JP2008092927A - Method for producing ethanol - Google Patents

Method for producing ethanol Download PDF

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JP2008092927A
JP2008092927A JP2006300899A JP2006300899A JP2008092927A JP 2008092927 A JP2008092927 A JP 2008092927A JP 2006300899 A JP2006300899 A JP 2006300899A JP 2006300899 A JP2006300899 A JP 2006300899A JP 2008092927 A JP2008092927 A JP 2008092927A
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raw materials
waste
ethanol
fermentation
producing ethanol
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Hiroyuki Sudo
浩之 須藤
Masato Kitamura
正人 北村
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing ethanol by using raw materials containing starchy materials and the raw materials containing cellulose, selected from food waste materials conveyed to a waste material-treating facility selectively and in view of the effective utilization of resources, improving production efficiency by using each of suitable methods in the waste materia-treating facility adopting a conventional waste material recovering system and using the waste material-treating facility as it is. <P>SOLUTION: This method for producing ethanol is provided with that each of the suitable methods is used for performing the alcohol fermentation of the raw materials selected from the food residues conveyed into the waste material-treating facility selectively, a solid fermentation method containing a relatively small water content is used for the raw materials containing the starchy materials, and an alcohol conversion method with microorganisms is used for the raw materials containing the cellulose. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、廃棄物処理施設におけるエタノール生産方法に関し、動植物性残渣の生ゴミより高効率にエタノールを生産するエタノール製造システムに関するものである。The present invention relates to an ethanol production method in a waste treatment facility, and relates to an ethanol production system that produces ethanol more efficiently than garbage of animal and vegetable residues.

近年、建設及び製材工場などから排出される廃材、稲わら、麦わら、サトウキビ、とうもろこしや古紙等のバイオマス資源からエタノールを生産する方法が提案されている。
ところで、わが国における食品廃棄物の排出状況は、一般廃棄物が1600万トンで、その内訳は一般事業系が600万トン、家庭系から1000万トンで、事業系の食品製造業から排出される食品廃棄物は340万トンとなっている。総排出量は1940万トンで、そのうち91%が焼却処分され再資源化への転換は9%にとどまっている。
In recent years, a method for producing ethanol from biomass resources such as waste materials, rice straw, wheat straw, sugarcane, corn and waste paper discharged from construction and lumber mills has been proposed.
By the way, the state of discharge of food waste in Japan is 16 million tons of general waste, of which 6 million tons for general business and 10 million tons from household, and are discharged from the food manufacturing industry Food waste is 3.4 million tons. Total emissions are 19.4 million tons, of which 91% is incinerated and only 9% is converted to recycling.

現在、食品循環資源の再利用等の促進に関する法律(食品リサイクル法)が施工され、食品関連事業者は事業所内から排出される食品廃棄物の発生抑制、再生利用、減量化を行わなければならない。Currently, a law on the promotion of reuse of food recycling resources (Food Recycling Law) has been put in place, and food-related businesses must control, recycle, and reduce the amount of food waste discharged from the establishment. .

なかでも、資源を可能な限り再利用するための技術が望まれている。すでに食品廃棄物からエタノールを生産する方法は実用化にむけて実施されている。例えば、デンプン質を含む原料を用い、発酵により生産する方法に於いて、エタノール生産過程で廃液の生じることのないエタノールの製造方法およびエタノール製造システム、また、従来の食品廃棄物(セルロース系廃棄物)よりエタノールを生産する方法に於いては、セルロース系廃棄物に酵素液を作用させて糖を生成する糖化工程と、この糖化工程で生成した糖を含有する糖含有液を用いて発酵を行うことにより、アルコールを取得する方法が開示されている。
特開2002−159954 特開2005−65695
In particular, a technique for reusing resources as much as possible is desired. A method for producing ethanol from food waste has already been put into practical use. For example, in a method of producing by fermentation using raw materials containing starch, ethanol production method and ethanol production system that does not generate waste liquid during ethanol production process, and conventional food waste (cellulosic waste) ) In the method of producing ethanol, fermentation is performed using a saccharification step in which an enzyme solution is allowed to act on cellulosic waste to produce sugar, and a sugar-containing solution containing the sugar produced in this saccharification step. Thus, a method for obtaining alcohol is disclosed.
JP 2002-159954 A JP 2005-65695 A

