JP2008137322A - Manufacturing method of resin plate having unevenly shaped part on surface - Google Patents

Manufacturing method of resin plate having unevenly shaped part on surface Download PDF

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JP2008137322A
JP2008137322A JP2006327197A JP2006327197A JP2008137322A JP 2008137322 A JP2008137322 A JP 2008137322A JP 2006327197 A JP2006327197 A JP 2006327197A JP 2006327197 A JP2006327197 A JP 2006327197A JP 2008137322 A JP2008137322 A JP 2008137322A
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resin plate
resin
concavo
mass
parts
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JP4933235B2 (en
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Naomi Oku
尚規 奥
Hiroko Kanetani
浩子 金谷
Akiyoshi Kanemitsu
昭佳 金光
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Sumitomo Chemical Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method of a resin plate whose surface has an unevenly shaped part formed by a cut processing, which method can thoroughly smooth the cut-processed surfaces of the uneven shape part without changing the uneven shapes formed by the cut processing. <P>SOLUTION: The manufacturing method of the resin plate 10 having the unevenly shaped part on its surface comprises the step of forming the unevenly shaped part 2 on the surface of the resin plate by providing the resin plate surface with the cut processing, and the step of coating the surfaces 2a on the resin plate, formed in the unevenly shaped part 2, with a treating solution containing 0.5-3 parts by mass of a resin based on 100 parts by mass of a solvent by a drip coating method and then drying the surfaces. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

この発明は、削り加工を施すことによって表面に凹凸形状部を有する樹脂板を製造するに際し、凹凸形状部の削り加工面を十分に平滑化できる製造方法に関する。   The present invention relates to a manufacturing method capable of sufficiently smoothing a shaved surface of a concavo-convex shape portion when a resin plate having a concavo-convex shape portion on a surface is manufactured by performing a shaving process.

樹脂板の表面にミクロンレベルの凹凸形状(三角形状等)を加工する方法としては、ダイヤモンドバイト等を用いた切削加工、ダイヤモンド砥石や金属砥石等を用いた研削加工、レーザー加工が公知である。   As a method for processing a micron level uneven shape (triangular shape or the like) on the surface of a resin plate, a cutting process using a diamond bite, a grinding process using a diamond grindstone, a metal grindstone, or the like is known.

また、プラスチックレンズの表面の凹凸(傷)を見えなくする方法として、レンズ基材を50〜150℃の温度で加熱処理する方法が知られている(特許文献1参照)。
特開2002−22902号公報
Further, as a method for making the unevenness (scratches) on the surface of the plastic lens invisible, there is known a method in which a lens substrate is heat-treated at a temperature of 50 to 150 ° C. (see Patent Document 1).
Japanese Patent Laid-Open No. 2002-22902

しかるに、上記切削加工で加工した場合、非常に平滑な削り加工面を得ることができるものの、長時間同一のダイヤモンドバイトで加工を行った場合、該バイトの刃先に荒れが生じ、これが削り加工面に微細な筋として残ることが懸念される。また、切削加工時に、ワークをセットするステージが僅かに揺れた場合でも、削り加工面に微細な筋が入ることも懸念される。このように樹脂板の削り加工面に微細な筋が残存していると、該削り加工面に入射してくる光が無秩序に散乱されるために、この樹脂板を例えばプリズムシート等の光学的用途に用いることはできなかった。   However, when machined by the above cutting process, a very smooth machined surface can be obtained, but when machining with the same diamond tool for a long time, the cutting edge of the tool is roughened, which is the machined surface. It is feared that it will remain as fine streaks. In addition, even when the stage on which the workpiece is set is slightly shaken during the cutting process, there is a concern that fine streaks may enter the machined surface. If fine streaks remain on the machined surface of the resin plate in this way, the light incident on the machined surface is randomly scattered. It could not be used for applications.

また、研削加工を用いる場合、刃の回転を用いて形状を加工するので、樹脂板の削り加工面には刃が回転した跡が残る。このように樹脂板の削り加工面に刃の回転跡が残存していると、該削り加工面に入射してくる光が無秩序に散乱されて樹脂板の削り加工面が白濁化するので、この樹脂板を例えばプリズムシート等の光学的用途に用いることはできなかった。   Further, when grinding is used, the shape is processed using the rotation of the blade, so that a trace of the rotation of the blade remains on the cut surface of the resin plate. When the blade rotation trace remains on the machined surface of the resin plate in this way, the light incident on the machined surface is randomly scattered and the machined surface of the resin plate becomes clouded. The resin plate could not be used for optical applications such as a prism sheet.

また、レーザー加工では、バイトや砥石の接触による加工跡が残存することはないものの、レーザー加工の際の熱によって加工表面が荒らされるという問題があり、この樹脂板を例えばプリズムシート等の光学的用途に用いることはできなかった。   Further, in laser processing, although the processing trace due to the contact of the cutting tool and the grindstone does not remain, there is a problem that the processing surface is roughened by the heat during the laser processing, and this resin plate is used as an optical material such as a prism sheet. It could not be used for applications.

また、上記特許文献1の加熱手法を、削り加工によって凹凸高さが1.0〜800μm程度のミクロンレベルの凹凸形状部が表面に形成された樹脂板に対して適用すると、削り加工によって一旦形成せしめた凹凸形状部の加工形状が、熱によって変形するという問題があった。   In addition, when the heating method of Patent Document 1 is applied to a resin plate having a concavo-convex shape portion having a concavo-convex height of about 1.0 to 800 μm formed on the surface by shaving, it is once formed by shaving. There has been a problem that the processed shape of the concavo-convex shape portion thus deformed is deformed by heat.

この発明は、かかる技術的背景に鑑みてなされたものであって、削り加工を施すことによって樹脂板の表面に凹凸形状部を形成する製造方法であって、削り加工により形成した凹凸形状を変形させることなく、凹凸形状部の削り加工面を十分に平滑化することのできる製造方法を提供することを目的とする。   The present invention has been made in view of such a technical background, and is a manufacturing method for forming a concavo-convex shape portion on the surface of a resin plate by shaving, and deforming the concavo-convex shape formed by the shaving process An object of the present invention is to provide a manufacturing method capable of sufficiently smoothing the shaving surface of the concavo-convex shape portion without causing the unevenness-shaped portion.

