JP2008069275A - Transferring type pressure-sensitive adhesive tape with scent - Google Patents

Transferring type pressure-sensitive adhesive tape with scent Download PDF

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JP2008069275A
JP2008069275A JP2006249465A JP2006249465A JP2008069275A JP 2008069275 A JP2008069275 A JP 2008069275A JP 2006249465 A JP2006249465 A JP 2006249465A JP 2006249465 A JP2006249465 A JP 2006249465A JP 2008069275 A JP2008069275 A JP 2008069275A
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pressure
sensitive adhesive
transfer
adhesive layer
transferred
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JP5052082B2 (en
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Koji Shimokawa
公司 下川
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Union Chemical Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a transferring type pressure-sensitive adhesive tape with scent having a secondary function that the scent is emitted even after an article to be transferred is stuck on an object to be transferred of a paper surface onto which the pressure-sensitive adhesive layer is transferred by the pressure-sensitive adhesive layer provided on an automatic winding type coating film transferring unit. <P>SOLUTION: The transferring type pressure-sensitive adhesive tape with the scent has a paying out part, a pressing/transferring part and a winding part at the inside of the automatic winding type coating film transferring unit, and the pressure-sensitive adhesive layer containing a perfume microcapsule is provided on the paying out part. When the pressure-sensitive adhesive layer is pressure-sensitively transferred on the object to be transferred of the paper surface by the coating film transferring unit, the scent is generated by destroying the pressure-sensitive adhesive layer by a transferring pressure applied to the pressing transferring part, and an effect that the scent is emitted even after the article to be transferred is stuck can be obtained. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、外枠を構成するケース内に転写式感圧接着テープを繰出す繰出し部と、前記テープを被転写体に押圧して押圧転写する押圧転写部と、転写後の基材テープを巻取る巻取り部を有する自動巻取り式の塗膜転写具に関し、特に前記塗膜転写具内に備えられた転写式感圧接着テープに関する。   The present invention includes: a feeding portion that feeds a transfer-type pressure-sensitive adhesive tape into a case constituting an outer frame; a press-transfer portion that presses and transfers the tape against a transfer target; and a base tape after transfer More particularly, the present invention relates to a transfer-type pressure-sensitive adhesive tape provided in the coating film transfer tool.

近年、取り扱いの容易さから両面接着テープや転写式感圧接着テープが注目を集めている。この種の転写式感圧接着テープとしては、例えば、特開平08−027433号に開示されているように紙や有機高分子フィルムなどの基材の片面に感圧接着層を設けた構造のものが知られている。この転写式感圧接着テープは手持ち型の転写具に収納して使用される。   In recent years, double-sided adhesive tapes and transfer-type pressure-sensitive adhesive tapes have attracted attention because of their ease of handling. As this type of transfer-type pressure-sensitive adhesive tape, for example, a structure having a pressure-sensitive adhesive layer provided on one side of a substrate such as paper or an organic polymer film as disclosed in JP-A-08-027433 It has been known. This transfer-type pressure-sensitive adhesive tape is used by being housed in a hand-held transfer tool.

通常、感圧接着層は透明であるが、紙面等に転写された感圧接着層の転写箇所が視認しやすいように感圧接着層を着色した色付粘着剤転写シート又はテープが特開2001−316641号に開示されている。   Usually, the pressure-sensitive adhesive layer is transparent, but a colored pressure-sensitive adhesive transfer sheet or tape in which the pressure-sensitive adhesive layer is colored so that the transfer location of the pressure-sensitive adhesive layer transferred onto the paper surface or the like can be easily seen is disclosed in Japanese Patent Laid-Open No. -3166641.

感圧接着層に2次的な機能を付与した塗膜転写具として、特開2004−230596号が開示されている。前記発明によれば、転写時に転写塗膜に2次的な機能を付与させるために、塗膜転写具内の転写ヘッド近傍に転写テープの塗膜に所定の機能を付与させるための機能付与装置を設けている。
特開平08−027433号公報 特開2001−316641号公報 特開2004−230596号公報
Japanese Patent Application Laid-Open No. 2004-230596 is disclosed as a coating film transfer tool in which a secondary function is imparted to the pressure-sensitive adhesive layer. According to the invention, in order to give a secondary function to the transfer coating film at the time of transfer, a function adding device for giving a predetermined function to the coating film of the transfer tape in the vicinity of the transfer head in the coating film transfer tool. Is provided.
Japanese Patent Application Laid-Open No. 08-027433 Japanese Patent Laid-Open No. 2001-316641 JP 2004-230596 A

前記第1の従来例では、紙面等の被転写体上に感圧接着層が転写されて紙等の被転写物を貼り付けるものであって、転写後の感圧接着層には2次的な機能を持ち合わせていない。   In the first conventional example, a pressure-sensitive adhesive layer is transferred onto a transfer medium such as paper and a transfer object such as paper is pasted. It does not have a special function.

