JP2008080496A - Method for producing embossed shape sheet and its production method - Google Patents

Method for producing embossed shape sheet and its production method Download PDF

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JP2008080496A
JP2008080496A JP2006259629A JP2006259629A JP2008080496A JP 2008080496 A JP2008080496 A JP 2008080496A JP 2006259629 A JP2006259629 A JP 2006259629A JP 2006259629 A JP2006259629 A JP 2006259629A JP 2008080496 A JP2008080496 A JP 2008080496A
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sheet
embossed
shape
die
cooling
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Takeshi Kanda
毅 神田
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Kuraray Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To continuously shape an embossed shape with the depth of the shape being relatively shallow in relation to the total thickness of a sheet in good shape accuracy at a high shaping rate on the surface of the sheet. <P>SOLUTION: When a thermoplastic resin melted/kneaded by an extruder 11 is discharged in a shape of a sheet through a T die 12, one surface of the sheet article 16 is cooled by a first cooling/molding roll 13, the other surface of the sheet article 16 is pressed/nipped by a second cooling/molding roll 14 with an embossment shape formed, and the embossed shape sheet 16 with the embossment shape of a shallow groove depth transferred/given is molded continuously. Wherein the sheet article 16 immediately after being discharged from the T die 12 is irradiated/heated by an external heater 18 set in the gap between the T die 12 and the second cooling/molding roll 14. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明はエンボス賦形シートの製造方法及びその製造装置に関し、特に、連続押出成形法による熱可塑性樹脂シートの片面若しくは両面に、エンボス形状を冷却成形ロールで連続的に転写賦形させるエンボス賦形シートの製造方法及びその製造装置に関するものである。   The present invention relates to a method for manufacturing an embossed shaped sheet and an apparatus for manufacturing the same, and in particular, embossed shaping in which an embossed shape is continuously transferred and shaped with a cooling molding roll on one or both sides of a thermoplastic resin sheet by a continuous extrusion method. The present invention relates to a sheet manufacturing method and a manufacturing apparatus thereof.

従来、此種エンボス賦形シートの製造方法(又は製造装置)を図7及び図8に従って説明する。同図において、エンボス賦形シートの製造装置は、熱可塑性樹脂を溶融混練する押出機11と、該溶融混練物をシート状に水平方向に吐出させるTダイ12と、該Tダイ12から吐出された溶融状態のシート状物16の表面を輻射熱で加熱する外部ヒーター18と、該加熱されたシート状物16を加圧ニップする第1の冷却成形ロール13と、エンボス形状を付与された第2の冷却成形(賦形)ロール14及び第3の冷却成形ロール15とを備えている。例えばアクリル樹脂、MS樹脂、或いはポリスチレン樹脂、PC樹脂、AS樹脂等の汎用の熱可塑性樹脂を溶融押出して、一対のエンボス賦形用冷却成形ロールで加圧ニップすることで連続的にエンボス賦形シートを得る場合、シートの総厚味Tが概ね0.6mm以上であって、かつ、エンボス形状の金型深さH’が相対的に浅いエンボス形状をシート表面に転写賦形させるときは、冷却成形ロールから離型後の型戻り現象が顕著となり、前記エンボス形状を高い賦形率(H/H’)でバラツキが無く、形状精度良く、連続的に転写賦形することに限界があった。   Conventionally, the manufacturing method (or manufacturing apparatus) of this kind of embossed shaped sheet will be described with reference to FIGS. In the figure, an embossed shaped sheet manufacturing apparatus includes an extruder 11 for melt-kneading a thermoplastic resin, a T-die 12 for discharging the melt-kneaded product in a sheet shape in a horizontal direction, and a discharge from the T-die 12. An external heater 18 that heats the surface of the melted sheet-like material 16 with radiant heat, a first cooling molding roll 13 that pressurizes the heated sheet-like material 16, and a second embossed shape. The cooling forming (shaping) roll 14 and the third cooling forming roll 15 are provided. For example, a general-purpose thermoplastic resin such as acrylic resin, MS resin, polystyrene resin, PC resin, AS resin, etc. is melt-extruded and continuously embossed by press nip with a pair of embossing cooling molding rolls. When obtaining a sheet, when the total thickness T of the sheet is approximately 0.6 mm or more and the embossed mold depth H ′ is relatively shallow, the embossed shape is transferred to the sheet surface. The mold return phenomenon after release from the cooling forming roll becomes remarkable, and there is a limit to the continuous embossing shape with high shaping rate (H / H '), no variation, high shape accuracy, and continuous transfer shaping. It was.

一方、前記シートの総厚味Tに対してエンボス形状の金型深さH’が前記同様に浅く、且つ、該シートの総厚味Tが0.1mm〜0.6mm以下のフィルム成形領域に近いときに、適切な冷却成形ロール径と押付圧、エアギャップ(Tダイ先端と冷却成形ロールとの距離)及び適切な吐出樹脂温度と冷却成形ロール温度等の組み合わせの最適化によって、エンボス形状の金型深さHが6μから60μ程度のエンボス形状を転写賦形させる場合、賦形形状のバラツキ範囲が1%以内、且つ、賦形率(H/H’)90%〜95%程度の達成は可能であった。   On the other hand, the embossed mold depth H ′ is shallow as described above with respect to the total thickness T of the sheet, and the total thickness T of the sheet is in a film forming region of 0.1 mm to 0.6 mm or less. The embossed shape is optimized by optimizing the combination of appropriate cooling forming roll diameter and pressing pressure, air gap (distance between T-die tip and cooling forming roll) and appropriate discharge resin temperature and cooling forming roll temperature. When an embossed shape with a mold depth H of about 6 to 60 μ is transferred and formed, the variation range of the formed shape is within 1% and the forming rate (H / H ′) is about 90% to 95%. Was possible.

しかしながら、前記シートの総厚味Tが0.6mm〜1.0mm程度のフィルム成形領域を超えると、急激に賦形率が70%から80%程度に低下すると同時に、前記賦形率の低下に伴って賦形高さHのバラツキが押出方向、押出幅方向ともに概ね比例的に増加する。このため、特に、光学用途向けのエンボス賦形シートの場合には、金型深さH’に成形設計形状に対して型戻りを加味し、より深くする必要があるために、金型製作の難易度が増すと同時に、得られたエンボス賦形シートの転写形状のバラツキが大きくなり、実用に耐えない性能品質となるという問題があった。   However, when the total thickness T of the sheet exceeds the film forming region of about 0.6 mm to 1.0 mm, the shaping rate is rapidly reduced from 70% to about 80%, and at the same time, the shaping rate is lowered. Along with this, the variation in the shaping height H increases approximately proportionally in both the extrusion direction and the extrusion width direction. For this reason, in particular, in the case of an embossed shaped sheet for optical applications, since it is necessary to add a mold return to the mold design shape to the mold depth H ′, it is necessary to make it deeper. At the same time as the difficulty level increased, there was a problem that variation in the transfer shape of the obtained embossed shaped sheet increased, resulting in performance quality that could not be put to practical use.

そこで、特開平17−289000号公報に開示されているように、(鏡面)ベルトでシート背面側をバックアップしつつ、冷却賦形(成形)ロールの加圧保持時間を長く取ることにより、賦形率の向上と賦形のバラツキを抑える製造装置が提案され、その一部は実用化されている。   Therefore, as disclosed in Japanese Patent Application Laid-Open No. 17-289000, shaping is performed by taking a long pressure holding time of the cooling shaping (molding) roll while backing up the back side of the sheet with a (mirror surface) belt. Manufacturing equipment that suppresses the improvement in rate and variation in shaping has been proposed, and some of them have been put into practical use.

