JP2008029781A - Antibacterial deodorizing agent, and antibacterial deodorizing method using the same - Google Patents
Antibacterial deodorizing agent, and antibacterial deodorizing method using the same Download PDFInfo
- Publication number
- JP2008029781A JP2008029781A JP2006227144A JP2006227144A JP2008029781A JP 2008029781 A JP2008029781 A JP 2008029781A JP 2006227144 A JP2006227144 A JP 2006227144A JP 2006227144 A JP2006227144 A JP 2006227144A JP 2008029781 A JP2008029781 A JP 2008029781A
- Authority
- JP
- Japan
- Prior art keywords
- antibacterial
- deodorant
- component
- reaction heat
- orthophenylphenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 66
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims description 14
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims abstract description 14
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 claims abstract description 12
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims abstract description 12
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 claims abstract description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 claims abstract description 10
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000010292 orthophenyl phenol Nutrition 0.000 claims abstract description 7
- 239000004306 orthophenyl phenol Substances 0.000 claims abstract description 7
- WADQOGCINABPRT-UHFFFAOYSA-N 3-chloro-2-methylphenol Chemical compound CC1=C(O)C=CC=C1Cl WADQOGCINABPRT-UHFFFAOYSA-N 0.000 claims abstract description 6
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 claims abstract description 6
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940067596 butylparaben Drugs 0.000 claims abstract description 6
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 claims abstract description 6
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 claims abstract description 6
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 claims abstract description 6
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 claims abstract description 6
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 claims abstract description 6
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- UQPLZHUFLPDORW-UHFFFAOYSA-N 2-phenylphenol;sodium Chemical compound [Na].OC1=CC=CC=C1C1=CC=CC=C1 UQPLZHUFLPDORW-UHFFFAOYSA-N 0.000 claims description 4
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- VHBFFQKBGNRLFZ-UHFFFAOYSA-N vitamin p Natural products O1C2=CC=CC=C2C(=O)C=C1C1=CC=CC=C1 VHBFFQKBGNRLFZ-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本発明は、抗菌消臭剤及びそれを用いた抗菌消臭方法に関し、さらに詳しくは燃焼によらない間接的な加熱で容易に揮散でき、使用時の人体への危険も回避できる抗菌消臭剤及びそれを用いた抗菌消臭方法に関するものである。
本発明の抗菌消臭剤は、屋内、室内、畜舎、鶏舎内、中でも自動車等の車両の車内、特にエアコン内やその通風路に用いて好適なものである。TECHNICAL FIELD The present invention relates to an antibacterial deodorant and an antibacterial deodorant method using the same, and more particularly, an antibacterial deodorant that can be easily volatilized by indirect heating not involving combustion and can avoid danger to the human body during use. And an antibacterial deodorizing method using the same.
The antibacterial deodorant of the present invention is suitable for use indoors, indoors, in livestock houses, poultry houses, especially in vehicles such as automobiles, especially in air conditioners and in their ventilation paths.
従来、屋内環境の清浄化用品としては、点火して燃焼させ、薬剤成分を加熱により発散させるものが提案されているが（特許文献１、２参照）、火災発生の危険を伴うなど安全上問題があった。
また、スプレー式のものもあるが、ワンタッチで使い勝手がよいものの、人体に有害な薬剤成分を含むスプレーガスを使用者が吸い込む危険性を伴うのを免れないという問題がある。Conventionally, products for cleaning indoor environments that have been ignited and combusted to dissipate chemical components by heating have been proposed (see Patent Documents 1 and 2). was there.
Although there are spray types, there is a problem that although it is easy to use with a single touch, there is a risk that the user is in danger of inhaling spray gas containing a chemical component harmful to the human body.
本発明は、このような事情の下、燃焼によらない間接的な加熱で容易に揮散でき、使用時の人体への危険も回避できる抗菌消臭剤を提供することを課題とするものである。 Under such circumstances, it is an object of the present invention to provide an antibacterial deodorant that can be easily volatilized by indirect heating that does not depend on combustion and that can avoid danger to the human body during use. .