また、前記第2の従来例では、紙面等の被転写体上に転写された感圧接着層は、有機顔料等で色付けされているので転写時の視認性は得られるが、被転写体に紙等の転写物を貼着した際にはその機能は消えてしまい、貼着後においての2次的な機能というのは得られない。   In the second conventional example, the pressure-sensitive adhesive layer transferred onto the transfer material such as paper is colored with an organic pigment and the like so that visibility during transfer is obtained. When a transfer material such as paper is pasted, the function disappears and a secondary function after the pasting cannot be obtained.

さらに、前記第3の従来例では、塗膜転写具内に配置された機能付与装置によって転写テープの塗膜に所定の機能を付与することは可能であるが、この塗膜転写具では塗膜転写具内に部品を追加しており安価に製品を提供することができず、また転写テープの使い始めから使い終わりまで所定の機能を付与するための液体もしくは微粉体を均一に付与するためには高い技術を要する。   Further, in the third conventional example, it is possible to give a predetermined function to the coating film of the transfer tape by the function applying device arranged in the coating film transfer tool. In order to uniformly apply liquids or fine powders to give a predetermined function from the beginning to the end of use of the transfer tape because parts are added in the transfer tool and the product cannot be provided at low cost. Requires high technology.

本発明は、上記した問題点に鑑み、自動巻取り式の塗膜転写具に備えられた感圧接着層が紙面等の被転写体上に感圧転写された際に、前記感圧接着層に含有された香料マイクロカプセルが転写ヘッド部でかかる転写圧によって破壊されることにより香りを発生させ、被転写物を貼着後にも香りがするという2次的な機能を有したことを特徴とする香り付き転写式感圧接着テープを提供するものである。   In view of the above-described problems, the present invention provides a pressure-sensitive adhesive layer when the pressure-sensitive adhesive layer provided in the automatic winding type film transfer tool is pressure-sensitive transferred onto a transfer target such as a paper surface. The fragrance microcapsule contained in the product has a secondary function of generating a scent by being broken by the transfer pressure at the transfer head portion and scenting even after the transfer object is pasted. A scented transfer-type pressure-sensitive adhesive tape is provided.

なお、ここでいう2次的な機能というものは、紙等の被転写体に押圧転写された感圧接着層が紙等の被転写物を貼着するという転写式感圧接着テープの機能に加えて、感圧接着層中に含有された香料マイクロカプセルの効果によって貼着後に香りを発することをいう。   The secondary function here refers to the function of a transfer-type pressure-sensitive adhesive tape in which a pressure-sensitive adhesive layer pressed and transferred to a material to be transferred such as paper adheres a material to be transferred such as paper. In addition, it means that a fragrance is emitted after sticking due to the effect of the fragrance microcapsule contained in the pressure-sensitive adhesive layer.

上記課題を解決するために、本発明の香り付き転写式感圧接着テープは、外枠を構成するケース内に少なくとも繰出しリールを含んだ繰出し部と少なくとも巻取りリールを含んだ巻取り部と転写ヘッドを含んだ押圧転写部を備え、前記繰出し部の繰出しリールに巻回された転写テープが繰り出され、前記転写ヘッドを経て前期巻取り部の巻取りリールに巻き取られるように構成した自動巻取り式の塗膜転写具において、前記転写テープが、基材上に粘着剤からなる感圧接着層を形成し、かつ前記感圧接着層中に2次的な機能を付与するための香料マイクロカプセルを含有している。   In order to solve the above-described problems, the scented transfer pressure-sensitive adhesive tape of the present invention includes a transfer part including at least a supply reel in a case constituting an outer frame, a transfer part including at least a take-up reel, and a transfer. An automatic winding comprising a pressure transfer part including a head, wherein a transfer tape wound around a feeding reel of the feeding part is fed out and wound around a winding reel of a previous winding part via the transfer head In the take-type coating film transfer tool, the transfer tape forms a pressure-sensitive adhesive layer made of a pressure-sensitive adhesive on a substrate, and imparts a secondary function to the pressure-sensitive adhesive layer. Contains capsules.

また、前記香料マイクロカプセルが前記感圧接着層中の固形分として5〜20重量パーセントとなるように配合されるよう構成されている。   Moreover, the said fragrance | flavor microcapsule is mix | blended so that it may become 5 to 20 weight% as solid content in the said pressure sensitive adhesive layer.

さらに、前記香料マイクロカプセルを含有した感圧接着層の厚みが5〜40μmとなるように構成されている。   Furthermore, the pressure-sensitive adhesive layer containing the fragrance microcapsule is configured to have a thickness of 5 to 40 μm.

