar, rice vinegar, rice vinegar, ponzu vinegar, sudachi vinegar, etc.), preservatives (Udo extract, Shirako protein extract, pectin degradation product, etc.), Enzyme (Amylase, Catalase, Protease, etc.), Emulsifier (Soybean saponin, Lecithin, etc.), Manufacturing agent (Kun solution, Pepper aqueous extract, Garlic extract) Products, sodium hypochlorite, etc.) and mixtures thereof.
Examples of processed foods include meat, fish, vegetables and the like.

上記の実施例によれば、従来のように一次蒸気を強制的に減圧することが無いので、従来問題であった過熱化蒸気の発生を無くすことができると共に、所望の低温(度)の飽和蒸気を食品加工用として継続的に、しかも安定して得ることができるので、加熱される目的物を一定の高品質に保つことができる。 According to the above embodiment, since the primary steam is not forcibly depressurized as in the prior art, it is possible to eliminate the generation of superheated steam, which has been a problem in the past, and to achieve a desired low temperature (degree) saturation. Since steam can be obtained continuously and stably for food processing, the object to be heated can be kept at a certain high quality.

本発明は、上記実施例では、食品加工用の飽和蒸気生成装置、或いは蒸気加熱装置とし説明したが、食品加工用に限らず、他の用途や分野においても、低温の飽和蒸気生成手段として、或いは飽和蒸気を用いた加熱手段として広く適用することができる。   In the above embodiment, the present invention has been described as a saturated steam generating device for food processing or a steam heating device, but not only for food processing, but also in other applications and fields, as a low temperature saturated steam generating means, Or it can apply widely as a heating means using saturated steam.

図1は食品加工用の蒸気加熱装置の構成を示した概念図である。FIG. 1 is a conceptual diagram showing the configuration of a steam heating apparatus for food processing. 図2は飽和蒸気生成装置の拡大図である。FIG. 2 is an enlarged view of the saturated steam generator. 図3は飽和蒸気生成装置の外観斜視図である。FIG. 3 is an external perspective view of the saturated steam generator. 図4は飽和蒸気生成装置の縦断面図である。FIG. 4 is a longitudinal sectional view of the saturated steam generator. 図5は飽和蒸気生成装置の第2の実施例を示す概念図である。FIG. 5 is a conceptual diagram showing a second embodiment of the saturated steam generator. 図6は飽和蒸気生成装置の第3の実施例を示す概念図である。FIG. 6 is a conceptual diagram showing a third embodiment of the saturated steam generator.

符号の説明Explanation of symbols

1 食品加工用の蒸気加熱装置
10 一次蒸気発生手段
11 一次蒸気
20 飽和蒸気生成装置
21 二次液体
22 飽和蒸気用容器
30 蒸気加熱装置
31 蒸気室
32 加熱目的物載置部
33 蒸気供給量調整手段
34 蒸気温度測定手段
35 加熱制御手段
36 食品
37 噴霧手段
38 空気(空気層)
39 空気排気手段
40 蒸気噴出手段
41 噴出間隙
42 縁
43 縁
44 蒸気噴出部
45 通気空間
50 蒸気噴出手段
51 蒸気管
52 ノズル
339 廃液手段
DESCRIPTION OF SYMBOLS 1 Steam heating apparatus for food processing 10 Primary steam generation means 11 Primary steam 20 Saturated steam generation apparatus 21 Secondary liquid 22 Saturated steam container 30 Steam heating apparatus 31 Steam chamber 32 Heating object mounting part 33 Steam supply amount adjustment means 34 Steam temperature measuring means 35 Heating control means 36 Food 37 Spray means 38 Air (air layer)
39 Air exhaust means 40 Steam ejection means 41 Ejection gap 42 Edge 43 Edge 44 Steam ejection part 45 Ventilation space 50 Steam ejection means 51 Steam pipe 52 Nozzle 339 Waste liquid means

Claims (15)