前記目的を達成するために、本発明は以下の手段を提供する。   In order to achieve the above object, the present invention provides the following means.

[1]樹脂板の表面に削り加工を施すことによって前記樹脂板の表面に凹凸形状部を形成する削り工程と、
前記樹脂板における前記凹凸形状部が形成された表面に、溶媒100質量部に対して樹脂を0.5〜3質量部含有してなる処理液をドリップコーティング法により塗布した後、乾燥させる工程と、
を包含することを特徴とする表面に凹凸形状部を有する樹脂板の製造方法。
[1] A shaving step of forming a concavo-convex shape portion on the surface of the resin plate by shaving the surface of the resin plate;
A step of applying a treatment liquid containing 0.5 to 3 parts by mass of a resin to 100 parts by mass of the solvent on the surface of the resin plate on which the concavo-convex shape part is formed, and then drying the solution. ,
The manufacturing method of the resin board which has an uneven | corrugated shaped part on the surface characterized by including.

[2]樹脂板の表面に削り加工を施すことによって前記樹脂板の表面に凹凸形状部を形成する削り工程と、
前記樹脂板における前記凹凸形状部が形成された表面に、溶媒100質量部に対して樹脂を3〜7質量部含有してなる処理液を刷毛塗り法により塗布した後、乾燥させる工程と、
を包含することを特徴とする表面に凹凸形状部を有する樹脂板の製造方法。
[2] A shaving step of forming a concavo-convex shape portion on the surface of the resin plate by shaving the surface of the resin plate;
Applying a treatment liquid containing 3 to 7 parts by mass of a resin to 100 parts by mass of the solvent on the surface of the resin plate on which the concavo-convex shape part is formed, followed by drying,
The manufacturing method of the resin board which has an uneven | corrugated shaped part on the surface characterized by including.

[3]前記削り加工が、切削加工または研削加工である前項1または2に記載の表面に凹凸形状部を有する樹脂板の製造方法。   [3] The method for producing a resin plate having a concavo-convex shape portion on the surface according to the item 1 or 2, wherein the shaving is cutting or grinding.

[4]前記凹凸形状部は、断面形状が三角形である三角形凸部を多数個備えてなる前項1〜3のいずれか1項に記載の表面に凹凸形状部を有する樹脂板の製造方法。   [4] The method for producing a resin plate, wherein the concavo-convex shape portion has a concavo-convex shape portion on the surface according to any one of the above items 1 to 3, wherein the concavo-convex shape portion includes a plurality of triangular convex portions having a triangular cross-sectional shape.

[5]前記処理液を構成する樹脂として、前記樹脂板の屈折率との屈折率差の絶対値が0.05以下である樹脂を用いる前項1〜4のいずれか1項に記載の表面に凹凸形状部を有する樹脂板の製造方法。   [5] The surface according to any one of the above items 1 to 4, wherein a resin having an absolute value of a difference in refractive index from the refractive index of the resin plate is 0.05 or less as the resin constituting the treatment liquid. The manufacturing method of the resin board which has an uneven | corrugated shaped part.

[6]前記削り工程において、前記樹脂板の表面に凹凸高さが1.0〜800μmの凹凸形状部を形成する前項1〜5のいずれか1項に記載の表面に凹凸形状部を有する樹脂板の製造方法。   [6] The resin having a concavo-convex shape portion on the surface according to any one of items 1 to 5 above, wherein in the shaving step, a concavo-convex height portion having a concavo-convex height of 1.0 to 800 μm is formed on the surface of the resin plate. A manufacturing method of a board.

[1]の発明では、樹脂板における凹凸形状部の削り加工面に、溶媒100質量部に対して樹脂を0.5〜3質量部含有してなる処理液をドリップコーティング法により塗布した後、乾燥させるので、削り加工により形成された凹凸形状を変形させることなく、凹凸形状部の削り加工面を十分に平滑化することができる。   In the invention of [1], after applying a treatment liquid containing 0.5 to 3 parts by mass of a resin with respect to 100 parts by mass of a solvent on a shaved surface of an uneven shape part in a resin plate, Since it dries, the shaving surface of the concavo-convex shape portion can be sufficiently smoothed without deforming the concavo-convex shape formed by the shaving process.

[2]の発明では、樹脂板における凹凸形状部の削り加工面に、溶媒100質量部に対して樹脂を3〜7質量部含有してなる処理液を刷毛塗り法により塗布した後、乾燥させるので、削り加工により形成された凹凸形状を変形させることなく、凹凸形状部の削り加工面を十分に平滑化することができる。   In the invention of [2], a treatment liquid containing 3 to 7 parts by mass of a resin with respect to 100 parts by mass of the solvent is applied to the shaving surface of the uneven part of the resin plate by a brush coating method and then dried. Therefore, the shaving surface of the concavo-convex shape portion can be sufficiently smoothed without deforming the concavo-convex shape formed by the shaving process.

[3]の発明では、切削加工または研削加工により削り加工するので、より精度の高い凹凸形状部を形成できる。   In the invention of [3], since the shaving is performed by cutting or grinding, it is possible to form an uneven shape portion with higher accuracy.

[4]の発明では、凹凸形状部は、断面形状が三角形である三角形凸部を多数個備えてなる構成であるから、製造された樹脂板は、例えばプリズムシート、光拡散板として好適である。   In the invention of [4], since the concavo-convex shape portion is configured to include a large number of triangular convex portions having a triangular cross-sectional shape, the manufactured resin plate is suitable as, for example, a prism sheet or a light diffusion plate. .

[5]の発明では、処理液を構成する樹脂として、樹脂板の屈折率との屈折率差の絶対値が0.05以下である樹脂を用いるから、得られた樹脂板では、凹凸形状部の表面における光の散乱と屈折を十分に抑制することができて、入射してくる光の強度を十分に維持しつつ光が透過するものとなる(優れた光透過性を確保できる)。   In the invention of [5], as the resin constituting the treatment liquid, a resin having an absolute value of the difference in refractive index from the refractive index of the resin plate of 0.05 or less is used. Scattering and refraction of light on the surface can be sufficiently suppressed, and light can be transmitted while sufficiently maintaining the intensity of incident light (excellent light transmission can be ensured).