自動巻取り式の塗膜転写具に備えられた感圧接着層が感圧転写された際に、前記感圧接着層に含有された香料マイクロカプセルが転写ヘッドでかかる転写圧によって破壊されることにより香りを発生させ、被転写物を貼着後にも香りがするという2次的な機能を有することができる。   When the pressure-sensitive adhesive layer provided in the automatic winding type film transfer tool is pressure-sensitive transferred, the perfume microcapsules contained in the pressure-sensitive adhesive layer are destroyed by the transfer pressure applied by the transfer head. A secondary function of generating a scent and giving a scent even after the transfer object is attached can be obtained.

以下に、本発明の実施の形態を図面に基づいて説明する。   Embodiments of the present invention will be described below with reference to the drawings.

図1に本発明の香り付き転写式感圧接着テープを具備した塗膜転写具を示す。前記塗膜転写具1内には、ケース2内に植設した2個の支軸3、4それぞれが、使用後の転写テープを回収する巻取りリール7と、基材テープの片面に塗膜を備えた転写式感圧接着テープ5を巻回した繰出しリール6とを連動して回動自在に支持されており、先端に転写ヘッド9を備えた押圧転写部8がその押圧転写部8をケース2外に突出するように備えられるよう配置されている。繰出し部として繰出しリール6に巻回された転写式感圧接着テープ5は引き出され、押圧転写部8の転写ヘッド9で転写式感圧接着テープ5の塗膜を被転写体に押圧して転写し、転写後の基材テープを巻取り部である巻取りリール7で巻き取るようになっている。   FIG. 1 shows a coating film transfer tool provided with the scented transfer pressure-sensitive adhesive tape of the present invention. In the coating film transfer tool 1, two support shafts 3 and 4 implanted in the case 2 each have a take-up reel 7 for collecting the used transfer tape, and a coating film on one side of the base tape. A pressure transfer unit 8 having a transfer head 9 at the tip is supported by a transfer reel 6 wound around a transfer pressure-sensitive adhesive tape 5 provided with a transfer head 9. It arrange | positions so that it may be provided so that it may protrude outside the case 2. FIG. The transfer-type pressure sensitive adhesive tape 5 wound around the supply reel 6 as the supply portion is drawn out, and the transfer head 9 of the pressure transfer portion 8 presses the coating film of the transfer-type pressure sensitive adhesive tape 5 against the transfer target. The base tape after transfer is wound up by a winding reel 7 which is a winding portion.

図2は本発明の実施の形態に係る前記塗膜転写具1に備えられた転写式感圧接着テープ5の断面構造を示す模式的断面図である。図2に示した転写式感圧接着テープ5は、基材11の上に設けられ、香料マイクロカプセル12を含有する感圧接着層13によって構成される。基材11にはロール状に巻かれた帯状の材料を用いているので、感圧接着層13を形成した後、所定の幅、長さに裁断する。   FIG. 2 is a schematic cross-sectional view showing a cross-sectional structure of the transfer-type pressure-sensitive adhesive tape 5 provided in the coating film transfer tool 1 according to the embodiment of the present invention. The transfer-type pressure-sensitive adhesive tape 5 shown in FIG. 2 is provided on a base material 11 and is constituted by a pressure-sensitive adhesive layer 13 containing a fragrance microcapsule 12. Since the base material 11 uses a band-shaped material wound in a roll shape, after forming the pressure-sensitive adhesive layer 13, it is cut into a predetermined width and length.

基材11は、ポリエチレンテレフタレート、ポリプロピレン、ポリカーボネート、ポリスチレン、ポリアミド、ポリアミドイミド、ポリエチレン、ポリ塩化ビニル等の合成樹脂製フィルムや、グラシン紙や、人造樹脂フィルム、洋紙和紙等のフィルム状物、あるいはこれらの複合フィルム状物などで構成されている。なお、前記基材11の厚みは特に限定されるものではないが、通常5μm〜100μm程度である。また、基材11の上に必要に応じてグラビア印刷法、ダイ印刷法、リバース印刷法などの方法によりシリコン樹脂やフッ素樹脂などで構成された剥離層を設けてもよい。   The base material 11 is a film made of a synthetic resin such as polyethylene terephthalate, polypropylene, polycarbonate, polystyrene, polyamide, polyamideimide, polyethylene, polyvinyl chloride, a film-like material such as glassine paper, artificial resin film, paper Japanese paper, or the like. It is composed of a composite film-like material. The thickness of the substrate 11 is not particularly limited, but is usually about 5 μm to 100 μm. Moreover, you may provide the peeling layer comprised by silicon resin, a fluororesin, etc. on the base material 11 by methods, such as a gravure printing method, die printing method, and reverse printing method, as needed.