本発明者らは、前記した好ましい特性を有する抗菌消臭剤を開発するために種々研究を重ねた結果、特定の抗菌剤と加熱にて揮散しやすい特定の消臭剤とを併用することによって課題が達成されることを見出し、この知見に基いて本発明をなすに至った。 As a result of repeating various studies in order to develop an antibacterial deodorant having the above-described preferable characteristics, the present inventors have used a specific antibacterial agent and a specific deodorant that easily evaporates by heating. The present inventors have found that the object can be achieved, and have made the present invention based on this finding.
すなわち、本発明は以下に示すとおりのものである。
（１） パラクロロフェノール、クロロフェン、オルトフェニルフェノール、オルトフェニルフェノールナトリウム、パラクレゾール、オルトクレゾール、メタクレゾール、４−クロロ−３，５−ジメチルフェノール、２−メチル−３−クロロフェノール、プロピルパラベン、メチルパラベン、エチルパラベン、ブチルパラベン、フェノール、イソプロピルメチルフェノール、２−イソプロピル−５−メチルフェノール、パラクロロフェニル−３−ヨウ化プロパギルフォルマール、２−（４−チアゾリル）ベンゾイミダゾール、２−（４−チオシアノメチルチオ）ベンゾチアゾール、２，４，４’−トリクロロ−２−ヒドロキシジフェニル、８−キノリノール、安息香酸、安息香酸ナトリウム、α−ブロモシンナムアルデヒド、α−［２−（４−クロロフェニル）エチル］−α−（１，１−ジメチルエチル）−１Ｈ−１，２，４−トリアゾール−１−エタノール、及びテトラクロロイソフタロニトリルの中から選ばれた少なくとも１種の抗菌成分と５０℃〜３５０℃の温度範囲内にて揮散する、分子量４００以下のポリフェノール系物質からなる消臭成分とを含有することを特徴とする抗菌消臭剤。
（２） さらに香料を含有する前記（１）記載の抗菌消臭剤。
（３） 前記（１）又は（２）記載の抗菌消臭剤を反応熱により間接的に加熱して消臭成分及び抗菌成分を屋内、室内、畜舎、鶏舎内に揮散させ、消臭・除菌することを特徴とする抗菌消臭方法。
（４） 前記（１）又は（２）記載の抗菌消臭剤を反応熱により間接的に加熱して消臭成分及び抗菌成分を車内に揮散させ、消臭・除菌することを特徴とする抗菌消臭方法。
（５） 前記（１）又は（２）記載の抗菌消臭剤を反応熱により間接的に加熱して消臭成分及び抗菌成分をエアコンやその通風路内に揮散させ、消臭・除菌することを特徴とする抗菌消臭方法。
（６） 反応熱が、酸化カルシウムと水との反応熱である前記（３）〜（５）のいずれかに記載の抗菌消臭方法。That is, the present invention is as follows.
(1) Parachlorophenol, chlorophene, orthophenylphenol, sodium orthophenylphenol, paracresol, orthocresol, metacresol, 4-chloro-3,5-dimethylphenol, 2-methyl-3-chlorophenol, propylparaben , Methylparaben, ethylparaben, butylparaben, phenol, isopropylmethylphenol, 2-isopropyl-5-methylphenol, parachlorophenyl-3-iodinated propargyl formal, 2- (4-thiazolyl) benzimidazole, 2- (4 -Thiocyanomethylthio) benzothiazole, 2,4,4'-trichloro-2-hydroxydiphenyl, 8-quinolinol, benzoic acid, sodium benzoate, α-bromocinnamaldehyde, α- [2- (4- (Rolophenyl) ethyl] -α- (1,1-dimethylethyl) -1H-1,2,4-triazole-1-ethanol, and at least one antibacterial component selected from tetrachloroisophthalonitrile and 50 An antibacterial deodorant containing a deodorizing component composed of a polyphenol-based substance having a molecular weight of 400 or less, which volatilizes within a temperature range of from ° C to 350 ° C.
(2) The antibacterial deodorant according to (1), further containing a fragrance.
(3) The antibacterial deodorant described in (1) or (2) is indirectly heated by reaction heat to volatilize the deodorant component and the antibacterial component indoors, indoors, livestock houses, poultry houses, An antibacterial deodorizing method characterized by fungi.