蒸気が原始的に生成される母体となる一次液体から一次蒸気を生成する一次蒸気発生手段と、飽和蒸気が生成される母体となる二次液体を備えた飽和蒸気用容器と、前記二次液体中に前記一次蒸気を噴出させる蒸気噴出手段とを備えたことを特徴とする飽和蒸気生成装置。 Primary steam generating means for generating primary steam from a primary liquid which is a base from which steam is originally generated, a saturated steam container including a secondary liquid which is a base from which saturated steam is generated, and the secondary liquid A saturated steam generating device comprising steam jetting means for jetting the primary steam therein. 蒸気噴出手段は、噴出間隙を形成する相対の縁が平行に形成された蒸気噴出部を有することを特徴とする飽和蒸気生成装置。   The steam jetting device includes a steam jetting unit in which relative edges forming jetting gaps are formed in parallel to each other. 二次液体中に設置される蒸気噴出手段に導入される一次蒸気は、噴出間隙の全域から均等に蒸気が噴出される蒸気圧であることを特徴とする請求項2に記載の飽和蒸気生成装置。 3. The saturated steam generator according to claim 2, wherein the primary steam introduced into the steam jetting means installed in the secondary liquid has a steam pressure at which the steam is jetted uniformly from the entire jetting gap. . 噴出間隙は円周状に形成されたことを特徴とする請求項2又は請求項3に記載の飽和蒸気生成装置。 The saturated steam generation device according to claim 2 or 3, wherein the ejection gap is formed in a circumferential shape. 噴出間隙は複数段にわたって形成されたことを特徴とする請求項2乃至請求項4の何れかに記載の飽和蒸気生成装置。 The saturated steam generation device according to any one of claims 2 to 4, wherein the ejection gap is formed in a plurality of stages. 請求項1乃至請求項5の何れかに記載の飽和蒸気生成装置を備えたことを特徴とする蒸気加熱装置。 A steam heating apparatus comprising the saturated steam generation apparatus according to any one of claims 1 to 5. 飽和蒸気生成装置からの飽和蒸気が導入される蒸気室と、導入された飽和蒸気で加熱される加熱目的物載置部とを備えたことを特徴とする請求項6に記載の蒸気加熱装置。   The steam heating apparatus according to claim 6, further comprising: a steam chamber into which saturated steam from the saturated steam generating apparatus is introduced; and a heating object mounting unit that is heated by the introduced saturated steam. 飽和蒸気生成装置からの飽和蒸気は噴霧手段を介して蒸気室内に噴霧されることを特徴とする請求項6又は請求項7の何れかに記載の蒸気加熱装置。   The steam heating apparatus according to claim 6 or 7, wherein the saturated steam from the saturated steam generating apparatus is sprayed into the steam chamber through a spraying means. 蒸気室の底に層状に溜まる空気を排出する空気排気手段を備え、加熱目的物載置部が空気の溜まる層より高い部位に設置されたことを特徴とする請求項7又は請求項8に記載の蒸気加熱装置。 9. The apparatus according to claim 7 or 8, further comprising an air exhaust means for discharging the air accumulated in a layered manner at the bottom of the steam chamber, wherein the heating object placing portion is installed at a position higher than the layer in which the air is accumulated. Steam heating device. 蒸気室の底は外部開放であることを特徴とする請求項7乃至請求項8の何れかに記載の蒸気加熱装置。 The steam heating device according to any one of claims 7 to 8, wherein the bottom of the steam chamber is open to the outside. 蒸気室への蒸気供給量調整手段と、蒸気室内の蒸気温度測定手段と、
前記蒸気温度測定手段からの温度情報に基づいて前記蒸気供給量調整手段を制御する加熱制御手段とを備えたことを特徴とする請求項7乃至請求項10の何れかに記載の食品加工用の蒸気加熱装置。
Means for adjusting the amount of steam supplied to the steam chamber, means for measuring the steam temperature in the steam chamber,
The food processing apparatus according to any one of claims 7 to 10, further comprising a heating control unit that controls the steam supply amount adjusting unit based on temperature information from the steam temperature measuring unit. Steam heating device.
蒸気が原始的に生成される母体となる一次液体と飽和蒸気が生成される母体となる二次液体とは、双方又は何れか一方が食品加工用液体組成物であることを特徴とする請求項11に記載の食品加工用の蒸気加熱装置。   The primary liquid that is a base from which steam is originally generated and the secondary liquid that is a base from which saturated steam is generated are both or any one of the liquid compositions for food processing, 11. A steam heating apparatus for food processing according to 11. 蒸気が原始的に生成される母体となる一次液体から生成された一次蒸気を、飽和蒸気が生成される母体となる二次液体中に噴出させて、前記二次液体中を通過させることにより飽和蒸気を生成させることを特徴とする飽和蒸気生成方法。 Saturation is achieved by ejecting the primary vapor generated from the primary liquid, which is the matrix from which steam is originally generated, into the secondary liquid, which is the matrix from which saturated vapor is generated, and passing through the secondary liquid. A saturated steam generation method characterized by generating steam. 請求項13の方法による飽和蒸気を用いて食品を加熱する食品加工用の蒸気加熱方法。 A steam heating method for food processing, wherein the food is heated using saturated steam according to the method of claim 13. 蒸気が原始的に生成される母体となる一次液体と飽和蒸気が生成される母体となる二次液体との双方又は何れか一方を食品加工用液体組成物とすることを特徴とする請求項13に記載の食品加工用の蒸気加熱方法。
14. The liquid composition for food processing is characterized in that either or either one of a primary liquid serving as a matrix from which steam is originally generated and a secondary liquid serving as a matrix from which saturated steam is generated is used. Steam heating method for food processing as described in 1.
JP2007014454A 2007-01-25 2007-01-25 Saturated steam producing method and its device, and steam heating method and its device Pending JP2008180448A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010005059A1 (en) 2008-07-10 2010-01-14 旭硝子株式会社 Wire grid type polarizer, and method for manufacturing the polarizer
WO2011013996A2 (en) * 2009-07-28 2011-02-03 주식회사 디마퓨어텍 Material obtained by ultrahigh pressure hydrolysis and liquefaction, and method for producing same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010005059A1 (en) 2008-07-10 2010-01-14 旭硝子株式会社 Wire grid type polarizer, and method for manufacturing the polarizer
WO2011013996A2 (en) * 2009-07-28 2011-02-03 주식회사 디마퓨어텍 Material obtained by ultrahigh pressure hydrolysis and liquefaction, and method for producing same
WO2011013996A3 (en) * 2009-07-28 2011-05-19 주식회사 디마퓨어텍 Material obtained by ultrahigh pressure hydrolysis and liquefaction, and method for producing same

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