又、特開平16−258188号公報に開示されているように、ダイ開口部から冷却ドラム(冷却成形ロール)までの距離を5〜100mmとすることで膜厚変化量が小さいフィルムの製造方法が提案されている。   In addition, as disclosed in JP-A-16-258188, a method for producing a film having a small film thickness change amount by setting the distance from the die opening to the cooling drum (cooling roll) to 5 to 100 mm. Proposed.

更に、特開2001−048995号公報に開示されているように、ダイ近傍において赤外線を照射するヒーターを設け、該ヒーターで溶融樹脂薄膜を加熱することにより、成形性を向上させる技術も提案されている。
特開平17−289000号公報。 特開平16−258188号公報。 特開2001−048995号公報。
Further, as disclosed in Japanese Patent Application Laid-Open No. 2001-049895, a technique for improving moldability by providing a heater that irradiates infrared rays in the vicinity of a die and heating the molten resin thin film with the heater has also been proposed. Yes.
JP-A-17-289000. Japanese Patent Laid-Open No. 16-258188. Japanese Patent Application Laid-Open No. 2001-049895.

しかしながら、上記特許文献1〜3記載の従来技術に於いては、ダイ開口部から冷却ドラムまでの距離が小さい場合はヒーターを設ける事が困難になる。特に、特許文献1記載の製造装置では構造自体が複雑となり、また、操業性に於いても困難さが増し、更には、装置の設備費用も高価になるという問題があった。   However, in the conventional techniques described in Patent Documents 1 to 3, it is difficult to provide a heater when the distance from the die opening to the cooling drum is small. In particular, the manufacturing apparatus described in Patent Document 1 has a problem in that the structure itself is complicated, the operability is increased, and the equipment cost of the apparatus is increased.

此種熱可塑性樹脂のエンボス賦形シート成形に於いては、シートの総厚味Tに対し、エンボス形状の深さが浅く、ピッチが微細になるにつれて、ロールから離型した後のエンボス形状の型戻り現象が大きくなる。この型戻り現象の発生理由は、次のように考えられる。即ち、冷却賦形ロールでニップされた溶融樹脂が一旦エンボス型の個々の形状溝に充満した後に冷却固化が芯部に向かって進むものの、冷却賦形ロールから離型した後に、シートの厚味中心からエンボス賦形側の表層に向かう熱移動が起こり、当該樹脂が再び軟化して次第に賦形形状が鈍るためと考えられる。   In this kind of thermoplastic resin embossing shaped sheet molding, the embossing shape after releasing from the roll as the embossing shape becomes shallower and the pitch becomes finer than the total thickness T of the sheet. The mold return phenomenon becomes large. The reason for the occurrence of this type return phenomenon is considered as follows. That is, although the melted resin niped by the cooling shaping roll once fills the embossed individual shape grooves, cooling solidification proceeds toward the core, but after releasing from the cooling shaping roll, the thickness of the sheet is increased. It is considered that heat transfer occurs from the center toward the surface layer on the embossing shaping side, the resin softens again, and the shaping shape gradually becomes dull.

他方、前記型戻り現象を解消すべく、予め型戻り現象を考慮した形で冷却成形ロール表面のエンボス形状の溝深さH’を深くする金型サイジング技術が一般的に用いられている。しかしながら、金型深さH’に対する成形シートの転写賦形率が概ね90%以下になると、サイジングした金型深さが深くなるにつれて、形状転写精度のバラツキが急激に増大する。このため、得られたエンボス賦形シートは、特に、光学用途向けの場合には実用に耐えないものとなる。   On the other hand, in order to eliminate the mold return phenomenon, a mold sizing technique is generally used in which the embossed groove depth H ′ on the surface of the cooling molding roll is deepened in advance in consideration of the mold return phenomenon. However, when the transfer forming rate of the molded sheet with respect to the mold depth H ′ is approximately 90% or less, the variation in shape transfer accuracy increases rapidly as the sized mold depth increases. For this reason, the embossed shaped sheet obtained is not practically usable particularly for optical applications.

そこで、本発明はシートの総厚味に対して目標とする形状高さが相対的に低くてピッチが微細なエンボス形状を、高い賦形率で、形状転写精度が良好で、且つ、連続的に賦形できるようにするために解決すべき技術的課題が生じてくるのであり、本発明はこの課題を解決することを目的とする。   Therefore, the present invention provides an embossed shape having a relatively low target shape height and a fine pitch with respect to the total thickness of the sheet, a high shaping rate, good shape transfer accuracy, and continuous. Therefore, a technical problem to be solved in order to be able to be shaped is generated, and the present invention aims to solve this problem.

本発明は上記目的を達成するために提案されたものであり、請求項1記載の発明は、熱可塑性樹脂を押出機に供給して溶融混練した後にTダイを通じてシート状に吐出押出し、一対の冷却成形ロールで加圧ニップして、該冷却成形ロール表面に施されたエンボス形状を連続的に転写賦形させるエンボス賦形シートの製造方法において、前記Tダイから吐出押出された直後のシート状物の外表面を、外部ヒーターにより空中で加熱させた後に、前記冷却成形ロールで加圧ニップして形状転写させるエンボス賦形シートの製造方法であって、前記外部ヒーターが赤外線ヒーターであり、該外部ヒーターの照射光を、前記Tダイのダイリップ先端の表面に設けた反射部材で反射させつつ前記シート状物の表面を空中で照射加熱させるエンボス賦形シートの製造方法を提供する。   The present invention has been proposed in order to achieve the above object, and the invention according to claim 1 is characterized in that a thermoplastic resin is supplied to an extruder, melt-kneaded, and then discharged and extruded into a sheet through a T die. In a method for producing an embossed shaped sheet that is press-niped with a cooling molding roll and continuously embosses the embossed shape applied to the surface of the cooling molding roll, the sheet shape immediately after being extruded and extruded from the T-die An outer surface of an object is heated in the air by an external heater, and then a method for producing an embossed shaped sheet in which the shape is transferred by press nip with the cooling molding roll, wherein the external heater is an infrared heater, Emboss shaping system that irradiates and heats the surface of the sheet-like material in the air while reflecting the irradiation light of the external heater by the reflecting member provided on the surface of the tip of the die lip of the T die. To provide a door method of manufacturing.

この製造方法によれば、前記外部ヒーターの照射光を、前記Tダイのダイリップ先端の表面に設けた反射部材で反射させつつ、前記シート状物の表面を空中で照射加熱させることにより、前記型戻り現象を最小限に抑えるべく、前記Tダイからのシート状物の吐出樹脂温度を適切に設定する。   According to this manufacturing method, the surface of the sheet-like object is irradiated and heated in the air while the irradiation light of the external heater is reflected by a reflecting member provided on the surface of the tip of the die lip of the T die. In order to minimize the return phenomenon, the discharge resin temperature of the sheet-like material from the T die is appropriately set.