[6]の発明では、凹凸高さが1.0〜800μmの微細な凹凸形状部を形成する場合においても、削り加工により形成された凹凸形状を変形させることなく、凹凸形状部の削り加工面を十分に平滑化することができる。   In the invention of [6], even in the case of forming a fine concavo-convex shape portion having a concavo-convex height of 1.0 to 800 μm, the processed surface of the concavo-convex shape portion is not deformed without deforming the concavo-convex shape formed by the shaving process. Can be sufficiently smoothed.

この発明の第1製造方法は、樹脂板の表面に削り加工を施すことによって前記樹脂板の表面に凹凸形状部を形成する削り工程と、前記樹脂板(1)における前記凹凸形状部(2)が形成された表面に、溶媒100質量部に対して樹脂を0.5〜3質量部含有してなる処理液をドリップコーティング法により塗布した後、乾燥させる工程と、を包含することを特徴とする。   The first manufacturing method of the present invention includes a shaving step of forming a concavo-convex shape portion on the surface of the resin plate by shaving the surface of the resin plate, and the concavo-convex shape portion (2) in the resin plate (1). And a step of applying a treatment liquid containing 0.5 to 3 parts by mass of a resin to 100 parts by mass of a solvent by a drip coating method and then drying the surface. To do.

また、この発明の第2製造方法は、樹脂板の表面に削り加工を施すことによって前記樹脂板の表面に凹凸形状部を形成する削り工程と、前記樹脂板(1)における前記凹凸形状部(2)が形成された表面に、溶媒100質量部に対して樹脂を3〜7質量部含有してなる処理液を刷毛塗り法により塗布した後、乾燥させる工程と、を包含することを特徴とする。   Moreover, the 2nd manufacturing method of this invention is a shaving process which forms an uneven | corrugated shaped part in the surface of the said resin board by shaving the surface of a resin board, and the said uneven | corrugated shaped part (in the said resin board (1) ( And a step of applying a treatment liquid containing 3 to 7 parts by mass of a resin to 100 parts by mass of a solvent on the surface on which 2) is formed, followed by drying. To do.

一般に、単に、樹脂板の表面に削り加工(切削加工、研削加工、レーザー加工等)を施すことによって樹脂板の表面に凹凸形状部(2)を形成した場合、図1(a)に示すように、凹凸形状部(2)の削り加工面(2a)は粗面(非平滑面)になっており、このために従来では特に光学用途への適用は困難であったのであるが、本発明の上記第1製造方法では、前記樹脂板(1)における前記凹凸形状部(2)が形成された表面に、溶媒100質量部に対して樹脂を0.5〜3質量部含有してなる処理液をドリップコーティング法により塗布した後、乾燥させるものであるから、図1(b)に示すように、削り加工により形成された凹凸形状を変形させることなく、凹凸形状部(2)の削り加工面(2a)を十分に平滑化することができ、また上記第2製造方法では、前記樹脂板(1)における前記凹凸形状部(2)が形成された表面に、溶媒100質量部に対して樹脂を3〜7質量部含有してなる処理液を刷毛塗り法により塗布した後、乾燥させるので、図1(b)に示すように、削り加工により形成された凹凸形状を変形させることなく、凹凸形状部(2)の削り加工面(2a)を十分に平滑化することができる。   In general, when the concavo-convex shape portion (2) is formed on the surface of the resin plate simply by subjecting the surface of the resin plate to cutting (cutting, grinding, laser processing, etc.), as shown in FIG. In addition, the machined surface (2a) of the concavo-convex shape portion (2) is a rough surface (non-smooth surface), and for this reason, it has been difficult to apply to optical applications in the past. In the said 1st manufacturing method, the process formed by containing 0.5-3 mass parts of resin with respect to 100 mass parts of solvent on the surface in which the said uneven | corrugated shaped part (2) in the said resin plate (1) was formed. Since the liquid is applied by the drip coating method and then dried, as shown in FIG. 1 (b), the concavo-convex shape portion (2) is shaved without deforming the concavo-convex shape formed by the shaving process. The surface (2a) can be sufficiently smoothed. In the second manufacturing method, a treatment liquid containing 3 to 7 parts by mass of a resin with respect to 100 parts by mass of the solvent is brushed on the surface of the resin plate (1) on which the uneven portion (2) is formed. Since it is dried after being applied by the coating method, as shown in FIG. 1B, the shaving surface (2a) of the concavo-convex shape portion (2) is sufficiently obtained without deforming the concavo-convex shape formed by the shaving process. Can be smoothed.

前記第1及び第2製造方法では、まず、樹脂板の表面に削り加工を施すことによって樹脂板の表面に凹凸形状部(2)を形成する(削り工程)。この凹凸形状部(2)の削り加工面(2a)は、単に削り加工しただけであるから、図1(a)に示すように、粗面(非平滑面)である。   In the first and second manufacturing methods, first, an uneven shape portion (2) is formed on the surface of the resin plate by performing a cutting process on the surface of the resin plate (a cutting step). The shaving surface (2a) of the concavo-convex shape portion (2) is a rough surface (non-smooth surface) as shown in FIG.

本実施形態では、樹脂板の表面に削り加工を施すことによって樹脂板の表面に断面形状が三角形である三角形凸部(7)が複数個突設されてなる凹凸形状部(2)を形成した(図1参照)。この三角形凸部(7)は、樹脂板の表面に平行な一方向に沿って延ばされた断面形状が三角形の凸条部(8)で形成され、これら複数の凸条部(8)の長さ方向は互いに略平行状である(図2参照)。   In the present embodiment, the surface of the resin plate is cut to form an uneven shape portion (2) formed by projecting a plurality of triangular protrusions (7) having a triangular cross-sectional shape on the surface of the resin plate. (See FIG. 1). The triangular convex portion (7) is formed of a triangular convex portion (8) having a cross-sectional shape extending along one direction parallel to the surface of the resin plate, and the plurality of convex portions (8). The length directions are substantially parallel to each other (see FIG. 2).

前記削り加工対象の樹脂板としては、特に限定されずどのような種類の樹脂板でも用いることができる。例えば、アクリル系樹脂、ポリエチレン、ポリプロピレン、ポリスチレン、ABS樹脂、ポリカーボネート等が挙げられるが、特にこれら例示のものに限定されない。   The resin plate to be machined is not particularly limited, and any type of resin plate can be used. For example, acrylic resin, polyethylene, polypropylene, polystyrene, ABS resin, polycarbonate and the like can be mentioned, but not particularly limited to those exemplified.