しかしながら、上記特許文献2記載の方法では、食品残渣のデンプン質を含む原料のみを用いエタノールの製造をおこなうものであった。However, in the method described in Patent Document 2, ethanol is produced using only raw materials containing starch residue of food residues.

本発明は、上記のアルコール発酵法の持っている問題点を基に考え、既存の廃棄物回収システム及び廃棄物処理施設をそのまま用い、回収した食品残渣の生ゴミ中のデンプン質を含む原料を用い、アルコール発酵を固体発酵法により生成する方法と、回収した食品残渣の生ゴミ中のセルロースを含む原料を用い、微生物による糖からアルコールに変換する生成方法を有し、それぞれ適した方法でエタノールの生産効率の向上および大幅な増産を可能とするエタノール製造システムを提供することを目的とする。The present invention is based on the problems of the alcohol fermentation method described above, and uses the existing waste collection system and waste treatment facility as they are, and the raw material containing starch in the garbage of the collected food residue is used. Used to produce alcohol fermentation by solid-state fermentation, and a production method of converting sugar to alcohol by microorganisms using a raw material containing cellulose in the garbage of recovered food residue, and ethanol by a suitable method. An object of the present invention is to provide an ethanol production system that can improve the production efficiency and greatly increase production.

上記目的を達成するため、本発明の廃棄物処理施設におけるエタノール製造システムは、廃棄物処理施設に搬入される食品廃棄物の中から生ゴミを選択的に、デンプン質を含む原料とセルロースを含む原料に選別する。前記原料をそれぞれ違った生成方法を用い、可能な限り資源の再利用を行いエタノールの大幅な増産と利用の拡大を可能にしたことを特徴とする。In order to achieve the above object, the ethanol production system in the waste treatment facility of the present invention selectively includes raw garbage from the food waste carried into the waste treatment facility, and includes a raw material containing starch and cellulose. Sort into raw materials. It is characterized in that the raw materials are reused as much as possible by using different production methods for each of the raw materials, thereby making it possible to greatly increase ethanol production and use.

この場合において、生ゴミよりデンプン質を含む原料を用いペレットを形成し、前記ペレットに麹菌を接種して麹を得る。前記麹と酵母、最少量の水分から構成された発酵もろみを用い、発酵から終了まで固体状で発酵する。前記発酵方法で発酵終了後の発酵もろみを蒸留してエタノールを回収する。また、生ゴミ中のセルロースを含む原料を用い、糖化処理する方法は、セルラーゼ系又はアミラーゼ系の酵素剤を用いて糖化処理する方法と硫酸を用いて加熱及び加圧する方法で糖化処理を行う方法等があるが、これは特に限定するものではない。本発明では、セルロースが糖化処理後酵母菌を用いてアルコール発酵するのではなく、財団法人地球環境産業技術研究機構の開発した糖をアルコールに変換する微生物であるライト(Rite)菌によるアルコール変換工程を備えた、2とおりのエタノール製造システムを提供するものである。
前記ライト(Rite)菌により、従来のセルロース系バイオエタノール製造プロセスと比較してアルコール変換の効率が飛躍的に向上させることが可能になった。
In this case, pellets are formed using raw materials containing starch from raw garbage, and koji molds are inoculated into the pellets to obtain koji. Fermented moromi composed of the koji, yeast and a minimum amount of water is used to ferment in a solid state from fermentation to completion. The fermentation mash after completion of fermentation is distilled by the fermentation method to recover ethanol. Moreover, the method of saccharifying using the raw material containing the cellulose in raw garbage is the method of saccharifying by the method of saccharifying using a cellulase type or amylase type enzyme agent, and the method of heating and pressurizing using sulfuric acid. However, this is not particularly limited. In the present invention, cellulose is not subjected to alcohol fermentation using yeast after saccharification treatment, but an alcohol conversion step by Rite bacteria, which is a microorganism that converts sugars developed by the Global Environmental Industrial Technology Research Organization into alcohol. Two types of ethanol production systems provided with the above are provided.
The light bacteria can dramatically improve the efficiency of alcohol conversion as compared with the conventional cellulose-based bioethanol production process.

