JP2008145147A - Electrode for detecting potential difference - Google Patents

Electrode for detecting potential difference Download PDF

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JP2008145147A
JP2008145147A JP2006330062A JP2006330062A JP2008145147A JP 2008145147 A JP2008145147 A JP 2008145147A JP 2006330062 A JP2006330062 A JP 2006330062A JP 2006330062 A JP2006330062 A JP 2006330062A JP 2008145147 A JP2008145147 A JP 2008145147A
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main body
electrode
holder
cover
porous filter
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Hideki Kiuchi
英樹 木内
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Shimadzu Corp
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Shimadzu Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an electrode for detecting potential difference capable of simply removing the air in a porous filter without the use of a pressure reducing device. <P>SOLUTION: The electrode for detecting potential difference is equipped with a cover 1 and a holder 2, both of which are connected integrally, the porous filter 7 provided to the opening part of the cover 1, the electrode element 5 provided to the holder 2 and positioned in the internal liquid 10 of the space between the cover 1 and the holder 2; a screw part 3 composed of the female screw 3a formed to the cover 1 and the male screw 3b formed to the holder 2 and the sealing material 4 provided in the vicinity of the screw part 3. Since the overlap part L of the cover 1, including the screw part 3 and the holder 2, is sealed by the sealing material 4 on the way of the threading of the cover 1 and the holder 2 by the screw part 3, the internal liquid 10 is extruded to the outside of the electrode on; and after through the porous filter 7 by a rise in liquid pressure accompanied by the advance of the threading, and at this time, the internal air of the porous filter 7 is also extruded together to the outside of the electrode. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

この発明は、海水中の電気的特性を測定するための測定機器に使用される電位差検出用電極に関する。   The present invention relates to a potential difference detection electrode used in a measuring instrument for measuring electrical characteristics in seawater.

海水中の電位差検出は、海水中に設置された2本の電極素子間の電位差を測定することで達成できる。その電極素子を有する電位差検出用電極として、外部ノイズの影響を受けないようにすることを目的に、電極本体(電極素子)の周囲のケース体に、電極本体を囲むようにシールド板を設け、このシールド板をケーブルの外部導体を経て回路部でアースに接続し、到来した外部ノイズをシールド板を経てアースに落すようにした電極がある(例えば、特許文献1参照)。   Potential difference detection in seawater can be achieved by measuring the potential difference between two electrode elements installed in seawater. As a potential difference detection electrode having the electrode element, a shield plate is provided so as to surround the electrode body in the case body around the electrode body (electrode element) for the purpose of not being affected by external noise. There is an electrode in which this shield plate is connected to the ground in the circuit section through the outer conductor of the cable, and incoming external noise is dropped to the ground through the shield plate (see, for example, Patent Document 1).

そのような電極では、潮流が電極素子に当たると、測定値が大きく揺らぐため、電極素子と海水との間の電気的接続のための多孔質フィルタを開口部に設けたケースに電極素子を収納した構造の電極が一般的に用いられている。   In such an electrode, when the tidal current hits the electrode element, the measured value greatly fluctuates. Therefore, the electrode element is housed in a case in which a porous filter for electrical connection between the electrode element and seawater is provided in the opening. Structured electrodes are commonly used.

その電極は例えば図5に示すような構造である。図5の電極は、カバー1とホルダ2がネジ部3で結合され、ネジ部3の後端部に隣接するようにカバー1とホルダ2との間に介在されたシール材4でカバー1とホルダ2との空間に充填された内部液10が漏出しないようにシールされている。ホルダ2には電極素子5が取り付けられ、電極素子5は内部液10中に位置し、電極素子5からのリード線6がホルダ2外部に導出されている。カバー1の開口部には、潮流を防止するとともに電極素子5と海水とを電気的に接続するための多孔質フィルタ7が設けられている。
特開2000−227411号公報
The electrode has a structure as shown in FIG. The electrode shown in FIG. 5 is formed by connecting the cover 1 and the holder 2 with the screw part 3 and the cover 1 with a sealing material 4 interposed between the cover 1 and the holder 2 so as to be adjacent to the rear end part of the screw part 3. The internal liquid 10 filled in the space with the holder 2 is sealed so as not to leak out. The electrode element 5 is attached to the holder 2, the electrode element 5 is located in the internal liquid 10, and the lead wire 6 from the electrode element 5 is led out of the holder 2. The opening of the cover 1 is provided with a porous filter 7 for preventing tidal current and electrically connecting the electrode element 5 and seawater.
JP 2000-227411 A