前記削り加工としては、切削加工、研削加工、レーザー加工等が挙げられるが、特にこれら例示の加工に限定されるものではない。ただ、切削加工または研削加工により削り加工した場合にはより精度の高い凹凸形状を形成できるので、切削加工または研削加工を採用するのが好ましい。   Examples of the shaving include cutting, grinding, and laser processing, but are not particularly limited to these exemplified processes. However, since it is possible to form a highly accurate uneven shape when machining is performed by cutting or grinding, it is preferable to employ cutting or grinding.

前記切削加工としては、特に限定されるものではないが、例えばダイヤモンドバイトを用いた切削加工等が挙げられる。また、前記研削加工としては、特に限定されるものではないが、例えばダイヤモンド砥石、金属砥石、合金バイト等を用いた研削加工等が挙げられる。   Although it does not specifically limit as said cutting process, For example, the cutting process using a diamond bit etc. are mentioned. The grinding process is not particularly limited, and examples thereof include a grinding process using a diamond grindstone, a metal grindstone, an alloy cutting tool, and the like.

前記削り加工により形成する凹凸形状部(2)の断面形状としては、例えば三角形形状(プリズム形状)、四角形形状(台形形状等)、その他の多角形形状、レンチキュラーレンズ形状、その他の入り組んだ凹凸形状などが挙げられるが、特にこれら例示の形状に限定されない。   Examples of the cross-sectional shape of the concavo-convex shape portion (2) formed by the shaving process include a triangular shape (prism shape), a square shape (trapezoidal shape, etc.), other polygonal shapes, lenticular lens shapes, and other complicated concavo-convex shapes. However, it is not particularly limited to these exemplified shapes.

前記削り加工により形成する凹凸形状部(2)の凹凸高さ(H)は、通常、1.0〜800μmである。   The concavo-convex height (H) of the concavo-convex shape portion (2) formed by the shaving process is usually 1.0 to 800 μm.

次に、第1製造方法では、前記樹脂板(1)における前記凹凸形状部(2)が形成された表面に、溶媒100質量部に対して樹脂を0.5〜3質量部含有してなる処理液をドリップコーティング法により塗布した後、乾燥させる。前記処理液としては、溶媒100質量部に対して樹脂を0.5〜3質量部含有してなる処理液を用いる。0.5質量部未満では削り加工で形成された凹凸形状部(2)が溶媒による溶解作用を受けやすくなって凹凸形状部の変形を生じて形状精度が低下する。また、3質量部を超えると、凹凸形状部の溝部に樹脂分が溜まりやすく形状精度が低下する。中でも、溶媒100質量部に対して樹脂を0.8〜2.5質量部含有してなる処理液を用いるのが好ましい。   Next, in the 1st manufacturing method, 0.5-3 mass parts of resin is contained with respect to 100 mass parts of solvents in the surface in which the said uneven | corrugated shaped part (2) in the said resin plate (1) was formed. The treatment liquid is applied by a drip coating method and then dried. As the treatment liquid, a treatment liquid containing 0.5 to 3 parts by mass of a resin with respect to 100 parts by mass of the solvent is used. If the amount is less than 0.5 parts by mass, the concavo-convex shape portion (2) formed by the shaving process is likely to be subjected to the dissolving action by the solvent, and the concavo-convex shape portion is deformed to reduce the shape accuracy. On the other hand, when the amount exceeds 3 parts by mass, the resin component tends to accumulate in the groove portion of the concavo-convex shape portion, and the shape accuracy decreases. Among them, it is preferable to use a treatment liquid containing 0.8 to 2.5 parts by mass of a resin with respect to 100 parts by mass of the solvent.

前記ドリップコーティング法とは、樹脂板(1)の塗布対象面を水平面に対して傾斜させて配置し、この状態で塗布対象面の一端側(上端側)に処理液を滴下することによって、樹脂板の塗布対象面に処理液をコーティングする方法である(図3参照)。なお、このドリップコーティング法により塗布する場合には、図3に示すように、処理液の滴下方向(即ち上下方向)に三角形凸部(7)からなる凸条部(8)の長さ方向を略一致させた態様で塗布を行うのが好ましく、この場合には凹凸形状部(2)の削り加工面(2a)をより一層平滑化することができる。   The drip coating method is a resin plate (1) in which a coating target surface is inclined with respect to a horizontal plane, and in this state, a treatment liquid is dropped onto one end side (upper end side) of the coating target surface. This is a method of coating the surface to be coated with a treatment liquid (see FIG. 3). In addition, when applying by this drip coating method, as shown in FIG. 3, the length direction of the ridge part (8) which consists of a triangular convex part (7) in the dripping direction (namely, up-down direction) of a process liquid is shown. It is preferable to apply in a substantially matched manner. In this case, the shaving surface (2a) of the concavo-convex shape portion (2) can be further smoothed.

また、第2製造方法では、前記樹脂板(1)における前記凹凸形状部(2)が形成された表面に、溶媒100質量部に対して樹脂を3〜7質量部含有してなる処理液を刷毛塗り法により塗布した後、乾燥させる。前記処理液としては、溶媒100質量部に対して樹脂を3〜7質量部含有してなる処理液を用いる。3質量部未満では削り加工で形成された凹凸形状部(2)が溶媒による溶解作用を受けやすくなって凹凸形状部の変形を生じて形状精度が低下する。また、7質量部を超えると、凹凸形状部の溝部に樹脂分が溜まりやすく形状精度が低下する。中でも、溶媒100質量部に対して樹脂を4〜6質量部含有してなる処理液を用いるのが好ましい。   Moreover, in the 2nd manufacturing method, the process liquid formed by containing 3-7 mass parts of resin with respect to 100 mass parts of solvent on the surface in which the said uneven | corrugated shaped part (2) in the said resin plate (1) was formed. After applying by brushing, it is dried. As the treatment liquid, a treatment liquid containing 3 to 7 parts by mass of a resin with respect to 100 parts by mass of the solvent is used. If the amount is less than 3 parts by mass, the concavo-convex shape portion (2) formed by the shaving process is likely to be subjected to a dissolving action by the solvent, causing deformation of the concavo-convex shape portion and lowering the shape accuracy. On the other hand, when the amount exceeds 7 parts by mass, the resin component tends to accumulate in the groove portion of the concavo-convex shape portion, and the shape accuracy decreases. Especially, it is preferable to use the processing liquid which contains 4-6 mass parts of resin with respect to 100 mass parts of solvents.

