JP2008006798A - Wood magnetizing method - Google Patents

Wood magnetizing method Download PDF

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JP2008006798A
JP2008006798A JP2006205346A JP2006205346A JP2008006798A JP 2008006798 A JP2008006798 A JP 2008006798A JP 2006205346 A JP2006205346 A JP 2006205346A JP 2006205346 A JP2006205346 A JP 2006205346A JP 2008006798 A JP2008006798 A JP 2008006798A
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wood
iron material
iron
methane gas
solution
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Hiroshi Ito
氾之 伊藤
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a wood magnetizing method which utilizes such a phenomenon that an iron material dissolved in an aqueous methane gas solution, automatically permeates/deposits in the wood as if a matter falls. <P>SOLUTION: This method is employed to soak the iron material and the wood in the aqueous methane gas solution inside a closed container, then violently stir or vibrate the solution to cause the permeation and deposition of the eluted iron material inside the wood. Since this deposit has magnetic properties like the iron material as a raw material, it is possible to impart magnetic properties to the wood without providing a special treatment and impairing the appearance of the wood and nature of the wood main body. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は木材を磁性化処理する方法に関する。詳しくは密閉容器内でメタンガス水溶液に鉄材と木材を浸漬させ、液を激しく撹拌または振動させて鉄材を溶出させ、それが木材に吸収され、浸透、沈積する事を利用する木材を磁性化処理する方法に関する。ここで磁性化処理された木材とは、単純に木材が鉄材を吸収しているため永久磁石に吸引されるようになったものを云う。  The present invention relates to a method for magnetizing wood. Specifically, iron and wood are immersed in an aqueous methane gas solution in a sealed container, and the liquid is vigorously stirred or vibrated to elute the iron material, which is absorbed into the wood and permeates and deposits to magnetize the wood. Regarding the method. Here, the magnetized wood refers to wood that is attracted to a permanent magnet because the wood simply absorbs the iron material.

従来、鉄イオン等を木材に吸収させて、鉄に還元するか、または酸化鉄に変化させて磁性化処理する試みは木材の外観、および本体の組織をかなり破壊させてしまう等の不都合があった。  Conventionally, attempts to absorb iron ions, etc. into wood and reduce them to iron, or change them to iron oxide and magnetize them have the disadvantages of considerably destroying the appearance of the wood and the structure of the body. It was.

本発明は天然ガス輸送管の凝縮水が鉄管を溶解する現象と、この溶出した鉄材が木材に吸収、沈積したものが磁性を有する事を利用する木材を磁性化処理する方法である。  The present invention is a method of magnetizing wood using the phenomenon that the condensed water of the natural gas transport pipe dissolves the iron pipe and that the eluted iron material is absorbed and deposited on the wood and has magnetism.

可燃性天然ガスの輸送管は管内の温度、圧力の変化等で凝縮水が生じる場合輸送管が鉄製であると往々にして腐食される(例えば特許文献1)。これは凝縮水に基づく天然ガス水溶液がガス流で激しく撹拌、振動すると鉄を溶解するようになるためであって、これは実験室で可燃性天然ガスの主成分であるメタンガスを用いた実験で確認できる。  The combustible natural gas transport pipe is often corroded if the transport pipe is made of iron when condensed water is produced due to changes in temperature and pressure in the pipe (for example, Patent Document 1). This is because an aqueous solution of natural gas based on condensed water stirs vigorously and vibrates in the gas stream, so that iron is dissolved. This is an experiment using methane gas, which is the main component of combustible natural gas, in the laboratory. I can confirm.

即ち、オートクレーブに水と鉄材を収容しメタンガスを圧入すると先ずメタンガス水溶液が容易に生成する。該水溶液を激しく撹拌すると鉄材が溶解するようになる。該水溶液に木材を浸すと鉄材が木材に吸収され浸透、沈積する。かくして木材に沈積した鉄材は磁性を有し、木材全体が永久磁石に吸引されるようになる。  That is, when water and an iron material are accommodated in an autoclave and methane gas is injected, an aqueous methane gas solution is easily generated. When the aqueous solution is vigorously stirred, the iron material is dissolved. When wood is immersed in the aqueous solution, the iron material is absorbed into the wood and penetrates and deposits. Thus, the iron material deposited on the wood has magnetism, and the whole wood is attracted to the permanent magnet.