図5のような電極に用いられるフィルタ7は多孔質であるため、この電極を海水に浸けてもフィルタ7の内部に空気が残り、この空気が結果的に電極素子5と海水との間の電気的抵抗を大きくしてしまい、測定値の揺らぎを大きくする原因となることが分かっている。   Since the filter 7 used for the electrode as shown in FIG. 5 is porous, air remains in the filter 7 even when the electrode is immersed in seawater. As a result, the air flows between the electrode element 5 and the seawater. It has been found that the electrical resistance is increased, causing the fluctuation of the measured value to increase.

図5に示す構造の電極の場合、カバー1とホルダ2を互いに完全に螺合させると、円形で囲むB部が最後にシール材4によりシールされる。従って、電極素子5を収納した空間の内部液圧は螺合により上昇するが、内部液10はその圧力でカバー1の先端の多孔質フィルタ7ではなく、隙間の大きいネジ部3を通って電極外部に押し出されるので、多孔質フィルタ7の内部空気は残ったままで除去されない。   In the case of the electrode having the structure shown in FIG. 5, when the cover 1 and the holder 2 are completely screwed together, the B portion surrounded by a circle is finally sealed by the sealing material 4. Accordingly, the internal fluid pressure in the space in which the electrode element 5 is accommodated rises due to screwing, but the internal fluid 10 does not pass through the threaded portion 3 having a large gap instead of the porous filter 7 at the tip of the cover 1 due to the pressure. Since it is pushed out, the internal air of the porous filter 7 remains and is not removed.

このため従来は、製造時に多孔質フィルタ内部の空気を除去するために、多孔質フィルタを塩水に浸け、減圧装置を用いて多孔質フィルタ周囲の圧力を下げて、多孔質フィルタ内部の空気を除去する方法が採用されてきた。   For this reason, conventionally, in order to remove the air inside the porous filter at the time of manufacturing, the porous filter is immersed in salt water, and the pressure around the porous filter is lowered using a decompression device to remove the air inside the porous filter. Has been adopted.

しかしながら、その方法は、多孔質フィルタ内部の空気を除去するために減圧装置が必要であり、また減圧時の圧力を海水が沸騰しない程度に制御する必要がある。   However, this method requires a pressure reducing device to remove the air inside the porous filter, and it is necessary to control the pressure at the time of pressure reduction to such a level that the seawater does not boil.

本発明は、そのような問題点に着目してなされたものであって、減圧装置を用いずに多孔質フィルタ内部の空気を簡単に除去することができる電位差検出用電極を提供することを目的としている。   The present invention has been made paying attention to such problems, and an object thereof is to provide a potential difference detection electrode that can easily remove air inside a porous filter without using a decompression device. It is said.

上記の課題を解決するために、本発明の電位差検出用電極は、一体に結合される本体一方部分及び本体他方部分と、本体一方部分の開口部に設けられた多孔質フィルタと、本体他方部分に設けられ、本体一方部分との結合状態で本体一方部分と本体他方部分との空間の内部液中に位置する電極素子と、本体一方部分と本体他方部分との間に介在され、本体一方部分と本体他方部分との空間の内部液をシールするシール材とを備える電極において、本体一方部分と本体他方部分を双方の間にシール材を介在させて結合するときに、結合の途中でシール材のシール機能を発揮させる手段を設けたことを特徴とする。   In order to solve the above problems, the potential difference detection electrode of the present invention includes a main body one part and a main body other part that are integrally coupled, a porous filter provided in an opening of the main body one part, and a main body other part. An electrode element located in the internal liquid in the space between the main body one part and the main body other part in a coupled state with the main body one part, and interposed between the main body one part and the other main body part. And a sealing material that seals the internal liquid in the space between the main body and the other portion of the main body, and when the main body one portion and the other main body portion are joined together with a sealing material interposed therebetween, Means for providing the sealing function is provided.