本発明の廃棄物処理施設におけるエタノール製造システムによれば、廃棄物処理施設に搬入される食品廃棄物より選択的にデンプン質とセルロースを含む原料に選別し、一方ではアルコール発酵を水分含水量の比較的少ない固体発酵法用い、もう一方は微生物であるライト(Rite)菌によるアルコール変換法を用い、蒸留を行い高効率にエタノールを生産する。これは、廃棄物の回収システム及び廃棄物処理施設として既存のものを使用できるので新たな回収システム及び運搬費用を必要とすることなく、エタノール製造に適した原料を効率的に確保することができる。According to the ethanol production system in the waste treatment facility of the present invention, the raw material containing starch and cellulose is selectively selected from the food waste carried into the waste treatment facility, while alcohol fermentation is performed with a moisture content of water. Relatively few solid fermentation methods are used, and the other uses an alcohol conversion method using a microorganism, Rite, to perform distillation and produce ethanol with high efficiency. This means that existing materials can be used as waste recovery systems and waste treatment facilities, so that it is possible to efficiently secure raw materials suitable for ethanol production without the need for new recovery systems and transportation costs. .

本発明では、アルコール発酵を固体発酵法で行うため蒸留後の固体形状の残渣fは、酵母や麹菌由来のたんぱく質を豊富に含むため家畜の飼料として利用できる。また、セルロース分解後の残渣物等bは自家用燃料として活用する。In the present invention, since the alcohol fermentation is carried out by the solid fermentation method, the solid residue f after distillation contains abundant proteins derived from yeast and koji mold, and therefore can be used as livestock feed. Moreover, the residue b etc. after decomposing cellulose are utilized as private fuel.

以下、本発明の廃棄物処理施設におけるエタノール製造システムの実施の形態を、図1に示すエタノール製造プロセスのフローシートに基づいて説明する。Hereinafter, an embodiment of an ethanol production system in a waste treatment facility of the present invention will be described based on a flow sheet of an ethanol production process shown in FIG.

廃棄物処理施設に搬入される動植物性残渣よりデンプン質を含む原料とセルロース質を含む原料とに選別し、既存のシステムを利用して生成処理する。例えば、デンプン質を含む原料については、アルコール発酵を固体発酵法で、セルロース質を含む原料は、酵素および硫酸等で糖化し、微生物を使いアルコール変換によりエタノールを製造する。尚、生ゴミ・原材料の収集システムとしては、既存の廃棄物収集運搬のシステムを使用して回収するため新たな廃棄物収集システムの創設は必要ない。The raw material containing starch and the raw material containing cellulosic material are selected from the animal and vegetable residues brought into the waste treatment facility, and generated and processed using an existing system. For example, for raw materials containing starch, alcohol fermentation is performed by solid fermentation, and for raw materials containing cellulose, saccharification is performed using enzymes, sulfuric acid, and the like, and ethanol is produced by alcohol conversion using microorganisms. In addition, as a garbage / raw material collection system, it is not necessary to create a new waste collection system since it is collected using an existing waste collection / transport system.