本発明は上記のように鉄材がイオン化ではなく別の形で溶解し、木材に吸収され磁性を有した状態で沈積する現象を利用した木材を磁性化処理する方法である。  As described above, the present invention is a method for magnetizing wood using a phenomenon in which an iron material is dissolved in another form, not ionized, and is absorbed in the wood and deposited in a magnetic state.

特開平 10−217208.  JP-A-10-217208.

本発明はメタンガス水溶液に鉄材と木材を共に入れ水溶液を激しく撹拌すると鉄材が溶出し木材に移動して浸透、沈積し、これが磁性を示す事を利用した木材を磁性化処理する方法である。
本発明は木材の外観その他の特性を損なわずに磁性化処理する方法を実現する事を目的とするものである。
The present invention is a method for magnetizing wood using the fact that iron material and wood are put together in an aqueous methane gas solution and the aqueous solution is vigorously stirred, the iron material is eluted, moves into the wood, penetrates and deposits, and this shows magnetism.
The object of the present invention is to realize a method of magnetizing without deteriorating the appearance and other characteristics of wood.

本発明は上記目的を達成するために密閉容器内でメタンガス水溶液に鉄材及び木材を浸潰して該水溶液を激しく撹拌すると鉄材を溶解し、これを木材が吸収することを利用した木材を磁性化処理する方法である。  In order to achieve the above-mentioned object, the present invention achieves the above object by immersing the iron material and wood in a methane gas aqueous solution in a sealed container, and vigorously stirring the aqueous solution to dissolve the iron material, and the wood is magnetized by utilizing the absorption of the wood. It is a method to do.

メタンガス水溶液を撹拌、振動させると鉄材を溶解するようになるがオートクレーブの場合は撹拌装置を使用する。一般の密閉容器では内部のメタンガス水溶液を取り出し外部ポンプで再圧入すること等で激しく循環または振動させることによっても鉄剤を溶解するようになる。  When the aqueous methane gas solution is stirred and vibrated, the iron material will be dissolved. In the case of an autoclave, a stirring device is used. In a general sealed container, the iron agent is also dissolved by vigorously circulating or vibrating by taking out the aqueous methane gas solution and re-pressing it with an external pump.

鉄材を溶解しているメタンガス水溶液は無色で標準単極電位は検出されずイオン溶液ではないことがわかる。溶解度を蒸発乾固法で測定すると常温でいずれの鉄材(市販試薬一級の鉄:Fe、酸化鉄:FeO、および四三酸化鉄:Fe)の溶解度も高温、高圧、では短時間で速く溶解するが、常温、常圧、長時間に置き換える事ができ、それらを限定することはできないものであった。It can be seen that the aqueous methane gas solution in which the iron material is dissolved is colorless and is not an ionic solution because the standard monopolar potential is not detected. When the solubility is measured by the evaporation to dryness method, the solubility of any iron material (commercial reagent first grade iron: Fe, iron oxide: FeO, and triiron tetroxide: Fe 3 O 4 ) at room temperature is short at high temperatures and high pressures. Although it dissolves quickly, it can be replaced at room temperature, normal pressure, and for a long time, and these cannot be limited.

オートクレーブの撹拌器の回転速度と鉄材の溶解度も相関関係は得られないが一例として回転速度を200rpmとしたとき、いずれの鉄材の溶解度も100〜150ppmであった。  Although the correlation between the rotational speed of the stirrer of the autoclave and the solubility of the iron material is not obtained, as an example, when the rotational speed was 200 rpm, the solubility of any iron material was 100 to 150 ppm.

ブランクテストとしてメタンガスの代わりに不活性ガスであるアルゴンガスを用いた試験では鉄材の溶解は認められなかった。従って、メタンガス水溶液は鉄材を特殊な形態にして溶解るものと思われる。  In the test using an argon gas, which is an inert gas instead of methane gas, as a blank test, no dissolution of the iron material was observed. Therefore, it seems that the aqueous methane gas solution dissolves iron material in a special form.