この電極によると、本体一方部分と本体他方部分を結合するときに、結合の途中でシール材のシール機能が発揮し、これ以降、結合の進行に連れて内部液圧が上昇するため、内部液はその圧力により本体一方部分と本体他方部分との間隙から漏洩することなく、多孔質フィルタを通過して電極外部に押し出されることになる。このとき、多孔質フィルタ内部に残る空気が内部液と一緒に電極外部に押し出されるので、多孔質フィルタ内部の空気を除去することができる。   According to this electrode, when the main body one part and the main body other part are joined, the sealing function of the sealing material is exerted in the middle of joining, and thereafter, the internal fluid pressure increases as the joining progresses. Will be pushed out of the electrode through the porous filter without leaking from the gap between the one part of the main body and the other part of the main body. At this time, the air remaining inside the porous filter is pushed out of the electrode together with the internal liquid, so that the air inside the porous filter can be removed.

この電極において、前記手段は具体的には、本体一方部分と本体他方部分を互いに螺合させるネジ部と、このネジ部に近接して設けられた前記シール材とからなり、本体一方部分と本体他方部分を螺合により完全に結合させたときに、シール材が本体一方部分と本体他方部分とのオーバーラップ部分の途中に位置するようにするのが好ましい。この場合、電極を組み立てる途中で、すなわち本体一方部分と本体他方部分をネジ部により螺合させる途中で、シール材によりネジ部を含む本体一方部分と本体他方部分とのオーバーラップ部分がシールされ、これ以降、螺合に伴って本体一方部分と本体他方部分との空間の内部液圧が自然に高まり、上記の通り多孔質フィルタ内部の残存空気が除去される。   Specifically, in this electrode, the means comprises a screw part for screwing together the main body one part and the other main body part, and the sealing material provided in the vicinity of the screw part. When the other part is completely joined by screwing, it is preferable that the sealing material is positioned in the middle of the overlap part between the one part of the main body and the other part of the main body. In this case, in the middle of assembling the electrode, that is, in the middle of screwing the main body one part and the main body other part with the screw part, the overlap part of the main body one part and the main body other part including the screw part is sealed by the sealing material, Thereafter, the internal fluid pressure in the space between the one part of the main body and the other part of the main body naturally increases with the screwing, and the residual air inside the porous filter is removed as described above.

請求項1記載の発明によれば、多孔質フィルタ内部の空気を除去するための減圧装置が不要となる。また、従来の電極と同じ要領で組み立てるだけで多孔質フィルタ内部の空気を除去することができるので、多孔質フィルタ内部の空気を除去する作業時間・手間が不要となる。   According to the first aspect of the present invention, a decompression device for removing air inside the porous filter is not necessary. Moreover, since the air inside the porous filter can be removed simply by assembling in the same manner as a conventional electrode, the work time and labor for removing the air inside the porous filter are not required.

請求項2記載の発明によれば、簡単な構造で多孔質フィルタ内部の空気を除去することができる。   According to the second aspect of the present invention, the air inside the porous filter can be removed with a simple structure.

以下、実施の形態により、この発明を更に詳細に説明する。   Hereinafter, the present invention will be described in more detail with reference to embodiments.

実施形態に係る電位差検出用電極のカバー1(本体一方部分)の縦断面図を図1に、ホルダ2(本体他方部分)の縦断面図を図2に示す。但し、図5に示す従来の電極と同じ要素には同一符号を付してある。この電極はカバー1とホルダ2を備えるものである。   FIG. 1 is a longitudinal sectional view of a cover 1 (one body part) of a potential difference detection electrode according to the embodiment, and FIG. 2 is a longitudinal sectional view of a holder 2 (other body part). However, the same elements as those of the conventional electrode shown in FIG. This electrode includes a cover 1 and a holder 2.

カバー1は、外部の海水を内部に導入する開口部(符号は付さず)を先端に有する円筒状を呈し、内部が空洞8になっている。空洞8は、内部液10(図3及び図4)が充填される部分8aと、ホルダ2が挿入される部分8bとからなり、部分8bは部分8aよりも大径である。カバー1の先端の開口部には、潮流を防止するとともに電極素子5と海水とを電気的に接続するための多孔質フィルタ7が設けられている。カバー1の後端側に位置する空洞部分8bの内周面の一部分には、ネジ部3を構成する雌ネジ3aが形成されている。   The cover 1 has a cylindrical shape having an opening (not denoted by a reference numeral) for introducing external seawater inside, and the inside is a cavity 8. The cavity 8 includes a portion 8a filled with the internal liquid 10 (FIGS. 3 and 4) and a portion 8b into which the holder 2 is inserted, and the portion 8b has a larger diameter than the portion 8a. A porous filter 7 for preventing tidal current and electrically connecting the electrode element 5 and seawater is provided at the opening at the tip of the cover 1. A female screw 3 a constituting the screw portion 3 is formed on a part of the inner peripheral surface of the hollow portion 8 b located on the rear end side of the cover 1.