廃棄物処理施設に、ゴミ収集車等により搬入された動植物性残渣より生ゴミAを、水槽に投下し、浮沈式比重選別1によりデンプン質を含む原料Bと、セルロース質を含む原料Cに分類される。浮沈式比重選別は、水等の液体媒体中に投下された生ごみ等を分散させ、媒体より比重の小さな生ゴミは(セルロース等を含む食品残渣)と、それよりも比重の大きな生ゴミ(デンプン質等を含む食品残渣)とに簡易に分離できる方法である。Garbage A is dropped into the aquarium from animal and vegetable residues brought into a waste disposal facility by garbage trucks, etc., and is classified into raw material B containing starch and raw material C containing cellulosic material by floatation / densification specific gravity sorting 1 Is done. Flotation-type specific gravity sorting disperses garbage, etc., dropped in a liquid medium such as water. Raw garbage with a specific gravity smaller than that of the medium (food residues containing cellulose, etc.) and garbage with a higher specific gravity than that ( It is a method that can be easily separated into food residues containing starch and the like.

ここで、浮沈式比重選別をおこなう際に、目開きの小さなスクリーンを水槽底部に、水槽中央部には目開きの大きいスクリーンを配置する。前記スクリーンを上下動作により前記媒体よりも比重の小さな生ゴミを水槽の中央に配置したスクリーン上側に成層させ、下側のスクリーン上に前記媒体よりも比重の大きな生ゴミを成層選抜させる。そして、下側スクリーン上に成層した生ゴミより選択的にデンプン質を含む原料Bを選別し圧縮装置2で原料中の水分を除去する。Here, when performing the float / sink type specific gravity sorting, a screen with a small opening is arranged at the bottom of the water tank, and a screen with a large opening is arranged at the center of the water tank. By moving the screen up and down, garbage having a specific gravity smaller than that of the medium is stratified on the upper side of the screen disposed in the center of the water tank, and garbage having a specific gravity larger than that of the medium is stratified on the lower screen. Then, the raw material B containing starch is selectively selected from the raw garbage stratified on the lower screen, and moisture in the raw material is removed by the compression device 2.

圧縮装置2から供給された原料は、蒸気乾燥装置3に蒸気ボイラーにより高温・高圧の加熱蒸気を、吹き付け攪拌をおこない原料を乾燥する。The raw material supplied from the compressor 2 is sprayed and stirred with high-temperature and high-pressure heated steam by a steam boiler to the steam drying device 3 to dry the raw material.

乾燥した原料を、脱脂機aで脱脂後、造粒機4でペレット状(円柱状)に押し出す。その大きさは4mm粒大が望ましい。The dried raw material is degreased with a degreasing machine a and then extruded into a pellet (columnar) with a granulator 4. The size is desirably 4 mm.

自動製麹装置5を用いて、外気の環境に左右されず自動的に、造粒機4で製造されたデンプン質を含むペレットの品温と湿度を制御し麹を得る。Using the automatic kneading apparatus 5, the temperature and humidity of the pellets containing starch produced by the granulator 4 are automatically controlled without depending on the environment of the outside air to obtain koji.

固体発酵装置6では、前記麹に酵母を添加し発酵もろみを酸素が存在しない状態で嫌気発酵を行う。In the solid state fermentation apparatus 6, yeast is added to the koji and anaerobic fermentation is performed on the fermented mash in the absence of oxygen.

連続蒸留装置7は、発酵が発酵もろみからエタノールを連続的に蒸留し、エタノールを得るものである。連続蒸留装置7は、セルロース系食品残渣より取得したエタノールもこの装置で生成する。The continuous distillation apparatus 7 is one in which the fermentation continuously distills ethanol from the fermentation cake and obtains ethanol. The continuous distillation apparatus 7 also generates ethanol obtained from cellulosic food residues.

前記エタノールを、精留装置8で高品質、高濃度のアルコールに生成する。The ethanol is produced into a high-quality, high-concentration alcohol by the rectifying device 8.