図3は感圧接着層13に含有される香料マイクロカプセル12の模式的断面図である。前記香料マイクロカプセル12は、一般的に香油21と前記香油21を内包するための壁膜材22で構成される。   FIG. 3 is a schematic cross-sectional view of the fragrance microcapsule 12 contained in the pressure-sensitive adhesive layer 13. The perfume microcapsule 12 is generally composed of a perfume oil 21 and a wall film material 22 for enclosing the perfume oil 21.

香油21としては、マイクロカプセル化できるものを任意に選択でき、イチゴをはじめとするフルーツ系、バラに代表されるような草花系、ムスクに代表されるような動物系などが挙げられる。   As the perfume oil 21, those that can be microencapsulated can be arbitrarily selected, and examples thereof include fruits such as strawberries, flowers and flowers represented by roses, and animals and others represented by musk.

壁膜材22には、一般的にゼラチン、ポリアミド、メラミンなどが使用される。製法としては、界面重合法や液中硬化被覆法に代表される化学的製法、コアセルベーション法や界面沈殿法に代表される物理化学的製法、スプレードライング法に代表される物理的製法が挙げられる。なお、香料マイクロカプセル12の製法としてはいずれの製法も選択可能であるが、感圧接着層13を形成するために使用されるインキの溶媒に壁膜材22が溶けないことが前提となる。   Generally, gelatin, polyamide, melamine or the like is used for the wall film material 22. Examples of the production method include a chemical production method represented by an interfacial polymerization method and a submerged curing coating method, a physicochemical production method represented by a coacervation method and an interfacial precipitation method, and a physical production method represented by a spray drying method. It is done. In addition, although any manufacturing method can be selected as a manufacturing method of the fragrance | flavor microcapsule 12, it is a premise that the wall film material 22 does not melt | dissolve in the solvent of the ink used in order to form the pressure-sensitive-adhesion layer 13. FIG.

感圧接着層13中の香料マイクロカプセル12は、一般的な転写テープの使用における転写圧によって前記感圧接着層13に含有される香料マイクロカプセル12が容易に破壊されるように、2.0kgf/cm以上の圧力で破壊されることが望ましい。 The perfume microcapsule 12 in the pressure-sensitive adhesive layer 13 is 2.0 kgf so that the perfume microcapsule 12 contained in the pressure-sensitive adhesive layer 13 can be easily broken by a transfer pressure in the use of a general transfer tape. It is desirable to be destroyed at a pressure of / cm 2 or more.

また、香料マイクロカプセル12が2.0kgf/cm以上の圧力で破壊されれば、前記感圧接着層13を形成させるための任意のコーティング方法での塗工過程中にニップロール等でかかる圧力によって香料マイクロカプセル12が破壊されるのを防ぐことが出来る。 Further, if the perfume microcapsule 12 is broken at a pressure of 2.0 kgf / cm 2 or more, the pressure applied by a nip roll or the like during the coating process in an arbitrary coating method for forming the pressure-sensitive adhesive layer 13 It is possible to prevent the perfume microcapsule 12 from being destroyed.

香料マイクロカプセル12が感圧接着層13中の固形分として占める割合は5〜20重量パーセントの範囲であることが望ましい。すなわち香料マイクロカプセル12が感圧接着層13中の固形分として占める割合が5重量パーセントに満たない場合には、香料マイクロカプセル12を含有した感圧接着層13が紙面等の被転写体上に感圧転写した際、前記香料マイクロカプセル12が転写ヘッド9で破壊されることにより発生する香りが弱くなり、被転写物を貼着後にも香りがするという2次的な機能を充分に発揮できない。   The ratio of the perfume microcapsule 12 as a solid content in the pressure-sensitive adhesive layer 13 is desirably in the range of 5 to 20 weight percent. That is, when the proportion of the fragrance microcapsule 12 as a solid content in the pressure-sensitive adhesive layer 13 is less than 5 weight percent, the pressure-sensitive adhesive layer 13 containing the fragrance microcapsule 12 is placed on a transfer medium such as paper. When pressure-sensitive transfer is performed, the perfume microcapsule 12 is destroyed by the transfer head 9 and the scent generated is weakened, and the secondary function of scenting after the transfer object is pasted cannot be fully exhibited. .

一方、香料マイクロカプセル12の感圧接着層13中の固形分として占める割合が20重量パーセントを超えると、感圧接着層13中の香料マイクロカプセル12によって感圧接着層13の接着力が低下し、被転写体に被転写物を貼着させるという転写式感圧接着テープ自体の性能が得られなくなる。   On the other hand, when the proportion of the fragrance microcapsule 12 as a solid content in the pressure-sensitive adhesive layer 13 exceeds 20 weight percent, the adhesive force of the pressure-sensitive adhesive layer 13 is reduced by the fragrance microcapsule 12 in the pressure-sensitive adhesive layer 13. The performance of the transfer pressure-sensitive adhesive tape itself in which the transfer object is adhered to the transfer object cannot be obtained.