ホルダ2は、カバー1に一体に結合される円柱状を呈し、その先端面の中心から突出する電極素子5を有する。電極素子5は例えばAg/AgClからなり、そのリード線6がホルダ2の後端面から外部に導出されている。ホルダ2の先端側の外周面には、ネジ部3を構成する雄ネジ3bが形成されている。この雄ネジ3bに近接して環状の溝21が形成され、この溝21に環状のシール材4が嵌合されている。このシール材4は、カバー1とホルダ2との空間(空洞部分8aと空洞部分8bの一部分)の内部液10がネジ部3を含むカバー1とホルダ2とのオーバーラップ部分L(図4)から漏洩しないようにシールする。また、ホルダ2の溝21よりも後端側は、カバー1の後端部9の厚さ分だけ段差22になっている。このホルダ2の雄ネジ3bから段差22までの部分がカバー1とのオーバーラップ部分Lとなる。   The holder 2 has a columnar shape that is integrally coupled to the cover 1, and includes an electrode element 5 that protrudes from the center of the front end surface thereof. The electrode element 5 is made of, for example, Ag / AgCl, and the lead wire 6 is led out from the rear end surface of the holder 2 to the outside. On the outer peripheral surface on the tip end side of the holder 2, a male screw 3b constituting the screw portion 3 is formed. An annular groove 21 is formed in the vicinity of the male screw 3b, and the annular sealing material 4 is fitted in the groove 21. This sealing material 4 is an overlap portion L (FIG. 4) between the cover 1 and the holder 2 in which the internal liquid 10 in the space between the cover 1 and the holder 2 (a part of the hollow portion 8a and the hollow portion 8b) includes the screw portion 3. Seal to prevent leakage. Further, the rear end side of the groove 2 of the holder 2 has a step 22 corresponding to the thickness of the rear end portion 9 of the cover 1. A portion from the male screw 3 b to the step 22 of the holder 2 becomes an overlap portion L with the cover 1.

このように構成した電極において、多孔質フィルタ7の内部に残存する空気を除去するには、カバー1とホルダ2を互いに螺合させるだけでよい。すなわち、図3に示すように、カバー1とホルダ2をネジ部3(雌ネジ3a及び雄ネジ3b)により互いに螺合させていくと、その途中で図3の円形で囲むA部がシール材4によりシールされる。つまり、シール材4がカバー1とホルダ2との間に介在し、カバー1の内周面に圧接する。これにより、螺合の途中でありながら、カバー1とホルダ2との隙間になり得るネジ部3を含むカバー1とホルダ2とのオーバーラップ部分Lがシールされるので、内部液10はオーバーラップ部分Lから漏洩しなくなる。   In the electrode configured as described above, in order to remove the air remaining in the porous filter 7, it is only necessary to screw the cover 1 and the holder 2 together. That is, as shown in FIG. 3, when the cover 1 and the holder 2 are screwed together by the screw part 3 (the female screw 3a and the male screw 3b), the A part surrounded by the circle in FIG. 4 is sealed. That is, the sealing material 4 is interposed between the cover 1 and the holder 2 and presses against the inner peripheral surface of the cover 1. Thereby, the overlap portion L between the cover 1 and the holder 2 including the screw portion 3 that can be a gap between the cover 1 and the holder 2 is sealed while being screwed, so that the internal liquid 10 is overlapped. No leakage from part L.