一方、水槽中央部の目開きの大きいスクリーンに、前記スクリーンの上下動作により水等の液体媒体よりも比重の小さな生ゴミから、前記スクリーン上側に成層したセルロース質Cを含む生ゴミだけを選択的に選別する。破砕処理装置9により、後工程でおこなわれる糖化処理に適した大きさに破砕する。また、破砕処理をした生ゴミの含水率を95%〜80%に保ち、糖化処理を行うのが望ましい、糖化装置10で糖化処理を行う方法としては、希硫酸をもちいた加水分解、セルラーゼ系及びアミラーゼ系の酵素剤をもちいる方法があるが、これは特に限定するものではない。但し、2〜3年後には安価なセルラーゼ酵素が開発されて酸触媒が酵素法に代わると言われている。On the other hand, only the garbage containing cellulosic C stratified on the upper side of the screen is selectively selected from the garbage having a specific gravity smaller than that of the liquid medium such as water by the vertical movement of the screen. To sort. The crushing apparatus 9 crushes into a size suitable for the saccharification treatment performed in the subsequent process. In addition, it is desirable to perform saccharification treatment while keeping the moisture content of the crushed garbage at 95% to 80%. As a method of saccharification treatment with the saccharification apparatus 10, hydrolysis using dilute sulfuric acid, cellulase system In addition, there is a method using an amylase-based enzyme agent, but this is not particularly limited. However, it is said that an inexpensive cellulase enzyme will be developed in two to three years and the acid catalyst will replace the enzyme method.

糖化装置10で、原料中のセルロースがグルコースに糖化される。グルコースを含んだ糖化処理後の糖液は加熱処理と言った滅菌または滅菌処理がされるが、希硫酸を添加した後、加熱処理をおこなった場合は滅菌処理を要しない。In the saccharification apparatus 10, the cellulose in the raw material is saccharified into glucose. The sugar solution after saccharification treatment containing glucose is sterilized or sterilized as heat treatment, but does not require sterilization treatment when the heat treatment is performed after adding dilute sulfuric acid.

糖化処理をおこない回収された糖液は中和後、変換処理槽11で遺伝子組み換え菌、RITE菌により、アルコールニ変換する。遺伝子組み換え菌・ライト(Rite)菌は、財団法人地球環境産業技術研究機構により開発された。財団法人地球環境産業技術研究機構は、コリネ型細菌の特性を利用しさらに高効率な生産性与えるため、コリネ型細菌の遺伝子組み換えにより創製に成功した。ライト(Rite)菌は、従来のセルロース系エタノール製造プロセスと比較してアルコール変換の効率を飛躍的に向上させることが可能になった。財団法人地球環境産業技術研究機構では、新規組み換え微生物を用いることによりセルロース系の発酵工程に大幅な合理化ができる工業化基礎技術を確立している。
よって、発酵工程周辺機器の装置固定費が従来より掛からない。
After the saccharification treatment is performed and the collected sugar solution is neutralized, it is converted into alcohol in the conversion treatment tank 11 by genetically modified bacteria and RITE bacteria. The genetically modified bacterium Rite was developed by the Institute for Global Environmental Industrial Technology. The Institute for Global Environmental Technology has succeeded in creating genetically modified coryneform bacteria in order to provide more efficient productivity using the characteristics of coryneform bacteria. Rite bacteria can drastically improve the efficiency of alcohol conversion as compared with the conventional cellulose ethanol production process. The Institute for Global Environmental Industrial Technology has established a basic industrialization technology that can greatly streamline the cellulosic fermentation process using new recombinant microorganisms.
Therefore, the apparatus fixed cost of a fermentation process peripheral device does not start conventionally.

また、糖化処理装置10及び変換槽11内にておこなわれる各処理により発生する残渣bは、脱水工程c、乾燥処理工程dで含水率を調整後、自家用燃料として処理する。Moreover, the residue b generated by each process performed in the saccharification processing apparatus 10 and the conversion tank 11 is processed as a private fuel after adjusting the water content in the dehydration process c and the drying process process d.