前記刷毛塗り法とは、前記処理液を刷毛に染み込ませて該刷毛を用いて塗布する塗布方法である。   The brush coating method is a coating method in which the treatment liquid is soaked into a brush and applied using the brush.

前記第1製造方法及び前記第2製造方法において、溶媒としては、特に限定されるものではないが、例えばクロロホルム、メチルアルコール、ベンゼン、アセトン等が挙げられる。中でも、揮発性が高く乾燥速度が大きい点で、クロロホルムが好適に用いられる。   In the first production method and the second production method, the solvent is not particularly limited, and examples thereof include chloroform, methyl alcohol, benzene, and acetone. Among these, chloroform is preferably used because it is highly volatile and has a high drying rate.

また、前記処理液を構成する樹脂としては、特に限定されるものではないが、アクリル系樹脂、ポリスチレン、ポリエチレン、ポリプロピレン、ABS樹脂、ポリカーボネート等が挙げられる。中でも、前記処理液を構成する樹脂としては、前記樹脂板(1)の屈折率との屈折率差の絶対値が0.05以下(0を含む)である樹脂を用いるのが好ましい。この場合には、得られた樹脂板(10)において、凹凸形状部(2)の表面における光の散乱と屈折を十分に抑制することができて、入射してくる光の強度を十分に維持しつつ光が透過するものとなる。前記処理液を構成する樹脂としては、前記樹脂板(1)の屈折率との屈折率差の絶対値が0.03以下である樹脂を用いるのがより好ましく、同0.01以下である樹脂を用いるのが特に好ましい。   In addition, the resin constituting the treatment liquid is not particularly limited, and examples thereof include acrylic resin, polystyrene, polyethylene, polypropylene, ABS resin, and polycarbonate. Among them, as the resin constituting the treatment liquid, it is preferable to use a resin having an absolute value of a difference in refractive index from the refractive index of the resin plate (1) of 0.05 or less (including 0). In this case, in the obtained resin plate (10), the scattering and refraction of light on the surface of the uneven portion (2) can be sufficiently suppressed, and the intensity of incident light is sufficiently maintained. However, light is transmitted. As the resin constituting the treatment liquid, it is more preferable to use a resin having an absolute value of the difference in refractive index from the refractive index of the resin plate (1) of 0.03 or less, and a resin having a value of 0.01 or less. It is particularly preferable to use

また、前記乾燥の手法としては、特に限定されるものではないが、例えば10〜30℃程度の温度で自然乾燥させる手法等が挙げられる。この乾燥処理によって、前記凹凸形状部(2)の削り加工面(2a)に樹脂のコーティング膜が形成されて平滑化処理が施される。   The drying method is not particularly limited, and examples thereof include a method of natural drying at a temperature of about 10 to 30 ° C. By this drying process, a resin coating film is formed on the shaved surface (2a) of the concavo-convex shape part (2), and a smoothing process is performed.

この発明に係る表面に凹凸形状部を有する樹脂板(10)の製造方法は、上記実施形態のものに特に限定されるものではなく、請求の範囲内であれば、その精神を逸脱するものでない限りいかなる設計的変更をも許容するものである。   The manufacturing method of the resin plate (10) having a concavo-convex shape portion on the surface according to the present invention is not particularly limited to the above embodiment, and does not depart from the spirit as long as it is within the scope of the claims. Any design changes are allowed as far as possible.

次に、この発明の具体的実施例について説明するが、本発明はこれら実施例のものに特に限定されるものではない。   Next, specific examples of the present invention will be described, but the present invention is not particularly limited to these examples.

<実施例1>
厚さ2mmのアクリル樹脂板(屈折率1.49)の表面に研削加工を施すことによって、アクリル樹脂板の表面に、図1(a)に示すような断面形状が三角形である三角形凸部(7)からなる凸条部(8)が多数個突設された凹凸形状部(2)を形成した。この三角形凸部(7)の頂角(α)は90度、三角形凸部(7)の高さ(H)は150μm、隣り合う三角形凸部(7)同士のピッチ間隔(P)は300μmであった。前記研削加工は、株式会社テクノロジック製の研削機(FM1280型)を用いて合金バイト(テーパー角度を20度に研磨したもの)により行った。
<Example 1>
By subjecting the surface of an acrylic resin plate (refractive index 1.49) to a thickness of 2 mm to grinding, a triangular convex portion (a cross-sectional shape as shown in FIG. The uneven | corrugated shaped part (2) in which many protruding item | line parts (8) which consist of 7) protruded was formed. The apex angle (α) of this triangular convex part (7) is 90 degrees, the height (H) of the triangular convex part (7) is 150 μm, and the pitch interval (P) between adjacent triangular convex parts (7) is 300 μm. there were. The grinding process was performed with an alloy cutting tool (having a taper angle of 20 degrees) using a grinder manufactured by Technotech (FM1280 type).

次に、前記樹脂板(1)における凹凸形状部(2)が形成された表面に、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)1.0質量部溶解せしめてなる処理液をドリップコーティング法(図3参照)により塗布した後、20℃の室内で自然乾燥させることによって、図2に示すような光学部材(10)を作製した。   Next, a treatment liquid obtained by dissolving 1.0 part by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform on the surface of the resin plate (1) where the uneven part (2) is formed. Was applied by a drip coating method (see FIG. 3), and then naturally dried in a room at 20 ° C. to produce an optical member (10) as shown in FIG.

<実施例2>
前記処理液として、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)2.0質量部溶解せしめてなる処理液を用いた以外は、実施例1と同様にして光学部材を作製した。
<Example 2>
An optical member was produced in the same manner as in Example 1 except that a treatment liquid prepared by dissolving 2.0 parts by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform was used as the treatment liquid. .

<実施例3>
前記処理液として、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)2.5質量部溶解せしめてなる処理液を用いた以外は、実施例1と同様にして光学部材を作製した。
<Example 3>
An optical member was produced in the same manner as in Example 1 except that a treatment liquid obtained by dissolving 2.5 parts by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform was used as the treatment liquid. .