即ち、前記型戻り現象を原理的に最小限に抑えるには、Tダイからの前記シート状物の吐出樹脂温度を、バンク成形が可能な当該熱可塑性樹脂のガラス転移点Tg以上とし、冷却賦形ロールで加圧ニップされる直前のシート表層部分をゴム遷移領域の温度に上げればよい。本発明は何れもこの原理に沿うものである。   That is, in order to minimize the mold return phenomenon in principle, the discharge resin temperature of the sheet-like material from the T die is set to be equal to or higher than the glass transition point Tg of the thermoplastic resin that can be bank-molded, and cooling is applied. What is necessary is just to raise the surface layer part of a sheet | seat just before a pressure nip with a shape roll to the temperature of a rubber transition area. All the present inventions are based on this principle.

本発明の製造方法において、Tダイから吐出された直後の樹脂温度は、一対の冷却成形ロールでバンク成形が可能なガラス転移点Tg以上の必要最小限な操作温度とし、エンボス形状を付与したい側のシート状物の表層部分を外部ヒーターで照射加熱してゴム遷移領域の温度に上げた上で、冷却成形ロールで加圧ニップする。斯くして、冷却成形ロール表面に施されたエンボス形状の溝への溶融樹脂の流入と充満性を上げ、且つ、離型後のシート中心層からの熱移動が抑制される。   In the production method of the present invention, the resin temperature immediately after being discharged from the T die is the minimum operating temperature above the glass transition point Tg that can be bank-formed with a pair of cooling forming rolls, and the embossed shape is to be imparted. The surface layer portion of the sheet-like product is irradiated and heated with an external heater to raise the temperature of the rubber transition region, and then subjected to a pressure nip with a cooling molding roll. Thus, the inflow and filling of the molten resin into the embossed groove formed on the surface of the cooling molding roll is increased, and the heat transfer from the sheet center layer after release is suppressed.

請求項2記載の発明は、上記外部ヒーターの照射光を、エンボス形状が付与された上記冷却成形ロール表面に照射させつつ、上記シート状物の表面を空中で照射加熱させる請求項1記載のエンボス賦形シートの製造方法を提供する。   The invention according to claim 2 is the embossing according to claim 1, wherein the surface of the sheet-like material is irradiated and heated in the air while irradiating the surface of the cooling molding roll having the embossed shape with the irradiation light of the external heater. A method for producing a shaped sheet is provided.

この製造方法によれば、前記外部ヒーターの照射光は、その一部がエンボス形状が付与された冷却成形ロール表面を直接加熱し、他の一部はシート状物の表層部分を直接照射する。特に、エンボス賦形の冷却成形ロール材質が銅メッキ製の場合には、冷却成形(賦形)ロールの表層部分の温度が上昇して、前記シート状物が個々の微細なエンボス形状溝に一層入り易くなる。   According to this manufacturing method, the irradiation light of the external heater directly heats the surface of the cooling forming roll provided with an embossed shape, and the other part directly irradiates the surface layer portion of the sheet-like material. In particular, when the embossed cooling forming roll material is made of copper plating, the temperature of the surface layer portion of the cooling forming (shaped) roll rises, and the sheet-like material is further layered in each fine embossed groove. Easy to enter.

請求項3記載の発明は、上記形状転写させるエンボス形状の最大深さをHと、シートの総厚味をTとしたとき、
0.6mm ≦ T ≦ 3.0mm
0.05 ≦ H/T ≦ 0.25
の範囲にある請求項1又は2記載のエンボス賦形シートの製造方法を提供する。
In the invention of claim 3, when the maximum depth of the embossed shape to be transferred is H and the total thickness of the sheet is T,
0.6mm ≤ T ≤ 3.0mm
0.05 ≤ H / T ≤ 0.25
The manufacturing method of the embossing shaped sheet | seat of Claim 1 or 2 in the range of this is provided.

この製造方法によれば、エンボス形状の最大深さHと、シートの総厚味Tとの関係が上記の範囲である場合、エンボス形状が微細であっても、溶融状態のシート状物がエンボス形状の溝に円滑に入り、従来に比べて充満性を高めて型戻り現象の発生を抑制する。   According to this manufacturing method, when the relationship between the maximum depth H of the embossed shape and the total thickness T of the sheet is in the above range, even if the embossed shape is fine, the molten sheet-like material is embossed. Smoothly enters the groove of the shape, enhances the fillability compared to conventional, and suppresses the occurrence of the mold return phenomenon.

請求項4記載の発明は、熱可塑性樹脂を押出機に供給して溶融混練した後にTダイを通じてシート状に吐出押出し、一対の冷却成形ロールで加圧ニップして、該冷却成形ロール表面に施されたエンボス形状を連続的に転写賦形させる請求項1,2又は3記載のエンボス賦形シートの製造方法に用いられるエンボス賦形シートの製造装置であって、前記Tダイから吐出された直後のシート状物の表面を照射加熱させる外部ヒーターと、前記Tダイのダイリップ先端の表面に設けられた反射部材とを備え、前記外部ヒーターが赤外線ヒーターであり、該外部ヒーターの照射光を前記反射部材で反射させつつ、前記シート状物の表面を空中で照射加熱するように構成して成るエンボス賦形シートの製造装置を提供する。   In the invention of claim 4, the thermoplastic resin is supplied to an extruder, melted and kneaded, and then discharged and extruded into a sheet shape through a T-die, followed by pressure nip with a pair of cooling molding rolls, and applied to the surface of the cooling molding roll. The embossed shaped sheet manufacturing apparatus used in the method for manufacturing an embossed shaped sheet according to claim 1, 2 or 3, wherein the embossed shape formed is continuously transferred and shaped immediately after being discharged from the T die. An external heater for irradiating and heating the surface of the sheet-like material, and a reflecting member provided on the surface of the tip of the die lip of the T-die, the external heater being an infrared heater, and irradiating the irradiation light of the external heater with the reflection Provided is an embossed shaped sheet manufacturing apparatus configured to irradiate and heat the surface of the sheet-like material in the air while being reflected by a member.

この構成によれば、前記外部ヒーターの照射光を前記反射部材で反射させつつ前記シート状物の表面を空中で照射加熱させることにより、Tダイから吐出された直後の樹脂温度は、一対の冷却成形ロールでバンク成形が可能なTg以上の必要最小限の操作温度に設定される。又、エンボス形状を付与したい側のシート状物の表層部分は、外部ヒーターで照射加熱してゴム遷移領域の温度に上げられる。そして、シート状物を冷却成形ロールで加圧ニップすることで、エンボス形状の溝への樹脂の流入と充満性を上げ、且つ、離型後のシート中心層からの熱移動が抑制される。要するに、本発明は、熱可塑性樹脂用の汎用的なシート成形装置を用い、Tダイとエンボス形状が付与された冷却成形ロールとの間隙に外部ヒーターを追加付与することによって、Tダイから吐出された直後のシート状物の表層部又はエンボス賦形用の冷却成形ロール表面、或いは、両者を同時に輻射熱で加熱しつつエンボス賦形する。   According to this configuration, the resin temperature immediately after being discharged from the T-die is a pair of cooling by irradiating and heating the surface of the sheet-like material in the air while reflecting the irradiation light of the external heater by the reflecting member. It is set to the minimum required operating temperature of Tg or higher that allows bank forming with the forming roll. Further, the surface layer portion of the sheet-like material on the side to be embossed is irradiated and heated by an external heater and raised to the temperature of the rubber transition region. Then, by pressurizing the sheet-like material with a cooling molding roll, the inflow and fullness of the resin into the embossed groove are increased, and the heat transfer from the sheet center layer after release is suppressed. In short, the present invention uses a general-purpose sheet forming apparatus for thermoplastic resin and is discharged from the T die by additionally applying an external heater to the gap between the T die and the cooling forming roll having the embossed shape. Embossing is performed while heating the surface layer portion of the sheet-like material immediately afterwards or the surface of the cooling forming roll for embossing shaping, or both simultaneously with radiant heat.