基材11上には香料マイクロカプセル12を含有した感圧接着層13が一定の厚みに形成できるようグラビアコーティング、ロールコーティング、ロッドコーティング等の方法が用いられるが、これに限定されるものではない。また、前記感圧接着層13は無色で透明或いは半透明であってもよく、または各種顔料、染料、金属粉末、蛍光物質、蓄光物質、燐光物質等の着色剤を用いて着色されていてもよい。さらに、感圧接着剤層13の厚みは5〜40μm程度で、好ましくは10〜30μmが最適である。   A method such as gravure coating, roll coating, or rod coating is used so that the pressure-sensitive adhesive layer 13 containing the fragrance microcapsule 12 can be formed on the substrate 11 with a certain thickness, but is not limited thereto. . The pressure-sensitive adhesive layer 13 may be colorless and transparent or translucent, or may be colored using various colorants such as pigments, dyes, metal powders, fluorescent substances, phosphorescent substances, and phosphorescent substances. Good. Furthermore, the thickness of the pressure-sensitive adhesive layer 13 is about 5 to 40 μm, and preferably 10 to 30 μm.

前記感圧接着層13の厚みが5μm未満の場合には、前記自動巻取り式の塗膜転写具1によって紙面等の被転写面に転写された香料マイクロカプセル12を含有した感圧接着層13は、被転写体に被転写物を貼着するための粘着性(タック)や接着力が不十分であり、また40μmを超える場合には、テープをリール状に加工して長期保存した際に基材11の背面へのブロッキングの恐れを生じる。さらに感圧接着層13の厚みが大きければ、その分だけリール状に加工したテープの大きさも大きくなってしまい、繰出し部、転写部、巻取り部を有した塗膜転写具1の大きさが大きくなってしまってハンドリング性が悪くなってしまう。   When the thickness of the pressure-sensitive adhesive layer 13 is less than 5 μm, the pressure-sensitive adhesive layer 13 containing the perfume microcapsules 12 transferred to the transfer surface such as paper by the automatic winding type coating film transfer tool 1. Is insufficient in tackiness (adhesiveness) and adhesive strength for adhering the transferred material to the transferred material, and when it exceeds 40 μm, when the tape is processed into a reel and stored for a long time There is a risk of blocking the back surface of the substrate 11. Furthermore, if the thickness of the pressure-sensitive adhesive layer 13 is large, the size of the tape processed into a reel shape also increases, and the size of the coating film transfer tool 1 having a feeding portion, a transfer portion, and a winding portion is large. It becomes large and handling becomes worse.

本発明をさらに詳しく説明するため以下に実施例を挙げるが、本発明はこられ実施例のみに限定されるものではない。   In order to describe the present invention in more detail, examples will be given below, but the present invention is not limited to these examples.

表1に本発明の感圧接着層13を形成するために用いた基本調合であり、粘着剤の配合剤および配合量を示している。   Table 1 shows the basic preparation used for forming the pressure-sensitive adhesive layer 13 of the present invention, and shows the compounding agent and the compounding amount of the pressure-sensitive adhesive.

Figure 2008069275
Figure 2008069275

実施例1として、両面離型加工したグラシン紙の片面に前記基本調合中に香料マイクロカプセル12を混合した後、乾燥後の厚みが12μmになるようロールコーティングにより塗布し、約120℃で乾燥することにより、感圧接着層13を形成した。なお、感圧接着層13中の香料マイクロカプセル12にはイチゴの香りを持つものを使用し、表1の基本調合中に香料マイクロカプセル12を3.5重量部(感圧接着層13中の前記香料マイクロカプセル12の固形分として占める割合は12.4重量パーセント)を加え、香り付き転写式感圧接着テープを得た。次いで、香り付き転写式感圧接着テープを10mm幅にスリット加工し、繰出しリールを含んだ繰出し部、転写ヘッドを含んだ押圧転写部、巻取りリールを含んだ巻取り部を備えた自動巻取り式の塗膜転写具に装着して被転写体に転写した。   As Example 1, after mixing the fragrance | flavor microcapsule 12 in the said basic preparation on the single side | surface of the glassine paper which carried out the double-side mold release process, it apply | coats by roll coating so that the thickness after drying may be set to 12 micrometers, and it dries at about 120 degreeC. As a result, the pressure-sensitive adhesive layer 13 was formed. In addition, the fragrance | flavor microcapsule 12 in the pressure sensitive adhesive layer 13 uses what has a strawberry fragrance, and 3.5 weight part of fragrance | flavor microcapsules 12 in the basic preparation of Table 1 (in the pressure sensitive adhesive layer 13) The ratio of the fragrance | flavor microcapsule 12 which occupies as solid content was 12.4 weight%), and the transcription | transfer type pressure-sensitive adhesive tape with a fragrance was obtained. Next, slitting the scented transfer-type pressure-sensitive adhesive tape to a width of 10 mm, automatic winding provided with a feeding part including a feeding reel, a pressure transfer part including a transfer head, and a winding part including a winding reel. A film transfer tool of the type was mounted and transferred to a transfer medium.