以上、本発明の廃棄物処理施設におけるエタノール製造システムについて説明したが、原料の残渣成分を有効なエネルギーに転換することにより、資源全体を可能な限り有効利用し経済的で環境にやさしいプロセスを構築できる。また、上記に記載した構成に限定するものでなく、その趣旨を逸脱しない範囲に於いて、その構成を変更することができる。As described above, the ethanol production system in the waste treatment facility of the present invention has been described. By converting the residual components of the raw materials into effective energy, the entire resource is utilized as much as possible to construct an economical and environmentally friendly process. it can. The configuration is not limited to the above-described configuration, and the configuration can be changed without departing from the spirit of the configuration.

本発明の廃棄物処理施設における、エタノール製造プロセスのフローシートである。It is a flow sheet of the ethanol manufacturing process in the waste disposal facility of the present invention.

符号の説明Explanation of symbols

A 回収動植物残渣
B 食品残渣のデンプン質を含む原料
C 食品残渣のセルロース質を含む原料
1 浮沈式比重選別工程
2 圧縮装置
3 蒸気乾燥装置
a 脱脂機
4 造粒機
5 自動製麹機
6 固体発酵装置
f 残渣
7 連続蒸留装置
8 精留装置
h 廃液処理
9 破砕機
10 糖化装置
g 廃液処理
b 残渣
c 脱水装置
d 乾燥機
e 木質バイオマスボイラー
11 変換処理槽
A Recovered animal and plant residue B Raw material including starch residue of food residue C Raw material including cellulosic material of food residue 1 Flotation specific gravity selection process 2 Compression device 3 Steam drying device a Degreasing machine 4 Granulator 5 Automatic koji making machine 6 Solid fermentation Equipment f Residue 7 Continuous distillation equipment 8 Rectification equipment h Waste liquid treatment 9 Crusher 10 Saccharification equipment g Waste liquid treatment b Residue c Dehydration equipment d Dryer e Wood biomass boiler 11 Conversion treatment tank

Claims (2)

廃棄物処理施設に搬入される食品廃棄物の中から生ゴミを選択的に、デンプン質を含む原料とセルロースを含む原料に選別し、選別されたデンプン質を含む原料は、アルコール発酵を水分含水量の比較的少ない固体発酵法を用い、又、セルロースを含む原料は、微生物であるライト(Rite)菌によるアルコール変換法を用いそれぞれ適した方法で、高効率にエタノールを生産することを特徴とする廃棄物処理施設におけるエタノール製造方法。The food waste that is brought into the waste treatment facility is selectively sorted into raw materials containing starchy substances and raw materials containing cellulose, and the selected raw materials containing starchy substances contain alcoholic fermentation. It uses a solid fermentation method with a relatively small amount of water, and the raw material containing cellulose is characterized by producing ethanol with high efficiency by using an alcohol conversion method using a microorganism called Rite. A method for producing ethanol in a waste treatment facility. 原料の確保を、廃棄物の回収システム及び廃棄物処理施設として既存のものを使用できるので新たな回収システム及び運搬費を必要とすることなくエタノール製造に適した原料を効率的に確保できることを特徴とする請求項1記載の廃棄物処理施設におけるエタノール製造方法。Since it is possible to use existing materials as a waste recovery system and waste treatment facility, it is possible to efficiently secure raw materials suitable for ethanol production without the need for a new recovery system and transportation costs. The method for producing ethanol in a waste treatment facility according to claim 1.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011212592A (en) * 2010-03-31 2011-10-27 Hitachi Zosen Corp Method for preparing biomass feedstock originated from waste

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011212592A (en) * 2010-03-31 2011-10-27 Hitachi Zosen Corp Method for preparing biomass feedstock originated from waste

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