<比較例1>
前記処理液として、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)5.0質量部溶解せしめてなる処理液を用いた以外は、実施例1と同様にして光学部材を作製した。
<Comparative Example 1>
An optical member was produced in the same manner as in Example 1 except that a treatment liquid prepared by dissolving 5.0 parts by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform was used as the treatment liquid. .

<比較例2>
前記処理液として、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)10.0質量部溶解せしめてなる処理液を用いた以外は、実施例1と同様にして光学部材を作製した。
<Comparative example 2>
An optical member was produced in the same manner as in Example 1 except that a treatment liquid obtained by dissolving 10.0 parts by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform was used as the treatment liquid. .

<比較例3>
前記処理液として、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)0.2質量部溶解せしめてなる処理液を用いた以外は、実施例1と同様にして光学部材を作製した。
<Comparative Example 3>
An optical member was produced in the same manner as in Example 1 except that a treatment liquid obtained by dissolving 0.2 part by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform was used as the treatment liquid. .

<実施例4>
厚さ2mmのアクリル樹脂板(屈折率1.49)の表面に研削加工を施すことによって、アクリル樹脂板の表面に、図1(a)に示すような断面形状が三角形である三角形凸部(7)からなる凸条部(8)が多数個突設された凹凸形状部(2)を形成した。この三角形凸部(7)の頂角(α)は90度、三角形凸部(7)の高さ(H)は150μm、隣り合う三角形凸部(7)同士のピッチ間隔(P)は300μmであった。前記研削加工は、株式会社テクノロジック製の研削機(FM1280型)を用いて合金バイト(テーパー角度を20度に研磨したもの)により行った。
<Example 4>
By subjecting the surface of an acrylic resin plate (refractive index 1.49) to a thickness of 2 mm to grinding, a triangular convex portion (a cross-sectional shape as shown in FIG. The uneven | corrugated shaped part (2) in which many protruding item | line parts (8) which consist of 7) protruded was formed. The apex angle (α) of this triangular convex part (7) is 90 degrees, the height (H) of the triangular convex part (7) is 150 μm, and the pitch interval (P) between adjacent triangular convex parts (7) is 300 μm. there were. The grinding process was performed with an alloy cutting tool (having a taper angle of 20 degrees) using a grinder manufactured by Technotech (FM1280 type).

次に、前記樹脂板(1)における凹凸形状部(2)が形成された表面に、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)5.0質量部溶解せしめてなる処理液を刷毛塗り法により塗布した後、20℃の室内で自然乾燥させることによって、図2に示すような光学部材(10)を作製した。   Next, a treatment liquid obtained by dissolving 5.0 parts by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform on the surface of the resin plate (1) on which the uneven part (2) is formed. 2 was applied by a brush coating method and then naturally dried in a room at 20 ° C. to produce an optical member (10) as shown in FIG.

<実施例5>
前記処理液として、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)4.0質量部溶解せしめてなる処理液を用いた以外は、実施例4と同様にして光学部材を作製した。
<Example 5>
An optical member was produced in the same manner as in Example 4 except that a treatment liquid obtained by dissolving 4.0 parts by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform was used as the treatment liquid. .

<実施例6>
前記処理液として、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)6.0質量部溶解せしめてなる処理液を用いた以外は、実施例4と同様にして光学部材を作製した。
<Example 6>
An optical member was produced in the same manner as in Example 4 except that a treatment liquid obtained by dissolving 6.0 parts by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform was used as the treatment liquid. .

<比較例4>
前記処理液として、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)1.0質量部溶解せしめてなる処理液を用いた以外は、実施例4と同様にして光学部材を作製した。
<Comparative Example 4>
An optical member was produced in the same manner as in Example 4 except that a treatment liquid obtained by dissolving 1.0 part by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform was used as the treatment liquid. .

<比較例5>
前記処理液として、クロロホルム100質量部に対してアクリル樹脂(屈折率1.49)10.0質量部溶解せしめてなる処理液を用いた以外は、実施例4と同様にして光学部材を作製した。
<Comparative Example 5>
An optical member was produced in the same manner as in Example 4 except that a treatment liquid obtained by dissolving 10.0 parts by mass of an acrylic resin (refractive index 1.49) with respect to 100 parts by mass of chloroform was used as the treatment liquid. .

<比較例6>
前記処理液として、クロロホルムからなる処理液を用いた以外は、実施例4と同様にして光学部材を作製した。
<Comparative Example 6>
An optical member was produced in the same manner as in Example 4 except that a treatment liquid composed of chloroform was used as the treatment liquid.

上記のようにして得られた各光学部材に対して下記評価法に基づいて評価を行った。これらの結果を表1に示す。   Each optical member obtained as described above was evaluated based on the following evaluation method. These results are shown in Table 1.

<加工面の観察による評価>
超深度顕微鏡(株式会社キーエンス製、超深度カラー3D形状測定顕微鏡 VK−9500型)を用いて、各光学部材(樹脂板)の表面(凹凸形状部形成面)及び断面を観察し、下記評価基準に基づいて評価を行った。
<Evaluation by observation of machined surface>
Using an ultra-deep microscope (manufactured by Keyence Corporation, ultra-deep color 3D shape measuring microscope VK-9500 type), the surface (uneven shape forming surface) and cross section of each optical member (resin plate) were observed, and the following evaluation criteria Based on the evaluation.

(凹凸形状部の溝部の形状の評価基準)
断面観察した結果、溝部の断面形状にシャープさがなくて丸みを帯びているものを「×」、溝部の断面形状が僅かに丸みを帯びているものを「△」、溝部の断面形状に丸みがなくシャープであるものを「○」とした。
(Evaluation criteria for the shape of the groove in the uneven part)
As a result of cross-sectional observation, the cross-sectional shape of the groove is not sharp and is rounded, “×”, the cross-sectional shape of the groove is slightly rounded, “△”, and the cross-sectional shape of the groove is rounded Those with no sharpness were marked with “◯”.

(凹凸形状部の頂部の形状の評価基準)
断面観察した結果、頂部の断面形状にシャープさがなくて丸みを帯びているものを「×」、頂部の断面形状が僅かに丸みを帯びているものを「△」、頂部の断面形状に丸みがなくシャープであるものを「○」とした。
(Evaluation criteria for the shape of the top of the uneven part)
As a result of cross-sectional observation, the cross-sectional shape of the top is not sharp and rounded, “X”, the cross-sectional shape of the top is slightly rounded, “△”, and the cross-sectional shape of the top is rounded Those with no sharpness were marked with “◯”.