実施例2として、両面離型加工したポリエチレンテレフタレートフィルムの片面に前記基本調合中に香料マイクロカプセル12を混合した後、乾燥後の厚みが25μmになるようロールコーティングにより塗布し、約120℃で乾燥することにより、感圧接着層13を形成した。なお、感圧接着層13中の香料マイクロカプセル12にはイチゴの香りを持つものを使用し、表1の基本調合中に香料マイクロカプセル12を5.8重量部(感圧接着層13中の前記香料マイクロカプセル12の固形分として占める割合は19.0重量パーセント)を加え、香り付き転写式感圧接着テープを得た。次いで、前記香り付き転写式感圧接着テープを10mm幅にスリット加工し、繰出しリールを含んだ繰出し部、転写ヘッドを含んだ押圧転写部、巻取りリールを含んだ巻取り部を備えた自動巻取り式の塗膜転写具に装着して被転写体に転写した。   As Example 2, after mixing the fragrance | flavor microcapsule 12 in the said basic preparation on the single side | surface of the polyethylene terephthalate film which carried out the double-side mold release process, it apply | coated by roll coating so that the thickness after drying might be set to 25 micrometers, and dried at about 120 degreeC. By doing so, the pressure-sensitive adhesive layer 13 was formed. In addition, the fragrance | flavor microcapsule 12 in the pressure sensitive adhesive layer 13 uses what has a strawberry fragrance, 5.8 weight part of fragrance | flavor microcapsules 12 in the basic preparation of Table 1 (in the pressure sensitive adhesive layer 13) The proportion of the fragrance microcapsule 12 as a solid content was 19.0% by weight) to obtain a scented transfer pressure-sensitive adhesive tape. Next, the scented transfer-type pressure-sensitive adhesive tape is slit into a width of 10 mm, and is provided with a winding part including a feeding reel, a pressing transfer part including a transfer head, and a winding part including a winding reel. It was mounted on a take-off type film transfer tool and transferred to a transfer medium.

実施例3〜実施例6として、表1の基本調合中に加える香料マイクロカプセル12の含有量及び、前記感圧接着層13の乾燥後の厚みはそれぞれ設定し、その数値を表2に示した。なお、それ以外については実施例1と同様にして香り付き感圧転写テープを作製し、前記香り付き転写式感圧接着テープを10mm幅にスリット加工し、繰出しリールを含んだ繰出し部、転写ヘッドを含んだ押圧転写部、巻取りリールを含んだ巻取り部を備えた自動巻取り式の塗膜転写具に装着して、被転写体に転写した。   As Example 3 to Example 6, the content of the perfume microcapsule 12 added during the basic preparation of Table 1 and the thickness after drying of the pressure-sensitive adhesive layer 13 were set, and the numerical values are shown in Table 2. . Otherwise, a scented pressure-sensitive transfer tape was prepared in the same manner as in Example 1, and the scented transfer-type pressure-sensitive adhesive tape was slit to a width of 10 mm, and a feeding part including a feeding reel, a transfer head The film was mounted on a self-winding type coating film transfer tool provided with a pressure transfer unit including a take-up reel and a winding unit including a take-up reel, and transferred to a transfer target.

作製した検体について、被転写物を貼着したあとの芳香性と転写された感圧接着層13の被転写体と被転写物との接着性を評価した。なお、前記評価方法としては以下の判定をおこなった。   The prepared specimen was evaluated for the fragrance after the transfer object was adhered and the adhesion between the transferred object of the transferred pressure-sensitive adhesive layer 13 and the transfer object. In addition, the following determination was performed as said evaluation method.

芳香性に関しては、被転写体に香料マイクロカプセル12を含有する感圧接着層13を転写させ、被転写物を押圧して貼着させた直後の芳香性について以下の判定基準により芳香性の判定をおこなった。
○・・・香りが漂った。
×・・・香りが漂わなかった。
Regarding the fragrance, the determination of fragrance is performed according to the following criteria for the fragrance immediately after the pressure-sensitive adhesive layer 13 containing the fragrance microcapsule 12 is transferred to the transfer body and the transfer object is pressed and pasted. I did it.
○… Aroma drifted.
X ... The scent did not drift.