上記、メタンガス水溶液に溶解している鉄材は木材によく吸収される事が確認された。使用した木材は杉、檜、白樺、楢、楓等であったが一般にリグニンとセルロースで構成される木材全般に吸収されるものと思われる。  It was confirmed that the iron material dissolved in the methane gas aqueous solution was well absorbed by wood. The timber used was cedar, birch, white birch, birch, cocoon, etc., but it seems that it is generally absorbed by timber composed of lignin and cellulose.

木材の形状は長丸太、板状、大鋸屑等、任意な形状のものに使用できる。この水溶液に溶解している鉄材は木材に吸収されると即時に木材内部に沈着する。この状態の鉄材は原料鉄材と同様に磁性を有するものであり、木材全体が磁石に吸引されるものとなる。  The shape of the wood can be used for any shape such as long logs, plates, and large sawdust. When the iron material dissolved in the aqueous solution is absorbed by the wood, it immediately deposits inside the wood. The iron material in this state has magnetism like the raw material iron material, and the whole wood is attracted to the magnet.

本発明のメタンガス水溶液に溶解している鉄材と木材へ沈積する鉄材の形態は詳らかではないが、磁性化処理された木材を燃焼させると木材の深部まで吸収されている事がわかる。燃焼後の鉄材は二三酸化鉄:Feになり磁性が消える。Although the form of the iron material dissolved in the aqueous methane gas solution of the present invention and the iron material deposited on the wood is not detailed, it can be seen that when the magnetized wood is burned, it is absorbed to the deep part of the wood. The iron material after combustion becomes ferric oxide: Fe 2 O 3 and the magnetism disappears.

本発明は上述したように、メタンガス水溶液に溶解している鉄材が「物が落下するが如く」自動的に木材中に浸透沈積する現象を利用した木材を磁性化処理する方法である。  As described above, the present invention is a method for magnetizing wood using a phenomenon in which an iron material dissolved in an aqueous methane gas solution automatically permeates and deposits in wood as if an object falls.

かくして鉄材を吸収した木材は木質部に鉄材を蓄積しているものとみられ表面上は何ら障害も受けず、磁性を有するが何ら木材としての本来の性質を失ってはいないものであり単純に磁石に吸引されるものとなり、本来の目的どおりの磁性化処理されるという効果を発揮するものであった。  Thus, the wood that has absorbed the iron material seems to have accumulated the iron material in the wood part, and it does not suffer any obstacles on the surface, it has magnetism but does not lose its original properties as a wood, it simply becomes a magnet It was attracted and exhibited the effect of being magnetized as intended.

本発明はメタンガス水溶液に溶解している鉄材が木材に磁性を有した状態で移動、沈積する事を利用した木材を磁性化処理する方法である。この鉄材の溶出、溶液中の移動および木材中への沈積の動作が容易に行われるように装置を組立てる事が最良の形態である。  The present invention is a method for magnetizing wood using the fact that an iron material dissolved in a methane gas aqueous solution moves and deposits while the wood has magnetism. It is the best mode to assemble the apparatus so that the elution of the iron material, movement in the solution, and deposition in the wood can be easily performed.

密閉容器に鉄材及び磁性化処理を目的とする木材の原木または成型品を収容しこれらを浸漬する十分な量の水を入れ上部空間部の空気をメタンガスと置換し更にメタンガスを圧入できるようにする。内部の水を撹拌するか、外部ポンプで液を循環または振動を可能にする。加熱方法は外部加熱方式が便利である。  An airtight container is used to store iron materials and wood logs or molded products for the purpose of magnetizing, and a sufficient amount of water to immerse them is put in. The air in the upper space is replaced with methane gas so that methane gas can be injected. . Stir the internal water or allow the liquid to circulate or vibrate with an external pump. An external heating method is convenient for the heating method.