請求項1記載の発明は、エンボス形状溝への溶融樹脂の流入と充満性を上げ、且つ、離型後のシート中心層からの熱移動を抑制できるので、シートの総厚味Tに対して目標とする形状高さHが相対的に低くてピッチが微細なエンボス形状を高い賦形率で、且つ、形状転写精度良く、連続的に賦形することができる。   Since the invention according to claim 1 can increase the inflow and fillability of the molten resin into the embossed groove and suppress the heat transfer from the sheet center layer after release, the total thickness T of the sheet can be reduced. An embossed shape having a relatively low target shape height H and a fine pitch can be continuously formed at a high forming rate and with high shape transfer accuracy.

請求項2記載の発明は、冷却賦形ロールの表層部分の温度が上昇して、前記シート状物が個々の微細なエンボス形状溝に入り易くなるので、請求項1記載の発明の効果に加えて、シートの総厚味Tに対して相対的に形状高さHが低いエンボス形状を付与した熱可塑性樹脂シートを、一層高い形状転写精度で連続的に製造することができる。   In the invention described in claim 2, since the temperature of the surface layer portion of the cooling shaping roll rises and the sheet-like material easily enters each fine embossed groove, in addition to the effect of the invention described in claim 1 Thus, a thermoplastic resin sheet provided with an embossed shape having a relatively low shape height H with respect to the total thickness T of the sheet can be continuously produced with higher shape transfer accuracy.

請求項3記載の発明は、微細なエンボス形状溝への溶融状態のシート状物の充満性を挙げて、型戻り現象を良好に抑制できるので、請求項1又は2記載の発明の効果に加えて、形状転写精度のバラツキの少ない高品質のエンボス賦形シートが容易に得られ、特に、得られたエンボス賦形シートは光学用途向けに好適に使用することができる。   Since the invention described in claim 3 can satisfactorily suppress the mold return phenomenon by mentioning the fullness of the molten sheet-like material into the fine embossed groove, in addition to the effect of the invention described in claim 1 or 2 Thus, a high-quality embossed shaped sheet with little variation in shape transfer accuracy can be easily obtained. In particular, the obtained embossed shaped sheet can be suitably used for optical applications.

請求項4記載の発明は、個々の微細なエンボス形状溝への溶融樹脂の流入と充満性を上げ、且つ、離型後のシート中心層からの熱移動を抑制できるので、シートの総厚味Tに対して形状高さHが相対的に低くてピッチが微細なエンボス形状を高い賦形率で、且つ、形状転写精度良く、連続的に賦形することができる。また、操業性が向上し、装置の設備費用も安価になる。   The invention according to claim 4 can increase the inflow and filling of the molten resin into each fine embossed groove, and can suppress the heat transfer from the sheet center layer after release, so that the total thickness of the sheet An embossed shape having a relatively low shape height H with respect to T and a fine pitch can be continuously shaped with a high shaping rate and with a good shape transfer accuracy. In addition, the operability is improved and the equipment cost of the apparatus is reduced.

本発明は、シートの総厚味Tに対して目標とする形状高さHが相対的に低くてピッチが微細なエンボス形状を、高い賦形率で、形状転写精度良く、連続的に賦形可能にするという目的を、熱可塑性樹脂を押出機に供給して溶融混練した後にTダイを通じてシート状に吐出押出し、一対の冷却成形ロールで加圧ニップして、該冷却成形ロール表面に施されたエンボス形状を連続的に転写賦形させるエンボス賦形シートの製造方法において、前記Tダイから吐出された直後のシート状物の表面を、外部ヒーターにより空中で加熱させた後に、前記冷却成形ロールで加圧ニップして形状転写させるエンボス賦形シートの製造方法であって、前記外部ヒーターが赤外線ヒーターであり、該外部ヒーターの照射光を、前記Tダイのダイリップ先端の表面に設けた反射部材で反射させつつ、前記シート状物の表面を空中で照射加熱させる方法または装置を採択したことにより実現した。   The present invention continuously forms an embossed shape having a relatively low target shape height H and a fine pitch with respect to the total thickness T of the sheet with a high forming rate and shape transfer accuracy. The purpose of making it possible is to supply the thermoplastic resin to an extruder, melt and knead, then discharge and extrude it into a sheet through a T-die, press nip with a pair of cooling molding rolls, and apply to the surface of the cooling molding roll In the method for producing an embossed shaped sheet in which the embossed shape is continuously transferred and shaped, the surface of the sheet-like material immediately after being discharged from the T die is heated in the air by an external heater, and then the cooling forming roll A method of manufacturing an embossed shaped sheet in which a shape is transferred by pressurization nip, wherein the external heater is an infrared heater, and the irradiation light of the external heater is used as a surface of the tip of the die lip of the T die. While reflected by the reflecting member provided, realized by a surface of the sheet was adopted a method or apparatus for irradiating heated in air.

〔実施形態〕
以下、本発明の好適な実施形態について説明する。本実施形態は、熱可塑性樹脂を押出機に供給して溶融混練した後に、Tダイを通じてシート状に吐出押出し、エンボス形状が付与された冷却成形ロールで加圧ニップして、該冷却成形ロール表面に施されたエンボス形状を連続的に転写賦形させるエンボス賦形シートの製造方法に適用したものである。
Embodiment
Hereinafter, preferred embodiments of the present invention will be described. In the present embodiment, a thermoplastic resin is supplied to an extruder and melt-kneaded, and then discharged and extruded into a sheet shape through a T-die, followed by pressure nip with a cooling molding roll having an embossed shape, and the surface of the cooling molding roll. This is applied to a method for producing an embossed shaped sheet in which the embossed shape applied to is continuously transferred and shaped.

Tダイから吐出押出した直後のシート状物の外表面は、外部ヒーターにより空中で加熱された後、一対の冷却成形ロールで加圧ニップして形状転写が行われる。この形状転写時に、シート状物は外部ヒーターの照射光により加熱されるが、この場合、照射光は、Tダイのダイリップ先端の表面に設けた反射部材で反射して、シート状物の表面を空中で照射加熱する。   The outer surface of the sheet-like material immediately after being discharged and extruded from the T-die is heated in the air by an external heater, and then subjected to a pressure nip with a pair of cooling forming rolls for shape transfer. During this shape transfer, the sheet-like object is heated by the irradiation light of the external heater. In this case, the irradiation light is reflected by the reflecting member provided on the surface of the tip of the die lip of the T die, and the surface of the sheet-like object is reflected. Irradiation heating in the air.

本発明の実施形態に係る製造装置(縦型の押出成形装置)は、図1に示すように、熱可塑性樹脂を溶融混練する押出機11と、該溶融混練物をシート状に水平方向に吐出させるTダイ12と、該Tダイ12から吐出された溶融状態のシート状物16の表面を輻射熱で加熱する外部ヒーター18と、該加熱されたシート状物16を加圧ニップする第1の冷却成形ロール13と、エンボス形状を付与された第2の冷却成形(賦形)ロール14及び第3の冷却成形ロール15とを備えている。   As shown in FIG. 1, a manufacturing apparatus (vertical extrusion molding apparatus) according to an embodiment of the present invention includes an extruder 11 that melt-kneads a thermoplastic resin, and discharges the melt-kneaded material in a sheet shape in a horizontal direction. A T die 12 to be discharged, an external heater 18 that heats the surface of the molten sheet-like material 16 discharged from the T-die 12 with radiant heat, and a first cooling that nips the heated sheet-like material 16 under pressure. A molding roll 13, a second cooling molding (shaping) roll 14 and a third cooling molding roll 15 provided with an emboss shape are provided.