(平滑度)
凹凸形状部の三角形凸部を構成する傾斜面(削り加工面2aに相当する面)が、削り加工後とあまり変わらず粗面であるものを「×」、ある程度平滑化されたものを「△」、十分に平滑化されたものを「○」とした。
(Smoothness)
“X” indicates that the inclined surface (surface corresponding to the machined surface 2a) constituting the triangular convex portion of the concavo-convex shape portion is not much different from that after the machining, and “△” indicates that the surface is smooth to some extent. “,” Which was sufficiently smoothed, was designated as “◯”.

表1から明らかなように、この発明の製造方法で製造された実施例1〜6の樹脂板は、凹凸形状部の溝部及び頂部の形状がシャープである(削り加工により形成された凹凸形状を変形させることがない)と共に、凹凸形状部の構成面は十分に平滑であった(凹凸形状部の削り加工面が十分に平滑化されていた)。   As is apparent from Table 1, the resin plates of Examples 1 to 6 manufactured by the manufacturing method of the present invention have sharp grooves and tops of the concavo-convex shape portion (the concavo-convex shape formed by the shaving process). In addition, the constituent surface of the concavo-convex shape portion was sufficiently smooth (the shaved surface of the concavo-convex shape portion was sufficiently smoothed).

実施例1の樹脂板(光学部材)の超深度顕微鏡による表面(凹凸形状部形成面)観察画像を図4(b)(図4の右側半分)に示すと共に、削り加工を施した直後(即ち処理液の塗布前)の樹脂板の表面観察画像を図4(a)(図4の左側半分)に示した。この図4(a)(b)の対比から、削り加工を施した直後の樹脂板の表面には多数本の筋(縦方向の筋)が観察されていたのであるが、処理液の塗布・乾燥を経た後の樹脂板の表面には筋が実質的に観察されておらず平滑面が形成されていることがわかる。また、実施例1において、削り加工を施した直後(即ち処理液の塗布前)の樹脂板は透明さが十分ではなかったが、処理液の塗布・乾燥を経た後の樹脂板は十分に透明な外観を有していた。   The surface (uneven shape forming surface) observation image of the resin plate (optical member) of Example 1 with an ultra-deep microscope is shown in FIG. 4B (right half of FIG. 4) and immediately after shaving (ie The surface observation image of the resin plate before application of the treatment liquid is shown in FIG. 4A (left half of FIG. 4). From the comparison of FIGS. 4 (a) and 4 (b), many streaks (longitudinal streaks) were observed on the surface of the resin plate immediately after the shaving process. It can be seen that no streaks are substantially observed on the surface of the resin plate after drying and a smooth surface is formed. In Example 1, the resin plate immediately after shaving (that is, before application of the treatment liquid) was not sufficiently transparent, but the resin plate after application and drying of the treatment liquid was sufficiently transparent. Had a good appearance.

また、自動変角光度計(村上色彩技術研究所製、GP−230型)を用いて、実施例1の樹脂板(光学部材)の表面(凹凸形状部形成面)に所定角度で光を入射させた場合に透過光の強度の角度分布がどのようになるかを測定した結果を図5(b)に示す。なお、図5(a)は、削り加工を施した直後(即ち処理液の塗布前)の樹脂板について同様にして透過光強度の角度分布を調べて得られたグラフである。なお、光束絞りを1.7mmφとし、測定時における出射光の強度と受光の感度は一定の状態で、光の入射角度(IA)を0°として、測定した。   In addition, using an automatic goniophotometer (Murakami Color Research Laboratory, GP-230 type), light is incident on the surface of the resin plate (optical member) of Example 1 (uneven shape forming surface) at a predetermined angle. FIG. 5 (b) shows the result of measuring how the angular distribution of the intensity of transmitted light becomes when this is done. FIG. 5A is a graph obtained by examining the angular distribution of transmitted light intensity in the same manner for a resin plate immediately after shaving (that is, before application of the treatment liquid). The measurement was performed with the light beam stop being 1.7 mmφ, the intensity of the emitted light and the sensitivity of the received light being constant, and the light incident angle (IA) being 0 °.

これら図5(a)(b)の対比から、この発明の製造方法で製造された樹脂板(光学部材)では、凹凸形状部の形状角度に依存した特定の出射角度で高い強度で光を透過させることができることがわかる。このようにこの発明の製造方法を適用すれば、樹脂板の透過光強度を向上させることができ、ひいては光学部材としての輝度を十分に向上させることができる。   5 (a) and 5 (b), the resin plate (optical member) manufactured by the manufacturing method of the present invention transmits light with high intensity at a specific emission angle depending on the shape angle of the concavo-convex shape portion. You can see that As described above, when the manufacturing method of the present invention is applied, the transmitted light intensity of the resin plate can be improved, and as a result, the luminance as the optical member can be sufficiently improved.

この発明の製造方法で製造された樹脂板(10)は、削り加工面(2a)が十分に平滑化されており、これにより精度の高い形状制御がなされた凹凸形状部(例えばプリズム部等)(2)が形成されるので、例えばプリズムシート、光拡散板等の光学部材として好適に用いられるが、特にこのような用途に限定されるものではない。中でも、液晶表示装置等の画像表示装置用の光学部材として特に好適である。   The resin plate (10) manufactured by the manufacturing method of the present invention has a machined surface (2a) that is sufficiently smoothed, and thereby has a concavo-convex shape portion (for example, a prism portion or the like) that has been subjected to highly accurate shape control. Since (2) is formed, it is preferably used as an optical member such as a prism sheet or a light diffusion plate, but is not particularly limited to such an application. Among them, it is particularly suitable as an optical member for an image display device such as a liquid crystal display device.