(4) The antibacterial deodorant described in (1) or (2) is indirectly heated by reaction heat to volatilize the deodorant component and the antibacterial component into the vehicle to deodorize and disinfect. Antibacterial deodorization method.
(5) The antibacterial deodorant described in the above (1) or (2) is indirectly heated by reaction heat to volatilize the deodorant component and the antibacterial component in the air conditioner and its ventilation path, and deodorize and disinfect the bacteria. An antibacterial deodorizing method characterized by that.
(6) The antibacterial deodorization method according to any one of (3) to (5), wherein the reaction heat is a reaction heat between calcium oxide and water.
以下、本発明を具体的に説明する。
本発明の抗菌消臭剤は、特定の抗菌成分と、５０℃〜３５０℃の温度範囲内にて揮散する、分子量４００以下のポリフェノール系物質からなる易揮散性消臭成分とを含有することで特徴付けられる。The present invention will be specifically described below.
The antibacterial deodorant of the present invention contains a specific antibacterial component and an easily volatile deodorant component that is volatilized within a temperature range of 50 ° C. to 350 ° C. and is made of a polyphenol-based material having a molecular weight of 400 or less. Characterized.
本発明の抗菌消臭剤に用いられる消臭成分は、分子量４００以下のポリフェノール系物質であればよく、中でも５０℃〜３５０℃の温度範囲内にて揮散する易揮散性のもの、例えばフラボン、クリシン、ケンペロール、フィセチン、モリン、クエルセチン、ミリセチン、クエルセタゲチン、フラビニウム、フラボノール、イソフラボン、フラバン、フラバノール、フラバノン、フラバノノール、カルコン、アントシアニン、アントシアニジン、ケルセチン、（−）−エピガロカテキン−３−ガレート、（−）−エピガロカテキン、（−）−エピカテキン−３−ガレート、（−）−エピカテキン、プロシアニジン、ガリック酸、エラジックアシド、カテコール、ピロガロール、ガリック酸誘導体（例えば、２，３，４−トリヒドロキシベンゾフェノン、２，３，４，４’−テトラヒドロキシベンゾフェノン、２，２’３，４，４’−ペンタヒドロキシベンゾフェノン、２，３，３’４，４’５’−ヘキサヒドロキシベンゾフェノン等）、メチルガレート、エチルガレート、プロピルガレート、エモジン、フスチオン、クリソファノール、オブッシフォリン、オブツシン、アロエエモジン（アントラキノン類）、アピゲニン、ローズマリー酸、カフェー酸、ルブロフサリン、ノルルブロフサリン（ナフトロピン誘導体）、トラクリソン、トララクトン、トロキサクリソンなどが好ましく、特にフラバノール、アピゲニン、エモジン、アロエエモジン、ガリック酸が、分子量が１７０〜２７０と小さく、加熱により揮散し易く、昇華する物質もあり、消臭効果を発揮しやすい為、好ましい。これらは単独で用いてもよいし、また２種以上を組み合わせて用いてもよい。 The deodorant component used in the antibacterial deodorant of the present invention may be a polyphenol-based material having a molecular weight of 400 or less, among others, an easily volatile material that volatilizes within a temperature range of 50 ° C. to 350 ° C., such as flavone, Chrysin, kaempferol, fisetin, morin, quercetin, myricetin, quercetagetin, flavinium, flavonol, isoflavone, flavan, flavanol, flavanone, flavanonol, chalcone, anthocyanin, anthocyanidin, quercetin, (-)-epigallocatechin-3-gallate, (- ) -Epigallocatechin, (−)-epicatechin-3-gallate, (−)-epicatechin, procyanidin, gallic acid, elastic acid, catechol, pyrogallol, gallic acid derivatives (eg 2,3,4-trihydroxybenzo F Non, 2,3,4,4′-tetrahydroxybenzophenone, 2,2′3,4,4′-pentahydroxybenzophenone, 2,3,3′4,4′5′-hexahydroxybenzophenone, etc.), methyl Gallate, ethyl gallate, propyl gallate, emodin, fustion, chrysophanol, obsifoline, obtusin, aloe emodin (anthraquinones), apigenin, rosemary acid, caffeic acid, rubrofusarin, norlubrofusarin (naphthopine derivative), trachrisone, tralactone, troxacrison In particular, flavanol, apigenin, emodin, aloe emodin, and gallic acid are preferable because they have a molecular weight as small as 170 to 270, are easily volatilized by heating, and have a sublimation substance and easily exhibit a deodorizing effect.These may be used alone or in combination of two or more.