これら3つの冷却成形ロール13,14,15はこの順に上方向に並んで配置され、隣接する冷却成形ロール13,14,15同士は互いに反対方向に回転するように構成されている。   These three cooling forming rolls 13, 14, and 15 are arranged in this order in the upward direction, and the adjacent cooling forming rolls 13, 14, and 15 are configured to rotate in directions opposite to each other.

図2に示すように、前記外部ヒーター18は、Tダイ12と第2の冷却成形ロール14の間に設置されている。この外部ヒーター18は、遠赤外線ヒーター、中赤外線ヒーター、近赤外線ヒーターの何れの輻射熱ヒーターであっても良いが、Tダイ12から吐出された熱可塑性樹脂製のシート状物16の表層近傍を瞬時に局部的に昇温させるためには、当該熱可塑性樹脂の吸収波長の関係から、近赤外線ヒーターもしくは中赤外線ヒーターが望ましい。尚、図2中の17はバンクを示す。   As shown in FIG. 2, the external heater 18 is installed between the T die 12 and the second cooling forming roll 14. The external heater 18 may be a radiant heat heater such as a far-infrared heater, a mid-infrared heater, or a near-infrared heater, but instantaneously near the surface layer of the thermoplastic resin sheet 16 discharged from the T-die 12. In order to raise the temperature locally, a near-infrared heater or a mid-infrared heater is desirable from the relationship of the absorption wavelength of the thermoplastic resin. Note that reference numeral 17 in FIG. 2 denotes a bank.

又、図3に示すように、Tダイ12のダイリップ先端の上側表面には反射部材19が設けられている。従って、前記外部ヒーター18の照射光を反射部材19で反射させつつ、シート状物16の上側の外表面を空中で照射加熱させることができる。   As shown in FIG. 3, a reflecting member 19 is provided on the upper surface of the tip of the die lip of the T die 12. Accordingly, the outer surface on the upper side of the sheet-like material 16 can be irradiated and heated in the air while the irradiation light of the external heater 18 is reflected by the reflecting member 19.

この製造装置を使用してエンボス賦形シートを製造する際は、先ず、押出機11で熱可塑性樹脂を溶融混練し、この溶融混練物をTダイ12を通じてシート状に吐出させる。この場合、吐出ムラを防ぐために、押出機11の吐出部にギヤポンプ(図示せず)を設けてもよい。   When producing an embossed shaped sheet using this production apparatus, first, a thermoplastic resin is melt-kneaded by the extruder 11, and this melt-kneaded material is discharged into a sheet through the T-die 12. In this case, in order to prevent discharge unevenness, a gear pump (not shown) may be provided in the discharge portion of the extruder 11.

次に、Tダイ12から吐出された溶融状態のシート状物16は、外部ヒーター18により照射加熱される。該照射加熱の直後に、第1の冷却成形ロール13と第2の冷却成形ロール14とによりシート状物16を加圧ニップし、エンボス形状が形成された第2の冷却成形ロール14にシート状物16を巻き付けた状態で、該シート状物16の冷却固化を進行させる。この後、第3の冷却成形ロール15により、シート状物16におけるエンボス賦形面と反対側のシート面を冷却する。   Next, the molten sheet-like material 16 discharged from the T die 12 is irradiated and heated by an external heater 18. Immediately after the irradiation heating, the sheet-like material 16 is pressure-niped by the first cooling forming roll 13 and the second cooling forming roll 14, and the second cooling forming roll 14 having the embossed shape is formed into a sheet shape. In a state where the object 16 is wound, the sheet-like object 16 is cooled and solidified. Thereafter, the third cooling molding roll 15 cools the sheet surface on the opposite side of the embossed surface of the sheet-like material 16.

本発明は、上記した縦型の製造装置に限らず、他のタイプの製造装置を採用できる。図4乃至図6は、本発明の他の実施形態に係る製造装置を示す。この製造装置は、図4に示すように、溶融混練物をシート状に下方向に吐出させるTダイ12と、該シート状物16を加圧ニップする第1の冷却成形ロール20と、エンボス形状を付与された第2の冷却成形ロール21、及び第3,4の冷却成形ロール22,23とを備えている。   The present invention is not limited to the vertical manufacturing apparatus described above, and other types of manufacturing apparatuses can be employed. 4 to 6 show a manufacturing apparatus according to another embodiment of the present invention. As shown in FIG. 4, the manufacturing apparatus includes a T-die 12 that discharges the melt-kneaded material downward in a sheet shape, a first cooling molding roll 20 that press-nips the sheet-like material 16, and an embossed shape. Are provided with a second cooling forming roll 21, and third and fourth cooling forming rolls 22 and 23.

これら4つの冷却成形ロール20〜23はこの順に横方向に並んで配置され、且つ、Tダイ12と第1の冷却成形20の間には外部ヒータ26が配設されている。更に、図5に示すように、Tダイのダイリップ先端の一側表面には反射部材27が配設されている。従って、前記外部ヒーター26の照射光を反射部材27で反射させつつ、シート状物16の両側の表面を空中で照射加熱させることができる。   These four cooling forming rolls 20 to 23 are arranged side by side in this order, and an external heater 26 is disposed between the T die 12 and the first cooling forming 20. Further, as shown in FIG. 5, a reflecting member 27 is disposed on one side surface of the tip of the die lip of the T die. Accordingly, it is possible to irradiate and heat the surfaces on both sides of the sheet-like material 16 in the air while reflecting the irradiation light of the external heater 26 by the reflecting member 27.

本発明に係る外部ヒーター26と反射部材27の配置方式は、目的や設計条件に対応して自由に構成できる。例えば、図5に示したように、Tダイ12と冷却成形ロール14等の位置関係に応じて、反射部材27の位置、大きさは適宜変更する事ができる。この反射部材27は、金属反射板など、公知の反射部材を使用する事ができる。   The arrangement method of the external heater 26 and the reflecting member 27 according to the present invention can be freely configured according to the purpose and design conditions. For example, as shown in FIG. 5, the position and size of the reflecting member 27 can be changed as appropriate according to the positional relationship between the T die 12 and the cooling forming roll 14. As the reflecting member 27, a known reflecting member such as a metal reflecting plate can be used.

更に、図6に示すように、Tダイ12の両側に外部ヒーター24,26と反射部材15,27を設ける事ができる。即ち、Tダイ12と第1の冷却成形((賦形))ロール28、第2の冷却成形ロール21の間に外部ヒーター24,26を夫々配設し、且つ、前記Tダイ12のダイリップ先端の一側、他側の表面に反射部材25,27を夫々設けることができる。この構成によれば、前記外部ヒーター24,26の照射光を反射部材25,27で反射させつつ、シート状物16の両側の表面を空中で照射加熱させることができる。   Furthermore, as shown in FIG. 6, external heaters 24 and 26 and reflecting members 15 and 27 can be provided on both sides of the T die 12. That is, external heaters 24 and 26 are disposed between the T die 12, the first cooling forming ((shaping)) roll 28, and the second cooling forming roll 21, respectively, and the die lip tip of the T die 12 is provided. Reflective members 25 and 27 can be provided on the surfaces of one side and the other side, respectively. According to this configuration, it is possible to irradiate and heat the surfaces on both sides of the sheet-like material 16 in the air while reflecting the irradiation light of the external heaters 24 and 26 by the reflecting members 25 and 27.