図3の状態から更にカバー1とホルダ2を螺合させていくと、カバー1の後端部9がホルダ2の段差22に当接した図4の状態になる。この状態で雌ネジ3aと雄ネジ3bとの螺合(結合)が完了する。この完全結合状態になる過程で、ホルダ2がカバー1の空洞部分8b内に進入するので、カバー1とホルダ2との空間の内部液10の液圧が上昇するが、既にネジ部3を含むオーバーラップ部分Lはシール材4で完全にシールされているので(図3のA部)、内部液10は液圧により多孔質フィルタ7を通って電極外部に押し出される。このとき、多孔質フィルタ7の内部に残留していた空気も内部液10と一緒に電極外部に押し出されることにより、多孔質フィルタ7の内部空気が除去される。   When the cover 1 and the holder 2 are further screwed together from the state of FIG. 3, the rear end portion 9 of the cover 1 comes into contact with the step 22 of the holder 2. In this state, the screwing (coupling) between the female screw 3a and the male screw 3b is completed. Since the holder 2 enters the hollow portion 8b of the cover 1 in the process of being in this completely coupled state, the hydraulic pressure of the internal liquid 10 in the space between the cover 1 and the holder 2 increases, but the screw portion 3 is already included. Since the overlap portion L is completely sealed with the sealing material 4 (A portion in FIG. 3), the internal liquid 10 is pushed out of the electrode through the porous filter 7 by the hydraulic pressure. At this time, the air remaining inside the porous filter 7 is also pushed out of the electrode together with the internal liquid 10, whereby the internal air of the porous filter 7 is removed.

但し、多孔質フィルタ7の内部空気を電極外部に押し出すことが目的であるため、カバー1とホルダ2との螺合作業は、カバー1の先端の多孔質フィルタ7を上に向けて行うことが肝要である。   However, since the purpose is to push the air inside the porous filter 7 to the outside of the electrode, the screwing operation of the cover 1 and the holder 2 can be performed with the porous filter 7 at the tip of the cover 1 facing upward. It is essential.

勿論、カバー1とホルダ2との螺合が完了した状態では、図4のようにシール材4はカバー1とホルダ2とのオーバーラップ部分Lの途中に位置することになる。   Of course, in a state where the cover 1 and the holder 2 are screwed together, the sealing material 4 is located in the middle of the overlap portion L between the cover 1 and the holder 2 as shown in FIG.

この電極によれば、多孔質フィルタ7の内部に残る空気を除去するための減圧装置が不要となるだけでなく、従来の電極と同じ要領で組み立てるだけで多孔質フィルタ7の内部空気を除去することができるので、多孔質フィルタ7の内部空気を除去する作業時間・手間が不要となる。すなわち、組立と同時に多孔質フィルタ7の内部空気の除去も行うことができる。また、ホルダ2の雄ネジ3bに近接して溝21を形成し、この溝21にシール材4を嵌合させる簡単な構造で多孔質フィルタ7の内部空気を除去することができる。   According to this electrode, not only a decompression device for removing the air remaining inside the porous filter 7 becomes unnecessary, but also the internal air of the porous filter 7 is removed simply by assembling in the same manner as the conventional electrode. Therefore, the work time and labor for removing the internal air of the porous filter 7 become unnecessary. That is, the internal air of the porous filter 7 can be removed simultaneously with the assembly. Further, the groove 21 is formed in the vicinity of the male screw 3 b of the holder 2, and the internal air of the porous filter 7 can be removed with a simple structure in which the sealing material 4 is fitted into the groove 21.

なお、上記実施形態では、シール材4をホルダ2の雄ネジ3bに近接して設けてあるが、可能であるならカバー1の雌ネジ3aに近接して溝を設け、この溝にシール材4を嵌合させてもよい。   In the above embodiment, the sealing material 4 is provided close to the male screw 3b of the holder 2, but if possible, a groove is provided close to the female screw 3a of the cover 1, and the sealing material 4 is provided in this groove. May be fitted.

また、上記実施形態では、カバー1とホルダ2をネジ部3により結合しているが、シール材4のみでカバー1とホルダ2を結合する構造であってもよい。この場合は、カバー1とホルダ2が図4のような完全な結合状態となる前に、A部(又はその付近)をシールできる構造とすることで、同様の効果を得ることができる。   Moreover, in the said embodiment, although the cover 1 and the holder 2 are couple | bonded by the screw part 3, the structure which couple | bonds the cover 1 and the holder 2 only with the sealing material 4 may be sufficient. In this case, the same effect can be obtained by adopting a structure in which the portion A (or the vicinity thereof) can be sealed before the cover 1 and the holder 2 are completely joined as shown in FIG.