転写された感圧接着層13の被転写体と被転写物との接着性に関しては、被転写体に香料マイクロカプセル12を含有する感圧接着層13を転写させた後、被転写物を押圧して貼着させた直後に被転写物の剥離をおこない、被転写物の剥離状態を目視にて観察し、以下の判定基準により接着性の判定をおこなった。なお、被転写体および被転写物ともに試験体として再生コピーペーパー(中性紙、プラスステーショナリー株式会社製)を使用した。
○・・・被転写体より剥した際に、押圧転写された感圧接着層部分で被転写物が全面で破壊した。
×・・・被転写体より剥した際に、押圧転写された感圧接着層部分で被転写物が破壊しなかった。
Regarding the adhesion between the transferred pressure-sensitive adhesive layer 13 and the transferred material, the pressure-sensitive adhesive layer 13 containing the fragrance microcapsule 12 is transferred to the transferred material, and then the transferred material is pressed. Immediately after being adhered, the transferred object was peeled off, the peeled state of the transferred object was visually observed, and the adhesiveness was determined according to the following criteria. Note that recycled copy paper (neutral paper, manufactured by Plus Stationery Co., Ltd.) was used as a test body for both the transfer object and the transfer object.
○: When peeled off from the transferred material, the transferred material was destroyed on the entire surface in the pressure-sensitive adhesive layer portion that was pressure-transferred.
X: When peeled off from the transferred material, the transferred material was not broken at the pressure-sensitive adhesive layer portion that was pressure-transferred.

リール状に巻回されたれた転写式感圧接着テープ5でブロッキングの確認を行い、以下の判定基準によりブロッキングの判定をおこなった。
○・・・ブロッキングの発生がみられなかった。
×・・・ブロッキングの発生がみられた。
Blocking was confirmed with the transfer-type pressure-sensitive adhesive tape 5 wound in a reel shape, and blocking was determined according to the following criteria.
○: No blocking was observed.
X: Generation of blocking was observed.

実施例1〜実施例6の香料マイクロカプセル12を含有する感圧接着層13の乾燥後の厚みと感圧接着層13中の香料マイクロカプセル12の含有量の設定値および、前記評価結果を表2に示す。   Table 1 shows the thickness after drying of the pressure-sensitive adhesive layer 13 containing the fragrance microcapsules 12 of Examples 1 to 6 and the set value of the content of the fragrance microcapsule 12 in the pressure-sensitive adhesive layer 13 and the evaluation results. It is shown in 2.

Figure 2008069275
Figure 2008069275

表2より香料マイクロカプセル12の含有量が固形分として5重量パーセントより少ない場合には芳香性が得られなかった。また、感圧接着層13の厚みが5μmより薄い場合には接着性は得られず、また感圧接着層13の厚みが40μmより厚い場合には接着性は得られたがテープをリール状にした際にブロッキングが発生し、香料マイクロカプセル13の含有量が固形分として5〜20重量パーセントである場合、および香料マイクロカプセル13を含有した感圧接着層12の厚みが5〜40μmである場合において接着性および芳香性が得られ、2次的な機能が得られた。   According to Table 2, when the content of the fragrance microcapsule 12 was less than 5 weight percent as a solid content, no fragrance was obtained. Further, when the thickness of the pressure-sensitive adhesive layer 13 is less than 5 μm, no adhesiveness is obtained, and when the pressure-sensitive adhesive layer 13 is thicker than 40 μm, the adhesiveness is obtained but the tape is reeled. When blocking occurs, the content of the fragrance microcapsule 13 is 5 to 20 weight percent as a solid content, and the thickness of the pressure-sensitive adhesive layer 12 containing the fragrance microcapsule 13 is 5 to 40 μm Adhesiveness and fragrance were obtained, and secondary functions were obtained.

本発明の感圧接着層を転写する際に用いられる塗膜転写具の構成を示した図The figure which showed the structure of the coating-film transfer tool used when transferring the pressure-sensitive adhesive layer of this invention 本発明の香り付き転写式感圧接着テープの断面構造を示す模式的断面図Schematic sectional view showing the sectional structure of the scented transfer pressure-sensitive adhesive tape of the present invention 本発明の香り付き転写式感圧接着テープに配合される香料マイクロカプセルの断面構造を示す模式的断面図Typical sectional drawing which shows the cross-section of the fragrance | flavor microcapsule mix | blended with the transcription | transfer pressure-sensitive adhesive tape with a fragrance of this invention