また、ポリフェノール系物質には、タンニンと呼ばれるものがあるが、そのうちでも「加水分解性タンニン」は分解によりガリック酸とブドウ糖になるため、加熱によってこのような分解物を生じる可能性のあるタンニン、例えば、タンニン酸、ゲンノショウコ、チョウジなども用いられる。 In addition, there are polyphenolic substances called tannins, but among them, “hydrolyzable tannins” become gallic acid and glucose by decomposition, so that tannins that can produce such decomposition products by heating, For example, tannic acid, gentian pepper, clove and the like are also used.
本発明の抗菌消臭剤に用いられる抗菌成分は、パラクロロフェノール、クロロフェン、オルトフェニルフェノール、オルトフェニルフェノールナトリウム、パラクレゾール、オルトクレゾール、メタクレゾール、４−クロロ−３，５−ジメチルフェノール、２−メチル−３−クロロフェノール、プロピルパラベン、メチルパラベン、エチルパラベン、ブチルパラベン、フェノール、イソプロピルメチルフェノール、２−イソプロピル−５−メチルフェノール、パラクロロフェニル−３−ヨウ化プロパギルフォルマール、２−（４−チアゾリル）ベンゾイミダゾール、２−（４−チオシアノメチルチオ）ベンゾチアゾール、２，４，４’−トリクロロ−２−ヒドロキシジフェニル、８−キノリノール、安息香酸、安息香酸ナトリウム、α−ブロモシンナムアルデヒド、α−［２−（４−クロロフェニル）エチル］−α−（１，１−ジメチルエチル）−１Ｈ−１，２，４−トリアゾール−１−エタノール、テトラクロロイソフタロニトリルであり、好ましくは、薬剤としての適度な揮散性、持続性等を考慮すると、分子量２５０以下のパラクロロフェノール、オルトフェニルフェノール、オルトフェニルフェノールナトリウム、パラクレゾール、オルトクレゾール、メタクレゾール、４−クロロ−３，５−ジメチルフェノール、２−メチル−３−クロロフェノール、プロピルパラベン、メチルパラベン、エチルパラベン、ブチルパラベン、フェノール、イソプロピルメチルフェノール、２−イソプロピル−５−メチルフェノール、８−キノリノール、安息香酸、安息香酸ナトリウム、２−（４−チアゾリル）ベンゾイミダゾール等が、さらに、経口毒性等の安全性を考慮すると、オルトフェニルフェノール、メタクレゾール、４−クロロ−３，５−ジメチルフェノール、２−メチル−３−クロロフェノール、プロピルパラベン、メチルパラベン、エチルパラベン、ブチルパラベン、イソプロピルメチルフェノール、８−キノリノール、安息香酸ナトリウム、２−（４−チアゾリル）ベンゾイミダゾール等が用いられる。
また、消臭効果をも併せ持つもの、例えば、ヒノキチオール等の植物精油、ハッカ、ローズマリー、ユーカリ、ラベンダー、ティーツリー、ジャスミン、ネロリ、ゼラニウムなども用いられる。
これらは単独で用いてもよいし、また２種以上を組み合わせて用いてもよい。Antibacterial components used in the antibacterial deodorant of the present invention are parachlorophenol, chlorophene, orthophenylphenol, sodium orthophenylphenol, paracresol, orthocresol, metacresol, 4-chloro-3,5-dimethylphenol, 2-methyl-3-chlorophenol, propylparaben, methylparaben, ethylparaben, butylparaben, phenol, isopropylmethylphenol, 2-isopropyl-5-methylphenol, parachlorophenyl-3-iodinated propargyl formal, 2- ( 4-thiazolyl) benzimidazole, 2- (4-thiocyanomethylthio) benzothiazole, 2,4,4′-trichloro-2-hydroxydiphenyl, 8-quinolinol, benzoic acid, sodium benzoate, α-bromo Nnamaldehyde, α- [2- (4-chlorophenyl) ethyl] -α- (1,1-dimethylethyl) -1H-1,2,4-triazole-1-ethanol, tetrachloroisophthalonitrile, preferably In view of moderate volatility and durability as a drug, parachlorophenol having a molecular weight of 250 or less, orthophenylphenol, sodium orthophenylphenol, paracresol, orthocresol, metacresol, 4-chloro-3,5 -Dimethylphenol, 2-methyl-3-chlorophenol, propylparaben, methylparaben, ethylparaben, butylparaben, phenol, isopropylmethylphenol, 2-isopropyl-5-methylphenol, 8-quinolinol, benzoic acid, sodium benzoate, 2- ( -Thiazolyl) benzimidazole, etc., further considering safety such as oral toxicity, orthophenylphenol, metacresol, 4-chloro-3,5-dimethylphenol, 2-methyl-3-chlorophenol, propylparaben, Methylparaben, ethylparaben, butylparaben, isopropylmethylphenol, 8-quinolinol, sodium benzoate, 2- (4-thiazolyl) benzimidazole and the like are used.