(a)は表面に削り加工を施した直後の樹脂板を示す模式的断面図であり、(b)はさらに処理液の塗布、乾燥を経て得られた樹脂板を示す模式的断面図である。(A) is typical sectional drawing which shows the resin board immediately after giving the surface processing, (b) is typical sectional drawing which shows the resin board obtained through application | coating and drying of a process liquid further. . この発明の製造方法で得られた樹脂板の一実施形態を示す模式的斜視図である。It is a typical perspective view which shows one Embodiment of the resin board obtained with the manufacturing method of this invention. ドリップコーティング法の説明図である。It is explanatory drawing of the drip coating method. 超深度顕微鏡による樹脂板の表面(凹凸形状部形成面)観察画像であり、(a)は削り加工を施した直後の樹脂板の表面観察画像、(b)は実施例1で得られた樹脂板(処理液の塗布・乾燥処理後)の表面観察画像である。It is the surface (uneven | corrugated shape part formation surface) observation image of the resin board by an ultra-deep microscope, (a) is the surface observation image of the resin board just after shaving, (b) is resin obtained in Example 1 It is a surface observation image of a board (after application | coating and drying process of a process liquid). 透過光強度の角度分布を示すグラフであり、(a)は削り加工を施した直後の樹脂板、(b)は実施例1で得られた樹脂板(処理液の塗布・乾燥処理後)のグラフである。It is a graph which shows angle distribution of transmitted light intensity, (a) is the resin board immediately after giving a shaving process, (b) is the resin board (after application | coating and drying process of a process liquid) obtained in Example 1. FIG. It is a graph.

符号の説明Explanation of symbols

1…削り加工が施された樹脂板
2…凹凸形状部
2a…削り加工面
7…三角形凸部
8…凸条部
10…処理液の塗布により平滑化処理された樹脂板
DESCRIPTION OF SYMBOLS 1 ... Resin board in which shaving process was given 2 ... Uneven shape part 2a ... Sharpening surface 7 ... Triangular convex part 8 ... Convex line part 10 ... Resin board smoothened by application | coating of a process liquid

Claims (6)

樹脂板の表面に削り加工を施すことによって前記樹脂板の表面に凹凸形状部を形成する削り工程と、
前記樹脂板における前記凹凸形状部が形成された表面に、溶媒100質量部に対して樹脂を0.5〜3質量部含有してなる処理液をドリップコーティング法により塗布した後、乾燥させる工程と、
を包含することを特徴とする表面に凹凸形状部を有する樹脂板の製造方法。
A shaving step of forming an uneven shape portion on the surface of the resin plate by shaving the surface of the resin plate;
A step of applying a treatment liquid containing 0.5 to 3 parts by mass of a resin to 100 parts by mass of the solvent on the surface of the resin plate on which the concavo-convex shape part is formed, and then drying the solution. ,
The manufacturing method of the resin board which has an uneven | corrugated shaped part on the surface characterized by including.
樹脂板の表面に削り加工を施すことによって前記樹脂板の表面に凹凸形状部を形成する削り工程と、
前記樹脂板における前記凹凸形状部が形成された表面に、溶媒100質量部に対して樹脂を3〜7質量部含有してなる処理液を刷毛塗り法により塗布した後、乾燥させる工程と、
を包含することを特徴とする表面に凹凸形状部を有する樹脂板の製造方法。
A shaving step of forming an uneven shape portion on the surface of the resin plate by shaving the surface of the resin plate;
Applying a treatment liquid containing 3 to 7 parts by mass of a resin to 100 parts by mass of the solvent on the surface of the resin plate on which the concavo-convex shape part is formed, followed by drying,
The manufacturing method of the resin board which has an uneven | corrugated shaped part on the surface characterized by including.
前記削り加工が、切削加工または研削加工である請求項1または2に記載の表面に凹凸形状部を有する樹脂板の製造方法。   The method for producing a resin plate having a concavo-convex shape portion on the surface according to claim 1, wherein the shaving process is a cutting process or a grinding process. 前記凹凸形状部は、断面形状が三角形である三角形凸部を多数個備えてなる請求項1〜3のいずれか1項に記載の表面に凹凸形状部を有する樹脂板の製造方法。   The method for producing a resin plate having a concavo-convex shape portion on the surface according to any one of claims 1 to 3, wherein the concavo-convex shape portion includes a large number of triangular convex portions having a triangular cross-sectional shape. 前記処理液を構成する樹脂として、前記樹脂板の屈折率との屈折率差の絶対値が0.05以下である樹脂を用いる請求項1〜4のいずれか1項に記載の表面に凹凸形状部を有する樹脂板の製造方法。   As a resin constituting the treatment liquid, a resin having an absolute value of a difference in refractive index from the refractive index of the resin plate of 0.05 or less is used. Of manufacturing a resin plate having a portion. 前記削り工程において、前記樹脂板の表面に凹凸高さが1.0〜800μmの凹凸形状部を形成する請求項1〜5のいずれか1項に記載の表面に凹凸形状部を有する樹脂板の製造方法。   In the said cutting process, the uneven | corrugated shaped part with an uneven | corrugated height of 1.0-800 micrometers is formed in the surface of the said resin board of the resin plate which has an uneven | corrugated shaped part on the surface of any one of Claims 1-5. Production method.
JP2006327197A 2006-12-04 2006-12-04 Method for producing resin plate having uneven portion on surface Expired - Fee Related JP4933235B2 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010204518A (en) * 2009-03-05 2010-09-16 Toppan Printing Co Ltd Optical sheet arranged with unit lens having a plurality of inflection points
JP2010237398A (en) * 2009-03-31 2010-10-21 Kimoto & Co Ltd Prism sheet and backlight using the same
CN102401913A (en) * 2010-09-10 2012-04-04 阿尔卑斯电气株式会社 Base plate with bumpy part and manufacturing method of the base plate

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JP2002022902A (en) * 2000-07-03 2002-01-23 Seiko Epson Corp Method for producing plastic lens
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JPS59123633A (en) * 1982-12-28 1984-07-17 Mitsubishi Rayon Co Ltd Manufacture of fresnel lens
JPH05200895A (en) * 1992-01-28 1993-08-10 Toshiba Silicone Co Ltd Scuff mark repairing method for plastic part
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JP2002071991A (en) * 2000-08-30 2002-03-12 Mitsubishi Chemicals Corp Method of manufacturing optical memory element and cutting device
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010204518A (en) * 2009-03-05 2010-09-16 Toppan Printing Co Ltd Optical sheet arranged with unit lens having a plurality of inflection points
JP2010237398A (en) * 2009-03-31 2010-10-21 Kimoto & Co Ltd Prism sheet and backlight using the same
CN102401913A (en) * 2010-09-10 2012-04-04 阿尔卑斯电气株式会社 Base plate with bumpy part and manufacturing method of the base plate

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