〔実施例1〜5〕
実施例1〜5は、前述した実施形態に於いて、図3の押出成形装置を使用してエンボス賦形シートを製造した。この場合の製造方法の具体的条件は、下記の通りとした。
押出原料樹脂…MS樹脂(p−MMA:PS=80:20)
押出機のスクリュ…φ150mm
押出機の吐出量…250Kg/h
Tダイの吐出幅…1450mm
Tダイの吐出樹脂温度…220℃〜240℃
Tダイのリップ開度…2mm〜6mm
Tダイと第1冷却の成形ロール、第2冷却の成形ロールとの距離(エアギャップ)…140mm
第1冷却の成形ロールの直径…φ400mm
第2冷却の成形ロールの直径…φ400mm
第2冷却の成形ロールのエンボス形状…ピッチ300μ、エンボス形状の溝深さH’152μの円柱状レンズ列第1冷却の成形ロールの熱媒操作温度…70℃〜80℃
第2冷却の成形ロールの熱媒操作温度…80℃〜90℃
[Examples 1 to 5]
In Examples 1 to 5, embossed shaped sheets were produced using the extrusion molding apparatus of FIG. 3 in the above-described embodiment. The specific conditions of the manufacturing method in this case were as follows.
Extrusion resin: MS resin (p-MMA: PS = 80: 20)
Screw of extruder ... φ150mm
Extruder discharge rate ... 250Kg / h
T-die discharge width ... 1450mm
T-die discharge resin temperature: 220 ° C-240 ° C
T-die lip opening 2mm to 6mm
Distance (air gap) between the T-die and the first cooling forming roll and the second cooling forming roll: 140 mm
Diameter of first cooling forming roll ... φ400mm
Diameter of second cooling forming roll ... φ400mm
Embossed shape of second cooling molding roll: heating medium operating temperature of first cooling molding roller of cylindrical lens array with pitch 300 μm and embossed groove depth H′152 μm 70 ° C. to 80 ° C.
Heating medium operating temperature of second cooling forming roll ... 80 ° C to 90 ° C

前記外部ヒーター18としてヘレウス株式会社製(ZKC8000/1500G、400V、8KW)の近赤外線ヒーターを使用した。又、反射部材は、鏡面を研磨して成るアルミニウム製シートを使用した。   As the external heater 18, a near infrared heater manufactured by Heraeus Co., Ltd. (ZKC8000 / 1500G, 400V, 8KW) was used. The reflecting member was an aluminum sheet having a mirror surface polished.

〔比較例1〜5〕
比較例1〜5では前記実施例1〜5と同一の押出成形装置を使用したが、外部ヒーターは使用せず、エアギャップのみを100mmとして成形した。その他の条件は全て各実施例1〜5と同一である。
[Comparative Examples 1-5]
In Comparative Examples 1 to 5, the same extrusion molding apparatus as in Examples 1 to 5 was used, but an external heater was not used and only the air gap was 100 mm. All other conditions are the same as in Examples 1-5.

図9は、実施例及び比較例に係る賦形ロール溝29(エンボス形状の溝深さ:H’=0.152mm、エンボス形状の溝ピッチ:P’=0.302mm)における溝形状を示し、図10は、実施例及び比較例に係る賦形されたエンボス賦形シート16(H:エンボス形状の溝賦形高さ、P:エンボス形状の溝ピッチ、T:シート総厚味)を示す。   FIG. 9 shows a groove shape in the shaped roll groove 29 (embossed groove depth: H ′ = 0.152 mm, embossed groove pitch: P ′ = 0.302 mm) according to Examples and Comparative Examples, FIG. 10 shows an embossed shaped sheet 16 (H: embossed groove shaped height, P: embossed groove pitch, T: total sheet thickness) shaped according to Examples and Comparative Examples.

〔エンボス賦形性の評価〕
前記実施例1〜5及び比較例1〜5によって得られた個々のエンボス賦形シートについて、形状測定機を用いてエンボス形状の形状精度と賦形のバラツキを測定した。尚、賦形シートのエンボス形状の測定は、接触式形状測定器(株式会社小坂研究所製:サーフコーダET4000A)、及び拡大投影機(株式会社ミツトヨ製:PJ−A3000、200倍〜500倍)を用いた。
[Evaluation of embossing formability]
About each embossing shaping sheet obtained by the said Examples 1-5 and Comparative Examples 1-5, the shape accuracy of the embossing shape and the variation in shaping were measured using the shape measuring machine. In addition, the measurement of the embossed shape of the shaped sheet is performed using a contact-type shape measuring device (manufactured by Kosaka Laboratory Co., Ltd .: Surfcorder ET4000A) and an enlargement projector (manufactured by Mitutoyo Corporation: PJ-A3000, 200 times to 500 times) Was used.

実施例1〜5の結果を〔表1〕に示し、比較例1〜5の結果を〔表2〕に示す。   The results of Examples 1 to 5 are shown in [Table 1], and the results of Comparative Examples 1 to 5 are shown in [Table 2].

Figure 2008080496
Figure 2008080496

Figure 2008080496
Figure 2008080496

〔表1〕に示す通り、実施例1〜5によれば、外部ヒーター18でTダイ12から吐出された直後のシート状物16の表面を加熱することによって、賦形率(H/H’)が93%〜98%に達し、且つ、押出方向と押出幅方向ともにエンボス形状の賦形高さのバラツキ範囲が±0.6%〜2%以下に収まった。又、エンボス形状の賦形ピッチPについては、当該熱可塑性樹脂の熱収縮率の範囲である0.5%〜0.6%以内の範囲に収まり、バラツキを生じなかった。   As shown in Table 1, according to Examples 1 to 5, by heating the surface of the sheet-like material 16 immediately after being discharged from the T die 12 by the external heater 18, the shaping rate (H / H ′ ) Reached 93% to 98%, and the variation range of the embossed shaping height in both the extrusion direction and the extrusion width direction was within ± 0.6% to 2%. Further, the embossed shaping pitch P was within the range of 0.5% to 0.6%, which is the range of the heat shrinkage rate of the thermoplastic resin, and no variation occurred.

又、前記外部ヒーター18として中赤外線ヒーター(ヘレウス株式会社製(BSG3750/1500、230V、3.75KW)を用いた場合は、賦形率(H/H’)が90%〜93%、賦形高さのバラツキ範囲は±0.6%〜2%以内となり、近赤外線ヒーターを用いた場合よりも賦形率がやや低下した(詳細は省略する)。   Further, when a mid-infrared heater (Hereus Co., Ltd. (BSG3750 / 1500, 230V, 3.75 KW)) is used as the external heater 18, the shaping rate (H / H ′) is 90% to 93%. The variation range of the height was within ± 0.6% to 2%, and the shaping rate was slightly lower than when the near infrared heater was used (details are omitted).