Moreover, what has a deodorizing effect, for example, plant essential oils, such as hinokitiol, mint, rosemary, eucalyptus, lavender, tea tree, jasmine, neroli, geranium, etc. are also used.
These may be used alone or in combination of two or more.
また、本発明の抗菌消臭剤においては、必要に応じ、その組成成分の臭気や、悪臭物質の臭気をマスキングするため、香料を添加配合してもよい。香料の例としては、リモネン、ゲラニオール、ピネン、シトロネラール、ミルセン、バニリン、フェネチルアルコール、酢酸ゲラニル、サリチル酸ベンジル、リナロール、ローズ油、レモン油、ジャスミン油、スペアミント油、酢酸イソペンチル、ターピノレン、ターピネン、フェランドレン、カリオフィレン、フェルネセン、ジフェニルメタン、ヘキセノール、デセノール、ウンデセノール、ノナジエノール、ネロール、ヒドロキシシトロネロール、ジヒドロミルセノール、ボルネオール、イソプレゴール、ファルネソール、ネロリドール、４−イソプロピルシクロヘキサノール、ジメチルベンジルカルビノール、１−メチル−１−メトキシシクロドデカン、ベンジルイソオイゲノール、トリメチルヘキシルアルデヒド、イソシクロシトラール、メチルノニルケトン、フラクトン、エチレンブラシレート、６−アセチルヘキサテトラリンなどが挙げられる。中でも、香料と消臭成分の機能、すなわちマスキングと消臭効果を併せ持つもの、例えばヒノキチオールのような植物精油等を含有させるのがよい。
これらは単独で用いてもよいし、また２種以上を組み合わせて用いてもよい。Moreover, in the antibacterial deodorant of this invention, in order to mask the odor of the component and the odor of a malodorous substance, you may add and mix | blend a fragrance | flavor as needed. Examples of perfumes include limonene, geraniol, pinene, citronellal, myrcene, vanillin, phenethyl alcohol, geranyl acetate, benzyl salicylate, linalool, rose oil, lemon oil, jasmine oil, spearmint oil, isopentyl acetate, tarpinolene, tarpinene, ferrandolene , Caryophyllene, fernesene, diphenylmethane, hexenol, decenol, undecenol, nonadienol, nerol, hydroxycitronellol, dihydromyrsenol, borneol, isopulegol, farnesol, nerolidol, 4-isopropylcyclohexanol, dimethylbenzyl carbinol, 1-methyl-1 -Methoxycyclododecane, benzylisoeugenol, trimethylhexyl aldehyde, isocyclocitola Le, methyl nonyl ketone, fractons, ethylene brassylate, such as 6-acetyl-hexamethylene tetralin and the like. Especially, it is good to contain what has the function of a fragrance | flavor and a deodorizing component, ie, a masking and a deodorizing effect, for example, plant essential oils, such as hinokitiol.
These may be used alone or in combination of two or more.