符号の説明Explanation of symbols

1 塗膜転写具
2 ケース本体
3 支軸
4 支軸
5 転写式感圧接着テープ
6 繰出しリール
7 巻取りリール
8 押圧転写部
9 転写ヘッド
11 基材
12 香料マイクロカプセル
13 感圧接着層
21 香油
22 壁膜材
DESCRIPTION OF SYMBOLS 1 Coating film transfer tool 2 Case main body 3 Support shaft 4 Support shaft 5 Transfer-type pressure-sensitive adhesive tape 6 Feeding reel 7 Take-up reel 8 Press transfer part 9 Transfer head 11 Base material 12 Perfume microcapsule 13 Pressure sensitive adhesive layer 21 Perfume oil 22 Wall membrane material

Claims (3)

外枠を構成するケース内に繰出し部と巻取り部と押圧転写部とを備え、前記繰出し部よりリール状に巻回された転写テープが繰り出され、前記押圧転写部を経て前記巻取り部に巻き取られるように構成した自動巻取り式の塗膜転写具において、前記転写テープが基材上に粘着剤からなる感圧接着層を形成し、かつ前記感圧接着層中に香料マイクロカプセルを含有したことを特徴とする香り付き転写式感圧接着テープ。   The case constituting the outer frame is provided with a feeding portion, a winding portion, and a pressure transfer portion, and a transfer tape wound in a reel shape is fed from the feeding portion, and passes through the pressure transfer portion to the winding portion. In a self-winding film transfer tool configured to be wound, the transfer tape forms a pressure-sensitive adhesive layer made of an adhesive on a substrate, and a perfume microcapsule is placed in the pressure-sensitive adhesive layer. A scented transfer-type pressure-sensitive adhesive tape characterized by containing. 前記香料マイクロカプセルが前記感圧接着層中の固形分として5〜20重量パーセントとなるように配合されたことを特徴とする請求項1の香り付き転写式感圧接着テープ。   The scented transfer pressure-sensitive adhesive tape according to claim 1, wherein the fragrance microcapsule is blended so as to be 5 to 20 weight percent as a solid content in the pressure-sensitive adhesive layer. 前記香料マイクロカプセルを含有した感圧接着層の厚みが5〜40μmであることを特徴とする請求項1もしくは請求項2の香り付き転写式感圧接着テープ。   The scented transfer pressure-sensitive adhesive tape according to claim 1 or 2, wherein the pressure-sensitive adhesive layer containing the fragrance microcapsule has a thickness of 5 to 40 µm.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016190904A (en) * 2015-03-30 2016-11-10 トッパン・フォームズ株式会社 Adhesive sheet for wall surface
JP2020090590A (en) * 2018-12-04 2020-06-11 リンテック株式会社 Pressure-sensitive adhesive sheet

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JPS61169237A (en) * 1985-01-24 1986-07-30 ミネソタ マイニング アンド マニユフアクチユアリング コンパニー Stripping sheet pad
JPH06239062A (en) * 1993-02-16 1994-08-30 Dainippon Printing Co Ltd Printed matter emitting smell upon peeling
JPH0827433A (en) * 1994-07-20 1996-01-30 General Kk Tacky agent and tool for transfer tacky agent
JPH08207561A (en) * 1995-02-02 1996-08-13 Lintec Corp Aromatic, deodorant and shade net
JP2001192625A (en) * 2000-01-06 2001-07-17 Tombow Pencil Co Ltd Pressure-sensitive transfer type tacky tape
JP2003191925A (en) * 2001-12-27 2003-07-09 Seed:Kk Mark transfer tool, mark transfer tape, and manufacturing method for the mark transfer tape

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61169237A (en) * 1985-01-24 1986-07-30 ミネソタ マイニング アンド マニユフアクチユアリング コンパニー Stripping sheet pad
JPH06239062A (en) * 1993-02-16 1994-08-30 Dainippon Printing Co Ltd Printed matter emitting smell upon peeling
JPH0827433A (en) * 1994-07-20 1996-01-30 General Kk Tacky agent and tool for transfer tacky agent
JPH08207561A (en) * 1995-02-02 1996-08-13 Lintec Corp Aromatic, deodorant and shade net
JP2001192625A (en) * 2000-01-06 2001-07-17 Tombow Pencil Co Ltd Pressure-sensitive transfer type tacky tape
JP2003191925A (en) * 2001-12-27 2003-07-09 Seed:Kk Mark transfer tool, mark transfer tape, and manufacturing method for the mark transfer tape

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016190904A (en) * 2015-03-30 2016-11-10 トッパン・フォームズ株式会社 Adhesive sheet for wall surface
JP2020090590A (en) * 2018-12-04 2020-06-11 リンテック株式会社 Pressure-sensitive adhesive sheet
JP7242276B2 (en) 2018-12-04 2023-03-20 リンテック株式会社 Adhesive sheet

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