一方、〔表2〕中に示す通り、比較例1(シート厚味T=0.6mm)によれば、上記実施例1との比較に於いて、エアギャップを更に詰めて一対の冷却成形ロール13,14で加圧ニップされる直前の樹脂温度を実施例1の場合と概ね同一としたにも拘わらず、賦形率が60%程度と低下し、且つ、賦形高さのバラツキが±3%〜±7%と悪化した。   On the other hand, as shown in [Table 2], according to Comparative Example 1 (sheet thickness T = 0.6 mm), in comparison with Example 1 above, a pair of cooling forming rolls were further packed with an air gap. Although the resin temperature immediately before the press nip at 13 and 14 is substantially the same as in the case of Example 1, the forming rate is reduced to about 60% and the variation in forming height is ± It deteriorated from 3% to ± 7%.

また、比較例2によれば、シート厚味Tが3mmと厚くなると、更に賦形率が53%に低下し、加えて、賦形高さのバラツキも±7%に拡大した。   Moreover, according to Comparative Example 2, when the sheet thickness T was as thick as 3 mm, the shaping rate further decreased to 53%, and in addition, the variation in shaping height was increased to ± 7%.

更に、比較例4及び比較例5によれば、冷却成形ロール装置を縦型から横型の冷却成形ロール装置とした場合でも、賦形率が54%〜60%、賦形のバラツキが±3%から±7%となり、実施例4,5に比べて賦形率、バラツキともに劣る結果となった。   Furthermore, according to Comparative Example 4 and Comparative Example 5, even when the cooling forming roll device is changed from a vertical type to a horizontal type cooling forming roll device, the forming rate is 54% to 60%, and the variation in forming is ± 3%. From the results, it was ± 7%, which was inferior in both the shaping rate and variation compared to Examples 4 and 5.

このように、何れの比較例1〜5の場合に於いても、シート厚味Tが0.6mmから3mmの範囲で外部ヒーター無しの装置条件では、賦形率が50%〜70%となった。   Thus, in any of Comparative Examples 1 to 5, the sheet thickness T is in the range of 0.6 mm to 3 mm, and the apparatus condition without an external heater is 50% to 70%. It was.

更に又、比較例1〜5においては、個々の形状に関する押出方向と押出幅方向の賦形高さのバラツキも±3%〜±7%以上のバラツキを生じ、特に、光学用途向けのエンボス賦形シートとしては、所要の設計性能が得られなかった。   Furthermore, in Comparative Examples 1 to 5, the variation in the shaping height in the extrusion direction and the extrusion width direction with respect to each shape also produced a variation of ± 3% to ± 7% or more, particularly embossing for optical applications. As a shaped sheet, the required design performance could not be obtained.

以上の如く、本発明は、外部ヒーターの照射光をTダイのダイリップ先端側反射部材で反射させつつ、シート状物の表面を空中で照射加熱させることにより、シート状物の吐出樹脂温度を、バンク成形が可能な熱可塑性樹脂のガラス転移点Tg以上とし、冷却賦形ロールで加圧ニップされる直前の表層部分をゴム遷移領域の温度に上げたので、型戻り現象を最小限に抑えることができた。   As described above, in the present invention, the surface of the sheet-like material is irradiated and heated in the air while reflecting the irradiation light of the external heater by the die lip tip-side reflecting member of the T die, thereby reducing the discharge resin temperature of the sheet-like material. The glass transition point Tg of the thermoplastic resin that can be bank-molded is set to be higher than the glass transition point Tg, and the surface layer portion immediately before being pressure-niped by the cooling shaping roll is raised to the temperature of the rubber transition region, so that the mold return phenomenon is minimized. I was able to.

即ち、Tダイからの吐出直後の樹脂温は、一対の冷却成形ロールでバンク成形が可能なガラス転移点Tg以上の必要最小限な操作温度とし、エンボス形状を付与したい側のシート吐出状物の表層部分を、外部ヒーターで照射加熱してゴム遷移領域の温度に上昇させた上で、冷却賦形ロールで加圧ニップした。これにより、エンボス形状の溝への溶融樹脂の流入と充満性を上げ、且つ、離型後のシート中心層からの熱移動を抑制することができた。   That is, the resin temperature immediately after the discharge from the T die is the minimum required operating temperature that is equal to or higher than the glass transition point Tg that can be bank-formed by a pair of cooling forming rolls. The surface layer portion was irradiated with an external heater and heated to the temperature of the rubber transition region, and then pressure-niped with a cooling shaping roll. Thereby, the inflow and filling property of the molten resin to the embossed groove were improved, and the heat transfer from the sheet center layer after release was suppressed.

斯くして、縦型の冷却成形ロールあるいは横型の冷却成形ロールのロール賦形装置を使用した汎用押出シートの製造において、シートの総厚味Tに対して相対的に形状高さHが低くてピッチが微細なエンボス形状を付与して成る熱可塑性樹脂シートを連続的に製造でき、且つ、賦形率及び形状転写精度が従来に比べて著しく向上した。   Thus, in the manufacture of a general-purpose extruded sheet using a roll shaping device for a vertical cooling forming roll or a horizontal cooling forming roll, the shape height H is relatively low with respect to the total thickness T of the sheet. A thermoplastic resin sheet having an embossed shape with a fine pitch could be continuously produced, and the forming rate and shape transfer accuracy were significantly improved as compared with the conventional one.

なお、本発明は、本発明の精神を逸脱しない限り種々の改変をなすことができ、そして、本発明が該改変されたものにも及ぶことは当然である。   The present invention can be variously modified without departing from the spirit of the present invention, and the present invention naturally extends to the modified ones.

本発明の実施形態例1に係るエンボス賦形シートの製造装置の概略図である。It is the schematic of the manufacturing apparatus of the embossing shaped sheet which concerns on Example 1 of embodiment of this invention. 図1の外部ヒーター周りの拡大図である。It is an enlarged view around the external heater of FIG. 本発明の実施形態例2に係るエンボス賦形シートの製造装置の外部ヒーター周りの拡大図である。It is an enlarged view around the external heater of the manufacturing apparatus of the embossing shaped sheet which concerns on Example 2 of this invention. 本発明の実施形態例3に係るエンボス賦形シートの製造装置の概略図である。It is the schematic of the manufacturing apparatus of the embossing shaped sheet which concerns on Example 3 of this invention. 実施形態例3のエンボス賦形シートの製造装置に外部ヒーターを1個設置した態様であって、該外部ヒーターの周りを示す拡大図である。It is the aspect which installed one external heater in the manufacturing apparatus of the embossing shaped sheet | seat of Example 3 of Embodiment, Comprising: It is an enlarged view which shows the circumference | surroundings of this external heater. 実施形態例3のエンボス賦形シートの製造装置に外部ヒーターを2個設置した態様であって、該外部ヒーターの周りを示す拡大図である。It is the aspect which installed the two external heaters in the manufacturing apparatus of the embossing shaped sheet | seat of Embodiment 3, and is an enlarged view which shows the circumference | surroundings of this external heater. 従来のエンボス賦形シートの製造装置を示し、縦型の冷却成形ロール装置に係る製造装置の概略図である。It is the schematic of the manufacturing apparatus which shows the manufacturing apparatus of the conventional embossing shaped sheet | seat, and concerns on a vertical-type cooling molding roll apparatus. 従来のエンボス賦形シートの製造装置を示し、横型の冷却成形ロール装置に係る製造装置の概略図である。It is the schematic of the manufacturing apparatus which shows the manufacturing apparatus of the conventional embossing shaped sheet, and concerns on a horizontal type cooling molding roll apparatus. 実施例及び比較例に係る賦形ロール(エンボス形状の溝深さ:H’=0.152mm、エンボス形状の溝ピッチ:P’=0.302mm)における溝形状断面を示す。The groove shape cross section in the shaping roll (Embossed groove depth: H ′ = 0.152 mm, Embossed groove pitch: P ′ = 0.302 mm) according to Examples and Comparative Examples is shown. 実施例及び比較例に係る賦形されたエンボス賦形シート(H:エンボス形状の溝賦形高さ、P:エンボス形状の溝ピッチ、T:シート厚味)を示す断面図である。It is sectional drawing which shows the embossing shaped sheet | seat (H: Embossed groove shaping height, P: Embossed groove pitch, T: Sheet | seat thickness) which concerns on the Example and the comparative example.