本発明の抗菌消臭剤において、各成分の配合割合は、使用目的、用途等により変動するが、一般的には抗菌成分と消臭成分との相互間で、モル比で、抗菌成分：消臭成分＝１：２〜２：１の範囲で選ばれる。 In the antibacterial deodorant of the present invention, the blending ratio of each component varies depending on the purpose of use, application, etc., but in general, the antibacterial component: Odor component is selected in the range of 1: 2 to 2: 1.
本発明の抗菌消臭剤を使用するに際しては、化学反応による発熱を利用して薬剤成分を間接的に加熱するのがよい。
すなわち、本発明の抗菌消臭剤を用いて消臭除菌するには、抗菌消臭剤を反応熱により間接的に加熱して消臭成分及び抗菌成分を屋内、室内、畜舎、鶏舎内に揮散させ、消臭除菌する方法が一般的であり、好ましくは、抗菌消臭剤を反応熱により間接的に加熱して消臭成分及び抗菌成分を車内に揮散させ、消臭・除菌する方法や、抗菌消臭剤を反応熱により間接的に加熱して消臭成分及び抗菌成分をエアコンやその通風路内に揮散させ、消臭・除菌する方法が用いられる。When the antibacterial deodorant of the present invention is used, it is preferable to indirectly heat the drug component using heat generated by a chemical reaction.
That is, in order to deodorize and sterilize using the antibacterial deodorant of the present invention, the antibacterial deodorant is indirectly heated by reaction heat, and the deodorant component and the antibacterial component are placed indoors, indoors, barns, poultry houses The method of volatilizing and deodorizing and sterilizing is common, and preferably, the antibacterial deodorant is indirectly heated by reaction heat to volatilize the deodorant component and antibacterial component into the vehicle to deodorize and sterilize A method or a method in which an antibacterial deodorant is indirectly heated by reaction heat to volatilize the deodorant component and the antibacterial component in an air conditioner or the ventilation path thereof to deodorize and disinfect the bacteria is used.
その際、用いられる反応熱は、化学反応により発生する発熱であり、中でも酸化カルシウムと水との反応熱が好ましい。
化学反応により発熱する発熱物質としては、例えば酸化カルシウム、塩化マグネシウム、塩化アルミニウム、塩化カルシウム、塩化鉄等水を添加するだけで発熱反応する加水発熱型のもの、空気中での酸化反応で発熱する空気酸化発熱型のものなどが挙げられ、中でも酸化カルシウムが、十分な加熱温度が得られるので好ましい。In this case, the reaction heat used is heat generated by a chemical reaction, and among them, the reaction heat between calcium oxide and water is preferable.
Examples of exothermic substances that generate heat by chemical reaction include hydrothermal exothermic substances that react exothermically by simply adding water, such as calcium oxide, magnesium chloride, aluminum chloride, calcium chloride, and iron chloride. Examples include an air oxidation exothermic type, among which calcium oxide is preferable because a sufficient heating temperature can be obtained.
間接的に加熱するのを、例えば、加水発熱型の発熱物質を用いた場合について具体的に説明すると、以下のとおりである。
すなわち、抗菌剤や、消臭剤等の薬剤は粒状の形態で用いられ、金属等の伝熱材製の容器、例えばアルミ缶等の金属缶などの中に収容される。該容器は、上面が開放されているか、あるいは上部、例えば着脱自在の天板部等に外気と連通する適当な開口を有し、また、少なくとも底部が空間部を有する二重構造に形成され、底部側面は発熱物質や水を供給しうる開口端部を有する供給部に連接され、底部の空間部に発熱物質を供給部から入れ、さらに水を供給部から入れると、発熱反応が起こり、この熱は容器の壁、例えば底壁等を通して粒状薬剤に伝達され、このようにして粒状薬剤は間接的に加熱される。
加熱された粒状薬剤は揮散され、容器開口から放散される。The indirect heating will be specifically described below, for example, in the case of using a heating exothermic substance.
That is, agents such as antibacterial agents and deodorants are used in a granular form and are accommodated in a container made of a heat transfer material such as metal, for example, a metal can such as an aluminum can. The container is formed in a double structure in which the upper surface is open or has an appropriate opening communicating with the outside air at the upper part, for example, a removable top plate part, and at least the bottom part has a space part, The bottom side surface is connected to a supply part having an open end that can supply exothermic material and water. When exothermic material is introduced into the space of the bottom part from the supply part and water is further introduced from the supply part, an exothermic reaction takes place. Heat is transferred to the granular drug through the container wall, such as the bottom wall, and thus the granular drug is indirectly heated.