本発明を効率よく稼働させるために、密閉容器1で鉄材を溶解し密閉容器2で鉄材を木材に浸透、沈積させるために用い、容器1と容器2間で水溶液を循環させる装置を用いる場合には容器1と容器2は共にメタンガスを封入可能としておく必要がある。
次に実施例を示すが、本発明を限定するものではない。
In order to operate the present invention efficiently, when using a device for dissolving an iron material in a sealed container 1 and infiltrating and depositing the iron material in wood with a sealed container 2 and circulating an aqueous solution between the container 1 and the container 2 Both the container 1 and the container 2 must be able to enclose methane gas.
The following examples illustrate but do not limit the invention.

SUS316製、500mlのオートクレーブに鉄材(市販試薬一級の鉄:Feの粉末)5gと水250mlを採り、5x5x20mmの木材(白樺)の一片を入れ封をした。
内部の空気をメタンガスと置換し、続けて圧入し内部圧力を5MPa(ゲージ圧)とした。オートクレーブの撹拌器の回転速度は200rpm,温度を100℃にして2時間保持した。常温まで冷やし木材を取出し水洗、乾燥させた。この木材は永久磁石に吸引されるものであった。
In a 500 ml autoclave made of SUS316, 5 g of iron (commercial reagent first grade iron: Fe powder) and 250 ml of water were taken, and a piece of wood (white birch) of 5 × 5 × 20 mm was put and sealed.
The internal air was replaced with methane gas, and the pressure was continuously pressed to set the internal pressure to 5 MPa (gauge pressure). The rotation speed of the agitator of the autoclave was 200 rpm, the temperature was 100 ° C., and the mixture was held for 2 hours. The wood was cooled to room temperature, taken out, washed with water and dried. This wood was attracted by a permanent magnet.

本発明は磁性化処理した木材の提供であり、木材に信号を埋設することなどが容易であり通信事業、物資の輸送事業等に利用が可能である。  The present invention provides magnetically treated wood, and it is easy to embed a signal in the wood and can be used for a communication business, a transportation business of goods, and the like.

本発明の磁性化処理した大鋸屑等を燃焼させると木材が鉄材の触媒作用を得て完全燃焼するので低温用の燃料材料となる。  When the large sawdust or the like magnetized according to the present invention is burned, the wood obtains a catalytic action of the iron material and burns completely, so that it becomes a low temperature fuel material.

本発明の方法を応用し木材に鉄材以外の物質を吸収させて異質の木材を提供するする事が可能である。  By applying the method of the present invention, it is possible to provide foreign wood by absorbing materials other than iron materials into the wood.

本発明で使用されるメタンガスは云わばその物理的性質を利用するのみで燃料や原料としての化学的な性質は保持されるので非常に有利である。  The methane gas used in the present invention is very advantageous because it only uses its physical properties and retains its chemical properties as a fuel and raw material.

Claims (2)

密閉容器に鉄材、木材およびこれらを十分に浸漬する量の水を収容し、さらにメタンガスを圧入しメタンガス水溶液を生成して、該水溶液を撹拌または振動させて鉄材を溶出させ、木材に吸収させ浸透、沈積させることを特徴とする木材を磁性化処理する方法。  An airtight container is filled with iron, wood and a sufficient amount of water to immerse them, and methane gas is injected into it to form a methane gas aqueous solution. The aqueous solution is stirred or vibrated to elute the iron material and absorb it into the wood to penetrate. A method of magnetizing wood, characterized by depositing. 鉄材が金属鉄:Fe、酸化鉄:FeO、または四三酸化鉄:Feの少なくとも一種類の物質であることを特徴とする請求項1記載の木材を磁性化処理する方法。2. The method of magnetizing wood according to claim 1, wherein the iron material is at least one kind of metal iron: Fe, iron oxide: FeO, or triiron tetraoxide: Fe 3 O 4 .
JP2006205346A 2006-06-29 2006-06-29 Wood magnetizing method Pending JP2008006798A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114851332A (en) * 2022-05-31 2022-08-05 东北林业大学 Preparation method of wood robot with magnetic anisotropy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114851332A (en) * 2022-05-31 2022-08-05 东北林业大学 Preparation method of wood robot with magnetic anisotropy
CN114851332B (en) * 2022-05-31 2023-02-17 东北林业大学 Preparation method of wood robot with magnetic anisotropy

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