実施形態に係る電位差検出用電極のカバーの縦断面図である。It is a longitudinal cross-sectional view of the cover of the potential difference detection electrode according to the embodiment. 実施形態に係る電位差検出用電極のホルダの縦断面図である。It is a longitudinal cross-sectional view of the holder of the potential difference detection electrode according to the embodiment. 実施形態に係る電位差検出用電極において、カバーとホルダとを螺合させる途中の状態を示す縦断面図である。In the potential difference detection electrode according to the embodiment, it is a longitudinal sectional view showing a state in the middle of screwing the cover and the holder. 同電位差検出用電極において、カバーとホルダとの螺合が完了した状態を示す縦断面図である。It is a longitudinal cross-sectional view which shows the state which the screwing of the cover and the holder was completed in the same potential difference detection electrode. 従来例に係る電位差検出用電極の縦断面図である。It is a longitudinal cross-sectional view of a potential difference detection electrode according to a conventional example.

符号の説明Explanation of symbols

1 カバー(本体一方部分)
2 ホルダ(本体他方部分)
3 ネジ部
3a 雌ネジ
3b 雄ネジ
4 シール材
5 電極素子
7 多孔質フィルタ
8 空洞
10 内部液
L カバーとホルダとのオーバーラップ部分
1 Cover (Body one part)
2 Holder (the other part of the main body)
DESCRIPTION OF SYMBOLS 3 Screw part 3a Female screw 3b Male screw 4 Seal material 5 Electrode element 7 Porous filter 8 Cavity 10 Internal liquid L The overlap part of a cover and a holder

Claims (2)

一体に結合される本体一方部分及び本体他方部分と、
本体一方部分の開口部に設けられた多孔質フィルタと、
本体他方部分に設けられ、本体一方部分との結合状態で本体一方部分と本体他方部分との空間の内部液中に位置する電極素子と、
本体一方部分と本体他方部分との間に介在され、本体一方部分と本体他方部分との空間の内部液をシールするシール材とを備える電極において、
本体一方部分と本体他方部分を双方の間にシール材を介在させて結合するときに、結合の途中でシール材のシール機能を発揮させる手段を設けたことを特徴とする電位差検出用電極。
One part of the main body and the other part of the main body coupled together,
A porous filter provided in the opening of one part of the main body;
An electrode element that is provided in the other part of the main body and is located in the internal liquid in the space between the main body one part and the main body other part in a combined state with the main body one part;
In an electrode that is interposed between the main body one part and the main body other part, and includes a sealing material that seals the internal liquid in the space between the main body one part and the main body other part,
An electrode for potential difference detection, comprising means for exerting a sealing function of a sealing material in the middle of coupling when the main body one portion and the other main body portion are coupled with a sealing material interposed therebetween.
前記手段は、本体一方部分と本体他方部分を互いに螺合させるネジ部と、このネジ部に近接して設けられた前記シール材とからなり、本体一方部分と本体他方部分を螺合により完全に結合させたときに、シール材が本体一方部分と本体他方部分とのオーバーラップ部分の途中に位置するようにしたことを特徴とする請求項1記載の電位差検出用電極。   The means comprises a screw portion for screwing the main body one portion and the main body other portion together, and the sealing material provided in the vicinity of the screw portion, and the main body one portion and the other main body portion are completely screwed together. 2. The potential difference detection electrode according to claim 1, wherein, when bonded, the sealing material is positioned in the middle of the overlap portion between the one part of the main body and the other part of the main body.
JP2006330062A 2006-12-07 2006-12-07 Electrode for detecting potential difference Pending JP2008145147A (en)

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JPH10170501A (en) * 1996-12-09 1998-06-26 Able Kk Apparatus and method for measurement of water quality
JP2000227411A (en) * 1999-02-05 2000-08-15 Shimadzu Corp Electrode for under-the-sea characteristic measuring instrument
JP2001082612A (en) * 1999-09-14 2001-03-30 Big Alpha Kk Seal device for screwing structure
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CN104937049A (en) * 2013-03-07 2015-09-23 富士胶片株式会社 Inkjet ink composition, inkjet recording method, printed matter and method of producing formed printed matter

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