The heated granular medicine is volatilized and diffused from the container opening.
本発明の抗菌消臭剤によれば、燃焼によらない間接的な加熱で容易に揮散でき、使用時の人体への危険も回避できる上に、抗菌性、抗菌持続性、消臭性、消臭持続性のいずれにも優れるという顕著な効果が奏される。 According to the antibacterial deodorant of the present invention, it can be easily volatilized by indirect heating not based on combustion, the danger to the human body during use can be avoided, and antibacterial properties, antibacterial durability, deodorant properties, The remarkable effect that it is excellent in both of odor persistence is show | played.
次に実施例により本発明を実施するための最良の形態を説明するが、本発明はこれらの例により何ら限定されるものではない。
なお、各例において、抗菌消臭剤の各成分の配合割合はモル基準のものである。Next, the best mode for carrying out the present invention will be described by way of examples, but the present invention is not limited to these examples.
In addition, in each example, the mixture ratio of each component of an antibacterial deodorant is a molar basis.
実施例１〜４
各成分を表１に示す配合割合で混合して抗菌消臭剤試料を調製した。
各試料について以下の各種試験を行い、評価した。その結果も表１に示す。Examples 1-4
Each component was mixed at a blending ratio shown in Table 1 to prepare an antibacterial deodorant sample.
Each sample was subjected to the following various tests and evaluated. The results are also shown in Table 1.
各成分を表２に示す配合割合で混合して比較のための抗菌消臭剤試料を調製した。
各試料について以下の各種試験を行い、評価した。その結果も表２に示す。The antibacterial deodorant sample for comparison was prepared by mixing each component at the blending ratio shown in Table 2.
Each sample was subjected to the following various tests and evaluated. The results are also shown in Table 2.
（抗菌性）
各試料を、大腸菌を接種した普通寒天培地及び黒麹黴胞子懸濁液を接種したポテトデキストロース寒天培地とともに容器内に封入し、３０℃で３日間放置した後、開封して微生物の繁殖状態を目視で確認し、以下の基準で評価した。なお、各培地の寸法形状は互いに全く同じである。
○ 繁殖せず
△ 少数繁殖（両培地の全表面積に対するコロニー面積が５０％を超えないコロニーを認める）
× 多数繁殖（両培地の全表面積に対するコロニー面積が５０％を超えるコロニーを認める）(Antibacterial)
Each sample was sealed in a container together with a normal agar medium inoculated with E. coli and a potato dextrose agar medium inoculated with a black spore suspension, left at 30 ° C. for 3 days, and then opened to check the propagation state of the microorganism. It confirmed visually and evaluated by the following references | standards. In addition, the dimension shape of each culture medium is the same mutually.
○ No breeding △ Minority breeding (The colony area with respect to the total surface area of both mediums does not exceed 50%)
× Large number of breeding (colonies with a total area of more than 50% of the total surface area of both media are recognized)
（抗菌持続性）
予め２５℃の室内にて２週間放置させた各試料を、大腸菌を接種した普通寒天培地及び黒麹黴胞子懸濁液を接種したポテトデキストロース寒天培地とともに容器内に封入し、３０℃で３日間放置した後、開封して微生物の繁殖状態を目視で確認し、以下の基準で評価した。なお、各培地の寸法形状は互いに全く同じである。
○ 繁殖せず
△ 少数繁殖（両培地の全表面積に対するコロニー面積が５０％を超えないコロニーを認める）
× 多数繁殖（両培地の全表面積に対するコロニー面積が５０％を超えるコロニーを認める）(Antimicrobial persistence)
Each sample that had been allowed to stand in a room at 25 ° C. for 2 weeks in advance was sealed in a container together with a normal agar medium inoculated with E. coli and a potato dextrose agar medium inoculated with black spore suspension, and then at 30 ° C. for 3 days. After leaving, it was opened and the propagation state of microorganisms was visually confirmed, and evaluated according to the following criteria. In addition, the dimension shape of each culture medium is the same mutually.