符号の説明Explanation of symbols

11 押出機
12 シート成形用Tダイ
13 縦型の第1の冷却成形ロール
14 縦型の第2の冷却成形ロール(エンボス形状付与用冷却賦形ロール)
15 縦型の第3の冷却成形ロール
16 シート状物(エンボス賦形シート)
17 バンク
18 縦型の第2の冷却成形ロール側の外部ヒーター
19 縦型の第2の冷却成形ロール側の外部ヒーター用反射部材
20 横型の第1の冷却成形ロール
21 横型の第2の冷却成形ロール(エンボス形状付与用冷却賦形ロール))
22 横型の第3の冷却成形ロール
23 横型の第4の冷却成形ロール
24 横型の第1の冷却成形ロール側の外部ヒーター
25 横型の第1の冷却成形ロール側の外部ヒーター用反射部材
26 横型の第2の冷却成形ロール側の外部ヒーター
27 横型の第2の冷却成形ロール側の外部ヒーター用反射部材
28 横型の第1の冷却成形ロール(エンボス形状付与用冷却賦形ロール)
11 Extruder 12 T-die for sheet molding
13 Vertical first cooling forming roll 14 Vertical second cooling forming roll (cooling shaping roll for embossing)
15 Vertical third cooling molding roll 16 Sheet (embossed sheet)
17 Bank 18 External heater 19 on the side of the vertical second cooling forming roll 19 Reflective member 20 for the external heater on the side of the vertical second cooling forming roll Horizontal first cooling forming roll 21 Horizontal type second cooling forming Roll (cooling shaping roll for embossing)
22 Horizontal third cooling forming roll 23 Horizontal fourth cooling forming roll 24 External heater 25 on horizontal first cooling forming roll Reflective member 26 for external heater on horizontal first cooling forming roll side External heater 27 on the second cooling molding roll side Reflective member 28 for the external heater on the horizontal second cooling molding roll side First cooling molding roll (cooling shaping roll for embossing shape imparting)

Claims (4)

熱可塑性樹脂を押出機に供給して溶融混練した後にTダイを通じてシート状に吐出押出し、一対の冷却成形ロールで加圧ニップして、該冷却成形ロール表面に施されたエンボス形状を連続的に転写賦形させるエンボス賦形シートの製造方法において、
前記Tダイから吐出押出された直後のシート状物の外表面を、外部ヒーターにより空中で加熱させた後に、前記冷却成形ロールで加圧ニップして形状転写させるエンボス賦形シートの製造方法であって、
前記外部ヒーターが赤外線ヒーターであり、該外部ヒーターの照射光を、前記Tダイのダイリップ先端の表面に設けた反射部材で反射させつつ、前記シート状物の表面を空中で照射加熱させることを特徴とするエンボス賦形シートの製造方法。
The thermoplastic resin is supplied to an extruder, melted and kneaded, then discharged and extruded into a sheet shape through a T-die, and press-niped with a pair of cooling molding rolls to continuously form the embossed shape applied to the surface of the cooling molding roll. In the method for producing an embossed shaped sheet for transfer shaping,
A method for producing an embossed shaped sheet in which an outer surface of a sheet-like material immediately after being extruded and extruded from the T-die is heated in the air by an external heater and then subjected to a pressure nip with the cooling molding roll to transfer the shape. And
The external heater is an infrared heater, and the surface of the sheet-like material is irradiated and heated in the air while reflecting the irradiation light of the external heater by a reflecting member provided on the surface of the tip of the die lip of the T die. A method for producing an embossed shaped sheet.
上記外部ヒーターの照射光を、エンボス形状が付与された上記冷却成形ロール表面に照射させつつ、上記シート状物の表面を空中で照射加熱させることを特徴とする請求項1記載のエンボス賦形シートの製造方法。   2. The embossed shaped sheet according to claim 1, wherein the surface of the sheet-like material is irradiated and heated in the air while irradiating the surface of the cooling molding roll provided with the embossed shape with irradiation light of the external heater. Manufacturing method. 上記形状転写させるエンボス形状の最大深さをHとし、シートの総厚味をTとしたとき、
0.6mm ≦ T ≦ 3.0mm
0.05 ≦ H/T ≦ 0.25
の範囲にあることを特徴とする請求項1又は2記載のエンボス賦形シートの製造方法。
When the maximum depth of the embossed shape to be transferred is H and the total thickness of the sheet is T,
0.6mm ≤ T ≤ 3.0mm
0.05 ≤ H / T ≤ 0.25
The method for producing an embossed shaped sheet according to claim 1, wherein the embossed shaped sheet is in the range.
熱可塑性樹脂を押出機に供給して溶融混練した後にTダイを通じてシート状に吐出押出し、一対の冷却成形ロールで加圧ニップして、該冷却成形ロール表面に施されたエンボス形状を連続的に転写賦形させる請求項1,2又は3記載のエンボス賦形シートの製造方法に用いられるエンボス賦形シートの製造装置であって、
前記Tダイから吐出押出された直後のシート状物の表面を照射加熱させる外部ヒーターと、前記Tダイのダイリップ先端の表面に設けられた反射部材とを備え、前記外部ヒーターが赤外線ヒーターであり、該外部ヒーターの照射光を前記反射部材で反射させつつ、前記シート状物の表面を空中で照射加熱するように構成したことを特徴とするエンボス賦形シートの製造装置。

The thermoplastic resin is supplied to an extruder, melted and kneaded, then discharged and extruded into a sheet shape through a T-die, and press-niped with a pair of cooling molding rolls to continuously form the embossed shape applied to the surface of the cooling molding roll. An embossed shaped sheet manufacturing apparatus used in the method for manufacturing an embossed shaped sheet according to claim 1, 2 or 3 for transfer shaping,
An external heater that irradiates and heats the surface of the sheet-like material immediately after being extruded and extruded from the T die, and a reflecting member provided on the surface of the die lip tip of the T die, and the external heater is an infrared heater, An apparatus for producing an embossed shaped sheet, wherein the surface of the sheet-like material is irradiated and heated in the air while the irradiation light of the external heater is reflected by the reflecting member.

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008179036A (en) * 2007-01-24 2008-08-07 Toshiba Mach Co Ltd Sheet forming apparatus
JP2012153030A (en) * 2011-01-27 2012-08-16 Hitachi Zosen Corp Method of molding eva resin sheet

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008179036A (en) * 2007-01-24 2008-08-07 Toshiba Mach Co Ltd Sheet forming apparatus
JP2012153030A (en) * 2011-01-27 2012-08-16 Hitachi Zosen Corp Method of molding eva resin sheet

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