○ No breeding △ Minority breeding (The colony area with respect to the total surface area of both mediums does not exceed 50%)
× Large number of breeding (colonies with a total area of more than 50% of the total surface area of both media are recognized)
（消臭性）
上記抗菌性評価試験後の容器中に発生した悪臭分濃度をガス検知管にて測定し、この濃度について、各試料を用いない他は上記抗菌性評価試験と同様にして比較した場合の同様の悪臭分濃度に対する割合を消臭率として求め、以下の基準で評価した。
○ 消臭率 ８０％以上
△ 消臭率 ４０％以上８０％未満
× 消臭率 ４０％未満(Deodorant)
The malodorous concentration generated in the container after the antibacterial evaluation test is measured with a gas detector tube, and this concentration is the same as in the case of comparison in the same manner as in the antibacterial evaluation test except that each sample is not used. The ratio to the malodorous concentration was determined as the deodorization rate and evaluated according to the following criteria.
○ Deodorization rate 80% or more △ Deodorization rate 40% or more and less than 80% × Deodorization rate less than 40%
（消臭持続性）
上記抗菌持続性評価試験後の容器中に発生した悪臭濃度をガス検知管にて測定し、この濃度について、各試料を用いない他は上記抗菌持続性評価試験と同様にして比較した場合の同様の悪臭分濃度に対する割合を消臭率として求め、以下の基準で評価した。
○ 消臭率 ８０％以上
△ 消臭率 ４０％以上８０％未満
× 消臭率 ４０％未満(Deodorant persistence)
The malodorous concentration generated in the container after the antibacterial sustainability evaluation test is measured with a gas detector tube, and this concentration is the same as when compared in the same manner as the antibacterial sustainability evaluation test except that each sample is not used. The ratio to the malodor concentration was determined as the deodorization rate and evaluated according to the following criteria.
○ Deodorization rate 80% or more △ Deodorization rate 40% or more and less than 80% × Deodorization rate less than 40%
以上より、実施例では抗菌性、抗菌持続性、消臭性、消臭持続性のいずれにも優れているのに対し、比較例ではこれらの少なくとも一つが悪い結果となることが分かる。 From the above, it can be seen that the examples are excellent in antibacterial properties, antibacterial persistence, deodorant properties, and deodorant persistence, whereas in the comparative examples, at least one of these results in a bad result.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011056144A (en) * | 2009-09-14 | 2011-03-24 | Shizuoka Prefecture | Deodorant having indicator function |
| WO2013051325A1 (en) | 2011-10-04 | 2013-04-11 | 住友ゴム工業株式会社 | Method for manufacturing pneumatic tires |
| JP2014217373A (en) * | 2013-04-12 | 2014-11-20 | 池田食研株式会社 | Method for producing rhodiola rosea plant extract |
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| JPS62204756A (en) * | 1986-03-04 | 1987-09-09 | 大研医工株式会社 | Drug volatilizing method and apparatus |
| JP2001178808A (en) * | 1999-12-27 | 2001-07-03 | Lion Corp | Aromatic deodorizer |
| JP2002263178A (en) * | 2001-03-09 | 2002-09-17 | Ishihara Chem Co Ltd | Stationary deodorant |
| JP2005103239A (en) * | 2003-09-09 | 2005-04-21 | Sumitomo Chemical Co Ltd | Deodorizing method, and deodorizing composition |
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| JP2001178808A (en) * | 1999-12-27 | 2001-07-03 | Lion Corp | Aromatic deodorizer |
| JP2002263178A (en) * | 2001-03-09 | 2002-09-17 | Ishihara Chem Co Ltd | Stationary deodorant |
| JP2005103239A (en) * | 2003-09-09 | 2005-04-21 | Sumitomo Chemical Co Ltd | Deodorizing method, and deodorizing composition |
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| JP2011056144A (en) * | 2009-09-14 | 2011-03-24 | Shizuoka Prefecture | Deodorant having indicator function |
| WO2013051325A1 (en) | 2011-10-04 | 2013-04-11 | 住友ゴム工業株式会社 | Method for manufacturing pneumatic tires |
| JP2014217373A (en) * | 2013-04-12 | 2014-11-20 | 池田食研株式会社 | Method for producing rhodiola rosea plant extract |
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